Corrosion Resistance of Acid Waste Drainline Piping and

KIMAX®

Corrosion Resistance of Acid Waste Drainline Piping and Vent Materials


Maximum Operating Temperature1

Materials:A – Very Good Service to oper.

limit of material. (see table)B – Moderate ServiceC – Limited or Variable ServiceF – Unsatisfactory

Chemicals:Solids assumed in solution.Room temperatures assumed unless other wise stated.Data represented is to be used as a guide only. For specific information, test under actual operating conditions.

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Acetaldehyde CH3CHO A A A A F A BAcetic Acid, 100 %, CH3COOH A A F A F F CAcetic Acid, (Dilute) 50 % A A B A C C AAcetic Anhydride, (CH3CO)2O A A B A B F CAcetone, CH3COCH3 A A A A F F BAlcohol, Amyl CH3(CH2)4OH A B B A C F CAlcohol, Butyl C4H9OH A A A A B F BAllyl Chloride CH2CHCH2CL A A B A F F FAluminium Chloride, AlCl3 A B F A A A AAluminium Hydroxide, AL(OH)3 A B A A B A AAluminium Sulfate, Al2(SO4)3 A B F A A A AAlums, Conc., Al2(SO4)3 · K2SO4, etc. A A F A A F AAmmonium Carbonate, (NH4)2CO3 A B B A A A AAmmonium Chloride, NH4Cl A B F A A A AAmmonium Fluoride NH4F 25 % F F C A A A AAmmonium Hydroxide, NH4OH A B A A A A AAmyl Acetate, C5H11COOCH3 A A A A F F FAmyl Chloride, C5H11Cl A B A A F F FAntimony Trichloride, SbCl3 A B F A A A BAniline C6H5NH2 A B A A F F BAniline Hydrochloride C6H5NH2 · HCI A B F A B F FAmmonia (Gas), (Moist), NH3 A B A A A A BArsenic Acid, HAsO3 A B F A A A CBarium Carbonate, BaCO3 A B B A A A ABarium Chloride, BaCl2 A B C A A A ABarium Hydroxide, Ba(OH)2 A B B A A A ABarium Sulfate, BaSO4 A B B A A A ABarium Sulfide, BaS A B B A A A ABenzaldehyde, C6H5CHO 100 % A B B A F F CBenzene, C6H6 A A B B F F FBenzoic Acid, C6H5COOH A B B A A A BBorax, Na2B4O7 · IOH2O A B B A A A ABoric Acid, H3BO3 A B B A A A ABromine, (Wet), Br2 A F F A F F FButane C4H10 A A A A F F FButyl Acetate, C4H9COOCH3 A B B A F F FButyric Acid, C3H7COOH A A F A F F ACalcium Bisulfite, Ca(HSO3)2 A F B A A A ACalcium Carbonate, CaCO3 A B A A A A ACalcium Chlorate, CaClO3 A B B A A A ACalcium Chloride, CaCl2 A B F A A A ACalcium Hydroxide, Ca(OH)2 A C B A A A ACalcium Hypochlorite, Ca(OCl)2 A B F A A C BCarbon Disulfide, CS2 A A B A F F FCarbon Tetrachloride (Moist) CCl4 A A F A F F FChloracetic Acid, ClCH2CO2H A B F A F F FChloralhydrate CCl3CH(OH)2 A A F A F A FChloric Acid, HCLO3 A B F A C A F

1) For operating pressures see Drainline Catalog. See back page for Physical and Chemical Data of KIMAX® Glass Drainline.




Corrosion Rate Code:A = < 2 mm Penetration / Yr. B = < 20 C = < 50 F = > 50

KIM

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304

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Chlorine (Dry), Cl2 A B B A F F FChlorine (Wet), Cl2+H2O A B F A F F FChlorobenzene, C6H5Cl A B B A F F FChloroform, CHCl3 A B A A F F FChlorosulfonic Acid, 100 % ClSO3OH A A B A F F FChlorox’ Bleach, SOL, 5,5 % Cl2 A A A A F F FChromic Acid, CrO3 sol’n A B F A C F BCopper Chloride, CuCl2 A B F A A A BCopper Nitrate Cu(NO3)2 A A A A A A BCopper Sulfate CuSO4 A A B A A A BCresol A B A A F F BCyclohexanone A B B A F F FDimethylamine (CH3)2NH A A A A F F BDioctyl Phthalate A A A A F F FDioxane A B B A F F FEthers (Various) A A B A F F FEthyl Acetate, C2H5COOCH3 A A B A F F FEthylene Bromide, C2H5Br2 A B A A F F FEthyl Chloride, C2H5Cl A A A A F F FEthyl Ether (C2H5)2O A A B A F F FEthylene Chlorohydrin, Cl(C2H4)OH A B B A F F CEthylene Dichloride, C2H4Cl2 A B B A F F FEthylene Glycol, CH2OHCH2OH A B B A A A AEthylene Oxide, CH2OCH2 A A B A F F FFatty Acids (Various) A A B A F A BFerric Chloride, FeCl3 A C F A A A AFerrous Chloride, FeCl2 A B F A A A AFerrous Sulfate FeSO4 A B B A A A AFluorine, F2 F F A A F B FFormaldehyde, CH2O 37 % A A A A A A BFormic Acid, HCOOH A A C A C F BFuel Oil A A A A F A FFurfural, C4H3OCHO A B B A F F FGallic Acid, (OH)3C6H2COOH A A B A A A AGasoline (Refined) A A A A F A FGlycerol, CH2OH.CHOHCH2OH A A A A A A AHeptane, CH3(CH2)5CH3 A A A A F C CHexane, C6H14 A A A A F F CHydrobromic Acid, HBr A F F A A A CHydrocarbons (Aliphatic) A A A A F F CHydrocarbons (Aromatic) A A A A F F F(Check individual listing)Hydrochloric Acid (Conc.), HCI A F F A A F CHydrochloric Acid (Dilute) A F F A A A BHydrofluoric Acid (Conc.), HF F F F A B C CHydrofluoric Acid (Dilute) F F F A A C BHydrofluosilicic Acid, H2SIF6 C F F A A A CHydrogen Peroxide (Conc.), H2O2 A B B A C F C

Teflon® is a registered trademark of DuPont. KIMAX® is a registered trademark of Gerresheimer Glass, Inc.





Chemicals:Solids assumed in solution.Room temperatures assumed unless other wise stated.Data represented is to be used as a guide only. For specific information, test under actual operating conditions.

KIM

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Iodine, I2 (Wet) A F F A F F CIsopropyl Ether (Ch3)2 CHOCH(CH3)2 A A A A F F CKerosene A A A A F A FKetones (Various), RCOR’ A A A A F F CLauryl Chloride A A A A F A CLead Acetate, Pb(CH3COO)2 A B B A A A AMagnesium Chloride, MgCl2 A B C A A A AMagnesium Hydroxide, Mg(OH)2 A B A A A A AMagnesium Sulfate, MgSO4 A A B A A A AMercury, Hg A A A A A A AMethanol (Conc.), CH3OH A A A A A A BMethyl Chloride, CH3Cl A A A A F F FMethylene Chloride, CH2Cl2 A A B A F F FMethyl Ethyl Ketone, CH3COC2H5 A B B A F F CMethyl Isobutyl Ketone, C6H12O A B B A F F CNaphtha A B A A F A CNickel Chloride, NiCl2 A B C A A A ANickel Sulfate, NiSO4 A B B A A A ANitric Acid (Conc.), HNO3 A A F A F F FNitric Acid (Dilute) A A A A A C BNitrobenzene, C6N5NO2 A A B A F F CNitrous Oxide A B B A F A COleum A F B A F F FOxalic Acid, CO2HCO2H A B F A A A CPerchloric Acid 70 % HClO4 A A F A A F CPhenylhydrazine C6H5NHNH2 A A A A F F CPhosphoric Acid (100 %), H3PO4 A B F A A A BPhosphoric Acid (> 45 % Cold) 80°F A B F A A A APhosphoric Acid(< 45 % Cold) 80°F A A B A A A APhosphorus, Trichloride, PCl3 A A B A B F CPicric Acid, (Sol’n.), HO. C6H2 (NO2)3 A B B A C F CPotassium Bromide, KBr A B B A A A APotassium Carbonate, K2CO3 A B A A A A APotassium Chlorate, KClO3 A B B A A A APotassium Chloride, KCl A A B A A A APotassium Cyanide, KCN A B B A A A APotassium Dichromate, K2Cr2O7 A A A A A A APotassium Ferrocyanide, K4Fe(CN)6 A A A A A A APotassium Hydroxide, KOH A F B A A A APotassium Nitrate, KNO3 A A A A A A APotassium Permanangate, KMnO4 A B B A B B CPotassium Sulfate, K2SO4 A A B A A A APotassium Sulfide, K2S A A B A A A APropylene Dichloride A A A A F F FSilver Nitrate, Ag NO3 A A B A A A ASodium Acetate, CH3COONa A B B A A A ASodium Azide NaN3 A A A A A A ASodium Bicarbonate, NaHCO3 A A A A A A A

1) For operating pressures see Drainline Catalog. See back page for Physical and Chemical Data of KIMAX® Glass Drainline.




Corrosion Rate Code:A = < 2 mm Penetration / Yr. B = < 20 C = < 50 F = > 50

KIM

AX

® B

oro

silic

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Gla

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250

°F

Hig

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Sodium Bisulfate, NaHSO4 A A F A A A ASodium Bisulfite, NaHSO3 A F C A A A ASodium Bromide, NaBr A B F A A A ASodium Carbonate, NA2CO3 A B B A A A ASodium Chlorate, NaClO3 A A B A A C ASodium Chloride, NaCl A B F A A A ASodium Cyanide, NaCN A A A A A A ASodium Fluoride, NaF B F F A A A ASodium Hydroxide, NaOH < 85°F A F C A A A ASodium Hydroxide NaOH < 140°F B F C A A A ASodium Hydroxide NaOH, > 160°F F F A A A A ASodium Hypochlorite, NaOCl A B F A C A BSodium Hyposulfate, Na2S2O4 A B B A A A BSodium Nitrate, NaNO3 A A A A A A ASodium Sulfate, Na2SO4 A A A A A A ASodium Sulfide, Na2S F B F A A A ASodium Sulfite, Na2SO3 A F B A A A AStannic Chloride, SnCl4 A A F A A A AStannous Chloride, SnCl2 A B F A A A AStearic Acid, CH3(CH2)16COOH A B B A F A BSulfur, (Molten), S A A A A C A BSulfur Chloride (Wet), S2Cl2 A F F A F F FSulfur Dioxide (Wet), SO2+H2O A F F A C F CSulfur Trioxide, SO3 A F B A A A FSulfuric Acid (Fuming to 98 %) A F A A F F FSulfuric Acid (Hot Conc.) H2SO4 A A F A F F FSulfuric Acid (Cold Conc.) A A F A F F CSulfuric Acid (75 % – 95 %) A A F A F F FSulfuric Acid (10 % – 75 %) A A F A C A CSulfuric Acid (> 10 %) A A F A A A CSulfurous Acid, H2SO3 A F F A A A BSulfuryl Chloride, SO2Cl2 A B B A F F FTetrahydrofuran (75 %) A A A A F F FTetralin A B A A F F FThionyl Chloride, SOCl2 A B B A F F CToluene, CH3C6H5 A A A A F F FTributyl Phosphate (C4H9)3PO4 A B A A F C FTrichlorethylene, (Dry), Cl2C.CHCl A A B A F F FTricresylphosphate, (CH3C6H4O)3PO A A A A F F CTurpentine A B B A F F FVinyl Acetate, C4H6O2 A B B A F F FWater, (Distilled Lab) A A A A A A AXylene, C8H10 A B B A F F FZinc Phosphate, Zn3(PO4)2 A B B A A A AZinc Sulfate, ZnSO4 A A B A A A A

Teflon® is a registered trademark of DuPont. KIMAX® is a registered trademark of Gerresheimer Glass, Inc.

Summary of Tests

References:Corrosion Data Survey, 1969 edition, NaceCorrosion Data Survey – Nonmetals, 1975, NaceChemical Engineering Handbook, Perry & Chilton, 5th edition, McGraw Hill, 1973“Super Corrosion Control”, The Carpenter Steel Company, 1965“A Guide to the Selection of Durco Corrosion Resisting Materials for Process Industries Service”, The Duriron Company, Inc., 1964“Corrosion Resistant Lined Pipe and Fittings”, Corrosion Resistance Rating, Resistoflex Corporation, 1975“Chemical Resistance Guide”, Asahi / America, 1977“Chemical Resistance of Plastic Piping Materials”, Cabot Corporation, 1971

Physical and Chemical Properties of KIMAX® Piping Systems Chemical Durability: KIMAX® Glass Pipe is measureably affected by only one acid, hydrofluoric, or strong caustics such as sodium or potassium hydroxide.

Under continuous exposure of 1 % hydrofluoric acid at 70 ° F will require approximately 30 to 35 years to destroy one-half the wall thickness of KIMAX® pipe. Ten percent HF at 70 ° F will require approximately five years of continuous exposure to destroy one-half the wall thickness.

When KIMAX® Glass is exposed to NaOH or KOH in concen-trations up to 50 % at room temperature, the pipe should last from 90 to 100 years. All other chemicals exhibit little or no effect on KIMAX® Piping Systems.

TubingSCHOTT AG

Erich-Schott-Strasse 1495666 Mitterteich

GermanyPhone +49 (0)9633/80-0Fax +49 (0)9633/[email protected]

www.schott.com/tubing

24 F

GB

08.2

019

KN

KIMAX® Duriron Polypropylene

A 179 81 72

B 2 81 27

C 1 2 35

F 6 24 54

Total Chem. Tested 188 188 188

General Chemical Composition Approximate Percentage

Silica (SiO2) 80.5 %

Boric Acid (B2O3) 13.0 %

Sodium Oxide (Na2O) 4.0 %

Aluminium Oxide (AI2O3) 2.0 %

Potassium Oxide (K2O) 0.5 %

Chemical Properties

Thermal Coefficient of Linear Expansion 18 x 10–7 in / in / ° F

Thermal Expansion KIMAX® brand drainline will expand only 0.22" per 100 ft. of length when temperature increases 100 ° F

Thermal Shock (Instantaneous) 1½" to 3" pipe – 200 ° F4" pipe – 175 ° F6" pipe – 160 ° F

© Copyright of SCHOTT AG 2019

Documents

Corrosion Resistance of Acid Waste Drainline Piping and