Code of Practice 2003 Hazardous Chemical

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    Hazardous chemicals

    Code of Practice 2003

    Workplace Health and Safety QueenslandDepartment of Justice and Attorney-General

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    Contents Introduction ........................................................................................................... 5 1. Safety data sheets (SDS) ................................................................................. 6 

    1.1 SDS detail .............................................................................................................................. 7 1.2 Size and terminology .............................................................................................................. 7 

    1.3 Review of SDS........................................................................................................................ 7 2. Labelling hazardous containers..................................................................... 8 

    2.1 Fixing labels ............................................................................................................................ 8 2.2 Colour, size and style.............................................................................................................. 8 2.3 Revision of labels.................................................................................................................... 8 2.4 Decanted hazardous chemicals.............................................................................................. 8 2.5 Unlabelled containers / unknown chemicals........................................................................... 9 2.6 Hazardous chemicals in enclosed systems............................................................................ 9 2.7 Working in a confined space................................................................................................... 9 

    3. Consultation .................................................................................................. 10 3.1 Why consult?......................................................................................................................... 10 3.2 How to consult....................................................................................................................... 10 3.3 What consultation should cover............................................................................................ 10 

    3.4 Equipment and hazardous chemicals................................................................................... 11 3.5 Workplace health and safety representatives....................................................................... 11 3.6 Providing access to an SDS for workers .............................................................................. 11 3.7 Hazardous chemicals register............................................................................................... 12 

    4. Training .......................................................................................................... 12 4.1 Using risk assessment results .............................................................................................. 12 4.2 Step 1: Identify who should be trained.................................................................................. 12 4.3 Step 2: Identify what training is needed................................................................................ 12 4.4 Step 3: Determine the method of training............................................................................. 15 4.5 Step 4: Evaluate the training program.................................................................................. 16 

    5. Managing risks from hazardous chemicals ................................................ 17 5.1 Risk management ................................................................................................................. 18 5.2 Managing risk – a 10 step plan ............................................................................................. 18 5.3 Assessing risk ....................................................................................................................... 18 5.4 Controlling the risks .............................................................................................................. 28 

    6. Emergency procedures................................................................................. 31 6.1 Procedures............................................................................................................................ 31 6.2 Preparing an emergency response plan............................................................................... 31 6.3 Review of emergency response plan.................................................................................... 32 6.4 Emergency service agencies ................................................................................................ 32 

    7. Monitor ing ...................................................................................................... 32 7.1 What is monitoring? .............................................................................................................. 33 7.2 The role of monitoring in review of control measures........................................................... 33 7.3 What monitoring should cover .............................................................................................. 34 7.4 Monitoring procedures .......................................................................................................... 34 

    8. Health monitoring .......................................................................................... 34 8.1 What is health monitoring? ................................................................................................... 35 8.2 Requirement for health monitoring........................................................................................35 8.3 Selection of the registered medical practitioner with experience in health monitoring......... 36 8.4 Access of information by a registered medical practitioner .................................................. 36 

     Appendix 1: Sampling techniques and methods of analysis .......................... 37  Appendix 2: Appropriate standards .................................................................. 38  Appendix 3: Meeting your duties – Other useful documents .......................... 40  Appendix 4: Dictionary ....................................................................................... 41 

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     Appendix 5: Additional information about hazardous chemicals ................... 42 

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    Introduction

    This Hazardous Chemicals Code of Practice is an approved code of practice undersection 274 of the Work Health and Safety Act 2011 (the Act).

     An approved code of practice is a practical guide to achieving the standards ofhealth, safety and welfare required under the Act and the Work Health and SafetyRegulation 2011 (the Regulation).

     A code of practice applies to anyone who has a duty of care in the circumstancesdescribed in the code. In most cases, following an approved code of practice wouldachieve compliance with the health and safety duties in the Act, in relation to thesubject matter of the code. Like regulations, codes of practice deal with particularissues and do not cover all hazards or risks which may arise. The health and safetyduties require duty holders to consider all risks associated with work, not onlythose for which regulations and codes of practice exist.

    Codes of practice are admissible in court proceedings under the Act andRegulation. Courts may regard a code of practice as evidence of what is knownabout a hazard, risk or control and may rely on the code in determining what isreasonably practicable in the circumstances to which the code relates.

    Compliance with the Act and Regulation may be achieved by following anothermethod, such as a technical or an industry standard, if it provides an equivalent orhigher standard of work health and safety than the code.

     An inspector may refer to an approved code of practice when issuing an

    improvement or prohibition notice.

    How is the code organisedIn providing guidance, the word ‘should’ is used in this Code to indicate arecommended course of action, while ‘may’ is used to indicate an optional courseof action.

    This Code also includes various references to provisions of the Act and Regulationwhich set out the legal requirements. These references are not exhaustive. Thewords ‘must’, ‘requires’ or ‘mandatory’ indicate that a legal requirement exists andmust be complied with.

    Who has duties?

     A person conducting a business or undertaking (PCBU) has the primary dutyunder the Act to ensure, as far as reasonably practicable, that workers and otherpersons are not exposed to health and safety risks arising from the business orundertaking.

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    Officers, such as company directors, have a duty to exercise due diligence toensure that the business or undertaking complies with the Act and Regulation. Thisincludes taking reasonable steps to ensure that the business or undertaking hasand uses appropriate resources and processes to provide and maintain a safework environment.

    Workers have a duty to take reasonable care for their own health and safety and

    that they do not adversely affect the health and safety of other persons. Workersmust comply with any reasonable instruction and cooperate with any reasonablepolicy or procedure relating to health and safety at the workplace.

    Consulting workersConsultation involves sharing of information, giving workers a reasonableopportunity to express views and taking those views into account before makingdecisions on health and safety matters.

    The Act requires that you consult, so far as is reasonably practicable, with workerswho carry out work for you who are (or are likely to be) directly affected by a work

    health and safety matter.

    If the workers are represented by a health and safety representative, theconsultation must involve that representative.

    You must consult your workers when proposing any changes to the work that mayaffect their health and safety.

    Consulting, cooperating and coordinating activities with other duty holdersThe Act requires that you consult, cooperate and coordinate activities with all otherpersons who have a work health or safety duty in relation to the same matter, so

    far as is reasonably practicable.

    Sometimes you may share responsibility for a health and safety matter with otherbusiness operators who are involved in the same activities or who share the sameworkplace. In these situations, you should exchange information to find out who isdoing what and work together in a cooperative and coordinated way so that allrisks are eliminated or minimised as far as reasonably practicable.

    Further guidance on consultation is available in the Work Health and SafetyConsultation, Coordination and Cooperation Code of Practice.

    1. Safety data sheets (SDS)Chapter 7, part 7.1, division 2 of the Regulation sets out the requirement of aSupplier  to:

      provide a copy of a current SDS to the PCBU, and

      provide a copy of an SDS when requested by certain people.

    Chapter 7, part 7.1, division 2 of the Regulation sets out the requirement of aPCBU to:

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      obtain an SDS of a hazardous chemical from the manufacturer, importer orsupplier

      keep a register containing a list of all hazardous chemicals used at theworkplace and put a copy of any SDS obtained in the register

      take reasonable steps to ensure the SDS is not changed other than by themanufacturer or importer, and

      keep the SDS close to where the chemical is being used.

    Many hazardous chemicals may present hazards at work. But if the hazards areknown and understood, appropriate precautions can be taken so that they can beused safely. An SDS will help a workplace to gather necessary information tosafely manage the hazardous chemical.

    When new chemicals are to be introduced into the workplace, the PCBU shouldmake arrangements to get a copy of the SDS before the chemical is brought intothe workplace.

    1.1 SDS detailThe Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practiceshould be used by a manufacturer or importer as a guide for the detail ofinformation that should be provided on an SDS.

    In workplaces where a large proportion of the workers are non-English speaking,the SDS may require translation into the relevant language(s).

    1.2 Size and terminology

     An SDS contains important information, so it should be written so that it can beeasily understood by everyone. Headings should follow the protocol outlined in thePreparation of Safety Data Sheets Code of Practice and should be logical andconcise. The number of pages should be kept to a minimum.

    1.3 Review of SDS

    To keep an SDS current it should be reviewed whenever there is:

      a change in formulation which:-   affects the hazardous properties of the chemical-   alters the form or appearance of the chemical

    -  alters the mode of application of the chemical

      a change to the hazardous chemical which alters its health and/or safetyhazard or risk, and

      new health and/or safety information on the hazardous chemical, for example,the exposure standard changes or a chemical previously considered notharmful is now established to be carcinogenic.

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    2. Labelling hazardous containers

    Manufacturers and importers:Chapter 7, part 7.1, division 2 of the Regulation sets out the requirement for amanufacturer or importer to ensure that the hazardous chemical is correctlylabelled as soon as practicable after manufactured or imported, and that labelling

    uses the correct elements and is in accordance with the GHS classification andlabelling system.

    Suppliers: The supplier of a hazardous chemical must not supply the hazardous chemical toanother workplace unless the supplier knows or ought reasonably to know that thehazardous chemical is correctly labelled.

    Chapter 7, part 7.1, division 3 of the Regulation sets out the requirement of aPCBU to:

      ensure that a hazardous chemical is correctly labelled (e.g. a label is fixed to a

    hazardous chemical’s container), and  ensure that any hazardous chemical in pipework is identified by a label, sign or

    another way on or near the pipe.

    2.1 Fixing labels

    The amount of information on a label will depend on the size of the container.However, where the container is so small that the label cannot be placed on theactual container, the label can be attached by other means, for example, by astring round the neck of a test tube.

    2.2 Colour, size and style

    Labels should be fixed to the container in colours that provide sufficient contrast tothe background. Lettering should be of a size and style that is clearly legible and inthe English language.

    2.3 Revision of labels

    If an SDS has been amended by the manufacturer, the label should be changed toensure that it contains the same information as the amended SDS.

    2.4 Decanted hazardous chemicals

    When a chemical is decanted at work, the requirement for labelling will depend onwhether the chemical is used immediately or over a longer period of time.

    Where a hazardous chemical is decanted to be used straight away, the containerinto which the hazardous chemical has been decanted does not require labelling

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    only if the container is cleaned immediately after the hazardous chemical has beenused.

    The labels on the decanting containers should be used to provide information forthe safe disposal of both the remaining hazardous chemical and the container.

    If the container into which the hazardous chemical is decanted is small, it may not

    provide sufficient room for label information. In this case, the label should beattached to a supporting device or container. For example, in the case of a testtube, the label may be attached to the test tube rack. Alternatively, a tag with therequired label information may also be used.

    If a container label is damaged or defaced, a replacement copy should be obtainedfrom the supplier. If the label cannot be obtained, the information on the SDSshould be used to produce a label for the container.

    2.5 Unlabelled containers / unknown chemicals

    If the container is not labelled and the contents of the container not known, thecontainer should be marked:

    “ Caution do not use: unknown chemical”

     A container of an unknown hazardous chemical should be stored away from otherchemicals where it cannot be used until its contents can be identified and thecontainer appropriately labelled. If the contents cannot be identified, they should bedisposed of following consultation with the relevant local Authority.

    2.6 Hazardous chemicals in enclosed systems

    Enclosed systems such as piping, conduits and ducts should be marked by signsdesigned in accordance with appropriate standards1.

    Colours, letters and symbols on the sign should enable everyone (not only workersbut visitors such as emergency services personnel) to identify the contents easily.

    2.7 Working in a confined space

    Confined spaces potentially contain many hazards. These hazards can include:

      oxygen deficient atmospheres  toxic atmospheres

      flammable or explosive atmospheres, and

      engulfment.

    The Regulation sets out the requirements when working in a confined space.

    1 Appropriate standards for managing hazardous chemicals in enclosed systems are provided in Appendix 2. 

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    3. Consultation

    Chapter 3, part 3.2, division 7, of the Work Health and Safety Regulation 2011requires the PCBU to:

      make any monitoring records available to a worker who may be exposed2 

    Chapter 7, part 7.1, division 6 of the Regulation sets out the requirement of aPCBU to:

      give a copy of a monitoring record result to a worker who may be exposed3 

      allow a worker to inspect the monitoring record at any reasonable time; and

      allow a worker to who may be exposed to a hazardous chemical at theworkplace to inspect the SDS register at any reasonable time.

    Chapter 7, part 7.1, division 8, of the Work Health and Safety Regulation 2011,requires a PCBU to:

      Give a worker who may be exposed to a prohibited or a restricted carcinogen, astatement of exposure to the carcinogen.

    3.1 Why consult?

    Consultation involves the sharing of information and exchange of views betweenPCBUs, workers and workplace health and safety representatives. While theresponsibility for health and safety decisions for the workplace rests with thePCBU, consultation provides an opportunity for workers to contribute to thedecision making process. Consultation fosters co-operation in the workplace andmay pre-empt or resolve problems relating to control of risks.

    3.2 How to consult

    Consultation can happen in two ways:

      at an industry level through the Workplace Health and Safety Board andIndustry Sector Standing Committees (see schedule 2 to the Act), and

      at the workplace level through informal discussion with the workers, the electionby workers of workplace health and safety representatives, the issuesresolution process and by the establishment of workplace health and safetycommittees (see part 5 of the Act).

    3.3 What consultation should cover

    2 A person is “exposed” to a hazardous chemical if the person absorbs, or is likely to absorb, the chemical –

    (a) by ingestion or inhalation, or(b) through the skin or mucous membrane. 3 A person is “exposed” to a hazardous chemical if the person absorbs, or is likely to absorb, the chemical –

    (a) by ingestion or inhalation, or

    (b) through the skin or mucous membrane. 

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    The consultative process should cover the following:

      the introduction of new hazardous chemicals to the workplace

      the identification of risks associated with hazardous chemicals at the workplace

      decisions about the control measures to be implemented

      induction and training requirements

      advice to any workers with potential exposure to a particular hazardouschemical

      selection of registered medial practitioner for health monitoring, and

      the relocation of workers to suitable alternative work because of healthmonitoring results.

    3.4 Equipment and hazardous chemicals

    Relevant information should be provided to workers and their workplace health andsafety representatives on the equipment used with a hazardous chemical, forexample exhaust ventilation systems. The following information should be

    available:  the use for which the equipment is designed

      the conditions necessary for its safe use, and

      results of relevant tests which may have been carried out in connection with thesafe operation of the equipment.

    3.5 Workplace health and safety representatives

    To assist the consultative process, workplace health and safety representativesshould have ready access to:

      the results of monitoring, if any, and  the results of health monitoring programs, if any, provided that medical

    confidentiality is maintained.

    3.6 Providing access to an SDS for workers

    Depending on the needs of your workplace, access to an SDS may be provided inseveral ways, including:

      paper copy collections of SDSs

      microfiche copy collections of SDSs with microfiche readers open to use by allworkers

      computerised SDS databases, and  internet databases.

     Any storage or retrieval equipment used to provide access to an SDS should bekept in good working order. Where information is displayed on a screen, thereshould be a means of obtaining a paper copy of that information.

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    3.7 Hazardous chemicals register

    The register should be used as an information tool for consultation regarding themanagement of hazardous chemicals at the workplace.

    4. TrainingChapter 7, part 7.1, division 7 of the Regulation sets out the requirement of aPCBU to:

      give a worker who may be exposed to a hazardous chemical induction andongoing training about the chemical having regard to the level of risk and to theworkers who may be exposed to the chemical.

    4.1 Using risk assessment results

    The results of risk assessments should be used to identify trainees, and to identify,choose, and evaluate training methods.

    4.2 Step 1: Identify who should be trained

    People who should be trained include:

      workers who may be exposed to a hazardous chemical at work,

      supervisors of workers at risk from exposure to a hazardous chemical,

      workplace health and safety committee members and workplace health andsafety representative(s),

      workers responsible for the purchasing of hazardous chemicals, control

    equipment, personal protective equipment and for the designing, scheduling,organisation and layout of work, and

      those who have direct involvement in fire or other emergency action.

    4.3 Step 2: Identify what training is needed

    Decide what competencies are neededThe following table lists the topics in which persons using hazardous chemicalsshould be trained and the competencies they should attain:

    Topic Competencies

    Legislativerequirements

    Supervisors, Workplace Health and Safety Representatives  should be able to demonstrate an understanding of the following:

      duties of PCBU, workers and others under the Act;

      requirements of the Regulation; 

      responsibilities of manufacturers, importers, suppliers,PCBUs under the hazardous chemicals provisions of theRegulation,

      the requirements for health monitoring, its purpose and the

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    necessary procedures,

      provisions for the supply of an SDS and labels to theworkplace, and

      requirements for hazardous chemicals registers and theaccess by workers to these.

    Workers should be able to demonstrate an understanding of the

    following:  the general duties of PCBUs, workers and others under the

     Act, and

      the purpose and basic requirements for health monitoring.

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    Informationonhazardouschemicals

    The person being trained should be able to:

      recognise and interpret information on an SDS and label fora hazardous chemical including:-   safety directions, and-   Globally harmonised system of  classification and labelling

    of hazardous chemicals (GHS)4 and the Australian

    Dangerous Goods Code classifications5 -   first aid and emergency procedures, and special

    directions,

      demonstrate an understanding of the importance of beingable to:-   know the different parts of an SDS and label and the

    significance of the information in each part-   extract and interpret information from an SDS and product

    label-   relate the hazardous chemical to the Poisons Schedule-   Dangerous Goods classification and GHS classification

      demonstrate ability to use the register and access the SDS,  demonstrate an understanding of any work practice or

    procedure to be followed in any aspect of the use of ahazardous chemical at a workplace, and

      demonstrate an understanding of any control measure to beused in the workplace, including any information required forthe correct use and maintenance of a control measure.

    Personalsafety

    The person being trained should be able to demonstrate anunderstanding of:

      the routes of entry into the body of a hazardous chemical andways of limiting exposure

      the risks presented by any hazardous chemicals commonlyused in the particular industry

      methods used to control the risks created by a hazardouschemical

      the precautions to be taken for a particular task, especially inrespect of protective equipment and clothing, and the valuein working with any other person when very toxic chemicalsare handled, and

      the correct use, fit and maintenance of protective equipmentand clothing, in addition to any special decontamination

    procedures to be followed by persons required to usepersonal protective equipment.

    Emergencyprocedures

    The person being trained should be able to demonstrate anunderstanding of:

      procedures to be followed in case of an emergency involvinga hazardous chemical, and

    4 GHS classifications are set out in schedules 6, 11 of the Regulation and published by the Commonwealth. 5 Dangerous goods’ classifications are set out in the Australian Dangerous Goods Code published by the Commonwealthand the Regulation. 

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      first aid or incident reporting procedures to be followed incase of an injury or illness.

    Determine the training needed for the workplace The extent of a training program and the amount of detail required will depend on:

      the hazards associated with a chemical used in the workplace

      the complexity of the work procedures, and  any controls, work practices and personal protective equipment required to

    minimise risks.

    Determine those workers who already have the desired competencies. Design andpresent training to address the competencies that persons are not yet able todemonstrate.

    4.4 Step 3: Determine the method of training

    Types of training

    There are two types of training that should be provided:  Induction training – the initial training given to workers when they commence

    employment. This training is of a generalised nature and may involve aworkplace tour, conditions of employment, administration, organisationalstructure and function, emergency procedures and workplace amenities, and

      On-going training – the training given to workers throughout theiremployment. This training should be relevant to the exposure the worker has tohazardous chemicals used in the workplace.

    Forms of trainingThe forms training can take are:

      Formal training – addresses specific needs of the workplace or workers andmay be of a theoretical nature. Issues may cover legislative requirements,relevant information about hazardous chemical, use of personal protectiveequipment and emergency procedures, and

      On-the-job training – covers supervised training received while actually doingthe job. This form of training should be used to introduce a new/redesignedprocess or hazardous chemical into the workplace and the precautions for itsuse.

    In some cases, formal training will be required, in others, on-the-job training maybe more appropriate. The focus of training should be on workers gaining and

    demonstrating the desired competencies.

    Special Needs Any special needs of workers should be taken into account in deciding on thestructure, content and delivery of training. These special needs may includeliteracy levels, work experience and specific skills required for the job.

    Design of training programTraining programs should be designed to:

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      draw on workers’ knowledge and experience

      take into account literacy levels and any language barriers. For example, if theliteracy level is low, then spoken or highly graphic visual methods should beused. If workers are from non-English speaking backgrounds, then the trainingshould be provided in languages that they understand, and

      be practical and include a hands-on component, for example, the use and fittingof personal protective equipment for routine and emergency procedures.

    4.5 Step 4: Evaluate the training program

     Assess effectiveness of the training Training should be assessed by observation or measuring against thecompetencies in real or simulated conditions or where that is not possible by oraland/or written examination.

    If persons undertaking the training are unable to demonstrate attainment of therequired competencies, a review should be undertaken to establish if:

      sufficient detail on the topics was provided to enable attainment of thecompetencies

      the form of training was appropriate, for example, fitting personal protectiveequipment during training session, and

      the training was delivered in a way that would ensure greatest understanding ofthe topics covered, for example language and literacy considerations.

    Validate competencies over time Competencies should be validated over time to check that a person assessed ascompetent in previous training is still competent in his/her current job. The resultsof the validation process should be used to determine how often the training should

    be given or repeated.

    Review training programThe overall training program, including induction and ongoing training should bereviewed to ensure the topics and competencies required are applicable to thework being carried out by the person being trained:

      at least once a year

      each time there is a change in:-   information provided on an SDS-   any hazard information available-   a work practice

    -  a control measure, or

      each time a worker is assigned to:-   a new task, or-   a new work area.

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    5. Managing risks from hazardouschemicals

    Chapter 7, part 7.1, division 5 of the Regulation sets out the requirement of a

    PCBU to:manage the risk to health from a hazardous chemical that is used, or is to be used,at the workplace in accordance with the risk management requirements found inChapter 3, part 3.2, division 7. Chapter 3 further requires the PCBU to:

      maintain control measures

      review control measures

    Chapter 7, part 7.1, division 5 expands on the need to review control measures,requiring the PCBU to:

      review the control measures implemented to control risks of hazardouschemicals at the workplace

    -  within 5 years after the last review

    -   when certain things happen at the workplace

    Chapter 3, part 3.2, division 7 requires the PCBU to:

      keep the monitoring result for 30 years if the report shows use of a hazardouschemical results in exposure of a worker which has exceeded the relevantexposure standard .

    Chapter 7.1, part 7.1,division 6 requires the PCBU to:

      keep a health monitoring report for 30 years

      manage risk by controlling exposure to a hazardous chemical by preventingexposure, or if not practicable, reduce exposure to as low a level as ispracticable, but in any case ensure exposure is not more than the relevantnational exposure standard for the relevant period for the chemical

      provide personal protective equipment, properly instruct in its use, ensure it isused if it is not practicable to prevent or reduce exposure by other ways

      ensure control measures decided are implemented as soon as practicable andensure monitoring is done if the risk assessment shows it is needed

      ensure a prohibited or restricted chemical6 is not used for a prohibited orrestricted purpose

      keep a register that has:-   a list of all hazardous chemicals used at the workplace

    -   the current SDS for each hazardous chemical, and

      ensure a worker who may be exposed to a hazardous chemical at a workplacemust be able to inspect the register at any reasonable time.

    6 Prohibited chemicals are contained in Schedule 10 (Prohibited carginogens, restricted carcinogens and restrictedhazardous chemicals) in the Regulation. 

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    5.1 Risk management

    Managing hazardous chemicals in the workplaceThe following issues should be considered when hazardous chemicals are used inthe workplace:

      how hazardous chemicals should be used

      how persons are exposed to hazardous chemicals

      whether the risk from the hazardous chemical is significant, and

      how exposure to hazardous chemicals in the workplace should be controlled.

    Defining the terms “Hazard” and “Risk” A Hazard is the potential for a chemical to adversely affect the health and safety ofpeople in the workplace.

     A Risk is the likelihood that a chemical will cause illness or injury in the conditionsof its use. The risk to health and safety usually increases with the severity of thehazard, the amount of hazardous chemical used, and the duration and frequencyof exposure.

    For example, the solvent Xylene has been identified through tests on animals andhumans as being a hazard to humans. The risk to a worker using Xylene willdepend on the way it is used. If it is used in an enclosed system the risk will be low.However, if it is used in a degreasing bath without ventilation, the risk to healthfrom inhaling the vapour is likely to be high.

    5.2 Managing risk – a 10 step plan

     A 10-step plan outlined in this code of practice should be followed to:

      identify hazardous chemicals used in the workplace  assess the risk from their use

      determine and implement appropriate control measures so that they can behandled and used safely, and

      review and monitor the effectiveness of control measures used.

    Management of risks from hazardous chemicals should be applied wherever thework is being carried out, for example the different locations where cleaners arecarrying out cleaning work while using hazardous chemicals.

    5.3 Assessing risk

     Although risk assessments are not required by regulation, a PCBU can undertakea risk assessment by examining ways in which a hazardous chemical is used atwork and the health risks involved. The purpose of the assessment is to enabledecisions to be made about appropriate control measures, training, monitoring ofairborne contaminants and health monitoring.

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    These decisions will depend on the risk that arises from the use of a hazardouschemical under particular working conditions.

    Types of AssessmentsThe way in which an assessment is conducted depends on the circumstances ofthe workplace. Two possible methods are:

      Workplace specific assessment – An example could be a walk-through

    survey of the workplace using a checklist. The checklist should be based oninformation on labels and SDSs, for example, risk phrases on labels could beused to get an idea of how a person using a chemical may be exposed.In some cases, considerably more detail will be required, particularly where:- a significant risk to health is suspected- there is uncertainty about the degree of risk, or- there are complex chemical processes and/or exposures involved.In these cases, additional detail on all facets of the assessment may berequired. This could include the use of outside professional assistance.

      Generic assessments – An example of a generic assessment may be in theuse of hazardous chemicals at service stations. In this case, the nature of the

    hazard and the degree of risk at one service station may be comparable to thedegree of risk at others.Therefore, a single assessment of the activity can be applied to otherworkplaces where the use for the hazardous chemical is the same.

    When a generic assessment is undertaken it should be checked for validity at eachindividual workplace.

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    Overview of the process for the assessment of health risksarising from the use of hazardous chemicals in the workplace

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    Factors in a risk assessmentThe purpose of a risk assessment is to allow appropriate control measures to bedeveloped. Once hazards have been identified, they should be assessed in termsof their potential to do harm.

     All the factors in risk assessment are interconnected. For the purposes ofperforming an assessment, the PCBU should consider the factors in isolation and

    then consider their combined effect. The factors are:  the risk associated with the hazard (for example, chemicals are inhaled, get on

    skin or in eyes)

      the probability that an event or an exposure will occur

      the length of time of exposure a person has to the hazard (ranging fromoccasional to continuous contact with the hazard), and

      the possible consequences that may result, for example, causing liver disease,cancer and burns.

    Step 1: Decide who wi ll do the risk assessmentIn a small business, assessments are usually undertaken by the PCBU or

    manager, in cooperation with the workers. The tasks needed to carry out anassessment may be delegated by the PCBU to other persons at the workplace.However, the overriding responsibility for the accuracy and appropriateness of theassessment is held by the PCBU.

    Professional persons from outside the workplace may provide assistance forelements of the assessment which require special expertise. In a large workplace itmight be useful to establish a team, for example, the relevant manager/supervisorand workplace health and safety representative to assess particular work.

    The person who conducts the assessment (the assessor) should have sufficient

    knowledge and skills to evaluate the health risks to workers arising from the use ofa hazardous chemical. They should understand the requirements of the WorkHealth and Safety Regulation 2011, relevant regulatory provisions and codes ofpractice and have a sound knowledge of the work activity.

    Where an outside consultant is engaged to assist with the assessment, workerswho have a thorough knowledge of the work should always be involved. Theassessor should have the authority to do the work necessary for the assessment,and enough resources to gather information, consult the appropriate workers,review existing records and examine the workplace.

    The assessor should also be able to:  interpret the information on an SDS and labels

      observe the conditions of work and foresee potential problems

      communicate effectively with everyone at the workplace

      draw all the information together in a systematic way to form valid conclusionsabout exposures and risks, and

      report the findings accurately to all parties concerned.

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    The PCBU should be aware of any limitations in the experience and knowledge ofthe personnel doing a risk assessment. In such instances it may be necessary tosupplement this knowledge by arranging appropriate training in risk assessment orengaging specialist assistance.

    If a team approach is used, members of the assessment team might be assigneddifferent tasks. Individual findings should be communicated to the person selected

    to coordinate the assessment. This person should reach appropriate conclusionsabout risks and determine control measures. In larger workplaces where manyassessments are needed, an overview committee may be established tocoordinate the assessments.

    Step 2: Divide the work into uni ts for assessmentTo make the risk assessment easier, the work that utilises a hazardous chemicalshould be divided into jobs, tasks or processes. Visiting the workplace and lookingat floor plans or process plans should help with this. Dividing a small workplace inthis way may not be necessary when only a few chemicals and persons areinvolved.

    Step 3: Identify chemicals used in workThe next step is to identify whether or not there are hazardous chemicals used inthe workplace. When identifying a hazardous chemical used or intended to beused, in the workplace, it is important to recognise that it could exist in variousstates or forms – solid, liquid, gas, vapour, dust, mist or fume.

    Chemicals used in the workplace should be identified by:

      referring to stock lists, inventories and registers

      checking all locations where chemicals are used or stored, and

      considering all chemicals that are used in, or that arise from, ancillary work

    such as maintenance and repair, cleaning, research or testing.

    Step 4: Determine if the chemicals are hazardous chemicalsFrom the information collected in Step 3 refer to the SDS and labels for informationon whether the chemical is hazardous.

     All hazardous chemicals that have been identified must be included in thehazardous chemicals register along with a copy of the SDS. (See Section 1 forinformation on Safety Data Sheets)Note: If you are unsure if the chemical is a hazardous chemical contact thesupplier.

    Step 5: Obtain information about hazardous chemicalsInformation should be obtained about the hazardous chemicals in the workplace,routes of exposure, recommended control measures and other action to prevent orminimise risks. For most risk assessments, container labels and SDSs will providethis information. Where the nature of the hazard is very serious, or chemicalprocesses are complex, it may be necessary to obtain more detailed informationfrom other sources, for example, from the manufacturer or supplier of the chemical,

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    a registered medical practitioner with experience in health monitoring or anoccupational hygienist.

    Step 6: Inspect workplace and evaluate exposure A “walk-through” inspection should provide information about hazardous chemicalsused in each work area. In assessing existing processes, it is important to talk to

    workers in each area regarding practical information about work practices andprocedures. For example, workers could describe what happens during abreakdown, maintenance, changes in personnel or volume of production, weatherconditions or other changes that can affect the ways hazardous chemicals arehandled and used.

    If a job, process or other work unit is being planned, an evaluation of the relevantwork process, plan or design should be undertaken before the commencement ofthe operation. This will enable any hazards inherent in each step of the processand consequent risks to be identified. Suitable control measures can then bedetermined. For example, a metal shop proposes to introduce electroplating, which

    will result in new chemicals being used in the workplace. Therefore it will benecessary to implement different measures to control the exposure of workers onthe electroplating line.

    The following questions should be answered when inspecting and evaluatingexposure:

    (a) Is the hazardous chemical released or emitted into the work area?In determining whether a hazardous chemical is released or emitted into a workarea, the following should be considered:

      evidence of contamination, that is dust or fumes visible in the air or on

    surfaces, chemical residue visible on a person’s skin or clothing, chemicalodour, visible leaks, spills or residues. Note: the use of odour should beused with caution as it is not necessarily an indicator of the levelspermitted by Regulation 

      handling chemicals, for example, powders not in containers

      chemical splashes, and

      workers’ experience or symptoms of exposure.

    If the hazardous chemical is not released or emitted into the work area, go on toStep 7.

    (b) Are workers exposed to the hazardous chemical through inhalation,ingestion, skin or eye contact, or is there a possibili ty of accidental injectioninto the body?It is important to identify the types of exposure which might affect workers. Workersinvolved in production, repairs, maintenance, cleaning or office work may all facedifferent types of exposure. Also consider contractors on site and people whomight be exposed in an emergency such as a chemical spill, leak or fire.

    People may be exposed by:

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      working directly with the hazardous chemical

      working near or passing through areas in which the hazardous chemical isstored, transported, disposed of, or produced by discharge of emissions, e.g.exhaust

      entering a confined space in which the hazardous chemical might be present,or

      cleaning, performing maintenance or other work in areas where the hazardouschemical might be present.

    (c) How much are workers and other persons exposed to hazardouschemicals and for how long? It is important to identify the amount of hazardous chemicals to which workers areexposed and the length of time over which exposure occurs. In particular,remember that exposure standards for hazardous chemicals are calculated on adaily 8 hour exposure. Where workers have been exposed in excess of 8 hoursduring their working day specialist help may be needed to apply the exposurestandard.

    In identifying how much and for how long, ask:  What degree of exposure is expected?

      Does exposure occur intermittently or continuously?

      Does exposure occur frequently?

      What are the different routes of exposure?

      How many workers are exposed?

    If monitoring is required it should be carried out by a person who has sufficientknowledge, skills and experience in the techniques and procedures listed below:

      when and how the monitoring is to be done

      the sampling procedures and analytical methods to be used  the sites and frequency of sampling, and

      how the results are to be interpreted.

    Section 7 of this code of practice provides more information on monitoring and Appendix 1 lists publications which provide advice on suitable sampling techniquesand methods of analysis.

    Monitoring records should contain the following information:

      the hazardous chemical concerned, the results of monitoring and when it wasdone

      what monitoring procedures were adopted, including the duration of sampling  the locations where samples were taken, the operations in progress at the time

    and, in the case of personal samples, the names of those individualsconcerned

      whether the results reflected normal operating conditions

      who undertook the analysis of the results

      how the results were interpreted, and

      the effectiveness of control measures.

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    (d) What control measures are used or proposed? Are the existing controlmeasures effective, properly used and maintained? During a walk-through inspection, the following points should be considered:

      Are any engineering controls in place, such as, isolation or enclosure ofprocesses?

      Are general ventilation and local exhaust ventilation systems in place effectiveand adequately maintained?

      Are workers trained in the proper use and maintenance of control measures?  Do work practices ensure safe handling?

      Are appropriate personal protective clothing and equipment used andmaintained in a clean and effective condition?

      Are facilities for changing, washing and eating meals maintained in goodcondition? Good personal hygiene practices can help reduce worker exposureto a hazardous chemical.

      Are good housekeeping practices in place?

      Are all hazardous chemicals stored correctly?

      Is disposal of waste appropriate?

      Are appropriate emergency procedures and equipment in place (for example,eye wash, safety shower, etc)?

    (e) Are there any risks associated with the storage and handling of thehazardous chemical?The risk associated with the storage and handling of a hazardous chemical in theworkplace often relates to spillage and fire. Under these circumstances, workersmight be exposed briefly but at high concentrations, i.e. the exposure is acute. Theterm hazardous chemical includes dangerous goods and hazardous substances.Dangerous goods are classified on the basis of immediate physical or chemicaleffects, such as fire explosion, corrosion and poisoning, the effect on property, theenvironment or people, while hazardous substances are classified only in thebasis of health effects (whether they be immediate or long term).

    Note: The Austral ian Dangerous Goods Code sets out the technicalrequirements for the transport of dangerous goods.

    Step 7: Evaluate the risk and determine conclusions about the riskThe conclusions at Step 6 will provide the necessary information to establish:

      the nature and severity of the hazard for each hazardous chemical

      the degree of exposure of persons in the workplace, and

      whether existing control measures adequately control exposure.

    Conclusions from the risk assessmentIt should now be possible to establish which of the following conclusions apply tothe assessment and what action is required.

    Conclusion 1: Risks not significant now and not likely to increase in the future This conclusion applies where it is unlikely that the use of the hazardous chemicalwill adversely affect the health of persons at the workplace and the risk is not likelyto increase in the future.

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    For example:

      the amounts or rate of use of a hazardous chemical are too small to constitutea risk, even if controls fail

      the operation obviously and strictly conforms to the information contained in theSDS and label, and

      similar assessments in the past have confirmed the risks were not significant,and work conditions now are the same.

     Action required:End current assessment and go to Step 9.

    “ Significant risk”  – means that the work with a hazardous chemical is likely toadversely affect the health of workers and other persons at the workplace. Forexample, there would be a “significant risk” if:

      the severity of the acute7 or chronic

    8 health effects from exposure to the

    hazardous chemical are substantial

      there are no control measures in place at the workplace or the controls that arein place are not adequate to protect workers from exposure to a hazardouschemical, or

      the level of exposure is high.

    Consultation should take place to decide if the risk is significant. If the contaminantconcentration in a person’s breathing zone is above half the national exposurestandard, a plan should be developed to review the levels before the nextassessment. Further action in reviewing the exposure will assist in ensuring thatthe concentration does not reach a level which poses a significant risk to healthand safety.

    Conclusion 2: Risks are significant but effectively controlled, and could increasein the future This conclusion usually applies to conditions where serious health effects couldresult if the control measures fail or deteriorate. This usually results from the use ofa highly toxic hazardous chemical or where the potential exposure is high.

    Risks, while presently adequately controlled, could increase in the future, owing to,for example:

      undetected deterioration in the efficiency of control measures

      plant including PPE or system failure

      control measures not used properly

      human error from lack of awareness

      ineffective monitoring

      insufficient or lack of ongoing training

    7 Acute effects occur immediately or soon after exposure, for example, poisoning with carbon monoxide from a petrolengine 8 Chronic effects are slow to occur and may take months or many years to show up, for example, silicosis – lung disease

    from silica dust 

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      changes in methods or rate of work, and

      a significant increase in the quantity of hazardous chemicals used.

     Action required:

      determine precautions to maintain controls and minimise chances of higherexposure occurring

      determine additional measures for regaining control if a high risk event occurs,despite precautions (see Step 8), and

      determine if health monitoring is required to check on effectiveness of controls(see Step 8).

    Conclusion 3: Risks significant now, and not effectively controlled. The following indicates where the use of a hazardous chemical is likely toconstitute a risk and further investigation may be necessary if:

      dusts, mists or fumes are visible in the air, for example in light beams, andthere are persistent or widespread complaints of illness, discomfort, irritation orexcessive odour

      hazardous chemicals are splashed

      control measures are broken, defective or badly maintained, for example apoorly maintained extraction system which no longer draws a hazardouschemical away from the work area

      recognised safe work practices are not being observed

      airborne concentrations approach or exceed exposure standards

      ill-health associated with exposure has been detected by health monitoring,and

      results of biological monitoring indicates workers are at risk.

     Action required:

    Identify and implement immediate measures for preventing or controlling exposure(see Step 8):

      work out if there is a need to stop the process

      begin review of longer term control requirements

      re-evaluate exposures when the upgraded control measures are in place, and

      determine if monitoring or health monitoring is required (see Step 8).

    Conclusion 4: Uncertain about risks: not enough information, or uncertain aboutdegree and extent of exposure If the level of exposure cannot be estimated with confidence, further investigation isnecessary. Atmospheric monitoring might be required to estimate the level of

    exposure. For a hazardous chemical absorbed through the skin, ingested orinhaled, biological monitoring might be required. A detailed evaluation might beneeded if there is the potential for a major hazard such as a large leak or spill. Inthese cases, relevant specialist advice would probably be required.

    If there is not enough information to estimate the risks, additional informationshould be obtained from other sources, such as suppliers, occupational health andsafety consultants and industry or trade associations.

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     Action required:

      obtain additional information or conduct a more detailed assessment. ThePCBU should obtain specialist advice if necessary and continue until he/she isable to arrive at Conclusion 1, 2 or 3 and then take the appropriate actions, and

      meanwhile, implement good work practices to minimise exposure.

    5.4 Controlling the risks

    Step 8: Implement control measures to address actions required from riskmanagementControl or prevention of exposure is undertaken by implementing appropriatecontrol measures. When considering methods to control exposure, all the possibleroutes of entry to the body should be taken into account.

    Control measures are not mutually exclusive and in some circumstances two ormore control measures may be required to reduce exposure to as low a level as ispracticable.

    Control measures for a hazardous chemical should be considered in the planningof any new workplace or modifications to an existing workplace. The costs of thecontrol should be considered in the same way and at the same time as all otherplant and process costs.

    Hierarchy of contro l measuresThe hierarchy of control measures is a list of control measures that can be used toeliminate or minimise exposure to a hazardous chemical through:

      Elimination

      Substitution

      Isolation

      Engineering Controls

    If the risk still remains, the following can be adopted:

      Administrative Controls, and

      Personal Protective Equipment (PPE).

     Application of the hierarchy of control measures involves firstly assessing whethera hazardous chemical can be eliminated. Where this is not practicable,consideration should be given to each of the other control measures (substitution,isolation, engineering controls, safe work practices and use of personal protectionequipment) with the objective of identifying a control measure or combination ofcontrol measures that will eliminate or minimise exposure.

    Control measures

    Elimination – where a work activity involves the use of a hazardous chemical thatis not essential to the work activity the hazardous chemical should be eliminated,wherever practicable. Examples of elimination include:

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      using a physical process rather than a chemical process to clean an object, forexample, use of ultra-sound

      using clips, clamps or bolts instead of adhesive, and

      purchasing supplies of a material in a ready-cut and sized form rather thancarrying out a dust producing cutting process on site.

    Substitution  – includes substituting a less hazardous chemical, the same

    chemical in a less hazardous form or the same chemical in a less hazardousprocess. Examples of substitution include:

      replacing a chlorinated degreasing solvent with a detergent

      using a water-based paint in place of an organic solvent-based paint

      using a hazardous chemical in paste or pellet form rather than a dusty powder,and

      brush application of paint rather than aerosol application.

    Isolation – involves separation of the process from people by distance or the useof barriers to prevent exposure. For example, a booth in an underground carpark issupplied with fresh air to minimise carbon monoxide exposure for a parkingattendant.

    Engineering controls – by the use of plant or processes which minimise thegeneration of a hazardous chemical, suppress or contain a hazardous chemical orwhich limit the area of contamination in the event of spills or leaks.

    Types of engineering controls include enclosure or partial enclosure, local exhaustventilation and automation of processes. Some examples of engineering controlsare:

      ventilated booths for spraying paint or fibre glassing

      robot welding

      local extraction systems attached to grinding machines

      automation of the removal of objects from degreasing baths, and

      closed reaction vessels.

     Administ rat ive controls – are work practices which require people to work insafer ways and are intended to limit the extent of exposure to a hazardouschemical. Examples of safe work practices include:

      excluding non essential persons from a work area

      shift or work rotation to reduce the period of exposure for workers

      regular cleaning of contamination from walls and surfaces

      providing means for safe storage and disposal of a hazardous chemical  prohibiting eating, drinking and smoking in contaminated areas

      prohibiting the use of compressed air for personal cleaning purposes

      vacuuming dust from areas where cutting processes take place

      keeping lids on containers when not in use

      providing and using facilities for effective decontamination

      providing first aid, safety showers and eye wash facilities, evacuationprocedures, and

      emergency procedures.

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    Personal protective equipment (PPE) – The basic personal protective equipmentavailable to guard against risks from hazardous chemicals includes respirators,goggles, face shields, gloves, footwear, and aprons. Self contained breathingapparatus or hazardous chemical suits may be required if the risk of exposure issignificant because a hazardous chemical is present in an uncontrolledenvironment.

    Situations where the use of suitable personal protective equipment may benecessary include:

      where it is not technically feasible to achieve adequate control by other means.In these cases, exposure should be reduced as far as practicable by othermeasures and then, in addition, suitable personal protective equipment shouldbe used to secure adequate control

      where personal protective equipment is necessary to safeguard health untilsuch time as adequate control is achieved by other means, for example, whereurgent action is required because of plant failure

      during routine maintenance operations where the infrequency and small

    number of people involved may make other control measures not practicable,or

      where SDS and labels indicate.

    The ongoing costs (e.g. training and maintenance and/or replacement) andoperator considerations9 (e.g. correct fit and medical factors) associated with PPEshould be given significant consideration before determining it as the preferredcontrol option.

    To ensure PPE is effective as a control it should be:

      selected for the contaminant, task and the operator in accordance with

    appropriate standards  readily available

      clean and functional

      checked before use

      correctly used when required, and

      appropriately maintained.

    Following the selection of appropriate PPE as a control measure, training shouldbe provided to ensure it is properly used in accordance with the appropriatestandards for the equipment.

    Step 9: Record the assessment Assessment reports should reflect the detail of the assessment, and providesufficient information to show how the decisions about risk and controls weremade.

    9 Refer to AS/NZS 1715 Selection, use and maintenance of respiratory protective devices for further information on

    selection factors relating to the use of respiratory protective devices. 

    http://www.standards.com.au/catalogue/script/Details.asp?DocN=stds000011448http://www.standards.com.au/catalogue/script/Details.asp?DocN=stds000011448

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    The risk assessment record should include:

      the name of the assessor or assessment team

      personnel involved

      description of the hazard and routes of entry to the body

      description of normal operations in the work area

      procedures used to assess exposure

      procedures used to assess the degree of exposure

      procedures used to assess existing control measures

      conclusion from the assessment whether the risk was not significant orsignificant

      action to be taken

      induction, training, emergency procedures and health monitoring action to betaken

      the circumstances when reassessment will be required

      signature, date and position of the assessor/assessment team, and

      signature, date and position of the PCBU accepting the assessment.

     A standard format might be considered.

    Step 10: Review of control measures All measures for the control of exposure should be thoroughly examined and testedat regular intervals to ensure effective performance. Controls should be reviewed ifwork-related ill health is reported.

    Routine maintenance including preventive service procedures should beestablished, specifying:

      which control measures require servicing

      the servicing needed

      the frequency of servicing  who is responsible for servicing

      how any defects will be corrected

      performance testing and evaluation, and

      record of servicing.

    6. Emergency procedures

    6.1 Procedures

    Even if control measures have been put in place, a leak, spill or uncontrolledrelease of a hazardous chemical may still occur. Emergency procedures should beestablished, and used, if appropriate, to enable the source of a release to be safelyidentified and repairs to be made. All persons not directly concerned with theemergency should be excluded from the area of contamination.

    6.2 Preparing an emergency response plan

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    The emergency response plan should be prepared in consultation with the workersat the workplace and emergency service agencies where appropriate.

    The issues which should be addressed in an emergency plan include the following:

      any on-site first aid or assistance which has to be administered in case of anaccident due to over exposure to a hazardous chemical

      details of the building(s) on the site

      the types of risks taken into account  emergency organisations and any mutual assistance resources involved

    including key personnel and responsibilities and liaison arrangements betweenthem

      emergency command structure and communications links includingtelephones, radios and standby methods

      special equipment including fire fighting materials, damage control and repairitems

      the limits of on-site action prior to the seeking of outside assistance

      technical information such as chemical and physical characteristics and

    dangers of every hazardous chemical and plant  locations of the hazardous chemicals, personnel, equipment and emergency

    control rooms at the workplace, and

      evacuation arrangements.

    6.3 Review of emergency response plan

    It is good practice to review an emergency response plan when:

      any hazardous chemical is introduced to the wor kplace in a quantity whichcauses alteration to the placarding requirements10 

      a change is made in the way a hazardous chemical is stored, handled or used

      a change is made to a process or procedure which may result in a change ofrisk, and

      new information becomes available concerning any property of a hazardouschemical which could lead to a significant risk.

    6.4 Emergency service agencies

    Emergency service agencies should be provided with information on the hazardouschemicals present at the workplace as well as other relevant information such asthe hazardous chemicals register and emergency response plan. However, it is notappropriate or necessary for emergency services to have access to monitoring orhealth monitoring results.

    7. MonitoringChapter 7, part 7.1, division 6 of the Regulation establishes a requirement toundertake health monitoring if there is a risk of exposure to a hazardous chemical

    10 Placarding requirements for dangerous goods are set out in Schedules 11 and 13 of the Regulations

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    mentioned in Schedule 14, table 4.1, column 2 or another hazardous chemical.The monitoring must be done at the workplace and a record of the result must bemade as soon as possible.

     A PCBU must:

      ensure a worker who may be exposed to a hazardous chemical at theworkplace is given a copy of the record, and

      allow a worker who may be exposed to inspect the record at any reasonable

    time.

    7.1 What is monitoring?

    This monitoring refers almost exclusively to monitoring of the air which a workerbreathes, as the majority of occupational exposures to hazardous chemicals occurthrough inhalation. Knowing the extent of exposure to a hazardous chemical isfundamental to providing adequate control against breathing a contaminatedatmosphere. In rare cases, monitoring may also relate to exposure occurring viathe unprotected skin, or even to the skin when personal protective equipment isworn.

    The review process for hazardous chemicals in chapter 7, part 7.1, division 5 of theWork Health and Safety Regulation 2011 section 352 (see also Section 5.3, Step 6(c) of this code of practice) calls upon using information about exposure toundertaking a review of control measures. In most of the simpler cases, the extentof exposure can be gauged from observation and relevant detail from the label andSDS. In some instances exposure can be tolerated without protection provided it ismaintained within accepted limits.

    There are some instances, however, where the procedure of observing a processaided by an SDS and a label will not provide reliable estimates of exposure.Examples include:

      a respirable dust which workers are exposed to often cannot be seen

      a visible dust concentration cannot be judged by eye

      some airborne contaminants have no odour so their presence is undetectedand hence underestimated

      an exposure standard may be exceeded before an odour is detected

      a strong odour at low concentration levels may lead to gross overestimation ofexposure and exacerbate the perception of risk, and

      there is significant process or environmental variability which makes an

    unmeasured estimate of exposure unreliable.

    7.2 The role of monitoring in review of controlmeasures

     Air monitoring provides a reliable estimate of exposure and is the primary means ofmaking a comparison with exposure standards possible. Air monitoring is alsoused to help in correct selection of controls, including personal protective

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    equipment. In some circumstances, monitoring can also be used to review theeffectiveness of any newly introduced engineering or process controls.

    7.3 What monitoring should cover

    Monitoring takes into consideration:

      individual worker behaviour by measuring concentration of contaminants in the

    worker’s breathing zone  all environmental and process variables

      collection of sufficient data needed to estimate any Time Weighted Average(TWA), Short Term Exposure Limit (STEL), Peak Limitation, or adjustedexposure standard that is appropriate for that hazardous chemical in that worksituation

      correct selection of workers from groups doing the same or different taskswhere it is not feasible to sample all workers

      adequate statistical evaluation of measurements, including the number ofmeasurements, to establish some confidence limits in the estimate ofexposure, and

      whether monitoring is for simple legislative (pass/fail) compliance or moreexacting health monitoring purposes.

    7.4 Monitoring procedures

    Monitoring can be conducted both in situ in the workplace, using direct readingindicating devices, or by collecting a sample for later laboratory analysis, or acombination of both.

    There are many different monitoring methods available to meet the large number of

    hazardous chemicals found in workplaces. Their reference and some commonlyapplied standard methods for field sampling are to be found in Appendix 1.

    8. Health monitoring

    Chapter 7, part 7.1, division 6 of the Regulation sets out the requirement of aPCBU to:

      arrange and pay for health monitoring if there is a significant risk that therelevant person or worker has been exposed to a hazardous chemical, and:-

      the hazardous chemical is listed in Schedule 14

    11

     and the degree of risk tohealth is significant or-   the relevant person reasonably believes, or ought to reasonably believe

      an identifiable adverse health effect may be related to exposure  the health effect may happen under the work conditions, and  a valid technique capable of detecting signs of the health effect exists or a

    valid biological monitoring procedure is available to detect changes from

    11 Schedule 14 – Requirements for health monitoring in the Regulations

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    the current accepted values for the chemical

      arrange the health monitoring to be done by, or under the supervision of, aregistered medical practitioner with experience in health monitoring

      ask the registered medical practitioner for a health monitoring report

      give the worker a copy of the health monitoring report12 

      obtain a worker’s medical record only with the worker’s written consent, and

      disclose the contents of the worker’s medical record only with the worker’swritten consent.

    8.1 What is health monitoring?

    Health monitoring involves the medical monitoring of a person who may beexposed to a hazardous chemical. This may be through the testing of body fluidssuch as blood and urine, or through testing of body function, for example, lungfunction tests for workers who work with respiratory sensitisers, or an examinationof the skin.

    PCBUs should not use health monitoring in place of atmospheric monitoring as anindicator of potential health effects. In addition, health monitoring is not analternative to maintenance of control measures.

    Further information about types of health monitoring, what health monitoring shouldcover and the role of biological monitoring can be found in the additionalinformation provided in the back of this publication.

    8.2 Requirement for health monitoringWorkers should be made aware that health monitoring is sometimes necessary toensure their ongoing health. Health monitoring is often used in addition toworkplace monitoring. Workplace monitoring will only indicate the potential forexposure of workers to a hazardous chemical, it can never be an indication of theactual amount of chemical absorbed or the effect on the body of absorbing thehazardous chemical.Workers should be made aware that their PCBU is required by law to ensure thatworkers exposed to a hazardous chemical have health monitoring, where:

      it is required in the Regulation for exposure to that chemical, or

      an identifiable adverse health effect has happened, or may happen under theworker’s work conditions, and valid health monitoring or biological monitoringtechniques exist.

    Note: Examples of costs associated with health monitoring are:

      medical fees

    12 “Health monitoring report” means information, other than a medical record, about -

    (a) the effects on a person’s health related to the person’s exposure to a hazardous chemical at a workplace, and

    (b) the need (if any) for remedial action. 

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      pathology tests

      travelling expenses, and

      time away from work.

    8.3 Selection of the registered medical practitionerwith experience in health monitoring

    Section 371 of the Regulation requires the PCBU to ensure that health monitoringis carried out by or under the supervision of a registered medical practitioner withexperience in health monitoring.

    Choose a registered medical practitioner who:

      is willing to visit the workplace so as to understand the hazards and workprocesses

      demonstrates good interpersonal skills with workers, and

      is sensitive to other considerations intrinsic to the workplace.

    8.4 Access of information by a registered medicalpractitioner  

    When the risk assessment requires health monitoring to be undertaken theregistered medical practitioner should be:

      provided with access to a list of the hazardous chemicals for which the workersare required to have health monitoring and a copy of the SDS and exposurestandards for those chemicals

      provided with a list of the names of workers requiring health monitoring

      permitted to have access to any relevant assessment reports, and

      provided with any air monitoring results.

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     Appendix 1: Sampling techniques andmethods of analysis

     Advice on suitable sampling techniques and methods of analysis can be found inthe following publications:

    (a) Australian Standards, from Standards Australia, for example:

      AS 3640 Workplace Atmospheres – Method for Sampling and GravimetricDetermination of Inhalable Dust, and

      AS 2985 Workplace Atmospheres – Method for Sampling and GravimetricDetermination of Respirable Dust, and

    (b) the National Commission’s Exposure Standards for Atmospheric Contaminantsin the Occupational Environment [NOHSC:1003(1995)]

    (c) Safe Work Australia Workplace Exposure Standard for Airborne Contaminants,

    2012 

    (d) Safe Work Australia Health Monitoring Guide for hazardous chemicals

    (e) the United Kingdom Health and Safety Executive’s ‘Monitoring Strategies forToxic Substances’, Environmental Hygiene, No.42

    (f) the United Kingdom Health and Safety Executive’s Methods for theDetermination of Hazardous Substances, MDHS Series

    (g) the United States National Institute for Occupational Safety and Health’s

    Manual of Analytical Methods

    (h) the United States National Institute for Occupational Safety and Health’sOccupational Exposure Sampling Strategy Manual.

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     Appendix 2: Appropriate standards Appropriate Standards for particular control measures in the Hazardous ChemicalsCode of Practice.

    STANDARD DESCRIPTION AS 1345

    Identification of thecontents of pipes,conduits and ducts

    Specifies means of identifying the contents of pipes, conduits,

    ducts and sheathing used to contain fluids, or for thedistribution of electrical or communications services in landinstallations and on board ships by the use of colours, wordsand symbols.

     AS 1319Safety signs for theoccupationalenvironment

    Specifies requirements for the design and use of safety signsintended for use in the occupational environment to regulateand control safety related behaviours, to warn of hazards andto provide emergency information including fire protectioninformation.

     AS/NZS 1715Selection, use andmaintenance of

    respiratory protectivedevices

    Sets out the principles of respiratory protection, requirementsand recommendations for the selection, use and maintenanceof personal respiratory protective equipment (RPE) in the

    workplace. Includes discussion of respiratory hazards, theassessment of associated risks and various methods of controlincluding the use of respiratory protective equipment (RPE).

     AS/NZS 1716Respiratory ProtectiveDevices

    Specifies requirements for respiratory protective devices(respirators) intended to provide, according to type, varyingdegrees of protection against atmospheres containingsubstances which may be harmful if breathed; also, with certaintypes, to provide protection against atmospheres which may bedeficient in oxygen. The Standard specifies requirements,performance and testing criteria to be observed in themanufacture of respirators.

     AS/NZS 1337.1

    Personal eyeprotection - Eye andface protectors foroccupationalapplications

    Specifies minimum requirements for non-prescription eye and

    face protectors and associated oculars. They are designed toprovide protection for the eyes and faces of persons againstcommon occupational hazards such as flying particles andfragments, dusts, splashing materials and molten metals,harmful gases, vapours and aerosols. The aim of this Standardis to assist in the provision of safe, efficient and comfortablevision in the occupational situation. The Standard does notapply to filter oculars for protection against optical radiationsgenerated by industrial processes, which are dealt with in

     AS/NZS 1338.

     AS/NZS ISO 6529

    Protective Clothing –protection againstchemicals –Determination ofresistance ofprotective clothingmaterials topermeation by liquidsand gases

    Describes laboratory test methods that enable a determinationof the resistance of materials used in protective clothing to

    permeation by liquid or gaseous chemicals under theconditions of either continuous or intermittent contact. 

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     AS/NZS 4503.2

    Protective clothing –protection againstliquid chemicals – testmethod: determinationof resistance topenetration by a jet ofliquid (jet test)

    Specifies a method for determining the resistance of chemicalprotective clothing to penetration by jets of liquid chemicals. Itis applicable to clothing which may comprise one or more itemsand which is intended to be worn where there is a risk ofexposure to a forceful projection of a liquid chemical. It isapplicable to clothing which is intended to be resistant topenetration under conditions which require total body surfacecover but do not demand the wearing of gas-tight clothing.

     AS/NZS 4503.3

    Protective clothing -Protection againstliquid chemicals - Testmethod: Determinationof resistance topenetration by spray

    (Spray Test) 

    Specifies a method for determining the resistance of chemicalprotective clothing to penetration by sprays of liquid chemicals.It is applicable to clothing which may comprise one or moreitems and which is intended to be worn when there is a risk ofexposure to slight splashes of a liquid chemical or to sprayparticles that coalesce and run off the surface of the garment. Itis applicable to clothing which is intended to be resistant topenetration under conditions which require total body surfacecover, but do not demand the wearing of gas-tight clothing.

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     Appendix 3: Meeting your duties – Otheruseful documents

    These references relate to the Regulations, documents produced by the NationalOccupational Health and Safety Commission (NOHSC) and by Safe Work

     Australia.

    Duty holder Reference material

    Manufacturers andImporters

    Schedule 8 (Regulations) Disclosure of ingredients insafety data sheetList of Designated Hazardous Substances – Thisdocument is a quick reference to chemicals which havealready been determined to be hazardous.

    Schedule 6 (Regulations) Classification of mixtures Approved Criteria for Classifying Hazardous Substances 

     – This document sets out the criteria and process fordetermining whether a chemical is hazardous or not.

    Schedule 7 (Regulations) Safety data sheets

    National Code of Practice on the Preparation of SafetyData Sheets for Hazardous Chemicals (Safe Work

     Australia)Sets out information regarding data required on an SDS,and the method of presentation.

    Workplace Exposure Standards for AirborneContaminants (Safe Work Australia) – Sets outexposure standards for a number of hazardouschemicals and includes explanatory material.

    PCBUs Workplace Exposure Standards for A