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0.999 0.001 SPK = 1

SPECIES INLET MIXER REACTOR

C - 0.58 C - 0.01 C - 0.0014 C - 0.28

Hydrogen 700 720.020848803 -0.962843019 -0.558448951

Methane 0 0 0.9628430188 -0.558448951

Benzene 0 0 199.4460539 0.9628430188 0.279224475

Toluene 100 687.745013462 -199.4460539 0.9972302695 -0.962843019

ylene 0 0 199.4460539 -0.9972302695 -0.279224475

0 0 0.9972302695

T!T"# 800 1407.76586226 199.4460539 0.9972302695 0 -1.116897902

SFL

= SFH

=

Tr$%ethyl&enzene

Ethylene

Problem 5.1Basis: 100 mole Toluene

58% Conversion!ass"C#$ #8&C#' #'(C#8 #10 58% Conversion!assTO)*E+E BE+,E+E -)E+E

1% Conversion!ass"C#8 #10&C#$ #8(C#/ #1" 1% Conversion!ass-)E+E TO)*E+E T2ET)BE+,E+E

0.13% Conversion!assC#$ #8(#"&C#' #'(C#3 0.13% Conversion!aTO)*E+E 4OE+ BE+,E+E 2ET6+E

"8% Conversion!assC#8 #10( "#"&C#' #'("C#3 "8% Conversi-)E+E 4OE+ BE+,E+E 2ET6+E

E6CTO+ 6+4 TE CO+7EO+ PE P6

RECYCLED HYDROGEN

Makeup Hydrogen

Toluene

MIER RE!CTOR

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'ro&le% 5.4 "((u%)t$on(*

Ba($(*

+nlet 1

100 %ole Chlor$ne

100 %ole ,thylene

Coner($on ele/t$$tyCl 1 0.99 ,C

1 0.01 TC,

HCl 1 0.95 ,C

0.96 0.05 TC,

0.995 0.005 SFK = 1

COMPONENT INLET 1 INLET 2DC - REACTOR

-1 -2 -!T

Tr$/hloroethane 0 0 0.5 0.5

,thylene 100 1 -99 -0.5 0.5

Chlor$ne 100 0 -99 -1 0!ygen 0 0.5

ater 0 0

,C 0 0 99 99

HCl 0 0 0.5 0.5

$nyl/hlor$de 0 0

T!T"# 200 1.5 -99 -0.5 100.5

"ll Cl2$n ,"C 2 a( /on(u%ed to or%

TC,

C2H

4

SFL= SF

H=

xyc or eReactor

Direct Chl"Reactor

Ethylene

Chlorine

C#" #3(Cl#"&

C#" #3("Cl(

"C#" #3 Cl#"&

Che%$/al ea/

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0.000404394

200.487430.0004039897

0.0200408897

SEPR - 1 SEPR - 2 SEPR - 3

- !T 2 - + 3 - + H - !T M - !T B - !T 4 - +

20.04088969 20.0208488 0.02004089 20.0208488 0 0.0200408897 0

0.404394068 0.000404394 0.403989674 0 0.000404394 0.0004039897 0.403585684

200.6881214 0 200.6881214 200.4874332768 0.200688121

588.3333468 588.3333468 0 588.3333468

198.1695992 198.1695992 198.1695992

0.99723027 0.99723027 0.99723027

1008.633581 20.0212532 988.6123282 20.0208488 0.000404394 200.5078781561 788.10445

)ight gases

Cl

Cl

ss

n!ass

RECYCLED TOL'ENE

#E(R$E(R$)

#E(R$% *en+ene

Methane

Methane

Hydrogen

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SEPR 1 OC - REACTOR SEPR 2

-1 2-+ -1 -2 -!T -!T -!T

0 0.5 0.912 0.91908778 0 0.001531813

0.0995 0.4005 -0.912 -0.912 -0.824 -0.1821955556 -0.641804444

0 0 -0.912 -0.912 -0.2016533333 -0.710346667-0.456 0.044 0.0097288889 0.0342711111

0.912 0.916559885 0.0045827994 0.907417201

0 99 0.912 0.916575238 0 0.001527625

0.0025 0.4975 0 0.912 58444.93195 0 97.40821975

0.102 100.398 0.456 0 58445.99217 -0.3695372006 97.00081639

#plitter $ % #plitter $ &

,urnace#plitter $ ) #plit

ater

E4C

E4C

Viny C!"#i$% P#"&%''

lC#" #3 Cl

1" O#"&ClC#" #3 Cl(#" O

"C#" #9 Cl("Cl

$on(

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0.20048743330.5877450135

197.97142956

0.0009972303

0.0005883333

0.1981695992

0.9962330392

SEPR - ( SEPR - 5

T - !T 5 - + - !T TMB - !T

0

0.403585684 0

0.000200688 0.2004874333 0.2004874333 0

587.7450135 0.5883333468 0.5877450135 0.0005883333

0 198.169599159 197.97142956 0.1981695992

0.9972302695 0.0009972303 0.9962330392

588.1487998 199.955650208 198.760659237 1.1949909718

*en+ene

#E(R$.#E(R$-

Toluene

ylene

TM*

Toluene

TM*

ylene

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SEPR 3 F)RNACE SEPR (

HCl-!T ,C-!T :- :-!T HCl-!T -!T

0.917555967 0 0.9175559669 1.417555967 0.0070877798 0

0 0 0 0.4005 0 0

0 0 0 0 0 00 0 0 0 0 0

0.004559885 0.0045598854 1.110223,-016 1.11022,-016 -4.44893,-306 -8.9529,-306

0.915047613 0.0045752381 0.9104723746 -99.9104723746 0 0 0

58347.52373 58055.786011 291.737718512 99.9104723746 392.1455905 388.23393826 1.960727953

99.9104723746 100.4100122 0.5020500609 99.90796212

58349.36089 58055.7951462 293.565746853 99.9104723746 494.3736587 388.7430761 101.8686901

3- +

er $ - #plitter $ .

7inyl ;hlori

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SEPR 5

,C-!T C-!T

0 0

0 0

0 00 0

0 -8.9529,-306

0 0

0 1.9607279526

0.4995398106 99.408422314

0.4995398106 101.36915027

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