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Characterization of local rainwater lenses in agricultural areas with upward saline seepage. Monitoring results Zeeland Perry de Louw Gualbert Oude Essink Sara Eeman (WUR) Bart Goes Tomasso Letterio Bastiaan de Veen Corne Prevo Sjors Stevens Valentina Marconi Franceso Sergi Piet Maljaars

Characterization of local rainwater lenses in agricultural areas with upward saline seepage. Monitoring results Zeeland Perry de Louw Gualbert Oude Essink

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Characterization of local rainwater lenses in agricultural areas with upward saline seepage.

Monitoring results Zeeland

Perry de LouwGualbert Oude EssinkSara Eeman (WUR)Bart Goes

Tomasso Letterio Bastiaan de VeenCorne PrevoSjors Stevens Valentina Marconi Franceso SergiPiet Maljaars

21 april 2008

Saline groundwater

Max. Holocene Transgression

21 april 2008

Factors controlling fresh-salt interface(base for 27 representative monitoring sites)

Salinity of groundwater

Seepage intensity

Surface water level

Comp. Cover

Layer (k,d,S)

Drainage

Dynamics

21 april 2008

Surface level and position of 27 field sites

21 april 2008

Field measurements at 27 sites

In-situ, 1D: Temperature and EC with depth with TEC-probe

Ex-situ,2D: Continuous Vertical Electrical Sounding (CVES)Ex-situ,2D: Continuous Vertical Electrical Sounding (CVES)

In-situ,1D: Groundwater sampling at different depth (filters)In-situ,1D: Groundwater sampling at different depth (filters)

Indirect: formation factor

21 april 2008

TEC-probe results

0

2000

4000

6000

8000

10000

12000

-150 -100 -50 0 50 100 150

surface level (cm above sea level)

max

imum

CL-

CO

NC

(mg/

l)

R^2=0.76

Max

. C

l-con

c (m

g/l)

Surface Level (cm relative to sea level)

21 april 2008

Site 11 Center ditchBorder ditch1m

7.5m 15m

30m

50m

100m

200m

300m

Ditch

Fossil Creek ridge

CVES line

21 april 2008

21 april 2008

Site 11 Center ditchBorder ditch1m

7.5m 15m

30m

50m

100m

200m

300m

Ditch

Fossil Creek ridge

CVES line

21 april 2008

ECa – depth profiles (TEC-probe)

-400

-350

-300

-250

-200

-150

-100

-50

0

0.0 5.0 10.0 15.0 20.0 25.0

ECa (mS/cm)

dep

th (

cm)

1m

7.5m

15m

30m

50m-2

100m

150m

200m

300m

Mixing zone

21 april 2008

Characterization using statistical moments (1st, 2th)

-400

-350

-300

-250

-200

-150

-100

-50

0

0 1000 2000 3000 4000 5000

cl-conc (mg/l)

dept

h (m

)

widthcenter

Cl-min

Cl-max

0

50

10

0

15

0

20

0

25

0

30

0

35

0

40

0

45

0

50

0

05

01

00

15

02

00

25

03

00

35

04

00

45

05

00

de

pth

(cm

)

Cl-gradient (Cl/dm)

norm

al d

istributio

n

Cl-g

rad

(ma

x)

wid

th (~

5S

)

(µ, 1st mom.)

(5S, 2th)

(µ, 1st mom.)

(5S, 2th)

21 april 2008

Fitting on field data

-300

-200

-100

0

100

200

300

400

500

0 100 200 300 400 500depth (cm)

Cl-

gra

die

nt

(Cl/

dm

)

normal distribution

measured

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

16

-50

0

50

100

150

200

250

300

0 100 200 300 400 500depth (cm)

Cl-

gra

die

nt

(Cl/

dm

)

normal distribution

measured

12

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

1212 16

1612

21 april 2008

Measured and calculated cl-depth profiles

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)normaldistribution

measurement2

5

11

9

-400

-350

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000cl-conc (mg/l)

de

pth

(m

)

normaldistribution

measurement

10

13

21 april 2008

Cl-MIN CENTER Cl-MAX WIDTHsite depth cl-conc M cl-conc depth cl-conc cl-grad max depth cl-conc 5*S S

cm mg/l mg/l cm mg/l mg/l/dm cm mg/l cm cm2 40 300 500 190 1900 280 350 4500 300 603 38 200 960 90 5000 1800 130 9700 105 214 46 400 600 90 3300 1300 130 6100 88 185 55 500 900 140 3800 800 230 7300 170 349 116 200 300 200 750 100 280 1000 168 34

10 81 100 170 150 2200 650 210 4600 138 2811 71 300 550 190 4000 700 310 8600 238 4812 154 400 400 200 1000 170 270 1700 150 3013 203 500 500 240 2000 600 290 3300 95 1916 155 200 250 250 2100 350 350 3500 190 3821 93 200 370 130 1500 570 170 2300 75 1522 146 400 470 190 900 180 230 1200 88 1824 89 1500 1400 120 3000 900 160 4200 63 1326 70 2000 550 170 5000 550 270 7500 200 4027 54 100 700 150 3800 700 250 6800 193 39

1 600 -6 250 4007 470 24008 350 450

15 250 35017 350 50018 250 30019 350 55020 350 45023 450 600

Results: characteristics of fresh-saline interface

-400

-350

-300

-250

-200

-150

-100

-50

0

0 1000 2000 3000 4000 5000

cl-conc (mg/l)

dep

th (m

)

widthcenter

Cl-min

Cl-max

21 april 2008

Groundwater sampling: filters at different depths

3m

1.3m

1m

1.6m

2m

0.3m

0.5m

0.8m

Verzadigde zone

Onverzadigde zone

2m

sloot

4m

4m

21 april 2008

Location of monitoring points

90m50m30m17.5m

7.5m1m

Drain tubes

21 april 2008

-4.5

-4

-3.5

-3

-2.5

-2

-1.5

-1

-0.5

0

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Cl-conc (mg/l)

de

pth

(m

be

low

su

rfa

ce

le

ve

l)

1m

7.5m

17.5m

border ditch

center ditch

Cl-conc in parcel and in ditch (sampling)

21 april 2008

Cl-conc with depth (sampling)

-4.5

-4

-3.5

-3

-2.5

-2

-1.5

-1

-0.5

0

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Cl-conc (mg/l)

dep

th (

m b

elo

w s

urf

ace

leve

l)

1m

7.5m

17.5m

30m

17.5m drain

50m drain

GWL

21 april 2008

Unsaturated zone?

-4.5

-4

-3.5

-3

-2.5

-2

-1.5

-1

-0.5

0

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Cl-conc (mg/l)

dep

th (

m b

elo

w s

urf

ace

leve

l)

1m

7.5m

17.5m

30m

17.5m drain

50m drain

? ? ?

21 april 2008

Dynamics of Cl-profiles

-5

-4.5

-4

-3.5

-3

-2.5

-2

-1.5

-1

-0.5

0

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Cl-conc (mg/l)

dep

th (

m b

elo

w s

urf

ace

lev

el)

21 april 2008

Dynamics of Cl-profiles

-5

-4.5

-4

-3.5

-3

-2.5

-2

-1.5

-1

-0.5

0

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Cl-conc (mg/l)

dep

th (

m b

elo

w s

urf

ace

lev

el) T=1

T=2T=3

T=0

21 april 2008

Dynamics of Cl-profiles

-5

-4.5

-4

-3.5

-3

-2.5

-2

-1.5

-1

-0.5

0

0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Cl-conc (mg/l)

dep

th (

m b

elo

w s

urf

ace

lev

el)

21 april 2008

Conclusions monitoring results

• No sharp interface fresh rainwater-saline groundwater is found; • Mixing zone is found at shallow depth;• Characterization of mixing zone is relevant;• Statistical moments can be used for characterization interface

• At seepage sites no fresh groundwater was found (while P-ET >> seepage)• - What happens in the unsaturated zone?• - What is the dynamic of the mixing zone/cl-profile?

21 april 2008

THANK YOU

21 april 2008

Cl – depth profiles (TEC-probe)

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000 12000

cl-conc (mg/l)

dep

th (

m)

Ditch

17m from ditch

21 april 2008

-300

-250

-200

-150

-100

-50

0

0 2000 4000 6000 8000 10000 12000

cl-conc (mg/l)

dep

th (

m)

Ditch

Infiltration and seepage near ditch

21 april 2008

Empirical relation: Cl(x) - Electrical Resistance of water(ρw) - HCO3

21 april 2008

21 april 2008

21 april 2008

21 april 2008

-400

-350

-300

-250

-200

-150

-100

-50

0

0.0 5.0 10.0 15.0 20.0 25.0

EC (mS/cm)

dep

th (

cm)

in ditch

30m from ditch

50m from ditch

PEAT

site 11

21 april 2008

TEC-probe measurements in parcel (red) and ditch (blue)

Dep

th (

m b

elo

w s

urf

ace)

Cl-conc (mg/l)

21 april 2008

0

0.5

1

1.5

2

2.5

3

3.5

2025 2026 2027 2028 2029 2030 2031 2032 2033 2034 2035

Time [years AD]

Th

ickn

ess o

f t

he len

s [

m]

case 1

Fresh rainwater lens on saline groundwater

21 april 2008

Cross section: groundwater systems Zeeland

21 april 2008

Composition of cover layer

clay peat

sand

21 april 2008

Seepage intensity: Qs=Δh/c

_

= Seepage intensity(Qs)

Δh

C

21 april 2008

Seepage intensity

21 april 2008

CVES

G eo-elektrische m eetapparaat

4 kabels m et ieder 21 e lektrodes

160 m

40 m

Principal Continuous Vertical Electrical Sounding (CVES)Principal Continuous Vertical Electrical Sounding (CVES)>80 electrodes at surface2D elektrical resistance in subsoilMaximum depth (~30 m)

21 april 2008

Compensation for soil type: Formation factor FF

ECw = FF * ECa

Soil type

FF

peat 1-1.5

clay 1.5-3.5

silt 2-3.5

sand 3.5-5

ECa = EC of water and soilECw = EC of water

Clay% Stan. Err. p-value m (=FF) FF dev.st. FF var. FF mean

Sand <20 3.94 < 2.2e-16 3.24 0.430 0.185 3.285

Clay >20 3.19 < 2.2e-16 2.08 0.404 0.163 1.987

21 april 2008

Correlation:Char. rainwater lens - factors

75

100

125

150

175

200

225

250

275

-0.60 -0.40 -0.20 0.00 0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60

seepage intensity (mm/d)

DE

PT

H o

f c

en

ter

of

mix

ing

zo

ne

(m

be

low

su

rf.

l) seepageinfiltrationR^2=0.41

Dep

th c

ente

r of

mix

ing

zone

(cm

be

low

sur

afec

)Seepage intensity (mm/d)

0

2000

4000

6000

8000

10000

12000

-150 -100 -50 0 50 100 150

surface level (cm above sea level)

ma

xim

um C

L-C

ON

C (

mg

/l)

R^2=0.76

Max

. C

l-con

c (m

g/l)

Surface Level (cm relative to sea level)

21 april 2008

Site 11

-2.5

-2.0

-1.5

-1.0

-0.5

0.0

0.5

1.0

1.5

2.0

-25 0 25 50 75 100 125 150 175 200 225 250 275 300distance (m)

Re

lati

ve

he

igh

t (m

)

11.3

11.6

11.411.5 11.7

cl= 5000 mg/l

cl= 2500 mg/l

cl= 1000 mg/l

cl= 500 mg/lditc

h

ditc

h

21 april 2008

Lithostratigraphy of Holocene cover layer

Lithostratigraphy (Formation) Layer Facies/ Lithology

Naaldwijk Schoorl Eolian sand (dunes)

Zandvoort Marine sand (beach)

Walcheren Tidal flats and creeks

Wormer Tidal flats and creeks

Nieuwkoop Hollandveen Marsh (peat)

Basisveen Marsh (peat)

First aquifer

Hol. cover layer

21 april 2008

Creek (sand) and reclaimed salt marches (clay-peat)