53
Chapter 4 Nuclear Reactions: BBN, Stars, etc This chapter is divided into three parts:  preliminaries: thermally averaged rates and the S-factor  application to the pp chain  He burning 4.1 Rates and cross sections We want to consider the reaction 1(  p 1 ) + 2(  p 2 ) 1 (  p 1 ) + 2 (  p 2 ) where the four-momentum of particle 1 is given by  p 1 , etc. The rate (ev en ts/ unit time in some volume V) is dN dt  =   d x ρ 1 (  p 1 , x)  ρ 2 (  p 2 , x)   m 1 m 2 E 1 E 2 |M f i | 2 (2π) 4 δ 4 (  p 1  +  p 2  p 1  p 2 )  m 1 (2π) 3 d 3  p 1 E 1 m 2 (2π) 3 d 3  p 2 E 2 =   d x ρ 1 (  p 1 , x)  ρ 2 (  p 2 , x) |  v 1   v 2 |  m 1 m 2 E 1 E 2 σ 12 (  p 1 , p 2 ) (1) where  ρ 1 (  p 1 , x) is the number density of particles of type 1 with four-momentum  p 1  (that is, the number of particles per unit volume). The relative velocity is dened |  v 1   v 2 | =  (  p 1 ·  p 2 ) 2 m 2 1 m 2 2 E 1 E 2 (2) Suppose the densities above are constant over the volume of interest (some region within a star). Then the integral over   x  is simple, yielding r  = events/unit time/unit volume =  1 V dN dt  =  ρ 1 ρ 2 1 + δ 12 | v 1 v 2 |σ 12  (3) Note the factor of 1 +  δ 12 . The rate should be pr oportional to the number of pair s of  interacting particles in the volume. If the particles are distinct, this is   ij   ρ 1 ρ 2 , but if the particles are identical, the sum over distinct pairs gives  1 2 ij   1 2 ρ 1 ρ 2 . Not e we can also write the destruction rate per particle for particle 1 due to interactions with particles of type 2 as ω (2) 1  =  ρ 2 1 + δ 12 | v 1 v 2 |σ 12  (4) whi ch is the result one usually uses in buildi ng a rea cti on netwo rk. If there are mu ltiple destruction channels,  ω 1  =  ω (2) 1  + ω (3) 1  + ....  and the mean lifetime is τ 1  =  1 ω (2) 1  + ω (3) 1  + ... or  1 τ 1 =  1 τ (2) 1 +  1 τ (3) 1 + ...  (5) 1

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Chapter 4Nuclear Reactions: BBN, Stars, etc

This chapter is divided into three parts:• preliminaries: thermally averaged rates and the S-factor

• application to the pp chain• He burning

4.1 Rates and cross sectionsWe want to consider the reaction

1( p1) + 2( p2) → 1( p1) + 2( p2)

where the four-momentum of particle 1 is given by p1, etc. The rate (events/unit time insome volume V) is

dN

dt =

dx ρ1( p1, x) ρ2( p2, x) m1m2

E 1E 2 |M fi|2(2π)4δ 4( p1 + p2 − p1 − p2) m1

(2π)3

d3 p1

E 1

m2

(2π)3d3 p2

E 2

=

dx ρ1( p1, x) ρ2( p2, x) | v1 − v2| m1m2

E 1E 2σ12( p1, p2) (1)

where ρ1( p1, x) is the number density of particles of type 1 with four-momentum p1 (that is,the number of particles per unit volume). The relative velocity is defined

| v1 − v2| =

( p1 · p2)2 − m2

1m22

E 1E 2(2)

Suppose the densities above are constant over the volume of interest (some region within astar). Then the integral over x is simple, yielding

r = events/unit time/unit volume = 1

V

dN

dt =

ρ1ρ2

1 + δ 12|v1 − v2|σ12 (3)

Note the factor of 1 + δ 12. The rate should be proportional to the number of pairs of interacting particles in the volume. If the particles are distinct, this is

ij ∝ ρ1ρ2, but if

the particles are identical, the sum over distinct pairs gives 12

ij ∝ 1

2ρ1ρ2. Note we canalso write the destruction rate per particle for particle 1 due to interactions with particlesof type 2 as

ω

(2)

1 =

ρ2

1 + δ 12 |v1 − v2|σ12 (4)which is the result one usually uses in building a reaction network. If there are multipledestruction channels, ω1 = ω

(2)1 + ω

(3)1 + .... and the mean lifetime is

τ 1 = 1

ω(2)1 + ω

(3)1 + ...

or 1

τ 1=

1

τ (2)1

+ 1

τ (3)1

+ ... (5)

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These destruction channels can also include processes like free decays, e.g., n → p + e− + ν e,which would have no dependence on the density of other particles (other than final-stateblocking effects), as we previously discussed in BBN.

4.2 Relative velocity distributions

We now discuss reactions of nonrelativistic charged nuclei in a stellar plasma, where thenuclei have a distribution of velocities. The rate formula discussed above for 1+2 → 1’+2’can be generalized to take care of the velocity distribution

r = N 1N 21 + δ 12

vσ12(v) → N 1N 21 + δ 12

vσ12(v) (6)

where represents a thermal average. Note that we have written the cross section as afunction of the relative velocity v: this is ok as the total cross section is invariant underGalilean transformations (as is the rate), so it must have this form.

Now we use our Maxwell-Boltzmann velocity distribution

N 1 →

N 1( v1)d v1 = N 1

(

m1

2πkT )3/2e−m1v21/2kT d v1 (7)

to define this thermal average

vσ12(v) =

d v1d v2(

m1

2πkT )3/2(

m2

2πkT )3/2e−(m1v21+m2v22)/2kT σ12(v)v (8)

We introduce the center-of-mass and relative velocities

vcm = m1v1 + m2v2

m1 + m2vrel = v = v1 − v2 (9)

so that

v1 = vcm + m2v

m1 + m2v2 = vcm − m1v

m1 + m2(10)

With these definitions,

e−(m1v21+m2v22)/2kT = e−((m1+m2)v2cm+µv2)/2kT (11)

where µ = m1m2

m1+m2is the reduced mass.

Now dv1dv2 =

d(

v1 − v2√ 2

)d(v1 + v2√

2) =

dvd(

v1 + v2

2 ) (12)

But

vcm = 1

2(v1 + v2) +

1

2(

m1 − m2

m1 + m2)v (13)

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Therefore dv1dv2 =

dv

dvcm (14)

If we make this transformation in our expression for r, the entire dependence on vcm is

dvcme−(m1+m2)v

2cm/2kT = (

2πkT

m1 + m2)3/2 (15)

So we derive our desired result

r = N 1N 21 + δ 12

( µ

2πkT )3/2

dvσ12(v)ve−µv2/2kT (16)

That is, we have the result that the relative velocity distribution is a Maxwellian based on

the reduced mass. This can be written

r = N 1N 21 + δ 12

4π( µ

2πkT )3/2

0

v3dvσ12(v)e−µv2/2kT (17)

In the center of mass

vcm = 0 ⇒ v1 = −m2

m1v2 (18)

so that

v = v1 − v2 = v1(m1 + m2

m2) (19)

Thusv1 = (

m2

m1 + m2)v v2 = −(

m1

m1 + m2)v (20)

leading to

E = E cm =

m1

2 v2

1 +

m2

2 v2

2 =

µ

2 v2

(21)Therefore dE = µvdv and

r = N 1N 21 + δ 12

8

πµ(

1

kT )3/2

∞0

EdEσ12(E )e−E/kT . (22)

4.3 Nonresonant reactionsNuclear reactions of various types can occur in stars. The first division is between chargedreactions and neutron-induced reactions. The physics distinctions are the Coulomb barriersuppression of the former, and the need for a neutron source in the latter.

The charged particle reactions can also be divided in several classes. First, it is helpful todevelop a general physical picture of the process 1 + 2 → 1’ + 2’ as the merging of 1 and 2to form a compound nucleus, followed by the decay of that nucleus into 1’ + 2’. The notionof the compound nucleus is important: a nucleus is formed that is clear unstable, as it wasformed from 1+2 and therefore can decay at least into the 1+2 channel. Yet it is a long-lived state in the sense that it exists for a time much much longer than the transit time of a

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nucleon to cross the nucleus. Although the picture is not entirely accurate, it is neverthelesshelpful to envision the following analogy. Imagine a shallow ashtray, the bottom of whichhas a fairly uniform covering of marbles. Now put a marble on the flat lip of the ashtrayand give it a push, so that it rolls to the bottom of the ashtray with some kinetic energy. Allcollisions will be assumed elastic. Thus the system that one has created is unstable: there is

enough energy for the system to eject the marble back to the lip of the ashtray and thus off to infinity. But once the marble collides with the other marbles in the bottom of the ashtray,the energy is shared among the marbles. It becomes extremely improbable for one marble toget all of the energy, enabling it to escape. This is thus the picture of a compound nucleus,an unstable state that nevertheless is long lived, as it can only fission by a very improbablecircumstance where one nucleon (or group of nucleons) acquires sufficient energy to escape.

If one probes a nucleus above its particle breakup threshold - this would be the intermediatenucleus in the discussion above - one will observe resonances, states that are not eigenstatesbut instead are unstable and thus have some finite spread in energy. You may be familiarwith some examples from quantum mechanics: the case often first studied is the shape res-onances that occur when scattering particles off a well, such as a square well. Such statesusually carry a large fraction of the scattering strength and can be thought of as quasista-tionary states.

The charged particles break up into two classes, resonant (where the incident energy cor-responds to a resonance) and nonresonant. The first applications we will make involvenonresonant reactions, so this is the example we will do in some detail.

A picture of a nonresonant charged particle reaction is shown in Figure 3. It depicts barrierpenetration: the incident energy is well below the Coulomb barrier, so the classical turning

point is well outside the region of the strong potential where fusion can occur. But thisenergy is not coincident with any of the resonant quasistates.

Suppose we were interested in the reaction

3He + 4He → 7Be∗ → 7Be(g.s.) + γ (23)

where 7Be∗ is the intermediate nucleus formed in the fusion. To calculate the cross section,it will prove sufficient to ask the following question: given the nucleus 7Be∗, what is theprobability for it to decay into the channels 3He + 4He and 7Be(g.s.) + γ ? The former willbe related by time reversal to the probability for forming the compound nucleus.

For definiteness we ask for the rate for decaying into 3He + 4He. This is

λ(7Be∗) = 1

τ = prob./sec for flux of 3He/4He through a sphere at very large r

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−30 MeV

Z1

Z2

MeV

E

V(r)

r

r0

~ 1.44 A 1/3 fm

Tunnelling through coulomb barrier

for nuclear fusion

Figure 1: Sketch of the potential as a function of the distance r between two fusing nuclei.The strong force dominates for r less than r0, roughly the nuclear radius ∼ 1.44 A1/3, withA the mass number. If the center-of-mass energy is below the Coulomb barrier, the reactionmust proceed by tunneling, and is exponentially suppressed.

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where r is the relative coordinate of the 3He and 4He. This can be written

v

r2 sin θdθdφ|Ψ(r,θ,φ)|2

r→∞

= v

|χl(r)

r |2|Y lm|2r2 sin θdθdφ

r→∞

= v|χl(∞)|2 (24)

Note that |

χl(∞

)|2 is a constant for very large r. We can write this result as follows

λ(7Be∗) = vP l|χl(RN )|2 where P l = |χl(∞)|2|χl(RN )|2 (25)

where |χl(RN )|2 is a strong interaction quantity that depends on the wave function at thenuclear radius.

The penetration factor P l, the square of the ratio of the wave function at the nuclear surfaceto that an infinity, will be small if the Coulomb barrier is high, as the tunneling probabilitywould be low. A simple estimate of this can be made by assuming the attractive nuclearpotential turns on sharply at radius RN , so that outside of the matching radius one has a

pure Coulomb wave function. The Coulomb radial equation is

(− 1

d2

dr2 +

l(l + 1)

2µr2 +

αZ 1Z 2r

− E )χl(r) = 0 (26)

where r is the relative 3He-4He coordinate. Defining

E = p2/2µ ρ = pr η = αZ 1Z 2

v =

αZ 1Z 2µ

p = αZ 1Z 2

µ

2E

and Coulomb equation can be written in its standard form

d2χl

dρ2 + (1 − l(l + 1)

ρ2 − 2η

ρ )χl = 0. (27)

The outgoing solution corresponds to the following combination of the standard Coulombfunctions

A(Gl(η, ρ) + iF l(η, ρ)) −→as r → ∞

A(ei( pr−lπ/2−η ln 2 p+σl) ∼ Aeipr (28)

Thus we find the penetration factor

P l = |χl(∞)|2|χl(RN )|2 =

1

|F l(η, ρ|2 + |Gl(η, ρ)|2ρ= pRN

(29)

While the above is the exact solution in the region outside the nuclear potential, there is anapproximate approach that brings out the physics more readily, illustrating both the basicpenetration probability and the effects of higher partial waves and the finite nuclear radius.

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The calculation, which can be found in Clayton, uses the WKB approximation, in which theSchroedinger equation is solved via an expansion in powers of . Thus this is a semiclassicalapproximation. The derivation is a bit tedious so it will not be repeated here. It yields thealternative approximate expression

P WKBl ∼

2ηρ

e

−2πη+4√ 2ηρ− 2l(l+1)√

2ηρ

=

E cE

e

− 2παZ 1Z 2v +4√ 2µR2N E c− 2l(l+1)√ 2µR2N Ec

(30)

where E c = Z 1Z 2α/RN is the Coulomb potential at the nuclear surface and RN is the nuclearradius. This expression for the penetration factor consists of three terms• The leading Gamow factor, which also comes from the l=0 Coulomb expression we derivedearlier• The effects of the angular momentum barrier, proportional to l(l + 1), which suppressesthe contributions of higher partial waves• The third term shows that the nuclear radius effects the penetration: if everything else isheld fixed, the larger the radius, the greater the penetration.

If we take some reaction like 12C( p, γ )13N, the theory of compound nucleus reactions givesthe cross section for α → β (e.g., α = 1+2 and β = 1’+2’) as

σβα = π

k2

ΓβΓα

(E − E r)2 + (Γ2 )2

(31)

Here E r is the energy of the nearest resonance, Γ = Γα + Γβ + ... is the total width, andk is the wave number. Widths are related to the decay rate we have calculated by Γ = λand thus have the units of energy: the larger the width, the faster the decay, in accordancewith the uncertainty principle. And k = p, so the wave number k has the dimensions of 1/length. Thus it is clear that the cross section so defined has the proper units. Now thedefinition of a nonresonant reaction is that (E − E r) is much larger that Γ, so that one is along way from the resonance. The denominator above is then relatively smooth: it can bequite smooth if there are a number of contributing distant resonances. Noting

1

k2 ∝ 1

E Γα ∝ vP l|χl(RN )|2 ∝

√ E

1√ E

e−2παZ 1Z 2

v (32)

it follows that

σ ∝ 1

E e−

2παZ 1Z 2v (33)

motivating the definition of the S-factor

σ = 1

E e−

2παZ 1Z 2v S (E ) ∝ 1

E e− b√

E S (E ) (34)

Effectively what one has done is to remove the most rapid dependence on energy, the de-pendence that would correspond to the s-wave interaction of two charged particles. What

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0

0.5

1

1.5

0 0.5 1 1.5 2 2.5

HO59

PA63

NA69

KR82, RO83a

OS84

AL84

HI88

S - f a c t o r ( k e V - b )

E (MeV)

0.0001

0.001

0.01

0.1

1

10

HO59

PA63

NA69

KR82, RO83a

OS84

AL84

HI88 c r o s s s e c t i o n

( b

a r n

3He(α,γ)7Be

Figure 2: An illustration of the usefulness of the S-factor. The top panel shows the crosssection data for 3Heg(α, γ ), which varies by orders of magnitude as one approaches near-threshold – the energies of relevance to astrophysics. The lower panel is the correspondingS-factor – the data after s-wave point Coulomb effects are removed. The S-factor data stillcontains a great deal of complicated physics, including finite nuclear size effects, electronscreening effects on the reaction rate, etc. But the data’s much smoother behavior helpsexperimentalists reliably extrapolate measurements to the near-threshold region. This isimportant because accurate higher energy data (better statistics) can be used in a nearlylinear extrapolation.

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remains is a much more gently changing function S(E), which contains a lot of physics: theeffects of finite nuclear size, high partial waves, etc. The importance of the S(E) is that itcan be fitted to experimental cross section measurements made at energies higher than thosecharacteristic of stars. But if S(E) evolves slowly, it can be extrapolated to lower energiesthat are relevant to stellar burning. This limits the need for nuclear theory: one needs to

estimate the shape of S(E) as a function of E, but not its magnitude, as the magnitudecan be pegged to experiment. This is the strategy followed for the nonresonant reactions of interest in solar burning.

4.4 Thermally averaged cross sectionsThe leading Coulomb effect - the Gamow penetration factor - is a sharply rising functionof E. The Maxwell-Boltzmann distribution has an exponentially declining high-energy tail.Thus one immediately sees that σv involves a sharp competition between these two effects,leading to some compromise most-effective-energy. This is illustrated in the figure. We candetermine this energy,

σv =

8πµ

( 1kT

)3/2 ∞

0

EdEe−E/kT 1E

e−2παZ 1Z 2/vS (E ) (35)

Recalling v =

2E/µ and defining b = 2παZ 1Z 2

µ2 this integral becomes

8

πµ(

1

kT )3/2

∞0

dES (E )e−(E/kT +b/√ E ) (36)

Clearly the exponential is small at small E and at large E.

Now S(E) is assumed to be a slowly varying function. The standard method for estimatingsuch an integral, then, is to find the energy that maximizes the exponential, and expand

around this peak in the integrand. This corresponds to solving

d

dE (

E

kT +

b√ E

) = 0 (37)

The solution is

b = 2E

3/2o

kT (38)

We now expand the argument of the exponential around this peak energy

f (E ) = E

kT +

b√ E

∼ f (E o) + (E − E o) df

dE o+

1

2(E − E o)2

d2f

dE 2o+ ...

= f (E o) + f (E o)1

2(E − E o)2 + ... (39)

where we have used f (E o) = 0 by definition of E o. It follows

σv ∼

8

πµ(

1

kT )3/2

∞0

dES (E )e−f (E o)e−12(E −E o)2f (E o)

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0

25

50

75

100

0 0.05 0.1 0.15 0.2 0.25 0.3

R e l a t i v e

p r o b a b

i l i t y

Energy

Maxwell-Boltzmann

Tunneling throughCoulomb barrier

∆E0

Figure 3: The relative velocity distribution in a stellar gas drops rapidly with increasingenergy, while cross sections generally rise rapidly because higher energies help in overcomingthe exponential suppression due to the Colomb barrier. Thus the most probably energyfor a reaction involves a compromise between these two effects, and favor energies on thehigh-energy tail of the Boltzmann velocity distribution.

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8

πµ(

1

kT )3/2S (E o)e−f (E o)

∞−∞

dEe−12(E −E o)2f (E o) (40)

In deriving this result, we have assume S(E) is slowly varying in the vicinity of the integrandpeak at E o, and thus can be replaced by its value at the peak. Note our formula could easily

be improved by doing a Taylor expansion on S(E), e.g.,

S (E ) ∼ S (E o) + (E − E o) dS

dE o+ ... (41)

Thus our final answer would have an additional contribution due to S (E o).

But if we just keep S (E o), the integral can be done, yielding

∞−∞

dEe−12(E −E o)2f (E o) =

f (E o) (42)

so that

σv = 4√

µ(

1

kT )3/2S (E o)

e−f (E o) f (E o)

(43)

Now

f (E o) = 3b

4E 5/2o

= 3

2E okT f (E o) =

E okT

+ b√

E o=

3E okT

(44)

Thus

σv = 4

√ µ

( 1

kT )3/2S (E o)e−3E o/kT

2E okT

3

= 16

9√

3

1

µ

1

2παZ 1Z 2S (E o)e−3E o/kT (

3E okT

)2. (45)

Now we define a quantity A by

AM N = A1A2

A1 + A2M N ∼ m1m2

m1 + m2= µ (46)

where M N is the nucleon mass. Substituting this in, evaluating some constants, and dividingout the dimensions of S (note S has the units of a cross section times energy) yields

r12 ≡ N 1N 21 + δ 12

vσ12(v) = N 1N 21 + δ 12

(7.21·10−19cm3/sec) 1AZ 1Z 2

S (E o)keV barns

e−3E o/kT (3E okT

)2 (47)

Note that the overall dimensions are clearly 1/(cm3sec), as the number densities have units1/cm3. Also remember that a barn = 10−24 cm2.

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Now E o defines the peak of the contributions to vσ. From its definition

E o = (ktb

2 )2/3 ⇒ E o

kT = (

παZ 1Z 2√ 2

)2/3(µc2

kT )1/3 (48)

where the speed of light has been reinserted to make it explicit that this quantity carries nounits. For example, in the center of our sun kT ∼ 1.5 · 107K ∼ 1.3 keV. So if we plug in theappropriate numbers for the 3He+3He reaction one finds

E o ∼ 16.5kT ∼ 21.5keV (49)

One could compare this to the average energy of a Maxwell- Boltzmann distribition of pat-icles of E ∼ 3 kT. Thus, indeed, the reactions are occurring far out on the Boltzmanntail, where nuclei have a better chance of penetrating the Coulomb barrier.

It might be helpful at this point to walk through the example of 12C+p going to 13N. If we

define the zero of energy as that of the

12

C nucleus and proton at rest, then

13

N is bound by1.943 MeV. Furthermore there is a resonance in 13N at 2.367 MeV, 424 keV above the zeroof energy. Thus a 12C+p collision at a center-of-mass energy of 424 keV would be directly onresonance. In the lab frame, this corresponds to a 460 keV proton incident on a 12C nucleusat rest.

The cross section is

σ = 1

E S (E )e

−2παZ 1Z 2v =

π

k2

Γ p(E )Γγ

(E − E r)2 + (Γ/2)2 (50)

One can reexpress the S-factor, then, as

S (E ) = π

Γγ

(E − E r)2 + (Γ/2)2

e2παZ 1Z 2/vΓ p(E )

(51)

Now the product of the exponential and Γ p on the right should be roughly energy indepen-dent, as the exponential cancels the penetration probability buried in Γ p. Thus the assump-tion the S(E) is weakly energy dependent requires that one not be too close to the resonance.

If one examines this system experimentally, the results are as shown in the Figures 6. Notethat S(E) is quite smooth for E 300 keV. Thus data in the 100-300 keV range can beused to extrapolate the measured cross section to the region of interest for p burning via

the CNO cycles. In contrast, the raw cross section varies over 9 orders of magnitude. Notethat the theory curve, which takes into account the resonance, does quite well throughoutthe illustrated region. Thus the success of theory in the 100-400 keV region gives one greatconfidence that the values extrapolated to 20-50 keV are correct. The sharp steeping of S (E )above 400 keV lab energy is a clear indication of the resonance at 460 keV lab proton energy.

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Figure 4: The data for 12C(p,γ ) and the resulting S-factor. The energies of astrophysicalinterest are around 30 keV, where the cross section data are very steeply falling due toColomb effects. 13

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Figure 5: Two schematic diagrams showing main-sequence sections of the HR diagram,including the position of our sun.

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specify the equation of state as a function of temperature, density, and composition.

• Energy is transported by radiation and convection. While the solar envelope is convective,radiative transport dominates in the core region where thermonuclear reactions take place.The opacity depends sensitively on the solar composition, particularly the abundances of

heavier elements.

• Thermonuclear reaction chains generate solar energy. The standard model predicts thisenergy is produced from the conversion of four protons into 4He.

4 p →4 He + 2e+ + 2ν e

About 98% of the time this occurs through the pp chain, with the CNO cycle contributingthe remaining 2%. The sun is a large but slow reactor: the core temperature, T c ∼ 1.5 · 107

K, results in typical center-of-mass energies for reacting particles of ∼ 10 keV, much lessthan the Coulomb barriers inhibiting charged particle nuclear reactions. Thus reaction cross

sections are small, and one must go to significantly higher energies before laboratory mea-surements are feasible. These laboratory data must then be extrapolated to the solar energiesof interest, as we discussed previously.

• The model is constrained to produce today’s solar radius, mass, and luminosity. An impor-tant assumption of the standard model is that the sun was highly convective, and thereforeuniform in composition, when it first entered the main sequence. It is furthermore assumedthat the surface abundances of metals (nuclei with A > 5) were undisturbed by the subse-quent evolution, and thus provide a record of the initial solar metallicity. The remainingparameter is the initial 4He/H ratio, which is adjusted until the model reproduces the presentsolar luminosity after 4.6 billion years of evolution. The resulting 4He/H mass fraction ratiois typically 0.27 ± 0.01, which can be compared to the big-bang value of 0.23 ± 0.01. (Notethat today’s surface abundance can differ from this value due to diffusion of He over thelifetime of the sun.) Note that the sun was formed from previously processed material.

The “standard solar model” is the terminology used to describe models, such as that of Bah-call and Pinsonneault, that implement the above physics in a computer code, then evolvethe sun forward from the onset of main sequence burning. Generally calculations are one-dimensional, which means that the physics such as convection can not arise dynamically. Itcan, and sometimes is, put in phenomenologically, through approximations such as “mixinglength theory.”

The model that emerges is an evolving sun. As the core’s chemical composition changes, theopacity and core temperature rise, producing a 44% luminosity increase since the onset of the main sequence. Some other features of the sun evolve even more rapidly. For example,the 8B neutrino flux, the most temperature-dependent component, proves to be of relativelyrecent origin: the predicted flux increases exponentially with a doubling period of about 0.9

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Figure 6: The pp chain, showing the terminations corresponding to the competing ppI, ppII,and ppIII cycles. Note the cycles are ”tagged” by associated characteristic neutrinos.

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billion years. This is the flux to which Ray Davis’s famous Homestake gold mine experi-ment is primarily sensitive. As another example of a time-dependent feature of the sun, theequilibrium abundance and equilibration time for 3He are both sharply increasing functionsof the distance from the solar center. Thus a steep 3He density gradient is established overtime. We will shortly see that the 3He is sort of a “caltalyst” in the pp chain, being produced

and then consumed as an intermediate step in synthesizing 4He.

Such models generally do not model the earliest history of our sun, when it first formed asa body of gas contracting under its own gravity, heating and ionizing as the gravitationalwork is done. The early contraction of the sun, when it approaches the main sequence ver-tically from above in the HR diagram, is characterized by high luminosity and convectionthroughout the star, lasting for a few million years. (Actually, there is thought to be con-tinued convection in the core of sun for perhaps 108 years, though this is driven by anothermechanism: the fact that the CNO cycle is burning out of equilibrium due to initials metalsin the sun.) The core of the sun reaches radiative equilibrium first, and this region thengrows outward.

But there are shortcomings in the standard solar model. Li had to be burned at some pointin the sun’s evolution to account for the fact that the solar surface abundance is roughly1/100th that found in meteorites. Perhaps this is due to the failure to model the sun’s earlyconvective stage. Or perhaps material can be pulled below the convective envelope by somemechanism, to a depth where the higher temperature allows 7Li(γ,3He)4He to occur.

Now a realistic standard solar model, even if restricted to 1D (as is usually the case) isa nontrivial numerical problem: the radiative transport requires detailed opacities, whichdepend on composition, the energy production also depends on composition and on compo-

sitions that are established as the pp-chain evolves, etc. However, much simpler (and lessdynamic) toy models exist which are not too unrealistic. One set is these comes from theLane-Emden equation, which provide a solution with a total mass and radius, for a givenpolytrope (defined below).

Consider a spherically symmetric star governed by the following equations

dp(r)

dr = −Gm(r)

r2 ρ(r)

dm(r)

dr = 4πr2ρ(r)

p(r) = kργ ⇒ p p0

=

ρρ0

γ

(56)

Here p(r) and ρ(r) are the star’s pressure and density profile, with p0 and ρ0 the centralpressure and density. The first equation is hydrostatic equilibrium. The second definesthe contained mass as a function of ρ. And the third is a simplifying assumption that the

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equation of state is defined by a single adiabatic index γ , where

γ ≡ c pcv

= 1 + 1

n =

n + 1

n (57)

is the ratio of the specific heats, and where n is the polytrope index. Different choices of n

are appropriate for different stars. The best approximation to stars like the Sun is n = 3.

Introduce the function

Φ(r) ≡

ρ(r)

ρ0

γ −1

=

p(r)

p0

γ −1γ

(58)

Then

dΦ(r)

dr =

γ − 1

γ

p(r)

p0

−1γ 1

p0

dp(r)

dr =

γ − 1

γ

ρ0

ρ(r)

1

p0

dp(r)

dr =

γ − 1

γ

ρ0

p0

−Gm(r)

r2

(59)

where we have used the hydrostatic equilibrium equation in the last step. Thus

m(r) = − 1

G

γ

γ − 1

p0

ρ0r2 dΦ(r)

dr

⇒ dm(r)

dr = − 1

G

γ

γ − 1

p0

ρ0

d

dr

r2 dΦ(r)

dr

= 4πr2ρ(r) = 4πr2ρ0Φ(r)

1γ −1

⇒ 2

r

dΦ(r)

dr +

d2Φ(r)

dr2 = −4πG

γ − 1

γ

ρ20

p0Φ(r)

1γ −1 (60)

Now define the dimensionless coordinate x = r/rx where

rx = p0γ

4πGρ20(γ − 1)

1/2(61)

and we obtain the Lane-Emden equation

d2Φ(x)

dx2 +

2

x

dΦ(x)

dx + Φ(x)

1γ −1 = 0 (62)

This must be solved with the boundary conditions ρ(0) = ρ0 and ρ(0) = 0 which yield

Φ(0) = 1 Φ(0) = 0 (63)

The n = 3 (γ = 4/3) polytrope provides a good description of stars like our sun. We evaluate

Φ(x) with NDSolve on Mathematica. With that solution we then

• Solve for Φ(x) == 0, finding x=6.89685, which we will use to determine the stellarradius below, as at this point the pressure and density vanish.

• Integrate x2Φ(x)1/(γ −1) from 0 to 6.89685, as we will be able to relate this quantity tiothe solar mass. This integral is 2.01824.

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11010

21010

31010

41010

20

40

60

80

100

120

140

Figure 7: The Lane-Emden n=3 polytrope solution for the solar density profile (units of g/cm3) as a function of radius (in cm). The solar surface is at r=5.582 ×1010 cm.

under the approximations described above. Consequently

P = ρN A 3 + 5X

4 kT (72)

where it is implicit the P, ρ, and X are also functions of r. If one knows X (r), one cancalculate T (r) in the Lane-Emden model described above. In the SSM at r = 0 X ∼ 0.341,from which one then finds T c ∼ 1.48×107K. This compares to the SSM value of 1.56×107K.By looking up X (r) from the SSM, we could calculate the temperature at other rs too.

In fact, we can do much better than this. One can convert this simple - but realistic, asseen above - model into an evolutionary model. At time t = 0, the beginning of the mainsequence, the standard assumption (as we have noted) is a homogeneous Sun. X would thenbe independent of r, a great simplification. Its value would be around 0.72, slightly smallerthan the primordial value since our Sun was created 9 b.y. after the Big Bang, and thus

was formed from material that had been processed by earlier generations of stars. We couldthen pick a value for ρ0 to start things off. As X (r) is initially independent of r, we wouldknow the temperature everywhere. Now we evolve for a time step ∆t. By putting in thenuclear reactions for the pp chain, at t = 0 + ∆t we could evaluate the produced 4He (aswell as the amount of 3He) as a function of r. All of the production would be near the star’scenter. We would then have µ(r) at that time, and thus we could evaluate T (r). Then we

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where the gas constant a = π2/15, from Chapter 3. Now assume β = P gas/P is constant.Then

P = 1

β

ρN Aµ

kT and 1 − β = P radiation

P =

1

3a(kT )4

1

P (74)

Eliminating T between these two equations yields

P =

1 − β

β 4

1/33N 4Aaµ4

1/3

ρ4/3 (75)

Thus γ = 4/3 and n=3. The observation that main sequence stars have roughly constant β is thus the reason for taking n=3. For the Sun, β ∼ 0.9993.

4.6 The pp-chainNow let’s turn to the pp chain. The controlling reaction of the chain is the initial reaction,the β decay of two protons in a plasma. This weak interaction is the mechanism by whichthe Sun produces neutrons, the necessary step in creating He. The slowness of this reaction

accounts for the long expected lifetime of the Sun, about 10 b.y.

The p+p cross section is

σ =

1

|v1 − v2| |H w|2(2π)δ (W − E e − E ν ) mν

(2π)3d3 pν

E ν

me

(2π)3d3 pe

E p(76)

where W , ignoring small momentum corrections, is the difference in (nuclear not atomic)masses, 2m p − mD ∼ 0.931 MeV. As we did previously in neutron β decay, we treat theamplitude in the allowed approximation and nucleon motion nonrelativistically. The Fermioperator connects only to the isospin analog state, that is, to the state identical to the initial

state in terms of space and spin, but with (T, M T ) = (T i, M T i ± 1) for β − and β + decay,respectively. Now the reaction of interest, p + p → d + e+ + ν e, produces a final nuclear statewith J = 1 and isospin T=0: this is an isospin singlet, so there is no corresponding statein p+p that can be reached by the Fermi operator. It follows that only the Gamow-Telleroperator contributes. Using an earlier result for integration over the phase space, we find

σ = 1

|v1 − v2|G2F cos2 θc

1

2π3 |M GT |2

W

me

F (Z, )(W − )2

2 − m2e d (77)

We can do the integral over the outgoing electron energy in β decay, ignoring the Coulombcorrection for the outgoing electron in the field of the nucleus. This is a good approximation

as the nuclear energy release in the decay, 0.931 MeV, means the outgoing electron andneutrino share .420 MeV of kinetic energy. If half of this goes to the electron on average,then the typical velocity of the electron is 0.7c. Thus

2πη = 2πZ 1Z 2α/β ∼ 0.065 ⇒ F (Z, ) ∼ 0.97

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So the Coulomb effects can be ignored. We find

σ = 1

|v1 − v2|G2F cos2 θc

1

2π3m5

e

√ x2 − 1(

x4

30 − 3x2

20 − 2

15) +

x

4 ln(x +

√ x2 − 1)

|M GT |2

(78)

where x = W/me.

Now we address the spin-isospin matrix element that appears in Eq. (78), as it is a bitdifferent from the one we discussed for neutron β decay. Recall for the earlier case:

|M GT |2neutron ≡ g2

A

2J i + 1|J f = 1/2; T f = 1/2, M T f = 1/2||στ +||J i = 1/2; T i = 1/2, M T i = −1/2|2

(79)This matrix element, reduced in angular momentum but not isospin, came from averagingover initial angular momentum states and summing over final, that is

1

2 |1/2; 1/2, 1/2||στ +||1/2; 1/2, −1/2|2

=1

2

mf ,m,mi

1/2, mf ; 1/2, 1/2|σmτ +|1/2, mi; 1/2, −1/2

× 1/2, mf ; 1/2, 1/2|σmτ +|1/2, mi; 1/2, −1/2† =

1

2

mf ,m,mi

(−1)1/2−mf

1/2 1 1/2−mf m mi

2

|1/2; 1/2, 1/2||στ +||1/2; 1/2, −1/2|2 =

1

2

m

1

3|1/2; 1/2, 1/2||στ +||1/2; 1/2, −1/2|2 =

12

|1/2; 1/2, 1/2||στ +||1/2; 1/2, −1/2|2 (80)

The Gamow-Teller transition matrix element for p+p is a bit more complicated than in thecase of the neutron: for the neutron, we had to specify only the initial and final spin andisospin. In contrast, the wave function of the p + p initial state and the final-state deuteroncan be written as a product of a center-of-mass piece and a relative wave function. Forexample, were we to ignore p-p interactions, the two-proton state could be decomposed

ei p1·x1ei p2·x2 = ei( p1+ p2)·(x1+ x2)/2ei( p1− p2)·( x1−x2)/2 (81)

The first term is part of the integration that is done to generate the three-momentum-conserving delta function, (2π)3δ 3( p1 + p2 − pd − pν − pe), that was already employed in Eq.(76) to do the integral over the final-state deuteron’s center-of-mass three-momentum. Thispart is analogous to the neutron. But for the two-nucleon system there remains a relativecoordinate piece that, for simple plane waves is immediate

ei( p1− p2)·(x1−x2)/2 →√

4πj0(kr)Y 00(Ωr) (82)

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where k = ( p1 − p2)/2, r = (x1 − x2), and where we have retained only the s-wave contribu-tion, which dominates at low energies. In a realistic case the relative wave function must begenerated from solutions to the Schroedinger equation for bound and continuum states – asdiscussed below.

The relative p+p wave function differs from a plane wave due to the Coulomb barrier atlarger separations and the strong interaction at short distance. To estimate the p+p ratewe thus need to build a model for the relative wave function: we follow here the histori-cal calculation of Bethe and Critchfield (though the derivation here differs in many of thedetails – and perhaps ought to be checked by the reader, as it is sufficiently complicatederrors can easily creep in). It is worthwhile going through the details so that one can seehow an S-factor is determined theoretically, in an important case where direct laboratorymeasurements are not possible. We also need to evaluate the spin/isospin matrix element.Since our radial wave function is s-wave, the spin is the angular momentum. We first do thespin/isospin matrix element (which interestingly Bethe and Critchfield did not address).

The deuteron is isoscalar and 95% s-wave: we will treat it as purely s-wave for this reasonand because only this part of the wave function will connect to the very low energy p+pwave function, as this will be almost entirely s-wave. As the deuteron has T=0, and as thePauli principle requires L + S + T = 0, the deuteron hasS = 1, that is, the spin state issymmetric and the isospin state antisymmetric. The initial p+p state is isovector (symmet-ric) and as we have noted, is almost entirely L = 0.. Thus the only component of the initialspin state that contributes is the spin-antisymmetric component, S = 0. As the initial statecorresponds to separated protons with uncorrelated spins, only the S = 0 component of thatspin-uncorrelated wave function contributes.

In analogy with the second line of Eq. (80), the required matrix elements involves anaverage over initial proton spin magnetic quantum numbers and a sum over the final deuteronmagnetic quantum numbers. The spin-part can be evaluated

|M GT |2 pp→d = g2

A

2 · 2

mp1,mp2 ,md,m

αd; S = 1md; T = 0, M T = 0|2

i=1

σ(i)mτ −(i)|α pp; 1/2m p1, 1/2m p2 ; T = 1M T i = 1

×αd; S = 1md; T = 0, M T = 0

|

2

i=1

σ(i)mτ −

(i)

|α pp; 1/2m p1, 1/2m p2; T = 1M T i = 1

† (83)

where αd and α pp denote spatial quantum numbers of the l = 0 initial and final states.But the spin sums must yield an S = 0 initial state by antisymmetry, so we know the onlycontributing terms in the initial-state sum are

|1/2, m p1 = 1/2; 1/2, m p2 = −1/2 =

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We begin by specifying a simple model that nevertheless has enough flexibility to reproduceimportant feature of the two-nucleon system, such as the binding energy E b = 2.22 MeV of the deuteron. (Note that E b is defined as positive.) We solve the 3D square well problemfor a bound n+p system,

R

l=0

d (r)Y 00(Ωr) ≡ χd

r Y 00(Ωr) (88)

− 1

2µd2

dr2 + |E b| − V t

χd = 0 r < RN

− 1

2µd2

dr2 + |E b|

χd = 0 r > RN

R0d(r) = A0

1ar sin (ar) r < RN

1are−b(r−RN ) sin(aRN ) r > RN

eigenvalue condition : cot(aRN ) = − b

a

A0 = a2

sin(aRN ) [2µ|E b|]1/4

1

2µV t

1/2

21 + bRN

1/2

where a =

2µ(V t − |E b|), b =

2µ|E b|, µ = m p/2, and RN and V t = |V t| are the radiusand depth of the spherical square well. Here the subscript “t” denotes that we are workingin the triplet channel, that is, S=1 (and thus T=0 as L=0). This is the NN channel that hasa bound state. For example, the choice V =50 MeV and RN = 1.66 f would give the correctdeuteron binding energy and thus the correct bound-state tail. (We will discuss later howwe fine tune V and RN .)

Similarly, we need to solve the 3D square well + Coulomb problem for the p+p system.This is the singlet channel, S=0, with L=0 and T=1. (L+S+T must be odd to producean antisymmetric wave function.) We know there is no bound state in this channel, so weanticipate the potential will be less deep than in the triplet case. (We return to this pointlater.) We assume the Coulomb potential outside of RN , and our square well inside. Forsimplicity, we take the same radius for the triplet and singlet channels. This yields,

Rl=0 pp (r)Y 00(Ωr) ≡ χ pp

r Y 00(Ωr) (

− 1

2µd2

dr2 − E − V s

χ pp = 0 r < RN

− 12µ

d2

dr2 − E + αr

χ pp = 0 r > RN

R0 pp(r) =

B01gr

sin (gr) r < R

√ 4π eiδ cos δ

kr [F 0(η,kr) + tan δG0(η,kr)] r > R

where g =

2µ(V s + E ), η = αZ 1Z 1µ/k = αµ/k, and E = k2/2µ. As we will see explicitly

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From these results, with some rearrangement, one can write the pp solution

R pp(r) =√

4πeiδ cos δC 0(η)

RN

rsin gr

sin gRN

1√ 2ηρN

I 1(2√

2ηρN ) + 2λ√

2ηρN K 1(2√

2ηρN )

r ≤ RN

1√ 2ηρ

I 1(2√

2ηρ) + RN

r 2λ√

2ρηK 1(2√

2ηρ) r

≥RN

(93)We can now break up the integral appearing in Eq. (87) into two parts ∞

0

r2drR∗d(r)R pp(r) =

RN

0

r2drR∗d(r)R pp(r) +

∞RN

r2drR∗d(r)R pp(r) (94)

The first integral can be done analytically, yielding RN

0

r2drR∗d(r)R pp(r) =

√ 8πeiδ cos δ C 0(η)

× [2µE b]1/4

2µ(V s − V t + E + E b)V t

−E b

V t1/2 1

1 +

2µE bR2N

1/2

ΛI (95)

where

ΛI ≡

1√ 2ηρN

I 1(2

2ηρN ) + 2λ

2ηρN K 1(2

2ηρN )

×

2µ(V t − E b)R2N cot

2µ(V t − E b)R2

N −

2µ(V s + E )R2N cot

2µ(V s + E )R2

N

(96)

The second integral requires a numerical integration (or some expansion, which is what Betheand Critchfield did).

∞RN

r2drR∗d(r)R pp(r) =

√ 8πeiδ cos δ C 0(η)

1

[2µE b]3/4

V t − E b

V t

1/2 1

1 +

2µE bR2N

1/2

ΛO

where ΛO ≡ 2µE bR2

N

1/4 ∞√ 2µE bR

2N

√ ydy e−(y−

√ 2µE bR

2N )

×

1√ 2ηρN

I 1

2√

y [2ηρN ]

1/2

[2µE bR2N ]

1/4

+ 2λ

2ηρN K 1

2√

y [2ηρN ]

1/2

[2µE bR2N ]

1/4

(97)

Except for an extremely small E dependence hiding in λ, Λ0 is energy independent.

We can now plug back into our original cross section formula and do a bit of algebra to find

σ =

µ

2E G2

F cos2 θc6g2

A

π2 m5

e

√ x2 − 1(

x4

30 − 3x2

20 − 2

15) +

x

4ln(x +

√ x2 − 1)

cos2 δC 20(η)

× 1

[2µE b]3/2

V t − E b

V t

1

1 +

2µE bR2N

E b

V s − V t + E + E bΛI + ΛO

2(98)

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We retain the same radius for the singlet channel, but find the V s that gives the anomalousscattering length as = −23.727 f (which indicates there is no bound state, but there is aresonance very close to threshold). Fitting V s to as yields

V s = 21.502 MeV (104)

And we note our model is not perfect. We can easily evaluate the effective ranges, findingrto = 1.772 f (1.833 f) and rs

o = 2.183 f (2.67 f), where the experimental values are givenin parenthesis. So now we can do our integrals (doing ΛO numerically on Mathematica),yielding

E bV s − V t + E b

ΛI = 1.138 ΛO = 4.543, (105)

so we find most of the integral comes from outside the nuclear range. Plugging these numbersinto Eq. (99) then yields

S pp(0) = 5.81 × 10−23 MeV f 2 = 5.81 × 10−25 MeV barns. (106)

The currently accepted value is 4.01(1

±0.009)

×10−25 MeV barns. Thus our value is 50%

higher. The consistency can be tested by altering our nuclear model over a reasonable range.For example, were we to adopt V t ∼ 50 MeV, a not unreasonable value if one looks atschematic models, and fit only the deuteron eigenvalue, then we would deduce RN ∼ 1.661f. The scattering length and effective range are a bit off, but not unreasonable, 5.180 f and1.444 f, respectively. We fit as

o to obtain V s = 35.09 MeV, and predict rso ∼ 1.708. We find

E bΛI /(V s − V t + E b) = 0.476 and ΛO = 3.159, and S (0) ∼ 2.65 × 10−25 MeV barns. This is∼ 50% too low. Thus we argue we are in the ballpark.

In a true effective theory calculation, one would have to worry about the operator as well.There is a short-range two-nucleon correction that requires the fixing of one low-energy con-

stant, called L1A, that yields about a 5% correction.

It would be quite interesting to embellish this calculation, to see if one can do better. Amore complicated square-well potential that included a repulsive hard core would introduceneeded parameters that could then be used to “mock-up” the low energy behavior: V HC

t ,V t, RN , RHC

N , V HC s , and V s could be fit to the effective range expansion up through order

k4 in both the singlet and triplet channels. The primary motivation for this would be todetermine S (0) and S (0). The literature gives a result for S (0),

limE → 0

dS pp(E )

dE ∼ S pp(0)(11.2 ± 0.1) MeV−1 (107)

Thus at 10 keV, this slope generates a ∼ 10% correction to the S-factor.

Now that we know the S-factor, we can plug it into our rate formula to determine the rateof the p+p reaction. Recall

E okT

παZ 1Z 2√ 2

2/3µc2

kT

1/3

∼ 5.23

T 1/37

(108)

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But from the S-factors

S 12(0) = 2.5 · 10−4 kev b S 11(0) = 4.01 · 10−22 kev b (114)

and our rate formula

λ12 = (7.21 · 10−19cm3/sec) 1AZ 1Z 2

S (E o)kev − b

(Z 21Z 22A)2/3( 19.7T

1/37

)2e−(Z 21Z 22A)1/319.7/T 1/37

(115)

We can plug in the values

p + p : Z 1 = Z 2 = 1 A = 1/2

p + d : Z 1 = Z 2 = 1 A = 2/3

to find N pN d

equil

= (0.9 · 10−18)e1.574/T 1/37 (116)

Therefore this ratio is a decreasing function of T 7: the higher the temperature, the lower theequilibrium abundance of deuterium. Therefore in the region of the sun where the ppI cycleis operating, the deuterium abundance is lowest in the sun’s center. Plugging in the solarcore temperature

T 7 = 1.5 ⇒

N dN p

= 3.6 · 10−18 (117)

There isn’t much deuterium about: using N p ∼ 3 · 1025/cm3 one finds N d ∼ 108/cm3.Remembering our previous result

r pp ∼ 0.6 × 108/cm3/sec (118)

it follows that the typical life time of a deuterium nucleus is τ d ∼ 1 sec. That is, deuteriumis burned instantaneously and thus reaches equilibrium very, very quickly.

This result then allows us to write the analogous equation for 3He as

dN 3dt

= λ pp

N 2 p2 − 2λ33

N 232

(119)

where the factor of two in the term on the right comes because the 3He+3He reaction destroystwo 3He nuclei. Thus at equilibrium

N 3N p

equil

=

λ pp2λ33

(120)

Using S 33(0) = 5.15 · 103 keV b we can again do the rate algebra to findN 3N p

equil

= (1.33 · 10−13)e20.65T −1/37 =

9.08 · 10−6 T 7 = 1.51.24 · 10−4 T 7 = 1.0

(121)

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Figure 10: The distribution of 3He in the sun, showing a sharp gradient in this element,which acts like a catalyst in the pp chain. The equilibrium abundance and the time requiredto reach equilibrium are both sharply decreasing functions of T – larger in the cooler partsof the sun. But at large radii, beyond 0.3Ro, the abundance has not yet reached equilibrium.

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However there are two other paths through the pp chain that can occur if 3He burns byanother path. Thus

3He + 3He → 4He + p + p vs. 3He + 4He → 7Be + γ

determines the ppI vs. ppII+ppIII splitting. The splitting between the ppII and ppIII cyclesdepends on the fate of the 7Be

7Be + e− → 7Li + ν vs. 7Be + p → 8B + γ .

Thus the two additional cycles are

p + p → d + e+ + ν e or p + p + e− → d + ν e

d + p → 3He + γ 3He + 4He → 7Be + γ

7Be + e− → 7Li + ν e7

Li + p → 24

He ppII cycle (126)

and

p + p → d + e+ + ν e or p + p + e− → d + ν e

d + p → 3He + γ 3He + 4He → 7Be + γ

7Be + p → 8B + γ 8B → 8Be + e+ + ν e

8Be → 24He ppIII cycle (127)

The calculations presented below will show that the competition between the three cyclesis quite sensitive to the interior temperature of the sun, and to core composition. We alsonote that, in principle, we can experimentally determine the relative importance of the threecycles: the cycles are distinguished by the neutrinos they produce.

ppI + ppII + ppIII rate ∝ Φν ( pp) : β endpoint ∼ 0.420 MeV

ppII rate ∝ Φν (7Be) : electron capture, E ν = 0.86 MeV(90%), 0.38 MeV(10%)

ppIII rate ∝ Φν (8B) : β endpoint ∼ 15MeV

• The 3

He+3

He ↔ 3

He+4

He branching:The Coulomb effects for these two reactions are rather similar, except for small effects pro-portional to the different masses. The heavier nucleus moves more slowly, and thus is at adisadvantage in overcoming Coulomb barriers. The S-factor for the 3+3 reaction is largerthan that for the 3+4 reaction by almost a factor of 104. However we have also seen that

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The normalizing density is typical of the center of the sun. If one uses a temperature of T 7 = 1.5, the above ratio is 0.4, which says that the electron density in hot solar core at the7Be nucleus is about 40% that in a cold terrestrial nucleus. As

ωterrestrial = ln 2

53.29 d ∼ 1.50 · 10−7/sec

⇒ ωsolar = N e

3.5 · 1025/cm3

0.72 · 10−7/sec

T 1/27

Again plugging in numbers, the above rate evaluated in the solar center corresponds to a7Be half life of 137 days, so a bit longer than the terrestrial half life.

Now the 7Be + p reaction comes right from our standard formula, which we write in termsof the rate per 7Be nucleus

ω17 = N p(7.21·

10−19cm3/sec) 1

AZ 1Z 2

S 17(E o)

kev − b(Z 2

1

Z 2

2

A)2/319.73

T 1/37

2

e−(Z 21Z 22A)1/319.73/T 1/37

= N p

3 · 1025/cm31.4 · 1010/sec e−47.6/T

1/37 T

−2/37 S 17(E o)

This S-factor has been the most controversial in the pp chain as the two best low-energymeasurements disagreed by about 25%, an amount much larger than the claimed experimen-tal uncertainties. But new measurements, especially one made at CENPA here at the UW,have yielded a more accurate value

S 17 ∼ .0207 ± .0009 keV − b

is now favored. Plugging in

ω17 = N p

3 · 1025/cm32.9 · 108/sec e−47.6/T

1/37 T

−2/37

Thusωe(7Be)

ω p(7Be) =

N e

3.5 · 1025/cm3/

N p3.0 · 1025/cm3

0.27 · 10−15T

1/67 e47.6/T

1/37

=

7900 T 7 = 1.2

330 T 7 = 1.5

Consistent with these number, when one averages over the solar core, one finds that 0.1% of

the 7Be burns by p + 7Be, while the remainder is destroyed by electron capture.

Note also, however, that this branching ratio is quite sensitive to temperature. Figure 9shows that the ppIII cycle can, indeed, becomes rapidly more important with increasing T,eventually dominating the pp cycle. Similarly, the temperature dependence determines thespatial region over which the various cycles are important in our sun.

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ppI cycle strongest at low T ⇔ burning occurs throughout the coreppII cycle increases with T ⇔ more important in central core

ppIII cycle increases fastest with T ⇔ most important in very center

Finally, a byproduct of these reactions are the solar neutrinos. By incorporating the nuclear

physics described above into the solar model, the following fluxes at earth are found (fromBahcall and Pinnsoneault 1995), in units of cm−2s−1

E maxν (MeV) Flux

p + p → d + e+ + ν e 0.42 6.00E 108B → 8Be + e+ + ν e ∼ 15 5.69E 67Be + e− → 7Li + ν e 0.86(90%) 4.89E 9

0.38(10%) p + e− + p → d + ν e 1.44 1.43E 8

4.6 CNO Cycles

Stars formed from the ashes of previous generations of stars will contain elements not pro-duced in the big bang. As we have seen that charged particle reactions are suppressed byCoulomb barriers, the most interesting of these for helping to burn hydrogen at low temper-atures are the lightest candidates. Carbon, nitrogen, and oxygen are the abundant, low Z,nonprimordial elements that one would first consider. These elements are produced by nu-clear burning cycles in heavier stars and can be ejected into the interstellar medium throughsupernova explosions, stellar winds, etc.

In stars somewhat heavier than our sun, higher temperatures and densities are produced inthe core when the star first achieves radiative equilibrium. If metals are present, hydrogenburning can be achieved more efficiently through the pp cycle by a faster process involving

proton capture on heavier elements. The cycle that dominates at the lowest temperatures is

12C + p → 13N + γ

13N → 13C + e+ + ν e (τ ∼ 870 s)

13C + p → 14N + γ

14N + p → 15O + γ

15O → 15N + e+ + ν e (τ ∼ 178 s)

15N + p

→12C + 4He

The important features of this cycle are• It burns 4p → 4He, just as the pp cycle does. The heavy nuclei are neither produced norconsumed. They are analogous to deuterium and 3He in our pp discussion. But this CNcycle requires some initial concentration of the heavy elements to turn on. In this regardthese metals are not like the pp cycle’s d, 3He.

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• The cycle will clearly burn to equilibrium in the metals, which can affect the relative por-tions of the metals. But this is only a redistribution: no new heavy elements are created.• The two β decay reactions are relatively fast. Thus when a temperature is reached wherethe proton capture reactions proceed readily, the cycle can be quite fast.

In our sun the total abundance by mass of elements with A greater than 5 is 0.02. With thissignificant metallicity, the CN cycle accounts for a nonneglible amount of the 4He synthesis,somewhat less than 2%. Under similar conditions but with the temperature elevated toT 7 ∼ 1.8, the CNO cycle would begin to overtake the pp chain in importance.

The fact that the CN cycle is taking over at T 7 ∼ 2.0 means, in our sun, that one will notreach conditions where the ppIII cycle is primarily responsible for hydrogen burning.

The “cold” CN cycle reaction that is slowest is the 14N( p, γ )15O reaction. The comparativelifetimes for the various reactions are

12C( p, γ )13N 6.1 × 109y13C( p, γ )14N 1.1 × 109y14N( p, γ )15N 2.1 × 1012y15N( p, α)12C 1.0 × 108y

using the conditions T 7 = 1, ρ = 100 g/cm3, and a hydrogen mass fraction of 0.5. Note (atthis temperature!) that all of these lifetimes are much longer than the two weak lifetimesthat play a role in the CN cycle. If the CN cycle is running in equilibrium, the productionrate of each isotope must equal its destruction rate. It follows that the resulting equilibriumabundance of each isotope is inversely proportional to the rates above. For similar conditionsbut with a higher temperature (T 7 = 5), the relative abundances are

12C 0.05513C 0.00914N 0.93615N 0.00004

The large abundance of 14N reflects its long lifetime.

The temperature dependence of energy production through the pp cycle is, at solar temper-ature, ∼ T 4. Since the 14N( p, γ ) is the controlling reaction for the CN cycle, we can pluginto our rate formula to find out the temperature dependence of energy production through

the CN cycle. The result is ∼ T 17, much steeper. A graph of the competition between thepp and CNO cycles is shown in the figure.

The discussion above assumes that 15N burns by the ( p, α) reaction, but there is a compet-ing possibility of 15N( p, γ )16O that leads to the CNO bi-cycle shown in the figure. Now the( p, α) reaction releases almost 5 MeV, which is nearly the height of the Coulomb barrier for

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the outgoing channel. Thus the reaction is relatively insensitive to the outgoing Coulombeffects, and therefore ratio of these two reactions depends only on the S-factors (roughly).(The initial state penetration factor is common to both reactions.) This ratio for the ( p, α)to ( p, γ ) reactions is 65 MeV-b to 64 keV-b, or about 1000. Thus the second cycle contributesonly about 0.1% to the total rate of energy production.

There are further cycles, as indicated in the figure, involving reactions not all of which aredefinitely measured to the accuracy desired. There is a lot of activity in nuclear laboratoriestrying to improve the measurements.

The charge particle reactions of the CNO cycles increase in speed rapidly in temperature. If we use the estimate of T 17 (see homework) and recall that the lifetime of 14N at T 7 = 1 is2.1 × 1012y, we would conclude that it would live for about 660 s at T 7 = 10. Thus at suchvery high temperatures, the cycle time matches or exceeds the β decay lifetimes of 13N and15O. Then it must be that the abundances of these isotopes become very significant. Withall the proton capture reactions becoming fast at such temperatures, new cycles then openup, involving reactions like 13N(p,γ )14O. The CNO cycle operating above T 7 = 10 is calledthe hot CNO cycle. We will not continue the discussion any further, except to note that attemperature in excess of T 7 ∼ 50, the rapid capture of protons may direct the nuclear flowoutside of the hot CNO cycle, into heavier nuclei. The correct description of this physicsrequires simulations with large nuclear networks, and depends on some nuclear physics thatis rather poorly known. This is also an interesting interface with stellar structure, as expertsstudying novae and other explosive environments have to specify what temperatures mightbe reached in order to access the probability of these rapid proton capture reactions.

4.7 Red giants and helium burning

We now consider the evolution off the main sequence of a solar-like star, with a mass abovehalf a solar mass. As the hydrogen burning in the core progresses to the point that no morehydrogen is available, the stellar core consists of the ashes from this burning, 4He. The starthen goes through an interesting evolution:• With no further means of producing energy, the core slowly contracts, thereby increasingin temperature as gravity does work on the core.• Matter outside the core is still hydrogen rich, and can generate energy through hydrogenburning. Thus burning in this shell of material supports the outside layers of the star. Noteas the core contracts, this matter outside the core also is pulled deeper into the gravitationalpotential. Furthermore, the shell H burning continually adds more mass to the core. Thismeans the burning in the shell must intensify to generate the additional gas pressure to fight

gravity. The shell also thickens as this happens, since more hydrogen is above the burningtemperature.• The resulting increasing gas pressure causes the outer envelope of the star to expand bya larger factor, up to a factor of 50. The increase in radius more than compensates for theincreased internal energy generation, so that a cooler surface results. Thus the star reddens.

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Figure 11: The CNO reaction cycle.

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Figure 12: Another depiction of the CNO and hot CNO cycles.

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Thus this class of star is named a red supergiant.• This evolution is relatively rapid, perhaps a few hundred million years: the dense corerequires large energy production and thus rapid evolution. The helium core is supportedby its degeneracy pressure, and is characterized by densities ∼ 106 g/cm3. This stage endswhen the core reaches densities and temperatures that allow helium burning through the

reactionα + α + α → 12C + γ

This reaction is very temperature dependent

∝ ρ3αT 30

Thus the conditions for ignition are very sharply defined. That is, the core mass at thishelium flash point is very well defined.• The onset of helium burning produces a new source of support for the core. The energyrelease elevates the temperature and the core expands: He burning, not electron degeneracy,now supports the core. The burning shell and envelope have moved outward, higher in thegravitational potential. Thus shell hydrogen burning slows (the shell cools) because lessgas pressure is needed to satisfy hydrostatic equilibrium. All of this means the evolutionof the star has now slowed: the red giant moves along the “horizontal branch”, as interiortemperatures slowly elevate much as in the main sequence.

The 3α process depends on some rather interesting nuclear physics. The first interesting“accident” involves the near degeneracy of the 8Be ground state and two separated αs: The8Be 0+ ground state is just 92 keV above the 2α threshold. The measured width of the 8Beground state is 2.5 eV, which corresponds to a lifetime of

τ m ∼ 2.6 · 10−16

sec

One can compare this number to the typical time for one α to pass another. The red giantcore temperature is T 7 ∼ 10 → E ∼ 8.6 keV. Thus v/c ∼ 0.002. So the transit time is

τ ∼ d

v ∼ 5f

0.002

1

3 · 1010cm/sec

10−13cm

f ∼ 8 · 10−21sec

This is more than five orders of magnitude shorter than τ m above. Thus when a 8Be nucleusis produced, it lives for a substantial time compared to this naive estimate.

This can be calculated from our resonant cross section formula.

σv = ( 2π

µkT )3/2 ΓΓ

Γ e−E r/kT

where Γ is the 2α width of the 8Be ground state. This is the flux-averaged cross section forthe α + α reaction to form the compound nucleus then decay by α + α. But since there is

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only one channel, this is clearly also the result for producing the compound nucleus 8Be.

By multiplying the rate/volume for producing 8Be by the lifetime of 8Be, one gets the numberof 8Be nuclei per unit volume

N (Be) = N αN α1 + δ αασvτ m

= N αN α1 + δ αα

σv 1

Γ

= N 2α

2 (

µkT )3/2e−E r/kT

Notice that the concentration is independent of Γ. So a small Γ is not the reason we obtain asubstantial buildup of 8Be. This is easily seen: if the width is small, then the production rateof 8Be goes down, but the lifetime of the nucleus once it is produced is longer. The two effectscancel to give the same 8Be concentration. One sees that the significant 8Be concentrationresults from two efects: 1) α + α is the only open channel and 2) the resonance energy islow enough that some small fraction of the α + α reactions have the requisite energy. AsE r = 92 keV, E r/kT = 10.67/T 8

N (Be) = N 2αT −3/28 e−10.67/T 8(0.94 · 10−33cm3)

So plugging in typical values of N α ∼ 1.5 · 1028/cm3 (corresponding to ρα ∼ 105 g/cm3) andT 8 ∼ 1 yields

N (8Be)

N (α) ∼ 3.2 × 10−10

Salpeter suggested that this concentration would then allow α+8

Be→12

C to take place. Hoylethen argued that this reaction would not be fast enough to produce significant burning unlessit was also resonant. Now the mass of 8Be + α is 7.366 MeV, and each nucleus has J π = 0+.Thus s-wave capture would require a 0+ resonance in 12C at ∼ 7.4 MeV. No such state wasthen known, but a search by Cook, Fowler, Lauritsen, and Lauritsen revealed a 0 + levelat 7.644 MeV, with decay channels 8Be+α and γ decay to the 2+ 4.433 level in 12C. Theparameters are

Γα ∼ 8.9eV

Γγ ∼ 3.6 · 10−3eV

Our resonant cross section formula gives

r48 = N 8N α( 2π

µkT )3/2 ΓαΓγ

Γ e−E r/kT

Plugging in our previous expression for N (8Be) yields

r48 = N 3αT −38 e−42.9/T 8(6.3 · 10−54cm6/sec)

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If we denote by ω3α the decay rate of an α in our plasma, then

ω3α = 3N 2αT −38 e−42.9/T 8(6.3 · 10−54cm6/sec)

= ( N α

1.5·

1028/cm3)2(4.3 · 103/sec)T −3

8 e−42.9/T 8

Now the energy release per reaction is 7.27 MeV. Thus we can calculate the energy producedper gram, :

= ω3α7.27MeV

3

1.5 · 1023

g

= (2.5 · 1021erg/g sec)( N α

1.5 · 1028/cm3)2T −3

8 e−42.9/T 8

We can evaluate this at a temperature of T 8 ∼ 1 to find

∼ (584ergs/g sec)( N α

1.5·

1028/cm3)2

Typical values found in stellar calculations are in good agreement with this:

red giant energy production ⇔ 100 ergs/g sec

To get a feel for the temperature sensitivity of this process, we can do a Taylor seriesexpansion

(T ) ∼ T −3e−42.9/T ∼ T −3o e−42.9/T o + (−3T −4

o e−42.9/T o + T −3o e−42.9/T o(

42.9

T 2o))(T − T o) + ...

= T −3

o e−42.9/T o(1 +

(T − T o)

T o

42.9 − 3T o

T o)

∼ T −3o e−42.9/T o(1 +

T − T oT o

)(42.9−3T o)/T o

∼ (T o)( T

T o)(42.9−3T o)/T o

That is

(T ) ∼ ( T

T o)40N 2α

This steep temperature dependence is the reason the He flash is delicately dependent onconditions in the core.

3.11 Red giant burning and the neutrino magnetic momentPrior to the helium flash, the degenerate He core radiates energy largely by neutrino pairemission. The process is the decay of a plasmon - which one can think of as a photon”dressed” by electron-hole excitations, thereby acquiring an effective mass of about 10 keV.The photon couples to a neutrino pair through a electron particle-hole pair that then decays

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into a Z o → ν ν .

If this cooling is somehow enhanced, the degenerate helium core would be kept cooler, andwould not ignite at the normal time. Instead it would continue to grow until it overcamethe enhanced cooling to reach, once again, the ignition temperature.

One possible mechanism for enhanced cooling is a neutrino magnetic moment. Then theplasmon could directly couple to a neutrino pair. The strength of this coupling would de-pend on the size of the magnetic moment.

A delay in the time of He ignition has several observable consequences, including changingthe ratio of red giant to horizontal branch stars. Thus, using the standard theory of redgiant evolution, investigators have attempted to determine what size of magnetic momentwould produce unacceptable changes in the astronomy. The result is a limit on the neutrinomagnetic moment of

µij

∼< 3

·10−12electron Bohr magnetons

This limit is more than two orders of magnitude more stringent than that from direct labo-ratory tests.

3.12 Carbon burningThe most abundant elements are H, He, C, and O, with the C/O ratio ∼ 0.6. We have seenthat the 3α process producing 12C proceeds because of two fortuitous features of the nuclearphysics: 1) there is a very small difference between the mass of two αs and 8Be (recall theabundance of 8Be depends on this mass difference); 2) there is a 0+ resonance in 12C thatallows resonant capture of an α on 8Be.

After 12C is produced, one could imagine that additional α capture might be easier: there isa series of stable even Z-even N nuclei: 12C, 16O, 20Ne, ... But there is an important question:is there a resonance in 16O that might allow the synthesis to continue?

The structure of 16O is shown in the figure. The mass of 12C+α is 7.162 MeV. If we calculatethe most effective energy E o for this reaction at a temperature T 8 ∼ 2, we obtain 300 keV.But there is no state in 16O at 7.462 MeV: the nearest candidates are below threshold, a 1−

state at 7.12 MeV and a 2+ state at 6.92 MeV. These states would allow 12C+α to proceedby p-wave (E1) and d-wave (E2) capture.

This situation is very complicated, with interfering subthreshold resonances. Through a va-riety of measurements the S-factor as been estimated at 0.3 MeV-b. By our usual techniquesone can calculate the reaction rate for a 12C nucleus

ω12C = ( N α

7.5 · 1026/cm3)2.2 · 1013/sec e−69.3/T

1/38 T

−2/38

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Figure 14: The HR diagram for red giant/horizontal branch star evolution. Various aspectsof the red giant to horizontal branch evolutionary track provide constraints on anomalouscooling processes in red giants, such as enhanced neutrino production because of neutrinomagnetic moments.

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Note that N α = 7.5 · 1026/cm3 corresponds to a red giant density of 104 g/cm3 and an αfraction of 0.5. Evaluating this yields

ω12C = ( N α

7.5 · 1026/cm3)

1.76 · 10−17/sec T 8 = 11.79 · 10−11/sec T 8 = 2

These numbers correspond to 12C lifetimes of 1.8 · 109 y and 1.8 · 103 y, respectively.

The net result is that the helium burning in a typical red giant is accompanied by relativelyeffective conversion of carbon to oxygen: the end ratio is about C/O ∼ 0.1. (This numbercan vary a lot depending on the red giant mass: see Clayton. Note that Clayton’s treatmentis a little different from ours numerically.) Significant subsequent conversion of 16O to 20Nedoes not occur because the 2− resonance in Ne that is in the vicinity of the most effectiveenergy has the wrong parity: since the α and 16O have positive parity, L=2 capture pro-duces a 2+ state, not a 2−. Thus the essential elements for life, carbon and oxygen, are theprinciple products of red giant burning.