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8/4/2019 chapter 5 energy and chemical changes form 4
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ENERGY AND CHEMICAL
CHANGES
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OBJECTIVES
Understand physical & chemical changes
Analyse heat changes in chemical reaction
Synthesize the reactivity series of metals and apply itsconcepts
Understand electrolysis
Understand the production of electrical energy by asimple cell
Understand chemical reactions that occur in the
presence of lightAppreciate the innovative efforts in the design ofequipments using chemical reactions as sources ofenergy.
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PHYSICAL & CHEMICAL CHANGES
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PHYSICAL CHANGES
DEFINITION
A CHANGE THAT ALTERS
THE FORM OF A MATERIALBUT DOES NOT CONVERT
THE MATERIAL INTO NEWSUBSTANCE
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CIRI-CIRI / PROPERTIES
Chemical composition of materials produced
remains the same.
Colour remains the same
Its shape can be change again to its original
form.
Involves little/no change in energy
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Example of physical changes
Melting of ice
heat
Ice
waterice only change its state from solid to liquid.
It can be change to its original form by
freezing
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Evaporation of water
heatwater water vapour
The water has change from liquid to gasIt can be change again to liquid by
condensation
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Dissolving a substance
dissolvesSugar + water sugar solution
No new substance is formed
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Crystallisation
Hot saturated NaCl solution cool down and
produced NaCl crystals.
No new substance is formed.
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Sublimation
Iodine crystals + heat sublimed iodineIodine has changed from crystals to powder
Freezing
cold
Water ice
Water change from liquid to solid
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CHEMICAL CHANGES
DEFINITION
A CHANGE IN MATTER
THAT PRODUCES ONE
OR MORE NEWSUBSTANCE
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CIRI-CIRI/ PROPERTIES
Chemical properties & composition of new
substance different from original
Reactants (bhn t/bls) changes in colour
Involves absorption or release of heat
Light energy also produced
New substances formed usually cannot bechanged back to original material physically
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Examples of chemical changes
Burning magnesium in air
burn
2Mg + O2
2MgO ( magnesium oxide)New substance is form
Has different chemical properties
Energy is released
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Heating a mixture of iron and sulphur
heat
Iron + sulphur iron sulphide
New substance is formedHas different chemical properties
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Mixing copper chloride solution and
sodium hydroxide solution
CuCl + NaOH COH +
NaCl
Two new substances are
formed
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Physical & Chemical changes in daily
lifePhysical changes Chemical changes
Crushing onions Lighting a match stick
Boiling water Frying fish
Freezing water into ice Rusting iron gate
Dissolving salt in water Digestion of food in our body
Drying clothes Mixing slaked lime in acidic soil
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Comparison between physical &
chemical changesPhysical Changes Similarities Chemical changes
Both experience physical changes eg : appearance
Differences
No Formation of new
substance
yes
Same Properties & composition
of reactants (bhn t/bls) and
product( hasil t/bls)
Different
Normally yes Reversible change (
perubahan berbalik)
Normally, no
Require a little energy Energy requirement Usually require a lot energy
same Mass(jisim) reactant and
products
different
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5.2 HEAT CHANGE IN CHEMICAL
REACTIONS
Occurs in most of Chemical Reaction
Involves energy transformation ( perubahantenaga)
CM can classified into two:
Exothermic & Endothermic reactions.
Heat energy absorbed from
surroundings
Heat energy released to
surroundings
To break the bond in a
compound
When the bond is formed
( to form new chemical bonds)
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Exothermic reaction properties Endothermic reaction
Heat energy is released to
the surroundings
Definition Heat energy is absorbed
from the surroundings
Lose heat to surroundings Reactant ( bhn t/bls) Gain heat from
surroundings
Energy level diagram
Surrounding Temperature
raised ( increase)
Surrounding temperature
( suhu sekeliling)
Surrounding temperature
is lowered
Become hot
-container feels hot when
touch
Content in container Become cool
-Container cool when
touch
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Examples of Exothermic Reaction
The burning of candle
- Candles burn heat & light are released
Reaction between magnesium & dilutesulphuric acid
- Produces a lot of heat
- Mg + H2SO4MgSO4 + H2
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Examples of Endothermic reaction
Boiling water
-heat absorbed when water is boiled
Water + heat
steamMelting wax
-Wax (solid) + heat liquid wax
Dissolving Ammonium chloride in water- NH4Cl(s) + H2O(l) NH4Cl (l)
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Heat Changes in Chemical Reactions In
Industries
Production of ammonia by the
Haber Process
Production of Sulphoric Acid
by the Contact process
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The Reactivities Series Of Metals All metals react in water but the reactivity is
different. Some metals reacts vigorously than others
Reactivity of metals with water :
vigorously
Reactive metals + watermetal hydroxide + Hydrogen
Eg: Sodium + water sodium hydroxide + hydrogen
Less vigorously
Metal + steammetal oxide + hydrogenEg: Magnesium + steammagnesium oxide +
hydrogen
Metals like lead, copper, silver &gold dont react in water.
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Reactivity of metals with acid
Reactive metals reacts with dilute acid to
produced hydrogen (g) and salt (s).
This reaction produces heat
Reactive metals reacts more vigorously.
Hydrogen collected burns with POP sound.
Salts obtained depends on metals used Eg: Mg + H2SO4MgSO4 + H2
Zn + H2SO4 ZnSO4 + H2
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Reactivity of metals in Oxygen
Metals reacts with oxygen to produced metaloxide
Metal + OxygenMetal oxide
Eg :
Mg + O2MgO
Zn + O2 ZnO
Inactive metals dont react with oxygen.
Eg : gold & platinum
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Reactivities series of metals.
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steps
5cm3 of dilute hydrochloric acid was poured
into a test tube
A magnesium powder was added to the dilute
acid
The gas released was collected as shown in
the diagram
The gas collected was tested with a burning
wooden splinter
The above steps were repeated with the other
metals.
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Volume and concentration of acid
Type of metals
Reactivity of metals
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ELECTROPLATING
The electroplating process provides a
protective coating to different types of metal.
The most common use in firearms
manufacturing is chrome or nickel plating,which provide a bright finish to the metal.
Electroplating can be used on various types of
metals; the result is a thin metal coating onthe exterior of the original metal part.