chapter 5 energy and chemical changes form 4

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    ENERGY AND CHEMICAL

    CHANGES

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    OBJECTIVES

    Understand physical & chemical changes

    Analyse heat changes in chemical reaction

    Synthesize the reactivity series of metals and apply itsconcepts

    Understand electrolysis

    Understand the production of electrical energy by asimple cell

    Understand chemical reactions that occur in the

    presence of lightAppreciate the innovative efforts in the design ofequipments using chemical reactions as sources ofenergy.

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    PHYSICAL & CHEMICAL CHANGES

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    PHYSICAL CHANGES

    DEFINITION

    A CHANGE THAT ALTERS

    THE FORM OF A MATERIALBUT DOES NOT CONVERT

    THE MATERIAL INTO NEWSUBSTANCE

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    CIRI-CIRI / PROPERTIES

    Chemical composition of materials produced

    remains the same.

    Colour remains the same

    Its shape can be change again to its original

    form.

    Involves little/no change in energy

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    Example of physical changes

    Melting of ice

    heat

    Ice

    waterice only change its state from solid to liquid.

    It can be change to its original form by

    freezing

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    Evaporation of water

    heatwater water vapour

    The water has change from liquid to gasIt can be change again to liquid by

    condensation

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    Dissolving a substance

    dissolvesSugar + water sugar solution

    No new substance is formed

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    Crystallisation

    Hot saturated NaCl solution cool down and

    produced NaCl crystals.

    No new substance is formed.

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    Sublimation

    Iodine crystals + heat sublimed iodineIodine has changed from crystals to powder

    Freezing

    cold

    Water ice

    Water change from liquid to solid

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    CHEMICAL CHANGES

    DEFINITION

    A CHANGE IN MATTER

    THAT PRODUCES ONE

    OR MORE NEWSUBSTANCE

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    CIRI-CIRI/ PROPERTIES

    Chemical properties & composition of new

    substance different from original

    Reactants (bhn t/bls) changes in colour

    Involves absorption or release of heat

    Light energy also produced

    New substances formed usually cannot bechanged back to original material physically

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    Examples of chemical changes

    Burning magnesium in air

    burn

    2Mg + O2

    2MgO ( magnesium oxide)New substance is form

    Has different chemical properties

    Energy is released

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    Heating a mixture of iron and sulphur

    heat

    Iron + sulphur iron sulphide

    New substance is formedHas different chemical properties

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    Mixing copper chloride solution and

    sodium hydroxide solution

    CuCl + NaOH COH +

    NaCl

    Two new substances are

    formed

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    Physical & Chemical changes in daily

    lifePhysical changes Chemical changes

    Crushing onions Lighting a match stick

    Boiling water Frying fish

    Freezing water into ice Rusting iron gate

    Dissolving salt in water Digestion of food in our body

    Drying clothes Mixing slaked lime in acidic soil

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    Comparison between physical &

    chemical changesPhysical Changes Similarities Chemical changes

    Both experience physical changes eg : appearance

    Differences

    No Formation of new

    substance

    yes

    Same Properties & composition

    of reactants (bhn t/bls) and

    product( hasil t/bls)

    Different

    Normally yes Reversible change (

    perubahan berbalik)

    Normally, no

    Require a little energy Energy requirement Usually require a lot energy

    same Mass(jisim) reactant and

    products

    different

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    5.2 HEAT CHANGE IN CHEMICAL

    REACTIONS

    Occurs in most of Chemical Reaction

    Involves energy transformation ( perubahantenaga)

    CM can classified into two:

    Exothermic & Endothermic reactions.

    Heat energy absorbed from

    surroundings

    Heat energy released to

    surroundings

    To break the bond in a

    compound

    When the bond is formed

    ( to form new chemical bonds)

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    Exothermic reaction properties Endothermic reaction

    Heat energy is released to

    the surroundings

    Definition Heat energy is absorbed

    from the surroundings

    Lose heat to surroundings Reactant ( bhn t/bls) Gain heat from

    surroundings

    Energy level diagram

    Surrounding Temperature

    raised ( increase)

    Surrounding temperature

    ( suhu sekeliling)

    Surrounding temperature

    is lowered

    Become hot

    -container feels hot when

    touch

    Content in container Become cool

    -Container cool when

    touch

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    Examples of Exothermic Reaction

    The burning of candle

    - Candles burn heat & light are released

    Reaction between magnesium & dilutesulphuric acid

    - Produces a lot of heat

    - Mg + H2SO4MgSO4 + H2

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    Examples of Endothermic reaction

    Boiling water

    -heat absorbed when water is boiled

    Water + heat

    steamMelting wax

    -Wax (solid) + heat liquid wax

    Dissolving Ammonium chloride in water- NH4Cl(s) + H2O(l) NH4Cl (l)

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    Heat Changes in Chemical Reactions In

    Industries

    Production of ammonia by the

    Haber Process

    Production of Sulphoric Acid

    by the Contact process

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    The Reactivities Series Of Metals All metals react in water but the reactivity is

    different. Some metals reacts vigorously than others

    Reactivity of metals with water :

    vigorously

    Reactive metals + watermetal hydroxide + Hydrogen

    Eg: Sodium + water sodium hydroxide + hydrogen

    Less vigorously

    Metal + steammetal oxide + hydrogenEg: Magnesium + steammagnesium oxide +

    hydrogen

    Metals like lead, copper, silver &gold dont react in water.

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    Reactivity of metals with acid

    Reactive metals reacts with dilute acid to

    produced hydrogen (g) and salt (s).

    This reaction produces heat

    Reactive metals reacts more vigorously.

    Hydrogen collected burns with POP sound.

    Salts obtained depends on metals used Eg: Mg + H2SO4MgSO4 + H2

    Zn + H2SO4 ZnSO4 + H2

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    Reactivity of metals in Oxygen

    Metals reacts with oxygen to produced metaloxide

    Metal + OxygenMetal oxide

    Eg :

    Mg + O2MgO

    Zn + O2 ZnO

    Inactive metals dont react with oxygen.

    Eg : gold & platinum

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    Reactivities series of metals.

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    steps

    5cm3 of dilute hydrochloric acid was poured

    into a test tube

    A magnesium powder was added to the dilute

    acid

    The gas released was collected as shown in

    the diagram

    The gas collected was tested with a burning

    wooden splinter

    The above steps were repeated with the other

    metals.

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    Volume and concentration of acid

    Type of metals

    Reactivity of metals

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    ELECTROPLATING

    The electroplating process provides a

    protective coating to different types of metal.

    The most common use in firearms

    manufacturing is chrome or nickel plating,which provide a bright finish to the metal.

    Electroplating can be used on various types of

    metals; the result is a thin metal coating onthe exterior of the original metal part.