Upload
sonohappy
View
222
Download
0
Embed Size (px)
Citation preview
8/2/2019 Chap 6 About Emission
1/33
59
Facts about emissions from motor vehicles
(based on H.Heywood Internal combustion engine fundamentals
and DieselNet website)
6.1 Complete combustion of hydrocarbon fuels
The vast majority of road transport in the world is powered by either gasoline (petrol) or
diesel fuel. Both of these fuels are derived from crude oil by using several refining processes
including distillation, reforming, cracking, polymerization and blending of different
compounds coming from different refining streams etc.
Regarding the chemical structure of gasoline and diesel fuel, both of them have two
elements in common: they both consist of carbon (C) and hydrogen (H), and are thus called
hydrocarbon (HC) fuels.
In addition to carbon and hydrogen, some of the so-called reformulated gasolines also
contain small amounts (typically about 2 mass-%) of oxygen (O2). The chemical composition of
reformulated gasolines has been especially selected to cause as low an impact as possible on
the environment. Fuels containing oxygen are also sometimes referred to as oxygenated
fuels. Oxygen in the fuel makes the combustion take place more effectively, especially under
certain conditions. From a theoretical point of view, it is not of great importance for the
reactions taking place, whether part of the oxygen needed for combustion originates in the
fuel or in the ambient air.
When the carbon (C) fraction of hydrocarbon fuel is combusted, the end product is carbon
dioxide (CO2). When the hydrogen (H) fraction of the fuel is combusted, the end product is
water (H2O). The following equations show the reactions:
C + O2
CO22H2 + O2 2H2O
The end products of the complete combustion of hydrocarbon fuels (CO2 and H2O) were for
a long time considered as totally harmless, since they are not toxic. However, recent findings
have revealed that carbon dioxide is the main contributor to the increase in the greenhouse
effect, causing global warming and climate change. Controlling CO 2 emissions and climate
change will probably be one of the greatest challenges ever faced by mankind.
6
8/2/2019 Chap 6 About Emission
2/33
Internal combustion engines
60
6.2 Real-world combustion products
In real conditions; that is, in the combustion chambers of engines, the process of combustion
is usually incomplete. This leads to the formation of unwanted components, in addition to
carbon dioxide and water, which affect air quality and cause harm both to human health and
to the environment.
The most important of these unwanted emission components (also called air quality
emissions), are carbon monoxide (CO), hydrocarbons (HC), oxides of nitrogen (NOx) and
particulate matter (PM). Of these four, particulates are solid, whereas the others are
gaseous.
These four compounds are referred to as the regulated emissions, since the emission
legislation sets limit values to these components. Under current European emission
legislation, CO, HC and NOx are regulated for gasoline powered vehicles, while all four are
regulated for diesel vehicles and engines.
In addition to the regulated components, the research literature on emissions also
recognizes the term unregulated emissions. This refers to emission components which cause
concern but are not regulated by the legislation. This group includes, for example, benzene,
1,3-butadiene, aldehydes and ultra-fine particulates.
Fig. 6.1. Division of different emission compounds
As mentioned above, CO2 has to be considered as a harmful emission component because of
its properties related to the greenhouse effect and global warming. Other emission
components contributing to this problem are, for example, methane (CH 4), the so-called CFC
Unregulatedemissions
- Carbon dioxide (CO2)
- Methane (CH4)
- CFC compounds
- Nitrous oxide (N2O)
Compounds not generallyregulated by legislation, butwhose detrimental properties areof interest among scientists.(E.g. benzene, 1,3-butadiene,aldehydes, fine particulates)
Tailpipe emission compounsregulated by legislation(CO, HC, NOX and PM).Also referred to as air qualityemissions (to differentiatefrom CO2)
Regulatedemissions
Greenhouse gasemissions
Mostly
local or
regional
problem
Global
problem
8/2/2019 Chap 6 About Emission
3/33
Chapter 6. Facts about emissions from motor vehicles
61
compounds (containing chlorine, fluoride and carbon) and nitrous oxide (N2O), whose popular
name is laughing gas). These compounds, as a group, are referred to as greenhouse gases
(GHG). Unlike regulated or unregulated emissions, which mostly affect the vicinity of the
emission source only (locally or regionally), the GHG emissions affect the whole atmosphere
regardless of the location of the emission source. The division between the three different
groups of emission compounds as described above is illustrated in Figure 6.1.
In the following four sections, each of the regulated emission components will be
discussed separately.
6.2.1 Carbon monoxide
Carbon monoxide (CO) is the product of incomplete combustion. It consists of a carbon atom
and an oxygen atom linked together. Usually it is formed due to lack of oxygen at least in
some parts of the combustion chamber. If the air-fuel mixture control system is not
functioning properly in the engine, there can be lack of oxygen throughout the combustion
chamber. If there is not enough oxygen available, the combustion takes place only partially,
and carbon from the fuel turns into carbon monoxide (CO) instead of carbon dioxide (CO 2) as
in the case of complete combustion.
In the case of gasoline engines (utilizing the so-called Otto-cycle), the air-fuel ratio is
controlled very strictly and is maintained constantly at the theoretically correct mixture in
almost all driving situations. The only exception occurs when a cold engine is started and
operated. Under these conditions it is usually necessary to enrich the mixture in order to
ensure the start-up and smooth operation of the engine before it is warmed up.
Under these conditions carbon monoxide emissions are high. They can be reduced,
however, after a cold start, providing the two following requirements are met: the
enrichment of the air-fuel ratio in the engine is turned off, and the temperatures of the
catalytic converter and the lambda sensor are high enough.
Engine and vehicle manufacturers are pursuing enrichment strategies which enrich the
mixture by as small an amount as possible. And they are trying to make the enrichment
period as short as possible. In addition, the catalytic exhaust after treatment device
manufacturers are working in order to find catalyst chemistry that will have as low a light-offtemperature as possible, meaning that the conversion (oxidation) of CO and hydrocarbons in
the catalyst would start as early as possible after a cold start. Typically, the light-off
temperature is in the range of 150 to 250 C. Ageing of the catalyst may increase this
temperature close to 300 C.
Figure 6.2 presents CO concentration measurement results for a European subcompact
gasoline-powered car (2003 model) with a 1.6 liter gasoline engine. Test temperature was -7
C. The drive cycle used in this test was the current European official emission test drive
cycle, also known as the New European Drive Cycle (NEDC) or "EC2000" cycle, which has been
implemented since the Euro 3 regulations came into effect in 2000.
8/2/2019 Chap 6 About Emission
4/33
Internal combustion engines
62
Essential in this test cycle is that the engine of the test vehicle and the emission sampling
are both started simultaneously. In previous legislation stages (up to the Euro 2 regulations),
the engine was started 40 seconds before the emission measurement began, allowing most of
the emissions to dissipate in the atmosphere without detection.
In Figure 6.2, cumulative CO emission and CO concentration measured from raw
(undiluted) exhaust are presented as a function of the distance driven.
Fig. 6.2. CO concentration and cumulative CO emission from a subcompact 1.6 liter gasoline car inthe official European test cycle at ambient temperature of -7 C. (VTT)
Figure 6.2 shows that the CO concentration in exhaust has been high, between 4 to 6%,
during the first 250 meters of driving. This is caused by the cold-start enrichment period.
Timewise, this means about 75 seconds from engine start-up. (there is an idle period of 11
seconds at the beginning of the test cycle before actual driving starts). After about 250
meters of driving, the CO concentration has decreased dramatically. This is due to the fact
that the fuel mixture enrichment has been turned off, and the air-fuel ratio has become
stoichiometric (lambda = 1). When a mixture (or a ratio) is stoichiometric, it means that the
engine receives exactly the correct amount of fuel corresponding to the amount of air
available. Under these conditions, there is just enough air for complete combustion.
However, the CO concentration has still been around 0.5% between about 300 meters and
350 meters of driving. This indicates that the mixture has been stoichiometric, but that the
catalytic converter temperature has not been high enough for effective CO conversion.
CO * EC2000 @ -7 C
0.088
0.217
0.279
0
10
20
30
40
50
60
70
0.00 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00
Trip length [km]
Cumulativeemissio
n[g]
0
2
4
6
8
10
12
14
Concentration[%]
Koe # 22470; Mini Cooper 2D-RC31/247
CO-pstkertym50 % kertymst, km90 % kertymst, km95 % kertymst, km
CO-tilavuusosuus
Cumulative CO emission
50 % accumulated
90 % accumulated
95 % accumulated
CO concentraton
CO * EC2000 @ -7 C
0.088
0.217
0.279
0
10
20
30
40
50
60
70
0.00 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00
Trip length [km]
Cumulativeemissio
n[g]
0
2
4
6
8
10
12
14
Concentration[%]
Koe # 22470; Mini Cooper 2D-RC31/247
CO-pstkertym50 % kertymst, km90 % kertymst, km95 % kertymst, km
CO-tilavuusosuus
Cumulative CO emission
50 % accumulated
90 % accumulated
95 % accumulated
CO concentraton
8/2/2019 Chap 6 About Emission
5/33
Chapter 6. Facts about emissions from motor vehicles
63
After about 350 meters of driving (about 90 seconds from engine start), the temperature
in the catalytic converter has apparently reached a sufficiently high level, because at that
stage the CO concentration dropped to almost negligible values.
The concentration trace has risen a few times after reaching the close-to-zero values for
the first time. This is probably due to slight enrichment periods in the engine operation
during the acceleration of the vehicle.
The red curve in Figure 6.2 (cumulative CO emission in grams) and the driving distances in
meters associated with it, show that almost all of the total CO emission is generated during
the first quarter of a kilometer of driving. For example, 95% of the CO from the whole test
distance (4.052 km) has been generated after 279 meters of driving.
Typically, carbon monoxide emissions from diesel engines are relatively low. This is due to
the fact that diesel engines always run on excess air, meaning that the air-fuel ratio, also
known as the lambda value, is all the time much greater than one. This results in fairly
complete combustion of carbon, since there is usually enough air and oxygen available in all
parts of the combustion chamber under most driving conditions.
Carbon monoxide is an insidious poisonous gas that can cause death very easily. It cannot
be smelled, seen or tasted, but it binds itself to the hemoglobin of the blood forming
carboxyhemoglobin, which prevents the blood circulation system from transporting oxygen to
the tissues of the body.
Persons with heart disease are especially sensitive to carbon monoxide poisoning and may
have chest pain if they breathe CO while exercising. Infants, elderly persons and individuals
with respiratory diseases are also particularly sensitive. Carbon monoxide can affect healthy
individuals, impairing their exercise capacity, visual perception, manual dexterity, learning
functions and ability to perform complex tasks. (EPA 1). The content of CO in air and the time
of exposure are the critical factors concerning how serious the consequences might be when a
human being is exposed to carbon monoxide.
Figure 6.3 indicates, for example, that exposure of one hour to breathing air containing
over 600 ppm of CO can cause death.
8/2/2019 Chap 6 About Emission
6/33
Internal combustion engines
64
Fig. 6.3 Effect of CO on human body at different concentrations and exposure times (Bartlett)
Carbon monoxide can usually be detected in ambient air around areas where there is
heavy traffic. CO concentration is typically at its highest during rush hours and/or if the
weather is cold there are several cars around starting cold engines. The area of influence of
CO is usually limited, causing mostly local problems, since carbon monoxide is oxidized to
carbon dioxide in the atmosphere fairly quickly. It has to be emphasized that a vehicle should
never be started in a closed garage, and no exhaust gas should ever be allowed to enter the
interior of a vehicle.
6.2.2 Hydrocarbons (HC)
Hydrocarbons in the exhaust are uncombusted or only partially combusted components of the
fuel. They contain hydrogen and carbon. Hydrocarbon pollution results when unburned or
partially burned fuel is emitted from the engine as exhaust, and also when fuel evaporates
directly into the atmosphere. Hydrocarbons are often also referred to as volatile organic
compounds (VOC).
Hydrocarbon compounds found in the exhaust can be aldehydes (CmHn-CHO), ketones
(CmHn-CO) or different carboxylic acids (CmHn-COOH) (Bosch, 2003). Because the
temperature in the engine is high, the hydrocarbon chains may crack due to the heat, and
they can also reconnect to form new kinds of compounds. These reactions may even continue
in the tailpipe. If the fuel travels through the engine completely unburned, hydrocarbons in
the form of CmHn (as in the fuel) are generated.
Hydrocarbons are typically formed in the engine under conditions similar to those
producing carbon monoxide. If there is a lack of oxygen in the combustion chamber,
hydrocarbon emissions increase. A typical case for this is the cold engine enrichment period.
8/2/2019 Chap 6 About Emission
7/33
Chapter 6. Facts about emissions from motor vehicles
65
Furthermore, the formation of unburned hydrocarbons can result from unvaporized fuel
droplets or from a liquid-state fuel layer on the surfaces of the combustion chamber. The
composition of the fuel has, of course, an effect on the hydrocarbon formation. Small isolated
spots in the combustion chamber, such as around the tip of the spark plug or between the
piston and the cylinder wall (above the first piston ring), may generate hydrocarbon emissions
because of a lack of oxygen locally.
As in the case of CO, the catalytic converter has to reach the light-off temperature in
order to be able to convert (oxidize) hydrocarbons into less harmful compounds. The light-off
temperature for hydrocarbons can be higher than for carbon monoxide, and it usually
increases as the converter gets older.
In principle, evaporative hydrocarbon emissions are always released into the atmosphere
when hydrocarbon fuel is poured from one container into another. In many gasoline stations,
a suction device is used nowadays to collect at least part of the hydrocarbon fumes escaping
from the vehicle fuel tank while it is being refilled.
The properties of the fuel also affect the evaporative hydrocarbon emissions. The vapor
pressure of gasoline should be kept as low as possible to minimize evaporative emissions. This
is the task of the fuel refiner. A drawback of low vapor pressure is that it can result in poor
cold starting properties of the fuel. However, blending gasoline with some oxygen-containing
compound (e.g. ethers like MTBE or ETBE or alternatively with alcohol) may result in equal
cold-start properties as before, even though the vapor pressure of the fuel is lowered.
Gasolines of this kind, the so-called oxygenated gasolines, have been used in some heavily
trafficked areas of the industrialized countries since the early 1990s.
Hydrocarbon emissions are mostly gaseous compounds, but they may also take the form of
tiny particles or droplets. Hydrocarbons include many toxic compounds that cause cancer and
other adverse health effects. Hydrocarbons also react with nitrogen oxide in the presence of
sunlight to form ozone, a serious air pollutant in major cities across the world. Ground-level
ozone, in turn, is the primary constituent of smog (EPA 2).
Hydrocarbons come from a great variety of industrial and natural processes. In typical
urban areas, a significant part of hydrocarbons come from road transportation and also from
non-road mobile sources such as construction vehicles. Traditional 2-stroke engines,
lubricated by oil blended in the fuel, are gross-emitters of hydrocarbons. This is caused bythe fact that the lubrication oil consists of heavy long-chained hydrocarbons which do not
combust well. This results in extremely high hydrocarbon emissions from small 2-stroke
engines that are used for mopeds, snowmobiles, chain saws, garden equipment etc.
6.2.3 Nitrogen oxides (NOx)
Nitrogen oxides are not end-products but side-products of fuel combustion, since the
constituents of nitrogen oxides (nitrogen and oxygen) do not originate from fuel but from
ambient air.
8/2/2019 Chap 6 About Emission
8/33
Internal combustion engines
66
Nitrogen oxides (NOx) is the generic term for a group of highly reactive gases, all of which
contain nitrogen and oxygen in varying amounts. The most significant oxides of nitrogen are
nitrogen oxide (NO) and nitrogen dioxide (NO2). Many of the nitrogen oxides are colorless and
odorless. However, one common pollutant, nitrogen dioxide (NO 2) along with particles in the
air can often be seen as a reddish-brown layer over many urban areas.
Nitrogen oxides form when fuel is burned at high temperatures, as in a combustion
process. The primary man-made sources of NOx are motor vehicles, electric utilities and
other industrial, commercial and residential sources that burn fuels. NOx can also be formed
naturally.
Nitrogen oxides can be controlled in gasoline engines by utilizing the three-way catalyst
which, through the chemical reduction process, converts NOx into nitrogen, carbon dioxide
and water. In diesel engines, which run on an excess amount of air, three-way catalyst
technology cannot be utilized. However, the means of controlling NOx emissions in diesel
engines include retarding injection timing, using exhaust gas recirculation (EGR) and utilizing
new catalytic reduction technology like the SCR (selective catalytic reduction) catalyst, which
uses urea solution as a reductant.
The adverse effects of NOx in the atmosphere include smog formation. Smog is formed
when NOx and volatile organic compounds (VOCs) react in the presence of sunlight. Children,
people with lung diseases such as asthma, and people who work or exercise outside are
susceptible to the adverse effects of NOx such as damage to lung tissue and reduction in lung
function. Ozone can be transported by wind currents and cause health impacts far from
original sources. Millions of people live in areas that do not meet the health standards for
ozone. Other impacts from ozone include damaged vegetation and reduced crop yields.
NOx and sulfur dioxide (SO2) react with other substances in the air to form acids (nitric and
sulfuric acid), which fall to earth as rain, fog, snow or dry particles. Some may be carried by
wind for hundreds of kilometers. Acid rain damages buildings and historical monuments as
well as cars, and also causes lakes and streams to become acidic and unsuitable for many fish
(EPA 3). NOx also reacts with ammonia, moisture, and other compounds to form nitric acid
and related particles. Human health concerns include effects on breathing and the respiratory
system, damage to lung tissue, and premature death.
8/2/2019 Chap 6 About Emission
9/33
Chapter 6. Facts about emissions from motor vehicles
67
Fig. 6.4 Annual amount of NOx emissions (kilotons per year) in Europe in 1995 (People)
One member of the NOx group, nitrous oxide or N2O, is a greenhouse gas. It accumulates in
the atmosphere with other greenhouse gases causing a gradual rise in the earth's
temperature. This will lead to increased risks to human health, a rise in the sea level, and
other adverse changes to plant and animal habitats.
In the air, NOx reacts readily with common organic chemicals and even ozone, to form a
wide variety of toxic products, some of which may cause biological mutations. Examples of
these chemicals include the nitrate radical, nitroarenes, and nitrosamines. Nitrate particles
and nitrogen dioxide can block the transmission of light, reducing visibility especially in urban
areas. The map in Figure 6.4 (above) shows the annual NOx emission in kilotons in different
parts of Europe in 1995.
6.2.4 Particulates (PM)
Particulates, also known as particles or particulate matter (PM), are solid exhaust
components while, as mentioned above, the compounds (CO, HC and NOx) are in the gaseous
state. Particulate emissions are regulated by law for diesel engines, but it seems evident
that, in the future, they will be regulated for gasoline engines, too. This will happen most
likely for at least direct-injected gasoline engines.
8/2/2019 Chap 6 About Emission
10/33
Internal combustion engines
68
Particulates are formed especially in diesel engines, in which the air-fuel mixture is not
homogenous, meaning that close to the fuel spray nozzles there is less air available for
combustion than at the outer edges of the combustion chamber. The mixture in diesel
engines is lean, meaning that there is, on average, always excess air available in the
combustion chamber compared to the amount of air needed for complete combustion.
However, due to the heterogeneity of the mixture, close to the fuel injector nozzles lack of
sufficient amounts of air may be encountered locally.
Lack of air is one of the main contributors to particulate formation. To limit particulate
formation in diesel engines, the amount of fuel injected has to be limited at low engine
speeds. This, of course, reduces the torque. The use of turbochargers, the very newest types
of which are equipped with electronically controllable vanes (also called variable geometry
turbochargers), has made it possible, along with increased amounts of air available, to
increase the amount of fuel sprayed at low engine speeds, thus increasing the low-rpm torque
without increasing particulate formation.
The actual composition of particulates varies according to the engine and driving
conditions, fuel composition etc., but basically they are formed from an uncombusted carbon
core which is surrounded by fuel and lubricant originated hydrocarbons, water and some
miscellaneous compounds. If the fuel contains sulfur, this too is found in particulates. The
size of particulates can also vary, with typical diesel particulate sizes ranging from 0.01 to 1
m. (Neste)
The most recent research has shown that particulates are also generated in gasoline
engines. This is especially true in the case of direct injection gasoline engines, which are
gaining popularity all the time due to their improved fuel economy. However, the particulate
size in gasoline engine exhaust is very small, which leads to considerably lower total
particulate mass emissions compared to those from diesel engines.
There is evidence, however, that the smallest particulates might pose the greatest danger
to human health, since the smaller the particle is, the further into the respiratory system it
can penetrate. Small particles could find their way deep into the sensitive parts of the lungs
and cause or worsen respiratory disease such as emphysema and bronchitis, and aggravate
existing heart disease (EPA 4). This fact will probably have the consequence that in the
future, also direct injection gasoline engines will be incorporated under particulate emissionregulations.
There is every reason to believe that diesel exhaust particulates can cause cancer,
although studies on humans do not provide sufficient evidence as yet. In performing these
kinds of studies, the difficulty is to prevent the test persons from being exposed to other
cancer-causing substances. In any case, numerous research results indicate elevated lung
cancer rates in occupational groups exposed to diesel exhaust.
In 1998, the California Air Resources Board (CARB) formally listed diesel particulates as a
toxic air contaminant. Extensive scientific literature demonstrates that exposure to diesel
exhaust increases the risk of developing lung cancer and creates other, non-cancer, health
problems, as well.
8/2/2019 Chap 6 About Emission
11/33
Chapter 6. Facts about emissions from motor vehicles
69
6.3 Evaporative emissions
In addition to combustion originated emissions (tailpipe emissions), evaporative emissions are
also generated from motor vehicles. Evaporative emissions are hydrocarbons, or volatile
organic compounds (VOC), that dissipate to the atmosphere from the vehicle's fuel system.
Generally, efforts at the reduction of evaporative emissions include the capturing of
vented vapors from within the vehicle, but also the reduction of emissions released to the
atmosphere when refueling vehicles or whenever liquid hydrocarbon fuels are transferred
from one container to another.
To control the evaporative emissions in modern vehicles, vapors from the fuel tank are
channeled through canisters containing activated carbon instead of being vented to the
atmosphere, as was the case with carbureted engines. The vapors are adsorbed within the
canister, which feeds them into the inlet manifold of the engine. When the vehicle is running,
the vapors are desorbed from the carbon, drawn into the engine and burned.
Evaporative emissions of passenger cars have to be measured as a part of the type
approval procedure, and the result of the test has to be below legislative limit values before
a new car model may enter the market.
Evaporative emissions are measured using the co called SHED-test. When conducting the
shed test, the test vehicle is parked inside a special measuring device, called "a shed", like a
small garage, the airspace of which is completely sealed and isolated from the surrounding
atmosphere. After keeping the vehicle in the shed a certain amount of time at a controlled
and certified temperature, the hydrocarbon concentration of the air inside the shed is
analyzed. The current limit is 2 grams of HC per hour, which may amount to an evaporation of
one liter of gasoline in a month (Wikipedia).
6.4 History of emission legislation
Emission legislation specifies the maximum amount of pollutants allowed in exhaust gasesdischarged from a vehicle or an engine. The first emission standards in the world were
initiated in California. The rationale behind the decisions in California was that air quality
was worsening alarmingly in the South Coast Air Basin, where the city of Los Angeles is
located. Already in the late 1950s, tailpipe emissions from motor vehicles were identified as
key contributors to the ambient air pollution problems encountered.
The gasoline-powered vehicles of those days utilized carbureted engines, the air-fuel ratio
of which varied within a wide range of mixtures in different driving conditions producing
plenty of carbon monoxide, hydrocarbons and nitrogen oxides. Needless to say, the vehicles
had no emission after treatment.
8/2/2019 Chap 6 About Emission
12/33
Internal combustion engines
70
The city of Los Angeles was heavily trafficked already in those days, and it is surrounded
by mountains which hinder the air from moving around. This phenomenon makes the pollution
from the cars stay in the air and not dilute and dissolve in the atmosphere.
The high population density and substantially large number of vehicles (for the time) in
that relatively small area combined with the given climatic conditions, made the air quality
so bad that legislative measures had to be taken.
Subsequently, in 1964, the State of California became the first region to issue regulations
stating maximum allowable emission levels for all 1966 and later model year new cars (EPA
5). A separate administrative office, the California Air Resources Board (CARB), was founded
at the same time.
The other states of the USA joined California by regulating emissions from motor vehicles
soon after that. In 1966, a very similar statute was passed by the US Congress covering new
cars from 1968 onwards. The next major milestone was passing of the Clean Air Act in 1970,
which established the Environmental Protection Agency (EPA), and gave it the jurisdiction to
control motor vehicle emissions. (Laurikko, 1998)
The first stages of emission regulations limited only carbon monoxide and hydrocarbons. In
response to this, the first catalytic converters appeared in 1975, having only the capability of
oxidizing CO and HC.
The character and adverse effects of NOx and particulates were not realized until several
years later. The next major milestone was reached in 1981, when the USA also began
regulating nitrogen oxides. Subsequently, three-way catalyst technology, capable of oxidizing
CO and HC while simultaneously also reducing NOx, was introduced in 1981.
In Japan, the emission legislation was initiated in 1967, when CO regulation for gasoline
passenger cars came into force. Hydrocarbon regulation began in Japan in 1970, and NOx
regulation in 1975. Since 1981, Japanese emission limit values have been 8 % below the levels
when no limitations were in force. (Minato, 2005)
In Europe, the first laws regulating vehicle emissions were initiated in 1970, when the
European Economic Community (EEC) passed its first directive (70/220/EEC) on the subject.
Already before that, the Inland Transport Committee (ITC), part of the United Nations
Economic Commission for Europe (UN/ECE), had established an expert forum, the Group of
Reporters on Pollution and Energy (GRPE), to collaborate internationally and report on thematter to the Working Party No 29 (WP.29), which deals with the regulations related to the
construction of motor vehicles. (Laurikko, 1998).
Since the original Directive in 1970, several Adaptations and Amendments have been
adopted. The limit values have been lowered step by step, and also the test method
designation has changed several times.
6.5 Emission legislation today
8/2/2019 Chap 6 About Emission
13/33
Chapter 6. Facts about emissions from motor vehicles
71
Today, emissions from internal combustion engines are regulated in dozens of countries
throughout the world. Their regulatory authorities usually apply American, Japanese or
European emission regulations to some degree, although the most recent and most stringent
steps are not enforced in all cases.
The regulated diesel emissions include:
Carbon monoxide (CO)
Hydrocarbons (HC), regulated either as total hydrocarbon emissions (THC) or as non-
methane hydrocarbons (NMHC). One combined limit for HC + NOx is sometimes used
instead of two separate limits.
Nitrogen oxides (NOx), composed of nitric oxide (NO) and nitrogen dioxide (NO2). Other
oxides of nitrogen which may be present in exhaust gases, such as N2O, are not regulated.
Diesel particulate matter (PM), measured by gravimetric methods (meaning mass
determination). Sometimes diesel smoke opacity measured by optical methods is also
regulated.
Emissions are measured over an engine or vehicle test cycle which is an important part of
every emission standard. Usually, light-duty vehicles are tested as complete vehicles on a
chassis dynamometer, and heavy-duty engines are tested as engines-only in an engine
dynamometer.
Regulatory test procedures are necessary to verify and ensure compliance with the various
standards. These test cycles are supposed to create repeatable emission measurement
conditions and, at the same time, simulate real driving conditions of a given application.
Analytical methods that are used to measure particular emissions are also regulated by the
standards.
Emission cycles are a sequence of speed and load conditions performed on a chassis or
engine dynamometer. Emissions measured on vehicle (chassis) dynamometers are usuallyexpressed in grams of pollutant per unit of traveled distance, e.g., g/km. Emissions measured
according to an engine dynamometer test cycle are expressed in grams of pollutant per unit
of mechanical energy delivered by the engine, typically g/kWh.
Depending on the character of speed and load changes, cycles can be divided into steady
state cycles and transient cycles. Steady state cycles are a sequence of constant engine speed
and load modes. Emissions are analyzed for each test mode. Then the overall emission result
is calculated as a (weighted) average from all test modes. In a transient cycle the vehicle
(engine) follows a prescribed driving pattern which includes accelerations, decelerations,
changes of speed and load, etc. Transient cycles usually represent real-world driving better.
8/2/2019 Chap 6 About Emission
14/33
Internal combustion engines
72
The final test results can be obtained either by analysis of exhaust gas samples collected
in plastic bags over the duration of the whole cycle, or by electronic integration of a fast
response, continuous emission measurement.
Regulatory authorities in different countries have not been unanimous in adopting emission
test procedures. Consequently, many types of test cycles are in use. Since exhaust emissions
depend on the engine speed and load conditions, specific engine emissions which were
measured on different test cycles may not be comparable, even if they are expressed or
recalculated in the same units of measurement. This should be kept in mind when comparing
emission standards from different countries.
Tailpipe emission standards are usually implemented by government ministries responsible
for the protection of the environment, such as the EPA (Environmental Protection Agency) in
the USA. In Europe, the legislation is set by the European Union Directives. The duty to
comply with these standards is on the equipment (vehicle or engine) manufacturer. Typically
all equipment has to be emission certified before it is released to the market. (Dieselnet 1)
6.6 Emission testing stages
In most cases, tailpipe emission legislation requires the emissions of a vehicle or an engine to
be tested at several stages over the whole of the lifetime of a product model. The emissions
usually have to be controlled at three different stages. These are:
type approval
conformity of production
in-use compliance
Type approval (or certification) testing means that the manufacturer brings a new vehicle
or engine model to an emission testing facility and has its product tested according to the
appropriate legislative testing methods. This usually happens when the new model is in itsprototype stage, and the actual production has not started yet.
The purpose of the type approval testing is to provide evidence that the manufacturer of
the product is capable of designing and building a vehicle or an engine that complies with the
current appropriate emission standards. If this is proven, the new product may enter the
market.
Conformity of production (COP) testing is performed for vehicle or engine units, taken
randomly from the production line, to provide evidence that the manufacturer of the product
is capable of producing units, the emissions of which are sufficiently alike with the unit
having been type approved, meaning that they are manufactured in mass-produced with
sufficient exactitude.
8/2/2019 Chap 6 About Emission
15/33
Chapter 6. Facts about emissions from motor vehicles
73
In-use compliance testing is performed for vehicles having been in use for a certain
amount of time. The purpose of this type of testing activity is to make sure that the emission
level of the vehicle does not increase dramatically along with vehicle aging, but stays within
the given range of deterioration.
In-use compliance testing may be implemented for randomly selected vehicles, or in many
cases for every vehicle in use, usually in conjunction with the legally required (annual)
technical inspection. In the USA this type of testing is called the "smog check".
In most cases, in-use compliance testing is performed using simpler measuring methods
than are utilized in type approval and COP testing. This means that usually no chassis
dynamometer is used, but the emissions are measured from an unloaded engine.
6.7 European regulations for light-duty vehicles
6.7.1 General
In Europe, and typically elsewhere, the type approval emission testing of light-duty vehicles
(passenger cars and vans up to 3500 gross vehicle weight) is carried out as complete-vehicle
testing using a road-simulation chassis dynamometer. A simple type of chassis dynamometer,
one which is capable of performing power measurements, is not suitable for emission testing,
since the emission test cycle consists of variable driving speeds. Variable speeds require that
the dynamometer has to feature the inertia-simulation capability, because the vehicle inertia
has to be accounted for when the speed is increasing or decreasing.
The exact road resistance values of the vehicle being tested have to be known based on
calculations and/or road-testing results. These values are then programmed into the chassis
dynamometer to simulate actual driving. The settings of the dynamometer can be checked by
performing a coast-down test on the dynamometer and comparing the results to the
corresponding values measured on a flat road under non-windy conditions.
The emissions are collected over the test using a device called constant volume sampler
(CVS). This device dilutes the exhausts gases with ambient air and measures the volume of
the diluted exhaust. Dilution is used to prevent the moisture in the exhaust condensing andcausing trouble in the analyzers. Another reason is to simulate normal conditions: the exhaust
coming out of the tailpipe is diluted with ambient air anyway.
Constant volume sampler vacuums a fixed pre-adjusted volume of the mixture of exhaust
and dilution air. This means that when the engine load is low and a small amount of exhaust
is generated, more dilution air is sucked through the system, whereas when the exhaust flow
is high, the flow of dilution air is low. This principle makes it possible to measure the
emissions (concentration multiplied by exhaust amount) over a transient test cycle without
knowing the actual concentrations and exhaust flow rates at each moment.
Figure 6.5 illustrates the complete test set-up for a type approval emission test for a
passenger car. Part of the diluted exhaust collected and measured by the CVS system is
8/2/2019 Chap 6 About Emission
16/33
Internal combustion engines
74
collected in sample bags with a plastic coating called tedlar. Samples are taken from both
diluted exhaust and from the dilution air. When calculating the final results, the possible
emissions originating from the dilution air can thus be eliminated.
Fig. 6.5 Test set-up for a type approval emission test (VTT)
After performing the test, the collected samples are analyzed, and the results are calculated
according to the measured exhaust volume, measured concentrations and densities of the
emission compounds, and distance driven. The final results are then expressed as grams per
kilometer (g/km).
The test conditions, like temperature and humidity, have to be controlled, recorded and
checked that they are within the limits set by the Directives. For example, because high
amounts of moisture in the intake air lowers combustion temperature and also NOxformation, humidity of the test cell has to be controlled and recorded.
When calculating the NOx result, a correction factor calculated from the test conditions is
used. If the humidity of the test cell is high, the correction factor for NOx is greater than 1,
because high humidity has lowered the amount of NOx generated. Under low humidity
conditions, however, high levels of NOx have been generated because of the elevated
combustion temperature, and in this case the value of the NOx correction factor is below 1.
The factor corrects the NOx result as if to represent average humidity conditions.
6.7.2 Performing the test
J.Lauri kko'96
Chassis dyno
Dyno anddriver's aid
control
Driver'said
display
Chassis DynoControl
CVS-system
Samplebags
Dilution Air
UndilutedSample
(optional)
DilutedExhaust
Printout
Storage
Calculations anddata acquisition
Gasanalysis
COCO
HCNOx
2
Exhaust evacuation
Dilutionair
Rawexhaust
8/2/2019 Chap 6 About Emission
17/33
Chapter 6. Facts about emissions from motor vehicles
75
The test cycle in the European test type consists of periods of steady acceleration, steady
speed and steady deceleration. The test is divided into two parts representing urban and
extra-urban driving. The maximum speed in the urban part is 50 km/h and in the extra urban
part is 120 km/h. The duration of the test is 1180 seconds (19 min 40 seconds), and the
distance driven is 11.007 kilometers. Average speed is 33.6 km/h (Figure 6.6). The engine and
emission measurement are both started simultaneously at the beginning of the test.
The New European Driving Cycle
0
20
40
60
80
100
120
140
0 200 400 600 800 1000 1200
time [s]
speed[km/h]
Fig. 6.6 The new European driving cycle
The cycle has been used as such from the beginning of the Euro 3 regulations, which
became effective in the year 2000. Before that, an extra idling period of 40 seconds was
applied before the emission sampling started. Needless to say, the old procedure was not a
realistic method of determining the amount of emissions, because the highest concentrations
right after cold start were not accounted for. Before 1991, only the urban part (the first 780
seconds) of the test was used.
During the test, the driver drives the vehicle just like s/he would drive it on the road.
S/he has a computer screen, called a driver's aid, which shows him or her the required speed
and use of gears. The driving cycle is programmed as a graphic curve in the system, and the
actual driving speed measured by the dynamometer is presented to the driver as a moving dot
on the screen. The driver's responsibility is to keep the dot on top of the speed curve by
moving the accelerator pedal as little and as slowly as possible.
The urban part of the test cycle consists of four elementary cycles (195 seconds). In each
of the elementary cycles, the car is accelerated from zero three times (Figure 6.7).
During the first acceleration, only first gear is used, the speed is increased to 15 km/hfollowed by a steady speed phase before bringing the speed back to zero for the next idle
8/2/2019 Chap 6 About Emission
18/33
Internal combustion engines
76
period. During the second acceleration, first gear is used up and till 15 km/h, when the gear
is switched to second, and the speed is increased to 32 km/h before slowing down. During the
third acceleration, after first and second gears, third gear is used from a speed of 32 km/h
upwards.
ECE 15 urban cycle
0
10
20
30
40
50
60
70
0 30 60 90 120 150 180
time [s]
speed
[km/h]
Fig. 6.7 Elementary cycle of the urban part of the European test cycle
In the extra-urban part of the test, constant speeds of 70 km/h, 50 km/h, 70 km/h, 100
km/h and, briefly, 120 km/h are used.
A lot of experience is required for the driver to be able to follow the required speed curve
exactly enough. Usually, a beginner driver overacts and moves the gas pedal too much when
correcting the speed that has drifted out of the required value.
As already mentioned, the cycle designation also determines the gears that the driver is
supposed to use. The gear changing pattern is the same for all light-duty vehicles, which
means that it can be more suitable for the gear ratios of some vehicles than those of others.
On the other hand, the gear changing pattern of the designated emission and fuel
consumption test cycle may be one of the factors the vehicle manufacturer considers, whenselecting the gear ratios.
In the case of automatic transmission, the gear selector is set to "D" position, and the
driver allows the selection of gears to happen automatically.
The acceleration and deceleration rates of the test cycle are quite low. As such, the cycle
does not represent actual aggressive driving of today very well. In most real-world driving
situations the speed changes are faster, and constant speed is used only seldom.
Before a vehicle can be tested, the fuel in the tank has to be replaced by a designated
test fuel. Also, the vehicle has to be driven on the dynamometer according to certain
procedures during the day preceding the actual test. This is called preconditioning the
vehicle.
8/2/2019 Chap 6 About Emission
19/33
Chapter 6. Facts about emissions from motor vehicles
77
The need for preconditioning the vehicle is due to the fact that the light-off temperature
and general functioning of the catalytic converter may vary depending on the type of use the
vehicle has experienced just before the test. For example, if the vehicle has been used only
for short cold-running periods preceding the test, the catalytic converter would be sooty and
would not function efficiently. On the other hand, if the vehicle has been used only for long
high-speed motorway driving before the test, the catalytic converter would be exceptionally
clean and effective at the time the test begins. The preconditioning of the vehicle evens out
these differences.
After the preconditioning of the vehicle is completed, the vehicle is soaked(i.e., left to
stand) under controlled temperature conditions for a certain amount of hours (in practice,
overnight). The engine is then not started until next day, at the very moment when the actual
test begins. As a result, type approval emission testing takes quite a long time. If something
goes wrong, the preconditioning has to be re-done, and the vehicle soaked overnight again.
6.7.3 Limit values
Over the years, the Directives have established several sets of limit values, which have
become stricter and stricter each time a new set of values has been issued. Figure 6.8
illustrates the development of the limit values from 1970, when the first limit values were
published, until today. It can be seen that current limit values for passenger cars are roughly
3 to 5 % compared with the typical values before limitations.
Fig. 6.8 Development of the European limit values for passenger cars
1970 1975 1980 1985 1990 1995 2000 2005 2010 2015
CO
HC
NOx
0
10
20
30
40
50
60
70
80
90
100
Psttaso[%]
Vuosi
Pstlaji
CO
HC
NOx
100% = taso ennen mryksi (=ECE15/00)
Summa
HC+NOx >
CO
HC
NOx
< 5%
< 5%
< 3%
Emissionlevel[%]
Year
100 % = The level before regulations(=ECE 15/00)
1970 1975 1980 1985 1990 1995 2000 2005 2010 2015
CO
HC
NOx
0
10
20
30
40
50
60
70
80
90
100
Psttaso[%]
Vuosi
Pstlaji
CO
HC
NOx
100% = taso ennen mryksi (=ECE15/00)
Summa
HC+NOx >
CO
HC
NOx
< 5%
< 5%
< 3%
Emissionlevel[%]
Year
100 % = The level before regulations(=ECE 15/00)
8/2/2019 Chap 6 About Emission
20/33
Internal combustion engines
78
Numerical values for the limit values from the Euro 1 stage onwards are presented in Table
6.1. It can be seen that the Euro 3 CO limit value for gasoline cars (2.30 g/km) is higher than
the preceding corresponding Euro 2 value (2.2 g/km). This seems strange, since, usually a
new standard is lower than the old one. The explanation for this is the change in the test
method. As already mentioned, until the introduction of the Euro 2 stage, the engine was
idling for 40 seconds before the measurement started. When Euro 3 became effective, all the
exhaust was collected right from the very start-up of the engine. This makes the Euro 3 CO
regulation much tighter than the old one, even though the numerical limit value is higher.
6.7.4 Cycle beating
The expression cycle beating refers to a way of calibrating an engines emission control
system in such a way that the emissions are low for the load conditions present during theofficial emission test cycle, but can be much higher when the engine is operating outside of
the load/engine speed range used in the test.
In many cases, the fuel injection system of a gasoline engine can be programmed so that
the air-fuel ratio (lambda value) is kept at the stochiometric value only at low load levels and
low engine speeds, which are the load conditions utilized during the emission test. Above this
range of engine operation, mixture enrichment is often used, and this leads to dramatically
increased CO and HC values in the exhaust.
This may not be known by the general public, who may believe that they can press down
on the accelerator pedal as hard as they want because the catalytic converter in the vehicleTable 6.1 Numerical values for the passenger car limit values in Europe (Dieselnet 2)
8/2/2019 Chap 6 About Emission
21/33
Chapter 6. Facts about emissions from motor vehicles
79
will keep the emissions low. Unfortunately, this is not the whole truth. In many cases the
emissions burst up from the rated values when the vehicle is accelerated hard.
A Swedish study on this issue, conducted in 1998 (Kgeson, 1998), provides evidence for
the assumptions mentioned above. Figure 6.9 illustrates the maximum power values as a
function of engine speed for two passenger cars. There are two curves presented for both
vehicles. The continuous curve indicates the power measured with regular fuel injection
settings programmed by the manufacturer. The lower curve (dotted line) indicates the
maximum power, measured when the mixture was kept at the lambda = 1 value.
The differences between the continuous and dotted curves illustrate the margin in power
output between the rated power and the power achieved at a mixture setting giving the
lowest possible emissions. It can be seen that the car on the left is only able to reach very
low power at the setting optimized for emissions. This kind of behavior can be called cycle
beating. The car on the right performs much better in this respect.
In the late 1990s, several heavy-duty truck engine manufacturers in the USA were caught
out manipulating the engine operation to release low emissions only at the engine operating
points used in the test cycle. The exposure of this cycle beating activity led to penalties and
resulted in substantial negative publicity for the manufacturers involved.
8/2/2019 Chap 6 About Emission
22/33
Internal combustion engines
80
Fig. 6.9 Differences in power in two passenger cars when the air-fuel ratio is at the manufacturerssetting and when it was kept at lambda = 1 (Kgeson)
6.8 European regulations for heavy-duty vehicles
Unlike in the case of passenger cars and vans, which are tested as complete vehicles, the
emission certification tests for heavy-duty transportation vehicles are conducted as engine-
only tests on an engine dynamometer. Engines used in heavy-duty vehicles are mostly diesel
engines, but also the use of gaseous fuel powered engines is increasing because of
environmental reasons.
The reasons for engine-only testing are very practical. Firstly, large-scale chassis
dynamometers capable of handling heavy-duty vehicles are very rare, and secondly, the
heavy-duty engines are used in so many applications and variations of vehicles that the large
amount of combinations that should be tested would made the complete-vehicle testing
method too work-consuming and too costly.
In the case of heavy-duty vehicles, the same engine is typically used in vehicles with
different transmissions and final drives, different amounts and different types of axles,
different states of load, different wheelbases and different weights of the vehicle. It is self-
evident that the amount of possible combinations make complete-vehicle testing unthinkable.
Before the year 2000, the European certification test method for heavy-duty engines
utilized a steady-state type test cycle only. The test used was called the ECE-R49.
From the Euro 3 regulations onwards (i.e., after 2000), the ECE-R49 test was replaced by a
new steady-state test, called the ESC (European Steady Cycle). Also, an additional transienttype test, called ETC (European Transient Cycle), became at the Euro 3 level compulsory for
8/2/2019 Chap 6 About Emission
23/33
Chapter 6. Facts about emissions from motor vehicles
81
engines having either advanced emission after-treatment systems (in other words, particulate
traps) and/or NOx catalysts. An oxidation catalyst was not considered an advanced after-
treatment system, so engines equipped with an oxidation catalyst were not required to take
the ETC test (Directive 1999).
From the Euro 4 level (2005) on, both steady-state (ESC) and transient type (ETC) tests
have to be passed before the certification for a heavy-duty engine is granted. Also, a smoke
opacity test (ELR, European Load Response) is required. This applies to all types of diesel
engines, regardless of their emission control systems. For gaseous fuel powered engines, only
the ETC test is required (Directive 1999).
6.8.1 The ECE-R49 test
The ECE-R49 test is a 13-mode test, where the engine is measured at idle and at five load
levels at two engine speeds. The idle is measured three times, which make the total amount
of measuring points equal to 13.
Table 6.2 presents the measuring points and the measuring sequence of the ECE-R49 cycle.
It can be seen that idle conditions are measured at the beginning, in the middle and at the
end of the test.
Table 6.2 Measuring points and test sequence of the ECE-R49 test (Dieselnet 3)
Figure 6.10 illustrates the measuring points of the ECE-R49 test. The numbers in the circles
represent the order of the measuring points, and the size of the circles visualize the
weighting factor of each point. The weighting factors are also marked next to the circles.
8/2/2019 Chap 6 About Emission
24/33
Internal combustion engines
82
Fig. 6.10 Schematic view of the test sequence of the ECE-R49 test (Dieselnet 3)
6.8.2 The ESC test
The ESC test is a modified form of the ECE-R49 test. It also has 13 modes, but there are 3
engine speeds instead of 2. Additionally, the lowest load level, 10 %, has been dropped. The
measuring points and the test sequence are presented in Table 6.3
Table 6.3 Measuring points and test sequence of the ESC test (Dieselnet 4)
8/2/2019 Chap 6 About Emission
25/33
Chapter 6. Facts about emissions from motor vehicles
83
Figure 6.11 illustrates the measuring points of the ECS test. The numbers in the circles
represent the order of the measuring points, and the size of the circles show the weighting
factor of each point. The weighting factors are also marked next to the circles.
Fig. 6.11 Schematic view of the test sequence of the ESC test (Dieselnet 4)
In Figure 6.11 three additional points, to be determined by the certification personnel, are
marked. This means that the person in charge of the measuring procedure, has to select three
load points between engine speeds "A" and "C" and between load levels of 25 % and of 100 %
maximum. At these additional measuring points, the NOx concentration of the exhaust is
measured. This procedure has been set up in order to prevent the cycle beating discussed
earlier.
8/2/2019 Chap 6 About Emission
26/33
Internal combustion engines
84
The three engine speeds used in the ESC test are marked as "A", "B", and "C". The
determination of these points is presented in Figure 6.12. The speed "nlo" is the speed below
the speed producing maximum power (Pmax), at which the engine delivers 50 % of its
maximum (rated) power. The speed "nhi" is the speed above Pmax, at which the engine
delivers 70 % of its maximum power. The speed B is in the middle of the speeds nlo and nhi,
whereas the speed A is in the middle of the speeds nlo and B, and the speed C is in the
middle of the speeds B and nhi (Directive 1999). Mathematically this can be presented as
follows:
A = nlo + 25 % (nhi - nlo)
B = nlo + 50 % (nhi - nlo)
C = nlo + 75 % (nhi - nlo)
Fig. 6.12 Determination of the engine speeds in the ESC test (Directive)
The speed nref (=nlo + 95 % (nhi - nlo)) in Figure 6.12 is needed for the ETC test only, and
is not used in the case of the ESC test.
The limit values for the ESC test cycle are presented in Table 6.4 (Directive 1999). The
smoke opacity limit values in the ELR (European Load Response) test are also presented in the
rightmost column of the table.
Table 6.4 Limit values of the ESC (and the ELR) tests.
8/2/2019 Chap 6 About Emission
27/33
Chapter 6. Facts about emissions from motor vehicles
85
Table 6.4 also shows a new vehicle category designation; that of EEV. The EEV, or
Environmentally Enhanced Vehicle, is a vehicle category that reaches lower emission values
than those required from every vehicle. This gives the governments of the countries of the
European Union the possibility to grant, for example, tax relief for vehicles that fulfill the
EEV designation. This is a way to make early (earlier than compulsory) purchasing of the best
possible emission control technology economically attractive for a new vehicle buyer.
6.8.3 The ETC test
The ETC test has been generated by collecting data from real-world driving. It simulates
urban, rural and motorway driving. The driving speed and engine conditions (speed and
torque) were recorded during an actual driving situation, and a certified emission cycle was
established on the basis of the results obtained. Figure 6.13 presents the time - driving speed
pattern that lies behind the ETC cycle.
8/2/2019 Chap 6 About Emission
28/33
Internal combustion engines
86
Fig. 6.13 The time - driving speed pattern behind the ETC test (Dieselnet 5)
Figure 6.14 shows the variation in engine speed during the ETC test. It can be clearly seen
that variations in engine speed are smaller in motorway than in rural or urban driving.
Fig. 6.14 The time - engine speed pattern of the ETC test (Dieselnet 5)
In Figure 6.15, the engine torque variation during the ETC test is shown. The torque varies
quite rapidly even at the motorway-simulating phase (end part of the test). It is also
noteworthy that the torque quite often reaches below-zero values. These phases in the test
cycle simulate engine braking situations. In real driving, engine braking occurs when the
vehicle is moving and the driver does not press the accelerator pedal, but the inertia
(movement) of the vehicle forces the engine to run.
8/2/2019 Chap 6 About Emission
29/33
Chapter 6. Facts about emissions from motor vehicles
87
During the engine braking simulation stages in the ETC test, the engine dynamometer acts
like an electric motor and forces the test engine to rotate rather than absorbs power from it.
Fig. 6.15 The time - engine torque pattern of the ETC test (Dieselnet 5)
In terms of equipment needed for running the ETC test, the rapid variations in engine
speed and torque, as well as the requirement to simulate engine braking, make the use of a
so-called active engine dynamometer a must. The active type engine dynamometers are very
expensive devices that have extremely sophisticated computerized control systems and can
also deliver power (during engine braking simulations) in addition to absorbing it. An active
engine dynamometer at the Technical Research Center of Finland, capable of handling power
levels up to 400 kW, is illustrated in Figure 6.16.
Fig. 6.16 The active engine dynamometer for ETC testingat the Technical Research Center of Finland (VTT)
8/2/2019 Chap 6 About Emission
30/33
Internal combustion engines
88
Limit values for the ETC test are presented in Table 6.5. It has to be noted that instead of
limiting the total amount of hydrocarbons (HC, also abbreviated as THC), the hydrocarbon
limits for this transient type test are given as non-methane hydrocarbons (NMHC). The NMHC
value can be determined, for example, by measuring both the total hydrocarbon (THC) and
the methane (CH4) values and subtracting the methane proportion from the total value.
For the ETC test, in addition to the NMHC limit, there is also a separate limit value for
methane (CH4). The methane limit is applicable to natural gas engines only. Methane is the
main constituent of natural gas, so the amount of unburned methane has to be limited. This is
especially important because the methane molecule is fairly sturdy and it is more difficult to
oxidize in the catalytic converter than other hydrocarbon compounds. Usually, natural gas
engines utilize catalysts, the chemical composition of which is explicitly optimized for
methane oxidation.
Methane itself is not considered to be toxic or reactive. However, methane emissions
became more of an issue after it was realized that methane is a greenhouse gas trapping the
heat in the atmosphere like carbon dioxide (CO2), but at a rate about 20 times stronger.
Among the ETC test limit values, there are also separate values for the EEV vehicle
category discussed earlier in conjunction with the ESC test.
Table 6.5 Limit values of the ETC test
8/2/2019 Chap 6 About Emission
31/33
Chapter 6. Facts about emissions from motor vehicles
89
6.8.4 The ELR test
The ELR engine test was introduced by the Euro 3 emission regulation, with effect from the
year 2000, for the purpose of smoke opacity measurement from heavy-duty diesel engines.
The test consists of a sequence of three load steps at each of the three engine speeds A
(cycle 1), B (cycle 2) and C (cycle 3), followed by cycle 4 at a speed between speed A and
speed C and a load between 10% and 100%, selected by the certification personnel. Speeds A,
B, and C are the same as in the ESC test, and they were defined earlier. The sequence of
dynamometer operation on the test engine is shown in Figure 6.17 (Dieselnet 6).
In the ELR test, the engine load is increased rapidly three times at each of the enginespeeds from 10 to 100 %, while the engine dynamometer keeps the engine speed constant. In
the ELR test, there are 3 designated engine speeds (cycles 1 to 3) and the fourth one (cycle
4). The purpose of cycle 4 is to prevent cycle beating. In cycle 4, both the engine speed and
the starting load level before increasing the load to 100 %, are to be selected by the testing
personnel. This makes it very difficult for the engine manufacturer to design the engine to
have good emissions performance only during the conditions existing in the known part of the
test cycle.
In the ELR test, smoke measurement values are continuously sampled during the test with
a frequency of at least 20 Hz. The smoke traces are then analyzed to determine the final
smoke values by calculation (Dieselnet 6).
8/2/2019 Chap 6 About Emission
32/33
Internal combustion engines
90
Figure 6.17 The ELR test
6.8.5 Conclusion
It is easy to see that steady-state testing does not represent real-world driving. Even in the
case of motorway driving at a relatively constant speed, the engine power varies all the time
because of wind conditions and the small inclinations (gradients) in the road, even though
they are not easily visible. This makes even steady-speed driving very transient in terms of
how the engine experiences it. Needless to say that driving in cities and in heavy traffic
provides even more transient conditions for the engine. Nevertheless, with the introduction
of a transient type test in the year 2000, emissions testing took a huge step forward in terms
of cycle correspondence to real-world conditions. In addition, the use of transient cycles
makes it more and more difficult for the manufacturer to commit cycle beating.
Review questions
1. What are the differences between the air quality emissions and greenhouse gas emissions?
2. What effects can CO, HC and NOx have on humans?
3. Why does a lean mixture contribute to the formation of PM in diesel engines?
4. How are the stochiometric ratio and the lambda value related?
5. What happens when the lambda value is greater than 1 in a) diesel engines, and b)gasoline engines?
8/2/2019 Chap 6 About Emission
33/33
Chapter 6. Facts about emissions from motor vehicles
6. How effective do you think emission legislation has been in reducing emissions worldwide?
7. Can you suggest some other measures to reduce emissions worldwide?
8. What are the advantages and disadvantages of emissions testing in a laboratory and
testing under real driving conditions?
9. Why is laboratory testing used - in other words, why isnt all emission testing carried out
under actual road driving conditions?