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Combustion, performance and
emission characteristics of a diesel
engine fueled with a pumpkin oilmethyl ester
P. CHANDRASEKAR
NIT ROURKELA
Guided by
Dr. S. Murugan
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Twin issues related to depletion of petroleum reserves,
increasing the vehicle population has forced to development
of alternative energy sources. The most suitable alternative
fuel is vegetable oil, because it is renewable in nature and
more environments friendly.
Much research has been done to use of vegetable oils as a
transport fuel. The direct use of vegetable oils in fuel
engines is not encouraged. Due to their high viscosity (11-17 times higher than diesel fuel) and low volatility, they do
not burn completely and form deposits in the fuel injector of
diesel engines.
Introduction
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There are four ways to use vegetable oil in a diesel engine:
(i) direct use or blending in diesel fuel, (ii) micro emulsions
in diesel fuel, (iii) thermal cracking (pyrolysis) of the
vegetable oil, and (iv) transesterification to producebiodiesel. Among these, the transesterification is the
commonly used commercial process to produce clean and
environmental friendly fuel.
The main cultivation of pumpkin seed areas are South andEast Austria and neighbouring countries, southern parts of
North America and Central America, some regions in Africa
as well as Asia.
Cont
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Experimental setup
DAS
LOADCELL
SMOKEMETER
GASANALYSER
ALTERNATOR
AIR TANK
ENGINE
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Make KirloskarModel TAF 1Bore x Stroke 87.5 x 110 mmCompression ratio 17.5:1Rated power 4.4 kWRated speed 1500 rpmStart of injection 23o bTDCNozzle opening pressure 200 bar
Engine specification
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PROPERTIES PSO POME DIESEL
Kinematic viscosity (40oC), mm2/sec 35.6 4.41 35Density (15
o
C), kg/m3 921.6
883.7
836
866
Flash point, oC >230 >120 4576Sulphur content, g/g 2 2 0.050.5Water content, g/g 584 490 Iodine number 115 115 Net calorific value MJ/kg 35.1 34.27 44.8
Physical and Chemical properties
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PUMPKIN OIL
MEHTYL ESTER
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Combustion parameters
Ignition delay
Pressure-crank angle
Heat release rate Performance parameters
Brake thermal efficiency
Exhaust gas temperature
Emission parameters NO emission
CO emission
Smoke density
Result and discussion
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Ignition delay with brake
power
10
11
12
13
14
15
0 1.1 2.2 3.3 4.4
IgnitiondelayinoCA
Brake power in kW
DIESEL POME10
POME20 POME30
POME40 POME50
POME
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Ignition delay is defined as the time difference in
crank angle between start of injection and start of
ignition. Ignition delay determines the premixed
combustion, heat release, maximum pressure and rateof pressure rise.
The shorter ignition delay of POME50 and POME is
due to higher cetane number of POME and its blendcompared to diesel.
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cylinder pressure with crank
angle
0
10
20
30
40
50
6070
80
90
330 360 390
Pressure,
bar
Crank angle , oCA
DIESEL
POME10
POME20
POME30
POME40
POME50
POME
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The cylinder pressure characterized by the ability of
the fuel to mix well with air and burn.
It is observed that the POME50 is higher than that ofdiesel. This may be due to the ignition delay period
increases with the decrease of engine load. At low
engine loads, because of the longer ignition delay
period, combustion starts later for diesel fuel than forbiodiesel blend.
For POME, the cylinder pressure is lower than diesel,
due to high viscosity and low volatility of biodiesel.
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Heat release rate with crank
angle
-10
0
10
20
30
40
50
60
70
330 360 390
HeatreleaserateJ/oCA
Crank angle in oCA
DIESEL
POME10
POME20
POME30
POME40
POME50
POME
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It can be observed that the heat release rate of POME
and its diesel blend is lower than that of diesel, this
may be due to POME and its blend attributes lower
calorific value than diesel fuel so it contributes lower
heat release.
At the time of ignition, less fuel/air mixture is
prepared for combustion with the diesel blend;therefore, more burning occurs in the diffusion-
burning phase rather than in the premixed phase.
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Brake thermal efficiency with
load
0
5
10
15
20
25
30
35
0 25 50 75 100
Braketherm
alefficiency,%
Load, %
DIESEL POME10
POME20 POME30
POME40 POME50
POME
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It can be observed that the brake thermal efficiency of
the tested fuels increase, with increase in the load.
The trends of the brake thermal efficiency of POME
and its blends are higher than that diesel, due to
presence of increased amount of oxygen in POME
and its blends, and additional lubricity.
The maximum brake thermal efficiency for POME atfull load is 33.05% for POME, which is 3.46% higher
than that of diesel.
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Exhaust gas temperature with
load
0
50
100
150
200
250300
350
0 25 50 75 100
Exhust
gastemperature,
oC
Load, %
DIESEL POME10
POME20 POME30POME40 POME50
POME
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For POME and its blends the exhaust gas temperature
is higher compared to that of diesel fuel.
This may be due to longer ignition after burning
stage. Longer ignition delay results in a delayed
combustion and higher exhaust temperature
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NO emission with load
0
50
100
150
200
250
0 25 50 75 100
NOemission,ppm
Load, %
DIESEL POME10
POME20 POME30
POME40 POME50
POME
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For all loads the NO emission for POME and its
blends is higher than that of diesel fuel, except 40%
blend is lower at full load.
The reason for higher NO emission for POME and itsblends is due to higher cylinder temperature.
Another reason may be due to oxygen content present
in biodiesel and its blends. The NO emissions level
was found to be directly related to the exhaust gastemperature while it was inversely related to the
smoke and CO values.
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CO emission with load
0
0.005
0.01
0.015
0.02
0.025
0.03
0.035
0 25 50 75 100
CO
emission,
%vol
Load, %
DIESEL POME10
POME20 POME30POME40 POME50
POME
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From the figure, it can be observed that the CO
emissions are lower for POME and its blends as
compared to that of diesel fuel.
Lower CO emissions form biodiesel fuelled enginemay be due to their more complete oxidation
compared to that of diesel.
Some of the CO produced during combustion of
biodiesel might have converted into CO2by taking upthe extra oxygen molecule present in the biodiesel
chain and thus reduced CO formation
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Smoke density with blends
05
10
15
20
25
30
35
40
45
Smokedensity,%
No load 25% 50%
75% Full load
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It can be observed that the smoke density is lower for
POME and its blends than that of diesel fuel.
But, POME gives more smoke density than the diesel
blends that may be due to higher viscosity of POME. The main reason for lower smoke density for diesel
blends may be due to the complete and stable
combustion of the biodiesel and its blends, which
contains more number of oxygen atoms
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It is concluded that neat pumpkin biodiesel (POME)which results in shorter ignition delay andcombustion duration.
The values heat release rate, pressure crank angle and
rate of pressure rise are comparable with standarddiesel fuel.
The pumpkin oil methyl ester gives better efficiencyand lower emissions as compared to that of dieselfuel.
The analysis reveals that methyl ester from unrefinedpumpkin seed oil is quite suitable as an alternative fordiesel engine.
Conclusion
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C.C. Enweremadu, H.L. Rutto. Combustion, emission and engine performance characteristics ofused cooking oil biodiesel - A review. Renewable and Sustainable Energy Reviews 14 (2010) 28632873.
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References
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THANK YOU