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    Chapter 16 - 1

    ISSUES TO ADDRESS...

    What are the classes and types of composites?

    What are the advantages of using compositematerials?

    How do we predict the stiffness and strength of the

    various types of composites?

    Chapter 16: Composite Materials

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    Chapter 16 - 2

    Composite

    Combination of two or more individualmaterials

    esign goal! obtain a more desirablecombination of properties "principle of

    combined action#

    $ e%g%& low density and high strength

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    Chapter 16 - '

    Composite!

    -- (ultiphase material that is artificiallymade%

    )hase types! -- (atri* - is continuous

    -- ispersed - is discontinuous andsurrounded by matri*

    Terminology/Classii!ation

    +dapted from ,ig% 16%1"a#&

    Callister & Rethwisch 9e%

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    Chapter 16 -

    ispersed phase! -- )urpose!

    ((C! increase y& TS& creep resist%

    C(C! increase K.c

    )(C! increase E& y& TS& creep resist%

    -- /ypes! particle& fiber& structural

    (atri* phase! -- )urposes are to! - transfer stress to dispersed phase

    - protect dispersed phase from

    environment

    -- /ypes! ((C& C(C& )(C

    metal ceramic polymer

    Terminology/Classii!ation

    0eprinted with permission from

    % Hull and /%W% Clyne&An

    Introduction to Composite Materials&

    2nd ed%& Cambridge niversity )ress&

    ew 3or4& 1556& ,ig% '%6& p% %

    woven

    fibers

    crosssectionview

    7%8mm

    7%8mm

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    Chapter 16 - 8

    Classii!ation o Composites

    Large-

    particle

    Dispersion-

    strengthened

    Particle-reinforced

    Continuous

    (aligned)

    Aligned Randomly

    oriented

    Discontinuous

    (short)

    Fiber-reinforced

    Laminates Sandwich

    panels

    Structural

    Composites

    +dapted from ,ig% 16%2&

    Callister & Rethwisch 9e%

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    Chapter 16 - 6

    Classii!ation: "arti!le#Reinor!e$ %i&

    9*amples!

    ,ig% 1%12& Callister &

    Rethwisch 9e%"Copyright 151 by nited

    :tates :teel Corporation%#

    - :pheroidite

    steel

    matri*!ferrite "#

    "ductile#

    particles!cementite",e

    'C#

    "brittle#

    67;m

    ,ig% 16%& Callister &

    Rethwisch 9e%"Courtesy of Carboloy

    :ystems epartment&

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    7/23Chapter 16 -

    Classii!ation: "arti!le#Reinor!e$ %ii&

    Concrete$ gravel > sand > cement > water - Why sand andgravel? :and fills voids between gravel particles

    0einforced concrete $ 0einforce with steel rebar or remesh

    - increases strength - even if cement matri* is crac4ed

    )restressed concrete - 0ebar=remesh placed under tension during setting of concrete

    - 0elease of tension after setting places concrete in a state of compression

    - /o fracture concrete& applied tensile stress must e*ceed this

    compressive stress

    )article-reinforced ,iber-reinforced :tructural

    threaded

    rod

    nut

    )osttensioning$ tighten nuts to place concrete under compression

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    9lastic modulus& Ec& of composites!

    -- two @rule of mi*tureA e*tremes!

    +pplication to other properties!

    -- 9lectrical conductivity& e! 0eplace EBs in euations with eBs%

    -- /hermal conductivity& k! 0eplace EBs in euations with kBs%

    ,ig% 16%'& Callister &

    Rethwisch 9e%"0eprinted with permission

    from 0% H% Droc4&ASTM

    roceedin!s& Eol% 6'& 156'%

    Copyright +:/( .nternational&

    177 Farr Harbor rive& West

    Conschohoc4en& )+ 152%#

    Classii!ation: "arti!le#Reinor!e$ %iii&

    lower limit!

    1

    EcG

    "m

    Em>

    "p

    Ep

    upper limit! c m mE G " E > "pEp

    )article-reinforced ,iber-reinforced :tructural

    ata!Cu matri*

    w=tungsten

    particles

    7 27 7 67 7 177

    187

    277

    287

    '77'87

    vol tungsten

    E"

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    9/23Chapter 16 - 5

    Classii!ation: 'i(er#Reinor!e$ %i&

    ,ibers very strong in tension

    $ )rovide significant strength improvement to the

    composite

    $ 9*! fiber-glass - continuous glass filaments in apolymer matri*

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    10/23Chapter 16 - 17

    Classii!ation: 'i(er#Reinor!e$ %ii&

    ,iber /ypes$ Whis4ers- thin single crystals - large length to diameter ratios

    graphite& silicon nitride& silicon carbide

    high crystal perfection $ e*tremely strong& strongest 4nown

    very e*pensive and difficult to disperse

    )article-reinforced ,iber-reinforced :tructural

    $ ,ibers

    polycrystalline or amorphous

    generally polymers or ceramics

    9*! alumina& aramid& 9-glass& boron& H(W)9

    $ Wires

    metals $ steel& molybdenum& tungsten

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    11/23Chapter 16 - 11

    'i(er Alignment

    alignedcontinuous

    aligned randomdiscontinuous

    ,ig% 16%& Callister &Rethwisch 9e%

    /ransverse

    direction

    Iongitudinal

    direction

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    12/23Chapter 16 - 12

    +ligned Continuousfibers 9*amples!

    ,rom W% ,un4 and 9% Flan4& @Creep

    deformation of i'+l-(o in-situ

    compositesJ& Metall# Trans# AEol% 15"#& pp%

    5-55& 15% sed with permission%

    -- (etal! B"i'+l#-$"(o#

    by eutectic solidification%

    Classii!ation: 'i(er#Reinor!e$ %iii&

    )article-reinforced ,iber-reinforced :tructural

    matri*! $"(o# "ductile#

    fibers! B"i'+l# "brittle#

    2;m

    -- Ceramic!

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    Chapter 16 - 1'

    iscontinuous fibers& random in 2 dimensions 9*ample! Carbon-Carbon -- fabrication process!

    - carbon fibers embedded

    in polymer resin matri*&

    - polymer resin pyrolyLed

    at up to 2877MC%

    -- uses! dis4 bra4es& gas

    turbine e*haust flaps&

    missile nose cones%

    Nther possibilities! -- iscontinuous& random '

    -- iscontinuous& aligned

    +dapted from ,%I% (atthews and 0%I% 0awlings&

    Composite Materials% En!ineerin! and Science&

    0eprint ed%& C0C )ress& Foca 0aton& ,I& 2777%

    "a# ,ig% %2"a#& p% 181K "b# ,ig% %2"b# p% 181%

    "Courtesy .%O% avies# 0eproduced with

    permission of C0C )ress& Foca 0aton& ,I%

    Classii!ation: 'i(er#Reinor!e$ %i)&

    )article-reinforced ,iber-reinforced :tructural

    "b#

    fibers liein plane

    view onto plane

    C fibers!very stiffvery strong

    C matri*!less stiffless strong

    "a#

    877 ;m

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    Chapter 16 - 1

    Critical fiber length for effective stiffening P strengthening!

    9*! ,or fiberglass& common fiber length Q 18 mm needed

    Classii!ation: 'i(er#Reinor!e$ %)&

    )article-reinforced ,iber-reinforced :tructural

    fiber diameter

    shear strength of

    fiber-matri* interface

    fiber ultimate tensile strength

    ,or longer fibers& stress transference from matri* is more efficient:hort& thic4 fibers! Iong& thin fibers!

    Iow fiber efficiency High fiber efficiency

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    Chapter 16 - 18

    Composite Stiness:

    *ongit+$inal *oa$ing

    Continuous fibers- 9stimate fiber-reinforced compositemodulus of elasticity for continuous fibers

    Iongitudinal deformation

    cG m"m

    > &"& and ec

    G em

    G e&

    volume fraction isostrain

    EclG Em"m> E " EclG longitudinal modulus

    c ' composite

    G fibermG matri*

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    Chapter 16 - 16

    Composite Stiness:

    Trans)erse *oa$ing

    .n transverse loading the fibers carry less of the load

    ecG em"m

    > e&"& and c

    G m

    G &

    G

    f

    f

    m

    m

    ctE

    V

    E

    V

    E+=

    EctG transverse modulus

    c ' composite

    G fibermG matri*

    isostress

    Ect=

    EmE

    f

    VmEf+VfEm

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    Chapter 16 - 1

    9stimate of Ecdfor discontinuous fibers!

    -- valid when fiber length R

    -- 9lastic modulus in fiber direction!

    efficiency factor!-- aligned! KG 1 "aligned parallel#

    -- aligned! KG 7 "aligned perpendicular#

    -- random 2! KG '= "2 isotropy#

    -- random '! KG 1=8 "' isotropy#

    /able 16%'& Callister & Rethwisch 9e%":ource is H% Drenchel& (i)re Reinorcement&

    Copenhagen! +4ademis4 ,orlag& 156%#

    Composite Stiness

    )article-reinforced ,iber-reinforced :tructural

    EcdG Em"m> KE"

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    Chapter 16 - 1

    Composite Strength

    )article-reinforced ,iber-reinforced :tructural

    9stimate of for discontinuous fibers!cd"

    2% When lR lc

    l

    1% When lQ lc

    l

    l

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    Chapter 16 - 15

    Composite "ro$+!tion Metho$s %i&

    ,ig% 16%1'& Callister & Rethwisch 9e%

    )ultrusion Continuous fibers pulled through resin tan4 to impregnate fibers with

    thermosetting resin .mpregnated fibers pass through steel die that preforms to the desired shape )reformed stoc4 passes through a curing die that is

    $ precision machined to impart final shape$ heated to initiate curing of the resin matri*

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    Chapter 16 - 27

    Composite "ro$+!tion Metho$s %ii&

    ,ilament Winding$ Continuous reinforcing fibers are accurately positioned in a predetermined

    pattern to form a hollow "usually cylindrical# shape$ ,ibers are fed through a resin bath to impregnate with thermosetting resin$ .mpregnated fibers are continuously wound "typically automatically# onto a

    mandrel$ +fter appropriate number of layers added& curing is carried out either in an

    oven or at room temperature

    $ /he mandrel is removed to give the final product

    ,ig% 16%18& Callister & Rethwisch 9e%S,rom % I% Hanco*& "9ditor#& (i)re Composite *y)rid

    Materials& /he (acmillan Company& ew 3or4& 151%T

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    Chapter 16 - 21

    Iaminates-

    -- stac4ed and bonded fiber-reinforced sheets

    - stac4ing seuence! e%g%& 7U=57U

    - benefit! balanced in-plane stiffness+dapted from

    ,ig% 16%16&

    Callister &

    Rethwisch +e%

    Classii!ation:Str+!t+ral

    )article-reinforced ,iber-reinforced :tructural

    :andwich panels -- honeycomb core between two facing sheets

    - benefits! low density& large bending stiffness

    honeycombadhesive layer

    face sheet

    ,ig% 16%1& Callister & Rethwisch 9e%"0eprinted with permission from En!ineered

    Materials *and)ook& Eol% 1& Composites&

    +:( .nternational& (aterials )ar4& NH& 15%#

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    Chapter 16 - 22

    Composite ,eneits

    )(Cs! .ncreased E=

    E"

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    Chapter 16 - 2'

    Composites types are designated by!

    -- the matri* material "C(C& ((C& )(C# -- the reinforcement "particles& fibers& structural#

    Composite property benefits! -- ((C! enhanced E& & creep performance

    -- C(C! enhanced KIc

    -- )(C! enhanced E-,& y& TS-, )articulate-reinforced! -- /ypes! large-particle and dispersion-strengthened

    -- )roperties are isotropic

    ,iber-reinforced!

    -- /ypes! continuous "aligned# discontinuous "aligned or random#

    -- )roperties can be isotropic or anisotropic

    :tructural! -- Iaminates and sandwich panels

    S+mmary