Ce Chem07 Ms

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  • 8/9/2019 Ce Chem07 Ms

    1/8

    2.

    (a)

    Cr-aa

    Y'' t

    /

    (b) (D

    The

    products

    of crackingcontained nsaturated

    h:rdrocarbons)

    alkenes

    C=C'/ ethene/

    reasonablb ame

    of alkene

    carbon-carbon

    oublebond

    must

    be shown f usingmolecular

    formulal which decolourisedhe brominewater mmediately

    by addition eaction.

    C2

    's

    a

    (ii)

    The

    products

    of cracking also contained aturated

    hydrocarbons)

    alkanes methane/

    reasonable

    ameor

    molecular

    ormulaof alkane

    do

    not

    acceptC-C] which decolourised

    the

    brominewater slowly by substitutioneaction.

    i l . , ' l

    / t

    '/ '

    g{ .1f ic

  • 8/9/2019 Ce Chem07 Ms

    2/8

    RTFfjy,Hilaffi

    FOR

    TEAGHERS'

    SE

    ONLY

    C

    +

    \

    1i,',"'.f1(---

    i" f;:,{

    .

    (a)

    L-rt{rf

    OCI'+

    Cl'

    +

    2H*

    *

    Clz

    +

    H2O

    or

    NaOCI

    2HCt--+

    Cl2

    +

    HzO

    +

    NaCl

    Chanee

    from

    colourless)

    o

    bpw:{y-qllp:Y

    Ci,

    +

    Zl'

    ZCI-

    Iz

    or

    Cl2

    +

    zKl

    +

    2KCl

    +

    lz

    (ii)

    Noobservablechange/reaction

    o'/,

    h,,4-&

    \Gv€

    ttfqit ,-(

    r rced/ lcsshnrmful to,

    '

    t l less

    (c)

    lesi ctreniicils

    are

    used

    less

    harmful

    o

    environmen

    money

    save

    ime

    ldo

    not

    accept

    eaction

    asterl

    .q

    dangerous

    easY

    o

    han

    dle

    save

    I

    I

    1

    41

    [1\rt1(

    4.

    (a)

    Both

    vinegar

    and

    wine

    contain

    $ot69ut:sa-

    ?

    unl.1

    s

    '.{'

    (

    "'

    ''k

    Only vinJgar (ethanoicacid) ffi in water / contains mobile)

    electricitY.

    (b)

    (D

    Ps+fe2+*2e-

    ( i i )

    ztf

    +2i

    -Hz

    (c)

    Iron

    reacts

    irectly

    with

    vinegar/fl*(aq)

    iving out

    hydrogen

    as.

    5, (a )

    (b)

    (c)

    Zn+ 2H*- Znz* Hz or Zn+2HCl- ZnClz Hz

    Z

    ^

    t'::

    { i -

    t i , . , , , " , f ;Y i .* :s

    I

    ions

    for conducting

    1

    tl:

    avi l

    {

    l,.t-{L

    {

    left

    behind

    I

    I

    I

    (t

    t f - i r

    1

    I

    I

    1

    No further

    gas

    gvolveo

    r*u drc.t.r,( 5"

    {.&b

    t.''up-"/fit' '

    ;r,.\.pL

    gr.

    .

    ,.f

    7

    To

    wash

    away

    Zn*

    I

    Cl' lH*

    lZnCl2

    /HCl

    lacid

    Dgaqt

    4-c-c-ept

    mpurit ies]

    d

    Copper

    will

    be

    oxidized

    /

    become

    co

    oxide

    / copper

    reacts

    with

    o

    en

    (or

    air)

    (e)

    Percentage

    f

    zinc

    by

    mass

    n

    the

    sample

    (2.00 1.75)

    2,00

    100%

    =

    12.5oA

    AF

    A**

    'f^

    tYtatatL

    aOO7-CE-CHEM

    -4

    L".2**

    )

    i

    'J

    C *

    /r

    ta^

    (

    F

    E+Y.HFaffi

    FOR

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  • 8/9/2019 Ce Chem07 Ms

    3/8

    FORTEACHERS'SEONLY

    MgO+Clz+C-*

    MgClr+CO

    or 2MgO

    +ZClz+C

    -ZMEClz+COz

    t

    redox

    reacti

    n)

    t

    displacement

    reaction)

    Potassium

    s a

    more

    powerful

    educing

    gent

    more

    eactive

    han

    magnesium.

    (c) (i) electrolysis

    (ii)

    Magnesium

    chloride

    s an

    electricity

    in

    molten

    state/

    contains

    obile ons.

    (d)

    sacrificial

    rotection

    making

    alloy firework

    flash

    do

    not accept

    pplication

    f MgO]

    r., .yrt ,L

    f

    concentrated

    odium ydroxide olution

    '

    ^

    .7,

    r-

    1:'

    {,(''

    t'5

    5'

    L'rrr

    }

    (white) olid./powder

    do.not

    ccgptprecipitateJeft ' -

    t" t i . l

    u

  • 8/9/2019 Ce Chem07 Ms

    4/8

  • 8/9/2019 Ce Chem07 Ms

    5/8

    RTF'Hilaffi

    FOR

    TEACHERS'USE

    NLY

    9.

    Chemicallkowledge

    6

    marks)

    Corrosive

    rooerly

    o

    safety

    glasses

    goggles

    rubber

    gloves

    protective

    lothings avoid

    contactwith skin

    or eyes I

    wash

    with

    plenty

    of

    water

    f contacted

    ith

    skin

    o

    because

    cidof high

    concentration

    s cofrosive

    '.1

    .;',

    t:,

    '(.,-rr1r-,J

    "

    DilUtion rg.ce_ss

    o

    add

    slowly)

    small amount

    of

    rust emover

    nto a

    largeamountof water

    with

    stirring)

    I

    r

    because

    arge amount

    of heat

    given

    out

    in dilution of the rust remover

    (acid

    of

    high I

    concentration)

    avoid

    rust remover

    acid)

    splashing

    ut

    '

    n,

    o

    ..

    ".1.*,

    ,.j;;1 i\w.

    u<

    ttnir

    ,

    '

    , ; ' . t - ' '11

    1- r

    Otherpotential

    aneers

    \'

    'i('{th'r"L{"rv

    ;-

    *.

    ptasti.

    "ontainer

    instead

    f metal

    do not

    use o cleanmarble

    do-'notmix with

    chlorine

    I

    bleach

    r caustic oda

    do not

    put

    n

    warm

    place

    o

    because

    ill

    damage

    metal

    container

    damage

    marble toxic

    gas

    evolvesf mix

    with chlorine

    I

    blpach large

    amount

    of heat

    eleases

    f mix with caustic oda/

    acidic

    gas

    evolves f

    put

    in

    (. -. -, ' r ,

    \ r; ' r t '

    warm

    place

    .".. r

    i,

    "r,._,r_

    i

    ,,

    r,n

    f

    tr,t"";,^

    \

    t,rr:\

    pp.,t

    ,l*,e+i'

    i

    \

    u. ,

    - * l , r *" . -Y\

    i

    -

    ( ' ' "5 ' - i : t

    c l ' ' * . ( i ' . ' - i1*- "1( ' 'u-

    ,,j

    1]

    "

    "*-\

    t

    '''a-"i(

    f,k

    I-"

    1t t-

  • 8/9/2019 Ce Chem07 Ms

    6/8

    Section

    RTF+f

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    x

    (

    tt

    r

    i'-..

    '' '

    "t'

    t

    /

    f

    c

    , , )

    p:

    P

  • 8/9/2019 Ce Chem07 Ms

    7/8

    RrF+f

    ilaffi

    FOR

    EACHERS'USE

    NLY

    t2.

    (a)

    Molerat ioofC:H:O

    0.401

    0.069

    0.531

    =-r- t-

    12

    I

    16

    (step-mark)

    FOR

    TEACHERS'

    :g/

    3>

    x

    dr(

    l*

    =

    0.033

    0.068

    0.033

    -l :Z:

    I

    Ernpirical

    ormula

    of

    Z:

    CH2O

    (b)

    Let

    he

    molecular

    ormula

    of

    Zbe

    (CH2O)"

    formula

    mass

    of Z

    =

    -*;-

    x24

    =60

    (step-mark)

    (400

    1000)

    --

    \---r

    ---E'r/'

    (12+2+16)n=60

    n

    (, : ,03)):o.ct66

    .

    n:2

    a\ :_. ,

    \1

    X.

    Molecular

    ormula

    of

    ZisC2HaO2

    W#4t

    t.

    q,,ttt->T

    (c)

    (i)

    HCoOcH3

    Explanations:

    /

    [Ja

    .4,u.

  • 8/9/2019 Ce Chem07 Ms

    8/8

    -

    \

    RTF?,f-HFaffi

    FOR

    TEACHERS'USENLY

    13.

    Chemical

    nowledge

    6

    marks)

    The

    ollowing5

    points.

    mark or

    each

    oint

    .;:''.'"

    '

    1'-n''

    "(

    nve ionic

    group

    headand ong hydrocarbon

    hain tail.

    ravehydrophilic

    property

    andhydrophobic

    roperty.

    ls, while soapless etergents

    ade rom

    petroleurn.

    g:

    I

    ,

    while

    soapless

    etergents

    ave

    SOr-

    /

    -OSO3-

    group.

    ardrvater acidic

    medium,while soapless

    etergents

    an.

    i \

    L'I

    .t

    \

    / \ : " ' \ -Lr , - r {

    ;

    ^^i"t

    I

    I

    '

    ,t -

    .l\tl,-

    U

    .

    i

    ,

    \

    \

    (B )

    Effective

    ommunication

    3

    marks)

    General uidelinesor marking ffective ommunication

    \

    t-

    ---'

    il

    "i

    "''

    \

    -----/'

    'J

    ?,

    ,

    e

    Both soapyand

    soapless etergents

    ct aswctting

    agents.

    r

    Both

    soapyand

    soapless etergents

    ct asemulsi&ing

    agents.

    o

    Soapy

    detergents reusually

    biodegradable, hile soapless etergents sually

    arenot.

    o

    Soapless

    etergents

    anbe ailor-made,

    while

    soapydetergents

    annot.

    (6)

    ( i i)

    (i)

    The

    mark for effective

    communication hould elate o the

    candidate's

    nowledge

    n

    chemistry.

    A candidate

    who wrote a

    paragraph

    hich

    s

    totally unrelated

    o the

    question

    should

    eserve eromarks oth

    n chemical nowledge

    nd

    n effective

    ommunication.

    The table

    below illustrates he

    relationship etween

    he mark

    for chemical

    knowledge

    and the maximum

    mark for effectivecommunication,ogetherwith

    the

    points

    o be

    considered

    n marking ffective

    ommunication.

    (iiD

    The hreemarks

    or effective

    ommunicationre

    awarded s

    ollows

    (A)

    the ability

    to

    present

    deas n

    a

    precise

    manner,

    ncluding he

    proper

    use of

    chemical

    erms

    (this

    mark

    shouldnot

    be awarded

    o answers

    hich

    contained

    a lot

    of incorrecVsuperfluous

    aterials);

    (c)

    the ability

    to

    present

    deas

    n

    a systematic

    manner

    follow);

    the ability

    to

    present

    answer in

    para9raph

    orm and

    sentences.

    (i.e.,

    he

    answer s

    easy

    o

    I

    to express

    deasusing

    full

    I

    -r

    /+

    ( . ,

    Y.

    r{

    K"

    P;-

    i v ' -

    \.

    .

    "a

    /. J

    2007-cE-cHEM-10

    mark or chemical

    knowledge

    maximum mark

    for effective

    communication

    points

    o

    be

    considered

    n

    paragraph

    (iii)

    below

    4 or

    above

    3

    (A),

    (B)

    and

    c)

    3 or

    below

    2

    (B)

    and

    c)

    RTF+Y,HFAffi

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    TEACHERS'

    SEONLY