CARRS OF SHEFFIELD (MANUFACTURING) LIMITED ASSESSMENT OF

CARRS OF SHEFFIELD (MANUFACTURING) LIMITED

ASSESSMENT OF WORK ACTIVITY

Date of Assessment: March 2002 Updated July 2009 Assessment by: Martin Carr

Responsible Manager:

Work Activity: Water Treatment Processes

General Description of Activity: Replace chemicals used in the treatment of water in the cooling tower. Taking of dip slides Duration: < 1 Hour/week Numbers Exposed: No more than 1 at any time, perhaps 3-4 people involved in the operation at some time Materials used:

1. GCO Visigard Is now 3DT289 2. Dushield 20 Is now ST40 3. Dushield 15 Is now ST40 4. Deep Crystal 5. GWT 46 6. Penetrex

Exposure Limits 1. None 2. None SEL only see datasheet 3. None 4. OES Chlorine, Dust see datasheet 5. OES Dust, S02 , Sodium Metabisulfite 6. None

Hazards 1. Mild Irritation Eyes/Skin 2. Burns Eyes/Skin 3. Severe Irritation Eyes/Skin 4. Severe Irritation Eyes/Skin 5. Skin Irritating / Eyes Severe Damage 6. Ski/Eyes Mild irritation

Control Measures: LEV Systems None Other Controls None PPE Requirement Alkali Resistant Gloves and Eye protection to be used when there is a chance of Eye/Skin contact. Atmospheric Monitoring Required for: Not Required

admin

Sticky Note

10/09/2015 For Clarity "Cooling Tower" now uses CW077 & CW166 03/10/2012 3 PMS* Products have been added. These are used to clean and keep bacteria down in the tool room machines. PPE should be worn to protect the eyes when there is a danger of splashes from un-diluted material. 31/08/2012 CWI60 replaced by CWI66 - No difference from HS point of view 06/02/2012 CWO 77 replaces ST40 & CWI 60 replaces 3DT289 27/01/2012 Multisol is used as an additive to in the toolroom for water cooling operations. PPE should be work where there is likely contact with eyes in it's un-diluted form.

Assessment of Control Given the nature of the job exposure to the chemicals is very limited. Therefore inhalation should not be a problem. However, PPE should be worn when there is a chance of eye/skin contact. For direct contact with chemicals, usually Nalco, also see www.carrssilverware.co.uk/database/coolingtowercoshh.zip IN EMERGENCY – SEE DATA SHEET

Pg 1 of 2 AGC REV 1 / 96

Health & Safety Data Sheet

MULTISOL SEMI-SYNTHETIC FLUIDS

PENNINE LUBRICANTS UNIT 35, NUTWOOD TRADING ESTATE LIMESTONE COTTAGE LANE SHEFFIELD S6 1NL TEL: 0114 2852987

FAX: 0114 2852988

PRODUCT NAME: MULTISOL G, SS, EPG PRODUCT CODE: AGC, AGE, AGH APPLICATION: Metalworking fluid to be used diluted with water prior to use.

2. COMPOSITION / INFORMATION ON INGREDIENTS General: This product is based on highly refined mineral oil, emulsifiers and additives. Hazardous Ingredients: Diethanolamine condensation product. 15 - 25% TWA 3ppm

3. HAZARD IDENTIFICATION Health and Safety Hazards: Eye contact with undiluted product may cause irritation. The undiluted product may be irritating to the skin, especially if the material is not removed promptly. Special Hazards of During use, metalworking emulsions may become contaminated with metal particles and Product after use: metal salts, other lubricants and microbiological contaminants. These may increase the irritancy of emulsions, and in some cases (e.g. contamination by chromium, cobalt and nickel) may be capable of inducing allergic reactions.

4. FIRST AID MEASURES Eyes: Immediately wash eye thoroughly with plenty of clean water. For contact with undiluted fluid, obtain prompt medical attention. For contact with diluted product if irritation persists. Skin: Following contact with the undiluted product, wash thoroughly with soap and water without delay. Remove heavily contaminated clothing. wash contaminated clothing before re-use. If irritation persists, obtain medical advice. Ingestion: DO NOT INDUCE VOMITING. Wash out mouth with water and obtain medical attention. Treat symptomatically. If aspiration is suspected, obtain immediate medical attention. Pressure Injection: Always obtain immediate medical attention.

5. FIRE FIGHTING MEASURES Flammability: May support combustion in a serious fire. Extinguishing Media: Foam, dry powder, CO2, sand or earth. Products of Combustion:See Section 10

6. ACCIDENTAL RELEASE MEASURES Always prevent entry into drains or watercourses. Spillages can be slippery. Small Spills: Soak in absorbent granules or sand. Large Spills: Bund using absorbent granules, sand or earth and reclaim bulk liquid. Disposal of Spillage: Via authorised waste disposal contractor. Disposal must be in accordance with the Environmental Protection Act 1990.

7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes with undiluted product, by wearing goggles or facemask and oil impervious gloves. Storage: Store in dry conditions between 0 and 40o C.

8. EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits: As for mineral oil mist: 5mg/m3 (8hr TWA) Eyes: Wear goggles or face mask when handling undiluted product. Skin: Wear oil impervious gloves when handling undiluted product. Change heavily contaminated clothing and overalls as soon as possible. Inhalation: Respiratory protection is not normally required. Industrial Hygiene: Wash hands after use, before eating, drinking or smoking and before and after using the toilet.


9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour: Viscous Liquid with Characteristic Odour Specific Gravity @ 20o C : 1.005 pH(5%): 9.0 - 9.4 Solubility in water: Emulsifyable Flash Point (C): >100 Autoignition Temp.: >150 Boiling Point (C): >100 Melting Point (C): <0 Viscosity @ 40 o C (cSt) 50 - 150

10. STABILITY AND REACTIVITY Stability: This product is stable and unlikely to react in a hazardous manner in normal conditions of use. Conditions to Avoid: Extremes of temperature. Store between 0 and 40oC. Materials to Avoid: Strong oxidising agents. Decomposition Products:Oxides of carbon, water and traces of other compounds some may contain chlorine.

11. TOXICOLOGICAL INFORMATION Eyes: Eye contact with undiluted product may cause moderate irritation and stinging. there maybe a potential to cause corneal injury if treatment is not prompt. Dilute emulsions are expected to cause only slight transient irritation or redness. Skin: The undiluted product in occasional skin contact is unlikely to cause any significant reaction. Prolonged contact with undiluted product may cause defatting of skin barrier leading to cracking and soreness. Inhalation: The product is unlikely to present any significant inhalation hazard at ambient temperatures. High temperatures or atomising systems may lead to generation of vapours, mists or fumes which could cause irritation to eyes or respiratory tract. Repeated excessive exposures to oil mists may cause respiratory damage and a condition resembling pneumonia. Ingestion: The product has a low order of acute oral toxicity; ingestion is not regarded as a significant health hazard likely to arise in normal use. Swallowing significant quantities may cause discomfort, nausea and diarrhoea. Aspiration: Aspiration into the lungs caused by vomiting following ingestion can be hazardous with possible resultant chemically induced pneumonia.

12. ECOLOGICAL INFORMATION Water: The individual components range from readily to poorly biodegradable. The components are not expected to be highly toxic to aquatic life. If released to water, the product may deplete the oxygen supply to bottom dwelling organisms. Soil: Small quantities will be absorbed in the upper soil layers where biodegredation may take place.

13. DISPOSAL CONSIDERATIONS All means of disposal should comply with local regulations and the Environmental Protection Act 1990. Dispose of the product and containers carefully and responsibly. Do not allow product to contaminate ponds, water courses, soil or drains.Dispose of via an authorised person / licensed waste disposal contractor.

14. TRANSPORT INFORMATION Classification: Not classified as dangerous for conveyance. UN Number: Not Applicable.

15. REGULATORY INFORMATION

16. OTHER INFORMATION (1) Other materials should not be added to the product or emulsions unless recommended. (2) Emulsions should be maintained at the recommended concentrations in order to minimise any health hazards. (3) Minimise tramp oil and contamination; remove metallic swarf or other debris from machines at frequent intervals. (4) During machining, emulsions may become contaminated with certain metals which are present in the workpiece or tools. These may solubilise in the emulsion. Some of these contaminants, such as chromium, nickel or cobalt may induce allergic reactions. ADDITIONAL INFORMATION Legislation: Chemical (Hazards, Information and Packaging) regulations 1993. Environmental Protection Act 1990. Control of Pollution Act 1974. The Environmental Protection (Duty of Care) Regulations 1991. HSE Publications: EH 26 Occupational Skin Diseases. Health and Safety Precautions. EH 40 Occupational Exposure Limits. EH 58 The Carcinogenicity of Mineral Oils. EH 62 Metalworking Fluids - Health Precautions. SHW 397 Effects of Mineral Oil on the Skin

Pg. 1 of 2 AGF REV 1 / 96


BIO-FLUSH (SYSTEM CLEANER) PENNINE LUBRICANTS LTD UNIT 35, NUTWOOD TRADING ESTATE LIMESTONE COTTAGE LANE SHEFFIELD S6 1NL TEL: 0114 2852987 FAX: 0114 2852988 PRODUCT NAME: Bio-Flush (System Cleaner) PRODUCT CODE: AGF APPLICATION: Industrial cleaner for metalworking fluids 2. COMPOSITION / INFORMATION ON INGREDIENTS General: This product is a mixture of alkali surfactants and biocides. Hazardous Ingredients: Classification & R Phrases: Exposure Limits % wt: Triazine Xi: R36 10 - 20 3. HAZARD IDENTIFICATION Health and Safety Hazards: Eye contact with undiluted product may cause irritation, there may be a potential to cause corneal injury if treatment is not prompt. Environmental Hazards: This product is readily biodegradable. 4. FIRST AID MEASURES Eyes: Immediately wash eye thoroughly with plenty of clean water. For contact with undiluted fluid, obtain prompt medical attention. For contact with diluted product, obtain medical attention if irritation persists. Skin: Following contact with the undiluted product, wash thoroughly with soap and water without delay. Remove heavily contaminated clothing. Wash contaminated clothing before re-use. If irritation persists, obtain medical advice. Ingestion: DO NOT INDUCE VOMITING. Wash out mouth with water and obtain medical attention. Treat symptomatically. If aspiration is suspected, obtain immediate medical attention. 5. FIRE FIGHTING MEASURES Flammability: May support combustion in a serious fire. Extinguishing Media: Foam, dry powder, CO2, sand or earth. Products of Combustion: See Section 10 6. ACCIDENTAL RELEASE MEASURES Always prevent entry into drains or watercourses. Spillages can be slippery. Small Spills: Soak in absorbent granules or sand. Large Spills: Bund using absorbent granules, sand or earth and reclaim bulk liquid. Disposal of Spillage: Via authorised waste disposal contractor. Disposal must be in accordance with the Environmental Protection Act 1990. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes with undiluted product, by wearing goggles or facemask and oil impervious gloves. Storage: Store in dry conditions between 0 and 40o C. 8. EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits: The product does not have an established Occupational Exposure Standard (OES) or Maximum Exposure Limit (MEL). Eyes: Wear goggles or face mask when handling undiluted product. Skin: Wear oil impervious gloves when handling undiluted product. Change heavily contaminated clothing and overalls as soon as possible. Inhalation: Respiratory protection is not normally required. Industrial Hygiene: Wash hands after use, before eating, drinking smoking and before and after using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES

Pg. 2 of 2 AGF REV 1 / 96

Appearance and Odour: Blue Liquid with Mild Odour Specific Gravity @ 20o C: 1.160 pH (5%): 10.0 - 11.0 Solubility in water: Miscible Flash Point (C): >100 Autoignition Temp: >150 Flammability limits in air: Not Known Vapour Pressure @ 20o C: Not known Vapour Density: Not Known Boiling Point (C): >100 Melting Point (C): <0 Viscosity @ 40 o C (cSt) 150 - 300 10. STABILITY AND REACTIVITY Stability: This product is stable and unlikely to react in a hazardous manner under normal conditions of use. Conditions to Avoid: Extremes of temperature. Store between 0 and 40oC. Materials to Avoid: Strong oxidising agents. Decomposition Products: Formaldehyde, amine and a small proportion of oxides of nitrogen may be released at high temperatures. 11. TOXICOLOGICAL INFORMATION Eyes: Eye contact with undiluted product may cause moderate irritation and stinging. There may be a potential to cause corneal injury if treatment is not prompt. Dilute solutions are expected to cause only slight transient irritation or redness. Skin: The undiluted product in occasional skin contact is unlikely to cause any significant reaction. Prolonged contact with undiluted product may cause defatting of skin barrier leading to cracking and soreness. Inhalation: The product is unlikely to present any significant inhalation hazard at ambient temperatures. High temperatures or atomising systems may lead to generation of vapours, mists or fumes which could cause irritation to eyes or respiratory tract. Ingestion: The product has a moderate order of oral toxicity; ingestion is expected to produce intense irritation to mouth, throat and digestive tract. Swallowing significant quantities may cause discomfort, nausea and diarrhoea. 12. ECOLOGICAL INFORMATION Water: This product is readily biodegradable. Nitrosamines may be formed with the nitrogen content in the water or in the presence of nitrites. Soil: Small quantities will be absorbed in the upper soil layers where biodegredation may take place. 13. DISPOSAL CONSIDERATIONS All means of disposal should comply with local regulations and the Environmental Protection Act 1990. Dispose of the product and containers carefully and responsibly. Do not allow product to contaminate ponds, watercourses, soil or drains. Do not dispose of undiluted product or untreated emulsions down the drains. This product must be disposed of via an authorised person / licensed waste disposal contractor. 14. TRANSPORT INFORMATION Classification: Not Applicable. UN Number: Not Applicable. Packaging Group: 111 15. REGULATORY INFORMATION EEC Classification: Eye Irritant (Xi). Risk Phrases: R36 Irritating to eyes. Safety Phrases: S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Note: The above classification applies to the undiluted product as supplied. It does not apply when the product is diluted for use at the correct operating strength. 16. OTHER INFORMATION Generally the usage concentration should be designed to give a level of between 1 and 2% in metalworking fluid emulsions. Exposure to excessive concentrations may give rise to skin irritation and occasionally sensitisation. Due to the potential problems that may be encountered when using at too high or too low a concentration, it is advised that our recommendation for each individual requirement is obtained if there is any doubt about the appropriate usage concentration. ADDITIONAL INFORMATION Legislation: Chemical (Hazards, Information and Packaging) regulations 1993. Environmental Protection Act 1990. Control of Pollution Act 1974. The Environmental Protection (Duty of Care) Regulations 1991. HSE Publications: EH 26 Occupational Skin Diseases. Health and Safety Precautions. EH 40 Occupational Exposure Limits. EH 62 Metalworking Fluids - Health Precautions.

Pg. 1 of 2 REV 1 / 96


BIO-TECT PENNINE LUBRICANTS LIMITED UNIT 35 NUTWOOD TRADING ESTATE WADSLEY BRIDGE SHEFFIELD S6 1NL TEL: 0114 285 2987 FAX: 0114 285 2988 PRODUCT NAME: Bio-Tect APPLICATION: Industrial biocide for metalworking fluids. 2. COMPOSITION / INFORMATION ON INGREDIENTS General: This product is a mixture of linear and cyclic hydroxyalklamines. Hazardous Ingredients: Classification & R Phrases: Exposure Limits % wt: Triazine Xi : R36 / R38 80 - 100 3. HAZARD IDENTIFICATION General: Eye contact with undiluted product may cause irritation, there may be a potential to cause corneal injury if treatment is not prompt. The undiluted product may be irritating to the skin, especially if the material is not removed promptly. 4. FIRST AID MEASURES Eyes: Immediately wash eye thoroughly with plenty of clean water. For contact with undiluted fluid, obtain prompt medical attention. Skin: Following contact with the undiluted product, wash thoroughly with soap and water without delay. Remove heavily contaminated clothing. wash contaminated clothing before re-use. If irritation persists, obtain medical advice. Ingestion: DO NOT INDUCE VOMITING. Wash out mouth with water and obtain medical attention. Treat symptomatically. If aspiration is suspected, obtain immediate medical attention. 5. FIRE FIGHTING MEASURES Flammability: May support combustion in a serious fire. Extinguishing Media: Foam, dry powder, CO2, sand or earth. Products of Combustion:See Section 10 6. ACCIDENTAL RELEASE MEASURES Always prevent entry into drains or watercourses. Spillages can be slippery. Soak in absorbent granules or sand. Disposal of Spillage: Via authorised waste disposal contractor. Disposal must be in accordance with the Environmental Protection Act 1990. 7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes with undiluted product, by wearing goggles or face mask and oil impervious gloves. Storage: Store in dry conditions between 0 and 40o C. 8. EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits: The product does not have an established Occupational Exposure Standard (OES). Eyes: Wear goggles or face mask when handling undiluted product. Skin: Wear oil impervious gloves when handling undiluted product. Change heavily contaminated clothing and overalls as soon as possible. Inhalation: Respiratory protection is not normally required. Industrial Hygiene: Wash hands after use, before eating, drinking or smoking and before and after using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour: Viscous Liquid with Mild Odour Specific Gravity @ 20o C : 1.160 pH(5%): 10.0 - 11.0 Solubility in water: Miscible

Pg. 2 of 2 REV 1 / 96

Flash Point (C): >100 Autoignition Temp.: >150 Flammability limits in air: Not Known Vapour Pressure @ 20o C: Not known Vapour Density: Not Known Boiling Point (C): >100 Melting Point (C): <0 Viscosity @ 40 o C (cSt) 150 - 300 10. STABILITY AND REACTIVITY Stability: This product is stable and unlikely to react in a hazardous manner under normal conditions. Conditions to Avoid: Extremes of temperature. Store between 0 and 40oC. Materials to Avoid: Strong oxidising agents. Decomposition Products:Formaldehyde, amine and oxides of nitrogen may be released at high temperatures. 11. TOXICOLOGICAL INFORMATION Eyes: Eye contact with undiluted product may cause moderate irritation and stinging. there maybe a potential to cause corneal injury if treatment is not prompt. Dilute emulsions are expected to cause only slight transient irritation or redness. Skin: The undiluted product in occasional skin contact is unlikely to cause any significant reaction. Prolonged contact with undiluted product may cause defatting of skin barrier leading to cracking and soreness. Inhalation: The product is unlikely to present any significant inhalation hazard at ambient temperatures. High temperatures or atomising systems may lead to generation of vapours, mists or fumes which could cause irritation to eyes or respiratory tract. Ingestion: The product has a moderate order of oral toxicity; ingestion is expected to produce intense irritation to mouth, throat and digestive tract. Swallowing significant quantities may cause discomfort, nausea and diarrhoea. 12. ECOLOGICAL INFORMATION Water: This product is readily biodegradable. Nitrosamines may be formed with the nitrogen content in the water or in the presence of nitrites. Soil: Small quantities will be absorbed in the upper soil layers where biodegredation may take place. 13. DISPOSAL CONSIDERATIONS All means of disposal should comply with local regulations and the Environmental Protection Act 1990. Dispose of the product and containers carefully and responsibly. Do not allow product to contaminate ponds, water courses, soil or drains. Do not dispose of undiluted product or untreated emulsions down the drains. Dispose of via an authorised person / licensed waste disposal contractor. 14. TRANSPORT INFORMATION Classification: Harmful substance n.o.s. UN Number: 2810 Marine Pollutant: No. Packaging Group: 111 15. REGULATORY INFORMATION EEC Classification: Skin and Eye Irritant (Xi) for supply. Risk Phrases: R36/38 Irritating to eyes and skin. Safety Phrases: S25: Avoid contact with eyes. S26: In case of contact with eyes, rinse Immediately with plenty of water and seek medical advice. Note: The above classification applies to the undiluted product as supplied. It does not apply when the product is diluted for use at the correct operating strength. 16. OTHER INFORMATION (generally the usage concentration should be designed to give a level of between 0.04 and 0.1% (400 - 1000 ppm) in metalworking fluid emulsions. Exposure to excessive concentrations may give rise to skin irritation and occasionally sensitisation. Due to the potential problems that may be encountered when using at too high or too low a concentration, it is advised that our recommendation for each individual requirement is obtained if there is any doubt about the appropriate usage concentration. ADDITIONAL INFORMATION Legislation: Chemical (Hazards, Information and Packaging) regulations 1993. Environmental Protection Act 1990. Control of Pollution Act 1974. The Environmental Protection (Duty of Care) Regulations 1991. HSE Publications: EH 26 Occupational Skin Diseases. Health and Safety Precautions. EH 40 Occupational Exposure Limits. EH 62 Metalworking Fluids - Health Precautions.

Product Name

Application

Supplier PROMANEX (WATER TREATMENT AND HYGIENE SERVICES)

PO BOX 11, WINNINGTON AVENUE,

NORTHWICH, CHESHIRE, CW8 4DX.

Tel: 0845 467 88 87 Fax: 01606 781 880

Email: [email protected]

RM

120C

RM

33C

RM

116C

RM

500C

R36/38

FA

6F

A6

FA

6F

A1

0

SDS for CWO 77-V Last updated: Date issued:

2. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical name CAS No % (active) EINECS-No. Symbols R-phrases

SAFETY DATA SHEET

1. IDENTIFICATION OF SUBSTANCE / PREPARATION AND COMPANY

CWO 77-V

A liquid biocide for the control of bacteria, fungi and algae in open recirculating cooling systems,

evaporative condnsers and closed systems.

C-Corrosive, R35, , , , 215-185-5

231-668-3 C-Corrosive, R31, R34, , , Sodium hypochlorite 7681-52-9 1 - 10%

Caustic soda 001310-73-2 1 - 5%

Sodium bromide 7647-15-6 1 - 10%

, , , , ,

Sodium sulphamate 13845-18-6 1 - 10% 237-572-8

Nil hazard, , , , ,

Nil hazard, , , , ,

, , , , ,

3. HAZARDS IDENTIFICATION

]Physical / chemical hazards: Corrosive

Environmental Hazards: Nil

Human health hazards: Irritating to eyes and skin

4. FIRST AID MEASURES

Ingestion: Irritating to mouth and gastrointestinal tract.

Drink plenty of water. Do not induce vomiting.

Inhalation: Irritating to respiratory tract

Remove to fresh air. Obtain medical advice if symptoms persist.

Skin contact: Irritation and redness of skin. Soreness on prolonged contact.

Wash with soap and water. Remove contaminated clothing for washing. Consult doctor in accordance with symptoms.

Eye contact: Severe irritation. Prolonged contact may cause damage.

Immediately rinse eye with sterile water for 20 minutes. Seek medical advice.

Page 1 of 4 24.3.2010 1-Dec-10

FA

1

5. FIRE FIGHTING MEASURES

Flammability:

Ex2 Extinguishing media:

EX

1 Unsuitable extinguishing media:

D5 Hazardous decompositions:

P1 Protective equipment:

6. ACCIDENTAL RELEASE MEASURES

SP

1E

P2

CU

2

7. HANDLING AND STORAGE

H2 Handling:

S2 Storage:

Shelf life:

PK

3 Suitable packaging:

PK

2 Unsuitable packaging:

Exposure limits:

mg/m3

mg/m3

EN

2 Engineering measures:

RP

2 Respiratory protection:

SH

B1

Skin, hand and body protection:

EP

1 Eye protection:


Notes to

doctor:

None

Non-flammable

Water spray jet, extinguishing powder or foam, carbon dioxide .

None

Thermal decomposition will evolve bromine which is toxic.

Protective clothing and self-contained breathing apparatus.

Personal precautions: Wear full protective equipment - gloves, eye/face protection and overalls. Ensure sufficient air

supply.

Environmental precautions: Do not allow to enter water courses.

Methods of clean up: Small spillages can be flushed to foul drain. Larger spillages should be contained, adsorbed onto

inert material and collected into suitable plastic containers. Clearly label. Disposal should be

handled by a licensed contractor in accordance with Waste Disposal regulations.

No special precautions. Before eating, drinking or smoking wash hands with soap and water.

Store above 10 C. Do not allow to freeze. Ensure that the container is firmly secure when not in

use.

>12 months

Polyethylene, polypropylene and stainless steel containers.

Metals and alloys.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Substance: Chlorine

EH40 Long term WEL (8 Hr): 0.5 ppm 1.5

Short term WEL (15 min): 1 ppm 3

None

Not applicable.

Overalls, boots and rubber gloves.

Chemical goggles or face shield.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Solution Boiling point (C): >100 C

Colour: Orange solution Decomposition temp (C): Decomposes on heating

Odour: Chlorine Specific Gravity: 1.324

Molecular weight: Solubility: Completely miscible

pH: >11 Flash point (C):

Page 2 of 4 24.3.2010 1-Dec-10

ST

2D

C7

CT

A1

MT

A2

HR

6D

P5

MO

D2

PK

2


10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions May crystalise below 0 C.

Thermal decomposition: Releases bromine.

Conditions to avoid: High temperatures and evaporation of water.

Materials to avoid: Normally unreactive.

Hazardous reactions: Reacts with acids to release bromine.

Decomposition products: Bromine

11. TOXICOLOGICAL INFORMATION (of hazardous constituents)

Acute toxicity: Oral; Sodium hypochlorite Corrosive

Dermal: Sodium hypochlorite Corrosive

Inhalation: Exposure to a mist or spray causes irritation of mouth, throat and digestive tract.

Eye: Corrosive

Other data:

12. ECOLOGICAL INFORMATION

Biodegradability

and persistence:

Degrades rapidly in soil or water.

Ecotoxic effects: Toxic to aquatic organisms, fish and wildlife.

Other data: The product is subtantially removed in biological treatment processes.

13. DISPOSAL CONSIDERATIONS

Methods of disposal: Small quantities can be disposed of via a foul drain. Larger quantities should be handled by a

licensed contractor in accordance with Waste Disposal Regulations.

Packaging disposal: Return empty containers to the supplier for recycling or destroy by cutting up or by

incineration. Do not use for potable water.

14. TRANSPORT INFORMATION

UN No.: 3266 Proper shipping name: PROPER SHIPPING NAME - CORROSIVE LIQUID, BASIC,

INORGANIC, N.O.S. (Contains sodium hydroxide, sodium

hypochlorite)

Mode Regulation Class Packing group Ems No. Stowage Code Subsidiary risk

Road/Rail European - ADR/RID 8 II

Sea IMO / IMDG

Air ICAO / IATA

Page 3 of 4 24.3.2010 1-Dec-10

Risk Phrases

Safety phrases

References:


15. REGULATORY INFORMATION (Classification and labelling according to UK CHIP Regs/EEC Directive 88/379/EEC)

]R34 Causes burns

R31 Contact with acids liberates toxic gas

S28 After contact with skin, wash immediately with plenty of water.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

S36/37/39 Wear suitable protective clothing gloves and eye/face protection

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

16.OTHER INFORMATION

The information contained in this SDS does not constitute an assessment of work place risks. The customer should

undertake a formal COSHH assessment which should ensure that employees are aware of the hazards / precautions

detailed in the SDS. The COSHH assessment should ensure that the recommended safety equipment is available

and where applicable, that the exposure limits detailed in section 8 are not being exceeded.

It is believed to be correct but does not purport to be all-inclusive and shall therefore be used only as a guide.

PROMANEX (WATER TREATMENT AND HYGIENE SERVICES) implies no warranty with respect to the quality,

specification or the suitability of the product. The client/user must completely satisfy themselves that the product is

entirely suitable for the intended purpose.

In no event shall PROMANEX (WATER TREATMENT AND HYGIENE SERVICES) be held liable for any injury, loss

or damage, to persons, plant or equipment or loss of production/sales resulting from its use or storage.

The above information is based on current knowledge of the product at the time of publication and is given in good

faith.

The Carriage of Goods by Road and Rail Regulations.

The Control of Substances Hazardous to Health Regulations (COSHH).

The Chemicals Hazard Information and Packaging Regulations (CHIP).

1-Dec-10Page 4 of 4 24.3.2010

Product Name

Application

Supplier PROMANEX (WATER TREATMENT AND HYGIENE SERVICES)



Tel: 0845 467 88 87 Fax: 01606 781 880


RM

20C

RM

30C

RM

108C

RM

97C

RM

75C

RM

15C

R36/38

FA

10

FA

1F

A6

FA

10

SDS for CWI 60-V Last updated: Date issued:

2. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical name CAS No % (active) EINECS-No. Symbols R-phrases

SAFETY DATA SHEET

1. IDENTIFICATION OF SUBSTANCE / PREPARATION AND COMPANY

CWI 60-V

An environmentally friendly corrosion and scale inhibitor for open evaporative cooling systems and

evaporative condensers.

C-Corrosive, R22, R35, , ,

220-552-8 C-Corrosive, R34, , , , 1-Hydroxy ethylidene-1,1-diphosphonic acid 2809-21-4 1 - 5%

Potassium hydroxide 001310-58-3 1 - 5%

Potassium silicate (K120) 1312-76-1 10 - 20% 215-199-1

Nil hazard, , , , ,

NTA (3Na) 139-13-9 1 - 5% 205-355-7

Xi-Irritant, R36/38, , , ,

Xi-Irritant, R36/38, , , ,

Xn-Harmful, R22, R36/37/38, , ,

Potassium pyrophosphate 7320-34-5

Benzotriazole 95-14-7 0.1 - 1% 202-394-1

1 - 5% 230-785-7

3. HAZARDS IDENTIFICATION

cPhysical / chemical hazards: Irritant

Environmental Hazards: Localised pH effects only.

Human health hazards: Irritating to eyes and skin

4. FIRST AID MEASURES

Ingestion: Severely irritating to mouth and gastrointestinal tract.

Wash out mouth with water then drink plenty of water. Do not induce vomiting. Consult doctor and show this datasheet,

Inhalation: No known ill effects

Not applicable

Skin contact: Irritation and redness of skin. Soreness on prolonged contact.

Wash with soap and water. Remove contaminated clothing for washing. Consult doctor in accordance with symptoms.

Eye contact: Severe irritation. Prolonged contact may cause damage.

Immediately rinse eye with sterile water for 20 minutes. Seek medical advice.

Page 1 of 4 25.10.2006 1-Feb-11

FA

1

5. FIRE FIGHTING MEASURES

Flammability:

Ex2 Extinguishing media:

EX

1 Unsuitable extinguishing media:

D10 Hazardous decompositions:

P1 Protective equipment:

6. ACCIDENTAL RELEASE MEASURES

SP

1E

P2

CU

3

7. HANDLING AND STORAGE

H3 Handling:

S2 Storage:

Shelf life:

PK

3 Suitable packaging:

PK

2 Unsuitable packaging:

Exposure limits:

mg/m3

mg/m3

EN

2 Engineering measures:

RP

2 Respiratory protection:

SH

B1

Skin, hand and body protection:

EP

1 Eye protection:


Notes to

doctor:

None

Non-flammable

Water spray jet, extinguishing powder or foam, carbon dioxide .

None

Decomposition generates oxides of carbon (CO and CO2) and sulphur (SO2).

Protective clothing and self-contained breathing apparatus.

Personal precautions: Wear full protective equipment - gloves, eye/face protection and overalls. Ensure sufficient air

supply.

Environmental precautions: Do not allow to enter water courses.

Methods of clean up: Small spillages can be flushed to drain with additional water. Large spillages should be contained.

Dilute and neutralise to pH 6-10 with a convenient acid before discharge to drain

Avoid direct contact with product. Before eating, drinking or smoking wash hands with soap and

water.

Store above 10 C. Do not allow to freeze. Ensure that the container is firmly secure when not in

use.

>12 months

Polyethylene, polypropylene and stainless steel containers.

Metals and alloys.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Substance: No materials present that are listed in EH40/2005.

Long term WEL (8 Hr): ppm

Short term WEL (15 min): ppm

None

Not applicable.

Overalls, boots and rubber gloves.

Chemical goggles or face shield.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Solution Boiling point (C): >100

Colour: Clear solution Decomposition temp (C): Decomposes on heating

Odour: Slight Specific Gravity: 1.277

Molecular weight: Solubility: Completely miscible

pH: 12 Flash point (C):

Page 2 of 4 25.10.2006 1-Feb-11

ST

2D

C12

CT

A1

MT

A3

HR

3D

P10

MO

D2

PK

2


10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions May crystalise below 0 C.

Thermal decomposition: Decomposition generates oxides of carbon (CO and CO2) and sulphur (SO2).

Conditions to avoid: High temperatures and evaporation of water.

Materials to avoid: Soft metals (aluminium, zinc etc) and strong acids.

Hazardous reactions: No known hazardous reactions.

Decomposition products: Decomposition generates oxides of carbon (CO and CO2) and sulphur (SO2).

11. TOXICOLOGICAL INFORMATION (of hazardous constituents)

Acute toxicity: Oral; Irritant

Dermal: Irritant

Inhalation: Nil hazard

Eye: Irritant

Other data:

12. ECOLOGICAL INFORMATION

Biodegradability

and persistence:

Fully biodegradable.

Ecotoxic effects: The polymers will contribute to the BOD and COD of the receiving waters - no data available.

Other data: Short term harm to equatic environment through pH effects.

13. DISPOSAL CONSIDERATIONS

Methods of disposal: Small quantities can be disposed of via a foul drain. Larger quantities should be handled by a

licensed contractor in accordance with Waste Disposal Regulations.

Packaging disposal: Return empty containers to the supplier for recycling or destroy by cutting up or by

incineration. Do not use for potable water.

14. TRANSPORT INFORMATION

UN No.: N/A Proper shipping name: PROPER SHIPPING NAME - Nil hazard for transport

Mode Regulation Class Packing group Ems No. Stowage Code Subsidiary risk

Road/Rail European - ADR/RID N/A N/A

Sea IMO / IMDG

Air ICAO / IATA

Page 3 of 4 25.10.2006 1-Feb-11

Risk Phrases

Safety phrases

References:


15. REGULATORY INFORMATION (Classification and labelling according to UK CHIP Regs/EEC Directive 88/379/EEC)

cR36/38 Irritating to eyes and skin

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice

S37/39 Wear suitable gloves and eye/face protection

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

16.OTHER INFORMATION

The information contained in this SDS does not constitute an assessment of work place risks. The customer should

undertake a formal COSHH assessment which should ensure that employees are aware of the hazards / precautions

detailed in the SDS. The COSHH assessment should ensure that the recommended safety equipment is available

and where applicable, that the exposure limits detailed in section 8 are not being exceeded.

It is believed to be correct but does not purport to be all-inclusive and shall therefore be used only as a guide.

PROMANEX (WATER TREATMENT AND HYGIENE SERVICES) implies no warranty with respect to the quality,

specification or the suitability of the product. The client/user must completely satisfy themselves that the product is

entirely suitable for the intended purpose.

In no event shall PROMANEX (WATER TREATMENT AND HYGIENE SERVICES) be held liable for any injury, loss

or damage, to persons, plant or equipment or loss of production/sales resulting from its use or storage.

The above information is based on current knowledge of the product at the time of publication and is given in good

faith.

The Carriage of Goods by Road and Rail Regulations.

The Control of Substances Hazardous to Health Regulations (COSHH).

The Chemicals Hazard Information and Packaging Regulations (CHIP).

1-Feb-11Page 4 of 4 25.10.2006

PENNINE LUBRICANTS, SHEFFIELD TEL:0114 2852987

Product Data Sheet

MULTISOL G

Product Code:AGC. Product Description Pennine Multisol G is a medium oil content, high dilution, semi synthetic soluble cutting fluid. When mixed with water it forms a biostable emulsion that is highly resistant to bacterial and fungal degradation giving freedom from bad smells and slimy deposits. It is a low odour, non-phenolic, nitrite free product based on solvent refined mineral oils giving a translucent green emulsion.

Applications Multisol G is recommended for general machine shop operations including CNC machines where extended tool life and a translucent product are desirable. It is suitable for use with most materials including medium tensile steels, aluminium and it's alloys and yellow metals.

Recommended Concentrations in Water The recommended user dilution with water is between 3 – 10 % depending upon the severity of the operation.

Typical Test Data Density @ 15oC 1.01 pH (1:25 dilution) 9.3 Herbert Corrosion Test IP125 1:90 no rust Breakpoint Corrosion IP287 1:70 Conversion Factor 1.37

Availability Pennine Multisol G is available in 205 litre barrels, 25 litre drums and 5 litre plastic bottles.

Storage Barrels of lubricant should always be stored in such a way that will prevent the ingress of water when stored in the open. Protect from frost.

Health and Safety Please refer to the relevant Health and Safety Data Sheet, a copy of which is freely available to all our customers. Data represented is typical of that obtained with normal production tolerances and does not constitute a specification. The policy of Pennine Lubricants is one of continual improvement, we therefore reserve the right to change specifications without notice.



MULTISOL SEMI-SYNTHETIC FLUIDS

PENNINE LUBRICANTS UNIT 35, NUTWOOD TRADING ESTATE LIMESTONE COTTAGE LANE SHEFFIELD S6 1NL TEL: 0114 2852987

FAX: 0114 2852988

PRODUCT NAME: MULTISOL G, SS, EPG PRODUCT CODE: AGC, AGE, AGH APPLICATION: Metalworking fluid to be used diluted with water prior to use.

2. COMPOSITION / INFORMATION ON INGREDIENTS General: This product is based on highly refined mineral oil, emulsifiers and additives. Hazardous Ingredients: Diethanolamine condensation product. 15 - 25% TWA 3ppm

3. HAZARD IDENTIFICATION Health and Safety Hazards: Eye contact with undiluted product may cause irritation. The undiluted product may be irritating to the skin, especially if the material is not removed promptly. Special Hazards of During use, metalworking emulsions may become contaminated with metal particles and Product after use: metal salts, other lubricants and microbiological contaminants. These may increase the irritancy of emulsions, and in some cases (e.g. contamination by chromium, cobalt and nickel) may be capable of inducing allergic reactions.

4. FIRST AID MEASURES Eyes: Immediately wash eye thoroughly with plenty of clean water. For contact with undiluted fluid, obtain prompt medical attention. For contact with diluted product if irritation persists. Skin: Following contact with the undiluted product, wash thoroughly with soap and water without delay. Remove heavily contaminated clothing. wash contaminated clothing before re-use. If irritation persists, obtain medical advice. Ingestion: DO NOT INDUCE VOMITING. Wash out mouth with water and obtain medical attention. Treat symptomatically. If aspiration is suspected, obtain immediate medical attention. Pressure Injection: Always obtain immediate medical attention.

5. FIRE FIGHTING MEASURES Flammability: May support combustion in a serious fire. Extinguishing Media: Foam, dry powder, CO2, sand or earth. Products of Combustion:See Section 10

6. ACCIDENTAL RELEASE MEASURES Always prevent entry into drains or watercourses. Spillages can be slippery. Small Spills: Soak in absorbent granules or sand. Large Spills: Bund using absorbent granules, sand or earth and reclaim bulk liquid. Disposal of Spillage: Via authorised waste disposal contractor. Disposal must be in accordance with the Environmental Protection Act 1990.

7. HANDLING AND STORAGE Handling: Avoid contact with skin and eyes with undiluted product, by wearing goggles or facemask and oil impervious gloves. Storage: Store in dry conditions between 0 and 40o C.

8. EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits: As for mineral oil mist: 5mg/m3 (8hr TWA) Eyes: Wear goggles or face mask when handling undiluted product. Skin: Wear oil impervious gloves when handling undiluted product. Change heavily contaminated clothing and overalls as soon as possible. Inhalation: Respiratory protection is not normally required. Industrial Hygiene: Wash hands after use, before eating, drinking or smoking and before and after using the toilet.


9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour: Viscous Liquid with Characteristic Odour Specific Gravity @ 20o C : 1.005 pH(5%): 9.0 - 9.4 Solubility in water: Emulsifyable Flash Point (C): >100 Autoignition Temp.: >150 Boiling Point (C): >100 Melting Point (C): <0 Viscosity @ 40 o C (cSt) 50 - 150

10. STABILITY AND REACTIVITY Stability: This product is stable and unlikely to react in a hazardous manner in normal conditions of use. Conditions to Avoid: Extremes of temperature. Store between 0 and 40oC. Materials to Avoid: Strong oxidising agents. Decomposition Products:Oxides of carbon, water and traces of other compounds some may contain chlorine.

11. TOXICOLOGICAL INFORMATION Eyes: Eye contact with undiluted product may cause moderate irritation and stinging. there maybe a potential to cause corneal injury if treatment is not prompt. Dilute emulsions are expected to cause only slight transient irritation or redness. Skin: The undiluted product in occasional skin contact is unlikely to cause any significant reaction. Prolonged contact with undiluted product may cause defatting of skin barrier leading to cracking and soreness. Inhalation: The product is unlikely to present any significant inhalation hazard at ambient temperatures. High temperatures or atomising systems may lead to generation of vapours, mists or fumes which could cause irritation to eyes or respiratory tract. Repeated excessive exposures to oil mists may cause respiratory damage and a condition resembling pneumonia. Ingestion: The product has a low order of acute oral toxicity; ingestion is not regarded as a significant health hazard likely to arise in normal use. Swallowing significant quantities may cause discomfort, nausea and diarrhoea. Aspiration: Aspiration into the lungs caused by vomiting following ingestion can be hazardous with possible resultant chemically induced pneumonia.

12. ECOLOGICAL INFORMATION Water: The individual components range from readily to poorly biodegradable. The components are not expected to be highly toxic to aquatic life. If released to water, the product may deplete the oxygen supply to bottom dwelling organisms. Soil: Small quantities will be absorbed in the upper soil layers where biodegredation may take place.

13. DISPOSAL CONSIDERATIONS All means of disposal should comply with local regulations and the Environmental Protection Act 1990. Dispose of the product and containers carefully and responsibly. Do not allow product to contaminate ponds, water courses, soil or drains.Dispose of via an authorised person / licensed waste disposal contractor.

14. TRANSPORT INFORMATION Classification: Not classified as dangerous for conveyance. UN Number: Not Applicable.

15. REGULATORY INFORMATION

16. OTHER INFORMATION (1) Other materials should not be added to the product or emulsions unless recommended. (2) Emulsions should be maintained at the recommended concentrations in order to minimise any health hazards. (3) Minimise tramp oil and contamination; remove metallic swarf or other debris from machines at frequent intervals. (4) During machining, emulsions may become contaminated with certain metals which are present in the workpiece or tools. These may solubilise in the emulsion. Some of these contaminants, such as chromium, nickel or cobalt may induce allergic reactions. ADDITIONAL INFORMATION Legislation: Chemical (Hazards, Information and Packaging) regulations 1993. Environmental Protection Act 1990. Control of Pollution Act 1974. The Environmental Protection (Duty of Care) Regulations 1991. HSE Publications: EH 26 Occupational Skin Diseases. Health and Safety Precautions. EH 40 Occupational Exposure Limits. EH 58 The Carcinogenicity of Mineral Oils. EH 62 Metalworking Fluids - Health Precautions. SHW 397 Effects of Mineral Oil on the Skin

MATERIAL SAFETY DATA SHEET PRODUCT

NALCO STABREX® ST40

EMERGENCY TELEPHONE NUMBER(S) See section 16, for Emergency Telephone Numbers.

NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • 0031 71 5241100

1 / 11

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : NALCO STABREX® ST40 APPLICATION : BIOCIDE COMPANY IDENTIFICATION : NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, The Netherlands EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers. Date issued : 16.09.2005 Version Number : 3.2 COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. +31 71 5241 100 NALCO AB (SE) +46 (0)8-50074000 NALCO ITALIANA S.R.L.(I) +39 06-542971 NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO Kft. (HU) +36 (0)1 471 91 81 NALCO APPLIED SERVICES OF EUROPE BV

+31 (0)73 6456980 NALCO LIMITED +44 (0)1606 74488

NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 NALCO NETHERLANDS B.V. +31 (0)13-5952200 NALCO DANMARK A/S +45-48195800 NALCO NORGE AS (NO) +47 51 96 36 00 NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 NALCO ÖSTERREICH Ges.m.b.H.

(A) + 43(0)1 27026350

NALCO ESPAÑOLA S.A. (E) +34 93-4095555 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750 NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO PORTUGUESA LDA. (P) +351 214130996 NALCO FRANCE SAS +33 (0)3 20 11 70 00 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38 2. COMPOSITION/INFORMATION ON INGREDIENTS This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Hazardous Substance(s) EINECS / ELINCS NO

SYMBOL R-PHRASES / NOTAS

% (w/w)

Sodium Hydroxide 215-185-5 C R35 1 - < 5 Sodium Hypochlorite 231-668-3 C, N R31, R34, R50

Nota B 0.0001 - 10

Refer to Section 16 for descriptions of relevant risk phrases and Notas. 3. HAZARDS IDENTIFICATION HAZARD CLASSIFICATION : This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Contact with acids liberates toxic gas. Causes burns. HUMAN HEALTH HAZARDS - ACUTE : INHALATION : Corrosive to respiratory system.





2 / 11

SKIN CONTACT : Corrosive; causes permanent skin damage. EYE CONTACT : Corrosive. Will cause eye burns and permanent tissue damage. INGESTION : Corrosive, causes burns to gastro-intestinal tract. Nausea, vomiting and stomach pain may occur. In severe cases blood may be vomited. May cause nausea and vomiting. HUMAN HEALTH HAZARDS - CHRONIC : No adverse effects expected other than those mentioned above. ENVIRONMENTAL HAZARDS : Toxic to aquatic organisms. PHYSICAL AND CHEMICAL HAZARDS : Contact with acids liberates toxic gas. 4. FIRST AID MEASURES INHALATION : Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. SKIN CONTACT : Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use. EYE CONTACT : Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open. INGESTION : Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. 5. FIRE FIGHTING MEASURES FLASH POINT : > 200 F/ > 93.3 C EXTINGUISHING MEDIA : Not expected to burn. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARD : May evolve hydrogen bromide and bromine under fire conditions. May evolve HCl under fire conditions. May evolve chlorine under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.





3 / 11

6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP : Contain and absorb with sand or vermiculite and mix well. Collect up and remove to a safe place until disposal. Wash site of spillage thoroughly with water. Assistance can be obtained from waste disposal companies. Do not clean up spills with sawdust, cotton waste or other combustible absorbent materials. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : This product may pose a risk to the aquatic ecosystem if released. Prevent material from entering sewers or waterways. If drains, streams, soil or sewers become contaminated, notify local authority. 7. HANDLING AND STORAGE HANDLING : Do not breathe vapors/gases/dust. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Do not mix with acids. Do not mix with any bleaches or oxidizing agents. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). STORAGE CONDITIONS : Store the containers tightly closed. Store separately from acids. Protect product from freezing. Store in a cool well ventilated area away from direct sunlight. Containers require venting bungs to avoid over pressure. SUITABLE CONSTRUCTION MATERIAL : Polyethylene, Polypropylene, Teflon, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use. UNSUITABLE CONSTRUCTION MATERIAL : This product is corrosive to mild steel., Brass, Stainless steel, Buna-N, EPDM SPECIFIC USE(S) : BIOCIDE For specific dosages and customized applications please contact your representative. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source Substance(s) Category: ppm mg/m3





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__AUSTRIA Sodium Hydroxide (Total dust.) MAK 2 BELGIUM Sodium Hydroxide Ceiling 2 DENMARK Sodium Hydroxide LOFT 2 FINLAND Sodium Hydroxide HTP 8H 2 FRANCE Sodium Hydroxide VME 2 GERMANY Sodium Hydroxide (Inhalable fraction.) MAK 2 IRELAND Sodium Hydroxide STEL 2 ITALY Sodium Hydroxide Ceiling 2 NETHERLANDS Sodium Hydroxide MAC-C 2 NORWAY Sodium Hydroxide CEIL 2 SPAIN Sodium Hydroxide VLA-EC 2 SWEDEN Sodium Hydroxide TGV 2 SWITZERLAND Sodium Hydroxide (Inhalable dust) TWA 2 STEL 2 UNITED KINGDOM Sodium Hydroxide STEL 2 * A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes. MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant Sodium Hydroxide US NIOSH: 7401 Titration PTFE filter ENGINEERING MEASURES : Use general ventilation with local exhaust ventilation. Use a closed dosing system. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: B-P The applicable European standard can be found in EN 141, EN 143 and EN 371. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection.





5 / 11

HAND PROTECTION : When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from Nitrile Viton Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : A full slicker suit is recommended if gross exposure is possible. Wear impervious apron and boots. The applicable European standard can be found in EN 345. EYE PROTECTION : Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Clear Light yellow ODOR Pungent FLASH POINT : > 200 F/ > 93.3 C SPECIFIC GRAVITY 1.32 - 1.36 (25.0 °C) SOLUBILITY IN WATER Complete pH (100.0 %) 13.0 VISCOSITY 7 cps FREEZING POINT -8.2 °C VAPOR PRESSURE 1.03 kPa (77.0 °C) Note: These physical properties are typical values for this product and are subject to change. 10. STABILITY AND REACTIVITY STABILITY : Stable under normal conditions. Room temperature degradation products are small amounts of nitrogen, sodium bromide, and sodium sulfate. Combustion may include nitrogen and sulfuric acid. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID : Extremes of temperature Heat and light which can accelerate decomposition. Freezing temperatures.





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MATERIALS TO AVOID : Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors., Contact with organic materials (e.g. rags, sawdust, hydrocarbon oils or solvents) and avoid reducing agents (e.g. hydrazine, sulfites, sulfide, aluminum or magnesium dust) which can generate heat, fires, explosions and the release of toxic fumes., Do not mix with any sodium hypochlorite or bleach product. Resulting mixture will result in a violent exothermic reaction releasing large amounts of nitrogen gas and liquid sulfuric acid., Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Chlorine gas, HCl, Bromine, Hydrogen bromide, Oxides of nitrogen 11. TOXICOLOGICAL INFORMATION The following results are for a similar product. ACUTE ORAL TOXICITY : Species LD50 Test Descriptor Rat > 5,000 mg/kg Similar Product PRIMARY SKIN IRRITATION : Draize Score Test Descriptor 7.9 / 8.0 Similar Product SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). For additional information on the hazard of the preparation, please consult section 3 and 12. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : The following results are for the product. ACUTE FISH RESULTS : Species Exposure LC50 Method Test Descriptor Rainbow Trout 96 hrs 4.5 mg/l Product Sheepshead Minnow

96 hrs 16 mg/l Product

Fathead Minnow 96 hrs 8.3 mg/l Product ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 EC50 Method Test Descriptor Daphnia magna 48 hrs 4.2 mg/l 4.2 mg/l Product





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Mysid Shrimp (Mysidopsis bahia)

96 hrs 27 mg/l Product

Ceriodaphnia dubia

48 hrs 1.6 mg/l Product

AQUATIC PLANT RESULTS : Species Exposure EC50/LC50 Method Test Descriptor Green Algae (Selenastrum capricornutum)

72 hrs 3.66 mg/l Product

CHRONIC INVERTEBRATE RESULTS : Species Test Type EC25 / IC25 End Point Method Test Descriptor Ceriodaphnia dubia

3 Brood 15.6 mg/l Reproduction

Product

ADDITIONAL ECOLOGICAL DATA: AOX information: Product contains no organic halogens. MOBILITY : The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages;

Air Water Soil/Sediment <5% 30 - 50% 30 - 50%

The portion in water is expected to be soluble or dispersible. PERSISTENCY AND DEGRADATION : Biological Oxygen Demand (BOD) : This material is an oxidizing biocide and is not expected to persist in the environment. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. 13. DISPOSAL CONSIDERATIONS If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product will generate an ash if burned. It can be burned directly in appropriate equipment. This product is NOT suitable for disposal via municipal sewers, drains, natural streams or rivers.





8 / 11

Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 03* - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code. 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT

Proper Shipping Name : CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. Technical Name(s) : Sodium Hydroxide, Sodium Hypochlorite UN/ID No : UN 3266 Hazard Class - Primary : 8 Packing Group : II ADR/RID H.I.n. : 80 CLASSIFICATION CODE : C5

AIR TRANSPORT (ICAO/IATA)

Proper Shipping Name : CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. Technical Name(s) : Sodium Hydroxide, Sodium Hypochlorite UN/ID No : UN 3266 Hazard Class - Primary : 8 Packing Group : II IATA Cargo Packing Instructions : 812 IATA Cargo Aircraft Limit : 30 L (Max net quantity per package) IATA Passenger Packing Instructions : Y808 / 808 IATA Passenger Aircraft Limit : 0.5 L / 1 L

MARINE TRANSPORT (IMDG/IMO)

Proper Shipping Name : CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. Technical Name(s) : Sodium Hydroxide, Sodium Hypochlorite UN/ID No : UN 3266 Hazard Class - Primary : 8 Packing Group : II

OTHER APPLICABLE INFORMATION

CEFIC TREMCARD REFERENCE : 80GC5-II+III EMERGENCY ACTION CODE : 2X

15. REGULATORY INFORMATION CLASSIFICATION AND LABELLING : GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations Directive 1999/45/EC.





9 / 11

HAZARD SYMBOLS

CORROSIVE Contains:..Sodium Hydroxide Sodium Hypochlorite RISK PHRASES R31 - Contact with acids liberates toxic gas. R34 - Causes burns. SAFETY PHRASES S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). NATIONAL REGULATIONS FRANCE Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s): 65 NATIONAL REGULATIONS GERMANY WGK 2 (Annex 4) NATIONAL REGULATIONS SWITZERLAND BAGT-Nr: 681063 Toxic class: 3 BIOCIDE REGISTRATION NUMBER Spain 00-100-02075 INTERNATIONAL CHEMICAL CONTROL LAWS UNITED STATES The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations. EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.





10 / 11

JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI). 16. OTHER INFORMATION RELEVANT RISK PHRASES AND NOTAS R31 - Contact with acids liberates toxic gas. R34 - Causes burns. R35 - Causes severe burns. R50 - Very toxic to aquatic organisms. - REVISED INFORMATION: section(s): - 2 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. EMERGENCY TELEPHONE NUMBER(S) Trans-European +32-(0)3-575-5555 Belgium / Luxembourg +32-(0)3-575-0330 Czech Republic +420-602-669421 Denmark +47-22-33-69-99 Finland +358-(0)9-4711 France / French Switzerland +33-(0)6-11-07-32-81 Germany / Austria / German Switzerland +49-(0)6232-130128 Hungary +36-30-9-506-447 Italy / Italian Switzerland +39-333-210-7947 The Netherlands +32-(0)3-575-0330 Norway +47-22-33-69-99 Poland +48-(0)601-66-2626 Portugal +351-91-911-1399 Russia / Belarus +7-812-449-0474 Saudi Arabia +966-(3)847-1515 Slovak Republic +421-(0)905-585-938 Spain +34-977-551577 Sweden +47-22-33-69-99 UAE +44-(0)7071-223-738 UK and Republic of Ireland +44-(0)7071-223-738 Nalfleet International +32-(0)3-575-5555 POISON CONTROL CENTER TELEPHONE NUMBERS Belgium +32-70-245245 Czech Republic +420 224 91 92 93 France +33-(0)145-42-59-59 ORFILA Slovak Republic +421 (0)2 5477 4166





11 / 11

Prepared By : SHE Department Date issued : 16.09.2005 Version Number : 3.2 Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand

SAFETY DATA SHEET PRODUCT

3D TRASAR® 3DT289


NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100

For additional copies of an MSDS visit www.nalco.com and request access 1 / 12

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

PRODUCT NAME : 3D TRASAR® 3DT289 APPLICATION : COOLING WATER TREATMENT COMPANY IDENTIFICATION : NALCO EUROPE B.V. Postbus 627 2300 AP Leiden, The Netherlands EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers. Date issued : 09.01.2009 Version Number : 1.10 COMPANY CONTACT TELEPHONE NUMBERS. NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00 NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) PRZEMYSLOWA 55

PL-43-110 TYCHY TEL:+48 (0)32-3262750 FAX: +48(0)32 329 13 11 e-mail: [email protected]

NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P)

+351 214130996

NALCO APPLIED SERVICES OF EUROPE BV

+31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325

NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 CHEMIA BRUGG AG (CH) +41 (0)56 4606260 NALCO DANMARK A/S +45-48195800 OEKOPHIL AG (CH) +41 (0)41 760 2220 NALCO DEUTSCHLAND GmbH (D)

+49 (0)69-79340 WYSS WASSERTECHNIK AG (CH)

+41 (0)52 235 38 38

NALCO ESPAÑOLA S.A. (E) +34 93-4095555 ZAO Nalco / Nalco Company OOO

+7 (0)495 980 72 80

NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO ÖSTERREICH Ges.m.b.H. (A)

+ 43(0)1 27026350

NALCO FRANCE SAS +33 (0)3 20 11 70 00 First Distributor: Nalco Czechia s.r.o. (CZ)

Stankova 882/2,CZ-149 00 Praha 4,Czech Republic,+420 (0)2 679 123 50

NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Hungary Kft. (HU)

+36 1 880 5761

NALCO ITALIANA S.R.L.(I) +39 06-54565000 Local Support: Nalco Österreich Ges.m.b.H., Representation Office Predstavnistvo Zagreb (HR)

+385 (0)1 377 95 21

NALCO LIMITED +44 (0)1606 74488 Local Support: Nalco Österreich Ges.m.b.H. Representation Office ROMANIA (RO)

+40 (0) 21 224 17 93

NALCO NETHERLANDS B.V. +31 (0)13-5952200 For Product Safety information please contact Jacqueline Bland, e-mail [email protected] 2. HAZARDS IDENTIFICATION HAZARD CLASSIFICATION : This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC. Any disclosed substance(s) are present below hazardous concentration levels for the product classification.


3D TRASAR® 3DT289




HUMAN HEALTH HAZARDS - ACUTE : INHALATION : May cause irritation of mucous membranes. SKIN CONTACT : Can cause mild irritation. EYE CONTACT : May cause irritation with prolonged contact. INGESTION : May cause gastrointestinal irritation. 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC. Any disclosed substance(s) are present below hazardous concentration levels for the product classification.

Hazardous Substance(s) EINECS / ELINCS NO

CAS NO SYMBOL R-PHRASES / NOTAS

% (w/w)

Phosphoric Acid 231-633-2 7664-38-2 C R34 1 - 5 Sulfuric Acid 231-639-5 7664-93-9 C R35 1 - 5 Benzotriazole 202-394-1 95-14-7 Xn, Xi R22, R36,

R52/53 1 - 5

Methanol 200-659-6 67-56-1 F, T R11, R23/24/25, R39/23/24/25

0.1 - 1

Refer to Section 16 for descriptions of relevant risk phrases and Notas. 4. FIRST AID MEASURES INHALATION : Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. SKIN CONTACT : Flush affected area with water. If symptoms develop, seek medical advice. EYE CONTACT : Immediately flush eye with water for at least 15 minutes while holding eyelids open. If symptoms develop, seek medical advice. INGESTION : Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If reflexive vomiting occurs, rinse mouth and repeat administration of water. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition.


3D TRASAR® 3DT289




5. FIRE FIGHTING MEASURES FLASH POINT : Not applicable EXTINGUISHING MEDIA : This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARD : May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water. 7. HANDLING AND STORAGE HANDLING : Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). STORAGE CONDITIONS : Store in suitable labeled containers. Store the containers tightly closed. SUITABLE CONSTRUCTION MATERIAL : Buna-N, Hypalon, EPDM, Polyethylene, Polypropylene, HDPE (high density polyethylene), PVC, Epoxy phenolic resin UNSUITABLE CONSTRUCTION MATERIAL : Brass, Stainless Steel 304, Neoprene, Viton, Polyurethane, 100% phenolic resin liner, Stainless Steel 316L


3D TRASAR® 3DT289




SPECIFIC USE(S) : COOLING WATER TREATMENT For specific dosages and customized applications please contact your representative. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below. Country/Source Substance(s) Category: ppm mg/m3 ACGIH/TLV Sulfuric Acid TWA 1 STEL 3 AUSTRIA Phosphoric Acid MAK 1 MAK STEL 2 Sulfuric Acid (Inhalable fraction.) MAK 1 MAK CEIL 2 BELGIUM Phosphoric Acid TWA 1 STEL 2 Sulfuric Acid TWA 1 STEL 3 BULGARIA Phosphoric Acid TWA 1 STEL 2 Sulfuric Acid TWA 1 DENMARK Phosphoric Acid GV 1 Sulfuric Acid GV 1 FINLAND Phosphoric Acid HTP 8H 1 HTP 15MIN 2 Sulfuric Acid HTP 8H 0.2 HTP 15MIN 1 FRANCE Phosphoric Acid VME 0.2 1 VLE 0.5 2 Sulfuric Acid VME 1 VLE 3 GERMANY Phosphoric Acid (Inhalable fraction.) MAK 2 AGW 2 Sulfuric Acid (Inhalable fraction.) MAK 0.1 IRELAND Phosphoric Acid TWA 1 STEL 2 Sulfuric Acid TWA 1 ITALY Phosphoric Acid TWA 1 STEL 2 Sulfuric Acid (Thoracic fraction.) TWA 0.2


3D TRASAR® 3DT289




NETHERLANDS Phosphoric Acid TGG 1 TGG 15 2 NORWAY Phosphoric Acid ADM. NORM 1 Sulfuric Acid (Aerosol.) ADM. NORM 0.2 ADM. NORM 0.1 SPAIN Phosphoric Acid VLA-ED 1 VLA-EC 2 Sulfuric Acid VLA-ED 1 VLA-EC 3 SWEDEN Phosphoric Acid NGV 1 KTV 3 Sulfuric Acid NGV 1 KTV 3 SWITZERLAND Phosphoric Acid TWA 1 STEL 2 Sulfuric Acid (Inhalable dust) TWA 0.1 STEL 0.1 UNITED KINGDOM Phosphoric Acid TWA 1 STEL 2 POLAND Phosphoric Acid MAC-NDS 1 MAC-NDSC

h 2

Sulfuric Acid MAC-NDS 1 MAC-NDSC

h 3

HUNGARY Phosphoric Acid ÁK 1 CK 2 Sulfuric Acid ÁK 1 CK 1 LATVIA Phosphoric Acid TWA 1 STEL 2 Sulfuric Acid TWA 1 CZECH REPUBLIC Phosphoric Acid PEL 1 NPK-P 2 Sulfuric Acid as SO3 PEL 1 NPK-P 2 CROATIA Phosphoric Acid MDK 1 KDK 3 Sulfuric Acid MDK 1 KDK 3 ROMANIA Phosphoric Acid TWA 0.2 TWA 1 STEL 0.5 STEL 2 Sulfuric Acid TWA 0.5


3D TRASAR® 3DT289




STEL 1 RUSSIAN FEDERATION

Sulfuric Acid (Aerosol.) CEIL 1

SERBIA Phosphoric Acid MAC 1 Sulfuric Acid MAC 1 SLOVAKIA Phosphoric Acid TWA 1 CEILING 2 Sulfuric Acid TWA 0.1 CEILING 0.1 SLOVENIA Phosphoric Acid TWA 1 STEL MULT Sulfuric Acid sulfuric acid (Inhalable fraction.) TWA 0.1 * A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and the eyes. MONITORING MEASURES : A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed or removed and analyzed as referenced below: Substance(s) Method Analysis Absorbant Phosphoric Acid US NIOSH: 7903 Ion chromatography Silica gel Sulfuric Acid US NIOSH: 7903 Ion chromatography Silica gel ENGINEERING MEASURES : The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces. PERSONAL PROTECTION GENERAL ADVICE : The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. The applicable European standard can be found in EN 140, EN 137, EN 143 and EN 14387. Consider the use of filter type: A-B-E-K-P If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed.


3D TRASAR® 3DT289




Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374. SKIN PROTECTION : When handling this product, the use of overalls is recommended. The applicable European standard can be found in EN ISO 20345. EYE PROTECTION : Wear chemical splash goggles. The applicable European standard can be found in EN 166. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Yellow ODOR None FLASH POINT : Not applicable SPECIFIC GRAVITY 1.151 (25 °C) SOLUBILITY IN WATER Complete pH (100 %) 1.8 VISCOSITY 5.4 cst (25 °C) INITIAL BOILING POINT 100 °C VAPOR PRESSURE 0.06 kPa (37.8 °C) Note: These physical properties are typical values for this product and are subject to change. 10. STABILITY AND REACTIVITY STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID : Freezing temperatures. MATERIALS TO AVOID : Bases, Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors., Contact with reactive metals (e.g. aluminum) may result in the generation of flammable hydrogen gas.


3D TRASAR® 3DT289




HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon, Oxides of sulfur, Oxides of phosphorus, Oxides of nitrogen 11. TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product. SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). For additional information on the hazard of the preparation, please consult section 2 and 12. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : The following results are for the product. ACUTE FISH RESULTS : Species Exposure LC50 NOEC Method Test Descriptor Fathead Minnow 96 hrs 3,750 mg/l 2,500 mg/l Product Rainbow Trout 96 hrs 1,830 mg/l 1,250 mg/l Product ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 EC50 Method Test Descriptor Daphnia magna 48 hrs 1,908 mg/l Product Ceriodaphnia dubia

48 hrs 1,875 mg/l Product

PERSISTENCY AND DEGRADATION : Total Organic Carbon (TOC) : 62,000 mg/l Chemical Oxygen Demand (COD) : 190,000 mg/l Biological Oxygen Demand (BOD) : Incubation Period Value Method Test Descriptor 5 d 9,240 mg/l Product The organic portion of this preparation is expected to be readily biodegradable. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate.


3D TRASAR® 3DT289




13. DISPOSAL CONSIDERATIONS If this preparation becomes a waste, the final user must define and assign the appropriate European Waste Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations. This product is suitable for disposal in an approved landfill or by controlled incineration. This product will generate an ash if burned. It can be burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers. Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor. EUROPE WASTE CODE : 16 03 04 - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes other than those mentioned in 16 03 03. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code. NATIONAL REGULATIONS CZECH REPUBLIC Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No. 477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. 381/2001 Coll.), as amended 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT

Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Technical Name(s) : Phosphoric Acid, Sulfuric Acid UN/ID No : UN 3264 Hazard Class - Primary : 8 Packing Group : III ADR/RID H.I.n. : 80 CLASSIFICATION CODE : C1

AIR TRANSPORT (ICAO/IATA)

Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Technical Name(s) : Phosphoric Acid, Sulfuric Acid UN/ID No : UN 3264 Hazard Class - Primary : 8 Packing Group : III IATA Cargo Packing Instructions : 820 IATA Cargo Aircraft Limit : 60 L (Max net quantity per package) IATA Passenger Packing Instructions : Y818 / 818 IATA Passenger Aircraft Limit : 1 L / 5 L

MARINE TRANSPORT (IMDG/IMO)

Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Technical Name(s) : Phosphoric Acid, Sulfuric Acid UN/ID No : UN 3264


3D TRASAR® 3DT289




Hazard Class - Primary : 8 Packing Group : III

OTHER APPLICABLE INFORMATION

CEFIC TREMCARD REFERENCE : 80GC1-II+III EMERGENCY ACTION CODE : 2X

15. REGULATORY INFORMATION CLASSIFICATION AND LABELLING : This preparation is not regulated, however, we recommend the following safety precautions: SAFETY PHRASES S24/25 - Avoid contact with skin and eyes. S37/39 - Wear suitable gloves and eye/face protection. NATIONAL REGULATIONS CZECH REPUBLIC This preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. 356/2003 Coll.) This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and Decree 231/2004 Coll. on detailed particulars of safety data sheet Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No. 178/2001 Coll. laying down conditions of health protection of employees at work NATIONAL REGULATIONS GERMANY WGK 1 (Annex 4) NATIONAL REGULATIONS HOLLAND ABM RESULT ABM RESULT Substance(s) % (w/w) 11 B PRODUCT REGISTRATION NUMBER Denmark 2068739 INTERNATIONAL CHEMICAL CONTROL LAWS EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. Safety Data Sheet according to Regulation (EC) No 1907/2006. Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals (REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into


3D TRASAR® 3DT289




European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment. Should you require any further information on Nalco's REACH programme please contact us at [email protected] or visit our website. UNITED STATES : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) CANADA : This product contains substance(s) which are found on the Non-Domestic Substances List (NDSL). JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI). 16. OTHER INFORMATION LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3 R11 - Highly flammable. R22 - Harmful if swallowed. R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R34 - Causes burns. R35 - Causes severe burns. R36 - Irritating to eyes. R39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. - REVISED INFORMATION: section(s): - 2 - 3 - 7 - 13 - 16 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. EMERGENCY TELEPHONE NUMBER(S) Trans-European +32-(0)3-575-5555 Belgium / Luxembourg +32-(0)3-575-0330 Bulgaria +32-(0)3-575-5555 Croatia +385 (0)91-1-25-75-23 Czech Republic +420-602-669421 Denmark +47-22-33-69-99 Finland +358-(0)9-471 977 France / French Switzerland +33-(0)6-11-07-32-81 Germany / Austria / German Switzerland +49-(0)6232-130128


3D TRASAR® 3DT289




Hungary +36-30-9-506-447 Italy / Italian Switzerland +39-333-210-7947 Latvia +32-(0)3-575-5555 The Netherlands +32-(0)3-575-0330 Norway +47-22-33-69-99 Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT) Portugal +351-91-911-1399 Romania +40-744 -34-14-53 Russia / Belarus +7-812-449-0474 Saudi Arabia +966-(3)847-1515 Serbia +32-(0)3-575-5555 Slovak Republic +421-(0)905-585-938 Slovenia +386-41-634-916 Spain +34-977-551577 Sweden +47-22-33-69-99 UAE +44-(0)7071-223-738 UK and Republic of Ireland +44-(0)7071-223-738 Nalfleet International +32-(0)3-575-5555 POISON CONTROL CENTER TELEPHONE NUMBERS Belgium +32-70-245245 Czech Republic +420 224 91 92 93 Hungary +36-80-201-199 ETTSZ, 1096 Budapest, Nagyvárad tér 2 France +33-(0)145-42-59-59 ORFILA Slovak Republic +421 (0)2 5477 4166 Prepared By : SHE Department Date issued : 09.01.2009 Version Number : 1.10 Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth and 0.001 = 1 thousandth

SAFETY DATA SHEETCWI 66-V

PROMANEX

Section 1: Identification of the substance/mixture and of the company/undertakingProduct identifier

Product Name: CWI 66-V

Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: An environmentally friendly corrosion and scale inhibitor

Details of the supplier of the safety data sheetCompany Name: PROMANEX



Tel: 0845 467 88 87 Fax: 01606 781 880


Emergency telephone number

Section 2: Hazards identificationClassification of the substance or mixture

Classification under CHIP: :R34;

Label elements

Hazard Symbols:

Risk phrases:

Safety phrases:

Precautionary phrases:

Other hazards

PBT: This substance is not identified as a PBT substance

0844 3727344

R34: Causes burns.

S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S28: After contact with skin, wash immediately with plenty of water.S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Page 1 of 4Revision No: 1 Compilation Date: 06-May-10


PROMANEX

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.

Exposure hazards: Corrosive. In combustion emits toxic fumes.

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers.

Section 5: Fire-fighting measures

Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing.

Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or nose.

Eye contact: Corneal burns may occur. May cause permanent damage.

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.

Most important symptoms and effects, both acute and delayed

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious and breathing is OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. If breathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer to hospital as soon as possible.

Ingestion: Wash out mouth with water. Do not induce vomiting. Give 1 cup of water to drink every 10 minutes. If unconscious, check for breathing and apply artificial respiration if necessary. If unconscious and breathing is OK, place in the recovery position. Transfer to hospital as soon as possible.

Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination.

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Transfer to hospital if there are burns or symptoms of poisoning.

Description of first aid measures

Section 4: First aid measures

Hazardous ingredients

Section 3: Composition/information on ingredients

Section 6: Accidental release measuresPersonal precautions: Notify the police and fire brigade immediately. If outside keep bystanders

Ingredients EINECS CAS PercentCHIP Classification

SODIUM MOLYBDATE 231-551-7 10102-40-6 1-10%Xi:R36/37/38;

HEDP.4NA 223-267-7 3794-83-0 1-10%Xi:R36/38;

SODIUM HYDROXIDE 215-185-5 1310-73-2 1-10%:R35;

POTASSIUM PYROPHOSPHATE

230-785-7 7320-34-5 1-10%Xi:R36;

SODIUM BENZOTRIAZOLE 2392696 15217-42-2 1-10%Xn:R22; Xi:R36/38;



PROMANEX

upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Do not attempt to take action without suitable protective clothing - see section 8 of SDS. Turn leaking containers leak-side up to prevent the escape of liquid.

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

Clean-up procedures: Clean-up should be dealt with only by qualified personnel familiar with the specific substance. Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method.

Section 7: Handling and StorageHandling requirements: Avoid direct contact with the substance. Ensure there is sufficient

ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air.

Storage conditions: Store in cool, well ventilated area. Keep container tightly closed.

Suitable packaging: Polyethylene. Polypropylene. Stainless steel. Unsuitable packaging: metals and alloys.

Section 8: Exposure controls/personal protectionControl Parameters

Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area.

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.

Hand protection: Impermeable gloves. Butyl gloves. Nitrile gloves.

Eye protection: Tightly fitting safety goggles. Ensure eye bath is to hand.

Skin protection: Impermeable protective clothing.

Ingredients State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL

Workplace exposure limits Respirable dust

SODIUM HYDROXIDE UK - 2 mg/m3 - -

Section 9: Physical and chemical propertiesState: Liquid

Odour: Barely perceptible odour

Colour: Pale orange

Solubility in water: Miscible in all proportions

Relative density: 1.19 pH: 12-14

Section 10: Stability and reactivityChemical Stability: Stable under normal conditions.

Conditions to avoid: Heat. Evaporation of water.

Materials to avoid: Soft metals (aluminium, zinc etc.) Strong acids.

Hazardous decomposition products: In combustion emits toxic fumes.

Section 11: Toxicological informationInformation on toxicological effects



PROMANEX

Skin contact: Blistering may occur. Progressive ulceration will occur if treatment is not immediate.

Eye contact: Corneal burns may occur. May cause permanent damage.

Ingestion: Corrosive burns may appear around the lips. Blood may be vomited. There may be bleeding from the mouth or nose.

Inhalation: There may be shortness of breath with a burning sensation in the throat. Exposure may cause coughing or wheezing.

Section 12: Ecological informationEcotoxicity values: Not applicable

Persistence and degradability: Biodegradable.

Bioaccumulative potential: No bioaccumulation potential.

Mobility in solid: Readily absorbed into soil.

PBT identification: This substance is not identified as a PBT substance

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerationsDisposal operations: Transfer to a suitable container and arrange for collection by specialised

disposal company.

Disposal of packaging: Return empty containers to the supplier for recycling. Damaged containers should be destroyed by cutting up or by incineration. Do not use for potable water.

NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.

Section 14: Transport informationUN number: -

Shipping name: NOT CLASSIFIED AS DANGEROUS IN THE MEANING OF TRANSPORT REGULATIONS.

Transport class:

Packing group:

Section 15: Regulatory informationChemical safety assessment: A chemical safety assessment has not been carried out for the substance

or the mixture by the supplier.

Section 16: Other infortmation

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.

Chemical safety assessment: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010


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