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Center for Biorenewable Chemicals
Brent ShanksDirector, CBiRC
Why Biobased Chemicals?
Center for Biorenewable Chemicals
Center for Biorenewable Chemicals
Center for Biorenewable Chemicals
Chemicals
Center for Biorenewable Chemicals
Refinery Products
Center for Biorenewable Chemicals
Petrochemicals
Benzene
Xylene
Ethylene
Propylene
Methanol
TolueneC4’s
Center for Biorenewable Chemicals
Ethylene and Derivatives
6% α-Olefins
52% Polyethylene
17% Ethylene 98% Vinylchloride 98% Polyvinyl chloride dichloride
13% Ethylene 58% Ethylene glycol 30% Antifreeze oxide 12% Ethoxylates 60% Polyethylene
10% Ethanolamines terephthalate
7% Ethyl 99% Styene 62% Polystyrene benzene 11% Rubbers/Elastomers
12% Vinyl acetate
Ethylene
Center for Biorenewable Chemicals
Production
Dow, Mark Jones, 2011
Center for Biorenewable Chemicals
Chemicals
Center for Biorenewable Chemicals
Biobased Chemicals Status
Center for Biorenewable Chemicals
Pathways to BiorenewablesCarbohydrates
PyruvateAcetyl CoAEthanol
Lactate
Amino Acid Metabolism
Fatty Acid Metabolism
Glycolysis
Citric Acid Cycle
Sorbitol
Succinate Keto Acids Array of Chains, Branches, Rings
Furans
Center for Biorenewable Chemicals
Biobased ChemicalsNew
Ring Pyrones
3-keto Fatty Acids
Fatty Acids
Ethers/Esters
3-en-2-ones
Center for Biorenewable Chemicals
Array of Opportunities
Center for Biorenewable Chemicals
CBiRC
Biomass Intermediates Plastics, Resins, etc.Fatty AcidsSugars Uses
Vision
Center for Biorenewable Chemicals
Participating Institutions
Abo Akademi University (Finland) Fritz Haber Institute (Germany) Technical University of Denmark Technische Universiteit (Netherlands)
Center for Biorenewable Chemicals
Biobased Chemicals
Center for Biorenewable Chemicals
Triacetic Acid Lactone Platform
Center for Biorenewable Chemicals
Coumalate Platform
O
O
CO2Me
CO2Me
N
CO2Me
CO2Me
NMe2OMe
CO2Me
CO2Me
CO2Me
NR
CO2Me
CO2Me
CO2Me
Carbazole (Activity against diseaseslike bronchitis, malaria)
Dimethyl Terephthalate(Monomer for poly(ethylene)
terephthalate)Isophathalic Acid Ester
(Polymer additive)
Methyl Benzoate(Flavors and fragrances)
Anisic Acid Ester(Bactericidal, used in
cosmetics, preservatives)
Methyl Isonicotinate(Precursor to
tuberculosis drug)
4-(Dimethylamino)benzoic Acid Ester(Precursor to sunblock agent)
Center for Biorenewable Chemicals
Thank you