Bulk Micromachining del silicio mediante impiantazione di protoni Comunicazione ENEA C.R. Frascati UTAPRAD-SOR Nenzi P., Fastelli A., Gallerano G., Marracino F., Picardi L., Ronsivalle C. ENEA C.R. Casaccia UTRINN-FVC Tucci M. Sapienza Universit di Roma DIET Balucani M., Klishko A. 100 Congresso Nazionale Societ Italiana di Fisica Pisa 25/09/2014 Outline Bulk micromachining of silicon MEMS and Advanced IC packaging applications Porous silicon based micromachining Porous Silicon growth on proton implanted silicon Uniform proton beam irradiation of silicon samples TOP-IMPLART Proton LINAC Experimental results Conclusions 100 SIF 25/09/2014 Bulk Micromachining of Silicon Bulk micromachining: realization of high aspect- ratio structures in the bulk of a silicon wafer. Applications: MEMS (Micro-Electro- Mechanical-Systems) IC Packaging (Silicon Interposers) 100 SIF 25/09/2014 Porous Silicon Porous silicon (PS or PSi) has been discovered in 1956 at Bell Labs by A. Uhlir and I. Uhlir and later rediscovered in the 90 because of its photoluminescence properties. Nano-porous silicon from n+ silicon Macro-porous silicon from p- silicon Pore Silicon Nanocrystals 100 SIF 25/09/2014 Porous Silicon Reference Card Pore width (nm)Classification 2Micro (nano) porous 2-50mesoporous >50macroporous ParameterRange (typ.)Unit HF Conc.2-40%wt Current Density mA/cm 2 Anodization time5-1800s Temperature K Wafer p-type cm Wafer n-type cm An increase ofPorosityEtch. rateE-polish. thr. HF conc.decrease increase Current densityincrease - Anod. timeincrease constant- Temperature--increase Doping (P-type)decreaseincrease Doping (N-type)increase- TheoryFormula Bruggeman Maxwell - Garnett Looyenga Siliconm p+ 2 n SIF 25/09/2014 Porous silicon for bulk micromachining In bulk micromachining applications porous silicon is used as a scarificial layer that is etched away to reveal the structure. Extremely high selectivity of PS etching in comparison with bulk Si. Etching ratio of PS to Si is :1! PS layers can be selectively etched by means of the structure sensitive mechanism. TSV structures filled with Cu formed from ordered macro PS (P. Nenzi et al., ECTC 2013) High aspect ratio macro-pores, random order (M. Balucani, 2010) 100 SIF 25/09/2014 POROUS SILICON GROWTH ON PROTON IMPLANTATED SILICON Experiments on 100 SIF 25/09/2014 Porous silicon growth suppression over irradiated areas Depth(um) surfaceDefect density Damage profile for protons with energy of 250 keV Damage profile almost constant for the first 2.2 m (below surface) Tenfold (10x) defect density increase at the at the stopping range. Low defect region High defect region The lateral electric field generated by implanted protons in the damaged regions causes a deflection of holes. Deflection increases near the highly defective region, corresponding to the stopping range. Hole current bends over the highly defective region. Porous silicon growth is suppressed only in the highly defective region at low doses (10 14 /cm 2 ). Electric field distribution with increasing dose High doseLow dose M. B. H. Breese at al., Phys. Rev B 73, SIF 25/09/2014 Porous silicon growth suppression over irradiated areas E. J. Teo et al., Opt. Express 16 (2) SIF 25/09/2014 UNIFORM PROTON BEAM IRRADIATION OF SILICON SAMPLES TOP IMPLART experiment on 100 SIF 25/09/2014 VARIABLE CURRENT 30keV SOURCE 3 7 MeV RFQDTL VERTICAL LINE TERMINAL HORIZONTAL LINE EXTRACTIONS TOP-IMPLART proton LINAC TOP-IMPLART project is aimed to the development of a proton LINAC for Hadron therapy using compact S-band accelerating sections (SCDTL) The LINAC is under construction at ENEA C.R. Frascati by the UTAPRAD Unit The machine is now capable of delivering a pulsed proton beam with energies up to 11.6 MeV Lower energy beams can be obtained on a vertical line (radiobiology) or by degrading the energy of the main beam line 100 SIF 25/09/2014 Experimental setup Silicon sample is masked with a 200m thick molybdenum mask Silicon sample and mask are mounted on a custom designed holder and installed at the end of the accelerator pipe. Beam current and sample temperature have been recorded during the processes 100 SIF 25/09/2014 Experimental Conditions Target implantation depth: 30m Target fluence: 1e 15 /cm 2 Beam current: 95A per pulse Exposure time: 75 min (4500 s) Substrate type: p - (100), 10 Ohm*cm, B doped SRIM/TRIM code has been used to compute energy Accelerator minimum energy is 3MeV so an aluminum energy degrader (60m thick) has been placed between the beam and the target to reduce it to 1.3MeV H + 3 MeV 60 m Al 45 m Si Pulse width 80s, PRF=30 Hz. Maximum temp. on sample 150 C. 100 SIF 25/09/2014 Expected results Irradiated Sicore Etching time We expect an increment in silicon resistivity of the implanted area (near stopping range) due to interaction with Boron dopant counteracting its electrical activity (neutralization). The presence of hydrogen in p-type semiconductor leads to the formation of the H+ donor, that neutralizes ionized impurities. Growth of porous silicon is suppressed on those high resistivity areas. 100 SIF 25/09/2014 FTIR analysis 100 SIF 25/09/2014 Exposed samples 100 SIF 25/09/2014 Exposed samples 100 SIF 25/09/2014 Exposed samples 100 SIF 25/09/2014 Conclusions TOP-IMPLART capability Current Experiments TOP-IMPLART proton linear accelerator has been used to test uniform beam irradiation of silicon samples for potential applications to silicon bulk micromachining (MEMS, Advanced IC Packaging) New experiments will be carried on in 2014 and 2015 to investigate the benefits and limit of TOP- IMPLART LINAC use for semiconductor processing When energies higher than 11.6 MeV will be reached (next LINAC section) activities on the qualification of electronics components are planned 100 SIF 25/09/2014