Bsaac1 2 Oxidative Rancidity

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    Unit

    Food Science

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    Problem Area

    Handling and Storing PlantProducts

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    Lesson

    Oxidative Rancidity

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    Student Learning Objectives

    1. Explain why food packaging is a critical

    component for the food industry.

    2. Explain what rancidity is and why rancidity is

    a problem to the food industry and consumers.

    3. Explain the presence of off-flavors in food

    products caused by oxidative rancidity.

    4. Explain various practices that limit or stopoxidative rancidity in foods.

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    Terms

    Antioxidants

    Fatty acids

    Glycerol

    Hydrolytic rancidity

    Oxidation

    Oxidative rancidity

    Rancidity

    Saturated fatty acid

    Unsaturated (polyunsaturated) fatty acids

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    Why is food packaging a critical component for the food

    industry?

    Food packaging is critical to food preservation. The

    purpose is to protect foods from light, microbial

    contamination, chemical changes, and physical damage.

    A. Food packaging can be made from a variety ofdifferent materials.

    1. Rigid and flexible metals can be made into cans, drums,

    and aluminum foil.

    2. Flexible plastics can be turned into a wide variety of

    containers.

    3. Paper, cardboard, and other wood products can be

    turned into boxes and bags.

    4. Containers made from laminates or multiple layers can

    be created from any of the above sources.

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    B. Packaging machinery and equipment must also be

    very unique and precise. Equipment must be careful to

    not contaminate, crush, or otherwise harm food

    products.

    C. Food packages must be strong enough to withstand

    high heat and cold, sterilization, and for highly

    convenient foods final cooking.

    D. Food packages must meet stringent guidelines for

    flexibility, permeability, burst strength, stretch and other

    qualities.

    E. Characteristics of good packaging materials include

    non-toxic, odorless, flexibility, pliable, puncture resistant,

    good tensile strength at varying temperatures,

    permeability, low transmission of vapor, easy

    identification, grease proof, stain proof, good sealing,

    and easy stripping for the consumer.

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    What is rancidity and why is it a problem?

    Rancidi ty is the condition reached in certain foods as

    the lipid material (fat) undergoes oxidation reactions

    producing aldehydes, hydroxyl acids, keta acids, and

    other compounds which are responsible for the odor and

    off-flavor producing stale foods. An oxygen ion isreplaced with a hydrogen ion in the fatty acid.

    A. Foods that are high in lipids and might become rancid

    include potato chips, peanut butter, crackers, and others.

    B. Light, oxygen, trace elements such as iron and zinc,

    salt, water, bacteria, and molds are factors that speed up

    the oxidation process.

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    What causes the off-flavors and odors in foods caused

    by oxidative rancidity?

    There are two types of rancidity.

    A. Hydro lyt ic Ranc idi ty is caused by a

    breakdown of the fat into glycerol and fatty acid.1. Fatty acids are organic compounds

    containing carbon, hydrogen, and oxygen that

    combine with glycerol to make a lipid.

    2. Glycerol is the storage form of fat in animals.

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    B. Oxidat ive Ranc idi ty results from oxidation of

    unsaturated and polyunsaturated fatty acids

    producing undesirable flavors and odors.1. Oxidat ion is when a chemical reaction occurs

    forming oxides by reacting with oxygen in the air.

    2. Saturated fatty acids are fatty acid molecules

    containing no double bonds between carbon atomsthemolecule is saturated with hydrogen atoms. Saturated

    fatty acids are the bad cholesterol.

    3. Unsaturated (po lyunsaturated) fatty acids are fatty

    acid molecules containing double bonds betweencarbon atomsplant oils are unsaturated. These are

    considered the good fats. Unsaturated fats are more

    susceptible to oxidative rancidity than saturated fatty

    acids.

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    What practices are used for controlling oxidative

    rancidity?

    A. Adding ant iox idantsAntioxidants are

    substances that are added to some foods to

    slow down oxidative deterioration.

    1. BHAbutylated hydroxyanisole2. BHTbutylated hydroxytoluane

    B. Package food protected from light because

    light accelerates oxidation.

    C. Vacuum packaging to keep oxygen out

    because oxygen accelerates oxidation.

    However, this process is too costly for most

    potato chip manufacturers.

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    D. Adding nitrogen to the bag to replace the oxygen.

    E. Speed up distribution to shorten the time fromprocessing to consumption.

    F. Shelf dating products allows for consumers to know

    when to use food products. Factors that affect the

    storage life of a perishable food include:1. length of storage

    2. temperature

    3. relative humidity

    4. light

    G. Vitamin E and Vitamin C also slow oxidative rancidity.

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    Review/Summary

    Why is food packaging a critical

    component for the food industry?

    What is rancidity and why is it a problem?What causes the off-flavors and odors in

    foods caused by oxidative rancidity?

    What practices are used for controllingoxidative rancidity?