2006

BismuthI 5400 [Bi6F11]

7+ — An Unusual, Highly Charged Bismuth Fluoro Complex in (Se4)[Bi6F11][AsF6]9·10SO2. — Title compound (II) crystallizes in the triclinic space group P1 with Z = 1 (single crystal XRD at 125 K). The complex crystal structure con-tains the known square-planar cation, octahedral anions, SO2 molecules, and the unprecedented Bi6 cation. — (BECK*, J.; STEDEN, F.; Chem. Commun. (Cambridge) 2005, 43, 5453-5455; Inst. Anorg. Chem., Rhein. Friedrich-Wilhelms--Univ., D-53121 Bonn, Germany; Eng.) — Schramke

05- 022Se2+

4 AsF-6

F7+11