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J. Knobloch, SRF 2007 1
Basics of Superconducting RF
J. Knobloch, BESSY
J. Knobloch, SRF 2007 2
Overview
• What is the theoretical behavior of superconducting RF cavities?
• Short introduction to RF cavities (details in Tutorials 2a/b)
• Need some „tools“ to characterize their performance/losses• Figures of Merit: Surface resistance, Q-factor, shunt impedance ...
• RF losses for normal and superconductors: theoretical behavior
• Use the Figures of Merit to understand the impact of losses on RF cavities
• Cavity losses: measured behavior, how to improve them
• Fundamental field limits of superconducting cavities (practical limits in Tutorial 4b)
• Note: Throughout will calculate examples• Always use a 1.5 GHz pillbox cavity• Superconductor: always bulk niobium (Other materials/thin films to Tutorial 6a/b)• Some equations, most you can forget again. Important ones are marked in yellow
J. Knobloch, SRF 2007 3
Making a cavity
• For acceleration we require an oscillating RF field
• Simplest form is an LC circuit
• Let L = 0.1 mH, C = 0.01 µF f = 160 kHz
• To increase the frequency, lower L, eventually only have a single wire
• To reach even lower values must add inductances in parallel
• Eventually have we have a solid wall
• Shorten „wires“ even further to reduce inductance
• Pillbox cavity, „simplest form“
• Add beam tubes to let the particles enter and exit
• Magnetic field concentrated in the cavity wall,losses will be here.
L
C
LC
1=ωE
B
E
Based on Feynman‘s Lect. on Physics.
J. Knobloch, SRF 2007 4
Cavity Modes
• Fields in the cavity are solutions to the wave equation
• Subject to the boundary conditions
• Solutions are two families of modes with different eigenfrequencies• TE modes have only transverse electric fields• TM modes have only transverse magnetic fields (but longitudinal component for E)
• TM modes are needed for acceleration. Choose the one with the lowest frequency (TM010)• For pillbox (no beam tubes) solution is:
• Note that the frequency scales inversely with the linear dimension of the cavity (call this „a“)
01
2
2
22 =
⎭⎬⎫
⎩⎨⎧⎟⎟⎠
⎞⎜⎜⎝
⎛∂∂−∇
H
E
tc
0ˆ ,0ˆ =⋅=× HE nn
E
B
E
J. Knobloch, SRF 2007 5
Cavity Fundamentals
• Optimizing Cavity Length
Enter Exit
2cacc
transitRFTL
T ==β
L
2
cacc
RFTL
β=⇒
E.g.: For 1.5 GHz cavity and speed of light electrons (ß = 1), Lacc = 10 cm
J. Knobloch, SRF 2007 6
Figure of Merit: Accelerating Voltage and peak fields
• How much energy gain can we expect?
• Integrate the E-field at the particle position as it traverses the cavity:
• For the pillbox cavity this is
• We can define the accelerating field as
• Important for the cavity performance is the ratio of the peak fields to the accelerating field.
• Ideally these should be relatively small tolimit losses and other trouble at high fields
(assume speed of light electrons)
c
Lc
L
LEdzc
ziEV
L
2
2sin
exp0
0
0
0
00c ω
ωω ⎟
⎠⎞
⎜⎝⎛
=⎟⎠⎞
⎜⎝⎛= ∫
0c
acc
2E
L
VE
π==
Typically more like 2
Typically more like 3600
2
cacc
RFTL =
LE0
2
π=
J. Knobloch, SRF 2007 7
Power dissipation in a cavity
• Tangential magnetic fields exist at the cavity wall
By Maxwell‘s equation currents must flow.
• Current density is proportional to the magnetic field
• If the material is lossy, this will lead to power dissipation• (one reason why one may want a low ratio of magnetic field to accelerating field)
• By Ohm‘s law one can define a surface resistance such that the power dissipated per unitarea is given by:
• The total power dissipated in the cavity is given by the integral over the surface:
EB
E
t
EJB
∂∂+=×∇r
rrrμεμ
J. Knobloch, SRF 2007 8
Figure of Merit: Cavity Quality
• How does this compare to the energy stored in the cavity?
• Define the cavity quality as:
• (Note: Easy quantity to measure. Just fill the cavity with energy, switch off and count thenumber of cycles it takes to dissipate the energy)
• The stored energy is:
• Hence
• Note that
• And hence
where G is the geometry factor which only depends on the cavity shape!
cycle RF onein dissipatedEnergy
cavity in the storedEnergy 20 π=Q energy stored thedissipate tocylces ofNumber 2 ×≈ π
Ω=+
Ω= 257
1
453 :pillbox aFor
R
dR
d
Gs
0 R
GQ =
19.6 ms QL = 1.6E8
J. Knobloch, SRF 2007 9
• The cavity quality: useful value for the performance of the cavity, measures how lossy thecavity material is
• But really we want to know how much power is dissipated to accelerate the charges.
• Hence one defines a shunt impedance:
• The higher the shunt impedance, the more acceleration we get per watt of dissipation
• A very useful quantity is generated by dividing by the quality factor:
• Why? Because
• Pillbox:
00
a
2c
diss
RV
P×
=⇒
Figure of Merit: Shunt Impedance
U
V
Q
R
0
2c
0
a
ω=
20
22c
1
ω∝∝ aV
30
3 1
ω∝∝ aU 0
2c ω∝⇒
U
V Depends only on the cavity shapebut not its size (frequency) or material!
diss
2c
a P
VR =
Operating parameter,given by Accelerator
Cavity geometry
Cavity material
Ω=Ω= 1961500 R
d
Q
R
s
0
a
2c
diss RG
Q
RV
P×
=⇒
0Q
R⇒
J. Knobloch, SRF 2007 10
Comparison Superconducting and Normal Conducting Cavities
• Lets calculate one example: Want to operate a 1.5 GHz Pillbox at 1 MV• For copper at 1.5 GHz, Rs = 10 mΩ• For SC niobium at 1.5 GHz, Rs = 10 nΩ (discussed later)
• Recall:
Ω=+
Ω= 257
1
453
R
dR
d
G
00
a
2c
diss
RV
P×
=
Ω=Ω= 1961500 R
d
Q
R
For Cu: Q0 = 25700 For Nb: Q0 = 2.57 x 1010
For Cu: Pdiss = 200 kW, For Nb: Pdiss = 200 mW!
m
MV10
acc
cacc ==
L
VE
m
MV7.15
2 accpk ==⇒ EEπ
mT31,m
A24300
m
A2430 pkaccpk === BEH
Huge difference Operating costs/cooling issues!Drastically different designs for SC and NC Cavities
s0 R
GQ =
For copper cavities, power dissipation is a huge constraintCavity design is driven by this fact
For SC cavities, power dissipation is minimaldecouples the cavity design from the dynamic lossesfree to adapt design to specific application
For a clock pendulum (1 sec): 815 years!
J. Knobloch, SRF 2007 11
Difference between NC and SC cavities
• NLC design developed to reduce power dissipation to a minimum
• But many other areas are impacted in a negative way• E.g., Strong wakefields are created impact beam dynamics• Small size extremely tight tolerances
• TELSA design
• Power dissipation less critical• Choose design that relaxes wakefields• Still: heat is deposited in LHe cost issue that must be understood
NLC TESLA
J. Knobloch, SRF 2007 12
What comes now
• Clearly, cavity losses strongly impact the design/operation of the cavity
• Will analyze the behavior of normal-conducting and superconducting RF losses
• Look at scaling laws: frequency, temperature, material purity …
• Then turn to the real world, look at deviation from the ideal• Residual losses• Trapped magnetic flux• The Q-disease
• How far can we push a superconducting cavity?
• Theoretical Limit of superconductors
J. Knobloch, SRF 2007 13
Calculating RF losses in a conductor
• For simplicity, use the nearly-free electron model
• Losses given by Ohm‘s law
• The electrons have a time τ between scattering events to gain energy
• In a cavity, the magnetic field drives an oscillating current in the wall• Start with Maxwell‘s equations
• Combine the two and take the exp(iωt) dependence into account
• Look at a typical copper RF cavity:
m
e τEv
−=Δ
timescattering ,2
n === ττσ EEjm
en
t∂∂+=×∇ E
jB μεμt∂
∂−=×∇ BE
BBB
jB 22
22 μεωμσωμεμ +−=
∂∂−×∇=∇− i
t
Vm
A108.5 7×=σ GHz 1.5at
Vm
A08.00 =ωε
Xt2
22
∂∂−×∇=∇− B
jB μεμ
J. Knobloch, SRF 2007 14
Field near a conductor
Consider now a uniform magnetic field (y-direction) at the surface of a conductor.
Solving
yields
where the field decays into the conductor with over a skin depth of
Similarly, from Maxwell find that
So that a small, tangential component of E also exists which decays into the conductor
0δδ
ixx
y eeHH−−
=
02 =−∇ BB μσωi
μσπδ
f
1=
yz Hi
Eσδ
)1( +−=
X
Z
Y
J. Knobloch, SRF 2007 15
Cavity losses due to the RF field
• The losses per area are simply
• Note: Surface resistance is just the real part of the surface impedance:
( ) )4/exp(11 π
σωμ
σμπ
σδi
fi
i
H
EZ
y
zs =+=+==
∫∫∞
=
∞
=
==′0
2
0
*diss 2
1
2
1
x
z
x
zz dxEdxEJP σ
σμπ
σδf
Rs == 1202
1H
σδ= 2
02
1HRs=
• Plug in some numbers:
• Copper: f = 1.5 GHz, σ = 5.8 x 107 A/Vm, µ0 = 1.26 x 10-6 Vs/Am
δ = 1.7 µm, Rs = 10 mΩQ0 = G/Rs = 25700
0δδ
ixx
y eeHH−−
=yz H
iE
σδ)1( +−=
J. Knobloch, SRF 2007 16
• Note that for , the surface resistance scales as
• Recall so that also scales with
• But consider the total power dissipation for the RF-cavity installation (e.g., linac):• For a total voltage Vt, we need N = Vt/Vc cavities• Thus the total power dissipation is
• Since
• The total power dissipation scales as:
s
0
a
2c
diss RG
Q
RV
P×
=
All geometry
Frequency scaling of the losses
σμπ
σδf
R == 1s ω
00
a
2c
diss
RV
P×
= ω
s
0
a
2c
c
tottot R
GQ
RV
V
VP
×=
accs
0
a
acctot LR
GQ
RE
V×
=
ω1
acc ∝L
ω1
tot ∝P For NC systems high frequencies are desirable(But beam dynamics may suffer!)
ωs
tot
RP ∝⇒
All geometry
Determined by what is feasiblein the cavity design
NLC
J. Knobloch, SRF 2007 17
Two fluid model, must consider both sc and nc components:
• Below Tc superconducting cooper pairs are formed with an energy gap 2Δ• The density of remaining „normal“ electrons is given by
• DC case: The lossless Cooper pairs short out the field
the normal electrons are not accelerated
the SC is lossless even for T > 0 K
Losses in a superconductor: Two-fluid model
⎟⎟⎠
⎞⎜⎜⎝
⎛ Δ−∝Tk
nB
n exp
J. Knobloch, SRF 2007 18
Losses in a superconductor: RF case
• What‘s different for the RF case?
• Cooper pairs have inertia!
they cannot follow an AC field instantly and thus do not shield it perfectly
a residual field remains
the normal electrons are accelerated and dissipate power
• Scalings of the surface resistance:
• The faster the field oscillates the less perfect the shielding
We expect the surface resistance to increase with frequency
• The more normal electrons exist, the lossier the material
We expect the surface resistance to drop exponentially below Tc
J. Knobloch, SRF 2007 19
Acts as the AC conductivity of the superconducting fluid. „Collision time“ is the RF period.
• Calculate surface impedance of a superconductor
Must take into account the „superconducting“ electrons (ns) in the 2-fluid model
• For these there is no scattering
• Thus:
• In an RF field with exp(iωt) dependance
or
• Total current: Just add the currents due to both „fluids“:
Ejωm
eni
2s
s −=⇒
Surface impedance of superconductors
Ev
et
m −=∂∂
Ej
m
en
t
2ss =
∂∂
⇒ First London Equation
depthn penetratioLondon theis where2
s0L2
L0s en
mi
μλ
λωμ=−= Ej
( )Ejjj snsn σσ i−=+=
vj enss =
J. Knobloch, SRF 2007 20
Surface impedance of superconductors
• Thus, the treatment with a superconductor is the same as before, only that we have to change:
• Impedance
• Penetration depth
• Where
• Note that 1/ω is of order 100 ps whereas for normal conducting electrons τ is of order few10 fs. Also, ns >> nn for T << Tc. Hence
• As a result one finds that:
• Again, the field decays rapidly but now over the London penetration depth
( ) ( )4exp4expsn
sπ
σσωμπ
σωμ i
iiZ
−→=
( )sn σσσ i−→
( )sn
11
σσμπμσπδ
iff −→=
( )ω
στσδ m
en
m
enx
iHH y
2s
s
2n
n0 and , 1
exp ==⎟⎠⎞
⎜⎝⎛ +−=
sn σσ <<
( ) ⎟⎟⎠
⎞⎜⎜⎝
⎛++≈
s
n
211
σσλδ ii L
Ls
n
L 20
λσσ
λ ixx
y eeHH−−
=
J. Knobloch, SRF 2007 21
Surface impedance of superconductors
• For the impedance we get:
• Lets look at some numbers:
For niobium λL = 36 nm, for Copper the penetration depth was 1.7 µm (@ 1.5 GHz)
The field penetrates over a much shorter distance than for a normal conductor
• At 1.5 GHz: Χs = 0.43 mΩ, whereas Rs is < 1µΩThe superconductor is mostly reactive in line with our previous explanation of losses in a
superconductor
⎟⎠⎞⎜
⎝⎛ +≈ iZ
sσσ
σωμ
2n
ss L0s λωμ=Χ 3
L20
2ns 2
1 λμωσ=R
Surface resistance of thesuperconductor
J. Knobloch, SRF 2007 22
Frequency scaling of the surface resistance
• Note
The surface resistance scales quadratically with frequency, also in agreement with ourprevious analysis
• Recall that the total dissipated power for all accelerating cavities was given by
• Hence for a superconductor
Favors low-frequency cavities if cryogenic power is an issue.
ωs
tot stufft independanfrequency R
P ×=
ω∝totP
3L
20
2ns 2
1 λμωσ=R
NLC
J. Knobloch, SRF 2007 23
Temperature scaling of the surface resistance
• The surface resistance is proportional to the conductivity of the normal fluid!
If the normal-state resistivity is low, the superconductor is more lossy!
• Explanation: For „residual“ field not shielded by the Cooper pairs more „normal current“ flows more dissipation
• Temperature dependance: Below Tc, electrons condense into the superconducting state.
• In the previous tutorial we saw for the normal fluid:
Conductivity is
• Hence the SC surface resistance is given by
3L
20
2ns 2
1 λμωσ=R
2ndiss EP σ∝
⎟⎠⎞⎜
⎝⎛−≈⎟
⎠⎞⎜
⎝⎛ Δ−∝ T
TTk
Tn c
Bn
86.1exp)(exp
⎟⎠⎞⎜
⎝⎛−∝ T
Tcn
86.1explσ
⎟⎠⎞⎜
⎝⎛−∝ T
TR c3L
2s
86.1explλω
Property of the cavityProperty of the superconductorProperty of the normal conductorProperty of cooling
J. Knobloch, SRF 2007 24
Scaling of the surface resistance
The surface resistance• Increases quadratically with frequency use low frequency cavities
• Decreases exponentially with temperature stay well below Tc
• Increases with increasing purity of the material use impure materials
⎟⎠⎞⎜
⎝⎛−∝ T
TR c3L
2s
86.1explλω
No! This statment breaks down for veryimpure SC + there are compellingarguments to use high-purity material(see later and turorial 4b!)
J. Knobloch, SRF 2007 25
Frequency scaling
• Measurements at 4.2 K and 1.8 K confirm the frequency dependance.
• Slight deviation at high frequencies due to anisotropy of niobium
Quadratic dependance
U. Klein, Thesis, Wuppertal Univ., WUB–DI 81–2 (1981)
J. Knobloch, SRF 2007 26
Temperature scaling
• Exponential dependance confirmed experimentally
• Measure Q factor of a cavity v. temperature
• Calculate surface resistance = G/Q0
H. Padamsee et. al, Cornell
J. Knobloch, SRF 2007 27
Impact of the purity of the superconductor
• Surface resistance decreases as the mean free path decreases (less pure)
• This is only valid as long as the coherence length is << mean free path
• Otherwise the first London equation (local equation) breaks down.
• In that case must replace:
• And thus the surface resistance increases when
⎟⎠⎞⎜
⎝⎛−∝ T
TR c3L
2ns
86.1explλω
l<<0ξ
l0
LLL 1ξλλ +=Λ⇒
nm640 =≤ ξl
J. Knobloch, SRF 2007 28
Impact of purity of superconductor
• Measurements have confirmed the general dependance on purity
• Sputtered niobium on copper
• By changing the sputtering species, the mean free path was varied (see Tutorial 6 (?))
C. Benvenuti et. al, Physica C 316 (1999)
J. Knobloch, SRF 2007 29
40RRR
nm64
nm33
9.1
K2.9
0
L
cB
c
===
=Δ=
ξλ
Tk
T
Calculating the surface resistance
3000 MHz
• Clearly, absolute calculation of surface resistance must take into account numerousparameters.
• Mattis & Bardeen developed theory based on BCS: „involves many tricky integrals“HSP
• Approximate expression for Nb:
• Program written by J. Halbritter to calculate resistance under wide range of conditions(J. Halbritter, Zeitschrift für Physik 238 (1970) 466)
• At Cornell: SHRIMP
• Must only supply a minimum numberof parameters
• Effect of material purity included
• Frequency dependance calculated
⎟⎠⎞
⎜⎝⎛ −
⎟⎠⎞
⎜⎝⎛Ω×≈ −
TT
fR
67.17exp
1
MHz1500102
24
BCS
Quadratic dependance
H. Lengeler et al., IEEE Trans. Magn MAG 21 1014
J. Knobloch, SRF 2007 30
Measured surface resistance
• Measured cavities display a behavior similar to the theoretical surface resistance
• Thus lowering the temperature furthershould always improve the dynamic losses
• But eventually the effect saturates
• Temperature independent term iscalled Residual Resistance
What is happening here?!
1 - 20 nOhm
H. Padamsee, Supercond. Sci. Technol. 14 (2001) R28–R51
J. Knobloch, SRF 2007 31
Pause
J. Knobloch, SRF 2007 32
Sources of residual resistance: Trapped flux
• Theory: Below Hc1, a superconductor always is in the Meissner State
• Reality: Nb „traps“ entire field if < 0.3 mT (even for high purity Nb)• Earths field (50 µT) would be completely trapped.
• The field penetrates the wall in „fluxoids“ of flux and normal conducting area
• The RF field „tugs“ on the fluxoids and because of their motiona current flows through the normal conducting region
• Total area of the NC region = number of fluxoids x AΦ.
• Number of fluxoids:
Fraction of surface in nc state =
Effective surface resistance due to trapped flux is:
e
hπ=Φ020πξ≈ΦA
2ξ0
n0
20ext0
ncav
RH
RA
ANR
Φ== ΦΦ
Φπξμ
0
cavext
0
flux external
Φ=
Φ=Φ
ABN
cavA
AN ΦΦ
Cool through TcCool through Tc
B < 0.3 mT
C. Valet et al., in Proc. EPAC 1992, p. 1295
J. Knobloch, SRF 2007 33
Trapped flux
• From the BCS theory we have:
• So that the contribution from trapped flux is simply:
• Note:1.Normal surface resistance scales as √f
resistivity due to flux trapping increases with frequency2.Resistivity decreases with increasing critical field
Thin film superconductors (which have a much higher critical field) are less susceptible to trapped flux.
• Some values: For Nb, Bc2 = 240 mT, at 1.5 GHz and 10 K, Rn ≈ 1.8 mΩ RΦ = 3.75 nΩ/µT
• In general (for Nb)
n0
20ext0 R
HR
Φ=Φ
πξμ
200
02c 2 ξπμ
Φ=H
n2c
ext
2R
H
HR ≈Φ
GHz1礣
n3 ext
fBR
Ω≈Φ
J. Knobloch, SRF 2007 34
Trapped flux due to earth‘s field
• Earth‘s field is 50 µT
Residual resistance (at 1.5 GHz) is = 175 nΩ• Hence for a pillbox cavity Q0 < 1.5 x 109
To achieve Q factors in the 1010 range, the earth‘s field must be shielded by at least a factor 10 – 20.
• Use µ-Metal for shielding
• + MAKE SURE NO MAGNETIC MATERIALS ARE NEAR THE CAVITY
• + Don‘t turn nearby magnets on until the cavity is superconducting
J. Knobloch, SRF 2007 35
Cavity with trapped flux
BCS Resistance + resistance due to trappedflux (1,25 µT)
Shielding was about a factor 40
J. Knobloch, SRF 2007 36
Generation of trapped flux
• Sometimes, during cavity tests, one observes a quench
• Cavity is heated locally above Tc due to• Defects on the surface• Electron bombardment from field emitters• Electron bombardment due to multipacting
• When the heating becomes to strong it drives the cavity normal conducting
• After the quench the Q-factor often is reduced
Details are covered in Tutorial 4b
J. Knobloch, SRF 2007 37
Generating trapped flux
• Perform measurements of the surface resistance in the region of the quench (with thermometry)
• After the quench, the surface resistance increased in this region
• Raising the temperature above Tc eliminates the additional resistivity
• Explanation: During the breakdown there is a large temperature gradient
• This creates a thermocurrent (Seeback effect) and hence a magnetic field
• As the cavity cools, the flux is trapped additional losses
• Warming the cavity above the critical temperature releases the flux
• Typical values:• Temperature gradient = few K/cm• Electrical resistivity of Nb: order 0.06 µΩ cm• Thermopower = order 0.1 µV/K (??)
current density is of order 3 A/cm2 and magnetic flux of order 200 µT
Resistance due to trapped flux of order 100s of nΩ (not an accurate calculation)
rthermopowe , =∇= TT STSE
Initially
After quenchWarm to 8 K
Warm to 11 K
New quenchTemperature map during quenchRatio surface resistance after quench to before
J. Knobloch, SRF 2007 38
The Q disease
• In the 80‘s and early 90‘s it was found that sometimes a good cavitycould go „bad“ when tests were repeated.
• This was especially the case when cavities were installed in „real“ accelerator modules
• This became known as the Q-disease
• What follows are some of the observations
J. Knobloch, SRF 2007 39
Losses due to hydrides: The Q disease
1E11
1E10
1E9
1E8
0 3 6 9 12 15Eacc (MV/m)
Low initial Q
Q drops further Q drops further with field
1st cooldown, vertical cavity test in a dewar (cooldown > 1 K/min)
For real accelerator modules have to coolslowly to avoid thermal stresses between components.
B. Aune et. al
Q0
B. Aune et. al, Proc. 1990 Linac Conference,
J. Knobloch, SRF 2007 40
Distribution of losses
Increased surface resistance is uniformly distributed (losses proportional to H 2)
Analyze loss-distribution using thermometry
R. Röth et. al, Proc. 5th SRF WS.
J. Knobloch, SRF 2007 41
The Danger Zone—100 K
1E11
1E10
1E9
1E80 2 4 6 8 10
Eacc (MV/m)
24 hr @ 175 K
24 hr @ 100 K
24 hr @ 75 K
24 hr @ 60 K
Danger zone: 75-150 K
300 K
24 hr @ T
2 K
J. Halbritter, P. Kneisel, K. Saito, Proc 6th SRF WS
J. Knobloch, SRF 2007 42
Room-Temperature Cycle
K. Saito & P. Kneisel
A room temperaturecycle removes the Q-virus
J. Knobloch, SRF 2007 43
Effect of Etching
• A heavy etch enhances the danger of the Q-virus
Light etch
Q virus free
3 µm etch + 100 K hold
Heavy etch
Q virus free
53 µm etch + 100 K hold
B. Bonin, B., and R. Röth, Proc. 5th SRF WS
J. Knobloch, SRF 2007 44
Effect of Niobium Purity
• High purity material is more susceptible
K. Saito & P. Kneisel
J. Knobloch, SRF 2007 45
Effect of Grain Size
Equator weld
Equator-weld region
Etched niobium
After fast cooldown
Following warm up to intermediate temp.
J. Knobloch, SRF 2007 46
Hydrogen
The most likely culprit is hydrogen:
• Nb-H system undergoes several phase transitions at low temperature, problems arise for concentrations greater than 2 wt ppm
• Mobile even at 120 K (300 µm in 1 hour!); not so other impuritiesDuring cooldown hydrogen moves to form high-concentration islands that precipitate to bad SC hydrides “weak superconductor”
• Cool quickly to < 100 K to “freeze” hydrogen in place
• Hydrogen likes to sit at “low-electron-density” sites in the niobiumnear the surface or at interstitial impuritiesfor impure niobium, much hydrogen is “bound” and cannot precipitate at the surface
• Copious hydrogen is present during BCP or EP and the protective oxide layer is missing
J. Knobloch, SRF 2007 47
Hydride Precipitation
Back
Disordered phase
Starting point
α + ν
α+ β
α+ η
J.F. Smith, Bulletin of Alloy Phase Diagrams, 4, 39–46 (1983).
J. Knobloch, SRF 2007 48
Avoiding the Q disease
How do we „vaccinate“ cavities against the Q disease?
• Buy niobium with little hydrogen to begin with (< 1 wt ppm)
• Etch your cavities with cold (< 15 C) acid
• Use a large acid volume to stabilize the temperature (exothermic reaction!)
• Vaccum-furnace bake at 700-900 C (P < 10-6 mbar) to drive out the hydrogen
J. Knobloch, SRF 2007 49
The Q disease: an example
• Tried a new scheme to remove acid without exposure to air• Was supposed to reduce field emission
• Following RF test showed VERY strong heatingin the lower portion of the cavity
• Presumably, acid removal in lower portion was probably slow
• Rather it diluted the acid slowly increased reaction rate
• How to solve the problem?• Heat the cavity to 900 C in a vacuum furnace (P < 10-6 mbar)• Hydrogen is removed and cavity performance recovered
Low Rs
Low Hc
J. Knobloch, SRF 2007 50
Achievable Surface Resistance
• With a carefully prepared cavity, well shielded from the earths field, one can achieve a veryhigh Q factor
• Surface resistance is around 1.3 nΩ• SHRIMP predicts a value around 1.8 nΩ for BCS losses
Power dissipation at 1 MV = 25 mW!
Could use an RF signal generator to run this cavity!
J. Knobloch, SRF 2007 51
Maximum Field
• What is the intrinsic field limitation of niobium cavities
MPFE
Q-slope
TB
?
1010
1011
0 10 20 30 40 50Eacc
Q0
Ideal
Real
Residual resistance
All this to be discussed in Tutorial 4b
J. Knobloch, SRF 2007 52
Cavity field limits
• Two field limits possible:• Electric field• Magnetic field
• Peak fields rather than accelerating field will be the limit
• Ratios play a vital role:
For pillbox
J. Knobloch, SRF 2007 53
Electric field limit
• BCS theory does not predict an electric field limit
• In real cavities, a practical electric field limit clearly exists: Field emission in high electricfield regions (Tutorial 4b)
• To test whether there is a fundamental field limit:• Design a cavity with relatively small Hpk/Eacc to eliminate any magnetic field limit• Pulse the cavity with high power (MW) in short time (µs) reach high field before field emission
can cause cavity quenches
• That way 145 MV/m (CW) and 220 MV/m (pulsed) peak fields have been achieved
• So far no fundamental electric-field limit observedD. Moffat et al., Proc. 4th SRF WSJ. Delayen and K. W. Shepard,Appl. Phys. Lett., 57(5):514
J. Knobloch, SRF 2007 54
Magnetic field limit
• BCS superconductivity does predict a magnetic field limit
• Intermediate state is lossy in RF field quenches cavity (see discussion on trapped flux)
must remain below Hc1?
• Not quite: Phase transition is first order (latent heat) it takes time to nucleate this (≈ 1µs)
• for short times can „superheat“ the field and remain in the Meißner State
• Theory predicts a superheating field Hsh = 240 mT (@ 0 K for Nb) Type-II superconductors
Meißner State
Intermediate State
Normal State
Bc1(170 mT)
Bc2(240 mT)
TemperatureTc
Mag
neti
cfi
eld
T
Limit (?)
Superheated state
Limit
• Temperature dependance of criticalfield is given by
⎥⎥⎦
⎤
⎢⎢⎣
⎡⎟⎟⎠
⎞⎜⎜⎝
⎛−=
2
cshsh 1)0()(
T
THTH
J. Knobloch, SRF 2007 55
Magnetic Field Limit
• Let‘s calculate an example with out Pillbox:• For Nb at 2 K: Bsh ≈ 231 mT
Eacc = 75 MV/m when Bpk = Bsh
Epk = 120 MV/m already exceeded with other cavities
• „Best real cavity results“ (@ 2 K)• Eacc = 52,3 MV/m• Epk = 116 MV/m• Bsh(229 mT) > Bpk = 197 mT > Bc1 (162 mT)
• At Bsh: Eacc = 60.9 MV/m
K.Saito, KEK
J. Knobloch, SRF 2007 56
Reaching the magnetic field limit
• To demonstrate the field limit Bpk = Bsh
• Apply short, high-power pulses to reach the maximum field before anomalous losses likethermal breakdown (due to particles) or field emission can kick in.
• Measure closer to Tc so that the superheating field is lower
• Clearly Hc1 has been exceeded and Hsh reached at higher temperatures
Hc1
Hsh
Measurement at KEK
T. Hays et. al, Proc. 8th SRF WS
⎥⎥⎦
⎤
⎢⎢⎣
⎡⎟⎟⎠
⎞⎜⎜⎝
⎛−=
2
cshsh 1)0()(
T
THTH
J. Knobloch, SRF 2007 57
Another „fundamental limit“: Global Thermal Instability
• Exponential increase of BCS surface resistance with temperature
Danger of thermal runaway (global quench, contrast with local quench)
Field limit is a direct consequence of RF superconductivity
2 K
0
200
400
600
800
1000
1200
1400
1600
1800
2000
2 2,5 3 3,5 4
T (K)
Su
rfac
e R
esis
tan
ce (
nO
hm
)
2.01 K2.10 K2.20 K2.35 K2.60K2.80K3.20KQuench
H
J. Knobloch, SRF 2007 58
GTI in 3 GHz Cavity
3 GHz
J. Graber, PhD thesis, Cornell University, 1993
J. Knobloch, SRF 2007 59
Global thermal insability
• To calculate onset need:• Surface resistance• Thermal conductivity of niobium• Kapitza conductivity into the helium bath
κT
K
J. Knobloch, SRF 2007 60
( ) ( )1
gB
31
3295 1exp
RRR
−−
⎟⎟⎠
⎞⎜⎜⎝
⎛+⎟
⎠⎞⎜
⎝⎛ Δ−Γ+⎟
⎠⎞
⎜⎝⎛ +
⋅=
BLTkTTTaT
LTTRT
ρκ
Thermal conductivity of niobium
• Thermal energy in a superconductor can be carried by electrons and lattice vibrations(phonons)• Cooper pairs do not scatter off lattice cannot transfer heat
only the normal „fluid“ is involved in heat transferLargest near Tc, then drops exponentiallySpecific heat due to electrons drops as T exp (-Δ/kBT)
• Only few phonons present at low temperatureElectronic contribution dominates near Tc
• Specific heat due to phonons only drop as T3
Phonons dominate at lowest temperatures
• Electronic contribution limited by:• NC electrons scattering off impurities (concentration determined by the RRR)• NC electrons scattering off phonons
• Phonon contribution limited by:• Phonons scattering off electrons• Phonons scattering off lattice defects, in particular grain boundaries
Electron contribution Phonon contribution
F. Koechling and B. Bonin, Supercond. Sci. Techn. 9 (1996)
J. Knobloch, SRF 2007 61
Thermal conductivity of niobium
To maximize thermal conductivity:• Decrease impurities of Nb (high RRR material)• Increase the size of the crystal grains
RRR 40= Λ 50祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 100= Λ 50祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 200= Λ 50祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 300= Λ 50祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 500= Λ 50祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 500= Λ 500祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 500= Λ 5 103× 祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
RRR 500= Λ 5 104× 祄=
2.31 4.63 6.94 9.251
10
100
1 .103
1 .104
KsTi( )watt
mK⋅
Ti
K
Phonon peak(high purity + large grains)
Rule of thumb: cond(4.2 K) = RRR/4
P. KneiselACCEL
J. Knobloch, SRF 2007 62
Kapitza Conductivity
• At the interface from the niobium to the helium, heat is transferred by phonons
• Theory not well understood, but generally dependance follows a T3 to T4 law
• Depends on the surface condition of the niobium
• Typical values are in the range 0.1-1 W/cm2 K
A. Bouchea et al., Proc. 7th SRF WS
J. Knobloch, SRF 2007 63
Global Thermal Instability
• Surface resistance, thermal conductivity and Kapitza conductivity are all non-linearMust simulate GTI
3 GHz
30 MV/m
J. Knobloch, SRF 2007 64
Typical thermal conductivity of niobium
Problem largest for• Cavities made of low thermal conductivity• Operation at temperatures where the BCS resistance is significant• High-frequency cavities, > 2 GHz (recall ω2 dependance of resistance)• Simulations at least partially validated by experiment
for highest gradients will need to stay at lowerfrequencies
J. Graber, PhD thesis, Cornell University, 1993
J. Knobloch, SRF 2007 65
Cavity modes in real cavities
• In reality one has to calculate the modes with field solvers. Simply adding beam tubesalready means there are no analytic solutions
• But can still identify the modes
• Length is still chosen according to the previous criterion
• Show a field map in a real cavity
J. Knobloch, SRF 2007 66
Different Cavity Designs: Trying to See the Forest for the Trees
NLC
J. Knobloch, SRF 2007 67
Different Cavities Designs
• First consideration is the speed of the particles to be accelerated• The slower the particles (ions) the shorter the gap:
• Application plays an important role (e.g., high current v. high energy)• Peak fields will play a role• + other issues that affect cavity geometry and the frequency
• Then consider SC or NC cavities• For NC cavities must reduce power dissipation with geometry
( )0
0
a
2
accaccdiss
RLE
P×
=
NLC
High current
2
cacc
RFTL
β=2/3
L0
a
2acc
th
ωQQ
RE
I×
∝
Ions
ß = 0.61
ß = 0.49
ß = 0.81 High energy
X X X
J. Knobloch, SRF 2007 68
Superconducting transition
• Measurement of surface resistancereveals a SC transition for degradedcavities
0.25 0.35 0.35 0.40 0.45 0.50 0.55 0.60 0.65
102
103
104
1/T (K-1)
Rs
(nΩ
)
BCS losses(drop exponentially)
Residual resistance
High residual losses
SC transition to weak superconductorat Tc = 2.2 K
Decreasing temperature
Saclay, 4 GHz