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Basic Water Chemistry
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BUILDING BLOCKS OF MATTER: ATOM
Neutrons : neutral in charge and are in the nucleus
Protons : positively charged and in the nucleus
Electrons : negatively charged, spin around the nucleus with negligible weight
FUNDAMENTAL STATES OF MATTER
Solids, liquids and gases are made up of molecules and elements.
In solids, molecules are joined together by strong and rigid bonds.
Liquid molecules have weaker bonds than solid and are not rigid.
There are no bonds between gas molecules and so it fills up any space it could.
IONS: ANIONS AND CATIONS
Cations are positively charged:
Na+, Mg2+, Ca2+, K+
Anions are negatively charged:
Cl-, SO42-, HCO3
-
UNITS OF MEASUREMENT IN CONCENTRATION
Milligrams per Liter (mg/L)
Parts per Million (ppm)
Parts per Billion (ppb) = µg/L
Equivalent Weight
CaCO3 Equivalent
+ =A B AB
EQUIVALENTS & CaCO3 EQUIVALENT
EQUIVALENTSEquivalents = Equivalent Weight = Thus, Equivalents = Mass of Ion X Example: Given 2.0 g/l of Ca2+ ; Eq =
CaCO3 EQUIVALENTCaCO3 equivalents = Example: 20.0 mg/l Ca2+ = CaCO3
CaCO3 EQUIVALENT
Customarily, total hardness, calcium hardness, and magnesium hardness is expressed in there CaCO3 equivalents. This equivalent extends to three forms of alkalinity – bicarbonate, carbonate, and caustic (or hydroxide).
pH The pH is an indication for the acidity of a substance. It is determined
by the number of free hydrogen ions (H+) in a substance. The pH is a very important factor, because certain chemical processes
can only take place when water has a certain pH.