b. Water Physical Properties

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    ENVIRONMENTAL

    TECHNOLOGY(CE20110)

    PROPERTIES OFWATER

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    Lesson Objectives Physical Properties:

    State of water.

    Density. Heat Capacity.

    Conductivity.

    Colour.

    Solubility

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    Introduction. Water is unique:

    Earth is the only planet known to contain this

    compound and present in all states.

    About 71% of the earth is covered with water

    and only 29% is landmass.

    Life on earth is dependent on it.

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    Introduction. Water is important:

    For human consumption.

    As a means of transport.

    As an energy provider, e.g. hydroelectric

    dams.

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    1a. States of water 3 physical states of water:

    Solid ice.

    Liquid water.

    Gaseous water (water vapor).

    Unusualas it can exist as all 3 states in the

    environment.

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    1a. States of water

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    1a. States of water

    Solid Ice Liquid water

    Gaseous water

    Melting

    Crystallising

    Condensing

    Boiling/

    Evaporation

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    1b. Density

    Density is the mass (weight) per unit

    volume.

    Usually expressed in units ofg/cm3.

    Relationship between mass and volume.

    Mass (weight)

    Density =

    Volume

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    1b. Density

    Ex: A solid has a mass of 45 kg and

    volume of3 m3. What is its density?

    Density = m/v

    = 45 kg/ 3 m3

    = 15 kg/m3

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    1b. Density

    Density of liquid water = 1.0 g/cm3.

    Density of solid ice = 0.92 g/cm3.

    Results:

    Ice floats on water.Freezing of pond or lake surfaces to

    preserve life in winter.

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    1b. Density Water expands when freezes.

    Examples:

    Keeping liquid water in a bottle and in the

    freezer.

    Bursting of pipes in cold weather.

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    1c. Specific Heat Capacity Amount of heat needed to raise 1 gof

    substance by 1C.

    Units is J (joules)/ g- C.

    For water it is 0.42 J/ g- C.

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    1c. Specific Heat Capacity Ex: To heat 50 kg of water from 30 C to 70

    DegC, the heat needed is:

    Energy = mc

    = 50kg x (70 30)C x 0.42J/g-C

    = 840000 J

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    1c. Heat Capacity Heat capacity is useful as:

    It can be used to calculate the amount of

    heat needed to heat up a given mass

    To calculate the capacity of a heat

    exchanger.

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    1d. Colour of water Pure water (100%) is colourless.

    (Not WHITE!)

    Colour in water is due to:

    Dissolved organic matter.

    Silt (mud, sand).

    Inorganic chemicals.

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    1d. Colour of water Filtering can only remove suspended

    matter (weeds, domestic waste etc.)

    Other dissolved materials can only be

    removed chemically.

    Eg: RO, distillation,

    Ion exchange

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    1e. Solids in water

    2 types of solids:

    Suspended solids.

    Dissolved solids.

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    1e. Solids in water

    Suspended solids:

    Solids that can be removed by a standardfilter or settling.

    Particle sizes varies a wide range.

    Large particles form suspensions (e.g. sand inwater).

    Fine particles form colloids (e.g. mud in

    water).

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    1e. Solids in water

    Dissolved solids:

    Examples: sugar, salt, etc. in water.

    Notretained by standard filters.

    Can only be removed by chemical means or by

    evaporation.

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    1e. Solids in water

    Residue:

    The solids (both dissolved and suspended)

    that remains after the water is removed.

    Total Solids (TS).

    Unit is in mg/L orppm.

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    1e. Solids in water

    Turbidity:

    Amount ofsuspendedsolids in a water

    sample.

    Measured using a nephelometer, by

    measuring the amount of light scattered.

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    1f. Temperature of water

    Important as it affects other properties of

    water.

    Examples:

    Reaction rates.

    Solubility of gases.

    Solubility of solids such as salt, sugar.

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    1g. Electrical Conductivity It is the ability of water to conduct

    electricity.

    Pure water is a poor electrical conductor.

    Conductivity improves when salts are

    added.

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    1g. Electrical Conductivity Electrical conductivity is expressed in micro-

    siemens (mS).

    Drinking water measures about 50 -1500 mS.

    Industrial water measures more than10 000 mS.

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    1g. Electrical Conductivity

    Can be measured using a conductivity

    meter(Lab Experiment).

    Different concentrations of salts will give

    different conductivity values.