B PROec.europa.eu/.../pdf/syntesis_report_annex2.pdf · 2016-04-19 · 4.1 Total annual emissions of POPs as reported in EMEP WebDab -> PCB? ... 4.7 Comparison of EMEP WebDab emissions

European Commission, Brussels

Support related to the international and Community work on Persistent Organic Pollutants

Reference: 070307/2007/465073/MAR/D1

Up-dated Synthesis report 2009

Annex II

08 July 2009

BIPRO

Beratungsgesellschaft für integrierte Problemlösungen

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Updated Synthesis Report 2009 Support related to the international and Community work on Persistent Organic Pollutants

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Annex II

3 OVERVIEW ON POPS EMISSION WITHIN THE EUROPEAN UNION ......................... 1

4 EMEP WEBDAB ........................................................................................................... 3

4.1 Total annual emissions of POPs as reported in EMEP WebDab -> PCB? .................... 3

4.2 NFR codes for Source Sectors covered by reporting on POPs in EMEP WebDab ....... 4

4.3 Sector distribution for PAH as reported in EMEP WebDab ........................................... 5

4.4 Sector distribution for PCDD/PCDF as reported in EMEP WebDab .............................. 7

4.5 Sector distribution for HCB as reported in EMEP WebDab ........................................... 9

4.6 Sector distribution for PCB as reported in EMEP WebDab ..........................................11

4.7 Comparison of EMEP WebDab emissions 1995 – 2006 in MS reporting both years ....13

4.8 Per capita calculation of POP emissions within the European Union from EMEP

WebDab ......................................................................................................................14

5 EMEP MSC-E CALCULATION ................................................................................... 15

5.1 Total annual emissions of POPs as calculated by EMEP MSC-E -> 2006? .................15

5.2 Trend of PAH emissions within the European Union from EMEP MSC-E ....................16

5.3 Trend of PCDD/PCDF emissions within the European Union from EMEP MSC-E .......22

5.4 HCB emissions within the European Union from EMEP MSC-E ..................................24

5.5 Per capita calculation of POP emissions within the European Union from EMEP MSC-E

....................................................................................................................................26

6 EU-EPER .................................................................................................................... 28

6.1 Categories of industrial activities and capacity threshold under EPER ........................28

6.2 Synthesis reports for PAH reported under EU-EPER ..................................................34

6.3 Synthesis reports for PCDD/PCDF reported under EU-EPER .....................................39

6.4 Synthesis reports for HCB reported under EU-EPER ..................................................41

6.5 Overview on EU-EPER releases for 2001 and 2004 by countries and industry sectors

reporting in both cycles ...............................................................................................43

7 E-PRTR PILOT INVENTORY ON RELEASES FROM DIFFUSE SOURCES .............. 46

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7.1 Source sectors covered in the pilot inventory on releases from diffuse sources ..........46

7.2 Reported Member State POPs emission to air from diffuse sources ...........................47

7.3 PAH ―diffuse‖ emissions by source sector and Member State .....................................48

7.4 PCDD/PCDF ―diffuse‖ emissions by source sector and Member State ........................49

7.5 HCB ―diffuse‖ emissions by source sector and Member State .....................................50

7.6 PCB ―diffuse‖ emissions by source sector and Member State .....................................51

8 DETAILS ON POP RELEASES ACCORDING TO ARTICLE 12 REPORTS .............. 52

8.1 Austria .........................................................................................................................52

8.2 Belgium .......................................................................................................................56

8.3 Bulgaria .......................................................................................................................58

8.4 Cyprus .........................................................................................................................60

8.5 Denmark .....................................................................................................................62

8.6 Finland ........................................................................................................................64

8.7 France .........................................................................................................................65

8.8 Germany .....................................................................................................................67

8.9 Italy .............................................................................................................................72

8.10 Lithuania .....................................................................................................................73

8.11 Romania ......................................................................................................................75

8.12 Slovak Republic ..........................................................................................................80

8.13 Slovenia ......................................................................................................................86

8.14 Spain ...........................................................................................................................87

8.15 Sweden .......................................................................................................................88

8.16 United Kingdom ...........................................................................................................90

9 ENVIRONMENTAL LEVEL OF POPS WITHIN THE EUROPEAN UNION FROM

EMEP MSC-E-COUNTRY REPORTS ......................................................................... 95

9.1 Average PCDD/PCDF concentrations in environmental compartments as reported in

EMEP country reports .................................................................................................95

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9.2 Average PAH concentrations in environmental compartments as reported in EMEP

country reports ............................................................................................................97

9.3 Detailed concentrations of single PAH congeners in environmental compartments in

Austria, Belgium and Bulgaria ................................................................................... 100


Cyprus, Czech Republic, Germany ........................................................................... 101


Denmark, Estonia, Spain ........................................................................................... 102


Finland, France, Greece ............................................................................................ 103


Hungary, Ireland, Italy ............................................................................................... 104


Lithuania, Luxembourg, Latvia .................................................................................. 105


Malta, the Netherlands, Poland ................................................................................. 106


Portugal, Romania, Sweden ...................................................................................... 107


Slovenia, Slovakia, United Kingdom .......................................................................... 108

9.12 Long-range transboundary transport of PCDD/PCDF and B[a]P in Austria ................ 109

9.13 Long-range transboundary transport of PCDD/PCDF and B[a]P in Belgium .............. 110

9.14 Long-range transboundary transport of PCDD/PCDF and B[a]P in Bulgaria .............. 111

9.15 Long-range transboundary transport of PCDD/PCDF and B[a]P in Cyprus ............... 112

9.16 Long-range transboundary transport of PCDD/PCDF and B[a]P in Czech Republic .. 113

9.17 Long-range transboundary transport of PCDD/PCDF and B[a]P in Germany ............ 114

9.18 Long-range transboundary transport of PCDD/PCDF and B[a]P in Denmark ............ 116

9.19 Long-range transboundary transport of PCDD/PCDF and B[a]P in Estonia ............... 117

9.20 Long-range transboundary transport of PCDD/PCDF and B[a]P in Spain .................. 118

9.21 Long-range transboundary transport of PCDD/PCDF and B[a]P in Finland ............... 119

9.22 Long-range transboundary transport of PCDD/PCDF and B[a]P in France ................ 120

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9.23 Long-range transboundary transport of PCDD/PCDF and B[a]P in Greece ............... 121

9.24 Long-range transboundary transport of PCDD/PCDF and B[a]P in Hungary ............. 122

9.25 Long-range transboundary transport of PCDD/PCDF and B[a]P in Ireland ................ 123

9.26 Long-range transboundary transport of PCDD/PCDF and B[a]P in Italy .................... 124

9.27 Long-range transboundary transport of PCDD/PCDF and B[a]P in Lithuania ............ 125

9.28 Long-range transboundary transport of PCDD/PCDF and B[a]P in Luxembourg ....... 126

9.29 Long-range transboundary transport of PCDD/PCDF and B[a]P in Latvia ................. 127

9.30 Long-range transboundary transport of PCDD/PCDF and B[a]P in Malta .................. 128

9.31 Long-range transboundary transport of PCDD/PCDF and B[a]P in the Netherlands .. 129

9.32 Long-range transboundary transport of PCDD/PCDF and B B[a]P in Poland ............ 130

9.33 Long-range transboundary transport of PCDD/PCDF and B[a]P in Portugal ............. 131

9.34 Long-range transboundary transport of PCDD/PCDF and B[a]P in Romania............. 132

9.35 Long-range transboundary transport of PCDD/PCDF and B[a]P in Sweden .............. 133

9.36 Long-range transboundary transport of PCDD/PCDF and B[a]P in Slovenia ............. 134

9.37 Long-range transboundary transport of PCDD/PCDF and B[a]P in Slovakia ............. 135

9.38 Long-range transboundary transport of PCDD/PCDF and B[a]P in the United Kingdom

.................................................................................................................................. 136

9.39 Balance of long-range transboundary transport of PCDD/PCDF and B[a]P in EU

Member States .......................................................................................................... 137

9.40 Environmental level of POPs according to Article 12 reports ..................................... 138

9.41 Environmental level of POPs according to NIPs ........................................................ 150

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3 Overview on POPs emission within the European Union

AIR PAH (t/a) PCDD/ PCDF (TEQ g/y)

MS Article 12

report year (Art. 12 report)

EMEP WebDab (2005)

EMEP WebDab corr.

(2005) ?

EMEP - MSC-E (2005)

EPER (2004)

PRTR diffuse (2003)

Article 12 report

year (Art. 12 report)

EMEP-WEB-DAB (2005)

EMEP - MSC-E (2005)

Article 15 report (2004)

EPER (2004)

PRTR diffuse (2003)

AT 8.9 2005 8.87 8.87 9.10 0.29 8.78 42.6 2005 42.62 43.00 1.47 35.00

BE 6.6*** 2000 242.26 242.26 17.80 24.53 106.00 43.6**** 2005 64.51 65.00 29.70 3.40

BG 129.75 2006 124.02 124.02 21.10 244.86 2006 229.53 230.00 0.00

CY 22.23 2005 3.94 3.94 3.90 5.84 2005 5.13 5.10 1.44

CZ 2.20* 2005 24.18 24.18 24.20 2.63 0.74 285.00 2005 178.57 179.00 345.00 0.33

DE 98 ** 2005 97.96 97.96 81.40 1.47 0.90 73.73 2005 73.73 74.00 116.00 106.10 0.00

DK 13.22 2005 13.22 13.22 13.20 5.86 25.30 2005 25.31 25.00 14.80

EE 12.58 12.58 12.60 0.17 10.90 3.27 3.30 1.67

ES 152.06 152.06 151.00 38.80 50.30 149.20 146.00 75.60 42.20

FI 13.2 2005 13.32 13.32 13.20 1.21 0.82 26.2 2005 26.18 26.00 0.92

FR 24.70 2005 24.66 24.66 24.60 8.66 34.90 220.00 2005 220.44 220.00 219.80 37.70

GR 24.50 0.00 159.00 0.00

HU 23.45 23.45 23.50 0.82 91.76 92.00 2.50 2.49

IE 10.9 2005 10.97 10.97 10.70 11.40 26.3 2005 26.27 26.00 7.81

IT 130 2005 134.27 134.27 132.00 28.04 0.00 298 2005 298.40 298.00 92.10 0.00

LT 15.56 2005 15.56 15.56 15.50 20.90 10.87 2005 10.87 11.00 9.69

LU 0.22 2003 1.40 1.68 2003 1.60 0.00

LV 35.13 35.13 35.50 5.85 19.18 19.00 0.00

MT 0.00

NL 483 2005 482.90 482.90 14.20 72.97 408.00 28 2005 27.96 28.00 34.30

PL 165.37 2005 165,369.00 165.37 166.00 1,186.65 0.46 417.30 2005 416.36 416.00 246.00 2.83

PT 37.40 1.12 574.00 11.60 0.00

RO 17.06 17.06 51.20 98.87 99.00 0.00

SE 16.87 16.87 16.80 10.98 14.80 38.58 39.00 20.70 2.96

SI 28.75 2005 28.75 28.75 7.70 1.65 4.94 9.30 2005 9.30 9.30 0.91

SK 19 2005 19.20 19.20 19.30 86 2005 85.93 86.00 0.00

UK 11.00 11.00 11.00 5.95 6.53 348.00 2004 204.52 205.00 68.90 21.50

total 399.79 166,881.21 1,677.58 938.80 1,390.95 681.78 1,568.15 2,346.48 3,079.30 1,121.90 219.94

* corresponds to releases according to PRTR (see also EPER); total release corresponds to EMEP figure

** Total PAH (Sum 16); *** Bruseels Capital Region only; **** Flanders only

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AIR PCB 153 (kg/y) Total PCB (kg/y) HCB (kg/y)

MS EMEP - MSC-E (2004) Article 12

report year (Art. 12

report)

EMEP WebDab (2005)

PRTR diffuse (2003)

Article 12 report

year (Art. 12 report)

EMEP WebDab (2005)

EMEP - MSC-E (2005)

EPER (2004)

PRTR diffuse (2003)

AT 53.00 46 2005 45.41 45.00 42.10

BE 374.00 36.03 36.00 21.00

BG 11.00 281.60 2006 258.68 24.70 2006 19.20 19.00

CY 2.70 30.00 2005 0.13 2005 0.30 0.30

CZ 125.00 0.10* 2005 82.32 0.00 2005 4.70 4.70

DE 885.00 17.6 2005 17.57 1.90 1.90

DK 12.00 115.00

EE 19.00 49.67 6.00 0.20 0.20 0.09

ES 853.00 7,738.38 7,678.70 14.60 5,630.00

FI 42.00 0.12 35.7 2005 35.70 36.00 16.70

FR 1,473.00 27.20 2005 27.18 16.10 18.00 2005 18.10 18.00 7.98

GR 18.00 175.00

HU 12.00 0.84 6.10 6.10 0.03

IE 15.00 0.1 2005 0.10 0.10

IT 857.00 286 2005 24 2005 795.00

LT 38.00 25.06 2005 25.10 7.40 na. 2005 176.00

LU 2.70 0.00 2003 1.54 2003 1.50

LV 32.00 6.12 0.50 0.50

MT 1.30

NL 15.00 92.00

PL 42.00 2,281.00 2005 2,281.48 2.92 8.96 2005 8.90 9.00 0.08

PT 11.00 145.00 23.70

RO 25.00 1.56 1,288.50 0.30

SE 56.00 0.10 0.08 0.02 0.00 0.02

SI 42.00 2005 42.00 61.00 0.26 2005 0.30 0.30

SK 35 2005 34.67 2.0 2005 2.00 2.00

UK 313.00 1,330.00 2004 1,027.80 7.11 851.39 851.00 271.00

total 5,287.70 4,016.86 3,854.38 101.45 53.59 10,057.73 10,208.60 76.00 5,951.30

* corresponds to releases according to PRTR (see also EPER); total release corresponds to EMEP figure

Table 3-1: Overview on reported POP emissions per country and data source (Source: EMEP WebDab, EMEP MSC-E, EU-EPER, E-PRTR)

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4 EMEP WEbDab

4.1 Total annual emissions of POPs as reported in EMEP WebDab

PAH [t/y]

1995 2006* PCDD/F

[g/y] 1995 2006*

HCB [kg/y]

1995 2006 PCB

[kg/y] 1995 2006*

AT 9.60 8.73 AT 58.17 43.69 AT 52.84 43.10 AT no data 1995 to 2005 NR

BE 256.02 241.42 BE 402.43 55.22 BE 29.57 46.55 BE 0.01 n.d.

BU oldest data: 2000 129.66 BU oldest data: 2001 247.26 BU oldest data: 2001 24.70 BU oldest data: 2001 281.70

CY oldest data: 2004 21.19 CY 6.18 5.86 CY 0.30 0.12 CY no data 1995 to 2005 30.69

CZ oldest data: 2000 17.12 CZ oldest data: 2001 174.78 CZ oldest data: 2002 3.69 CZ oldest data: 2001 88.76

DE 87.94 101.12 DE 78.45 84.61 DE 1.60 2.04 DE 17.27 17.66

DK 7.87 13.54 DK 49.35 24.76 DK no data 1995 to 2005 NA DK no data 1995 to 2005 NA

EE 14.47 11.71 EE 4.51 2.66 EE 0.10 0.12 EE 51.77 45.84

ES 228.13 217.66 ES 158.96 158.02 ES 4859.82 7,653.30 ES no data 1995 to 2005 0.00

FI 16.90 13.41 FI 33.80 14.24 FI oldest data: 2003 42.54 FI only data: 2004 176.80

FR 38.89 23.96 FR 1,695.22 127.10 FR 74.60 13.43 FR 38.33 26.03

GR no data for 1995 to 2006 GR no data for 1995 to 2006 GR no data 1995 to 2006 GR no data for 1995 to 2006

HU oldest data: 2001 22.83 HU oldest data: 2002 92.31 HU oldest data: 2002 7.10 HU data only for 2002 and 2003 NA

IE oldest data: 2001 10.97* IE oldest data: 2001 26.27* IE oldest data: 2002 0.10 IE no data for 1995 to 2005

IT 111.23 134.36 IT 502.80 301.95 IT no data 1995 to 2005 0.02 IT no data 1995 to 2005 0.25

LT oldest data: 2002 15.99 LT oldest data: 2002 11.20 LT no data 1995 to 2005 NA LT oldest data: 2002 26.21

LU no data for 1995 to 2006 LU no data for 1995 to 2006 LU no data for 1995 to 2006 LU no data for 1995 to 2006

LV 34.20 33.75 LV 11.50 13.84 LV 0.40 0.45 LV 8.50 5.22

MT no data 1995 to 2005

0.00 MT no data 1995 to 2005 0.00 MT

no data 1995 to 2005 0.00 MT

no data 1995 to 2005 0.00

NL 899.94 462.40 NL 66.02 35.41 NL no data 1995 to 2005 0.00 NL no data 1995 to 2006

PL oldest data: 2001 161.99 PL oldest data: 2001 449.26 PL oldest data: 2001 8.62 PL oldest data: 2001 2,291.89

PT no data 1995 to 2005

10.36 PT no data 1995 to 2005 8.99 PT

no data 1995 to 2005 NE PT

no data 1995 to 2005 1,064.30

RO oldest data: 2005 16.55 RO oldest data: 2005 267.77 RO oldest data: 2005 1.68 RO oldest data: 2005 1.52

SE 16.43 18.24 SE 39.62 37.47 SE 0.02 0.02 SE 0.07 0.09

SI oldest data: 2000 10.20 SI oldest data: 2000 7.23 SI oldest data: 2000 0.30 SI oldest data: 2000 47.49

SK oldest data: 2000 18.18 SK oldest data: 2000 66.71 SK oldest data: 2000 2.21 SK oldest data: 2000 34.47

UK 97.39 11.10 UK 712.90 196.95 UK 4549.37 813.22 UK 4,891.30 1,003.48

TOTAL 1,819 1,715.45 3,820 2,427.31 9,569 8,663.19 5,007 5,142.41

*data IE 2005 *data IE 2005

Table 4-1: Total annual emissions of POPs per country 1995 and 2006 (Source: EMEP WebDab)

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4.2 NFR codes for Source Sectors covered by reporting on POPs in

EMEP WebDab

NFR /CRF Code Source sector

NO2 01 Combustion in Power Plants and Industry

N02 02a Transport above 1000 m (Aviation international)

N02 02b Transport below 1000 m (Aviation international)

N02 03 Commercial, Residential and other stationary Combustion Sources

N02 04 Fugitive Emissions from Fuels

N02 05 Industrial Processes

N02 06 Solvent and other Product Use

N02 07 Agriculture

N02 08 Waste

N02 Natural

Table 4-2: Overview on CRF/NFR codes corresponding to source sectors covered by POP

reporting under EMEP WebDab

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4.3 Sector distribution for PAH as reported in EMEP WebDab

PAH

[t/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

Residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use

Agriculture Waste

Natural

(not

included

in total)

Austria 8.73 0.20 0 1.59 6.52 0 0.22 0 0.20 0.00 0

Belgium 241.42 3.16 0 87.20 84.59 13.88 41.01 11.55 0 0.04 0

Bulgaria 129.66 5.81 0 67.48 39.60 0.60 16.17 0 0 0.00 0

Cyprus 21.19 0 0 0.05 20.33 0 0.01 0 0.74 0.06 0

Czech Rep. 17.12 0.93 0.00 0 12.78 2.13 0 0 0 0 0

Denmark 13.54 0 0 0.27 13.04 0 0 0 0 0 0

Estonia 11.71 2.12 0 0.04 9.55 0 0 0 0 0 0

Finland 13.41 0.49 0 1.04 10.47 1.30 0.02 0.05 0 0.02 0

France 23.96 0.36 0 4.70 18.69 0 0.22 0 0 0.00 0

Germany 101.12 1.43 0 1.77 90.12 2.21 5.60 0 0 0 0

Greece NN

Hungary 22.83 0.22 0 3.15 18.04 1.43 0 0 0 0 0

Ireland NN

Italy 134.36 0.73 0.00 2.69 53.99 0 44.48 0.01 0 32.45 0

Latvia 33.75 1.75 0 2.65 25.51 0 0 0 3.83 0.00 0

Lithuania 15.99 0.13 0.00 0.08 15.78 0 0 0 0 0 0

Luxembourg NN

Malta 0 0 0 0 0 0 0 0 0 0 0

Netherlands 462.40 8.23 0 70.36 74.34 0.04 98.71 210.72 0 0 0

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PAH

[t/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

Residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use

Agriculture Waste

Natural

(not

included

in total)

Poland 161.99 0.80 1.80 139 14.90 5.39 0.01 0 0 0

Portugal 10.36 6.60 0 0.21 0.70 0 0 0 0 2.86 0

Romania 16.55 1.92 0 0.23 13.82 0.54 0.04 0 0 0 0

Slovakia 18.18 1.61 0 0.12 15.05 0 1.28 0 0.12 0.01 0

Slovenia 10.20 0.05 0.00 0.10 9.61 0 0.44 0.00 0 0 0

Spain 217.66 51.66 0.15 3.13 19.82 1.29 46.89 0.00 94.70 0.01 0

Sweden 18.24 0.80 0 0.10 8.03 1.20 8.08 0 0 0.03 0

United Kgd. 11.10 0.76 0 1.43 4.24 0.57 0.64 0.06 0 3.40 6.76

EU TOTAL

(t/y) 1,715.45 90.00 0.15 250.19 703.70 40.08 263.78 222.39 99.59 38.88 6.76

Table 4-3: Sectoral share of PAH emissions per country 2006 (Source: EMEP WebDab)

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4.4 Sector distribution for PCDD/PCDF as reported in EMEP WebDab

PCDD/PCDF

[g TEQ/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use

Agriculture Waste

Natural

(not

included

in total)

Austria 43.69 5.99 0 1.16 31.47 0 4.76 0 0.15 0.17 0

Belgium 55.22 0.93 0 0.36 36.77 0.42 13.00 0 0 3.75 0

Bulgaria 247.26 119.59 0 28.32 71.96 0 23.42 0 0 3.97 0

Cyprus 5.86 0.12 0 0.03 0.70 0 0.09 0 0.27 4.65 0

Czech Rep. 174.78 86.05 0.00 0 14.50 0.41 0 0 0 0 0

Denmark 24.76 1.87 0 0.25 16.48 0.00 6.12 0 0 0.04 0

Estonia 2.66 1.24 0 0.05 1.32 0 0 0 0 0.05 0

Finland 14.24 5.09 0 2.72 1.10 0 4.96 0.00 0 0.17 0

France 127.10 44.55 0 2.36 22.48 1.27 14.17 0 0 42.27 0

Germany 84.61 6.93 0 3.64 23.77 1.70 48.43 0 0 0.13 0

Greece

Hungary 92.31 30.10 0 1.40 17.61 2.76 3.17 0 37.19 0.09 0

Ireland NN

Italy 301.95 129.98 0 2.49 43.78 0 87.80 0 0 37.90 0.40

Latvia 13.84 5.84 0 0.02 6.45 0 0.31 0 1.16 0.06 0

Lithuania 11.20 1.42 0 0.24 9.54 0 0 0 0 0 0

Luxembourg NN

Malta 0 0 0 0 0 0 0 0 0 0 0

Netherlands 35.41 8.69 0 0.67 4.57 0 4.24 17.00 0 0.25 0

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PCDD/PCDF

[g TEQ/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use

Agriculture Waste

Natural

(not

included

in total)

Poland 449.26 46.73 0 0.69 201.38 2.88 14.82 0 0 182.24 0

Portugal 8.99 3.80 0 0 5.19 0 0 0 0 0.00 0

Romania 267.77 88.31 0 0.19 77.51 5.37 36.33 0 0 60.05 0

Slovakia 66.71 34.92 0 0.14 3.68 0 5.78 0 0.63 21.57 0

Slovenia 7.23 0.82 0 0.08 6.09 0 0.23 0 0 0.01 0

Spain 158.02* 78.55 0 8.10 31.60 0 29.42 0 5.72 4.62 0

Sweden 37.47 27.04 0 0.62 2.89 0 5.86 0 0 1.07 0

United Kgd. 196.95 51.89 0 5.63 12.74 0.67 24.03 0 0 101.99 66.39

EU TOTAL

(g/y) 2,427.31 780.45 0.00 59.16 643.56 15.69 326.95 17.00 45.11 465.05 66.79

Table 4-4: Sectoral share of PCDD/PCDF emissions per country 2006 (Source: EMEP WebDab)

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4.5 Sector distribution for HCB as reported in EMEP WebDab

HCB

[kg/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

Residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use

Agriculture Waste Natural

Austria 43.10 1.84 0 0.23 37.20 0 3.76 0 0.03 0.03 0

Belgium 46.55 0 0 0 0 0 45.54 0 0 1.01 0

Bulgaria 24.70 0 0 0 0 0 24.70 0 0 0 0

Cyprus 0.12 0 0 0.05 0 0 0.02 0 0.02 0.03 0

Czech Rep. 3.69 3.34 0.00 0.00 0.27 0 0 0 0 0 0

Denmark NA 0 0 0 0 0 0 0 0 0 0

Estonia 0.12 0.04 0 0 0.08 0 0 0 0 0 0

Finland 42.54 0.31 0 0.23 2.90 0 34.96 0.00 0.03 4.11 0

France 13.43 3.18 0 7.63 1.09 0 0 0 0 1.54 0

Germany 2.04 0.75 0 0 1.01 0 0.27 0 0 0 0

Greece NN

Hungary 7.10 4.88 0.00 0.00 0.22 0 1.19 0 0 0.81 0

Ireland NN

Italy 0.02 0.00 0 0.01 0.01 0 0 0 0 0.01 0

Latvia 0.45 0.10 0 0 0.34 0 0.00 0 0 0 0

Lithuania NA 0 0 0 0 0 0 0 0 0 0

Luxembourg NN

Malta 0 0 0 0 0 0 0 0 0 0 0

Netherlands 0 0 0 0 0 0 0 0 0 0 0

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HCB

[kg/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

Residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use


Poland 8.62 6.12 0 0.03 1.68 0 0 0 0 0 0

Portugal NE 0 0 0 0 0 0 0 0 0 0

Romania 1.68 1.39 0 0 0 0 0.29 0 0 0 0

Slovakia 2.21 1.18 0 0.01 0.17 0 0.05 0 0.01 1 0

Slovenia 0.30 0.11 0.00 0.09 0.08 0 0.01 0 0 0 0

Spain 7,653.30 3.46 0 0.18 0.09 0 385.43 0 7264.08 0 0

Sweden 0.02 0 0 0.01 0.01 0 0 0 0 0 0

United Kgd. 813.22 1.70 0 0 0.07 0 23.45 0 787.51 0.48 0

EU TOTAL (t/y) 8,663.19 28.42 0.00 8.48 45.21 0.00 519.68 0.00 8,051.68 8.88 0.00

Table 4-5: Sectoral share of HCB emissions per country 2006 (Source: EMEP WebDab)

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4.6 Sector distribution for PCB as reported in EMEP WebDab

PCB

[kg/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

Residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use


Austria NR 0 0 0 0 0 0 0 0 0 0

Belgium 0 0 0 0 0 0 0 0 0 0 0

Bulgaria 281,70 46.19 0 60.11 175.34 0 0 0 0 0.07 0

Cyprus 30,69 0 0 0 0.34 0 0 0 0 30.35 0

Czech Rep. 88,76 9.03 0.00 35.12 7.31 0 0 0 0 0 0

Denmark NA 0 0 0 0 0 0 0 0 0 0

Estonia 45,84 40.31 0 0 5.53 0 0 0 0 0 0

Finland 176,80 0.25 0 19.10 6.27 16.35 22.14 0 0 112.69 0

France 26,03 5.48 0 0.33 16.14 0 0 0 0 4.09 0

Germany 17,66 0.60 0 0 0 0 17.06 0 0 0 0

Greece NE

Hungary NN

Ireland 0 0 0 0 0 0 0 0 0 0 0

Italy 0,25 0.10 0 0 0 0 0 0 0 0.00 0

Latvia 5,22 1.43 0 0 3.79 0 0 0 0 0 0

Lithuania NN

Luxembourg 26,21 6.69 0 11.94 7.59 0 0 0 0 0 0

Malta NO 0 0 0 0 0 0 0 0 0 0

Netherlands 0 0 0 0 0 0 0 0 0 0 0

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PCB

[kg/y] Total

Combustion

in power

plants and

industry

Transport

above

1000 m

Transport

below

1000 m

Commercial,

Residential

and other

stationary

combustion

Fugitive

Emissions

from Fuel

Industrial

Processes

Solvent

and other

Product

use


Poland 2.291,89 135.53 0 90.03 397.71 0 1,667* 0 0 0 0

Portugal 1.064,30 941.34 0 0 0 0 0 0 0 122.96 0

Romania 1,52 0 0 0 0 0 1.26 0 0 0.26 0

Slovakia 34,47 8.25 0 12.19 9.94 0 2.08 0 0.08 1.94 0

Slovenia 47,49 19.98 0 0 3.90 0 6.02 17.57 0 0.02 0

Spain 0 0 0 0 0 0 0 0 0 0 0

Sweden 0,09 0 0 0.06 0.03 0 0 0 0 0 0

United Kgd. 1.003,48 80.61 0 0 5.04 6.20 744.43 0 0 167.20 0

EU TOTAL

(kg/y) 5,142.41 1,295.77 0.00 228.87 638.96 22.56 793.10 17.57 0.08 439.58 0.00

Table 4-6: Sectoral share of PCB emissions per country 2006 (Source: EMEP WebDab)

* = dominated by 060507 electric power equipment

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4.7 Comparison of EMEP WebDab emissions 1995 – 2006 in MS reporting both years

PAH

[t/y] 1995 2006

PCDD/F

[g/y] 1995 2006

HCB

[kg{y] 1995 2006

PCB

[kg/y] 1995 2006

NL 900 462 FR 1,695 127 ES 4,859.82 7,653.30 UK 4,891.30 1,003.48

BE 256 241 UK 713 197 UK 4,549.37 813.22 EE 51.77 45.84

ES 228 218 IT 503 302 FR 74.60 13.43 FR 38.33 26.03

IT 111 134 BE 402 55 AT 52.84 43.10 DE 17.27 17.66

UK 97 11 ES 159 158 BE 29.57 46.55 LV 8.49 5.22

DE 88 101 DE 79 85 DE 1.60 2.04 SE 0.07 0.09

FR 39 24 NL 66 35 LV 0.40 0.45 Total 5,007 1,098

LV 34 34 AT 58 44 CY 0.30 0.12

FI 17 13 DK 49 25 EE 0.10 0.12

SE 16 18 SE 40 37 SE 0.02 0.02

EE 15 12 FI 34 14 Total 9,569 8,572

AT 10 9 LV 12 14

DK 8 14 CY 6 6

Total 1,819 1,291 EE 5 3

Total 3,820 1,102

Table 4-7: Trend of reported POP air emissions 1995 and 2006 in MS reporting to EMEP WebDab in both years

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4.8 Per capita calculation of POP emissions within the European Union from EMEP WebDab

PAH [t/a]

Inhab. [Mio]

per capita [g/y]

PCDD/F [g/a]

Inhab. [Mio]

per capita [μg/y]

HCB [kg/y]

Inhab. [Mio]

per capita [mg/y]

PCB [kg/a]

Inhab. [Mio]

per capita [mg/y]

AT 8.87 8.30 1.07 AT 42.62 8.30 5.13 AT 45.41 8.30 5.47 BG 258.68 7.70 33.60

BE 242.26 10.50 2.31 BE 64.51 10.50 6.14 BE 36.03 10.50 3.43 CZ 82.32 10.30 7.99

BG 124.02 7.70 1.61 BG 229.53 7.70 29.81 BG 19.20 7.70 2.49 DE 17.57 82.50 0.21

CY 3.94 0.80 0.49 CY 5.13 0.80 6.41 CY 0.30 0.80 0.38 EE 49.67 1.30 38.21

CZ 24.18 10.30 0.23 CZ 178.57 10.30 17.34 CZ 4.70 10.30 0.46 FI 0.12 5.30 0.02

DE 97.96 82.50 0.12 DE 73.73 82.50 0.89 DE 1.90 82.50 0.02 FR 27.18 60.90 0.45

DK 13.22 5.40 0.24 DK 25.31 5.40 4.69 EE 0.20 1.30 0.15 LT 25.10 3.40 7.38

EE 12.58 1.30 0.97 ES 149.20 43.80 3.41 ES 7,738.38 43.80 176.68 LV 6.12 2.30 2.66

ES 152.06 43.80 0.35 FI 26.18 5.30 4.94 FI 35.70 5.30 6.74 PL 2,281.48 38.10 59.88

FI 13.32 5.30 0.25 FR 220.44 60.90 3.62 FR 18.10 60.90 0.30 RO 1.56 21.60 0.07

FR 24.66 60.90 0.04 HU 91.76 10.10 9.08 HU 6.10 10.10 0.60 SE 0.10 9.00 0.01

HU 23.45 10.10 0.23 IE 26.27 4.20 6.25 IE 0.10 4.20 0.02 SI 42.00 2.00 21.00

IE 10.97 4.20 0.26 IT 298.40 58.80 5.07 LV 0.50 2.30 0.22 SK 34.67 5.40 6.42

IT 134.27 58.80 0.23 LT 10.87 3.40 3.20 PL 8.90 38.10 0.23 UK 1,027.80 60.40 17.02

LT 15.56 3.40 0.46 LV 19.18 2.30 8.34 RO 1,288.50 21.60 59.65 Mean 13.92

LV 35.13 2.30 1.53 NL 27.96 16.30 1.72 SE 0.02 9.00 0.00

NL 482.90 16.30 2.96 PL 416.36 38.10 10.93 SI 0.30 2.00 0.15

PL 165.37 38.10 0.43 RO 98.87 21.60 4.58 SK 2.00 5.40 0.37

RO 17.06 21.60 0.08 SE 38.58 9.00 4.29 UK 851.39 60.40 14.10

SE 16.87 9.00 0.19 SI 9.30 2.00 4.65 Mean 14.29

SI 28.75 2.00 1.44 SK 85.93 5.40 15.91

SK 19.20 5.40 0.36 UK 204.52 60.40 3.39

UK 11.00 60.40 0.02 Mean 7.26

Mean 0.69

Table 4-8: Overview on per capita emissions of POP into air in EU Member States (2005) (Source: EMEP WebDab)

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5 EMEP MSC-E calculation

5.1 Total annual emissions of POPs as calculated by EMEP MSC-E -> 2006?

Member State PAH [t/y] B[a]P [t/y] B[b]F [t/y] B[k]F [t/y] IP[ t/y] PCDD/PCDF

[g I-TEQ/y] HCB [ kg/y]

AT 9.10 2.70 3.30 1.10 2.00 43.00 45.00

BE 17.80 5.40 5.30 1.60 5.50 65.00 36.00

BG 21.10 6.30 7.00 2.60 5.20 230.00 19.00

CY 3.90 1.90 0.56 0.22 1.20 5.10 0.30

CZ 24.20 8.30 7.00 3.30 5.60 179.00 4.70

DE 81.40 36.00 4.40 13.00 28.00 74.00 1.90

DK 13.20 3.90 4.20 2.30 2.80 25.00 115.00

EE 12.60 3.80 4.30 2.20 2.30 3.30 0.20

ES 151.00 41.00 56.00 24.00 30.00 146.00 7,678.70

FI 13.20 4.00 4.80 1.60 2.80 26.00 36.00

FR 24.60 6.80 8.00 5.50 4.30 220.00 18.00

GR 24.50 7.00 9.20 3.10 5.20 159.00 175.00

HU 23.50 6.90 8.20 3.90 4.50 92.00 6.10

IE 10.70 3.00 3.90 2.00 1.80 26.00 0.10

IT 132.00 40.00 48.00 16.00 28.00 298.00 795.00

LT 15.50 3.70 4.10 2.40 5.30 11.00 176.00

LU 1.40 0.42 0.55 0.07 0.37 1.60 1.50

LV 35.50 13.00 17.00 3.90 1.60 19.00 0.50

MT 0.00

NL 14.20 4.60 4.60 1.70 3.30 28.00 92.00

PL 166.00 48.00 52.00 15.00 51.00 416.00 9.00

PT 37.40 11.00 14.00 4.40 8.00 574.00 145.00

RO 51.20 17.00 16.00 7.20 11.00 99.00 0.30

SE 16.80 5.20 6.10 2.00 3.50 39.00 0.00

SI 7.70 2.30 2.30 1.40 1.70 9.30 0.30

SK 19.30 5.30 7.00 2.90 4.10 86.00 2.00

UK 11.00 3.50 3.50 2.40 1.60 205.00 851.00

EU TOTAL 938.80 291.02 301.31 125.79 220.67 3,079.30 10,208.60

Table 5-1: Total annual emissions of POPs per country in 2005 (Source: EMEP MSC-E calculations)

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5.2 Trend of PAH emissions within the European Union from EMEP MSC-E

PAH (t/y) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 17.5 18.0 13.4 10.1 9.3 9.8 10.9 9.3 9.1 8.8 8.2 9.1 7.7 8.7 8.7 9.1 8.7

BE 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.4 20.7 19.9 19.1 18.5 17.8 15.5

BG 24.0 24.0 24.0 24.0 24.0 24.0 24.0 24.0 24.0 24.0 24.0 23.5 22.9 22.3 21.8 21.1 19.5

CY 24.5 23.2 23.0 22.7 21.3 21.0 19.7 19.5 19.2 17.9 17.6 16.4 15.9 15.3 14.6 16.4 20.9

CZ 40.2 40.2 40.2 40.2 40.2 40.2 40.2 40.2 40.2 40.2 40.2 32.3 24.5 21.3 24.4 24.2 17.1

DE 211.0 166.0 122.0 115.0 106.0 107.0 107.0 116.0 107.0 107.0 107.0 118.0 112.0 114.0 115.0 122.0 119.0

DK 6.7 7.6 7.7 8.2 7.9 7.9 8.4 8.4 7.4 7.7 9.4 10.0 9.8 11.1 11.6 13.2 13.6

EE 12.2 11.8 8.4 7.1 8.6 14.4 16.8 16.6 13.3 12.7 12.7 12.5 12.8 13.3 13.9 12.6 11.8

ES 124.0 122.0 120.0 121.0 121.0 120.0 122.0 121.0 122.0 122.0 114.0 103.0 101.0 98.0 94.0 91.0 73.0

FI 15.7 14.6 14.9 15.0 15.9 16.8 15.8 15.9 16.2 15.9 15.1 16.2 16.8 16.5 15.8 13.2 13.2

FR 42.3 49.6 46.0 45.5 39.1 39.4 39.6 36.0 36.1 34.3 31.4 31.3 27.9 27.9 26.1 24.6 24.0

GR 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 21.6 22.1 22.7 23.3 23.9 24.5 25.1

HU 48.5 44.7 27.0 26.8 26.1 26.3 24.0 22.3 18.6 18.9 19.0 19.3 19.8 22.2 21.0 23.5 22.8

IE 12.2 12.2 12.2 12.2 12.2 12.2 12.2 12.2 12.2 12.2 12.2 12.2 12.2 11.3 10.6 10.7 10.7

IT 91.0 105.0 101.0 102.0 107.0 109.0 101.0 113.0 109.0 118.0 118.0 118.0 109.0 115.0 132.0 132.0 132.0

LT 71.0 71.0 71.0 71.0 71.0 71.0 71.0 71.0 53.0 44.3 34.2 87.0 45.3 46.6 15.4 15.5 15.9

LU 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.7 1.6 1.6 1.5 1.5 1.4 1.4

LV 26.1 29.6 28.4 28.8 28.7 34.3 35.5 34.5 34.6 35.8 33.5 33.2 33.3 34.3 35.5 35.5 33.3

MT 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

NL 18.0 18.0 18.0 18.0 18.0 18.0 18.0 18.0 18.0 18.0 18.0 17.2 16.5 15.6 14.8 14.2 13.4

PL 159.0 175.0 171.0 253.0 231.0 238.0 225.0 196.0 177.0 177.0 167.0 164.0 160.0 157.0 158.0 166.0 162.0

PT 8.5 8.5 8.5 8.7 8.2 8.5 9.0 8.7 8.2 8.5 8.4 9.1 9.9 10.3 10.6 10.3 10.6

RO 52.2 51.2 42.2 52.2 52.2 52.2 52.2 52.2 52.2 42.2 52.2 52.2 52.2 52.2 52.2 52.2 49.9

SE 16.7 18.1 15.9 15.7 15.8 16.4 17.3 14.7 15.6 17.2 13.9 14.5 14.2 15.2 15.1 16.8 18.3

SI 13.5 13.8 13.2 12.8 12.4 12.2 11.1 11.9 11.8 11.8 11.8 10.4 10.3 10.4 10.3 10.1 10.1

SK 29.1 34.0 30.6 26.8 23.3 15.1 18.7 13.9 13.9 13.8 13.4 13.8 12.5 13.5 15.7 19.3 18.2

UK 219.0 204.0 180.0 133.0 123.0 98.0 43.6 32.5 24.6 21.5 16.5 16.6 14.4 12.7 12.0 11.0 11.1

EU TOTAL 1327.8 1307.0 1183.4 1214.6 1167.1 1156.6 1087.9 1052.7 988.0 974.6 942.4 984.2 905.1 908.6 892.9 908.2 871.1

Europe TOTAL 2,129 2,086 1,951 1,970 1,922 1,906 1,852 1,811 1,750 1,743 1,665 1,676 1,605 1,608 1,598 1,612

Table 5-2: Total PAH emissions 1990-2006 (Source: EMEP MSC-E calculations)

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Figure 5-1: Time trend for PAH in EU MS with decreasing, increasing and stable values 1990 –

2006 (Source: EMEP MSC-E calculations)

Total PAH emissions for EU-MS with decreasing values (1990-2006)

0

50

100

150

200

250

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

t

ES

UK

DE

LT

FR

HU

CZ

SK

AT

BE

UK

ES

DE

Total PAH emissions for EU-MS with stable values (1990-2006)

0

50

100

150

200

250

300

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

t

PL

PT

RO

BG

GR

NL

FI

EE

IE

SI

LU

SE

CY

PL

Total PAH emissions for EU-MS with increasing values (1990-2006)

0

20

40

60

80

100

120

140

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

t

IT

LV

DK

LV

IT

DK

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B[a]P (t/y) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 5.2 5.4 4.0 3.0 2.8 2.9 3.2 2.8 2.7 2.6 2.4 2.7 2.6 2.6 2.6 2.7 2.6

BE 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.1 6.7 6.3 5.8 5.4 5.0

BG 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.5 7.2 6.9 6.6 6.3 6.0

CY 15.0 14.0 14.0 14.0 13.0 13.0 12.0 12.0 12.0 11.0 11.0 10.0 9.9 9.5 9.1 11 10.0

CZ 14.0 14.0 14.0 14.0 14.0 14.0 14.0 14.0 14.0 14.0 14.0 11.0 7.7 6.4 8.1 8.3 5.9

DE 65.0 51.0 38.0 36.0 33.0 33.0 33.0 36.0 33.0 33.0 33.0 36.0 35.0 36.0 36.0 38.0 37.0

DK 1.9 2.2 2.2 2.3 2.3 2.2 2.4 2.4 2.1 2.2 2.7 2.9 2.8 3.2 3.4 3.9 4.0

EE 3.6 3.5 2.5 2.1 2.6 4.4 5.0 5.0 4.0 3.8 3.8 3.7 3.8 4.0 4.1 3.8 3.8

ES 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 26.0 25.0 24.0 23.0 22.0 20.0

FI 4.7 4.6 4.7 4.7 4.7 5.1 4.7 4.8 4.9 4.8 4.6 4.9 5.1 5.0 5.0 4.0 4.0

FR 12.0 14.0 13.0 13.0 11.0 11.0 11.0 10.0 10.0 10.0 9.0 9.0 8.0 8.0 7.2 6.8 6.6

GR 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.3 6.5 6.7 6.9 7.0 7.2

HU 14.0 12.0 7.5 7.5 7.5 7.7 7.0 6.6 5.8 5.9 6.0 6.0 6.0 6.7 6.4 6.9 6.5

IE 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.3 3.1 2.9 3.0 3.0

IT 28.0 32.0 31.0 31.0 32.0 33.0 31.0 34.0 33.0 36.0 36.0 36.0 33.0 35.0 40.0 40.0 40.0

LT 19.0 19.0 19.0 19.0 19.0 19.0 19.0 19.0 14.0 13.0 11.0 30.0 17.0 18.0 3.6 3.7 3.8

LU 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.4 0.4 0.4

LV 12.0 13.0 12.0 11.0 11.0 13.0 13.0 13.0 13.0 13.0 12.0 12.0 12.0 13.0 13.0 13.0 12.0

MT

NL 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 6.2 5.9 5.6 5.2 4.9 4.6 4.3

PL 46.0 51.0 50.0 73.0 67.0 69.0 65.0 57.0 51.0 51.0 48.0 47.0 46.0 46.0 46.0 48.0 47.0

PT 2.5 2.5 2.5 2.6 2.4 2.5 2.6 2.6 2.4 2.5 2.5 2.7 2.9 3.0 3.1 3.0 3.1

RO 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 16.0

SE 5.2 5.6 5.0 4.9 4.9 5.1 5.4 4.5 4.8 5.3 4.3 4.5 4.4 4.7 4.7 5.2 5.7

SI 3.9 4.0 3.9 3.7 3.6 3.6 3.5 3.5 3.4 3.4 3.4 3.0 3.0 3.0 2.9 2.9 2.9

SK 8.1 7.3 6.6 5.8 5.0 4.2 4.0 3.9 3.9 3.8 3.7 3.9 3.6 3.9 4.7 5.3 4.9

UK 66.0 61.0 52.0 33.0 30.0 23.0 12.0 10.0 8.8 7.8 5.7 5.7 4.9 4.1 3.9 3.5 3.6

EU TOTAL 402 392 357 356 341 341 323 317 298 299 289 305 279 282 271 276 265

Table 5-3: Total B[a]P emissions 1990-2006 (Source: EMEP MSC-E calculations)

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B[b]F (t/y) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 6.4 6.6 4.9 3.7 3.4 3.6 4.0 3.4 3.3 3.3 3.0 3.3 3.2 3.2 3.2 3.3 3.2

BE 6.4 6.4 6.4 6.4 6.4 6.4 6.4 6.4 6.4 6.4 6.2 6.0 5.7 5.5 5.5 5.3 5.1

BG 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.8 7.7 7.5 7.3 7.2 7.0 6.8

CY 5.7 5.5 5.4 5.2 5.0 4.9 4.7 4.600 4.4 4.3 4.1 4.0 3.8 3.7 3.5 4.0 3.2

CZ 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 13.0 10.0 7.3 6.9 7.2 7.0 5.0

DE 73.0 58.0 42.0 40.0 37.0 37.0 37.0 40.0 37.0 37.0 37.0 41.0 39.0 39.0 39.0 42 41.0

DK 2.1 2.4 2.4 2.6 2.5 2.5 2.7 2.7 2.4 2.5 3.0 3.2 3.2 3.6 3.7 4.2 4.3

EE 4.3 4.2 2.9 2.4 2.8 4.7 5.5 5.5 4.4 4.2 4.2 4.2 4.3 4.4 4.7 4.3 3.9

ES 37.0 37.0 37.0 37.0 37.0 37.0 37.0 37.0 37.0 37.0 37.0 35.0 34.0 32.0 30.0 29.0 27.0

FI 5.7 5.5 5.6 5.7 5.6 6.1 5.7 5.8 5.9 5.7 5.5 5.9 6.1 6.0 6.0 4.8 4.8

FR 14.0 16.0 15.0 15.0 13.0 13.0 13.0 12.0 12.0 11.0 10.0 10.0 9.0 9.0 8.5 8.0 7.8

GR 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.1 8.3 8.5 8.8 9.0 9.2 9.4

HU 15.0 14.0 8.6 8.6 8.4 8.6 7.7 7.2 6.0 6.1 6.2 6.2 6.5 7.4 7.0 8.2 8.1

IE 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.5 4.2 3.9 3.9 3.9

IT 33.0 38.0 37.0 37.0 39.0 40.0 37.0 41.0 40.0 43.0 43.0 43.0 40.0 42.0 48.0 48.0 48.0

LT 14.0 14.0 14.0 14.0 14.0 14.0 14.0 14.0 11.0 9.2 7.3 19.0 10.0 11.0 4.1 4.1 4.2

LU 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.64 0.63 0.61 0.59 0.57 0.55 0.5

LV 10.0 12.0 12.0 13.1 13.0 16.0 17.0 16.0 16.0 17.0 16.0 16.0 16.0 16.0 17.0 17.0 16.0

MT

NL 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.3 5.1 4.9 4.7 4.6 4.4

PL 50.0 55.0 54.0 80.0 73.0 75.0 71.0 62.0 56.0 56.0 53.0 51.0 50.0 49.0 49.0 52.0 50.0

PT 3.2 3.2 3.2 3.3 3.1 3.2 3.4 3.3 3.1 3.2 3.1 3.4 3.7 3.9 4.0 3.9 4.0

RO 17.0 16.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17.0 16.0

SE 6.0 6.5 5.7 5.6 5.7 5.9 6.2 5.3 5.6 6.2 5.0 5.2 5.1 5.5 5.4 6.1 6.6

SI 5.1 5.3 5.0 4.9 4.7 4.6 3.6 4.5 4.5 4.5 4.5 3.8 3.9 3.9 3.9 3.8 3.8

SK 9.9 8.9 8.0 7.0 6.1 5.1 4.9 4.7 4.7 4.7 4.5 4.7 4.3 4.6 5.4 7.0 6.6

UK 80.0 75.0 68.0 54.0 51.0 41.0 16.0 11.0 6.7 5.6 4.6 4.8 4.3 3.9 3.7 3.5 3.5

EU TOTAL 437 429 394 402 387 385 353 343 323 323 314 323 303 303 301 308 297

Table 5-4: Total B[b]F emissions 1990-2006 (Source: EMEP MSC-E calculations)

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B[k]F (t/y) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 2.1 2.1 1.6 1.2 1.1 1.2 1.3 1.1 1.1 1.0 0.979 1.1 0.032 1.0 1.0 1.1 1.0

BE 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.1 2.0 1.8 1.7 1.6 1.5

BG 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.1 3.0 2.9 2.8 2.6 2.5

CY 0.503 0.486 0.468 0.451 0.434 0.416 0.399 0.382 0.364 0.347 0.329 0.312 0.295 0.277 0.260 0.220 1.1

CZ 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 3.8 3.3 2.6 3.3 3.3 2.3

DE 23.0 18.0 13.0 12.0 11.0 12.0 12.0 13.0 12.0 12.0 12.0 13.0 12.0 13.0 13.0 13.0 13.0

DK 1.1 1.2 1.3 1.4 1.3 1.4 1.5 1.5 1.3 1.4 1.7 1.8 1.8 2.0 2.1 2.3 2.4

EE 2.2 2.1 1.5 1.3 1.6 2.6 3.1 3.0 2.4 2.3 2.3 2.3 2.3 2.4 2.5 2.2 2.1

ES 40.0 38.0 36.0 37.0 37.0 36.0 38.0 37.0 38.0 38.0 30.0 23.0 23.0 24.0 24.0 24.0 10.0

FI 1.9 1.8 1.9 1.9 1.9 2.0 1.9 1.9 2.0 1.9 1.8 2.0 2.0 2.0 2.0 1.6 1.6

FR 9.0 11.0 10.0 9.7 8.4 8.7 8.7 7.8 7.8 7.4 6.9 6.9 6.1 6.1 5.8 5.5 5.4

GR 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.7 2.8 2.9 2.9 3.0 3.1 3.2

HU 8.5 7.7 4.4 4.4 4.3 4.3 4.1 3.8 3.3 3.3 3.3 3.4 3.5 3.8 3.6 3.9 3.1

IE 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.1 2.0 2 2.0

IT 11.0 13.0 12.0 12.0 13.0 13.0 12.0 14.0 13.0 14.0 14.0 14.0 13.0 14.0 16.0 16 16.0

LT 14.0 14.0 14.0 14.0 14.0 14.0 14.0 14.0 10.0 8.1 6.0 15.0 7.3 7.6 2.4 2.4 2.5

LU 0.093 0.093 0.093 0.093 0.093 0.093 0.093 0.093 0.093 0.093 0.093 0.089 0.085 0.081 0.077 0.073 0.07

LV 2.2 2.6 2.6 2.9 3.0 3.6 3.8 3.7 3.8 3.9 3.7 3.6 3.7 3.7 3.9 3.9 3.7

MT

NL 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.1 2.0 1.9 1.8 1.7 1.6

PL 15.0 17.0 16.0 24.0 22.0 23.0 22.0 19.0 17.0 17.0 16.0 15.0 15.0 15.0 15.0 15.0 15.0

PT 1.0 1.0 1.0 1.0 1.0 1.0 1.1 1.0 1.0 1.0 1.0 1.1 1.2 1.2 1.3 1.2 1.3

RO 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 7.2 6.9

SE 2.0 2.2 1.9 1.9 1.9 2.0 2.1 1.8 1.9 2.1 1.7 1.7 1.7 1.8 1.8 2.0 2.2

SI 1.8 1.7 1.6 1.6 1.6 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.3 1.4 1.4 1.4 1.4

SK 4.4 8.9 8.0 7.0 6.1 2.3 4.9 2.1 2.1 2.1 2.1 2.1 1.9 2.1 2.4 2.9 2.8

UK 42.0 39.0 35.0 28.0 26.0 21.0 9.0 6.3 5.3 4.2 3.3 3.4 3.1 2.7 2.6 2.4 2.4

EU TOTAL 206 206 187 186 180 174 166 157 148 146 133 135 122 126 123 123 107

Table 5-5: Total B[k]F emissions 1990-2006 (Source: EMEP MSC-E calculations)

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I_P (t/y) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 3.8 3.9 2.9 2.2 2.0 2.1 2.4 2.0 2.0 1.9 1.8 2.0 1.9 1.9 1.9 2.0 1.9

BE 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 5.5 3.9

BG 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 4.2

CY 3.3 3.2 3.1 3.0 2.9 2.7 2.6 2.5 2.4 2.3 2.2 2.1 1.9 1.8 1.7 1.2 6.6

CZ 8.8 8.8 8.8 8.8 8.8 8.8 8.8 8.8 8.8 8.8 8.8 7.5 6.2 5.4 5.8 5.6 3.9

DE 50.0 39.0 29.0 27.0 25.0 25.0 25.0 27.0 25.0 25.0 25.0 28.0 26.0 26.0 27.0 29.0 28.0

DK 1.6 1.8 1.8 1.9 1.8 1.8 1.8 1.8 1.6 1.6 2.0 2.1 2.0 2.3 2.4 2.8 2.9

EE 2.1 2.0 1.5 1.3 1.6 2.7 3.2 3.1 2.5 2.4 2.4 2.3 2.4 2.5 2.6 2.3 2.0

ES 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 19.0 19.0 18.0 17.0 16.0 16.0

FI 3.4 2.7 2.7 2.7 3.7 3.6 3.5 3.4 3.4 3.5 3.2 3.4 3.6 3.5 2.8 2.8 2.8

FR 7.3 8.6 8.0 7.8 6.7 6.7 6.9 6.2 6.3 5.9 5.5 5.4 4.8 4.8 4.6 4.3 4.2

GR 4.6 4.6 4.6 4.6 4.6 4.6 4.6 4.6 4.6 4.6 4.6 4.7 4.8 4.9 5.0 5.2 5.3

HU 11.0 11.0 6.5 6.3 5.9 5.7 5.2 4.7 3.5 3.6 3.5 3.7 3.8 4.3 4.0 4.5 5.1

IE 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 1.9 1.8 1.8 1.8

IT 19.0 22.0 21.0 22.0 23.0 23.0 21.0 24.0 23.0 25.0 25.0 25.0 23.0 24.0 28.0 28.0 28.0

LT 24.0 24.0 24.0 24.0 24.0 24.0 24.0 24.0 18.0 14.0 9.9 23.0 11.0 10.0 5.3 5.3 5.4

LU 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.43 0.42 0.40 0.39 0.38 0.37 0.4

LV 1.9 2.0 1.8 1.8 1.7 1.7 1.7 1.8 1.8 1.9 1.8 1.6 1.6 1.6 1.6 1.6 1.6

MT

NL 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 3.9 3.8 3.6 3.4 3.3 3.1

PL 48.0 52.0 51.0 76.0 69.0 71.0 67.0 58.0 53.0 53.0 50.0 51.0 49.0 47.0 48.0 51.0 50.0

PT 1.8 1.8 1.8 1.8 1.7 1.8 1.9 1.8 1.7 1.8 1.8 1.9 2.1 2.2 2.2 2.2 2.2

RO 11.0 11.0 1.0 11.0 11.0 11.0 11.0 11.0 11.0 1.0 11.0 11.0 11.0 11.0 11.0 11.0 11.0

SE 3.5 3.8 3.3 3.3 3.3 3.4 3.6 3.1 3.3 3.6 2.9 3.1 3.0 3.2 3.2 3.5 3.8

SI 2.7 2.8 2.7 2.6 2.5 2.5 2.5 2.4 2.4 2.4 2.4 2.1 2.1 2.1 2.1 2.0 2.0

SK 6.7 8.9 8.0 7.0 6.1 3.5 4.9 3.2 3.2 3.2 3.1 3.1 2.7 2.9 3.2 4.1 3.9

UK 31.0 29.0 25.0 18.0 16.0 13.0 6.6 5.2 3.8 3.9 2.9 2.7 2.1 2.0 1.8 1.6 1.6

EU TOTAL 283 280 246 270 259 256 246 236 219 207 207 222 201 198 197 202 202

Table 5-6: Total I_P emissions 1990-2006 (Source: EMEP MSC-E calculations)

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5.3 Trend of PCDD/PCDF emissions within the European Union from EMEP MSC-E

PCDD/F (g I-TEQ) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 160.0 135.0 76.0 67.0 56.0 58.0 60.0 60.0 56.0 54.0 52.0 55.0 42.0 42.0 41.0 43.0 44.0

BE 569.0 563.0 529.0 496.0 489.0 402.0 347.0 291.0 235.0 180.0 124.0 88.0 59.0 62.0 65.0 65.0 55.0

BG 554.0 535.0 515.0 495.0 476.0 456.0 341.0 310.0 288.0 245.0 233.0 201.0 219.0 255.0 239.0 230.0 247.0

CY 7.7 7.4 7.8 7.9 7.8 7.8 7.5 7.3 7.3 7.3 7.1 7.2 7.3 6.1 5.9 5.9 5.9

CZ 1,252.0 1,220.0 1,220.0 1,140.0 1,135.0 1,135.0 922.0 830.0 767.0 643.0 744.0 620.0 177.0 114.0 187.0 179.0 175.0

DE 114.0 105.0 86.0 82.0 80.0 89.0 85.0 90.0 84.0 80.0 83.0 82.0 81.0 81.0 83.0 83.0 85.0

DK 67.0 64.0 59.0 53.0 51.0 49.0 47.0 44.0 37.0 31.0 32.0 30.0 27.0 29.0 24.0 25.0 2.5

EE 5.7 5.4 4.3 3.6 3.8 4.5 4.9 4.8 3.8 3.4 3.4 3.5 3.7 4.1 3.7 3.3 2.7

ES 181.0 187.0 195.0 192.0 186.0 161.0 160.0 133.0 134.0 140.0 147.0 141.0 142.0 147.0 150.0 150.0 155.0

FI 36.0 35.0 33.0 35.0 41.0 41.0 40.0 39.0 40.0 41.0 32.0 31.0 32.0 32.0 32.0 26.0 14.0

FR 1,768.0 1,817.0 1,837.0 1,895.0 1,893.0 1,695.0 1,479.0 1,044.0 939.0 611.0 520.0 385.0 358.0 237.0 299.0 216.0 127.0

GR 279.0 279.0 279.0 279.0 279.0 279.0 279.0 279.0 279.0 279.0 279.0 255.0 231.0 207.0 183.0 159.0 135.0

HU 172.0 148.0 104.0 103.0 100.0 95.0 90.0 84.0 74.0 77.0 74.0 76.0 75.0 74.0 74.0 92.0 92.0

IE 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 27.0 26.0 27.0 26.0 26.0

IT 473.0 495.0 476.0 451 441.0 460.0 419.0 426.0 413.0 388.0 369.0 293.0 283.0 282.0 290.0 294.0 302.0

LT 5.6 5.6 5.6 5.6 5.6 5.6 5.6 5.6 6.0 5.0 4.3 13.0 12.0 12.0 11.0 11.0 11.0

LU 45.0 40.0 34.0 29.0 23.0 24.0 16.0 16.0 8.0 6.7 5.4 4.1 2.9 1.6 1.6 1.6 1.6

LV 7.1 7.6 7.3 8.3 9.1 10.0 11.0 12.0 11.0 12.0 10.0 11.0 11.0 12.0 13.0 13.0 14.0

MT

NL 743.0 979.0 752.0 525.0 297.0 66.0 56.0 54.0 43.0 33.0 31.0 30.0 29.0 26.0 28.0 36.0 35.0

PL 529.0 535.0 517.0 592.0 520.0 515.0 484.0 440.0 381.0 381.0 333.0 447.0 433.0 482.0 387.0 416.0 449.0

PT 18.0 18.0 18.0 18.0 18.0 18.0 19.0 21.0 18.0 17.0 15.0 11.0 11.0 11.0 11.0 9.0 10.0

RO 113.0 113.0 113.0 113.0 113.0 113.0 113.0 113.0 113.0 87.0 101.0 104.0 152.0 201.0 249.0 297.0 268.0

SE 60.0 53.0 50.0 53.0 44.0 40.0 38.0 37.0 35.0 34.0 33.0 34.0 34.0 33.0 36.0 38.0 37.0

SI 16.0 16.0 15.0 13.0 13.0 12.0 12.0 11.0 11.0 11.0 11.0 10.0 10.1 10.2 9.1 8.6 8.4

SK 136.0 132.0 128.0 124.0 120.0 116.0 106.0 96.0 109.0 98.0 90.0 87.0 91.0 70.0 65.0 86.0 67.0

UK 1,146.0 1,124.0 1,097.0 889.0 692.0 739.0 476.0 379.0 284.0 258.0 229.0 218.0 201.0 199.0 227.0 199.0 197.0

EU TOTAL 8,484 8,646 8,185 7,696 7,120 6,618 5,645 4,854 4,403 3,749 3,589 3,264 2,751 2,656 2,741 2,712 2,566

Table 5-7: Total PCDD/PCDF emissions 1990-2006 (Source: EMEP MSC-E calculations)

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Figure 5-2: Time trend for PCDD/PCDF in EU MS with decreasing, increasing and stable values

1990 – 2006 (Source: EMEP MSC-E calculations)

Total PCDD/PCDF emissions for EU-MS with decreasing values (1990-2006)

0

200

400

600

800

1,000

1,200

1,400

1,600

1,800

2,000

199

0

199

1

199

2

199

3

199

4

199

5

199

6

199

7

199

8

199

9

200

0

200

1

200

2

200

3

200

4

200

5

200

6

g I

-TE

Q

FR

CZ

UK

PT

NL

BE

BG

PL

IT

FI

PT

FR

Total PCDD/PCDF emissions for EU-MS with stable values (1990-2006)

0

5

10

15

20

25

30

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

g I

-TE

Q

IE

CY

IE

CY

Total PCDD/PCDF emissions for EU-MS with increasing values (1990-2006)

0

50

100

150

200

250

300

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

g I

-TE

Q

LV

LT

ROLV LT

RO

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5.4 HCB emissions within the European Union from EMEP MSC-E

HCB (kg/y) 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

AT 92.0 84.0 69.0 64.0 52.0 53.0 56.0 52.0 49.0 48.0 44.0 48.0 45.0 45.0 44.0 45.0 43.0

BE 18.0 17.0 16.0 19.0 30.0 30.0 35.0 40.0 45.0 50.0 55.0 55.0 61.0 55.0 36.0 36.0 47.0

BG 544.0 451.0 358.0 265.0 172.0 79.0 87.0 47.0 76.0 46.0 54.0 43.0 38.0 45.0 21.0 19.0 25.0

CY 0.17 0.15 0.17 0.17 0.16 0.16 0.15 0.13 0.14 0.15 0.14 0.14 0.15 0.13 0.14 0.12 0.12

CZ 317.0 297.0 277.0 256.0 236.0 216.0 186.0 155.0 125.0 95.0 65.0 34.0 4.1 4.2 4.3 4.7 3.7

DE 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.8 1.9 1.9 1.9 1.9 1.9 2.0 2.0 1.9 2.0

DK 131.0 128.0 125.0 121.0 118.0 115.0 115.0 115.0 115.0 115.0 115.0 115.0 115.0 115.0 115.0 115.0 115.0

EE 0.06 0.06 0.05 0.04 0.07 0.12 0.14 0.14 0.13 0.12 0.13 0.14 0.13 0.25 0.16 0.15 0.12

ES 6,607.0 6,138.0 5,310.0 5,088.0 5,524.0 4,822.0 5,404.0 6,053.0 6,407.0 6,547.0 7,005.0 7,308.0 7,683.0 7,720.0 7,669.0 7,678.7 7,595.0

FI 40.0 40.0 40.0 40.0 39.0 40.0 41.0 42.0 42.0 41.0 41.0 21.0 15.0 12.9 29.2 36.0 43.0

FR 1,199.0 1,221.0 1,248.0 631.0 77.0 75.0 76.0 67.0 61.0 54.0 50.0 40.0 33.0 28.0 23.0 18.0 13.0

GR 195.0 191.0 187.0 183.0 179.0 175.0 175.0 175.0 175.0 175.0 175.0 175.0 175.0 175.0 175.0 175.0 175.0

HU 7.0 5.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 5.0 4.4 4.6 3.6 6.1 7.1

IE 47.0 47.0 47.0 46.0 46.0 46.0 39.0 33.0 26.0 20.0 13.0 6.6 0.04 0.04 0.05 0.05 0.05

IT 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02

LT 213.0 206.0 198.0 191.0 183.0 176.0 176.0 176.0 176.0 176.0 176.0 176.0 176.0 176.0 176.0 176.0 176.0

LU 0.4 0.5 0.6 0.7 0.8 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.5 1.5 1.5 1.5

LV 0.3 0.3 0.3 0.3 0.3 0.4 0.4 0.4 0.4 0.5 0.4 0.4 0.5 0.5 0.5 0.5 0.5

MT

NL 93.0 93.0 93.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0 92.0

PL 62.0 39.0 39.0 43.0 38.0 51.0 48.0 51.0 43.0 40.0 46.0 8.0 8.5 7.0 8.0 9.0 8.6

PT 159.0 156.0 153.0 151.0 148.0 145.0 145.0 145.0 145.0 145.0 145.0 145.0 145.0 145.0 145.0 145.0 145.0

RO 5.7 5.7 5.7 5.7 5.7 5.7 5.7 5.7 5.7 1.1 12.0 3.5 3.0 2.5 2.0 1.6 1.7

SE 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.03 0.02 0.02 0.02

SI 47.0 41.0 38.0 38.0 38.0 37.0 36.0 38.0 37.0 38.0 38.0 38.0 0.34 0.34 0.32 0.27 0.30

SK 2.5 2.5 2.4 2.4 2.3 2.3 2.1 1.9 2.1 1.7 1.7 1.7 1.6 1.8 2.1 2.0 2.2

UK 1,080.0 958.0 1,127.0 904.0 656.0 668.0 696.0 593.0 564.0 534.0 325.0 314.0 327.0 329.0 850.0 838.0 813.0

EU TOTAL 10,862 10,123 9,340 8,147 7,643 6,835 7,422 7,889 8,194 8,227 8,461 8,633 8,931 8,963 9,400 9,402 9,310

Table 5-8: Total HCB emissions 1990-2006 (Source: EMEP MSC-E calculations)

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Figure 5-3: Time trend for HCB in EU MS with decreasing, increasing and stable values 1990 –

2006 (Source: EMEP MSC-E calculations)

Total HCB emissions for EU-MS with decreasing values (1990-2006)

0

200

400

600

800

1,000

1,200

1,400

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

kg

UK

FR

BG

CZ

LT

GR

PT

DK

AT

PL

IE

RO

SI

EE

FR

BG

UK

CZ

Total HCB emissions for EU-MS with stable values (1990-2006)

0

10

20

30

40

50

60

70

80

90

100

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

kg

NL

SE

HU

DE

SK

FI

CY

IT

NL

FI

Total HCB emissions for EU-MS with increasing values (1990-2006)

0

1,000

2,000

3,000

4,000

5,000

6,000

7,000

8,000

9,000

1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

kg

ES

BE

LU

LV

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5.5 Per capita calculation of POP emissions within the European Union from EMEP MSC-E

Inhabitant

[Mio]

PAH [t/a] per capita

[g/y]

PCDD/PCDF [g/y] per capita

[μg/y]

HCB [kg/y] per capita

[mg/y] 2006 2006 2006

AT 8.3 8.7 1.0 43.0 5.2 45.0 5.42

BE 10.5 15.5 1.5 65.0 6.2 36.0 3.43

BG 7.7 19.5 2.5 230.0 29.9 19.0 2.47

CY 0.8 20.9 26.1 5.1 6.4 0.3 0.39

CZ 10.3 17.1 1.7 179.0 17.4 4.7 0.46

DE 82.5 119.0 1.4 74.0 0.9 1.9 0.02

DK 5.4 13.6 2.5 25.0 4.6 115.0 21.30

EE 1.3 11.8 9.1 3.3 2.5 0.2 0.12

ES 43.8 73.0 1.7 146.0 3.3 7,678.7 175.31

FI 5.3 13.2 2.5 26.0 4.9 36.0 6.79

FR 60.9 24.0 0.4 220.0 3.6 18.0 0.30

GR 11.1 25.1 2.3 159.0 14.3 175.0 15.77

HU 10.1 22.8 2.3 92.0 9.1 6.1 0.60

IE 4.2 10.7 2.5 26.0 6.2 0.1 0.01

IT 58.8 132.0 2.2 298.0 5.1 795.0 13.52

LT 3.4 15.9 4.7 11.0 3.2 176.0 51.76

LU 0.5 1.4 2.7 1.6 3.2 1.5 3.00

LV 2.3 33.3 14.5 19.0 8.3 0.5 0.23

MT 0.4 0.0 0.0 0.0 0.00

NL 16.3 13.4 0.8 28.0 1.7 92.0 5.64

PL 38.1 162.0 4.3 416.0 10.9 9.0 0.24

PT 10.6 10.6 1.0 574.0 54.2 145.0 13.68

RO 21.6 49.9 2.3 99.0 4.6 0.3 0.01

SE 9 18.3 2.0 39.0 4.3 0.0 0.00

SI 2 10.1 5.1 9.3 4.7 0.3 0.13

SK 5.4 18.2 3.4 86.0 15.9 2.0 0.37

UK 60.4 11.1 0.2 205.0 3.4 851.0 14.09

Mean 3.7 8.7 12.4

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Table 5-9: Overview on per capita emissions of POP into air in EU Member States (2005) (Source: EMEP MSC-E)

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6 EU-EPER

6.1 Categories of industrial activities and capacity threshold under EPER

Code Activity Capacity threshold

1 Energy industries

1.2 Mineral oil and gas refineries

1.4 Coal gasification and liquefaction plants

1.1 Combustion installations with a rated thermal input exceeding 50 MW

1.3 Coke ovens

2 Production and processing of metals

2.1 Metal ore (including sulphide ore) roasting or sintering installations

2.2 Installations for the production of pig iron or steel (primary or secondary

fusion) including continuous casting with a capacity exceeding2.5 tonnes per hour

2.3 Installations for the processing of ferrous metals:

(a) hot-rolling mills with a capacity exceeding 20 tonnes of crude steel per hour

(b) smitheries with hammers the energy of which exceeds 50 kilojoule per hammer, where the

calorific power used exceeds 20 MW

(c) application of protective fused metal coats with an input exceeding 2 tonnes of crude steel per hour

2.4 Ferrous metal foundries with a production capacity exceeding 20 tonnes per day

2.5 Installations

(a) for the production of non-ferrous crude metals from ore, concentrates

or secondary raw materials by metallurgical, chemical or electrolytic

processes

(b) for the smelting, including the alloyage, of non-ferrous metals, including

recovered products (refining, foundry casting, etc.)

with a melting capacity exceeding 4 tonnes per day for lead and

cadmium or 20 tonnes per day for all other metals

2.6 Installations for surface treatment of metals and plastic materials using an where the volume of the treatment vats exceeds 30 m3

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electrolytic or chemical process

3 Mineral industry

3.1 Installations for the production of

cement clinker in rotary kilns with a production capacity exceeding 500 tonnes per day

or lime in rotary kilns with a production capacity exceeding 50 tonnes per day

or in other furnaces with a production capacity exceeding 50 tonnes per day

3.2 Installations for the production of asbestos and the manufacture of

asbestos-based products

3.3 Installations for the manufacture of glass including glass fibre with a melting capacity exceeding 20 tonnes per day

3.4 Installations for melting mineral substances including the production of

mineral fibres with a melting capacity exceeding 20 tonnes per day

3.5 Installations for the manufacture of ceramic products by firing, in particular

roofing tiles, bricks, refractory bricks, tiles, stoneware or porcelain

with a production capacity exceeding 75 tonnes per day, and/or with a

kiln capacity exceeding 4 m3 and with a setting density per kiln

exceeding 300 kg/m3

4.

Chemical industry

Production within the meaning of the categories of activities contained in

this section means the production on an industrial scale by chemical

processing of substances or groups of substances listed in Sections 4.1 to

4.6

4.1 Chemical installations for the production of basic organic chemicals, such

as:

(a) simple hydrocarbons (linear or cyclic, saturated or unsaturated,

aliphatic or aromatic)

(b) oxygen-containing hydrocarbons such as alcohols, aldehydes, ketones,

carboxylic acids, esters, acetates, ethers, peroxides, epoxy resins

(a) sulphurous hydrocarbons

(d) nitrogenous hydrocarbons such as amines, amides, nitrous

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compounds, nitro compounds or nitrate compounds, nitriles, cyanates,

isocyanates

(e) phosphorus-containing hydrocarbons

(f) halogenic hydrocarbons

(g) organometallic compounds

(h) basic plastic materials (polymers synthetic fibres and cellulose-based

fibres)

(i) synthetic rubbers

(j) dyes and pigments

(k) surface-active agents and surfactants

4.2 Chemical installations for the production of basic inorganic chemicals,

such as:

(a) gases, such as ammonia, chlorine or hydrogen chloride, fluorine or

hydrogen fluoride, carbon oxides, sulphur compounds, nitrogen oxides,

hydrogen, sulphur dioxide, carbonyl chloride

(b) acids, such as chromic acid, hydrofluoric acid, phosphoric acid, nitric

acid, hydrochloric acid, sulphuric acid, oleum, sulphurous acids

(c) bases, such as ammonium hydroxide, potassium hydroxide, sodium

hydroxide

(d) salts, such as ammonium chloride, potassium chlorate, potassium

carbonate, sodium carbonate, perborate, silver nitrate

(e) non-metals, metal oxides or other inorganic compounds such as

calcium carbide, silicon, silicon carbide

4.3 Chemical installations for the production of phosphorous-, nitrogen- or

potassium-based fertilizers (simple or compound fertilizers)

4.4 Chemical installations for the production of basic plant health products and

of biocides

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4.5 Installations using a chemical or biological process for the production of

basic pharmaceutical products

4.6 Chemical installations for the production of explosives

5.

Waste management

Without prejudice of Article 11 of Directive 75/442/EEC or Article 3 of

Council Directive 91/689/EEC of 12 December 1991 on hazardous waste1

5.1

Installations for the disposal or recovery of hazardous waste as defined in

the list referred to in Article 1(4) of Directive 91/689/EEC, as defined in

Annexes II A and II B (operations R1, R5, R6, R8 and R9) to Directive

75/442/EEC and in Council Directive 75/439/EEC of 16 June 1975 on the

disposal of waste oils2

with a capacity exceeding 10 tonnes per day

5.2

Installations for the incineration of municipal waste as defined in Council

Directive 89/369/EEC of 8 June 1989 on the prevention of air pollution

from new municipal waste incineration plants3 and Council Directive

89/429/EEC of 21 June 1989 on the reduction of air pollution from existing

municipal waste-incineration plants4

with a capacity exceeding 3 tonnes per hour

5.3 Installations for the disposal of non-hazardous waste as defined in Annex

II A to Directive 75/442/EEC under headings D8 and D9, with a capacity exceeding 50 tonnes per day

5.4 Landfills excluding landfills of inert waste receiving more than 10 tonnes per day or with a total capacity

exceeding 25 000 tonnes,

6.5 Installations for the disposal or recycling of animal carcases and animal

waste exceeding 10 tonnes per day

- 1 OJ No L 377, 31. 12. 1991, p. 20. Directive as amended by Directive 94/31/EC (OJ No L 168, 2. 7. 1994, p. 28). - 2 OJ No L 194, 25. 7. 1975, p. 23. Directive as last amended by Directive 91/692/EEC (OJ No L 377, 31. 12. 1991, p. 48). 3 OJ No L 163, 14. 6. 1989, p. 32.

4 OJ No L 203, 15. 7. 1989, p. 50.

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6. Other activities

6.1 Industrial plants for the production of:

(a) pulp from timber or other fibrous materials

(b) paper and board with a production capacity exceeding 20 tonnes per day

6.6 Installations for the intensive rearing of poultry or pigs (a) more than 40,000 places for poultry

(b) more than

2,000 places for production pigs (over 30 kg), or

(c) more than 750 places for sows

6.4 (a) Slaughterhouses with a carcase production capacity greater than 50 tonnes per day

(b) Treatment and processing intended for the production of food products

from:

— animal raw materials (other than milk) with a finished product production capacity greater than 75 tonnes per

day

— vegetable raw materials with a finished product production capacity greater than 300 tonnes

per day (average value on a quarterly basis)

(c) Treatment and processing of milk the quantity of milk received being greater than 200 tonnes per day

(average value on an annual basis)

6.2 Plants for the pre-treatment (operations such as washing, bleaching,

mercerization) or dyeing of fibres or textiles where the treatment capacity exceeds 10 tonnes per day

6.3 Plants for the tanning of hides and skins where the treatment capacity exceeds 12 tonnes of finished products

per day

6.7

Installations for the surface treatment of substances, objects or products

using organic solvents, in particular for dressing, printing, coating,

degreasing, waterproofing, sizing, painting, cleaning or impregnating,

with a consumption capacity of more than 150 kg per hour or more

than 200 tonnes per year

6.8 Installations for the production of carbon (hard-burnt coal) or

electrographite by means of incineration or graphitization

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Table 6-1: Categories of industrial activities and capacity threshold under EPER (Annex A3 of Council Decision 2000/479/EC (EPER Decision ) and Annex I

of Directive 96/61 (IPPC Directive)

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6.2 Synthesis reports for PAH reported under EU-EPER

Table 6-2: PAH emissions to air by MS 2001 and 2004 (source: EU-EPER)

2001 PAH [t/y] % of EU total Facilities 2004 PAH (t/y) % of EU total Facilities

Netherlands 0.081 0.06 1 Netherlands 72.97 5.25 4

Austria 0.21 0.16 1 Austria 0.29 0.02 2

Portugal 0.83 0.63 1 Portugal 1.12 0.08 2

Finland 1.15 0.88 2 Finland 1.21 0.09 2

Germany 2.21 1.86 8 Germany 1.47 0.11 7

Sweden 6.57 5.00 6 Sweden 10.98 0.79 7

Belgium 9.38 7.14 8 Belgium 24.53 1.76 13

United Kingdom 11.10 8.45 18 United Kingdom 5.95 0.43 13

Spain 17.67 13.45 16 Spain 38.80 2.79 24

Italy 29.61 22.53 14 Italy 28.04 2.02 7

France 52.59 40.03 11 France 8.66 0.62 20

Estonia 0.17 0.01 3

Slovenia 1.65 0.12 1

Czech Republic 2.63 0.19 4

Latvia 5.85 0.42 3

Poland 1,186.65 85.31 56

TOTAL 131.39 100 86 TOTAL 1,390.95 100 168

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Table 6-3: PAH emissions to air by industrial activity 2001 and 2004 (source: EU-EPER)

2001 2004 (EU 15) 2004 (EU 25)

PAH [t/y] % of EU

total PAH [t/y]

% of EU

total PAH [t/y]

% of EU

total

Combustion installations > 50 MW 2.23 1.70 4.47 2.30 17.17 1.23

Mineral oil and gas refineries 6.69 5.09 5.89 3.04 11.21 0.81

Coke ovens 1.35 1.03 0.828 0.43 42.24 3.04

Metal industry and metal ore roasting or sintering installations, Installations

for the production of ferrous and non-ferrous metals 55.13 41.96 86.48 44.58 208.09 14.96

Installations for the production of cement klinker (>500t/d), lime (>50t/d),

glass (>20t/d), mineral substances (>20t/d) or ceramic products (>75t/d) 7.97 6.07 4.60 2.37 21.88 1.57

Basic organic chemicals 33.45 25.46 8.30 4.28 15.36 1.10

Basic inorganic chemicals or fertilisers 0.17 0.13 0.276 0.14 0.276 0.02

Installations for the disposal or recovery of hazardous waste (>10t/d) or

municipal waste (>3t/h) 0.88 0.67 5.49 2.83 5.94 0.43

Installations for surface treatment or products using organic solvents

(>200t/y) 20.17 15.35 3.31 1.71 34.84 2.50

Installations for the production of carbon or graphite 3.34 2.54 74.30 38.30 74.30 5.34

Plants for the pre-treatment of fibres or textiles (>10t/d) 0.062 0.03 0.062 0.00

Slaughterhouses (>50t/d), plants for the production of milk (>200t/d), other

animal raw materials (>75t/d) or vegetable raw materials (>300t/d) 959.59 68.99

TOTAL 131.39 100 194.01 100.00 1,390.95 100

http://eper.cec.eu.int/eper/%09%09%09%09%09%09Emissions_source_Category.asp?ActivityId=2&year=2001&CountryCode=EU15%09%09%09%09%09%09%09&EmissionAir=on%09%09%09%09%09%09%09%09%09%09%09%09%09&EmissionWaterDirect=on%09%09%09%09%09%09%09%09%09%09%09%09%09&EmissionWaterIndirect=on%09%09%09%09%09%09














http://www.eper.cec.eu.int/eper/%09%09%09%09%09%09Emissions_source_Category.asp?ActivityId=21&year=2004&CountryCode=EU15%09%09%09%09%09%09%09&EmissionAir=on%09%09%09%09%09%09%09%09%09%09%09%09%09&EmissionWaterDirect=on%09%09%09%09%09%09%09%09%09%09%09%09%09&EmissionWaterIndirect=on%09%09%09%09%09%09



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Table 6-4: PAH releases into water (direct) by MS 2001 and 2004 (source: EU-EPER)

2001 PAH [t/y] % of EU total Facilities 2004 PAH [t/y] % of EU total Facilities

Belgium 0.041 0.32 1


Germany 0.19 1.47 2 Germany 0.349 1.69 5

United Kingdom 0.22 1.73 3 Unied Kingdom 0.21 1.01 3


France 1.11 8.73 13 France 0.20 0.96 3

Spain 2.75 21.70 5 Spain 1.39 6.71 7

Italy 8.02 63.39 13 Italy 3.45 16.67 9

Sweden 0.41 1.98 4


Slovakia 0.10 0.49 3

Poland 11.17 54.00 3

TOTAL 12.66 100 44 TOTAL 20.67 100 43

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Table 6-5: PAH releases into water (direct) by industrial activity 2001 and 2004 (source: EU-EPER)

2001 2004 (EU 15) 2004 (EU 25)

PAH [t/y] % of EU

total PAH [t/y]

% of EU

total PAH [t/y]

% of EU

total



Coke ovens 0.11 1.15 0.13 0.60







Installations for the disposal of nonhazardous waste (>50t/d) and landfills

(>10t/d) 0.06 0.31

Industrial plants for pulp from timber or other fibrous materials and paper or

board production (>20t/d) 0.006 0.05 0.22 2.37 0.22 1.08




Installations for the production of carbon or graphite 0.02 0.17 0.0053 0.06 0.0053 0.03

TOTAL 12.66 100 9.39 100.00 20.67 100


















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2001 PAH [t/y] % of EU total Facilities 2004 PAH [t/y] % of EU total Facilities

Italy 0.005 0.04 1

United Kingdom 0.006 0.02 1

Germany 0.046 0.35 4 Germany 1.48 5.08 7


France 0.18 1.36 4

Spain 0.55 4.24 6 Spain 0.29 0.99 2



Poland 25.54 87.69 4

TOTAL 13,03 100 19 TOTAL 29.12 100 20

Table 6-6: PAH releases into water (indirect) by MS 2001 and 2004 (source: EU-EPER)

Table 6-7: PAH releases into water (indirect) by industrial activity) 2001 and 2004 (source: EU-EPER)

2001 2004 (EU 15) 2004 (EU 25)

PAH [t/y] % of EU

total PAH [t/y]

% of EU total

PAH [t/y] % of EU

total

Combustion installations > 50 MW 0.005 0.04 0.00 0.77t 2.66


Coke ovens 0.024 0.19 0.14 5.29 1.12 3.84

Metal industry and metal ore roasting or sintering installations, Installations for the production of ferrous and non-ferrous metals 0.37 2.73 0.27 10.24 0.27 0.92


Basic inorganic chemicals or fertilisers 0.011 0.09

Pharmaceutical products 0.036 0.27 0.07 2.66 0.07 0.24

Installations for the disposal or recovery of hazardous waste (>10t/d) or municipal waste (>3t/h) 0.08 0.61 0.03 1.13 24.13 82.83

Plants for the pre-treatment of fibres or textiles (>10t/d) 12.28 94.27 0.08 3.19 0.08 0.29

Slaughterhouses (>50t/d), plants for the production of milk (>200t/d), other animal raw materials (>75t/d) or vegetable raw materials (>300t/d) 0.077 0.59

TOTAL 13.03 100 2.60 100 29.13 100

http://www.eper.cec.eu.int/eper/%09%09%09%09%09%09Emissions_source_Category.asp?ActivityId=2&year=2001&CountryCode=EU15%09%09%09%09%09%09%09&EmissionWaterIndirect=on%09%09%09%09%09%09













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6.3 Synthesis reports for PCDD/PCDF reported under EU-EPER

Table 6-8: PCDD/PCDF emissions into air by MS 2001 and 2004 (source: EU-EPER)

2001 PCCD/PCDF

[g TEQ/y] % of EU total Facilities 2004

PCCD/PCDF

[g TEQ/y] % of EU total Facilities

Austria 1.36 0.19 1 Austria 1.47 0.12 1

Sweden 1.70 0.23 1 Sweden 20.65 1.69 6

Netherlands 2.30 0.31 2 Netherlands



Belgium 57.57 7.83 4 Belgium 29.68 2.43 5

Germany 88.40 12.03 11 Germany 106.11 8.7 14

Spain 122.53 16.67 9 Spain 75.60 6.2 3

France 185.47 25.24 29 France 219.82 18.03 35

Italy 232.40 31.62 11 Italy 92.10 7.55 7

Hungary 2.50 0.21 1

Poland 246.00 20.17 6


TOTAL 734.88 g 100 84 TOTAL 1,121.94 100 98

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Table 6-9: PCDD/PCDF emissions to air by industrial activity 2001 and 2004 (source: EU-EPER)

2001 2004 (EU 15) 2004 (EU 25)

PCDD/PCDF

[g TEQ/y]

% of EU

total

PCDD/PCDF

[g TEQ/y]

% of EU

total

PCDD/PCDF

[g TEQ/y]

% of EU

total


Coke ovens 9.10 1.45 9.10 0.75



Installations for the production of cement klinker (>500t/d), lime (>50t/d),

glass (>20t/d), mineral substances (>20t/d) or ceramic products (>75t/d) 25.70 3.50 30.40 4.86 63.40 5.20


Basic inorganic chemicals or fertilisers 7.41 1.01 0.00

Biocides and explosives 3.00 0.25

Pharmaceutical products 9.00 1.22 0.00




(>10t/d) 6.00 0.82 13.00 1.07

Industrial plants for pulp from timber or other fibrous materials and paper or

board production (>20t/d) 2.85 0.39 11.68 1.87 11.68 0.96



Installations for surface treatment or products using organic solvents

(>200t/y) 1.06 0.14 1.27 0.20 1.27 0.10

TOTAL 734.88 100 625.95 100 1,219.45 100




















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6.4 Synthesis reports for HCB reported under EU-EPER

2001 HCB [kg/y] % of EU total Facilities 2004 HCB [kg/y] % of EU total Facilities

Spain 14.6 19.21 1

Finland 16.7 21.97 1

Belgium 21.0 27.63 1

Portugal 23.7 31.18 1

TOTAL TOTAL 76.0 100 4

Table 6-10: HCB emissions to air by MS 2001 and 2004 (source: EU-EPER)

Table 6-11: HCB emissions to air by industrial activity 2001 and 2004 (source: EU-EPER)


Sweden 1.02 7.02 1


France 2.00 12.92 1

Belgium 5.60 36.18 1

Italy 5.20 35.79 2

Germany 6.00 38.76 1 Germany 6.20 42.67 3

TOTAL 15.48 100 4 TOTAL 14.53 100 7

Table 6-12: HCB releases into water (direct) by MS 2001 and 2004 (source: EU-EPER)

2001 2004 (EU 15) 2004 (EU 25)

HCB [kg/y] % of EU total HCB [kg/y] % of EU

total HCB [kg/y]

% of EU total

Metal industry and metal ore roasting or sintering installations, Installations for the production of ferrous and non-ferrous metals 44.70 58.82


Installations for surface treatment or products using organic solvents (>200t/y) 14.60 19.21

TOTAL 76.00 100






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Table 6-13: HCB releases into water (direct) by industrial activity 2001 and 2004 (source: EU-EPER)



TOTAL TOTAL 7.50 100 1

Table 6-14: HCB releases into water (indirect) by MS 2001 and 2004 (source: EU-EPER)

Table 6-15: HCB releases into water (indirect) by industrial activity 2001 and 2004 (source: EU-EPER)

2001 2004 (EU 15) 2004 (EU 25)

HCB [kg/y] % of EU

total

HCB

[kg/y]

% of EU

total

HCB

[kg/y]

% of EU

total




municipal waste (>3t/h) 1.50 10.32 1.50 10.32


(>10t/d) 1.02 7.02 1.02 7.02

TOTAL 15.48 100 14.53 100 0.0145.3 100

2001 2004 (EU 15) 2004 (EU 25)

HCB [kg/y] % of EU

total

HCB

[kg/y]

% of EU

total

HCB

[kg/y]

% of EU

total

Basic organic chemicals 7.50 100.00

TOTAL 75.00 100








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6.5 Overview on EU-EPER releases for 2001 and 2004 by countries and industry sectors reporting in both

cycles

PAH emissions to AIR [t/y] Direct PAH releases into water [t/y] Indirect PAH releases into water [t/y] PCDD/PCDF [gTEQ/y]

2001 2004 2001 2004 2001 2004 2001 2004

NL 0.08 73.00 IT 8.02 3.45 PT 12.90 0.13 AT 1.36 1.47

AT 0.21 0.29 ES 2.75 1.39 ES 0.55 0.29 SE 1.70 20.65

PT 0.82 1.12 FR 1.11 0.20 NL 0.19 0.70 PT 3.52 11.60

FI 1.15 1.21 PT 0.27 3.38 DE 0.05 1.48 UK 39.63 68.92

DE 2.21 1.47 UK 0.22 0.21 Total 13.69 2.60 BE 57.57 29.68

SE 6.57 10.98 DE 0.19 0.35 DE 88.40 106.11

BE 9.38 24.53 NL 0.05 0.02 ES 122.53 75.60

UK 11.10 5.95 SE 0.02 0.41 FR 185.47 219.82

ES 17.67 38.80 Total 12.62 9.41 IT 232.40 92.10

IT 29.61 28.04 Total 732.58 625.95

FR 52.59 8.66

Total 131.39 194.05

Table 6-16: POP releases from large point sources for 2001 and 2004 by Member States reporting in both cycles

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PAH into AIR (both years reported) 2001 EU 15 % 2001 EU 15 %

Combustion installations > 50 MW 2.23 1.70 4.47 2.30

Mineral oil and gas refineries 6.69 5.09 5.89 3.04

Coke ovens 1.35 1.03 0.83 0.43

Metal industry and metal ore roasting or sintering installations, Installations for the production of ferrous and non-ferrous metals 55.13 41.96 86.48 44.59

Installations for the production of cement klinker (>500t/d), lime (>50t/d), glass (>20t/d), mineral substances (>20t/d) or ceramic products (>75t/d) 7.97 6.07 4.60 2.37

Basic organic chemicals 33.45 25.46 8.30 4.28

Basic inorganic chemicals or fertilisers 0.17 0.13 0.28 0.14

Installations for the disposal or recovery of hazardous waste (>10t/d) or municipal waste (>3t/h) 0.88 0.67 5.49 2.83

Installations for surface treatment or products using organic solvents (>200t/y) 20.17 15.35 3.31 1.71

Installations for the production of carbon or graphite 3.34 2.54 74.30 38.31

TOTAL [t/y] 131.38 100.00 193.94 100.00

Table 6-17: PAH emissions to air for 2001 and 2004 by industrial sector included in both reporting cycles

PAH WATER DIRECT (both years reported)

2001 EU 15

% 2001 EU 15 %

Combustion installations > 50 MW 1.02 8.23 0.58 34.15


Metal industry and metal ore roasting or sintering installations, Installations for the production of ferrous and non-ferrous metals 10.22 82.48 0.00


Basic inorganic chemicals or fertilisers 0.16 1.30 0.13 7.30


Industrial plants for pulp from timber or other fibrous materials and paper or board production (>20t/d) 0.01 0.05 0.22 13.02

Installations for the production of carbon or graphite 0.02 0.17 0.01 0.31

TOTAL [t/y] 12.39 100.00 1.71 100.00

Table 6-18: Direct PAH releases into water for 2001 and 2004 by industrial sector included in both reporting cycles






















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PAH WATER INDIRECT (both years reported)

2001 EU 15

% 2004 EU 15 %


Coke ovens 0.02 0.19 0.14 5.29

Metal industry and metal ore roasting or sintering installations, Installations for the production of ferrous and non-ferrous metals 0.36 2.75 0.27 10.24



Pharmaceutical products 0.04 0.28 0.07 2.66



TOTAL [t/y] 12.94 100 2.61 100

Table 6-19: Direct PAH releases into water for 2001 and 2004 by industrial sector included in both reporting cycles

PCDD/PCDF AIR (both years reported) 2001 EU 15 % 2004 EU 15 %

Combustion installations > 50 MW 0.10 13 0.12 19

Metal industry and metal ore roasting or sintering installations, Installations for the production of ferrous and non-ferrous metals 0.33 47 0.28 46

Installations for the production of cement klinker (>500t/d), lime (>50t/d), glass (>20t/d), mineral substances (>20t/d) or ceramic products (>75t/d) 0.03 4 0.03 5

Basic organic chemicals 0.13 18 0.00 0

Installations for the disposal or recovery of hazardous waste (>10t/d) or municipal waste (>3t/h) 0.12 17 0.18 28

Industrial plants for pulp from timber or other fibrous materials and paper or board production (>20t/d) 0.00 0 0.01 2

Installations for surface treatment or products using organic solvents (>200t/y) 0.00 0 0.00 0

TOTAL [g TEQ/y] 0.71 100 0.62 100

Table 6-20: PCDD/PCDF emissions to air for 2001 and 2004 by industrial sector included in both reporting cycles

1HCB WATER Direct (both years reported) 2001 EU 15 % 2004 EU 15 %

Basic organic chemicals 0.01 88 0.01 52

Basic inorganic chemicals or fertilisers 0.00 12 0.01 48

TOTAL [kg/y] 0.02 100 0.01 100

Table 6-21: Direct HCB releases into water for 2001 and 2004 by industrial sector included in both reporting cycles





















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7 E-PRTR pilot inventory on releases from diffuse sources

7.1 Source sectors covered in the pilot inventory on releases from diffuse sources

Diffuse Source CRF/NFR

code CRF/NFR code

ROAD TRANSPORT

1 A 3 b (i-vii)

1 A 3 e (i+ii)

Fuel Combustion in Road Transportation ( including passenger cars, light and heavy duty, mopeds and motorcycles, gasoline evaporation, tyre and brake wear and road abrasion)

Fuel Combustion in Other Transportation ( including pipeline compressors and other mobile sources and machinery)

SHIPPING 1 A 3 d ii Fuel Combustion in Navigation (national)

AVIATION 1 A 3 a ii (i+ii) Fuel Combustion in Civil Aviation (domestic LTO and cruise)

RAILWAY 1 A 3 c Fuel Combustion in Railways

SMALL CONSUMER FUEL COMBGSTION

1 A 4 a

1 A 4 b (i+ii)

Commercial and Institutional Fuel Combustion

Residential Fuel Combustion (including residential plants and household and gardening (mobile))

MILITARY 1 A 5 a

1 A 5 b

Stationary Fuel Combustion (including Military

Mobile Fuel Combustion (including Military)

FOSSIL FUEL DISTRIBGTION (GAS) 1 B 2 b Distribution of natural gas

ROOFING AND ROAD PAVING WITH ASPHALT

2 A 5

2 A 6

Industrial Processes - Asphalt Roofing

Industrial Processes - Road Paving with Asphalt

SOLVENT USE

3 A

3 B

3 D

- Paint Application

- Degreasing and Dry Cleaning

- Other Solvent Use and Application (including products containing HMs and POPs)

AGRICULTURE

1 A 4 c (i-iii)

4 A

4 B

4 C

4 D

4 F

4 G

Fuel Combustion in Agriculture/Forestry/Fishing

Enteric Fermentation

Manure Managements

Rice Cultivation

Agricultural Soils (corresponding to 4D1 ―direct soil emissions‖; no data reported for other 4D sub-sectors))

Field Burning of Agricultural Wastes

Other Agricultural Processes

CRF = Common Reporting Format used for the reporting under NEC, CLRTAP and UNFCCC; NFR = Nomenclature For Reporting,

Table 7-1: Overview of diffuse sectors used in the pilot E-PRTR inventory on releases of diffuse sources and corresponding CRF/NFR sub-codes

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7.2 Reported Member State POPs emission to air from diffuse sources

MS PAH (t/a) % of EU total PCDD/ PCDF (g/a) % of EU total HCB (kg/a) % of EU total PCB (kg/a) % of EU total

AT 8.78 1.29 35.00 15.91 42.10 0.71

BE 106.00 15.55 3.40 1.55

CY 1.44 0.65

CZ 0.74 0.11 0.33 0.15

DE 0.90 0.13

DK 5.86 0.86 14.80 6.73

EE 10.90 1.60 1.67 0.76 0.09 6.00 5.91

ES 50.30 7.38 42.20 19.19 563 94.60

FI 0.82 0.12 0.92 0.42

FR 34.90 5.12 37.70 17.14 7.98 0.13 16.10 15.87

GR

HU 0.82 0.12 2.49 1.13 0.03 0.84 0.83

IE 11.40 1.67 7.81 3.55

IT

LT 20.90 3.07 9.69 4.41 7.40 7.29

LU

LV

MT

NL 408.00 59.84 34.30 15.60

PL 0.46 0.07 2.83 1.29 0.08 2.92 2.88

PT

SE 14.80 2.17 2.96 1.35 0.02 0.08 0.08

SI 4.94 0.72 0.91 0.41 61.00 60.13

SK

UK 6.53 0.96 21.50 9.78 271.00 4.55 7.11 7.01

TOTAL 681.78 100.77 219.94 100 5951.30 100 101.45 100

Table 7-2: EU overview on POPs emission from diffuse sources to air 2003 (Source: Pilot E-PRTR data base on diffuse sources)

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7.3 PAH “diffuse” emissions by source sector and Member State

PAH [kg/y]

TOTAL

ALL

SECTORS

ROAD

TRANSPORT SHIPPING AVIATION RAILWAY MILITARY

AGRI-

CULTURE

SOLVENT

USE

SMALL

CONSUMER

FUEL

COMBGSTION

FOSSIL

FUEL

DISTRIBGT

ION (GAS)

ROOFING

AND ROAD

PAVING WITH

ASPHALT

AT 8.78 1.43 0.02 0.76 6.57

BE 106.00 75.50 2.13 0.79 2.32 11.50 2.42 11.00

CY

CZ 0.74 0.64 0.06 0.03

DE 0.90 0.90

DK 0.59 0.01 0.57

EE 10.90 0.04 0.03 10.80

ES 50.30 2.36 0.23 0.14 27.90 19.70

FI 0.82 0.04 0.78

FR 34.90 4.23 0.50 30.20

GR

HU 0.82 0.82

IE 11.40 0.21 0.09 11.00

IT

LT 20.90 0.65 0.82 19.40

LU

LV

MT

NL 408.00 106.00 4.58 1.98 0.30 0.25 10.30 219.00 65.00

PL 0.46 0.02 0.01 0.42

PT

SE 14.80 0.10 14.70

SI 4.94 4.56 0.02 0.36

SK

UK 6.53 1.77 0.04 0.02 0.10 4.59 0.02

Total 681.78 198.29 6.99 2.12 1.19 0.29 42.83 230.63 187.36 11.02

source: EMEP WebDab (reporting year: 2003, GR and PT 2000, PL 2001)

Table 7-3: Data on PAH emission from diffuse sources to air 2003(Source: Pilot E-PRTR data base on diffuse sources)

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7.4 PCDD/PCDF “diffuse” emissions by source sector and Member State

PCDD+PCDF

[gTEQ/y]

TOTAL

ALL

SECTORS

ROAD


AGRI-

CULTURE

SOLVENT

USE

SMALL

CONSUMER

FUEL

COMBGSTION

FOSSIL FUEL

DISTRIBGTION

(GAS)

ROOFING

AND ROAD

PAVING WITH

ASPHALT

AT 35.00 1.22 0.02 2.11 31.60

BE 3.40 0.44 2.97

CY 1.44 1.44

CZ 0.33 0.06 0.05 0.21

DE

DK 14.80 0.20 1.30 13.30 0.04

EE 1.67 0.10 0.01 1.56

ES 42.20 4.87 3.06 3.83 30.40

FI 0.92 0.01 0.90

FR 37.70 2.71 1.40 32.50 0.84

GR

HU 2.49 2.27 0.22

IE 7.81 0.16 0.06 7.59

IT

LT 9.69 0.07 9.62

LU

LV

MT

NL 34.30 0.89 0.12 10.20 0.01 0.06 0.33 18.50 4.22

PL 2.83 0.61 0.43 1.78

PT

SE 2.96 0.58 0.05 0.02 2.31

SI 0.91 0.91

SK

UK 21.50 3.57 0.22 1.30 7.52 8.91

Total 219.94 14.80 4.74 10.20 1.33 0.12 15.95 33.24 136.40 2.89


Table 7-4: Data on PCDD/PCDF emission from diffuse sources to air 2003 (Source: Pilot E-PRTR data base on diffuse sources)

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7.5 HCB “diffuse” emissions by source sector and Member State

HCB

[kg/y]

TOTAL

ALL

SECTORS

ROAD


AGRI-

CULTURE

SOLVENT

USE

SMALL CONSUMER

FUEL

COMBGSTION

FOSSIL FUEL

DISTRIBGTION

(GAS)

ROOFING AND

ROAD PAVING

WITH ASPHALT

AT 42.10 0.25 2.99 38.90

BE

CY

CZ

DE

DK

EE 0.09 0.09

ES 5,630.00 0.15 5,630.00

FI

FR 7.98 6.91 0.01 1.06

GR

HU 0.03 0.03

IE

IT

LT

LU

LV

MT

NL

PL 0.08 0.08

PT

SE 0.02 0.02

SI

SK

UK 271.00 271.00 0.07

Total 5,951.30 7.16 0.18 5,903.99 40.24

Source: EMEP WebDab (reporting year: 2003, GR and PT 2000, PL 2001)

Table 7-5: Data on HCB emission from diffuse sources to air 2003 (Source: Pilot E-PRTR data base on diffuse sources)

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7.6 PCB “diffuse” emissions by source sector and Member State

PCB

[kg/y]

TOTAL

ALL

SECTORS

ROAD


AGRI-

CULTURE

SOLVENT

USE

SMALL CONSUMER

FUEL COMBGSTION

FOSSIL FUEL

DISTRIBGTION

(GAS)

ROOFING AND

ROAD PAVING

WITH ASPHALT

AT

BE

CY

CZ

DE

DK

EE 6.00 0.06 5.95

ES

FI

FR 16.10 0.01 0.09 16.00

GR

HU 0.84 0.84

IE

IT

LT 7.40 0.19 7.21

LU

LV

MT

NL

PL 2.92 2.92

PT

SE 0.08 0.08

SI 61.00 61.00

SK

UK 7.11 0.06 7.05

Total 101.45 0.10 0.40 39.97


Table 7-6: Data on PCB emission from diffuse sources to air 2003 (Source: Pilot E-PRTR data base on diffuse sources)

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8 Details on POP releases according to Article 12 Reports

8.1 Austria

Table 8-1: Dimension of emission reduction of POP emissions in Austria (Source: Article 12 Report)

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Table 8-2: Time trend and sector allocation for HCB emissions in Austria (Source: Article 12 Report)

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Table 8-3: Time trend and sector allocation for PCDD/PCDF emissions in Austria (Source: Article 12 Report)

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Table 8-4: Time trend and sector allocation for HCB emissions in Austria (Source: Article 12 Report)

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8.2 Belgium

Flanders

Source Category according to Action plan Annual Releases (gTEQ/a)

Air

Residential combustion 8,8

Open burning of waste 22,92

Ferrous metal industry 7,12

Non-ferrous metal industry 0,78

Wood industry 0,08

Construction, asphalt and rubber industry 0,096

Road transport 0,17

Refineries 0,25

Municipal waste incineration 0,07

Industrial waste incineration 3

Hazardous waste incineration 0,09

Heating in service sector 0,22

Crematoria 0,001

Sewage sludge incineration and other 0,07

Total 43,57

Table 8-5: Major sources for PCDD/PCDF emissions to air in Flanders 2005 (Source: Article 12 report)

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Brussels Capital Region

Années Emission en tonnes % évolution / 1990

1990 8.365,0 0,0

1991 8.883,1 6,2

1992 8.634,1 3,2

1993 8.331,4 -0,4

1994 7.692,0 -8,0

1995 7.629,6 -9,1

1996 7.117,1 -8,8

1997 6.561,4 -14,9

1998 6.561,4 -21,6

1999 3.799 -54,6

2000 1.972 -77,6

Table 8-6: Time trend of PAH emissions to air in the Brussels Capital Region (Source: Article 12 Report)

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8.3 Bulgaria

Figure 8-1: Time trend and major sources for PCDD/PCDF emissions to air in Bulgaria (Source: NIP)

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Figure 8-2: Time trend for PCB and HCB for emissions to air and major sources for PCB in Bulgaria (Source: NIP)

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8.4 Cyprus

Figure 8-3: Time trend and major sources for PCDD/PCDF emissions to air in Cyprus (Source: NIP)

0

2

4

6

8

10

12

14

1990

1991

1992

1993

1994

1995

1996

1997

1998

1999

2000

2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

g I-T

EQ

/year

Total

Dioxins Air

Dioxins Land

0

1

2

3

4

5

6

7

8

1990

1991

1992

1993

1994

1995

1996

1997

1998

1999

2000

2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

g I-T

EQ

/ye

ar

Combustion Industrial Processes

Open Burning Incineration

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Figure 8-4: Time trend and major sources for HCB emissions to air in Cyprus (Source: NIP)

Figure 8-5: Time trend of PCB emissions to air in Cyprus (Source: NIP)

0

20

40

60

80

100

120

140

160

180

200

1990

1991

1992

1993

1994

1995

1996

1997

1998

1999

2000

2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

g H

CB

/year

Total

Incineration/Open burning

Combustion

0

20

40

60

80

100

120

140

160

180

200

1990

1991

1992

1993

1994

1995

1996

1997

1998

1999

2000

2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

g H

CB

/year

Incineration/Open burning

Combustion

0

5

10

15

20

25

30

35

1990

1991

1992

1993

1994

1995

1996

1997

1998

1999

2000

2001

2002

2003

2004

2005

2006

2007

2008

2009

2010

kg

PC

Bs/y

ear

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8.5 Denmark

Activity Release (g TEQ/yr)

1995 2000-2002

Industrial processes Chemicals production Secondary steel production Secondary aluminium production Other metallurgical industry Production of cement and quicklime Other industrial production

not determined

7.5 not determined not determined

0.08 - 1.5 0.1

0.001 - 0.007

0.1 - 2.4 < 0.001 - 0.79

0.02 - 0.5 0.2 - 1.4 0.04 - 0.1

Energy transfer Burning of coal Burning of other fossil fuels Wood-burning stoves Combustion of biomass in other small plants Combustion of biomass in larger plants

2

0.02 1.1

0.1 - 3.2 0.4 - 1.3 0.4 - 22 0.3 - 15

0.03 - 4.4

Use of products PCP-treated wood Other PCP-treated materials

not determined not determined

0.5 - 26 < 0.05

Miscellaneous activities Accidental fires Intentional fires Traffic Crematoria Other activities

not determined not determined

0.2 0.16

not determined

0.5 - 20

0.03 - 6.5 1.3 - 1.7 0.01 - 0.1 0.1 – 0.2

Treatment and disposal of waste Recovery of cable waste Car-breakers Incineration of waste oil Incineration of hazardous waste Incineration of municipal waste Incineration of medical waste Incineration of sewage sludge Landfill fires

0.13

not determined 0.03 0.23 25 5

0.072 not determined

0.03 - 0.2

< 0.001 - 0.079 < 0.001 - 0.17 0.004 - 0.03

6.4 - 29 < 0.001 - 0.35

0.002 0.25 - 10

Total 38 - 45 11 - 163

0.07 - 6.6

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Please note that the figures are being revised. New figures for 1990 and 2004 will be available before the end of 2006

Table 8-7: Releases of dioxin into the air, analysed by source categories, in 1995 and 2000-2002 (Source: NIP)

Activity Release (g TEQ/yr)

Water Soil

Industrial processes

Chemicals production

Secondary steel production

Secondary aluminium production

Other metallurgical industry

Production of cement and quicklime

Other industrial production

< 0.001

?

< 0.01

< 1

?

?

Energy transfer

Wood-burning stoves

Combustion of biomass in other small plants

< 0.001 - 2.2

< 0.001 - 0.09

Use of products

Animal feed (manure)

?

< 10

Miscellaneous activities

Accidental fires

Intentional fires

Cremation

Other activities

?

?

0.01-27.5

?

?

Treatment and disposal of waste

Incineration of hazardous waste

Wastewater and storm water discharges

Sewage sludge

Other activities

< 0.001

0.4 - 1.4

0.7 - 1.3

0.01 - 0.1

Total 0.4 - 1.4 (+?) 0.7 - 42 (+?)

Table 8-8: Releases of dioxin into the air and oil, analysed by source categories in 2000-2002 (Source: NIP)

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8.6 Finland

Figure 8-6: Total dioxin and furan emissions into the air in Finland, 1990-2003 (Source: NIP)

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8.7 France

PCB PCDD-F HCB

Source / Année 2003 2004 2005 2003 2004 2005 2003 2004 2005

Energy 22.6 23.4 22.9 176 237 161 11 11 12

Fuel combustion (Sectoral Approach)

22.6 23.4 22.9 175 235 159 11 11 12

Energy Industries 3.1 3.5 3.1 97 163 93 3 3 3

Manufacturing Industries and construction

3.2 3.6 3.6 48 45 41 0 0 0

Transport 0 0 0 3 3 2 7 7 7

Other Sectors 16.3 16.2 16.1 26 25 23 1 1 1

Industrial Processes 0 0 0 14 15 14 0 0 0

Mineral Products 0 0 0 1 1 1 0 0 0

Metal Production 0 0 0 13 14 13 0 0 0

Waste Incineration 4.2 4.2 4.3 49 51 46 17 12 7

National Total 26.8 27.6 27.2 240 303 220 28 23 18

Table 8-9: Sector allocation for POP emissions in France Source: Article 12 report (Emissions between 2002 – 2005)

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Benzo(a)pyrene Benzo(b)fluoranthene

Benzo(k)fluoranthene Indeno(1,2,3-cd)pyrene TOTAL 4 HAP

Source / année

2003 2004 2005 2003 2004 2005 2003 2004 2005 2003 2004 2005 2003 2004 2005

Energy 7.6 7.2 6.7 8.9 8.5 8 5.9 5.7 5.4 4.8 4.6 4.3 27.2 25.9 24.4

Fuel combustion (Sectoral Approach)

7.6 7.2 6.7 8.9 8.5 8 5.9 5.7 5.4 4.8 4.6 4.3 27.2 25.9 24.4

Energy Industries

0.1 0.1 0 0.1 0.1 0.1 0.1 0.1 0.1 0 0 0 0.2 0.2 0.2

Manufacturing Industries and construction

0 0 0 0.1 0.1 0.1 0 0 0 0 0 0 0.2 0.2 0.2

Transport 0.9 1 1 1.3 1.3 1.3 1.1 1.1 1.2 0.9 0.9 0.9 4.2 4.3 4.4

Other Sectors

6.5 6.1 5.7 7.5 7 6.5 4.7 4.4 4.1 3.8 3.6 3.3 22.6 21.2 19.6

Industrial Processes – Metal production

0.1 0.1 0.1 0 0 0 0.2 0.2 0.2 0 0 0 0.2 0.2 0.2

National Total

7.6 7.2 6.8 8.9 8.5 8 6.1 5.8 5.5 4.8 4.6 4.3 27.4 26.1 24.7

Table 8-10: Sector allocation of PAH emissions in France Source: Article 12 report (Emissions between 2002 – 2005)

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8.8 Germany

Table 8-11: Time trend of PCDD/PCDF air emissions in Germany (Source: Article 12 Report)

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Table 8-12: Time trend of PAH (total not only Sum 4!) air emissions in Germany (Source: Article 12 Report)

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Table 8-13: Time trend of PCB air emissions in Germany (Source: Article 12 Report)

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8.9 Italy

Substance 2004 2005

PCDD/PCDF 294 g TEQ/anno 298 g TEQ/anno

PAH 134 tonn/anno 130 tonn/anno

PCB 286 kg/anno

HCB 24 kg/anno

Table 8-14: Overview on POP emissions to air in Italy (Source: Article 12 Report)

Substance 2004 2005

PAH 3,5 tonn/anno 8,4 tonn/anno

HCB 5 kg/anno 39 kg/anno

Table 8-15: Overview on POP releases to water in Italy (Source: Article 12 Report)

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8.10 Lithuania

Source category Annual releases (gTEQ/y)

Air Water Land Product Residue

Waste incineration 20.22 1.14

Metal production 0.09 0.24

Power generating and heating

2.6 0.88

Production of mineral products

0.38 0.06

Transportation 0.07

Uncontrolled combustion processes

14 0.3 13

Production of chemicals and consumer goods

0.42

Miscellaneous 0.08 0.21

Disposal/landfilling 0.1 0.02 3.1

TOTAL 37.44 0.1 0.3 0.44 18.63

Table 8-16: PCDD/PCDF air emissions in Lithuania in 2003 Source: Inventory of Dioxin and Furan releases in Lithuania

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Chemical Source category 2004 2005

Dioxins/furans Public electricity and Heat production 0.82 0.84

Manufacturing industries and construction 0.55 0.57

Road transportation 0.21 0.2

National navigation 0.02 0.03

Commercial/institutional 0.12 0.12

Residential 9.03 9.08

Agriculture 0.03 0.03

Mineral products 0.02

Total 10,80 gTEQ/y 10,87 gTEQ/y

HCB Total NA NA

PCB Total 23,80 kg/y 25,06 kg/y

PAH Total 15430 kg/y 15560 kg/y

Table 8-17: Sector distribution for POP emissions to air in Lithuania, Source: Annual Report according to the requirements of UN Convention on Long-

Range Transboundary Air Pollution

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8.11 Romania

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Figure 8-7: Evolution of PAH, PCDD/PCDF emissions in the period of time 1989 –2001 (Source: NIP)

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Figure 8-8: Evolution of PCB and HCB emissions into air in the period of time 1989 –2001 (Source: NIP)

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Figure 8-9: Participation of economic sector to the total POPs unintentionally emitted in 2001 (PAH, PCBs, Dioxins, HCB) (Source: NIP)

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8.12 Slovak Republic

Category

G TEQ PCDD/PCDF

2004 2005

Air* Surface water* Soil* Air

Surface water Soil

Waste incineration 19,723 0 0 41,213 - -

Ferrous and non-ferrous metal production 37,523 2,9E-07 0 36,153 - -

Power and heat generation, thermic processes 8,137 0 0 7,011 - -

Production of mineral products 0,488 0 0 0,551 - -

Transport 0,167 0 0 0,160 - -

Uncontrolled combustion processes 0,561 0 0,373 0,742 - -

Production and use of chemicals 0,020 0,002 0 0,021 - -

Miscellaneous 0,078 0 0 0,084 - -

TOTAL 66,697 0,002 0,373 85,935 - -

* Estimated in the framework of GEF project ―Initial Assistance to the Slovak Republic to Meet its Obligations under the Stockholm Convention on Persistent Organic Pollutants (POPs)―, year 2001

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Category

PAH

2004 2005

Air Surface water

Soil

Air Surface water

Soil kg/y kg/y kg/y kg/y

Waste incineration 10 - - 11 - -

Ferrous and non-ferrous metal production 2 933 29,9 - 2 245 22,2 -

Power and heat generation, thermic processes 11 996 - - 16 084 0,002 -

Production of mineral products 0

Without mining 0,003

(including mining

16,5) - 0

Without mining 0,012

(including mining

20,5) -

Transport 107 - - 124 - -

Uncontrolled combustion processes 111 - - 146 - -

Production and use of chemicals 0

Without refinery

- 0

Without refinery

17,4 (including

refinery 62,1) -

0 (including refinery

51,2)

Miscellaneous 598 12,2 - 591 7,6 -

TOTAL 15 755 - - 19 201 - -

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Category

HCB

2004 2005

Air Surface water

Soil

Air Surface water


Waste incineration 1 - - 0,656 - -

Ferrous and non-ferrous metal production 0,371 - - 0,512 - -

Power and heat generation, thermic processes 0,924 - - 0,750 - -

Production of mineral products 0,038 - - 0,043 - -

Transport 0,009 - - 0,010 - -

Uncontrolled combustion processes 0,010 - - 0,013 - -

Production and use of chemicals 0,038 - - 0,043 - -

Miscellaneous 0 - - 0 - -

TOTAL 2,39 - - 2,027 - -

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Category

PCB

2004 2005

Air

Surface

water

Soil

Air

Surface

water


Waste incineration 1,709 - - 1,987 - -

Ferrous and non-

ferrous metal

production 6,053 - - 5,837 - -

Power and heat

generation, thermic

processes 13,371 - - 13,953 - -

Production of mineral

products 0,016 - - 0,020 - -

Transport 10,471 - - 12,783 - -

Uncontrolled

combustion processes 0,067 - - 0,089 - -

Production and use of

chemicals 0,016 - - 0,020 - -

Miscellaneous 0,002 - - 0,002 - -

TOTAL 31,705 - - 34,691 - -

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Figure 8-10: Development of unintended POPs emissions to the air during years 1990 – 2004: PCDD/F and PCB (Source: NIP)

Figure 8-11: Development of unintended POPs emissions to the air during years 1990 – 2004: PAH (Source: NIP)

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Figure 8-12: Proportion of individual sectors on air emissions of PCDD/PCDF and PCB in 2004 (Source: NIP)

Figure 8-13: Proportion of individual sectors on air emissions of HCB and PCB in 2004 (Source: NIP)

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8.13 Slovenia

Year PCB PCDD/PCDF PAH HCB

kg g I-Teq Mg kg

1990 358 15.87 36.07 0.75

1991 358 16.26 34.09 0.63

1992 317 14.74 31.93 0.63

1993 287 13.39 31.56 0.63

1994 266 12.51 31.1 0.63

1995 236 11.93 30.85 0.63

1996 215 11.82 30.14 0.64

1997 195 10.9 30.8 0.66

1998 185 10.55 30.47 0.65

1999 154 10.45 30.71 0.63

2000 144 10.35 30.9 0.63

2001 123 9.48 29.33 0.64

2002 93 9.5 26.43 0.54

2003 82 9.65 28.25 0.25

2004 52 9.31 28.56 0.26

2005 42 9.3 28.75 0.26

trend -88.27 -41.4 -20.29 -65.37

(Source: Art. 12 report)

Table 8-18: Emissions to air from 1990 to 2006

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8.14 Spain

Data on PCDD/PCDF, HCB and PAH for the years 2004, 2005 and 2006 are available through the EPER Register. Releases to water (direct and

indirect) and air are registered as follows:

N.B. The EPER Register does not consider releases to land.

It has to be noted that the Spanish industrial sector is composed mainly of SMEs.

PCDD + PCDF.

Air (tons/year)

Water (direct releases

tons/year)

Water (indirect releases

tons/year)

2004 0 0 0

2005 0 0 0

2006 0.016 0 0

HCB.

Air (tons/year)


tons/year)


tons/year)

2004 0.015 0 0

2005 0.065 0 0

2006 0.552 0 0

HAP

Air (tons/ year)


tons/ year)


tons/ year)

2004 38.7 1.38t 0.287

2005 34.0 0.85 0

2006 526 3.980 8.25

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8.15 Sweden

DIOXINS

Emissions to air (g TEQ/yr)

Releases to water (g TEQ/yr)

Products and wastes (g TEQ/yr)

Iron and steel work and pellet plants 5.9 - 8.6 -- --

Non-ferrous metal works and foundries

5.6 - 10.3 -- < 2

Cement industry 0.2 - 0.3 -- --

Pulp and paper industry 1.2 < 0.1 < 5

Chlor-alkali industry -- 0.001 - 0.02 0.008 - 0.26

Fossil fuel-fired boilers < 4 -- --

Small-scale wood burning and large-scale burning of biomass fuels

< 14 -- < 11

Waste incineration 1.1 -- ~ 160

Landfill fires 0.4 - 65 -- --

Road transport 0.6 -- --

Shipping to and from Swedish ports 0.2 - 0.5 -- --

Table 8-19: Magnitudes of a number of primary dioxin sources 2004 (Source: Article 12 reports)

Quantities of dioxins have been estimated using different systems, and are shown in grams TEQ (Toxic equivalents). The systems used are

Eadon, I-TEQ, N-TEQ and WHO-TEQ. The purpose of the table is to give an idea of the relative order of magnitude of the different types of

sources. A dash means that no reliable data are available. The figures are based on emission factors and/or measurements.

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PCBs and HCB

Emissions to air Releases to water Products and wastes

PCBs (g/yr) HCB (g/yr) PCBs (g/yr) HCB (g/yr) PCBs (g/yr) HCB (g/yr)

Iron and steel works and pellet plants

-- 33,000 -- -- -- --

Non-ferrous metal works and foundries

-- 370 - 1,500 -- -- 0.11 --

Cement industry 0.41 < 3.9 -- -- -- --

Pulp and paper industry -- -- -- -- -- --

Chlor-alkali industry -- -- 0.1 - 0.651 1.5 - 15.5 0.4 - 1.2

1 7 - 29

Fossil fuel-fired boilers -- -- -- -- -- --

Small-scale wood burning and large-scale burning of biomass fuels

< 0.41 < 800 -- -- 1,000 - 7,000

2 50 - 330

Waste incineration < 1202 -- -- -- 3,000 - 4,000

2 600 - 6,000

Landfill fires 300 – 4,0003 100 - 2,500 -- -- -- --

Road transport -- -- -- -- -- --

Shipping to and from Swedish ports

280 - 6602 70 - 160 -- -- -- --

1 TEQ

2 PCB tot

3 PCB7

Table 8-20: Magnitudes of a number of primary sources of unintentionally produced PCB and HCB 2004 (Source: Article 12 reports)

Quantities of PCBs have been estimated using different systems: each number is labelled and explained in the footnotes below the table. The

purpose of the table is to give an idea of the relative order of magnitude of the different types of sources. A dash means that no reliable data are

available. The figures are based on emission factors and/or measurements.

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8.16 United Kingdom

Figure 8-14: Dioxin releases in the UK (2004) Total Emissions 348 g I-TEQ/year (Source: NIP)

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Figure 8-15: PCBs (1330 kg/year) and HCB (870 kg/year) releases in the UK (2004) Total Emissions (Source: NIP)

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Figure 8-16: Total Time series of dioxins emissions to air (grams I-TEQ) (Source: NIP)

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Figure 8-17: Time series of PCBs emissions to air (kg) (Source: NIP)

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Figure 8-18: Time series of HCB emissions to air (kg) (Source: NIP)

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9 Environmental level of POPs within the European Union from EMEP MSC-E-Country

Reports

9.1 Average PCDD/PCDF concentrations in environmental compartments as reported in EMEP country

reports

MS Air concentrations PCDD/Fs

(fg TEQ/m3)

Soil concentrations PCDD/Fs

(pg TEQ/g)

Vegetation concentrations PCDD/Fs

(pg TEQ/g)

Mean Min Max Mean Min Max Mean Min Max

AT 1.66 0.73 4.05 0.38 0.29 0.53 5.79 2.95 8.35

BE 3.02 1.43 4.83 0.61 0.43 0.86 8.94 2.44 12.32

BG 4.83 1.87 38.62 0.23 0.12 0.31 9.24 3.02 62.45

CY 2.42 1.99 3.12 0.05 0.03 0.08 5.8 2.26 7.84

CZ 3.96 1.42 13.50 0.53 0.42 0.62 9.81 4.19 25.36

DE 1.46 0.76 6.16 0.51 0.21 0.80 4.52 1.1 13.51

DK 1.11 0.41 3.46 0.19 0.01 0.30 2.96 1.01 11.61

EE 0.68 0.53 1.07 0.14 0.10 0.16 2.05 0.88 3.64

ES 0.86 0.41 15.08 0.11 0.02 0.21 2.68 0.43 20.17

FI 0.38 0.12 1.88 0.11 0.02 0.18 2.76 0.42 9.4

FR 1.16 0.53 7.10 0.37 0.02 0.86 3.85 0.83 14

GR 3.33 1.87 25.26 0.17 0.01 0.27 8.15 1.02 36.08

HU 4.16 1.83 27.09 0.29 0.24 0.43 3.92 3.85 33.97

IE 0.57 0.32 2.06 0.06 0.03 0.08 2.86 0.9 10.39

IT 2.54 0.73 23.32 0.23 0.04 0.47 5.77 0.56 47.08

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MS Air concentrations PCDD/Fs

(fg TEQ/m3)

Soil concentrations PCDD/Fs

(pg TEQ/g)

Vegetation concentrations PCDD/Fs

(pg TEQ/g)

Mean Min Max Mean Min Max Mean Min Max

LT 1.02 0.77 1.72 0.18 0.13 0.25 2.32 1.58 4.1

LU 2.20 1.71 2.75 0.72 0.65 0.80 7.79 6.87 8.27

LV 0.82 0.56 2.99 0.16 0.11 0.17 2.11 0.99 3.65

MT 3.04 1.64 3.28 0.03 0.03 0.03 10.9 5.84 11.8

NL 2.31 1.04 9.89 0.50 0.28 0.62 5.98 1.49 11.77

PL 3.52 1.26 13.50 0.36 0.17 0.62 7.49 1.82 23.41

PT 0.51 0.36 1.23 0.07 0.03 0.10 1.65 0.5 4.02

RO 3.36 1.87 9.10 0.21 0.08 0.33 5.98 3.19 11.87

SE 0.44 0.13 3.46 0.13 0.03 0.27 2.29 0.42 12.22

SI 2.59 1.75 5.90 0.31 0.27 0.36 5.09 3.62 12.58

SK 3.89 3.02 14.57 0.42 0.28 0.56 7.88 4.16 18.16

UK 1.25 0.29 5.70 0.21 0.01 0.45 5.69 1.05 21.4

Total 2.11 1.09 9.28 0.27 0.15 0.40 5.34 2.13 17.02

Table 9-1: Average concentrations of PCDD/PCDF in environmental compartments 2006 (Source: EMEP MSC-E country reports)

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9.2 Average PAH concentrations in environmental compartments as reported in EMEP country reports

MS Mean PAH concentrations in ambient air

(ng/m3)

Mean PAH concentrations in soil

(ng/g)

Mean PAH concentrations in vegetaion

(ng/g)

PAH* B[a]P B[b]F B[k]F IP PAH* B[a]P B[b]F B[k]F IP PAH* B[a]P B[b]F B[k]F IP

AT 0.75 0.17 0.29 0.08 0.21 0.51 0.12 0.2 0.06 0.13

279.36 69.70 107.22 35.06 67.38

BE 1.24 0.34 0.44 0.13 0.33 0.46 0.14 0.16 0.06 0.10

323.12 127.80 99.79 43.94 51.59

BG 1.12 0.26 0.42 0.13 0.31 0.53 0.13 0.20 0.07 0.13

245.74 65.28 90.17 34.89 55.40

CY 3.15 1.22 0.63 0.17 1.13 0.66 0.28 0.11 0.04 0.23

681.53 391.24 107.49 43.28 139.52

CZ 1.30 0.33 0.46 0.14 0.37 0.65 0.17 0.23 0.08 0.17

373.17 109.71 128.69 47.75 87.02

DE 1.33 0.34 0.49 0.14 0.36 0.60 0.17 0.22 0.07 0.14

337.48 111.23 121.79 45.38 59.08

DK 0.78 0.19 0.28 0.11 0.20 0.35 0.10 0.12 0.06 0.07

170.14 59.74 53.46 35.00 21.94

EE 0.94 0.24 0.38 0.13 0.19 0.56 0.16 0.22 0.09 0.09

365.03 116.61 134.16 59.81 54.45

ES 0.43 0.09 0.18 0.05 0.11 0.19 0.05 0.08 0.03 0.04

97.62 26.86 37.67 15.45 17.64

FI 0.24 0.05 0.10 0.03 0.06 0.20 0.05 0.08 0.03 0.04

93.07 21.13 48.12 17.52 6.30

FR 0.36 0.07 0.14 0.05 0.09 0.18 0.04 0.07 0.03 0.04

88.49 21.23 33.71 15.50 18.05

GR 0.74 0.14 0.31 0.08 0.21 0.36 0.08 0.14 0.05 0.09

161.99 41.53 61.89 23.95 34.62

HU 1.73 0.40 0.65 0.21 0.47 0.59 0.14 0.23 0.08 0.1 265.12 76.30 98.81 39.76 50.25

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(ng/m3)


(ng/g)


(ng/g)


4

IE 0.30 0.06 0.12 0.05 0.07 0.18 0.05 0.07 0.04 0.03

139.14 51.29 42.44 34.49 10.92

IT 1.21 0.28 0.49 0.13 0.31 0.50 0.13 0.20 0.06 0.11

254.09 75.19 96.37 34.69 47.84

LT 1.30 0.30 0.46 0.15 0.39 0.61 0.15 0.22 0.09 0.15

361.20 99.51 129.84 54.99 76.86

LU 0.95 0.24 0.36 0.09 0.26 0.47 0.13 0.18 0.05 0.11

287.92 89.48 105.23 33.62 59.59

LV 1.54 0.44 0.70 0.17 0.23 0.86 0.28 0.37 0.11 0.10

549.89 192.85 229.63 70.40 57.01

MT 0.27 0.02 0.13 0.02 0.10 0.07 0.007 0.03 0.007 0.03

64.01 11.57 28.93 10.17 13.34

NL 1.32 0.36 0.47 0.14 0.35 0.48 0.15 0.17 0.06 0.10

270.40 110.29 80.82 41.02 38.27

PL 2.15 0.53 0.72 0.20 0.70 0.93 0.25 0.32 0.10 0.26

500.31 155.95 165.08 57.32 121.96

PT 0.40 0.08 0.17 0.04 0.11 0.19 0.05 0.08 0.03 0.04

114.09 28.78 46.57 15.51 23.23

RO 1.20 0.29 0.43 0.15 0.33 0.52 0.13 0.19 0.07 0.13

230.46 66.33 79.84 33.81 50.48

SE 0.25 0.05 0.10 0.03 0.07 0.25 0.06 0.10 0.04 0.05

149.80 38.81 57.44 21.32 32.23

SI 1.66 0.39 0.66 0.20 0.41 0.92 0.23 0.36 0.13 0.20

453.25 121.04 171.56 63.41 97.24

SK 1.82 0.42 0.67 0.22 0.51 0.89 0.22 0.33 0.12 0.22

446.64 119.72 159.27 62.60 105.05

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(ng/m3)


(ng/g)


(ng/g)


UK 0.23 0.05 0.09 0.03 0.06 0.13 0.03 0.05 0.02 0.02

75.09 25.50 24.33 17.20 8.06

Total 1.06 0.27 0.38 0.11 0.29 0.48 0.13 0.17 0.06 0.11 273.26 89.80 94.09 37.33 52.05

Table 9-2: Mean concentrations of PAH in environmental compartments 2006 (Source: EMEP MSC-E country reports)

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9.3 Detailed concentrations of single PAH congeners in environmental compartments in Austria, Belgium

and Bulgaria

Austria Belgium Bulgaria

POPs Mean Min Max POPs Mean Min Max POPs Mean Min Max

Air concentrations, ng/m3

B[a]P 0.17 4.06·10-2

0.48 B[a]P 0.34 0.13 0.76 B[a]P 0.26 9.78·10-2

2.7

B[b]F 0.29 0.1 0.78 B[b]F 0.44 0.21 0.92 B[b]F 0.42 0.21 3.49

B[k]F 7.86·10-2

2.48·10-2

0.24 B[k]F 0.13 6.59·10-2

0.26 B[k]F 0.13 5.70·10-2

1.2

IP 0.21 7.08·10-2

0.48 IP 0.33 0.15 0.7 IP 0.31 0.15 2.23

Soil concentrations, ng/g

B[a]P 0.12 3.83·10-2

0.25 B[a]P 0.14 5.42·10-2

0.31 B[a]P 0.13 5.29·10-2

1.24

B[b]F 0.2 7.56·10-2

0.37 B[b]F 0.16 7.63·10-2

0.29 B[b]F 0.2 8.21·10-2

1.33

B[k]F 6.10·10-2

2.11·10-2

0.13 B[k]F 5.59·10-2

2.58·10-2

0.11 B[k]F 7.20·10-2

3.03·10-2

0.56

IP 0.13 4.35·10-2

0.21 IP 0.1 4.54·10-2

0.18 IP 0.13 5.91·10-2

0.74

Vegetation concentrations, ng/g

B[a]P 69.7 20.28 141.3 B[a]P 127.8 8.77 304.39 B[a]P 65.28 2.83 862.07

B[b]F 107.22 35.37 208.25 B[b]F 99.79 3.88 201.2 B[b]F 90.17 2.81 699.99

B[k]F 35.06 10.78 73.98 B[k]F 43.94 3.12 95.45 B[k]F 34.89 1.61 362.83

IP 67.38 13.27 136.17 IP 51.59 1.01 104.83 IP 55.4 0.85 344.93

Table 9-3: Concentrations of PAH congeners in environmental compartments AT, BE, BG 2006 (Source: EMEP MSC-E country reports)

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9.4 Detailed concentrations of single PAH congeners in environmental compartments in Cyprus, Czech

Republic, Germany

Cyprus Czech Republic Germany



B[a]P 1.22 0.11 1.8 B[a]P 0.33 0.2 1.23 B[a]P 0.34 4.65·10-2

0.9

B[b]F 0.63 0.23 0.94 B[b]F 0.46 0.33 1.33 B[b]F 0.49 0.11 1.14

B[k]F 0.17 2.65·10-2

0.25 B[k]F 0.14 9.01·10-2

0.49 B[k]F 0.14 2.62·10-2

0.34

IP 1.13 0.26 1.76 IP 0.37 0.25 1.26 IP 0.36 7.55·10-2

0.8


B[a]P 0.28 4.85·10-2

0.5 B[a]P 0.17 0.11 0.51 B[a]P 0.17 5.06·10-2

0.36

B[b]F 0.11 4.32·10-2

0.18 B[b]F 0.23 0.16 0.65 B[b]F 0.22 7.54·10-2

0.41

B[k]F 3.65·10-2

1.16·10-3

6.04·10-2

B[k]F 7.84·10-2

5.30·10-2

0.22 B[k]F 7.30·10-2

2.46·10-2

0.14

IP 0.23 7.96·10-2

0.32 IP 0.17 0.11 0.53 IP 0.14 4.83·10-2

0.25


B[a]P 391.24 7.93 645.23 B[a]P 109.71 45.92 388.02 B[a]P 111.23 6.34 314.29

B[b]F 107.49 1.78 161.33 B[b]F 128.69 66.94 382.76 B[b]F 121.79 3.24 382.55

B[k]F 43.28 0.93 69.53 B[k]F 47.75 21.69 153.33 B[k]F 45.38 2.65 113.42

IP 139.52 0.53 223.5 IP 87.02 36.96 309.51 IP 59.08 0.56 164.76

Table 9-4: Concentrations of PAH congeners in environmental compartments for CY, CZ, DE 2006 (Source: EMEP MSC-E country reports)

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9.5 Detailed concentrations of single PAH congeners in environmental compartments in Denmark,

Estonia, Spain

Denmark Estonia Spain



B[a]P 0.19 8.54·10-3

0.28 B[a]P 0.24 0.1 0.53 B[a]P 8.63·10-2

5.02·10-3

3.56

B[b]F 0.28 2.35·10-2

0.4 B[b]F 0.38 0.19 0.68 B[b]F 0.18 3.03·10-2

5.22

B[k]F 0.11 6.30·10-3

0.17 B[k]F 0.13 5.04·10-2

0.29 B[k]F 5.13·10-2

5.13·10-3

1.82

IP 0.2 1.67·10-2

0.28 IP 0.19 0.11 0.35 IP 0.11 2.14·10-2

3.01


B[a]P 9.55·10-2

1.27·10-2

0.13 B[a]P 0.16 6.36·10-2

0.29 B[a]P 4.54·10-2

1.19·10-3

0.79

B[b]F 0.12 2.28·10-2

0.16 B[b]F 0.22 9.15·10-2

0.39 B[b]F 7.69·10-2

4.91·10-3

1.11

B[k]F 5.56·10-2

1.02·10-2

7.89·10-2

B[k]F 8.59·10-2

3.83·10-2

0.13 B[k]F 2.79·10-2

1.30·10-3

0.45

IP 7.46·10-2

1.24·10-2

0.12 IP 9.26·10-2

4.41·10-2

0.16 IP 4.08·10-2

3.74·10-3

0.52


B[a]P 59.74 6.34 147.43 B[a]P 116.61 25.42 201.54 B[a]P 26.86 0.17 443.76

B[b]F 53.46 3.39 171.67 B[b]F 134.16 21.54 284.85 B[b]F 37.67 0.43 357.52

B[k]F 35 2.84 82.42 B[k]F 59.81 12.77 93.5 B[k]F 15.45 0.16 213.74

IP 21.94 0.74 102.96 IP 54.45 7.67 142.56 IP 17.64 0.13 142.35

Table 9-5: Concentrations of PAH congeners in environmental compartments for DK, EE, ES 2006 (Source: EMEP EMEP MSC-E country reports)

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9.6 Detailed concentrations of single PAH congeners in environmental compartments in Finland, France,

Greece

Finland France Greece



B[a]P 5.20·10-2

8.80·10-3

0.39 B[a]P 7.26·10-2

1.95·10-2

0.34 B[a]P 0.14 2.84·10-2

0.58

B[b]F 9.52·10-2

2.27·10-2

0.52 B[b]F 0.14 5.65·10-2

0.49 B[b]F 0.31 0.15 0.96

B[k]F 2.65·10-2

6.39·10-3

0.16 B[k]F 5.01·10-2

1.47·10-2

0.15 B[k]F 8.40·10-2

2.70·10-2

0.35

IP 6.49·10-2

1.79·10-2

0.31 IP 9.44·10-2

3.77·10-2

0.35 IP 0.21 0.11 0.59


B[a]P 5.07·10-2

4.17·10-3

0.19 B[a]P 4.07·10-2

9.50·10-3

0.2 B[a]P 7.77·10-2

6.42·10-3

0.26

B[b]F 8.12·10-2

1.05·10-2

0.27 B[b]F 7.26·10-2

1.53·10-2

0.26 B[b]F 0.14 2.66·10-2

0.3

B[k]F 2.78·10-2

3.38·10-3

9.40·10-2

B[k]F 3.00·10-2

5.51·10-3

8.79·10-2

B[k]F 4.79·10-2

7.25·10-3

0.12

IP 4.02·10-2

5.79·10-3

0.17 IP 4.16·10-2

9.59·10-3

0.16 IP 9.24·10-2

1.98·10-2

0.17


B[a]P 21.13 0.89 213.42 B[a]P 21.23 1.67 142.85 B[a]P 41.53 2.1 220.98

B[b]F 48.12 5.87 311.71 B[b]F 33.71 1.5 191.66 B[b]F 61.89 2.51 214.72

B[k]F 17.52 2.74 110.56 B[k]F 15.5 1.2 64.61 B[k]F 23.95 1.17 97.62

IP 6.3 2.07 170.63 IP 18.05 0.22 125.6 IP 34.62 0.37 146.34

Table 9-6: Concentrations of PAH congeners in environmental compartments for FI, FR, GR 2006 (Source: EMEP MSC-E country reports)

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9.7 Detailed concentrations of single PAH congeners in environmental compartments in Hungary,

Ireland, Italy

Hungary Ireland Italy



B[a]P 0.4 0.18 1.28 B[a]P 6.08·10-2

1.87·10-3

0.35 B[a]P 0.28 2.37·10-2

3.08

B[b]F 0.65 0.33 1.87 B[b]F 0.12 4.05·10-2

0.56 B[b]F 0.49 8.98·10-2

4.79

B[k]F 0.21 8,88·10-2

0.65 B[k]F 4.924·10-2

1.28·10-2

0.25 B[k]F 0.13 2.06·10-2

1.38

IP 0.47 0.24 1.25 IP 7.03·10-2

2.65·10-2

0.28 IP 0.31 6.27·10-2

2.89


B[a]P 0.14 9.14·10-2

0.5 B[a]P 5.03·10-2

8.77·10-3

0.24 B[a]P 0.13 7.39·10-3

1.75

B[b]F 0.23 0.16 0.64 B[b]F 6.65·10-2

1.92·10-2

0.23 B[b]F 0.2 2.7·10-2

1.59

B[k]F 8.00·10-2

5.17·10-2

0.26 B[k]F 3.66·10-2

7.23·10-3

0.16 B[k]F 5.50·10-2

6.74·10-3

0.71

IP 0.14 0.1 0.35 IP 2.68·10-2

9.88·10-3

8.28·10-2

IP 0.11 1.57·10-2

0.73


B[a]P 76.3 34.67 390.85 B[a]P 51.29 4.81 312.42 B[a]P 75.19 2.18 1.64·103

B[b]F 98.81 58.58 303.54 B[b]F 42.44 3.83 193.7 B[b]F 96.37 2.11 1.27·103

B[k]F 39.76 19.33 176.74 B[k]F 34.49 3.54 195.81 B[k]F 34.69 1.04 622.69

IP 50.25 28.06 116.21 IP 10.92 0.46 42.16 IP 47.84 0.45 519.81

Table 9-7: Concentrations of PAH congeners in environmental compartments for HU, IE, IT 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.8 Detailed concentrations of single PAH congeners in environmental compartments in Lithuania,

Luxembourg, Latvia

Lithuania Luxembourg Latvia



B[a]P 0.3 0.17 0.57 B[a]P 0.24 0.16 0.29 B[a]P 0.44 0.17 2.01

B[b]F 0.46 0.29 0.9 B[b]F 0.36 0.26 0.44 B[b]F 0.7 0.29 2.93

B[k]F 0.15 8.11·10-2

0.22 B[k]F 9.25·10-2

7.12·10-2

0.11 B[k]F 0.17 8.11·10-2

0.65

IP 0.39 0.23 0.53 IP 0.26 0.19 0.31 IP 0.23 0.16 0.44


B[a]P 0.15 9.57·10-2

0.39 B[a]P 0.13 0.1 0.15 B[a]P 0.28 6.34·10-2

0.99

B[b]F 0.22 0.15 0.49 B[b]F 0.18 0.15 0.19 B[b]F 0.37 9.76·10-2

1.14

B[k]F 8.52·10-2

4.72·10-2

0.14 B[k]F 5.36·10-2

4.80·10-2

5.57·10-2

B[k]F 0.11 2.84·10-2

0.32

IP 0.15 9.01·10-2

0.23 IP 0.11 0.11 0.11 IP 0.1 4.45·10-2

0.17


B[a]P 99.51 52.65 321.35 B[a]P 89.48 62.96 106.08 B[a]P 192.85 26.82 701.12

B[b]F 129.84 70.29 254.37 B[b]F 105.23 90.83 110.27 B[b]F 229.63 26.03 751.46

B[k]F 54.99 21.98 108.54 B[k]F 33.62 28.5 34.98 B[k]F 70.4 10.94 221

IP 76.86 38.46 200.74 IP 59.59 57.2 68.58 IP 57.01 8.68 108.96

Table 9-8: Concentrations of PAH congeners in environmental compartments for LT, LU, LV 2005 (Source: EMEP MSC-E country reports)

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BiPRO

9.9 Detailed concentrations of single PAH congeners in environmental compartments in Malta, the

Netherlands, Poland

Malta Netherlands Poland


Air concentrations ng/m3

B[a]P 2.22·10-2

2.16·10-2

2.52·10-2

B[a]P 0.36 0.1 3.9 B[a]P 0.53 0.17 1.23

B[b]F 0.13 0.13 0.13 B[b]F 0.47 0.16 1.14 B[b]F 0.72 0.27 1.43

B[k]F 2.11·10-2

2.08·10-2

2.25·10-2

B[k]F 0.14 4.79·10-2

0.34 B[k]F 0.2 7.49·10-2

0.49

IP 9.53·10-2

9.48·10-2

9.78·10-2

IP 0.35 0.12 0.8 IP 0.7 0.23 1.43

Soil concentrations ng/g

B[a]P 7.09·10-3

6.91·10-3

8.08·10-3

B[a]P 0.15 3.95·10-2

0.31 B[a]P 0.25 6.17·10-2

0.56

B[b]F 2.55·10-2

2.91·10-2

2.75·10-2

B[b]F 0.17 5.02·10-2

0.29 B[b]F 0.32 9.15·10-2

0.65

B[k]F 7.03·10-3

6.92·10-3

7.64·10-3

B[k]F 6.33·10-2

2.08·10-2

0.11 B[k]F 9.83·10-2

2.66·10-2

0.22

IP 3.00·10-2

2.93·10-2

3.22·10-2

IP 0.1 4.44·10-2

0.18 IP 0.26 7.46·10-2

0.55

Vegetation concentrations ng/g

B[a]P 11.57 11.24 13.46 B[a]P 110.29 6.39 312.62 B[a]P 155.95 19.1 365.19

B[b]F 28.93 28.17 33.18 B[b]F 80.82 3.24 201.2 B[b]F 165.08 17.21 382.46

B[k]F 10.17 9.96 11.38 B[k]F 41.02 2.65 104.28 B[k]F 57.32 7.76 138.48

IP 13.34 12.83 16.24 IP 38.27 0.56 104.13 IP 121.96 11.15 309.51

Table 9-9: Concentrations of PAH congeners in environmental compartments for MT, NL, PL 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.10 Detailed concentrations of single PAH congeners in environmental compartments in Portugal,

Romania, Sweden

Portugal Romania Sweden


Air concentrations ng/m3

B[a]P 7.69·10-2

2.33·10-2

0.47 B[a]P 0.29 0.13 1.75 B[a]P 5.27·10-2

8.80·10-3

0.77

B[b]F 0.17 9.13·10-2

0.69 B[b]F 0.43 0.24 1 B[b]F 9.88·10-2

2.48·10-2

1.08

B[k]F 4.27·10-2

1.79·10-2

0.21 B[k]F 0.15 6.14·10-2

0.67 B[k]F 2.80·10-2

6.62·10-2

0.32

IP 0.11 5.83·10-2

0.41 IP 0.33 0.19 1.03 IP 6.91·10-2

1.90·10-2

0.68

Concentrations in soil ng/g

B[a]P 4.61·10-2

8.04·10-3

0.2 B[a]P 0.13 4.02·10-2

0.63 B[a]P 6.48·10-2

8.97·10-3

1.08

B[b]F 7.90·10-2

1.94·10-2

0.24 B[b]F 0.19 5.74·10-2

0.37 B[b]F 9.97·10-2

2.27·10-2

1.00

B[k]F 2.64·10-2

6.33·10-3

8.85·10-2

B[k]F 7.21·10-2

2.23·10-2

0.23 B[k]F 3.51·10-2

7.37·10-3

0.43

IP 3.99·10-2

1.27·10-2

0.12 IP 0.13 4.25·10-2

0.3 IP 5.15·10-2

1.05·10-2

0.40

Concentrations in vegetation ng/g

B[a]P 28.78 1.79 231.89 B[a]P 66.33 3.11 583.5 B[a]P 38.81 3.96 601.44

B[b]F 46.57 2.35 164.18 B[b]F 79.84 2.84 154.8 B[b]F 57.44 4.41 583.35

B[k]F 15.51 1.05 89.14 B[k]F 33.81 1.63 189.21 B[k]F 21.32 2.74 247.24

IP 23.23 0.71 76.4 IP 50.48 0.78 138.8 IP 32.23 0.96 292.83

Table 9-10: Concentrations of PAH congeners in environmental compartments for PT, RO, SE 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.11 Detailed concentrations of single PAH congeners in environmental compartments in Slovenia,

Slovakia, United Kingdom

Slovenia Slovakia United Kingdom



B[a]P 0.39 0.18 0.76 B[a]P 0.42 0.31 0.82 B[a]P 5.22·10-2

1.38·10-2

0.21

B[b]F 0.66 0.32 1.2 B[b]F 0.67 0.5 1.07 B[b]F 8.77·10-2

3.24·10-2

0.26

B[k]F 0.2 8.63·10-2

0.36 B[k]F 0.22 0.13 0.34 B[k]F 3.38·10-2

9.36·10-3

0.14

IP 0.41 0.22 0.72 IP 0.51 0.37 1.03 IP 5.65·10-2

2.27·10-2

0.14


B[a]P 0.23 0.11 0.35 B[a]P 0.22 0.1 0.51 B[a]P 3.30·10-2

9.93·10-3

0.11

B[b]F 0.36 0.17 0.51 B[b]F 0.33 0.17 0.65 B[b]F 4.84·10-2

1.98·10-2

0.11

B[k]F 0.13 5.36·10-2

0.19 B[k]F 0.12 5.38·10-2

0.22 B[k]F 2.35·10-2

7.38·10-3

7.38·10-2

IP 0.20 8.91·10-2

0.28 IP 0.22 0.11 0.53 IP 2.41·10-2

1.08·10-2

4.48·10-2


B[a]P 121.04 18.96 215.39 B[a]P 119.72 53.42 341.08 B[a]P 25.5 2.48 103.46

B[b]F 171.56 11.92 230.81 B[b]F 159.27 75.63 382.76 B[b]F 24.33 1.73 57.69

B[k]F 63.41 7.73 95.17 B[k]F 62.60 35.72 138.48 B[k]F 17.2 1.47 61.11

IP 97.24 3.12 126.13 IP 105.05 37.74 309.51 IP 8.06 0.27 23.3

Table 9-11: Concentrations of PAH congeners in environmental compartments for SI, SK, UK 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.12 Long-range transboundary transport of PCDD/PCDF and B[a]P in Austria

Table 9-12: Long range transboundary transport of PDCC/PCDF in Austria 2006 (Source: EMEP MSC-E country reports)

Table 9-13: Long range transboundary transport of B[a]P in Austria 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.13 Long-range transboundary transport of PCDD/PCDF and B[a]P in Belgium

Table 9-14: Long range transboundary transport of PDCC/PCDF in Belgium 2006 (Source: EMEP MSC-E country reports)

Table 9-15: Long range transboundary transport of B[a]P in Belgium 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.14 Long-range transboundary transport of PCDD/PCDF and B[a]P in Bulgaria

Table 9-16: Long range transboundary transport of PDCC/PCDF in Bulgaria 2006 (Source: EMEP MSC-E country reports)

Table 9-17: Long range transboundary transport of B[a]P in Bulgaria 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.15 Long-range transboundary transport of PCDD/PCDF and B[a]P in Cyprus

Table 9-18: Long range transboundary transport of PDCC/PCDF in Cyprus 2006 (Source: EMEP MSC-E country reports)

Table 9-19: Long range transboundary transport of B[a]P in Cyprus 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.16 Long-range transboundary transport of PCDD/PCDF and B[a]P in Czech Republic

Table 9-20: Long range transboundary transport of PDCC/PCDF in Czech Republic 2006 (Source: EMEP MSC-E country reports)

Table 9-21: Long range transboundary transport of B[a]P in Czech Republic 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.17 Denmark

9.18 Estonia

9.19 Finland

9.20 France

070307/2007/465073/MAR/D1 115


BiPRO

9.21 Long-range transboundary transport of PCDD/PCDF and B[a]P in Germany

Table 9-22: Long range transboundary transport of PDCC/PCDF in Germany 2006 (Source: EMEP MSC-E country reports)

Table 9-23: Long range transboundary transport of B[a]P in Germany 2006 (Source: EMEP MSC-E country reports)

070307/2007/465073/MAR/D1 116


BiPRO

9.22 Long-range transboundary transport of PCDD/PCDF and B[a]P in Denmark

Table 9-24: Long range transboundary transport of PDCC/PCDF in Denmark 2006 (Source: EMEP MSC-E country reports)

Table 9-25: Long range transboundary transport of B[a]P in Denmark 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.23 Long-range transboundary transport of PCDD/PCDF and B[a]P in Estonia

Table 9-26: Long range transboundary transport of PDCC/PCDF in Estonia 2006 (Source: EMEP MSC-E country reports)

Table 9-27: Long range transboundary transport of B[a]P in Estonia 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.24 Long-range transboundary transport of PCDD/PCDF and B[a]P in Spain

Table 9-28: Long range transboundary transport of PDCC/PCDF in Spain 2006 (Source: EMEP MSC-E country reports)

Table 9-29: Long range transboundary transport of B[a]P in Spain 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.25 Long-range transboundary transport of PCDD/PCDF and B[a]P in Finland

Table 9-30: Long range transboundary transport of PDCC/PCDF in Finland 2006 (Source: EMEP MSC-E country reports)

Table 9-31: Long range transboundary transport of B[a]P in Finland 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.26 Long-range transboundary transport of PCDD/PCDF and B[a]P in France

Table 9-32: Long range transboundary transport of PDCC/PCDF in France 2006 (Source: EMEP MSC-E country reports)

Table 9-33: Long range transboundary transport of B[a]P in France 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.27 Long-range transboundary transport of PCDD/PCDF and B[a]P in Greece

Table 9-34: Long range transboundary transport of PDCC/PCDF in Greece 2006 (Source: EMEP MSC-E country reports)

Table 9-35: Long range transboundary transport of B[a]P in Greece 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.28 Long-range transboundary transport of PCDD/PCDF and B[a]P in Hungary

Table 9-36: Long range transboundary transport of PDCC/PCDF in Hungary 2006 (Source: EMEP MSC-E country reports)

Table 9-37: Long range transboundary transport of B[a]P in Hungary 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.29 Long-range transboundary transport of PCDD/PCDF and B[a]P in Ireland

Table 9-38: Long range transboundary transport of PDCC/PCDF in Ireland 2006 (Source: EMEP MSC-E country reports)

Table 9-39: Long range transboundary transport of B[a]P in Ireland 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.30 Long-range transboundary transport of PCDD/PCDF and B[a]P in Italy

Table 9-40: Long range transboundary transport of PDCC/PCDF in Italy 2006 (Source: EMEP MSC-E country reports)

Table 9-41: Long range transboundary transport of B[a]P in Italy 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.31 Long-range transboundary transport of PCDD/PCDF and B[a]P in Lithuania

Table 9-42: Long range transboundary transport of PDCC/PCDF in Lithuania 2006 (Source: EMEP MSC-E country reports)

Table 9-43: Long range transboundary transport of B[a]P in Lithuania 2005 (Source: EMEP MSC-E country reports)

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BiPRO

9.32 Long-range transboundary transport of PCDD/PCDF and B[a]P in Luxembourg

Table 9-44: Long range transboundary transport of PDCC/PCDF in Luxembourg 2006 (Source: EMEP MSC-E country reports)

Table 9-45: Long range transboundary transport of B[a]P in Luxembourg 2005 (Source: EMEP MSC-E country reports)

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BiPRO

9.33 Long-range transboundary transport of PCDD/PCDF and B[a]P in Latvia

Table 9-46: Long range transboundary transport of PDCC/PCDF in Latvia 2006 (Source: EMEP MSC-E country reports)

Table 9-47: Long range transboundary transport of B[a]P in Latvia 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.34 Long-range transboundary transport of PCDD/PCDF and B[a]P in Malta

Table 9-48: Long range transboundary transport of PDCC/PCDF in Malta 2006 (Source: EMEP MSC-E country reports)

Table 9-49: Long range transboundary transport of B[a]P in Malta 2006 (Source: EMEP MSC-E country reports

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BiPRO

9.35 Long-range transboundary transport of PCDD/PCDF and B[a]P in the Netherlands

Table 9-50: Long range transboundary transport of PDCC/PCDF in the Netherlands 2006 (Source: EMEP MSC-E country reports)

Table 9-51: Long range transboundary transport of B[a]P in the Netherlands 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.36 Long-range transboundary transport of PCDD/PCDF and B B[a]P in Poland

Table 9-52: Long range transboundary transport of PDCC/PCDF in Poland 2006 (Source: EMEP MSC-E country reports)

Table 9-53: Long range transboundary transport of B[a]P in Poland 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.37 Long-range transboundary transport of PCDD/PCDF and B[a]P in Portugal

Table 9-54: Long range transboundary transport of PDCC/PCDF in Portugal 2006 (Source: EMEP MSC-E country reports)

Table 9-55: Long range transboundary transport of B[a]P in Portugal 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.38 Long-range transboundary transport of PCDD/PCDF and B[a]P in Romania

Table 9-56: Long range transboundary transport of PDCC/PCDF in Romania 2006 (Source: EMEP MSC-E country reports)

Table 9-57: Long range transboundary transport of B[a]P in Romania 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.39 Long-range transboundary transport of PCDD/PCDF and B[a]P in Sweden

Table 9-58: Long range transboundary transport of PDCC/PCDF in Sweden 2006 (Source: EMEP MSC-E country reports)

Table 9-59: Long range transboundary transport of B[a]P in Sweden 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.40 Long-range transboundary transport of PCDD/PCDF and B[a]P in Slovenia

Table 9-60: Long range transboundary transport of PDCC/PCDF in Slovenia 2006 (Source: EMEP MSC-E country reports)

Table 9-61: Long range transboundary transport of B[a]P in Slovenia 2006 (Source: EMEP MSC-E country reports)

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BiPRO

9.41 Long-range transboundary transport of PCDD/PCDF and B[a]P in Slovakia

Table 9-62: Long range transboundary transport of PDCC/PCDF in Slovakia 2006 (Source: EMEP MSC-E country reports)

Table 9-63: Long range transboundary transport of B[a]P in Slovakia 2006 (Source: EMEP MSC-E country reports)

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9.42 Long-range transboundary transport of PCDD/PCDF and B[a]P in the United Kingdom

Table 9-64: Long range transboundary transport of PDCC/PCDF in the United Kingdom 2006 (Source: EMEP MSC-E country reports)

Table 9-65: Long range transboundary transport of B[a]P in the United Kingdom 2006 (Source: EMEP MSC-E country reports)

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Updated Synthesis Report 2009 Support related to the international and Community work on Persistent Organic Pollutants BiPRO

9.39 Balance of long-range transboundary transport of PCDD/PCDF and B[a]P in EU Member States (2006)

MS AT BE BG CY CZ DE DK EE ES FI FR GR HU

∑ deposition from MS

PCDD/F [g/y] 38.4 46.6 202.7 2.4 158.2 74.7 17.3 2.2 113.6 11.6 104.1 71.1 83.6

∑ deposition to MS

PCDD/F [g/y] 41.0 191.6 4.2 102.4 111.8 11.3 6.2 101.9 24.0 130.1 114.8 96.2

MS IE IT LT LU LV MT NL PL PT RO SE SI SK UK Total


PCDD/F [g/y] 19.5 207.5 14.3 1.4 11.8 0.9 26.8 408.2 6.63 236.3 30.7 7.3 61.0 145.6 2104.5


PCDD/F [g/y] 17.8 187.3 19.9 1.3 15.9 0.1 22.9 343,5 9.0 223.8 50.7 15.7 123.3 1966.7

Table 9-66: Deposition balance for PCDD/PCDF to and from EU Member States (Source: EMEP MSC-E)

MS AT BE BG CY CZ DE DK EE ES FI FR GR HU


PAH (BaP) [kg/y] 1331 2708 2589 1538 3238 20375 1729 4183 6644 10848 3280 1656 3515


PAH (BaP) [kg/y] 2015 1592 3459 1319 3270 16621 1065 1915 6073 3577 6835 2154 3349

MS IE IT LT LU LV MT NL PL PT RO SE SI SK UK Total


PAH (BaP) [kg/y] 1361 11971 2402 7267

2125 27298 1068 8013 3298 1424 2709 1583 134154


PAH (BaP) [kg/y] 1061 10398 2556 84 4691 1 1631 20067 1100 7760 5161 1127 2563 1983 113427

Table 9-67: Deposition balance to PAH to and from EU Member States (Source: EMEP MSC-E)

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Environmental level of POPs according to other data sources

9.40 Environmental level of POPs according to Article 12 reports

MS from to substance objective compartment mean min max unit no of

samples other

BG 1997 2002 PCB 28 environmental monitoring soil 0,003 4,37 µg/kg 231 agricultural lands

1997 2002 PCB 52 environmental monitoring soil 0,007 5,76 µg/kg 231 agricultural lands








1997 2002 PCBs total environmental monitoring soil 0,009 12,47 µg/kg 231 agricultural lands

CY 2003 2005 PCB 28 environmental monitoring water 0,019 µg/L 124 Dams

2003 2005 PCB 47 environmental monitoring water 0,013 µg/L 124 Dams



2003 2005 Heptachlor environmental monitoring water 0,021 µg/L 124 Dams

2003 2005 HCB environmental monitoring water 0,001 µg/L 124 Dams

2003 2005 ppDDT environmental monitoring water 0,002 µg/L 124 Dams

2003 2005 PCB1 environmental monitoring water 0,249 µg/L 124 Polemida Dam



2003 2005 PCB 52 environmental monitoring water 0,019 µg/L 124 Rivers


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BiPRO


samples other


2003 2005 Heptachlor environmental monitoring water 0,021 µg/L 124 Rivers

2003 2005 HCB environmental monitoring water 0,007 µg/L 124 Rivers

2003 2005 Aldrin environmental monitoring water 0,002 µg/L 124 Rivers

2003 2005 PCB1 environmental monitoring water 0,038 µg/L 124 River Garilis

2003 2005 PCB52 environmental monitoring water 0,004 µg/L 124 River Garilis

DK 1998 2003 1234678HpCDD environmental monitoring 1) WWTP sludge 6,9* 9,2 µg/kg d.m. 59 98

1998 2003 1234678-HpCDF environmental monitoring 1) WWTP sludge 5,5* 7,5 µg/kg d.m. 59 97

1998 2003 1234789-HpCDF environmental monitoring 1) WWTP sludge 0,5 1,4 µg/kg d.m. 47 74

1998 2003 123478-HxCDD environmental monitoring 1) WWTP sludge 0,2 1,1 µg/kg d.m. 54 78

1998 2003 123478-HxCDF environmental monitoring 1) WWTP sludge 0,5 3,2 µg/kg d.m. 56 88





1998 2003 12378-PeCDD environmental monitoring 1) WWTP sludge 0,2 0,7 µg/kg d.m. 54 74

1998 2003 12378-PeCDF environmental monitoring 1) WWTP sludge 0,2 1,9 µg/kg d.m. 53 77


1998 2003 23478-PeCDF environmental monitoring 1) WWTP sludge 0,4 1,6 µg/kg d.m. 57 88

1998 2003 2378-TCDD environmental monitoring 1) WWTP sludge 0,01 0,01 µg/kg d.m. 50 48

1998 2003 2378-TCDF environmental monitoring 1) WWTP sludge 0,3 0,8 µg/kg d.m. 56 96

1998 2003 OCDD environmental monitoring 1) WWTP sludge 56* 48 µg/kg d.m. 60 98

1998 2003 OCDF environmental monitoring 1) WWTP sludge 11* 0,9 µg/kg d.m. 58 98

1998 2003 PCB environmental monitoring 3) WWTP sludge 25 µg/kg d.m. 4 25

1998 2003 PCB 28 environmental monitoring 3) WWTP sludge - µg/kg d.m. 58 25

1998 2003 PCB 31 environmental monitoring 3) WWTP sludge 3,6 18 µg/kg d.m. 65 25

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samples other

1998 2003 PCB 52 environmental monitoring 3) WWTP sludge 4 14 µg/kg d.m. 65 25


1998 2003 PCB 105 environmental monitoring 3) WWTP sludge 1,7 8,1 µg/kg d.m. 65 25






PL 2003 2003 PCB environmental monitoring river waters 0,02133 nd/0,0001 0,1 µg/l 259

2005 2005 PCB sum 7 environmental monitoring river sediments 1,07 <0,5 29,8 µg/l 80

2005 2005 PCB 28 environmental monitoring lake sediments 0,2 µg/l 10 lake: Białe Włodawskie

2005 2005 PCB 52 environmental monitoring lake sediments <0,1 µg/l 10






2005 2005 PCB (all 7) environmental monitoring lake sediments <0,1 µg/l 10 lake: Tarnowskie Duże, Długie Wigierskie,

Jasień Południowy, Jasień Ołnocny,

Jegocin, Łękuk, Wukśniki, Krępsko Długie,

Śremskie

SE Aldrin pesticide monitoring 1,2 µg/l 1830 in three samples detected

Dieldrin pesticide monitoring 1,6 µg/l 1832 in two samples detected

2004 2004 DDT environmental monitoring 6) Hering muscle 0,4 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 DDT environmental monitoring 6) Cod liver 0,2 µg/g lw approx.

40/year

lw = liquid weight

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samples other

2004 2004 DDT environmental monitoring 6) Common

mussels

0,15 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 DDT environmental monitoring 6) Guillemot eggs 50 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 DDT environmental monitoring 6) Human breast

milk

100 ng/g lw

(DDE)

approx. 20

- 40

lw = liquid weight

2004 2004 PCB environmental monitoring 6) Hering muscle 0,2 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 PCB environmental monitoring 6) Cod liver 1 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 PCB environmental monitoring 6) Common

mussels


40/year

lw = liquid weight

2004 2004 PCB environmental monitoring 6) Guillemot eggs 50 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 PCB environmental monitoring 6) Human breast

milk

40 ng/g lw

(CB153)

approx. 20

- 40

lw = liquid weight

2004 2004 PCDD/F environmental monitoring 6) Hering muscle 50 pg/g approx.

40/year

lw = liquid weight

2004 2004 PCDD/F environmental monitoring 6) Guillemot eggs 1 ng/g approx.

40/year

lw = liquid weight

2004 2004 PCDD/F environmental monitoring 6) Human breast

milk

~200 pg/g approx. 20

- 40

lw = liquid weight

2004 2004 HCB environmental monitoring 6) Hering muscle 0,05 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 HCB environmental monitoring 6) Cod liver 0,02 µg/g lw approx.

40/year

lw = liquid weight

2004 2004 HCB environmental monitoring 6) Common

mussels


40/year

lw = liquid weight

2004 2004 HCB environmental monitoring 6) Guillemot eggs 1,5 µg/g lw approx.

40/year

lw = liquid weight

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samples other

2004 2004 HCB environmental monitoring 6) Human breast

milk

30 ng/g lw approx. 20

- 40

lw = liquid weight

Table 9-68: Selected information on monitoring activities on the basis of Article 12 reporting

Remarks related to Table 9-68:

1) The value indicated in the row ―mean‖ is the 95% fractile; the figure in the row ―other‖ represents the share of samples below detection limit in %

The Nova monitoring programme was established in 1987 in order to follow development in the aquatic environment and record the effects of the reduction

in discharges. In 1998 hazardous substances and heavy metals were added to the programme. Monitoring was also designed to comply with international

obligation and to fulfil national needs for assessment of the effectiveness of national initiatives.

Type of sampling point: Waste water treatment plants

Geografical location: 38 waste water treatment plants, mostly relatively equally spread between Sealand and Jutland, and a few on Funen.

Analytical method applied and compartments in which the substance was sampled: The values presented constitute a mean of the concentrations found. As

a rule two measurement rounds have been undertaken on each of the involved waste water treatment plants. The first round was undertaken in the period

1998-2000 and the second in the period 2001-2003. One round of measurement rounds involves analysis on 4 week samples made up from 5 samples

taken on different days in the week. The content of substances is determined by analysis of the week samples, and are therefore representative of the

average discharge over time without information on the maximum concentrations.

Mean values have been determined for all plants. If a substance has been measured at 5 or fewer plants, it has not been included in the presentation of

data. If more than 10% of the analytical results for a substance have been under the detection limit, no mean has been calculated. The total national mean

of concentrations in wastewater has been calculated as a mean for the individual plant and subsequently as a national mean. It has not been weighted

according to plant size, since this have shown not to influence the national level. 95% fractiles for the concentration in discharges and in sludge are

calculated on the basis of the spread in means for the individual plants.

In the calculation the results under the detection limit has been included according to two criteria:

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1) If more than 50% of the analytical results are over the detection limit, results under the detection limit are set at ½ the detection limit

2) If less than 50% of the analytical results are over the detection limit, results under the detection limit are set to 0.

In cases when the calculated mean is a factor 10 or more of the median, the mean is marked in the tables in the annex (bilag) with a star.

The values found: The values are presented in the annex to Miljøfremmede stoffer og tungmetaller i vandmiljøet‖- faglig rapport fra DMU, nr. 585, table 9.2.

The table specifies middel=mean; 95% fraktil = 95% fractile; antal analyser = number of analytical findings; andel analyser > DG,% = part of the analytical

findings that are under the detection limit, in %.

2) Type of sampling point: Industry plants waste water, depositionplants and protective measures connected to soil contamination.

Geografical location: 14 plants were involved. Locations not specified. Plants selected to give a representative picture.

Analytical method applied and compartments in which the substance was sampled: Two measurement rounds were undertaken. Each round of

measurement rounds involved analysis on 4 week samples made up from 5 samples taken on different days in the week. Additionally other data from the

inspections of the regional authorities regarding discharges and the plants own control measurements were involved. The calculations of content of the

substances were undertaken in the same way as for waste water treatment plants, as an average for 2001-2003. There is a high uncertainly connected with

the calculation, since the separate plants do not participate in the monitoring every year.

The values found: The values are presented in the annex to Miljøfremmede stoffer og tungmetaller i vandmiljøet‖- faglig rapport fra DMU, nr. 585, table

10.1. The table specifies middel=mean; 95% fraktil = 95% fractile; antal analyser = number of analytical findings; andel analyser > DG,% = part of the

analytical findings that are under the detection limit, in %.

3) The value indicated in the row ―mean‖ is the 95% fractile; the figure in the row ―other‖ represents the share of samples below detection limit in %

Type of sampling point, geografical location, analytical method applied and compartments in which the substance was sampled: Same as for dioxins in

sludge.

The values found: The values are presented in the annex to Miljøfremmede stoffer og tungmetaller i vandmiljøet‖- faglig rapport fra DMU, nr. 585, table 9.2.

The table specifies middel=mean; 95% fraktil = 95% fractile; antal analyser = number of analytical findings; andel analyser > DG,% = part of the analytical

findings that are under the detection limit, in %.

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4) Analytical method as under dioxin - sludge from waste water treatment plants. Practically no PCB detected. Results listed in in the annex to Miljøfremmede

stoffer og tungmetaller i vandmiljøet‖- faglig rapport fra DMU, nr. 585, table 9.1.

5) Summary of measurement included in the existing Swedish environmental monitoring programme

6) Measured levels of certain POPs in some of the matrices used in the national monitoring programme (2004)

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9.40.1 Lithuania, details on national feedstuffs monitoring

Results of chemical analyses on PCDD/PCDF and PCB in the Baltic fish in 2004 in accordance with the Monitoring Programme for dioxins and

dioxin-like polychlorinated biphenyl’s in the fish from the Baltic Sea for 2004

No. Code Region Species

Matrix PCDDs/PCDFs

WHO-TEQ

amount in pg/g (ppt), original wet weight based

PCDDs/PCDFs and PCBs WHO-TEQ

amount in pg/g (ppt), original wet weight based

Classification of the date

1. 9309 Baltic Sea herring fish 1,9 5,1 below limit value

2. 9310-1 Baltic Sea herring fish 1 3,3 below limit value

3. 9310-2 Baltic Sea herring fish 1,1 3,5 below limit value



No. Title of product Fishing square Sample

code

Age of fish

(year)

Fish size, Sample

weight Fats,%

WHO

PCDD/F

-TEQ, amount in pg/g

original wet weight based

WHO PSO -PCDD/F-

PCB-TEQ, amount in

pg/g original wet

weight based

1 Baltic herring square-441 3443-1 1-9 16,0 cm

27,2 g

2,6 1,6 4,8

2 Baltic sprat square-441 3443-2 1-9 16,0 cm

27,2 g

6,1 1,5 4,1

3 Baltic herring square-littoral,

17 zone

3444 2-8 19,6 cm

45,8 g

2,5 1,6 4,6

4 Cod liver,

(seal 247808)

square

III D 26

10100 3-4 30-40 cm

62 10 66

5 Cod liver square 10101 5-6 50-60 cm 70 16 90

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code

Age of fish

(year)

Fish size, Sample

weight Fats,%

WHO

PCDD/F



WHO PSO -PCDD/F-

PCB-TEQ, amount in

pg/g original wet

weight based

(seal 247807) III D 26

6 Cod liver,

(seal 247806)

square 473 10102 4-5 40-50 cm 70 15 92

7 Baltic herring

(seal 247805)

littoral 441

square

10103 iki 1 up to 15,5 cm 3,2 (mean

of n= 2)

0,44 1,3

8 Baltic herring

(seal 247804)

littoral 441

square

10104 1-2 15,5-18,4 cm 8,3 1,9 4,6

9 Baltic herring

(seal 247812)

littoral 441

square

10105 2-3 18,4-19,3 cm 9,7 3,0 6,9

10 Baltic herring

(seal 251237)

littoral 441

square

10106 3-5 19,3-20,5 cm 6,5 2,3 5,9

11 Baltic herring

(seal 251236)

Nautical square

536

10107 7 over 21 cm 8,4 3,8**

(mean of n= 2)

9,2(mean of n= 2)

12 Baltic herring

(seal 251235)

Nautical square

536

10108 4-5 20-20,5 cm 8,5 3,3**

(average 2)

8,8

(mean of n= 2)

13 Baltic herring

(seal 251394)

Nautical square

535

10109 3-4 19-20,2 cm 9,2 3,2**

(mean of n= 2)

11

(mean of n= 2))

14 Baltic herring

(seal 251393)

Nautical square

535

10110 5-6 20-21,5 cm 9,2 3,7**

(mean of n= 2)

9,8

(mean of n= 2)

15 Baltic salmon

(seal 251392)

littoral –

Curonian Bay,

free zone

10111 3 50-55 cm 5,3 0,94 3,4

16 Baltic salmon

seal 251391)

littoral –

Curonian Bay,

10112 2-3 47-52 cm 7,8 1,4

4,7

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code

Age of fish

(year)

Fish size, Sample

weight Fats,%

WHO

PCDD/F



WHO PSO -PCDD/F-

PCB-TEQ, amount in

pg/g original wet

weight based

free zone

17 Baltic salmon

(seal 251449)

littoral –

Curonian Bay,

free zone

10113 4 60-65 cm 1,2

(mean of n=

2)

2,2 9,4

18 Baltic sprat

(seal 251344)

FAO 27 III d 10114 1 about 7,6 cm 11 0,66 2,3

19 Baltic sprat

(seal 251343)

FAO 27 III d 10115 1 about 8,2 cm 13 0,65 2,4

20 Baltic sprat

(seal 251342)

FAO 27 III d 10116 2 about 10,4 cm 18 1,6 5,1

21 Baltic sprat

(seal 251341)

FAO 27 III d 10117 3 about 11,5 cm 20 1,8 5,6

22 Baltic sprat

(seal 251340)

FAO 27 III d 10118 4 about 12 cm 19 1,9 5,8

23 Baltic sprat

(seal 251339)

FAO 27 III d 10119 5 about 12,3 cm 16 2,2 6,9

24 Baltic sprat

(seal 251338)

nautical 535 10120 1 about 8,2 cm 14 0,68 2,3

25 Baltic sprat

(seal 251337)

nautical square

535

10121 2 about 10,4 cm 18 1,5 4,9

26 Baltic sprat

(seal 247813)

nautical square

535

10122 3 about 11,5 cm 18 1,9 5,9

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No Species of fish Fishing area

(statistical square

No of

sample

Age of fish

(years)

Size

(cm)

Fat

content,%

Sum of dioxins

(WHO-PCDD/F

-TEQ), pg/g established

for fresh product weight

Sum of dioxins

and dioxins-like

PCBs (WHO -

PCDD/F-PCB-

TEQ), pg/g

established for

fresh product

weight

1. Baltic sprat (hot

smoking)

Baltic Sea, FAO 27 III

d., ICES 26 (40H0)

11007 - - 14 3,0 7,4

2. Baltic sprat (hot

smoking)

Baltic Sea ,FAO 27 III

d., ICES 26 (40H0)

11008 - - 15 3,4 8,6**

3. Baltic herring in oil

(hot smoking)

Baltic Sea, FAO 27 III

d., ICES 26 (40H0)

11009 - - 6,1 1,8 5,1

4. Baltic sprat Baltic Sea, FAO 27 III

d., ICES 26 (39H0)

11010 4 11,5-12 17 2,1 6,3

5. Baltic sprat Baltic Sea, FAO 27 III d,

ICES 26 (39H0)

11011 3 10,4-11,5 18 2,0 5,8


d., ICES 26 (39H0)

11012 1 <7,6 12 0,41 1,6


d., ICES 26 (39H0)

11013 5 12,3 and > 5,4 1,4 3,3


d., ICES 26 (39H0)

11014 2-3 10,4-11,5 18 1,3 4,1


d., ICES 26 (39H0)

11015 2 8,2-10,4 19 1,6 5,2


d., ICES 26 (39H0)

11016 1-2 10,4 18 2,1 6,6

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No Species of fish Fishing area

(statistical square

No of

sample

Age of fish

(years)

Size

(cm)

Fat

content,%

Sum of dioxins

(WHO-PCDD/F

-TEQ), pg/g established

for fresh product weight

Sum of dioxins

and dioxins-like

PCBs (WHO -

PCDD/F-PCB-

TEQ), pg/g

established for

fresh product

weight


d, ICES 26 (39H0)

11017 1 8,2 14 0,62 2,1


d., ICES 26 (39H0)

11018 1 7,6-8,2 13 0,47 1,7

13. Baltic herring Baltic Sea, FAO 27 III

d., ICES 26 (40H0)

11019 2-3 18,4-19 10 9,9* 20**


d., ICES 26 (40H0)

11020 5-6 20,5-21 13 3,8 9,6**


d., ICES 26 (40H0)

11021 1-2 18-18,4 7,5 3,1 6,9

16. Baltic salmon Baltic sea, FAO 27 III

d., ICES 26, coastal

11931 4 65 7,9 1,5 5,3

* - above the EU normative level (4,0 pg/g fresh weight)

** - above the EU normative level (8,0 pg/g fresh weight)

(Commission Regulation (EC) No. 1881/2006)

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9.41 Environmental level of POPs according to NIPs

9.41.1 Environmental levels in Denmark

Figure 9-1: Time trend of PCB contamination in animal biota in Denmark (Source: NIP)

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Figure 9-2: Measured sum of dioxin and dioxin-like PCB (total TEQ) in samples of Danish foodstuffs 2000-2004. (Source: NIP)

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9.41.2 Environmental levels in Finland

Figure 9-3: Trends in PCB concentrations in precipitation in Northern and Southern Finland.(Source: NIP. Remark: The use of PCB has been prohibited

since 1995)

Figure 9-4: Concentrations of DDT and PCB in pike from three different regions of the Finnish coast [ng/g wet weight], 19712001 (Source: NIP)

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9.41.3 Environmental levels in Sweden

Levels in Guillemot eggs

Figure 9-5: Time trend of PCB and DDT contamination in animal biota in Sweden (Source: NIP)

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POP levels in animal biota in Sweden

Figure 9-6: estimated levels of POP concentration in animal biota in Sweden (Source: NIP)

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9.41.4 Environmental levels in the UK

Figure 9-7: Total PCBs and PCDD/PCDF time trend in selected UK Soils (Source: NIP)

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Figure 9-8: Dioxin and dioxin-like PCBs in UK Soil and Herbage (Source: NIP)

Documents

B PROec.europa.eu/.../pdf/syntesis_report_annex2.pdf · 2016-04-19 · 4.1 Total annual emissions of POPs as reported in EMEP WebDab -> PCB? ... 4.7 Comparison of EMEP WebDab emissions