August 29, 2014

Hope Ta ylor , Ph.D.

Larry Walker Associates

707 4th Street, Suite 200

Davis, CA 95616

530.753.6400

[email protected]

Andrew Kong

Laboratory Data Consultants, Inc. (LDC)

7750 El Camino Real, Suite 2L

Carlsbad, CA 92009

TECHNICAL MEMORANDUM

Sacramento Coordinated Water Quality Monitoring Program Receiving Water Monitoring Annual Data Review

2013/2014

August 29, 2014

Table of Contents Coordinated Monitoring Program

2013/2014 Technical Memorandum

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Contents Executive Summary ........................................................................................................ ES-1

1 Introduction ...................................................................................................... 1-1

1.1 Origins and Organization ................................................................................ 1-1

1.2 Content of Technical Memorandum .............................................................. 1-1

1.3 Acknowledgments ............................................................................................ 1-2

2 Methods ............................................................................................................. 2-1

2.1 Sampling Methods ............................................................................................ 2-1

2.1.1 Sampling Sites ................................................................................................. 2-1

2.1.2 Monitoring Plan .............................................................................................. 2-2

2.1.3 Sampling Schedule .......................................................................................... 2-4

2.1.4 Sample Collection ........................................................................................... 2-4

2.2 Quality Assurance and Quality Control ........................................................ 2-4

2.2.1 Field-initiated QA/QC ................................................................................... 2-5

2.2.2 Laboratory-initiated QA/QC ........................................................................ 2-5

2.2.3 Data Validation Procedures ........................................................................... 2-5

2.3 Analytical Methods ........................................................................................... 2-8

3 Annual Data Summary ................................................................................... 3-1

3.1 Data Validation Results .................................................................................... 3-1

3.2 Ambient Water Quality Conditions ............................................................... 3-4

3.3 Comparisons with Water Quality Objectives ............................................. 3-16

3.3.1 Comparisons with Water Quality Objectives for Conventional Pollutants 3-16

3.3.2 Comparisons with Nutrient Water Quality Objectives ........................... 3-17

3.3.3 Comparisons with Metals Water Quality Objectives .............................. 3-18

3.3.4 Comparisons with Microbiological Limits ................................................ 3-18

3.3.5 Comparisons with Pesticide Water Quality Objectives .......................... 3-19

3.3.6 Comparison with Trace Organics Water Quality Objectives ................. 3-19

3.4 Summary Statistics .......................................................................................... 3-19

3.4.1 Treatment of Values below Reporting Limits ........................................... 3-20



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Appendices Appendix A. Data Evaluation and Validation (July 2013 – June 2014) Appendix B. Time-Series Plots (December 1992 – June 2014) Appendix C. Laboratory Data Reports

List of Tables Table 2-1. Constituents Analyzed for Coordinated Monitoring Program Events ..... 2-3

Table 2-2. CMP Sampling Schedule, July 2013 through June 2014 .............................. 2-4

Table 2-3. Summary of CMP QA/QC Samples and Specifications for 2013/2014 ... 2-5

Table 2-4. CMP Constituents, Analytical Methods, and Reporting Limits ................ 2-8

Table 3-1. Summary of Relevant Water Quality Objectives ......................................... 3-6

Table 3-2. Summary of July 2013 through June 2014 Data for Sacramento River at Veterans Bridge ........................................................................................................... 3-8

Table 3-3. Summary of July 2013 through June 2014 Data for Sacramento River at Freeport Marina ......................................................................................................... 3-10

Table 3-4. Summary of July 2013 through June 2014 Data for American River at Nimbus Dam .............................................................................................................. 3-12

Table 3-5. Summary of July 2013 through June 2014 Data for American River at Discovery Park .......................................................................................................... 3-14

Table 3-6. Summary Statistics for the Sacramento River at Veterans Bridge ........... 3-21

Table 3-7. Summary Statistics for the Sacramento River at Freeport Marina .......... 3-23

Table 3-8. Summary Statistics for the American River at Nimbus Dam ................... 3-25

Table 3-9. Summary Statistics for the American River at Discovery Park ............... 3-27

List of Figures Figure 2-1. Sampling Sites for the CMP, 2013/2014 ...................................................... 2-2

Figure 2-2. ADaPT Process for Checking and Validating Data .................................... 2-7

Figure 3-1. American River Sampling Events, Mean Daily River Flows in Cubic Feet Per Second (cfs) and Regional Precipitation in Inches (1992-2014) ..................... 3-2



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Figure 3-2. American River Sampling Events, Mean Daily River Flows in Cubic Feet Per Second (cfs) and Regional Precipitation in Inches (July 2013-June 2014) .... 3-2

Figure 3-3. Sacramento River Sampling Events, Mean Daily River Flows in Cubic Feet Per Second (cfs) and Regional Precipitation in Inches (1992-2014) ............. 3-3

Figure 3-4. Sacramento River Sampling Events, Mean Daily River Flows in Cubic Feet Per Second (cfs) and Regional Precipitation in Inches (July 2013-June 2014)........................................................................................................................................ 3-3

Acronyms Coordinated Monitoring Program


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Acronyms µg/L Micrograms per liter µmhos/cm Micromhos per centimeter µS/cm Microsiemens per centimeter ADaPT Automated Data Processing Tool BOD Biological oxygen demand cfs Cubic feet per second CMP Sacramento Coordinated Water Quality Monitoring Program COD Chemical oxygen demand CTR California Toxics Rule EDD Electronic Data Deliverable MCL Maximum contaminant level mg/L Milligrams per liter mL Milliliters MPN Most Probable Number MS Matrix Spike MTBE Methyl tertiary butyl ether NCI National Cancer Institute ng/L Nanograms per liter NPDES National Pollutant Discharge Elimination System NTU Nephelometric Turbidity Units P4 Pretreatment Pollution Prevention Program PAH Polycyclic aromatic hydrocarbon QA/QC Quality assurance/quality control RPD Relative percent difference SRCSD Sacramento Regional County Sanitation District SRWTP Sacramento Regional Wastewater Treatment Plant TKN Total Kjeldahl nitrogen USEPA United States Environmental Protection Agency UVA254 Ultraviolet Adsorption at 254 nm

Executive Summary Coordinated Monitoring Program


ES-1

Executive Summary In May 1991, the Sacramento Regional County Sanitation District (SRCSD), the County of Sacramento (County) Department of Water Resources and the City of Sacramento (City) jointly established the Sacramento Coordinated Water Quality Monitoring Program (CMP). The CMP was established to conduct water quality monitoring on the Sacramento and American Rivers to comply with federal NPDES permit requirements. The primary goals of the CMP are to:

• Develop high quality data;

• Operate a cost-effective ambient monitoring program;

• Fulfill regulatory requirements;

• Communicate findings; and

• Coordinate and collaborate with regional efforts. Data collected under the CMP conform to the current National Pollutant Discharge Elimination System (NPDES) stormwater permit for the Sacramento area and to the NPDES municipal wastewater permit for SRCSD. The CMP monitoring period is October through June, the stormwater permit reporting period is from July through June, and the wastewater permit reporting period is the January through December calendar year. This memorandum reviews the field activities for the stormwater permit in the CMP monitoring period, but summarizes data collected for both permits. SRCSD performed a characterization study at Freeport Marina on the Sacrament River in the 2013 calendar year as part of the wastewater permit requirements. These activities were reported in a separate report in 20141 and are not specifically discussed in this report, but the results from that study are included in summary statistics and trend plots.

The Sacramento Stormwater Quality Partnership (Partnership), represented by the County as the lead permittee in the CMP agreement with SRCSD, manages the stormwater permit compliance effort. SRCSD staff members lead the day-to-day CMP activities while City and County staff members participate on the CMP Steering Committee on behalf of the Partnership.

This technical memorandum reviews CMP activities to fulfill stormwater permit requirements for the CMP monitoring period, but includes data summaries for all ambient data collected for both permits for the entire previous period of record, December 1992 to June 2013. The following text is a brief summary of the contents of this technical memorandum.

1 Sacramento Regional Sanitation District. Self-Monitoring Report Submittal for 2013 Effluent and Receiving Water Characterization Monitoring for Sacramento Regional County Sanitation District, Sacramento Regional Wastewater Treatment Plant (SRWTP), Sacramento County, Order R5-2013-0124, NPDES No. CA0077682. March 31, 2014.



ES-2

Methods Water quality samples for the CMP's ambient water quality monitoring efforts have been obtained from sites in the Sacramento and American Rivers within Sacramento County since December 1992. In 2013/2014, two sites were sampled on the Sacramento River: at the Interstate 5 Veterans Bridge near Alamar Marina and at Freeport Marina. Two sites were sampled on the American River: below Nimbus Dam and at Discovery Park. Figure ES-1 identifies the locations of each site.

For compliance with the stormwater permit, sampling was performed four times at each site over the 2013/2014 monitoring period. Water quality parameters measured in 2013/2014 under the CMP include:

• Conventional parameters—Hardness, pH, dissolved oxygen, temperature, conductivity, turbidity, alkalinity, biological oxygen demand (BOD5), chemical oxygen demand (COD), chloride, total organic carbon, dissolved organic carbon, total dissolved solids, and total suspended solids

• Trace metals—Dissolved and total copper, iron, lead, and zinc; and total mercury and methylmercury

• Pesticides—Organophosphate and pyrethroid

• Pathogen indicators—Fecal coliform and E. coli bacteria

• Nutrients—Nitrogen and phosphorus species

• Trace organic compounds—Polycyclic aromatic hydrocarbons; total petroleum hydrocarbons; and semi-volatile and non-volatile organics



ES-3

Figure ES-1. Sampling Sites for the CMP, 2013/2014

The sampling methods, analytical methods and quality assurance/quality control (QA/QC) procedures are summarized in Section 2 of this technical memorandum. An automated data checking and validation system was applied and the data are stored in the CMP data management system.

Annual Data Summary Data collected under the CMP for 2013/2014 (Events #209 through #212) are presented and evaluated in Section 3. The CMP has completed 233 sampling events since December 19922. Summary statistics for the entire dataset representing the period December 1992 through June 2014 are presented in Section 3.

2 In years during which monitoring events are conducted for the Pretreatment Pollution Prevention Program (P4), P4 events are denoted by integers and additional stormwater events (triggered by targeted storm conditions occurring between the P4 event and the dry-weather stormwater program event) are denoted using decimal point numbering – thus, the total number of events conducted by the CMP is greater than the integer values used for event numbering.



ES-4

Ambient Water Quality Conditions The CMP reviewed and evaluated 1,644 individual results generated from July 2013 through June 2014. Data qualifications were required for 619 analytical results, resulting in 1,025 results not qualified for an overall analytical success rate of 62.3% for Events #209 through #212. Results above the Method Detection Limit but below the Reporting Limit are not included in the number of analytes qualified. None of the 1,644 results were rejected. Therefore, 100% of the data are considered valid and are incorporated into the database. The data quality evaluation is discussed in Appendix A.

The majority of the results for conventional parameters, ammonia, nitrate, total Kjeldahl nitrogen (TKN), phosphorus, nitrite, and E. coli bacteria were found to be above their respective analytical reporting limits. The majority of the results for pesticides and trace organics were found to be below their respective analytical reporting limits and the applicable water quality objectives. Each trace metal was detected at least once.

Individual parameter levels found in 2013/2014 were comparable to levels found during previous sampling events. Time-series plots for select constituents covering the entire period of record (Appendix B) demonstrate these constant trends.

Comparisons with Water Quality Objectives In Section 3, water quality data for 2013/2014 (Events #209 through #212) are compared to the lowest relevant water quality objectives from the California Toxics Rule (CTR), the Central Valley Regional Water Quality Control Board’s (Regional Water Board’s) Water Quality Control Plan for the Sacramento and San Joaquin Rivers (“Basin Plan”), and USEPA criteria for ammonia and E. coli bacteria. The vast majority of the constituents measured in the rivers during 2013/2014 indicated compliance with existing water quality objectives.

Exceedances of water quality objectives were observed for a few constituents, including the indicator bacteria E. coli and fecal coliform, and the metals copper and lead. Occasional exceedances are typical for these constituents, and higher bacteria levels are typical of the first storm event, when the indicator bacteria exceedances occurred. Exceedances of water quality objectives for PAHs occurred during two events, and there was one instance where the turbidity increase in the Sacramento River exceeded the Basin Plan objective for relative increase from upstream to downstream site. In addition, there was one exceedance for specific conductivity.

Section 1 – Introduction Coordinated Monitoring Program


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1 Introduction

This section describes the Sacramento Coordinated Water Quality Monitoring Program (CMP) origins and organization, its goals and objectives, and the monitoring plan. Finally, the report contents are outlined and acknowledgements are made.

1.1 Origins and Organization

In May 1991, the Sacramento Regional County Sanitation District (SRCSD), the County of Sacramento Department of Water Resources and the City of Sacramento Department of Utilities jointly established the Sacramento Coordinated Water Quality Monitoring Program (CMP) for ongoing and future Sacramento-area water quality monitoring programs on the Sacramento and American Rivers. The County of Sacramento Department of Water Resources and the City of Sacramento Department of Utilities lead the countywide stormwater program through the Sacramento Stormwater Quality Partnership (Partnership). The CMP is, thus, a collaborative effort between SRCSD and the Partnership.

The primary goals of the CMP are to:

• Develop high quality data;

• Operate a cost-effective ambient monitoring program;

• Fulfill regulatory requirements;

• Communicate findings; and

• Coordinate and collaborate with regional efforts. Data collected under the CMP conform to the current National Pollutant Discharge Elimination System (NPDES) stormwater permit for the Sacramento area and to the NPDES municipal wastewater permit for SRCSD.

1.2 Content of Technical Memorandum

This technical memorandum presents information in the following two sections.

Section 2 – Methods Section 2 briefly describes sampling methods and field and laboratory Quality Assurance / Quality Control (QA/QC). The monitored analytes and sampling schedule are tabulated. QA/QC results are also discussed.

Section 3 – Annual Data Summary Section 3 presents an analysis and evaluation of data collected under the CMP during the 2013/2014 monitoring period. This year’s CMP monitoring period was October 2013 through June 2014, and the stormwater reporting period is from July 2013 to June 2014. This memorandum reviews the field activities for the stormwater permit, but includes data collected for both permits during the stormwater reporting period for the purpose of summary statistics and time series plots.

Each year, in order to assess the accuracy and precision of the data collected, a standard

Section 1 – Introduction Coordinated Monitoring Program


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QA/QC evaluation is conducted prior to analyzing the data generated under the CMP. Further data analysis is only performed for data deemed acceptable under the QA/QC evaluation. The evaluation of the ambient data serves to: (1) characterize water quality conditions; and (2) compare the water quality conditions with applicable water quality objectives. The water quality objective comparison presented in this report is for the stormwater permit required events. Events conducted under SRCSD’s 2010 NPDES Permit are included in the summary statistics and time series plots, and comparison to water quality objectives was previously submitted in the Receiving Water Characterization Monitoring Report1 to comply with SRCSD Permit reporting requirements.

1.3 Acknowledgments

The CMP Steering Committee directs and supervises the performance of the CMP. The CMP Steering Committee is currently comprised of representatives from the following sponsoring agencies:

CMP Agencies and Representatives

Sacramento Regional County Sanitation District Policy and Planning Department Environmental Laboratory Sacramento Stormwater Quality Partnership County of Sacramento, Department of Water

Resources City of Sacramento, Department of Utilities

The CMP Program Manager for the 2013/2014 CMP monitoring period was Vyomini Upadhyay of the SRCSD. In addition to agency staff, private consulting firms under contract to the SRCSD also contributed to the CMP. Larry Walker Associates was the prime consultant and provided technical support in the areas of program management, data analyses, coordination activities, and reporting. Laboratory Data Consultants provided technical support for analytical data validation and database management.

Section 2 – Methods Coordinated Monitoring Program


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2 Methods

This section summarizes the sampling methods and field and laboratory quality assurance/quality control (QA/QC) procedures implemented under the CMP for the 2013/2014 monitoring period. Detailed Standard Operating Procedures are presented in The Ambient Monitoring Program of the CMP Standard Operating Procedures3. The Sacramento Regional County Sanitation District (SRCSD) Environmental Laboratory sampling crew maintains this document.

2.1 Sampling Methods

Sampling methods employed during CMP sampling events are described in this section.

2.1.1 Sampling Sites

For the 2013/2014 monitoring effort, the CMP collected water quality samples from two sites on the Sacramento River and two sites on the American River. The sites are selected to bracket (upstream and downstream) urban stormwater discharges and for logistical reasons. Figure 2-1 presents the sampling sites, which were as follows:

River Sampling Sites

Sacramento River • Interstate 5 Veterans Bridge near Alamar Marina, upstream from the Sacramento urban area

• Freeport Marina, downstream from the Sacramento urban area and upstream from the Sacramento Regional Wastewater Treatment Plant (SRWTP) discharge

American River • Nimbus Dam, below the dam outlet4 and upstream from the Sacramento urban area

• Discovery Park, near the confluence of the American and Sacramento Rivers and downstream from the Sacramento urban area that drains into the American River

3 SCRSD 2001. The Ambient Monitoring Program of the CMP: Standard Operating Procedures 2001. Sacramento Regional Wastewater Treatment Plant Control Laboratory/Plant Engineering. Elk Grove, California. 4 Samples have been collected above the dam when dangerous conditions exist due to high releases.



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Figure 2-1. Sampling Sites for the CMP, 2013/2014

2.1.2 Monitoring Plan

Sampling events were organized according to the monitoring plan, as shown in Table 2-1. Based on the SRCSD NPDES municipal wastewater permit adopted in 2010, the CMP will only sample during stormwater permit-required events. Accordingly, all CMP events conducted during 2013/2014 were to fulfill stormwater permit monitoring requirements. The stormwater permit requires river samples to be collected from three storm events and one dry-weather event. There were four sampling events during the monitoring season (October-June)..



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Table 2-1. Constituents Analyzed for Coordinated Monitoring Program Events

Analyses Method Lab Nim

bus

Dis

cove

ry P

ark

Vete

rans

Brid

ge

Free

port

Fiel

d D

up (1

)

Fiel

d B

lank

(1)

Equi

p. B

lank

(1)

Temperature SM 2550 B SRCSD EL X X X X pH SM 4500-H+B SRCSD EL X X X X Dissolved oxygen SM 4500-OG SRCSD EL X X X X Conductivity EPA120.1 SRCSD EL X X X X Standard trace metals(2) EPA 200.8 SRCSD EL X X X X X X X Mercury, unfiltered EPA 1631 SRCSD EL X X X X X X X Methylmercury, unfiltered EPA 1630 Caltest C C C C C Hardness as CaCO3 SM 2340C SRCSD EL X X X X X Alkalinity SM 2320B SRCSD EL X X X X X Ammonia EPA 350.1 SRCSD EL X X X X X Nitrate/Nitrite EPA 353.2 SRCSD EL X X X X X Total Kjeldahl Nitrogen EPA 351.3 SRCSD EL X X X X X Total Nitrogen SM 4500-N SRCSD EL X X X X X Total Phosphorus EPA 365.4 SRCSD EL X X X X X BOD5 SM 5210 B SRCSD EL X X X X X COD HA 8000 SRCSD EL X X X X X Total dissolved solids SM 2540 C SRCSD EL X X X X X Total suspended solids SM 2540 D SRCSD EL X X X X X Turbidity EPA 180.1 SRCSD EL X X X X X Chloride SM 4500-Cl E SRCSD EL X X X X X Fecal coliform / E. Coli 9221E / 9221F SRCSD EL X X X X X Organic carbon (total / dissolved) SM 5310B SRCSD EL X X X X X PCBs EPA 608 Caltest X X X X X Organophosphate pesticides(3) EPA 614/8270 Caltest X X X X X Pyrethroid pesticides EPA 8270 Mod Caltest X X X X Semi-volatile organics EPA 625 Caltest X X X X X X Carbamates EPA 632 Caltest X X X X X TPH (gasoline, motor oil, and diesel) EPA 8015M Caltest X X X X X

Notes: SM = Standard method; EPA = Environmental Protection Agency Caltest = Caltest Analytical Laboratory; SRCSD EL = Sacramento Regional County Sanitation District Environmental

Laboratory. “X” = required for Stormwater events; “C” = CMP interest but not required by Stormwater program. (1) Locations for field duplicate, field blank and equipment blank according to the CMP QA/QC schedule. (2) Total recoverable and dissolved metals: copper, iron, lead, and zinc. (3) OP pesticides, diazinon and chlorpyrifos, were also analyzed by EPA 8270 Mod (GCMS-NCI-SIM).



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2.1.3 Sampling Schedule

River sites were monitored during four sampling events5 during the 2013/2014 monitoring period. Table 2-2 presents dates and event types for each sampling event (#205 through #208). Table 2-2. CMP Sampling Schedule for 2013/2014 Event # Date Event Type

209 November 20, 2013 Stormwater 210 February 6, 2014 Stormwater 211 February 27, 2014 Stormwater 212 May 8, 2014 Stormwater (dry)

2.1.4 Sample Collection

Sample collection equipment and protocols were designed to minimize contamination consistent with USEPA guidance6 for “clean” sampling methodologies. Cross-sectional composite samples were collected by boat at the Discovery Park site on the American River and at the Veterans Bridge and Freeport Marina sites on the Sacramento River. Composite sample aliquots for most analytes were collected using a peristaltic pump with acid-cleaned silicone tubing. Composite samples were comprised of sub-samples collected from three depths at each of five sampling points along a designated sampling transect. Details of cross-sectional composite sample collection procedures and sampling equipment for individual sites are documented in SRCSD’s Standard Operating Procedures (SOP)7. Composite samples were collected into acid-cleaned polyethylene carboys and divided into glass and polyethylene sample containers appropriate for the analyses to be performed.

At the Nimbus Dam sampling site on the American River, only single aliquot grab samples were collected from near the shore. These grab samples were collected either by pumping or by collecting the sample directly into a polyethylene carboy or other appropriate sample containers.

At all sites, samples analyzed for pathogen indicators, pesticides and trace organics were collected as separate near-surface grabs by submerging the sample containers 6 to 12 inches below the water surface. This sampling method was employed to avoid potential contamination from the sampling equipment. Samples for dissolved metals, orthophosphate and dissolved organic carbon analyses were filtered immediately upon collection.

2.2 Quality Assurance and Quality Control

A QA/QC program was implemented to achieve high quality laboratory results at low analytical detection limits. Table 2-3 summarizes QA/QC samples and analyses applied for 2013/2014. Appendix A presents details of the QA/QC procedures, along with the validation results of the 2013/2014 CMP data. 5 During 2012/2013, there were no P4 events required by the SRCSD Permit; thus, only stormwater events were conducted. 6 USEPA 1995. Method 1669. Sampling ambient water for trace metals for EPA water quality criteria levels. EPA 821-R-95034. Office of Water, Washington DC. 36 p. 7 Available upon request to Mike Cook, SRCSD Environmental Lab.



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Table 2-3. Summary of CMP QA/QC Samples and Specifications for 2013/2014

QA/QC Sample Type Parameter Evaluated

Source of Contamination or Variation

CMP QA/QC Specifications

Field blanks Contamination Sampling and equipment < Reporting limit Method or Preparation blanks Contamination Blank water < Reporting limit

Duplicate samples (splits) Precision Sample handling ≤ 50% RPD Method blanks Contamination Analytical procedures < Reporting limit Lab control samples Accuracy Analytical procedures 80 – 120% Recovery(1)

Duplicate and lab control samples analyses Precision Analytical procedures ≤ 25% RPD(1)

Surrogate Accuracy Matrix effects 30 – 150% Matrix spikes Accuracy Matrix effects 80 – 120% Recovery(1) Matrix spike duplicates Precision Matrix effects ≤ 25% RPD(1) (1) Data quality objectives for trace organic and pesticide analyses are specific to each analyte and are documented in data

reports from each analyzing laboratory. RPD = Relative Percent Difference.

2.2.1 Field-initiated QA/QC

Field-initiated QA/QC samples were prepared and submitted to contract laboratories to characterize and evaluate potential impacts of sampling procedures and equipment on the precision and accuracy of the resulting data. Field-initiated QA/QC samples submitted to the contract laboratory consisted of (1) field blanks and equipment blanks to assess the potential for sample contamination and (2) sample duplicates to assess sampling and sample handling precision. Field-initiated QA/QC samples were typically prepared and submitted at the rate of one sample of each type per sampling event.

2.2.2 Laboratory-initiated QA/QC

Laboratory QA/QC procedures were specified by the CMP to ensure that the laboratories generated high quality data. Analysis of laboratory-initiated QA/QC samples was conducted at a minimum rate of one per analytical batch.

For most parameters, analytical accuracy was evaluated by each laboratory through analysis of (1) laboratory control samples and/or standard reference material samples and (2) matrix spikes, as appropriate for specific analyses. Analytical precision was evaluated by each laboratory through analysis of (1) duplicate samples split from a single sample in the laboratory, (2) laboratory control sample duplicates, and (3) matrix spike duplicate analyses. The laboratories monitored potential contamination due to analytical reagents or laboratory sample processing through the analysis of method blanks and filter blanks.

2.2.3 Data Validation Procedures

Data checking and quality validation was performed using the Automated Data Processing Tool (ADaPT) software package. ADaPT is a Microsoft® Access program designed to perform:

• Compliance screening or error checking to ensure the correctness and completeness of the laboratory analytical data; and



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• Data review of the Electronic Data Deliverable (EDD) reports provided by the laboratory that measures the quality and integrity of sample results against associated laboratory quality control, holding times and method detection limits.

ADaPT uses a specific library created for the CMP as the reference for EDD report error checking and data review8. The project library is an electronic representation of the Quality Assurance Project Plan. The project library contains all analytes along with data review criteria within the scope of the CMP (e.g., reporting limits, blank contamination rules, holding times, and accuracy and precision criteria for each method and sample matrix).

The compliance screening module examines each EDD report for correct standard values, data omission in required fields, date/time format, logical date/time values and duplicate records. The screening module also checks for target analyte completeness and correct reporting limits. The error checker examines each EDD report to make sure various laboratory QA/QC samples are included, as specified by the analytical methods reported. After checking the EDD report for errors, the software creates an error log that can be viewed on screen or as a report. Each error is described in detail and, if applicable, the record number where the error occurs is identified.

The Automated Data Review module evaluates the EDD report and applies data review qualifiers (flags) to each water quality sample record based on laboratory quality control results reported in the EDD report and project-specific data review criteria specified in a project library. Water quality sample records in the EDD report are updated with applicable data review qualifiers and reason codes, which provide a coded explanation for any data review qualification. The software provides a variety of post data review qualification and outlier reports summarizing the results of the automated data review.

Figure 2-2 presents a summary of the steps performed for the data checking and validation. The flow chart illustrates how ADaPT is used to evaluate the quality of data produced under the CMP. The results and discussion of the QA/QC data review for Events #209 through #212 are included in Appendix A and summarized in Section 3 (Annual Data Summary) of this memo.

8 CDM 2004. “Data Management Protocols (Draft).” Prepared for the Sacramento Regional County Sanitation District, Sacramento County Water Agency, and the City of Sacramento. CDM and Laboratory Data Consultants (LDC). June.



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Figure 2-2. ADaPT Process for Checking and Validating Data



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2.3 Analytical Methods

Table 2-4 presents methods used to analyze CMP water quality samples and program reporting limits. Reporting limits were determined based on detection limit studies conducted by the analyzing laboratories. Table 2-4. CMP Constituents, Analytical Methods, and Reporting Limits

Analyte Method(1) Lab(2) Reporting Limits Units

Field Temperature SM 2550 B SRCSD EL 0.1 ˚C Dissolved Oxygen SM 4500-O G SRCSD EL 0.1 mg/L pH SM 4500-H+-B SRCSD EL 1 pH units

Electrical Conductivity EPA 120.1 SRCSD EL 1 µmhos/cm @ 25˚C

Turbidity EPA 180.1 SRCSD EL 1 NTU Conventional Total Organic Carbon SM 5310B SRCSD EL 0.5 mg/L Dissolved Organic Carbon SM 5310B SRCSD EL 0.5 mg/L Hardness, as CaCO3 SM 2340 C SRCSD EL 5.0 mg/L Total Suspended Solids SM 2540D SRCSD EL 3.0(3) mg/L Total Dissolved Solids SM 2540C SRCSD EL 20 mg/L Other Chloride SM 4500-Cl-E SRCSD EL 2 mg/L Mercury EPA 1631 SRCSD EL 0.2-0.5 ng/L Methylmercury EPA 1630 Caltest 0.05 ng/L Nutrients Ammonia EPA 350.1 SRCSD EL 0.1 mg/L Nitrate EPA 353.2 SRCSD EL 0.1 mg/L Nitrite EPA 353.2 SRCSD EL 0.1 mg/L Total Kjeldahl Nitrogen EPA 351.2 SRCSD EL 0.1 mg/L Total Phosphorus EPA 365.4 SRCSD EL 0.05 mg/L Trace Metals (total recoverable and dissolved) Copper EPA 200.8 SRCSD EL 0.2–0.5 µg/L Iron EPA 200.8 SRCSD EL 5-50 µg/L Lead EPA 200.8 SRCSD EL 0.1–0.3 µg/L Zinc EPA 200.8 SRCSD EL 1.0 µg/L Bacteria / Pathogens E. coli SM 9221 F SRCSD EL 2 MPN/100 mL Fecal Coliform SM 9221 E SRCSD EL 2 MPN/100 mL Selected Organophosphate Pesticides Diazinon EPA 614 Caltest 0.02/0.007 µg/L Diazinon EPA 8270 Caltest 0.0005/0.0001 µg/L Chlorpyrifos EPA 614 Caltest 0.01/0.005 µg/L Chlorpyrifos EPA 8270 Caltest 0.001/0.0002 µg/L Malathion EPA 614 Caltest 0.05/0.008 µg/L Selected Additional Pesticides Pyrethroid Pesticides EPA 625 NCl Caltest Variable (4) ng/L Selected Semi-volatile Organics Polycyclic aromatic hydrocarbons (PAHs) EPA 625 Caltest Variable (4) µg/L



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Analyte Method(1) Lab(2) Reporting Limits Units

Selected PCBs PCBs EPA 608 SRCSD EL Variable (4) µg/L Selected Carbamate Pesticides Carbamate pesticides EPA 632 Caltest Variable (4) µg/L

Notes: (1) SM = Standard method; EPA = Environmental Protection Agency (2) Caltest = Caltest Analytical Laboratory; SRCSD EL = Sacramento Regional County Sanitation District Environmental

Laboratory. (3) Reported to 2.0 mg/L for American River to match the Partnership’s NPDES stormwater permit. (4) Reporting limits vary by individual analyte and analytical run, but are below applicable water quality objectives.

Section 3 – Annual Data Summary Coordinated Monitoring Program


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3 Annual Data Summary

This data summary presents and evaluates water quality data collected during the stormwater reporting period from July 2013 through June 2014 under the CMP. Samples were collected from two sites on the American River (Nimbus Dam and Discovery Park) and from two sites on the Sacramento River (Veterans Bridge and Freeport Marina). Figure 2-1 in the previous section identifies these sites on a regional map.

The CMP began monitoring in December 1992. Since then, a total of 232 sampling events (including events coordinated with the Partnership) have been performed, with samples collected over a wide range of flows (Figure 3-1 through Figure 3-4). The 2013/2014 monitoring period had below normal rainfall and runoff total amounts.

The scope of this data summary addresses three related objectives:

• Review QA/QC data for this year’s events (#209 through #212);

• Characterize ambient water quality conditions in the Sacramento and American Rivers for monitoring year July 2013 – June 2014 and for the full December 1992 – June 2014 period of record; and

• Compare water quality data for July 2013 – June 2014 to relevant water quality objectives for the American and Sacramento Rivers.

3.1 Data Validation Results

CMP data for July 2013 – June 2014 were evaluated to determine the ability of the program’s sampling and analytical methods to produce representative and reliable water quality data for the American and Sacramento Rivers. Sample results were reviewed for conformance with recommended, allowable holding times for specific analyses and for compliance with CMP data quality objectives for laboratory and field QA/QC results. These evaluations and results are presented in detail in Appendix A.

The CMP reviewed and evaluated 1,644 individual results generated from July 2013 through June 2014. Data qualifications were required for 619 analytical results, resulting in 1,025 results not qualified for an overall analytical success rate of 62.3% for Events #209 through #212. Non-detected or detected but not quantified values (above the Method Detection Limit but below the Reporting Limit) are not considered qualified. Most qualifications were due to laboratory control sample recoveries outside of QC limits for semi-volatile organic compounds (SVOC), pyrethroid pesticides, and organophosphorus pesticides.

None of the 1,644 results were rejected. Therefore, 100% of the data are considered valid and are incorporated into the database. The accuracy and precision of CMP data generally achieved the QA/QC specifications listed in Table 2-3 presented in the previous section and no systematic problems with sampling or analytical procedures were found.



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Figure 3-1. American River Sampling Events, Mean Daily River Flows in Cubic Feet

Per Second (cfs) and Regional Precipitation in Inches (1992-2014)

Figure 3-2. American River Sampling Events, Mean Daily River Flows in Cubic Feet

Per Second (cfs) and Regional Precipitation in Inches (July 2013-June 2014)



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Figure 3-3. Sacramento River Sampling Events, Mean Daily River Flows in Cubic Feet

Per Second (cfs) and Regional Precipitation in Inches (1992-2014)

Figure 3-4. Sacramento River Sampling Events, Mean Daily River Flows in Cubic Feet

Per Second (cfs) and Regional Precipitation in Inches (July 2013-June 2014)



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3.2 Ambient Water Quality Conditions

A primary goal of the CMP is to characterize ambient water quality conditions in the CMP study area. For the purpose of this technical memorandum, ambient conditions are characterized by the individual values measured for all samples collected in the stormwater permit reporting period, temporal variations in these parameters, conditions associated with extreme values, and comparison to water quality objectives for the stormwater permit events.

Water quality data for 2013/2014 (Events #209 through #212) were compared to the lowest applicable water quality objectives from the California Toxics Rule9, the Central Valley Regional Water Quality Control Board’s (Regional Water Board’s) Water Quality Control Plan for the Sacramento and San Joaquin Rivers (Basin Plan)10, and USEPA criteria for ammonia11 and E. coli bacteria. For hardness-adjusted metals criteria (cadmium, chromium, copper, lead, nickel, silver and zinc), the criteria used for comparison were adjusted for the corresponding hardness value for each sampling event and site. For the pH and temperature-adjust ammonia criteria, the criteria used for comparison were adjusted to the corresponding pH and temperature values for each sampling site and event. Table 3-1 presents various numeric water quality objectives for all CMP constituents. Table 3-2 through Table 3-5 summarize ambient conditions at each site for the parameters monitored from July 2013 through June 2014. Cells with values exceeding applicable water quality objectives are shaded.

Table 3-9 through Table 3-12 present summary statistics for the entire data period (December 1992 – June 2014). The following statistics were calculated for constituents of interest monitored under the CMP:

• Total number of environmental samples analyzed;

• Number of samples in which a detectable quantity was measured;

• Percentage of samples in which a detectable quantity was measured;

• Minimum and maximum detected value; and

• Minimum and maximum reporting limits for data below detection. If 80% or more of the data for a parameter were detected values, the arithmetic mean and standard deviation were calculated based on the entire CMP data set (1992-2014). If less than 80% of the data were detected values, the data set was considered insufficient to reliably estimate the mean and standard deviation for that parameter and no additional statistics were calculated.

9 California Toxics Rule (CTR), Establishment of Numeric Criteria for Priority Toxic Pollutants for the State of California; Final Rule. 40 CFR Part 131, Federal Register No. 97. May 18, 2000. 10 Central Valley Regional Water Quality Control Board 1995. “Water Quality Control Plan (Basin Plan), 3rd Ed.”Amended, Sept. 1995. 11 United States Environmental Protection Agancy (USEPA), Aquatic Life Ambient Water Quality Criteria for Ammonia – Freshwater, 2013. EPA 822-R-13-001, April 2013.



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Summary statistics were computed using the Robust Lognormal Regression method12 when censored data were reported (i.e., data below program reporting limits). Data below detection were assigned values based on lognormal distribution regression statistics of the detected values. Distribution parameters (means and standard deviations) were calculated directly from the combined data sets of detected and estimated data.

Appendix B presents time-series plots for the same period of record for constituents of interest. These plots provide more detailed views of water quality data and variations in water quality characteristics over the period monitored. The "constituents of interest" plotted include the Partnership’s stormwater target pollutants and others:

Target Pollutants

• Copper (dissolved) • Mercury (total) • Methylmercury • Total suspended solids • E. coli • Chlorpyrifos • Diazinon • PAHs (chrysene) • Pyrethroids13 (bifenthrin)

Others

• TKN • Nitrate • Ortho-phosphate • Total organic carbon • Temperature

12 Helsel, D.R. and Cohn, T.A. 1988. “Estimation of descriptive statistics for multiply-censored water quality data.” Water Res. Res., 24(12):1997-2004.

Helsel, D.R. 1990. “Less than obvious.” Envir. Sci. Techn., 24(12):1766-1774. 13 These include Bifenthrin, Cypermethrin, Cyfluthrin, Lambda-Cyhalothrin, and Permethrin. Bifenthrin is typically the toxicity culprit, but each of the others is periodically detected. Occasionally deltamethrin or fenvalerate are also detected, but have almost never been at levels that contributed noticeably to toxicity (as calculated by toxic units) (pers. comm., T. Young of UC Davis to S. McCord of LWA, 7/22/11).



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Table 3-1. Summary of Relevant Water Quality Objectives

Parameter California

Toxic Rule

(CTR) # Units

Water Quality Objectives California Toxic Rule

Basin Plan Lowest Objective

Freshwater Aquatic Life Human Health (Consumption of)

Chronic Acute Water & Organisms

Organisms Only

Conventional

Chloride, total — mg/L — — — — 250 250

Dissolved Oxygen — mg/L — — — — 7 7

pH — Std. Units — — — — 6.5–8.5 6.5–8.5

Total Dissolved Solids — mg/L — — — — 125 125/250(1)

Electrical Conductivity (Specific Conductance)

— µS/cm — — — — 240/340 240/340(2)

Temperature — ˚C — — — — 20(3) 20(3)

Turbidity — NTU — — — — 10/150 10/150(4)

Bacteriological

Fecal coliform — MPN/100 mL — — — — 400 400

E. coli — MPN/100 mL — — — — 235(5) 235(5)

Nutrient

Ammonia as nitrogen — mg-N/L —) — — — 0.87-4.1 (6) 0.87-4.1 (6)

Nitrate plus Nitrite as N — mg-N/L — — — — 10(7) 10(7)

Nitrite as nitrogen — mg-N/L — — — — 1(7) 1(7)

Metals

Copper, Dissolved 6 µg/L 2.3-7.9 (8) 2.9-11.7 (8) — — 10 2.3-7.9 (8)

Copper, Total 6 µg/L 2.4-8.2 (8) 3.1-12.1(8) — 1300 1000(7) 2.4-8.2 (8)

Iron, Dissolved — µg/L — — — — 300 300

Iron, Total — µg/L — — — — 300(7) 300(7)

Lead, Dissolved 7 µg/L 0.42-2.3(8) 10.8-54.8 (8) — — — 0.42-2.1(8)

Lead, Total 7 µg/L 0.41-2.6(8) 10.5-67.4 (8) — — 15 0.41-2.6 (8)

Mercury, Total 8 ng/L — — 50 51 2000 50

Zinc, Dissolved 13 µg/L 30-104 (8) 30-103 (8) — — 100 30-103 (8)

Zinc, Total 13 µg/L 31-105 (8) 31-105(8) — — 5000(7) 31-105 (8)

Organophosphate Pesticides

Chlorpyrifos — µg/L — — — — 0.015 / 0.025 0.015(9)

Diazinon — µg/L — — — — 0.05 / 0.08 -0.10 / 0.16 0.05-0.10(10)

PAH

Acenaphthene 56 µg/L — — 1200 2700 — 1200

Anthracene 58 µg/L — — 9600 110000 — 9600

Benzo(a)anthracene 60 µg/L — — 0.0044 0.049 — 0.0044

Benzo(a)pyrene 61 µg/L — — 0.0044 0.049 0.2 0.0044

Benzo(b)fluoranthene 62 µg/L — — 0.0044 0.049 — 0.0044

Benzo(k)fluoranthene 64 µg/L — — 0.0044 0.049 — 0.0044

Chrysene 73 µg/L — — 0.0044 0.049 — 0.0044

Dibenzo(a,h)anthracene 74 µg/L — — 0.0044 0.049 — 0.0044



3-7

Notes: (1) 125 mg/L (90th percentile) applies only to the American River sites only. 250 mg/L (USEPA NAWQC) applies to the

Sacramento River. (2) Applies only to the Sacramento River at I Street Bridge as not to exceed 240 µS/cm (50th percentile) and 340 µS/cm (90th

percentile). (3) This objective (maximum 68 °F) applies only to Sacramento River above the I Street Bridge during periods when

temperature increases will be detrimental to fisheries: April through June and September through November. (4) 10 NTU applies to American River site and 150 NTU applies to Sacramento River sites; excluding periods of storm

water runoff. Turbidity also cannot increase 20% or more from the next upstream site where natural turbidity is between 5 and 50 NTUs, or by greater than 1 NTU where natural turbidity is between 1 and 5 NTU.

(5) Based on USEPA criteria not yet officially adopted into the Basin Plan. See http://www.swrcb.ca.gov/rwqcb5/board_decisions/adopted_orders/resolutions/r5-2002-0150.pdf

(6) The Basin Plan narrative objective is typically interpreted using USEPA ambient water quality criteria for Ammonia, which was recently updated in 2013. The 30-day average concentration of total ammonia (in mg-N/L) cannot exceed more than once every three years on the average, the pH- and temperature-dependent chronic criteria where salmonid fish are present. Based on the 2013 EPA National Recommended Water Quality Criteria. See http://water.epa.gov/scitech/swguidance/standards/criteria/aqlife/ammonia/upload/AQUATIC-LIFE-AMBIENT-WATER-QUALITY-CRITERIA-FOR-AMMONIA-FRESHWATER-2013.pdf.

(7) These water quality objectives are incorporated into the Basin Plan by reference to Title 22 drinking water standard MCLs, and are considered dissolved objectives.

(8) Adjusted for sample hardness (as CaCO3), as specified in the CTR. Objectives were calculated for each site individually using river hardness. Minimum and maximum values are provided to indicate the range.

(9) Limits apply as 4-day / 1-hour averages. The concentration limits for chlorpyrifos apply to Delta waterways, which include only the Freeport and River Mile 44 CMP sampling sites.

(10) Limits apply as 4-day / 1-hour averages. The lower pair applies to the Sacramento River from the Colusa Basin Drain to I Street Bridge (encompassing only CMP site Veterans Bridge). The higher pair applies to Delta waterways, which include only CMP sites Freeport and River Mile 44.

http://water.epa.gov/scitech/swguidance/standards/criteria/aqlife/ammonia/upload/AQUATIC-LIFE-AMBIENT-WATER-QUALITY-CRITERIA-FOR-AMMONIA-FRESHWATER-2013.pdf




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Table 3-2. Summary of July 2013 through June 2014 Data for Sacramento River at Veterans Bridge

Parameter Unit Event # 209 11/20/2013

Event # 210 02/06/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

Conventional

Alkalinity, total mg/L 86 98 98 70 ---

Biological Oxygen Demand mg/L < 2 < 2 < 2 2.0 ---

Chemical Oxygen Demand mg/L < 5.0 5.0 < 5.0 < 5.0 ---

Chloride mg/L 8.5 9.3 11 5.7 250

Dissolved organic carbon mg/L 7.3 7.2 7.6 6.6 ---

Dissolved oxygen mg/L 10.1 11.0 10.5 9.7 7

Electrical Conductivity μmhos/cm 197 228 252 167 240

Hardness mg/L 68 86 84 62 ---

pH pH Units 7.4 7.5 7.9 8.0 6.5-8.5

Temperature deg C 12.5 9.54 13.7 19.8 20

Total dissolved solids mg/L 110 150 150 110 250

Total organic carbon mg/L 6.9 9.0 8.4 6.4 ---

TSS mg/L 5.7 14 26 8.2 ---

Turbidity (field) NTU 8.3 16 16 4.1 150

Metals

Copper (dissolved) μg/L 2.4 2.5 1.6 1.9 6-7.9

Copper (total) μg/L 1.7 < 2.6 3.6 1.8 6.2-8.2

Iron (dissolved) μg/L < 8.1 15 32 < 8.1 300

Iron (total) μg/L 320 940 1200 220

Lead (dissolved) μg/L < 0.062 < 0.062 < 0.062 < 0.062 1.5-2.1

Lead (total) μg/L 0.15 0.36 0.44 0.10 1.7-2.6

Mercury (total) ng/L 1.4 2.3 3.3 1.2 50

Methyl mercury (total) ng/L 0.08 0.06 0.11 0.13 ---

Zinc (dissolved) μg/L 2.6 3.4 3.3 3.1 78-103

Zinc (total) μg/L 2.3 < 4.1 6.8 2.4 80-105

Nutrients

Ammonia as nitrogen mg/L < 0.040 < 0.040 < 0.040 < 0.040 1.7-4.7

Nitrate as nitrogen mg/L 0.11 0.088 0.11 < 0.0078 10

Nitrite as nitrogen mg/L 0.0022 0.0031 0.0026 0.0016 1

Total Kjeldahl nitrogen (TKN) mg/L 0.27 0.26 0.40 0.21 ---

Total phosphorus mg/L 0.069 0.081 0.037 0.064 ---

Bacteria

E. coli MPN/100 ml 17 7.8 7.8 4.5 235

Fecal coliform MPN/100 ml 22 7.8 7.8 4.5 400



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Table 3-2. Summary of July 2013 through June 2014 Data for Sacramento River at Veterans Bridge


Event # 210 02/06/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

OP Pesticides

Chlorpyrifos μg/L < 0.005 < 0.005 < 0.005 < 0.005 0.015

Diazinon μg/L < 0.007 < 0.007 < 0.007 < 0.007 0.05

Malathion μg/L < 0.005 < 0.005 < 0.005 < 0.005 ---

PAHs

Acenaphthene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 1200

Anthracene μg/L < 0.0040 < 0.0040 < 0.0040 0.02 9600

Benz(a)anthracene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044

Benzo(a)pyrene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044

Benzo(g,h,i)perylene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

Benzo(k)fluoranthene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044

Chrysene μg/L < 0.0040 < 0.0040 < 0.0040 0.01 0.0044

Dibenz(a,h)anthracene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044

Fluoranthene μg/L < 0.0040 < 0.0040 < 0.0040 0.04 300

Fluorene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 1300

Indeno(1,2,3-c,d)pyrene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044

Naphthalene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

Phenanthrene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

Pyrene μg/L < 0.0040 < 0.0040 < 0.0040 0.03 960

Semivolatile Organics

1-methylnaphthalene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

1-methylphenanthrene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

2,3,5-trimethylnaphthalene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

2,6-dimethylnaphthalene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---

2-methylnaphthalene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 --- Notes: Refer to Table 3-1 for a listing of the lowest applicable water quality objectives. “<” indicates that the sample analyte was not detected at that analytical detection limit. Blank spaces indicate no data were reported for that event. Cells highlighted in gray indicate that the individual value exceeds its lowest applicable water quality objective.



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Table 3-3. Summary of July 2013 through June 2014 Data for Sacramento River at Freeport Marina


Event # 210 02/06/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

Conventional


Biological Oxygen Demand mg/L 3.8 2.2 < 2 < 2 ---

Chemical Oxygen Demand mg/L < 5.0 < 5.0 < 5.0 < 5.0 ---

Chloride mg/L 6.3 9.7 9.3 5.3 250


Dissolved oxygen mg/L 10.1 11.5 10 9.4 7

Electrical Conductivity μmhos/cm 178 236 239 159 ---

Hardness mg/L 62 84 78 56 ---

pH pH Units 7.5 8.0 7.7 7.9 6.5-8.5

Temperature deg C 12.5 9.77 13.9 20.3 ---



TSS mg/L 5.2 7.0 12 6.3 ---

Turbidity (field) NTU 8.4 6.9 8.3 6.41 150

Metals

Copper (dissolved) μg/L 2.3 1.8 1.9 1.6 5.5-7.7

Copper (total) μg/L 1.5 1.9 2.6 1.9 5.7-8

Iron (dissolved) μg/L < 8.1 9.8 12 < 8.1 300

Iron (total) μg/L 230 340 600 240


Lead (total) μg/L 0.13 0.21 0.24 0.12 1.5-2.5



Zinc (dissolved) μg/L 4.1 1.4 14 3.1 72-101

Zinc (total) μg/L 2.3 < 2.9 < 4.5 < 2.8 73-103

Nutrients

Ammonia as nitrogen mg/L < 0.040 < 0.040 0.056 < 0.040 1.7-4.4

Nitrate as nitrogen mg/L 0.13 0.074 0.20 < 0.0078 10

Nitrite as nitrogen mg/L 0.0024 0.0046 0.0031 < 0.0012 1

Total Kjeldahl nitrogen mg/L 0.14 0.23 0.34 0.19 ---

Total phosphorus mg/L 0.054 0.074 < 0.032 0.049 ---

Bacteria

E. coli MPN/100 ml 20 13 2.0 6.8 235

Fecal coliform MPN/100 ml 20 13 4.5 6.8 400 1Turbidity increased by >1 NTU from the level at Veterans Bridge (4.1 NTU)



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Table 3-3. Summary of July 2013 through June 2014 Data for Sacramento River at Freeport Marina


Event # 210 02/6/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

OP Pesticides


Diazinon μg/L < 0.007 < 0.007 < 0.007 < 0.007 0.05

Malathion μg/L < 0.005 < 0.005 < 0.005 < 0.005 ---

PAHs


Anthracene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 9600





Chrysene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044


Fluoranthene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 300

Fluorene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 1300


Naphthalene μg/L < 0.005 < 0.0040 < 0.0040 < 0.0040 ---


Pyrene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 960





2,6-dimethylnaphthalene μg/L 0.006 < 0.0040 < 0.0040 < 0.0040 ---

2-methylnaphthalene μg/L 0.006 < 0.0040 < 0.0040 < 0.0040 --- Notes: Refer to Table 3-1 for a listing of the lowest applicable water quality objectives. “<” indicates that the sample analyte was not detected at that analytical detection limit. Blank spaces indicate no data were reported for that event. Cells highlighted in gray indicate that the individual value exceeds its lowest applicable water quality objective.



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Table 3-4. Summary of July 2013 through June 2014 Data for American River at Nimbus Dam


Event # 210 2/6/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

Conventional


Biological Oxygen Demand mg/L < 2 < 2 < 2 < 2 ---

Chemical Oxygen Demand mg/L < 5.0 5.0 < 5.0 < 5.0 ---

Chloride mg/L 2.0 < 3.2 < 3.5 < 3.1 250



Electrical Conductivity μmhos/cm 75 79 94 87.9 ---

Hardness mg/L 20 22 26 26 ---

pH pH Units 6.7 7.4 7.5 6.7 6.5-8.5

Temperature deg C 13.8 9.12 10.5 15.8



TSS mg/L 3.5 < 2.0 4.1 1.6 ---

Turbidity (field) NTU 3.7 1.3 5.0 1.1 150

Metals


Copper (total) μg/L 0.69 0.63 1.6 0.92 2.4-3

Iron (dissolved) μg/L < 8.1 < 8.1 8.3 < 8.1 300

Iron (total) μg/L 130 57 240 70


Lead (total) μg/L 0.13 0.047 0.21 < 0.072 0.41-0.6


Methyl mercury (total) ng/L 0.06 < 0.020 0.03 < 0.020 ---


Zinc (total) μg/L < 2.7 < 3.8 2.9 2.2 31-38

Nutrients

Ammonia as nitrogen mg/L < 0.040 < 0.040 0.086 < 0.040 4-6.4

Nitrate as nitrogen mg/L 0.046 0.013 0.17 0.096 10

Nitrite as nitrogen mg/L 0.0013 < 0.0012 0.0039 0.0020 1


Total phosphorus mg/L < 0.032 < 0.032 < 0.032 < 0.032 ---

Bacteria

E. coli MPN/100 ml 330 7.8 23 20 235

Fecal coliform MPN/100 ml 330 13 23 20 400



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Table 3-4. Summary of July 2013 through June 2014 Data for American River at Nimbus Dam


Event # 210 02/6/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

OP Pesticides


Diazinon μg/L < 0.007 < 0.007 < 0.007 < 0.007 0.05

Malathion μg/L < 0.005 < 0.005 < 0.005 < 0.005 ---

PAHs


Anthracene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 9600





Chrysene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 0.0044


Fluoranthene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 300

Fluorene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 1300


Naphthalene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 ---


Pyrene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 960









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Table 3-5. Summary of July 2013 through June 2014 Data for American River at Discovery Park


Event # 210 02/06/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

Conventional


Biological Oxygen Demand mg/L 4.9 < 2 < 2 2.5 ---

Chemical Oxygen Demand mg/L < 5.0 < 5.0 < 5.0 < 5.0 ---

Chloride mg/L 3.7 < 3.3 3.7 < 3.2 250



Electrical Conductivity μmhos/cm 70.0 75.0 91.0 83.0 ---

Hardness mg/L 24 26 30 28 ---

pH pH Units 7.3 7.7 7.5 7.8 6.5-8.5

Temperature deg C 13.7 9.77 13.3 18.6 ---



TSS mg/L 4.0 < 2.0 0.84 6.9 ---

Turbidity (field) NTU 11 4.5 1.5 3.2 150

Metals


Copper (total) μg/L 2.0 0.78 1.3 1.2 2.8-3.3

Iron (dissolved) μg/L < 8.1 < 8.1 27 19 300

Iron (total) μg/L 130 68 110 210

Lead (dissolved) μg/L 0.15 < 0.062 < 0.062 < 0.062 0.52-0.66

Lead (total) μg/L 0.58 0.094 0.099 0.23 0.52-0.69




Zinc (total) μg/L 8.6 < 2.0 3.5 2.5 36-43

Nutrients

Ammonia as nitrogen mg/L 0.059 < 0.040 < 0.040 < 0.040 2.4-5.1

Nitrate as nitrogen mg/L 0.17 0.070 0.23 0.092 10

Nitrite as nitrogen mg/L 0.0094 0.0025 0.0057 0.0029 1


Total phosphorus mg/L 0.061 0.048 < 0.032 0.034 ---

Bacteria

E. coli MPN/100 ml 5400 13 20 20 235

Fecal coliform MPN/100 ml 9200 13 20 20 400



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Table 3-5. Summary of July 2013 through June 2014 Data for American River at Discovery Park


Event # 210 02/06/2014

Event # 211 02/27/2014

Event # 212 05/08/2014

Lowest Objectives

OP Pesticides


Diazinon μg/L < 0.007 < 0.007 < 0.007 < 0.007 0.05

Malathion μg/L < 0.005 < 0.005 < 0.005 < 0.005 ---

PAHs


Anthracene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 9600

Benz(a)anthracene μg/L < 0.0040 < 0.0040 0.007 < 0.0040 0.0044

Benzo(b)fluoranthene ug/L < 0.0040 < 0.0040 0.02 < 0.0040 0.0044

Benzo(a)pyrene μg/L < 0.0040 < 0.0040 0.01 < 0.0040 0.0044

Benzo(g,h,i)perylene μg/L < 0.0040 < 0.0040 0.02 < 0.0040 ---

Benzo(k)fluoranthene μg/L < 0.0040 < 0.0040 0.005 < 0.0040 0.0044

Chrysene μg/L < 0.0040 < 0.0040 0.01 < 0.0040 0.0044


Fluoranthene μg/L 0.008 < 0.0040 0.01 < 0.0040 300

Fluorene μg/L < 0.0040 < 0.0040 < 0.0040 < 0.0040 1300

Indeno(1,2,3-c,d)pyrene μg/L < 0.0040 < 0.0040 0.01 < 0.0040 0.0044

Naphthalene μg/L < 0.007 0.005 < 0.0040 < 0.0040 ---

Phenanthrene μg/L 0.008 < 0.0040 < 0.0040 < 0.0040 ---

Pyrene μg/L 0.008 < 0.0040 0.02 0.004 960









3-16

3.3 Comparisons with Water Quality Objectives

Water quality data for 2013/2014 CMP monitoring year and stormwater permit events (Events #209 through #212) were compared to the lowest applicable water quality objectives listed in Table 3-1 above. The lowest applicable water quality objectives as well as ambient conditions are included in Table 3-2 through Table 3-5 above. Where comparisons are made to objectives, refer to Table 3-1 for the specific water quality objectives exceeded. Some of these water quality objectives are not entirely appropriate for exceedance comparisons. In particular:

• This simple comparison does not consider the frequency or duration of exceedances. CTR human health water quality objectives are based on the assumption of long-term human consumptive exposure and some water quality objectives are based on chronic (four-day) or monthly average in-stream concentrations.

• Because the American and Sacramento Rivers are designated with municipal and domestic water supply beneficial uses, the Basin Plan incorporates Title 22 maximum contaminant levels (MCLs). Title 22 Secondary MCLs were established to maintain the taste, odor or appearance of treated drinking water delivered to customers rather than to maintain ambient water quality. Title 22 MCLs regulate treated drinking water quality and were not intended to be applied to untreated source water in local rivers and creeks. In particular, sampling results for total metals—most of which are in filterable form—are compared to standards for filtered metals.

Comparisons with applicable regulatory limits indicate that most ambient water quality characteristics monitored under the CMP consistently met these limits at all sampling sites in the rivers for 2013/2014. A discussion of these results is presented below.

3.3.1 Comparisons with Water Quality Objectives for Conventional Pollutants

In general, the levels of the conventional parameters monitored under the CMP (pH, temperature, dissolved oxygen, conductivity, chloride, turbidity and total dissolved solids) met applicable Basin Plan water quality objectives during all of the 2013/2014 sampling events. Details are presented below.

3.3.1.1 Comparisons with pH Water Quality Objective

The Basin Plan water quality objective for pH is between 6.5 to 8.5 standard units. All pH measurements from the two sites on the Sacramento River and the two sites on the American River during 2013/2014 met the water quality objectives for pH.

3.3.1.2 Comparisons with Temperature Water Quality Objectives

According to the Basin Plan, the natural receiving water temperature of intrastate waters shall not be altered unless it can be demonstrated to the satisfaction of the Regional Water Board that such alteration in temperature does not adversely affect beneficial uses. In addition, at no time or place shall the temperature of COLD or WARM intrastate waters be increased more than 5 °F above natural receiving water temperature.

The Basin Plan also includes a specific temperature limit that applies to the Sacramento River sampling site at Veterans Bridge: “The temperature shall not be elevated above 68 °F



3-17

(20 °C) in the reach from Hamilton City to the I Street Bridge during periods when temperature increases will be detrimental to the fishery.” All temperature levels measured in the Sacramento River during 2013/2014 met their Basin Plan water quality objectives. There are no specific temperature limits applicable to the lower Sacramento River sites or to the American River sites.

3.3.1.3 Comparisons with Dissolved Oxygen Water Quality Objectives

The Basin Plan water quality objective for dissolved oxygen levels is 7.0 mg/L minimum. All dissolved oxygen concentrations measured at CMP sites in the American and Sacramento Rivers during 2013/2014 were greater than 7.0 mg/L.

Historical dissolved oxygen data appear high, occasionally exceeding temperature-dependent saturation concentrations. SRCSD has determined that the field sensor used historically (based on Clark cell membrane diffusion technology because they carry USEPA approval) was likely biased high.

3.3.1.4 Comparisons with Chloride Water Quality Objectives

All chloride measurements at sites in the American and Sacramento Rivers during 2013/2014 were below the Basin Plan water quality objective of 250 mg/L.

3.3.1.5 Comparisons with Specific Conductivity Water Quality Objectives

The Basin Plan includes water quality objectives for specific conductivity (or electrical conductivity) for the Sacramento River. Specific conductivity is to be below 240 μS/cm for 50 percent of the measurements and below 340 μS/cm for 90 percent of the measurements. Specific conductance was above the Basin Plan value for the 50th percentile objective in the Sacramento River at Veterans Bridge during event #211 on 2/27/2014.

3.3.1.6 Comparisons with Total Dissolved Solids Water Quality Objective

All total dissolved solids concentrations measured at sites in the American River during 2013/2014 met the Basin Plan water quality objective of 125 mg/L within the 90th percentile. All total dissolved solids concentrations measured at sites in the Sacramento River during 2013/2014 met the USEPA Ambient Water Quality Criterion of 250 mg/L.

3.3.1.7 Comparisons with Turbidity Water Quality Objectives

The Basin Plan provides explicit turbidity limits for the American River below Folsom Lake (10 NTU) and for the Sacramento River below I Street Bridge (150 NTU). These water quality objectives apply throughout the year except for periods when storm runoff occurs. There were no exceedances of the explicit limits for turbidity during 2013/2014.

The Basin Plan also provides limits for the relative increase in turbidity from an upstream to downstream site. The Basin Plan requires that where natural turbidity is between 5 and 50 NTUs, increases shall not exceed 20 percent, and where natural turbidity is between 1 and 5 NTUs, increases shall not exceed 1 NTU. There was one exceedance of the relative increase water quality objective, where the turbidity at Veterans was below 5 NTU, and increased by greater than 1 NTU at Freeport during the dry weather event (#212) on 5/8/2014.

3.3.2 Comparisons with Nutrient Water Quality Objectives

There are no applicable water quality objectives for most nutrient parameters monitored



3-18

under the CMP (i.e., total Kjeldahl nitrogen (TKN), total phosphorus and dissolved orthophosphate) with the exception of ammonia, nitrate and nitrite. Concentrations of nitrate and nitrite did not exceed their respective primary MCLs (10 mg-N/L and 1 mg-N/L) in any samples during 2013/2014. Ammonia chronic criteria are based on the temperature and pH-corrected 30-day chronic (salmonid fish present) National Recommended Water Quality Criteria14. Ambient concentrations were generally 1-2 orders of magnitude below those event-specific values.

3.3.3 Comparisons with Metals Water Quality Objectives

The majority of concentrations of trace metals were below their respective water quality objectives, as set by CTR water quality criteria and Basin Plan objectives, for both the American and Sacramento Rivers sites for 2013/2014. The two exceedances of water quality objectives for trace metals are summarized below.

The dissolved copper concentration on the American River at Discovery Park exceeded CTR freshwater aquatic life chronic criterion during event #209. The total lead concentration at Discovery Park also exceeded CTR freshwater aquatic life chronic criterion during event #209; however the dissolved lead concentration was below the criterion. All other metal levels measured at the sites in the American and Sacramento Rivers during 2013/2014 were below applicable CTR criteria and Basin Plan water quality objectives. 3.3.4 Comparisons with Microbiological Limits

Numbers of bacteria were compared to the Basin Plan water quality objective for fecal coliform bacteria of 400 Most Probable Number (MPN)/100 mL for the 90th percentile values. Indicator bacteria concentrations exceeding the water quality objective for fecal coliform occurred at Discovery Park during the first wet weather sampling event, #209 on 11/20/2013. Previous evaluations of the bacteria data have indicated that higher concentrations tend to occur during the wet season at all CMP sampling sites15.

The Regional Water Board updated the Basin Plan water quality objectives for bacteria to use E. coli as a pathogen indicator rather than fecal coliform. The Regional Water Board adopted the new water quality objectives, based on USEPA criteria, on 6 September 2002 in Resolution No. R5-2002-015016; however, the amendment still has not been approved by the State Board or Office of Administrative Law. Concentrations of E. coli were compared to the USEPA objective for E. coli of 235 MPN/100 mL for a single sample maximum17. E. coli

14 See http://water.epa.gov/scitech/swguidance/standards/criteria/aqlife/ammonia/upload/AQUATIC-LIFE-AMBIENT-WATER-QUALITY-CRITERIA-FOR-AMMONIA-FRESHWATER-2013.pdf.

15 Larry Walker Associates 2003. Sacramento Coordinated Water Quality Monitoring Program 2002-2003. Prepared for the Sacramento Regional County Sanitation District, Sacramento County Water Agency, and the City of Sacramento. November.

16 Central Valley Regional Water Quality Control Board 2002. Amendment To The Water Quality Control Plan For The Sacramento River And San Joaquin River Basins For Bacteria—Staff Report And Functional Equivalent Document. (DRAFT May 2002). See http://www.swrcb.ca.gov/rwqcb5/board_decisions/adopted_orders/resolutions/r5-2002-0150.pdf

17 US EPA (1986). Ambient Water Quality Criteria for Bacteria – 1986. EPA-440/5-84-002. Washington, DC: Office of Water. January 1986. Available at http://www.epa.gov/waterscience/beaches/files/1986crit.pdf.





3-19

concentrations exceeding 235 MPN/100 mL occurred during the first wet weather sampling event #209 on 11/20/2013 on the American River at Discovery Park and at Nimbus.

The Sacramento River at Veterans Bridge and Freeport, and the American River at Nimbus Dam did not have any fecal coliform or E. coli exceedances.

3.3.5 Comparisons with Pesticide Water Quality Objectives

All samples were below pesticide water quality objectives for 2013/2014. Although the organophosphates diazinon and chlorpyrifos have been infrequently detected in samples collected under the CMP, the pesticides are cited as causes for impaired Delta waterways and several urban runoff-affected waterbodies in the Sacramento area due to observed concentrations in previous years. Total Maximum Daily Loads addressing these pesticides have been completed. Diazinon is no longer registered for any urban uses, and registered chlorpyrifos urban uses are limited to only a few specialized types, resulting in a very small amount of total use within urban areas in Sacramento.

3.3.6 Comparison with Trace Organics Water Quality Objectives

There were exceedances of the CTR criteria for PAHs during two events. Chrysene exceeded the CTR human health criterion in the Sacramento River at Veterans Bridge during event #212 on 5/8/14, and multiple PAHs exceeded the CTR human health criteria in the American River at Discovery Park during event #211 on 2/27/2014. There were exceedances for benzo(a)pyrene, benz(a)anthracene, benzo(b)fluoranthene, benzo(k)fluoranthene, chrysene, and indeno(1,2,3-c,d)pyrene at Discovery Park during that event.

As pollutants, these compounds are of concern in drinking water as probable human carcinogens. Exceedances are not uncommon in urban waterways, where the average PAH flux from urban areas is up to 45 times as great as flux from undeveloped areas18. PAHs found in urban runoff are largely associated with combustion-derived particulate matter19.

3.4 Summary Statistics

Summary statistics for CMP data for the period December 1992 through June 2014 are presented in Tables 3-9 through 3-12. All constituents listed in Tables 3-2 through 3-5 included here. In addition to the four stormwater events conducted for the CMP during 2013/2014, the summary statistics include results from monthly monitoring conducted at Freeport during 2013 per requirements in SRCSD’s 2010 NPDES Permit.

For each water quality parameter measured by the CMP, the following statistics were calculated:

• Number of measurements (n); • Percent of measurements for which a measurable quantity was detected; • Number of measurements for which a measurable quantity was detected;

18 Stein, E.D., L.L. Tiefenthaler, and K. Schiff (2006). “Watershed-based sources of polycyclic aromatic hydrocarbons in urban storm water.” Enviro. Tox. & Chem., 25:373-385.

19 Stout, S.A., A.D. Uhlern, and S.D. Emsbo-Mattingly (2004). “Comparative evaluation of background anthropogenic hydrocarbons in surficial sediments from nine urban waterways.” Enviro. Sci. & Techn., 38:2987-2994.



3-20

• Mean and standard deviation; • Minimum and maximum detected values; and • Minimum and maximum reporting limits for data below detection.

If the dataset for a parameter contained no data below the reporting limits, the arithmetic mean and standard deviation were calculated using the complete dataset. If 80 to 99 percent of the data were above their respective reporting limits, distribution parameters were estimated using the Robust Lognormal Regression method (see following discussion). If less than 80% of the data were above their reporting limits, the program considered the dataset to have insufficient detected data available to reliably estimate the mean and standard deviation, and no additional statistics were calculated.

Split samples submitted as part of the QA/QC program are not used to calculate summary statistics. For cases where parameters were analyzed by more than one method (most commonly EPA 625 and 8260 for volatile organics), the most definitive results (e.g., the result from the method with the lowest detection limit) were used for plots and other analyses.

3.4.1 Treatment of Values below Reporting Limits

Summary statistics are computed using the Robust Lognormal Regression method when censored data were reported (i.e., data below program reporting limits). This method fits the detected values to a lognormal distribution, using the censored data to calculate cumulative distribution values for the detected data. Data below detection are assigned values based on the lognormal distribution regression statistics and distributional parameters (means and standard deviations) are calculated directly from the combined dataset of detected and synthetic data. In cases where more than 20% of the values are censored, the mean and standard deviation are not calculated because the dataset is considered insufficient to accurately estimate these statistics.



3-21

Table 3-6. Summary Statistics for the Sacramento River at Veterans Bridge

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e)

min det. (f)

max det. (g)

min reporting limit (h)

max reporting limit (i)

Ammonia (as N) mg/L 81 12% 10 id id 0.027 0.34 0.1 0.2 Arsenic (dissolved) ug/L 115 79% 91 1.34 0.50 0.29 3.4 0.15 1 Arsenic (total) ug/L 185 94% 173 1.71 0.51 0.7 3.63 0.15 1 Cadmium (dissolved) ug/L 170 52% 89 0.015 0.023 0.003 0.24 0.008 0.02 Cadmium (total) ug/L 183 86% 157 0.059 0.096 0.0072 0.74 0.008 0.1 Chloride mg/L 131 95% 124 5.68 2.18 2.2 14 1 3 Chromium (dissolved) ug/L 105 26% 27 0.29 0.40 0.02 2.1 0.03 1 Chromium (total) ug/L 186 85% 159 2.65 2.71 0.03 19.2 0.03 1 Copper (dissolved) ug/L 197 98% 193 1.50 0.57 0.33 5 0.04 0.5 Copper (total) ug/L 198 98% 195 4.02 2.45 0.72 18.3 0.04 0.51 Cyanide ug/L 28 7% 2 id id 1.16 5 3 5 Dissolved organic carbon mg/L 160 77% 123 2.77 1.61 0.7 10 0.2 1 Dissolved oxygen mg/L 205 100% 205 10.1 1.44 6.6 17 0.1 1 E. coli mpn/100

103 98% 101 53.2 164 2 1300 1.8 2

Electrical conductivity umhos/cm 210 100% 210 150 42.4 21.2 260 1 10 Fecal coliform mpn/100

147 99% 145 110 344 2 2400 1.8 2

Hardness mg/L 210 100% 209 62.1 26.4 28 350 4 16 Lead (dissolved) ug/L 178 50% 89 0.053 0.069 0.011 0.54 0.015 0.1 Lead (total) ug/L 198 95% 188 0.58 0.67 0.04 7.2 0.015 0.31 Mercury (dissolvedl) ng/L 185 89% 164 1.40 1.14 0.35 7.96 0.0005 0.5 Mercury (total) ng/L 202 98% 198 7.27 5.60 0.77 34.9 0.15 0.51 Methylmercury (dissolvedl) ng/L 78 64% 50 0.041 0.021 0.025 0.11 0.025 0.056 Methylmercury (unfiltered) ng/L 97 85% 82 0.093 0.043 0.02 0.21 0.025 0.056 Molybdenum (dissolved) ug/L 44 89% 39 0.55 0.25 0.22 1.1 0.02 0.3 Molybdenum (total) ug/L 51 90% 46 0.44 0.20 0.055 0.99 0.02 0.3 Nickel (dissolved) ug/L 164 79% 130 0.80 0.42 0.2 2.8 0.04 0.2 Nickel (total) ug/L 167 98% 163 4.67 4.36 0.43 28 0.04 0.5 Nitrate (as N) mg/L 84 75% 63 0.16 0.35 0.035 2.6 0.05 0.5 Nitrite (as N) mg/L 84 27% 23 0.013 0.031 0.0016 0.22 0.03 0.33 Orthophosphate (dissolved) mg/L 64 36% 23 0.07 0.022 0.015 0.16 0.05 0.1 pH pH Units 219 100% 219 7.61 0.39 6.2 8.94 0.01 1 Silver (dissolved) ug/L 45 13% 6 id id 0.001 0.049 0.015 0.02 Silver (total) ug/L 53 32% 17 0.0077 0.0065 0.0031 0.04 0.015 0.1 Specific conductance umhos/cm 8 100% 8 181 42.6 142 252 1 1 Temperature deg C 211 100% 211 14.9 4.48 6.51 25 0 0.1 Total coliform mpn/100

135 100% 135 1550 2896 17 16000 2 2

Total dissolved solids mg/L 107 98% 105 114 31.1 47 193 20 20 Total Kjeldahl nitrogen mg/L 83 77% 64 0.33 0.17 0.11 1 0.1 0.2 Total organic carbon mg/L 154 74% 114 2.86 1.66 0.52 9 0.2 1 Turbidity NTU 110 100% 110 27.5 34.5 1.5 200 1 1 UVA 254 cm-1 65 98% 64 0.076 0.062 0.014 0.31 0.0001 0.014 Zinc (dissolved) ug/L 191 60% 114 1.28 2.41 0.04 23 0.1 1 Zinc (total) ug/L 196 86% 169 6.54 6.02 0.49 39.2 0.1 1



3-22

Table 3-9. Summary Statistics for the Sacramento River at Veterans Bridge

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e)

min det. (f)

max det. (g)



2,4,6-trichlorophenol ng/L 59 0% 0 id id ND ND 2 100 Acenaphthene ng/L 75 4% 3 id id 0.34 1 0.005 5 Benz(a)anthracene ng/L 75 12% 9 id id 0.12 1.64 0.005 5 Benzo(a)pyrene ng/L 75 7% 5 id id 0.18 2.38 0.005 5 Benzo(b)fluoranthene ng/L 66 5% 3 id id 1.6 2.3 0.005 5 Benzo(b,j,k)fluoranthene ng/L 1 100% 1 0 0 0.32 0.32 0 0 Bifenthrin ng/L 21 5% 1 id id 0.2 0.2 0.5 2 Bis(2-ethylhexyl) phthalate ng/L 55 11% 6 id id 72.3 1190 1 125 Chlorpyrifos ng/L 124 3% 4 id id 0.2 1 0.002 2 Diazinon ng/L 151 8% 12 id id 0.3 160 0.004 1.5 Dibenz(a,h)anthracene ng/L 75 0% 0 id id ND ND 0.005 5 Fluoranthene ng/L 75 32% 24 1.34 6.14 0.41 40 0.005 5 Fluorene ng/L 75 8% 6 id id 0.38 1.7 0.005 5 Glyphosate ug/L 17 0% 0 id id ND ND 25 25 Hexachlorobenzene ng/L 63 2% 1 id id 1.11 1.11 1 62.5 Indeno(1,2,3-c,d)pyrene ng/L 75 8% 6 id id 0.39 4.4 0.005 5 Malathion ug/L 109 0% 0 id id ND ND 0.006 0.1 Methyl parathion ug/L 103 0% 0 id id ND ND 0.002 0.1 MTBE ug/L 29 10% 3 id id 0.51 0.7 0.5 0.5 Naphthalene ng/L 70 16% 11 id id 1 15.1 0.005 5 N-nitroso-di-n-propylamine ng/L 63 3% 2 id id 8.6 48.2 1 100 Parathion ug/L 102 0% 0 id id ND ND 0.02 0.1 Pentachlorophenol ng/L 62 3% 2 id id 2.5 257 1 100 Phenanthrene ng/L 66 18% 12 id id 1 4.68 0.005 5 (a) number of samples analyzed (b) percent of samples in which analyte was detected (c) number of samples in which analyte was detected (d) arithmetic mean value; "id" indicates insufficient detected data to calculate value (e) standard deviation of data; "id" indicates insufficient detected data to calculate value (f) minimum detected value reported, or ND if no detected values (g) maximum detected value reported, or ND if no detected values (h) minimum reporting limit for data below detection, or NA if all data above (i) maximum reporting limit for data below detection, or NA if all data above reporting limits



3-23

Table 3-7. Summary Statistics for the Sacramento River at Freeport Marina

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e) min det.

(f)

max det. (g)



Ammonia (as N) mg/L 79 22% 17 0.051 0.032 0.017 0.18 0.1 0.2 Arsenic (dissolved) ug/L 107 77% 82 1.20 0.46 0.6 2.9 0.15 1 Arsenic (total) ug/L 187 94% 175 1.51 0.45 0.53 3.6 0.15 1 Cadmium (dissolved) ug/L 165 46% 76 0.012 0.0095 0.003 0.06 0.008 0.02 Cadmium (total) ug/L 185 72% 134 0.049 0.25 0.01 2.5 0.008 0.25 Chloride mg/L 138 93% 129 5.29 1.99 2.1 11 1 3 Chromium (dissolved) ug/L 97 27% 26 0.29 0.44 0.11 2.25 0.03 1 Chromium (total) ug/L 186 85% 159 2.51 2.77 0.13 18.5 0.03 1 Copper (dissolved) ug/L 189 97% 183 1.45 0.57 0.27 5.1 0.04 0.5 Copper (total) ug/L 199 99% 197 3.71 2.63 0.89 20.4 0.04 0.51 Cyanide ug/L 36 8% 3 id id 0.77 5 3 5 Dissolved organic carbon mg/L 155 82% 127 2.73 1.60 1.1 11 0.2 1 Dissolved oxygen mg/L 201 100% 201 10.0 1.54 6.9 16 0.05 1 E. coli mpn/100 ml 103 99% 102 91.5 189 2 900 1.8 2 Electrical conductivity umhos/cm 204 100% 204 144 36.7 54 254 0.1 10 Fecal coliform mpn/100 ml 148 100% 148 209 874 2 8000 1.8 2 Hardness mg/L 213 100% 212 57.1 13.3 26 100 4 17 Lead (dissolved) ug/L 175 53% 93 0.06 0.12 0.006 1.2 0.015 0.1 Lead (total) ug/L 199 91% 181 0.55 0.55 0.017 3.71 0.015 0.51 Mercury (dissolvedl) ng/L 186 91% 169 1.46 1.59 0.26 14.92 0.0005 0.5 Mercury (total) ng/L 210 99% 207 6.8615 8.57 0.97 89.1 0.0002 0.51 Methylmercury (dissolvedl) ng/L 80 65% 52 0.047 0.026 0.009 0.171 0.025 0.056 Methylmercury (total) ng/L 100 86% 86 0.088 0.055 0.032 0.318 0.025 0.056 Molybdenum (dissolved) ug/L 44 84% 37 0.46 0.19 0.16 0.95 0.02 0.3 Molybdenum (total) ug/L 56 91% 51 0.44 0.16 0.11 0.81 0.02 0.3 Nickel (dissolved) ug/L 156 80% 125 0.76 0.43 0.075 2.5 0.04 0.2 Nickel (total) ug/L 168 96% 162 4.14 4.32 0.51 30.6 0.04 1 Nitrate (as N) mg/L 82 72% 59 0.13 0.083 0.023 0.42 0.05 0.1 Nitrite (as N) mg/L 82 24% 20 0.0078 0.016 0.002 0.1 0.03 0.1 Orthophosphate (dissolved) mg/L 71 44% 31 0.040 0.024 0.014 0.15 0.05 0.1 pH pH Units 212 100% 212 7.59 0.38 5.6 8.79 0.01 1 Silver (dissolved) ug/L 45 4% 2 id id 0.001 0.002 0.015 0.02 Silver (total) ug/L 61 25% 15 0.0067 0.005 0.003 0.026 0.015 0.25 Specific conductance umhos/cm 13 100% 13 162 38.8 123 239 1 1 Temperature deg C 207 100% 207 14.8 4.45 6.2 23.1 0 0.1 Total coliform mpn/100 ml 137 100% 137 2187 5805 13 50000 2 2 Total dissolved solids mg/L 114 98% 112 104 27.0 39 180 20 20 Total Kjeldahl nitrogen mg/L 78 79% 62 0.32 0.18 0.1 0.89 0.05 0.2 Total organic carbon mg/L 146 80% 117 2.82 1.63 1.2 8.3 0.2 0.5 Turbidity NTU 110 100% 110 20.6 31.0 2 250 1 1 UVA 254 cm-1 66 95% 63 0.070 0.06 0.024 0.37 0.0001 0.014 Zinc (dissolved) ug/L 182 69% 126 1.49 2.86 0.12 27 0.1 1 Zinc (total) ug/L 197 83% 164 5.71 5.79 0.74 39.6 0.1 1



3-24

Table 3-10. Summary Statistics for the Sacramento River at Freeport Marina

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e)

min det. (f)

max det. (g)



2,4,6-trichlorophenol ng/L 71 0% 0 id id ND ND 2 10000 Acenaphthene ng/L 87 8% 7 id id 0.35 5.2 0.005 1000 Anthracene ng/L 89 8% 7 id id 0.12 4.8 0.005 10000 Benz(a)anthracene ng/L 86 14% 12 id id 0.18 3.6 0.005 5000 Benzo(a)pyrene ng/L 86 6% 5 id id 0.29 2.5 0.005 10000 Benzo(b)fluoranthene ng/L 75 4% 3 id id 2.3 5.43 0.005 10000 Benzo(b,j,k)fluoranthene ng/L 1 0% 0 id id ND ND 0 0 Benzo(k)fluoranthene ng/L 75 3% 2 id id 2.7 3.1 0.005 10000 Bifenthrin ng/L 30 23% 7 0.23 0.23 0.1 1.1 0.5 2 Bis(2-ethylhexyl) phthalate ng/L 65 15% 10 id id 22.8 575 1 5000 Chlorpyrifos ng/L 132 6% 8 id id 0.3 150 0.002 2 Diazinon ng/L 158 8% 12 id id 0.3 140 0.004 1.5 Dibenz(a,h)anthracene ng/L 86 3% 3 id id 1.4 2.6 0.005 100 Fluoranthene ng/L 86 41% 35 1.82 3.62 0.54 27.2 0.005 1000 Fluorene ng/L 86 9% 8 id id 0.41 7.5 0.005 10000 Glyphosate ug/L 25 0% 0 id id ND ND 6 25 Hexachlorobenzene ng/L 74 4% 3 id id 0.43 1.17 1 1000 Indeno(1,2,3-c,d)pyrene ng/L 86 9% 8 id id 0.38 2.1 0.005 10000 Malathion ug/L 116 0% 0 id id ND ND 0.006 0.1 Methyl parathion ug/L 110 0% 0 id id ND ND 0.002 0.1 MTBE ug/L 37 11% 4 id id 0.43 2.3 0.5 0.5 Naphthalene ng/L 87 25% 22 2.03 3.81 1 25.5 0.005 1000 N-nitroso-di-n-propylamine ng/L 64 2% 1 id id 12 12 1 101 N-nitrosodi-n-propylamine ng/L 11 0% 0 id id ND ND 100 5000 Parathion ug/L 109 0% 0 id id ND ND 0.02 0.1 Pentachlorophenol ng/L 69 6% 4 id id 1.7 26 1 5000 Phenanthrene ng/L 75 31% 23 1.75 2.74 1.1 19.3 0.005 5000 (a) number of samples analyzed (b) percent of samples in which analyte was detected (c) number of samples in which analyte was detected (d) arithmetic mean value; "id" indicates insufficient detected data to calculate value (e) standard deviation of data; "id" indicates insufficient detected data to calculate value (f) minimum detected value reported, or ND if no detected values (g) maximum detected value reported, or ND if no detected values (h) minimum reporting limit for data below detection, or NA if all data above (i) maximum reporting limit for data below detection, or NA if all data above reporting limits



3-25

Table 3-8. Summary Statistics for the American River at Nimbus Dam

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e)

min det. (f)

max det. (g)



Ammonia (as N) mg/L 78 19% 15 id id 0.026 0.24 0.1 0.2 Arsenic (dissolved) ug/L 100 30% 30 0.33 0.15 0.2 1 0.15 1 Arsenic (total) ug/L 171 60% 103 0.40 0.32 0.03 2.9 0.15 1 Cadmium (dissolved) ug/L 153 39% 59 0.011 0.019 0.002 0.18 0.008 0.02 Cadmium (total) ug/L 168 48% 81 0.051 0.53 0.002 5.1 0.008 0.1 Chloride mg/L 121 45% 54 1.86 1.46 0.2 13 1 3 Chromium (dissolved) ug/L 102 17% 17 id id 0.02 0.87 0.03 1 Chromium (total) ug/L 179 55% 99 0.60 4.20 0.02 41 0.03 1 Copper (dissolved) ug/L 189 84% 158 0.61 0.29 0.13 1.9 0.04 0.5 Copper (total) ug/L 192 92% 177 0.81 0.51 0.24 4.3 0.04 0.51 Cyanide ug/L 28 11% 3 id id 1.1 5 3 5 Dissolved organic carbon mg/L 146 68% 99 1.87 0.75 0.7 4.6 0.2 1 Dissolved oxygen mg/L 205 100% 205 10.6 2.10 5.8 16 0.1 1 E. coli mpn/100 ml 100 100% 100 145 929 2 7000 1.8 2 Electrical conductivity umhos/cm 209 100% 209 56.6 15.8 4.3 123 0.1 10 Fecal coliform mpn/100 ml 143 100% 143 148 749 4 7000 1.8 2 Hardness mg/L 203 100% 202 25.7 9.74 4 74 1 12 Lead (dissolved) ug/L 159 35% 56 0.040 0.054 0.004 0.33 0.015 0.1 Lead (total) ug/L 189 71% 135 0.15 0.22 0.004 1.95 0.015 0.31 Mercury (dissolvedl) ng/L 184 85% 157 0.83 0.64 0.19 4.43 0.0005 0.5 Mercury (total) ng/L 197 96% 189 2.17 3.46 0.4 37 0.15 0.5 Methylmercury (dissolvedl) ng/L 77 30% 23 0.024 0.044 0.008 0.31 0.025 0.056 Methylmercury (total) ng/L 96 55% 53 0.040 0.051 0.015 0.41 0.025 0.056 Molybdenum (dissolved) ug/L 42 71% 30 0.20 0.051 0.12 0.31 0.02 0.3 Molybdenum (total) ug/L 49 76% 37 0.21 0.061 0.14 0.46 0.02 0.3 Nickel (dissolved) ug/L 101 57% 58 0.43 0.29 0.07 1.9 0.04 0.2 Nickel (total) ug/L 160 79% 126 1.096 2.96 0.21 30 0.04 0.5 Nitrate (as N) mg/L 81 49% 40 0.066 0.15 0.0064 1.1 0.05 0.1 Nitrite (as N) mg/L 81 15% 12 id id 0.0013 0.1 0.03 0.1 Orthophosphate (dissolved) mg/L 61 16% 10 id id 0.0039 0.05 0.05 0.1 pH pH Units 219 100% 219 7.24 0.57 5.82 9.4 0 1 Silver (dissolved) ug/L 43 7% 3 id id 0.002 0.002 0.015 0.02 Silver (total) ug/L 51 12% 6 id id 0.001 0.071 0.015 0.1 Specific conductance umhos/cm 8 100% 8 76.2 11.3 62 94 1 1 Temperature deg C 212 100% 212 13.5 3.67 7.04 23 0 0.1 Total coliform mpn/100 ml 132 100% 132 606 974 13 7000 2 2 Total dissolved solids mg/L 103 96% 99 50.1 20.4 13 150 20 20 Total Kjeldahl nitrogen mg/L 79 76% 60 0.24 0.20 0.068 1.1 0.1 0.2 Total organic carbon mg/L 143 67% 96 2.04 0.82 0.93 6.4 0.2 1 Turbidity NTU 71 97% 69 2.96 4.65 0.85 33 1 1 UVA 254 cm-1 63 97% 61 0.040 0.019 0.014 0.14 0.0001 0.014 Zinc (dissolved) ug/L 185 58% 107 0.87 1.76 0.04 16 0.1 1 Zinc (total) ug/L 187 67% 126 2.69 7.41 0.1 60 0.1 1



3-26

Table 3-11. Summary Statistics for the American River at Nimbus Dam

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e) min det.

(f)

max det. (g)



2,4,6-trichlorophenol ng/L 61 0% 0 id id ND ND 2 103 Acenaphthene ng/L 74 3% 2 id id 0.56 1.5 0.005 5.15 Anthracene ng/L 77 3% 2 id id 0.28 0.36 0.005 5.15 Benz(a)anthracene ng/L 74 4% 3 id id 0.25 2.4 0.005 5.15 Benzo(a)pyrene ng/L 74 0% 0 id id ND ND 0.005 5.15 Benzo(b)fluoranthene ng/L 65 0% 0 id id ND ND 0.005 5.15 Benzo(b,j,k)fluoranthene ng/L 1 0% 0 id id ND ND 0 0 Benzo(k)fluoranthene ng/L 65 0% 0 id id ND ND 0.005 5.15 Bifenthrin ng/L 21 10% 2 id id 0.1 1.2 0.5 2 Bis(2-ethylhexyl) phthalate ng/L 54 15% 8 id id 109 148000 1 129 Chlorpyrifos ng/L 119 3% 4 id id 0.2 1.4 0.002 2 Diazinon ng/L 146 2% 3 id id 0.2 90 0.004 1.5 Dibenz(a,h)anthracene ng/L 74 1% 1 id id 0.35 0.35 0.005 5.15 Fluoranthene ng/L 74 20% 15 id id 0.32 53.1 0.005 5.15 Fluorene ng/L 74 9% 7 id id 0.22 1.3 0.005 5.15 Glyphosate ug/L 18 0% 0 id id ND ND 4.6 25 Hexachlorobenzene ng/L 62 5% 3 id id 0.27 1.1 1 62.5 Indeno(1,2,3-c,d)pyrene ng/L 74 4% 3 id id 0.22 2.3 0.005 5.15 Malathion ug/L 103 0% 0 id id ND ND 0.006 0.1 Methyl parathion ug/L 98 0% 0 id id ND ND 0.002 0.1 MTBE ug/L 29 14% 4 id id 0.26 0.85 0.5 0.5 Naphthalene ng/L 69 19% 13 id id 1.7 7.2 0.005 5.15 N-nitroso-di-n-propylamine ng/L 62 0% 0 id id ND ND 1 103 Parathion ug/L 97 0% 0 id id ND ND 0.02 0.1 Pentachlorophenol ng/L 62 3% 2 id id 4.5 4.6 1 103 Phenanthrene ng/L 65 15% 10 id id 1 3.5 0.005 5.15 (a) number of samples analyzed (b) percent of samples in which analyte was detected (c) number of samples in which analyte was detected (d) arithmetic mean value; "id" indicates insufficient detected data to calculate value (e) standard deviation of data; "id" indicates insufficient detected data to calculate value (f) minimum detected value reported, or ND if no detected values (g) maximum detected value reported, or ND if no detected values (h) minimum reporting limit for data below detection, or NA if all data above (i) maximum reporting limit for data below detection, or NA if all data above reporting limits



3-27

Table 3-9. Summary Statistics for the American River at Discovery Park

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e)

min det. (f)

max det. (g)



Ammonia (as N) mg/L 79 19% 15 id id 0.029 0.16 0.1 0.2 Arsenic (dissolved) ug/L 104 33% 34 0.41 0.26 0.16 1.82 0.15 1 Arsenic (total) ug/L 176 60% 106 0.41 0.28 0.02 2.9 0.15 1 Cadmium (dissolved) ug/L 164 43% 71 0.011 0.022 0.002 0.23 0.008 0.02 Cadmium (total) ug/L 173 53% 91 0.047 0.32 0.003 3.3 0.008 0.02 Chloride mg/L 124 46% 57 2.25 1.07 1 10 1 3 Chromium (dissolved) ug/L 106 18% 19 id id 0.02 0.55 0.03 1 Chromium (total) ug/L 182 55% 100 0.45 0.62 0.03 6.4 0.03 1 Cyanide ug/L 27 7% 2 id id 0.88 5 3 5 Dissolved organic carbon mg/L 148 69% 102 2.27 1.30 0.9 12 0.2 1 Dissolved oxygen mg/L 214 100% 214 10.3 1.65 6.18 18 0.05 1 E. coli mpn/100 ml 103 100% 103 513 2028 2 16000 1.8 2 Electrical conductivity umhos/cm 27 100% 27 67.7 14.9 44 110 1 1 Fecal coliform mpn/100 ml 146 100% 146 845 2752 2 16000 1.8 2 Hardness mg/L 207 99% 205 25.7 8.47 14 70 2 16 Lead (dissolved) ug/L 175 51% 89 0.058 0.11 0.01 1.1 0.015 0.1 Lead (total) ug/L 193 90% 173 0.27 0.32 0.03 2.36 0.015 0.31 Mercury (dissolvedl) ng/L 182 86% 156 1.12 1.17 0.07 11.3 0.0005 0.5 Mercury (total) ng/L 200 97% 195 3.27 12.9 0.078 139 0.15 0.51 Methylmercury (dissolvedl) ng/L 80 53% 42 0.031 0.019 0.011 0.11 0.025 0.056 Methylmercury (total) ng/L 98 81% 79 0.064 0.086 0.016 0.714 0.025 0.056 Molybdenum (dissolved) ug/L 44 70% 31 0.22 0.11 0.15 0.69 0.02 0.2 Molybdenum (total) ug/L 51 80% 41 0.21 0.080 0.06 0.46 0.02 0.2 Nickel (dissolved) ug/L 105 53% 56 0.42 0.21 0.09 1.1 0.04 0.2 Nickel (total) ug/L 165 80% 132 0.92 1.02 0.18 8 0.04 0.2 Nitrate (as N) mg/L 83 51% 42 0.068 0.069 0.0025 0.46 0.05 0.5 Nitrite (as N) mg/L 83 24% 20 0.015 0.058 0.0019 0.42 0.03 0.33 Orthophosphate (dissolved) mg/L 62 21% 13 0.028 0.11 0.0045 0.64 0.05 0.1 pH pH Units 219 100% 219 7.44 0.42 6.37 8.62 0 1 Silver (dissolved) ug/L 45 9% 4 id id 0.001 0.016 0.015 0.02 Silver (total) ug/L 53 13% 7 id id 0.001 0.004 0.015 0.02 Specific conductance umhos/cm 8 100% 8 72.1 11.3 57 91 1 1 Temperature deg C 217 100% 217 14.0 3.95 7.56 24.4 0 0.1 Total coliform mpn/100 ml 135 100% 135 4478 18334 17 160000 2 2 Total dissolved solids mg/L 105 96% 101 52.6 20.4 16 140 20 20 Total Kjeldahl nitrogen mg/L 80 71% 57 0.26 0.17 0.062 0.97 0.05 0.5 Total organic carbon mg/L 146 67% 98 2.46 1.47 1.1 12 0.2 0.5 Turbidity NTU 107 100% 107 5.04 4.96 0.2 25 1 1 UVA 254 cm-1 64 100% 64 0.044 0.015 0.022 0.087 0.0001 0.014 Zinc (dissolved) ug/L 189 60% 113 1.19 1.89 0.03 11 0.1 1 Zinc (total) ug/L 194 69% 134 4.85 21.6 0.15 230 0.1 1



3-28

Table 3-12. Summary Statistics for the American River at Discovery Park

Parameter Unit

n

(a) % det.

(b) n det.

(c) mean

(d) std dev

(e)

min det. (f)

max det. (g)



2,4,6-trichlorophenol ng/L 58 2% 1 id id 0.29 0.29 2 100 2,4,6-trichlorophenol

ng/L 1 0% 0 id id ND ND 0 0

Acenaphthene ng/L 74 8% 6 id id 0.72 1.5 0.005 5 Anthracene ng/L 78 6% 5 id id 0.3 1.6 0.005 5 Benz(a)anthracene ng/L 74 23% 17 0.65 1.18 0.11 7 0.005 5 Benzo(a)pyrene ng/L 74 11% 8 id id 0.27 10 0.005 5 Benzo(b)fluoranthene ng/L 65 8% 5 id id 1.04 20 0.005 5 Benzo(b,j,k)fluoranthene ng/L 1 0% 0 id id ND ND 0 0 Benzo(k)fluoranthene ng/L 65 6% 4 id id 1.3 5 0.005 5 Bifenthrin ng/L 21 52% 11 1.26 2.09 0.1 7.3 0.5 2 Bis(2-ethylhexyl) phthalate ng/L 54 17% 9 id id 101 4220 1 584 Chlorpyrifos ng/L 120 4% 5 id id 0.2 4 0.002 2 Diazinon ng/L 146 10% 15 id id 0.2 100 0.004 1.5 Dibenz(a,h)anthracene ng/L 74 4% 3 id id 0.33 2.45 0.005 5 Fluoranthene ng/L 74 50% 37 2.33 2.53 0.52 10 0.005 5 Fluorene ng/L 74 16% 12 id id 0.32 2.9 0.005 5 Glyphosate ug/L 18 0% 0 id id ND ND 25 25 Hexachlorobenzene ng/L 62 5% 3 id id 0.81 1.3 1 62.5 Indeno(1,2,3-c,d)pyrene ng/L 74 12% 9 id id 0.36 10 0.005 5 Malathion ug/L 105 0% 0 id id ND ND 0.006 0.1 Methyl parathion ug/L 98 0% 0 id id ND ND 0.002 0.1 MTBE ug/L 29 10% 3 id id 0.47 0.55 0.5 0.5 Naphthalene ng/L 69 20% 14 id id 1.2 17.3 0.005 5 N-nitroso-di-n-propylamine ng/L 62 2% 1 id id 13 13 1 100 Parathion ug/L 99 0% 0 id id ND ND 0.02 0.1 Pentachlorophenol ng/L 59 7% 4 id id 0.95 26 1 100 Phenanthrene ng/L 65 29% 19 2.03 2.10 1.3 8.8 0.005 5 (a) number of samples analyzed (b) percent of samples in which analyte was detected (c) number of samples in which analyte was detected (d) arithmetic mean value; "id" indicates insufficient detected data to calculate value (e) standard deviation of data; "id" indicates insufficient detected data to calculate value (f) minimum detected value reported, or ND if no detected values (g) maximum detected value reported, or ND if no detected values (h) minimum reporting limit for data below detection, or NA if all data above (i) maximum reporting limit for data below detection, or NA if all data above reporting limits

A-1

Appendix A. Data Evaluation and Validation (July 2013 – June 2014) Quality Assurance / Quality Control (QA/QC) data for CMP monitoring Events #209, #210,

#211, and #212, collected between July 2013 and June 2014, are reviewed in this appendix.

All data were evaluated using the automated data checker and validation software program,

ADR.net, discussed in Section 2. Sample results were reviewed for conformance with

recommended allowable holding times for specific analyses and for compliance with CMP

data quality objectives (DQOs) for laboratory and external QA/QC results. Internal

laboratory QA/QC data reviewed include results for method and reagent blanks, laboratory

control samples, laboratory duplicates, surrogate recoveries, matrix spikes and matrix spike

duplicates. Field and external laboratory QA/QC data reviewed include results for field and

equipment blanks and field duplicates. CMP specifications for data quality are summarized

in Table A-1. A summary of the QA/QC checks performed for the CMP data validation is

presented in Figure A-1 (LWA, 2003). The flow chart illustrates how QA/QC samples and

specific steps in the data review procedures are used to evaluate the quality of data produced

by the CMP. Additional checks included comparison of total and dissolved parameters,

method detection limits (MDLs) versus reporting limits (RLs) and temperature of the sample.

Table A-1 Summary of QA/QC Samples and Program Specifications for 2012-2013

QA/QC Sample Type Parameter Evaluated

Source of Contamination or Variation

CMP QA/QC Specifications

Field Blanks Contamination Sampling and equipment < Reporting limit

Method or Preparation Blanks Contamination Blank water < Reporting limit

Field Duplicate Samples Precision Sample handling ≤ 50% RPD

Method Blanks Contamination Analytical procedures < Reporting limit

Lab Control Samples Accuracy Analytical procedures 80 – 120% Recovery(1)

Lab Control Sample Duplicates Precision Analytical procedures ≤ 25% RPD(1)

Surrogate Accuracy Matrix effects 30 – 150%

Matrix Spikes Accuracy Matrix effects 80 – 120% Recovery(1)

Matrix Spike Duplicates Precision Matrix effects ≤ 25% RPD(1) (1) Data quality objectives for trace organic and pesticide analyses are specific to each analyte and are documented in data

reports from each analyzing laboratory. RPD = Relative Percent Difference.

Appendix A Data Evaluation and Validation

A-2

Figure A-1. CMP General QA/QC Review Procedures

YES

YES

YES

YES

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

NO

YES

YES

YES

YES

YES

YES

YES

YES

YES

Holding time

compliance?

Batch QC

adequate?

Method blanks ND

or within project specs?

Are sample results

ND or > 5 x blank?

Is measured difference

between samples less

than the reporting limit?

Is measured difference

between samples less

than the reporting limit?

Are sample results

ND or > 5 x blank?

Lab duplicate RPDs

within project specs?

MS/MSD recoveries and

RPDs within project specs?

LCS and SRM recoveries

within project specs?

Field and equipment blanks

ND or within project specs?

Field duplicate sample

RPDs within project specs?

Do overall QC results indicate

no systematic problems?

Data Evaluations Data Qualifications

Qualify results as estimated if holding

time variance allowed, or reject results.

Determine impact on data quality

assessment and validity; qualify data

and initiate corrective action.

Results qualified as

ND at reported value

Results qualified as

ND at reported value

No qualification

No qualification

No qualification

No qualification

Qualify sample results

as not reproducible due

to analytical variability.

Check LCS results; if acceptable,

qualify associated samples as

estimated due to matrix interference.

Qualify sample results as

potentially biased in

direction of recovery bias.

Qualify results

as estimated.

Make additional qualifications as

necessary by matrix, method, etc.

Unqualified data, no limitations on use


A-3

The CMP reviewed and evaluated 1,644 individual results generated between July 2013 and

June 2014. Data qualifications were required for 619 analytical results, leaving 1,025 results

not qualified for an overall analytical success rate of 62.3% for Events #209 through #212.

Table A-2 summarizes the data qualification by analyte name or analyte category. Results

above the Method Detection Limit but below the Reporting Limit are not included in the

number of analytes qualified. This modification is made since values below the Reporting

Limit are considered to have less impact on the overall quality of data. None of the 1,644

results were rejected as shown in Table A-3. Therefore, 100% of the data are considered

valid and are incorporated into the database. The accuracy and precision of CMP data

generally achieved the established DQOs and no systematic problems with sampling or

analytical procedures were found.

Table A-2 Summary of Qualified Data for Events #209 through #212

Analyte Type Lab Analysis

Method ID

Number of

Analytes

Number

Qualified

Percent Not

Qualified

Electrical Conductivity 120.1 16 0 100

Methyl Mercury 1630 24 5 79.2

Mercury 1631 24 0 100

Turbidity 180.1 16 0 100

Trace Metals 200.8 176 21 88.1

Ammonia (as N) 350.1 20 2 90

Total Kjeldahl Nitrogen 351.2 20 4 80

Nitrate/Nitrite 353.2 40 2 95

Total Phosphorus 365.4 20 2 90

Organophosphorus Pesticides 614 160 89 44.4

Semi-Volatile Organic Compounds 625 600 364 39.3

Total Petroleum Hydrocarbons - Gasoline 8015 16 2 87.5

Total Petroleum Hydrocarbons - Diesel/Motor

Oil 8015M 32 1 96.9

Pyrethroids 8270 Mod (GCMS-

NCI-SIM) 200 113 43.5

Dissolved Oxygen ASTM D-888-09

YSI 16 0 100

Chemical Oxygen Demand HA 8000 20 4 80

Total Alkalinity SM 2320B 20 0 100

Hardness SM 2340 C 20 0 100

Total Dissolved Solids SM 2540C 20 0 100

Total Suspended Solids SM 2540D 20 0 100

Temperature SM 2550 B 16 0 100

Chloride SM 4500-CL-E 20 6 70

pH SM 4500-H+-B 16 0 100

Total Nitrogen (as N) SM 4500-N 20 4 80

Biochemical Oxygen Demand SM 5210B 20 0 100

Total Organic Carbon/ Dissolved Organic

Carbon SM 5310B 40 0 100

Fecal Coliform SM 9221 E 16 0 100

E. coli SM 9221 F 16 0 100

TOTAL 1,644 619 62.3


A-4

Table A-3 Summary of Rejected Data for Events #209 through #212

Analyte Type Lab Analysis

Method ID

Number of

Analytes

Rejected

Data

Percent

Accepted

Electrical Conductivity 120.1 16 0 100

Methyl Mercury 1630 24 0 100

Mercury 1631 24 0 100

Turbidity 180.1 16 0 100

Trace Metals 200.8 176 0 100

Ammonia (as N) 350.1 20 0 100

Total Kjeldahl Nitrogen 351.2 20 0 100

Nitrate/Nitrite 353.2 40 0 100

Total Phosphorus 365.4 20 0 100

Organophosphorus Pesticides 614 160 0 100

Semi-Volatile Organic Compounds 625 600 0 100

Total Petroleum Hydrocarbons - Gasoline 8015 16 0 100

Total Petroleum Hydrocarbons - Diesel/Motor

Oil 8015M

32

0 100

Pyrethroids 8270 Mod (GCMS-

NCI-SIM)

200

0 100

Dissolved Oxygen ASTM D-888-09

YSI

16

0 100

Chemical Oxygen Demand HA 8000 20 0 100

Total Alkalinity SM 2320B 20 0 100

Hardness SM 2340 C 20 0 100

Total Dissolved Solids SM 2540C 20 0 100

Total Suspended Solids SM 2540D 20 0 100

Temperature SM 2550 B 16 0 100

Chloride SM 4500-CL-E 20 0 100

pH SM 4500-H+-B 16 0 100

Total Nitrogen (as N) SM 4500-N 20 0 100

Biochemical Oxygen Demand SM 5210B 20 0 100

Total Organic Carbon/ Dissolved Organic

Carbon SM 5310B

40

0 100

Fecal Coliform SM 9221 E 16 0 100

E. coli SM 9221 F 16 0 100

TOTAL 1,644 0 100

Table A-4 lists all Sample Delivery Groups (SDGs) reported between November 2013 and

May 2014, along with the associated events and laboratories. The results qualified per SDG,

along with the associated reason code are summarized in Table A-13. A description of the

reason codes applied to this data can be found in Table A-14.

Table A-4 SDGs for Events #209 through #212

Event Lab Sample Delivery Group (SDG)

#209 SRCSD 53162 Caltest N110830

#210 SRCSD 53864 Caltest P020495




A-5

Holding Times Holding times were reviewed from: (1) collection to analysis, (2) collection to extraction, and

(3) extraction to analysis. Allowable holding times ranged from six hours for microbiological

analyses to six months for metals and hardness (after preservation).

For CMP Event #209, a total of 150 SVOC results, analyzed by method 625 were qualified

as estimated or non-detect estimated due to exceedance of the 7-day extraction holding time.

Qualified results are presented in Table A-5.

Table A-5 Summary of Qualified Data due to Exceeded Holding Times

Event(s) Analyte Total Number of Qualified

Results Included Number of FD

or EB

#209 SVOCs 150 50 TOTAL 150 50

Data with reason code D are listed in Table A-13. Overall, these results indicate that the

integrity and representativeness of the water quality samples is not a significant problem and

were adequate to produce reliable data.

Sample Temperature A review of cooler temperatures was performed based on data provided in the laboratory

electronic data deliverable. All cooler temperatures met data review criteria (4 + 2 ˚C).

Laboratory Method Blanks Laboratory method blanks were analyzed to evaluate the potential for contamination

attributable to analytical reagents and sample processing. The CMP DQO for laboratory

method blanks was defined as below the reporting limit. The analyte concentrations in the

samples were compared to the analyte concentrations detected in the method blanks. Positive

sample results were not qualified unless the concentration was less than or equal to ten times

the concentration found in the associated blank for the common contaminants, or five times

the concentration for the other contaminants on the target analyte list.

For CMP Events #209 through #212, a total of 16 results were qualified as non-detect (U)

due to method blank contamination. The qualified results, summarized in Table A-6 were

associated with samples analyzed by methods 200.8, 625, 8270 modified, and Standard

Method 4500-CL-E.

Table A-6 Summary of Qualified Data due to Laboratory Method Blanks



or EB

#209 Naphthalene 3 1

#210 Chloride 3 1 L-Cyhalothrin 1 0 Zinc 6 2

#211 Chloride 1 0 #212 Chloride 2 0 TOTAL 16 4

Data with reason code F are listed in Table A-13. Overall, these results indicate that

laboratory contamination of water quality samples is not a significant problem.


A-6

Laboratory Control Samples Laboratory control samples (LCS) were analyzed to evaluate analytical accuracy in the

absence of matrix effects. The CMP DQO for laboratory control sample recoveries was

defined as the range between 80% and 120% for all parameters, with the exception of trace

organic compounds and pesticides, which have recovery targets specific to each individual

analyte. If recoveries are outside the desired range, associated samples results are qualified as

estimated with a low or high bias as indicated by the LCS recovery.

Percent recovery of LCS is calculated as:

% Recovery = 100% x (measured concentration / expected concentration)

For CMP Events #209 through #212, a total of 88 organophosphorous (OP) pesticide results,

analyzed by method 614; 189 SVOC results, analyzed by method 625; and 108 pyrethroid

results, analyzed by method 8270 modified were qualified as estimated or non-detect

estimated due to LCS recoveries outside QC limits. Qualified results are presented in Table

A-7.

Table A-7 Summary of Qualified Data due to Laboratory Control Samples

Event # Analyte Type

Total Number of Qualified Results

Included Number of FD

or EB

#209 OP Pesticides 36 0 SVOCs 8 3 Pyrethroids 20 0




TOTAL 385 63

Data with reason code J are listed in Table A-13. Overall, these results indicate that

analytical accuracy was adequate for analysis of water quality samples.

Laboratory Control Sample Duplicates Analyses of LCS duplicates (LCSDs) were performed to evaluate analytical precision. The

CMP DQO for laboratory control sample duplicates was defined as relative percent

differences (RPD) of less than or equal to 25%. In the cases where RPD values exceeded

criteria, the results of the associated analytical batch were qualified. RPD for laboratory

control sample duplicates is calculated using recovered spike concentrations:

RPD = 100% x |spike 1 – spike 2| / average of spike 1 and spike 2

Where spike = measured spiked concentration.


A-7

For CMP Event #212, a total of 42 SVOC results, analyzed by method 625 were qualified as

non-detect estimated due to LCSD RPDs outside QC limits. Qualified results are presented in

Table A-8.

Table A-8 Summary of Qualified Data due to Laboratory Control Sample Duplicates




or EB

#212 SVOCs 42 14 TOTAL 42 14

Data with reason code K are listed in Table A-13. Overall, these results indicate that

analytical accuracy was adequate for analysis of water quality samples.

Laboratory Duplicates Analysis of duplicate samples was conducted to evaluate analytical precision. The CMP

DQO for laboratory duplicates was defined as RPD values of less than or equal to 25%. If

laboratory duplicate results are outside this range, associated samples results are qualified as

estimated due to analytical variability. An RPD greater than 25% was not considered cause

for qualification of data if measured differences between replicates were less than the

reporting limit, or if matrix spike duplicate results were acceptable. The RPD of laboratory

duplicate analyses is calculated using sample results rather than spike recoveries, with the

following formula:

RPD = 100% x |replicate 1 – replicate 2|/ average of replicate 1 and replicate 2

All RPD values for laboratory duplicates met data review criteria for CMP Events #209

through #212.

Matrix Spike Recoveries Analyses of matrix spike (MS) samples were performed to evaluate the effect of sample

matrix on analytical accuracy. MS sample analysis provides information regarding the effect

of the sample matrix on sample extraction and analysis. The CMP DQO for matrix spike

recoveries was defined as the range between 80% and 120% for all parameters. When a MS

does not meet DQOs, associated sample results are qualified as estimated due to matrix

interference. Percent recovery of matrix spikes is calculated as:

% Recovery = 100% x (Spiked concentration - Sample concentration)/ Spike added

For CMP Events #209 through #212, a total of 5 methyl mercury results, analyzed by method

1630; 20 OP pesticide results, analyzed by method 614; 41 SVOC results, analyzed by

method 625; 27 pyrethroid results, analyzed by method 8270 modified; two TPH-gasoline

results, analyzed by method 8015; and one TPH-diesel result, analyzed by method 8015M

were qualified as estimated or non-detect estimated due to MS recoveries outside control

limits. Qualified results are presented in Table A-9.


A-8

Table A-9 Summary of Qualified Data due to Matrix Spike Samples




or EB

#209 OP Pesticides 7 0 TPH-diesel 1 0


#211

Methyl Mercury 5 1 OP Pesticides 1 0 SVOCs 18 0 TPH-gasoline 1 0 Pyrethroids 6 0

#212

OP Pesticides 2 0 SVOCs 12 0 TPH-gasoline 1 0 Pyrethroids 10 0

TOTAL 96 1

Individual analytes flagged with reason code H for matrix spike recoveries are included in

Table A-13. MS recoveries outside acceptance criteria may indicate poor analytical

technique and/or sample matrix effects that may interfere with accurate analyses.

With the exception of the results qualified in Table A-13, the MS data in combination with

the LCS results indicate that matrix interference did not represent a significant problem and

that analytical accuracy was adequate to produce reliable data for water quality samples.

Matrix Spike Duplicates Analyses of matrix spike duplicate (MSD) samples were performed to evaluate the effect of

sample matrix on analytical precision. The CMP DQO for MSDs was defined as RPD values

of less than or equal to 25%. If MSD results are outside this range, associated samples results

are qualified as estimated due to matrix variability. RPD for matrix spike duplicates is

calculated in the same manner as for laboratory duplicates, using recovered spike

concentrations instead of measured sample results:

RPD = 100% x |spike 1 – spike 2| / average of spike 1 and spike 2

Where spike = measured spiked concentration minus measured sample concentration.

For CMP Event #209, #211, and #212, MS/MSD RPDs for 9 SVOC results, analyzed by

method 625 and 4 pyrethroid results, analyzed by method 8270 modified were outside QC

criteria. Since the RPDs were biased high and the sample results were reported as non-detect,

no data was qualified.

Surrogate Recoveries Analyses of surrogate recoveries were performed to evaluate laboratory performance and

accuracy. Surrogates are compounds which are similar in chemical composition and behavior

in the analytical process, but which are not normally found in environmental samples.

Surrogates provide information about both the laboratory performance on individual samples

and the possible effects of the sample matrix on the analytical results. Results were qualified

as estimated in accordance with the CMP DQO when surrogate recoveries were:

Greater than 150% or


A-9

Less than 30%.

Surrogate recoveries outside of the control limits are qualified as estimated (J) or non-detect

estimated (UJ). Surrogate recoveries less than 10% are qualified as rejected or unusable (R).

Percent recovery of surrogates is calculated as:

% Recovery = 100% x (measured value / expected value)

For CMP Event #211, a total of 25 SVOC results, analyzed by method 625 were qualified as

estimated or non-detect estimated due to surrogates recoveries outside control limits.

Qualified results are presented in Table A-10.

Table A-10 Summary of Qualified Data due to Surrogate Recoveries




or EB

#211 SVOC 25 0 TOTAL 25 0

Data with reason code G are listed in Table A-13. Overall, these results indicate that

analytical accuracy and/or sample matrix effects that may interfere with accurate analyses

was adequate for analysis of water quality samples.

Equipment Blanks Equipment blanks were submitted and analyzed to evaluate the potential for sampling

equipment to contaminate water quality samples. The CMP DQO for equipment blanks was

defined as below the analytical reporting limit. The analyte concentrations in the samples

were compared to the analyte concentrations detected in the field and equipment blanks.

Positive sample results were not qualified unless the concentration was less than or equal to

10 times the concentration found in the associated blank for the common contaminants, or

five times the concentration for the other contaminants on the target analyte list.

A total of 6 trace metals results, analyzed by method 200.8 were qualified as non-detect (U)

due to equipment blank contamination. The equipment blanks were collected during Events

#209, #210, #211, and #212. These data are flagged with the reason code N in Table A-11.

Results of analyses of equipment blanks indicate the equipment was generally adequate to

prevent detectable or significant levels of contamination of water quality samples collected.

Table A-11 Summary of Qualified Data due to Equipment Blanks



#209 Zinc 1 0

#210 Copper 1 0 Zinc 1 0

#211 Zinc 2 1 #212 Zinc 1 0 TOTAL 6 1

Data with reason code N are listed in Table A-13. Overall, these results indicate that the

equipment blank contamination of water quality samples is not a significant problem.


A-10

Field Duplicates The purpose of field duplicate samples is to measure the reproducibility of analyte

concentrations in field samples split from the same composite or grab sample. The results

provide a measure of the variability attributable to sample handling and aliquoting

procedures after sample collection. The CMP DQO for field duplicates (splits) was defined

as RPD values of less than or equal to 50%. Duplicate RPD values outside this range are

considered outliers due to sample variability, but they are not qualified data. An RPD greater

than 50% was not considered cause for qualification of data if measured differences between

replicates were less than the reporting limit. RPD is calculated in the same manner as

described above for laboratory duplicates.

For CMP Events #209 through #212, a total of 14 trace metals results, analyzed by method

200.8; two ammonia (as N) results, analyzed by method 350.1; 4 total kjehldahl nitrogen

results, analyzed by 351.2; two nitrite results, analyzed by method 353.2; two total

phosphorus results, analyzed by method 365.4; 8 SVOC results, analyzed by method 625; 4

chemical oxygen demand results, analyzed by HA 8000; and 4 total nitrogen (as N) results,

analyzed by Standard Method 4500-N were qualified as estimated or non-detect estimated

due to field duplicate RPD values exceeding 50%. Qualified results are presented in Table

A-12.

Table A-12 Summary of Outlier Data Field Duplicates

Event # Location Method ID Analyte Total Outliers

#209 Discovery 200.8 Copper (Dissolved) 1

200.8 Lead (Dissolved) 1

HA 8000 Chemical Oxygen Demand 1

#210 Nimbus

200.8 Copper (Dissolved) 1

200.8 Zinc (Dissolved) 1

200.8 Zinc (Total) 1

351.2 Total Kjehldahl Nitrogen 1

HA 8000 Chemical Oxygen Demand 1

SM 4500-N Total Nitrogen (as N) 1

#211 Freeport

200.8 Zinc (Dissolved) 1

200.8 Zinc (Total) 1

350.1 Ammonia (as N) 1

#212 Veterans 351.2 Total Kjehldahl Nitrogen 1

353.2 Nitrite 1

365.4 Total Phosphorus 1

625 SVOCs 4

SM 4500-N Total Nitrogen (as N) 1


A-11

These data are flagged with the reason code P in Table A-13. These results indicated that

sampling and handling procedures were generally adequate for all parameters.

A-12

Table A-13 Overall Qualified Results for Events #209 - #212

Sample Lab Unc / Overall Reason Analytical Method Field Sample ID Matrix Type Analyte RL Result Error Qualifier Units Code

SDG: 53162

200.8 Discovery AQ N Copper 0.50 3.0 J ug/L P Lead 0.10 0.15 J ug/L P 200.8 Discovery FD AQ FD Copper 0.50 1.5 J ug/L P Lead 0.10 0.081J J ug/L L,P 200.8 Nimbus AQ N Zinc 1.0 2.7 U ug/L N 350.1 Discovery AQ N Ammonia as Nitrogen 0.10 0.059J J mg/L L 350.1 Discovery FD AQ FD Ammonia as Nitrogen 0.10 0.063J J mg/L L 353.2 Discovery AQ N Nitrite 0.10 0.0094J J mg/L L 353.2 Discovery FD AQ FD Nitrite 0.10 0.0071J J mg/L L 353.2 Freeport AQ N Nitrite 0.10 0.0024J J mg/L L 353.2 Nimbus AQ N Nitrate 0.10 0.046J J mg/L L Nitrite 0.10 0.0013J J mg/L L 353.2 Veterans AQ N Nitrite 0.10 0.0022J J mg/L L HA 8000 Discovery AQ N COD,Total-LowRange 5.0 5.0U UJ mg/L P HA 8000 Discovery FD AQ FD COD,Total-LowRange 5.0 8.0 J mg/L P Page 1 of 32


A-13



SDG: 53864

200.8 Discovery AQ N Lead 0.10 0.094J J ug/L L Zinc 1.0 2.0 U ug/L F 200.8 Equip Blk AQ EB Lead 0.10 0.047J J ug/L L Zinc 1.0 2.9 U ug/L F 200.8 Freeport AQ N Iron 10 9.8J J ug/L L Zinc 1.0 2.9 U ug/L F 200.8 Nimbus AQ N Copper 0.50 1.5 J ug/L P Lead 0.10 0.047J J ug/L L Zinc 1.0 3.8 UJ ug/L F,P Zinc 1.0 2.9 J ug/L P 200.8 Nimbus FD AQ FD Copper 0.50 0.69 J ug/L P Lead 0.10 0.046J J ug/L L Zinc 1.0 0.81J J ug/L L,P Zinc 1.0 1.4 UJ ug/L F,P 200.8 Veterans AQ N Copper 0.50 2.6 U ug/L N Zinc 1.0 4.1 U ug/L F,N 351.2 Discovery AQ N Total Kjehldahl Nitrogen 0.10 0.062J J mg/L L 351.2 Nimbus AQ N Total Kjehldahl Nitrogen 0.10 0.11 J mg/L P 351.2 Nimbus FD AQ FD Total Kjehldahl Nitrogen 0.10 0.059U UJ mg/L P 353.2 Discovery AQ N Nitrate 0.10 0.070J J mg/L L Nitrite 0.10 0.0025J J mg/L L Page 2 of 32


A-14



SDG: 53864

353.2 Freeport AQ N Nitrate 0.10 0.074J J mg/L L Nitrite 0.10 0.0046J J mg/L L 353.2 Nimbus AQ N Nitrate 0.10 0.013J J mg/L L 353.2 Nimbus FD AQ FD Nitrate 0.10 0.017J J mg/L L 353.2 Veterans AQ N Nitrate 0.10 0.088J J mg/L L Nitrite 0.10 0.0031J J mg/L L 365.4 Discovery AQ N Total Phosphorus 0.050 0.048J J mg/L L HA 8000 Nimbus AQ N COD,Total-LowRange 5.0 5.0 J mg/L P HA 8000 Nimbus FD AQ FD COD,Total-LowRange 5.0 5.0U UJ mg/L P SM 4500-CL-E Discovery AQ N Chloride 2.0 3.3 U mg/L F SM 4500-CL-E Nimbus AQ N Chloride 2.0 3.2 U mg/L F SM 4500-CL-E Nimbus FD AQ FD Chloride 2.0 3.1 U mg/L F SM 4500-N Nimbus AQ N Total Nitrogen (as N) 0.10 0.12 J mg/L P SM 4500-N Nimbus FD AQ FD Total Nitrogen (as N) 0.10 0.10U UJ mg/L P Page 3 of 32


A-15



SDG: 54049

200.8 Discovery AQ N Lead 0.10 0.099J J ug/L L 200.8 Freeport AQ N Zinc 1.0 14 J ug/L P Zinc 1.0 4.5 UJ ug/L N,P 200.8 Freeport FD AQ FD Zinc 1.0 3.6 J ug/L P Zinc 1.0 8.2 UJ ug/L N,P 200.8 Nimbus AQ N Iron 10 8.3J J ug/L L 350.1 Freeport AQ N Ammonia as Nitrogen 0.10 0.056J J mg/L L,P 350.1 Freeport FD AQ FD Ammonia as Nitrogen 0.10 0.040U UJ mg/L P 350.1 Nimbus AQ N Ammonia as Nitrogen 0.10 0.086J J mg/L L 353.2 Discovery AQ N Nitrite 0.10 0.0057J J mg/L L 353.2 Freeport AQ N Nitrite 0.10 0.0031J J mg/L L 353.2 Freeport FD AQ FD Nitrite 0.10 0.0032J J mg/L L 353.2 Nimbus AQ N Nitrite 0.10 0.0039J J mg/L L 353.2 Veterans AQ N Nitrite 0.10 0.0026J J mg/L L 365.4 Veterans AQ N Total Phosphorus 0.050 0.037J J mg/L L SM 4500-CL-E Nimbus AQ N Chloride 2.0 3.5 U mg/L F Page 4 of 32


A-16



SDG: 54665

200.8 Equip Blk AQ EB Copper 0.50 0.22J J ug/L L 200.8 Freeport AQ N Zinc 1.0 2.8 U ug/L N 351.2 Veterans AQ N Total Kjehldahl Nitrogen 0.10 0.21 J mg/L P 351.2 Veterans FD AQ FD Total Kjehldahl Nitrogen 0.10 0.44 J mg/L P 353.2 Discovery AQ N Nitrate 0.10 0.092J J mg/L L Nitrite 0.10 0.0029J J mg/L L 353.2 Nimbus AQ N Nitrate 0.10 0.096J J mg/L L Nitrite 0.10 0.0020J J mg/L L 353.2 Veterans AQ N Nitrite 0.10 0.0016J J mg/L L,P 353.2 Veterans FD AQ FD Nitrite 0.10 0.0012U UJ mg/L P 365.4 Discovery AQ N Total Phosphorus 0.050 0.034J J mg/L L 365.4 Freeport AQ N Total Phosphorus 0.050 0.049J J mg/L L 365.4 Veterans AQ N Total Phosphorus 0.050 0.064 J mg/L P 365.4 Veterans FD AQ FD Total Phosphorus 0.050 0.11 J mg/L P SM 4500-CL-E Discovery AQ N Chloride 2.0 3.2 U mg/L F SM 4500-CL-E Nimbus AQ N Chloride 2.0 3.1 U mg/L F Page 5 of 32


A-17



SDG: 54665

SM 4500-N Veterans AQ N Total Nitrogen (as N) 0.10 0.21 J mg/L P SM 4500-N Veterans FD AQ FD Total Nitrogen (as N) 0.10 0.44 J mg/L P Page 6 of 32


A-18



SDG: N110830

614 DISCOVERY AQ N Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L J Diazinon 0.02 0.007U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J Ethion 0.02 0.005U UJ ug/L J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L J Parathion 0.05 0.008U UJ ug/L J Thiobencarb 0.05 0.008U UJ ug/L J 614 FREEPORT AQ N Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L J Diazinon 0.02 0.007U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J Ethion 0.02 0.005U UJ ug/L J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L J Parathion 0.05 0.008U UJ ug/L J Thiobencarb 0.05 0.008U UJ ug/L J 614 NIMBUS AQ N Azinphos-methyl 0.05 0.04U UJ ug/L H Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L H,J Diazinon 0.02 0.007U UJ ug/L H,J Disulfoton 0.1 0.08U UJ ug/L H,J Ethion 0.02 0.005U UJ ug/L H,J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L H,J Parathion 0.05 0.008U UJ ug/L H,J Thiobencarb 0.05 0.008U UJ ug/L J Page 7 of 32


A-19



SDG: N110830

614 VETERANS AQ N Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L J Diazinon 0.02 0.007U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J Ethion 0.02 0.005U UJ ug/L J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L J Parathion 0.05 0.008U UJ ug/L J Thiobencarb 0.05 0.008U UJ ug/L J Page 8 of 32


A-20



SDG: N110830

625M DISCOVERY AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L D 1-Methylphenanthrene 0.005 0.0040U UJ ug/L D 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L D 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L D 2-Methylnaphthalene 0.005 0.0040U UJ ug/L D Acenaphthene 0.005 0.0040U UJ ug/L D Acenaphthylene 0.005 0.0040U UJ ug/L D Anthracene 0.005 0.0040U UJ ug/L D,J Benz(a)anthracene 0.005 0.0040U UJ ug/L D Benzo(a)pyrene 0.005 0.0040U UJ ug/L D Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L D Benzo(e)pyrene 0.005 0.0040U UJ ug/L D Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L D Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L D Biphenyl 0.005 0.0040U UJ ug/L D Chrysene 0.005 0.0040U UJ ug/L D Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L D Dibenzothiophene 0.005 0.0040U UJ ug/L D Fluoranthene 0.005 0.008 J ug/L D Fluorene 0.005 0.0040U UJ ug/L D Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L D Naphthalene 0.005 0.007 UJ ug/L D,F Perylene 0.005 0.0040U UJ ug/L D Phenanthrene 0.005 0.008 J ug/L D Pyrene 0.005 0.008 J ug/L D,J Page 9 of 32


A-21



SDG: N110830

625M DISCOVERY FD AQ FD 1-Methylnaphthalene 0.005 0.0040U UJ ug/L D 1-Methylphenanthrene 0.005 0.0040U UJ ug/L D 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L D 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L D 2-Methylnaphthalene 0.005 0.0040U UJ ug/L D Acenaphthene 0.005 0.0040U UJ ug/L D Acenaphthylene 0.005 0.0040U UJ ug/L D Anthracene 0.005 0.0040U UJ ug/L D,J Benz(a)anthracene 0.005 0.0040U UJ ug/L D Benzo(a)pyrene 0.005 0.0040U UJ ug/L D Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L D Benzo(e)pyrene 0.005 0.0040U UJ ug/L D Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L D Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L D Biphenyl 0.005 0.0040U UJ ug/L D Chrysene 0.005 0.0040U UJ ug/L D Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L D Dibenzothiophene 0.005 0.0040U UJ ug/L D Fluoranthene 0.005 0.007 J ug/L D Fluorene 0.005 0.0040U UJ ug/L D Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L D Naphthalene 0.005 0.006 UJ ug/L D,F Perylene 0.005 0.0040U UJ ug/L D Phenanthrene 0.005 0.006 J ug/L D Pyrene 0.005 0.006 J ug/L D,J Page 10 of 32


A-22



SDG: N110830

625M EQ. BLANK AQ EB 1-Methylnaphthalene 0.005 0.0040U UJ ug/L D 1-Methylphenanthrene 0.005 0.0040U UJ ug/L D 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L D 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L D 2-Methylnaphthalene 0.005 0.0040U UJ ug/L D Acenaphthene 0.005 0.0040U UJ ug/L D Acenaphthylene 0.005 0.0040U UJ ug/L D Anthracene 0.005 0.0040U UJ ug/L D,J Benz(a)anthracene 0.005 0.0040U UJ ug/L D Benzo(a)pyrene 0.005 0.0040U UJ ug/L D Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L D Benzo(e)pyrene 0.005 0.0040U UJ ug/L D Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L D Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L D Biphenyl 0.005 0.0040U UJ ug/L D Chrysene 0.005 0.0040U UJ ug/L D Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L D Dibenzothiophene 0.005 0.0040U UJ ug/L D Fluoranthene 0.005 0.0040U UJ ug/L D Fluorene 0.005 0.0040U UJ ug/L D Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L D Naphthalene 0.005 0.0040U UJ ug/L D Perylene 0.005 0.0040U UJ ug/L D Phenanthrene 0.005 0.0040U UJ ug/L D Pyrene 0.005 0.0040U UJ ug/L D Page 11 of 32


A-23



SDG: N110830

625M FREEPORT AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L D 1-Methylphenanthrene 0.005 0.0040U UJ ug/L D 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L D 2,6-Dimethylnaphthalene 0.005 0.006 J ug/L D 2-Methylnaphthalene 0.005 0.006 J ug/L D Acenaphthene 0.005 0.0040U UJ ug/L D Acenaphthylene 0.005 0.0040U UJ ug/L D Anthracene 0.005 0.0040U UJ ug/L D,J Benz(a)anthracene 0.005 0.0040U UJ ug/L D Benzo(a)pyrene 0.005 0.0040U UJ ug/L D Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L D Benzo(e)pyrene 0.005 0.0040U UJ ug/L D Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L D Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L D Biphenyl 0.005 0.0040U UJ ug/L D Chrysene 0.005 0.0040U UJ ug/L D Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L D Dibenzothiophene 0.005 0.0040U UJ ug/L D Fluoranthene 0.005 0.0040U UJ ug/L D Fluorene 0.005 0.0040U UJ ug/L D Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L D Naphthalene 0.005 0.005J UJ ug/L D,F Perylene 0.005 0.0040U UJ ug/L D Phenanthrene 0.005 0.0040U UJ ug/L D Pyrene 0.005 0.0040U UJ ug/L D Page 12 of 32


A-24



SDG: N110830

625M NIMBUS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L D 1-Methylphenanthrene 0.005 0.0040U UJ ug/L D 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L D 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L D 2-Methylnaphthalene 0.005 0.0040U UJ ug/L D Acenaphthene 0.005 0.0040U UJ ug/L D Acenaphthylene 0.005 0.0040U UJ ug/L D Anthracene 0.005 0.0040U UJ ug/L D,J Benz(a)anthracene 0.005 0.0040U UJ ug/L D Benzo(a)pyrene 0.005 0.0040U UJ ug/L D Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L D Benzo(e)pyrene 0.005 0.0040U UJ ug/L D Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L D Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L D Biphenyl 0.005 0.0040U UJ ug/L D Chrysene 0.005 0.0040U UJ ug/L D Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L D Dibenzothiophene 0.005 0.0040U UJ ug/L D Fluoranthene 0.005 0.0040U UJ ug/L D Fluorene 0.005 0.0040U UJ ug/L D Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L D Naphthalene 0.005 0.0040U UJ ug/L D Perylene 0.005 0.0040U UJ ug/L D Phenanthrene 0.005 0.0040U UJ ug/L D Pyrene 0.005 0.0040U UJ ug/L D Page 13 of 32


A-25



SDG: N110830

625M VETERANS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L D 1-Methylphenanthrene 0.005 0.0040U UJ ug/L D 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L D 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L D 2-Methylnaphthalene 0.005 0.0040U UJ ug/L D Acenaphthene 0.005 0.0040U UJ ug/L D Acenaphthylene 0.005 0.0040U UJ ug/L D Anthracene 0.005 0.0040U UJ ug/L D,J Benz(a)anthracene 0.005 0.0040U UJ ug/L D Benzo(a)pyrene 0.005 0.0040U UJ ug/L D Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L D Benzo(e)pyrene 0.005 0.0040U UJ ug/L D Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L D Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L D Biphenyl 0.005 0.0040U UJ ug/L D Chrysene 0.005 0.0040U UJ ug/L D Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L D Dibenzothiophene 0.005 0.0040U UJ ug/L D Fluoranthene 0.005 0.0040U UJ ug/L D Fluorene 0.005 0.0040U UJ ug/L D Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L D Naphthalene 0.005 0.0040U UJ ug/L D Perylene 0.005 0.0040U UJ ug/L D Phenanthrene 0.005 0.0040U UJ ug/L D Pyrene 0.005 0.0040U UJ ug/L D 8015M NIMBUS AQ N Total Petroleum Hydrocarbons - Diesel 50 10U UJ ug/L H Page 14 of 32


A-26



SDG: N110830

8270 Mod (GCMS- DISCOVERY AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Chlorpyrifos 1.0 0.5U UJ ng/L J Cypermethrin 0.5 0.3J J ng/L L Diazinon 0.5 0.1U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J 8270 Mod (GCMS- FREEPORT AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Bifenthrin 0.5 0.1J J ng/L L Chlorpyrifos 1.0 0.5U UJ ng/L J Diazinon 0.5 0.1U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J 8270 Mod (GCMS- NIMBUS AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Chlorpyrifos 1.0 0.5U UJ ng/L J Diazinon 0.5 0.1U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J 8270 Mod (GCMS- VETERANS AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Bifenthrin 0.5 0.2J J ng/L L Chlorpyrifos 1.0 0.5U UJ ng/L J Diazinon 0.5 0.1U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J Page 15 of 32


A-27



SDG: P020495

1630 DISCOVERY AQ N Methylmercury 0.05 0.04J J ng/L L 614 DISCOVERY AQ N Azinphos-methyl 0.05 0.04U UJ ug/L J Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L J Diazinon 0.02 0.007U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J Ethion 0.02 0.005U UJ ug/L J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L J Parathion 0.05 0.008U UJ ug/L J Thiobencarb 0.05 0.008U UJ ug/L J 614 FREEPORT AQ N Azinphos-methyl 0.05 0.04U UJ ug/L J Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L J Diazinon 0.02 0.007U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J Ethion 0.02 0.005U UJ ug/L J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L J Parathion 0.05 0.008U UJ ug/L J Thiobencarb 0.05 0.008U UJ ug/L J Page 16 of 32


A-28



SDG: P020495

614 NIMBUS AQ N Azinphos-methyl 0.05 0.04U UJ ug/L J Chlorpyrifos 0.01 0.005U UJ ug/L J Demeton -O and -S 0.1 0.09U UJ ug/L J Diazinon 0.02 0.007U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J Ethion 0.02 0.005U UJ ug/L J Malathion 0.05 0.005U UJ ug/L J Methyl Parathion 0.1 0.08U UJ ug/L J Parathion 0.05 0.008U UJ ug/L J Thiobencarb 0.05 0.008U UJ ug/L J 614 VETERANS AQ N Azinphos-methyl 0.05 0.04U UJ ug/L H,J Chlorpyrifos 0.01 0.005U UJ ug/L H,J Demeton -O and -S 0.1 0.09U UJ ug/L H,J Diazinon 0.02 0.007U UJ ug/L H,J Disulfoton 0.1 0.08U UJ ug/L H,J Ethion 0.02 0.005U UJ ug/L H,J Malathion 0.05 0.005U UJ ug/L H,J Methyl Parathion 0.1 0.08U UJ ug/L H,J Parathion 0.05 0.008U UJ ug/L H,J Thiobencarb 0.05 0.008U UJ ug/L H,J 625M DISCOVERY AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.005J J ug/L J Page 17 of 32


A-29



SDG: P020495

625M EQ. BLK AQ EB 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J 625M FREEPORT AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J 625M NIMBUS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J Page 18 of 32


A-30



SDG: P020495

625M NIMBUS FD AQ FD 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J 625M VETERANS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L H,J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L H,J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L H,J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L H,J Acenaphthene 0.005 0.0040U UJ ug/L H,J Acenaphthylene 0.005 0.0040U UJ ug/L H Biphenyl 0.005 0.0040U UJ ug/L H,J Dibenzothiophene 0.005 0.0040U UJ ug/L H,J Fluorene 0.005 0.0040U UJ ug/L H,J Naphthalene 0.005 0.0040U UJ ug/L H,J Phenanthrene 0.005 0.0040U UJ ug/L H 8270 Mod (GCMS- DISCOVERY AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Bifenthrin 0.5 0.1J J ng/L L Chlorpyrifos 1.0 0.5U UJ ng/L J Deltamethrin:Tralomethrin 1.0 0.2U UJ ng/L J Diazinon 0.5 0.1U UJ ng/L J Esfenvalerate:Fenvalerate 1.0 0.2U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J Tetramethrin 0.5 0.2U UJ ng/L J Page 19 of 32


A-31



SDG: P020495

8270 Mod (GCMS- FREEPORT AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Bifenthrin 0.5 0.2J J ng/L L Chlorpyrifos 1.0 0.5U UJ ng/L J Deltamethrin:Tralomethrin 1.0 0.2U UJ ng/L J Diazinon 0.5 0.4J J ng/L J,L Esfenvalerate:Fenvalerate 1.0 0.2U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J Tetramethrin 0.5 0.2U UJ ng/L J 8270 Mod (GCMS- NIMBUS AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Chlorpyrifos 1.0 0.5U UJ ng/L J Deltamethrin:Tralomethrin 1.0 0.2U UJ ng/L J Diazinon 0.5 0.1U UJ ng/L J Esfenvalerate:Fenvalerate 1.0 0.2U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J Tetramethrin 0.5 0.2U UJ ng/L J Page 20 of 32


A-32



SDG: P020495

8270 Mod (GCMS- VETERANS AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L H,J Bifenthrin 0.5 0.1U UJ ng/L H Chlorpyrifos 1.0 0.5U UJ ng/L H,J Cyfluthrin 0.5 0.2U UJ ng/L H Deltamethrin:Tralomethrin 1.0 0.2U UJ ng/L H,J Diazinon 0.5 0.4J J ng/L H,J,L Esfenvalerate:Fenvalerate 1.0 0.2U UJ ng/L H,J L-Cyhalothrin 0.5 0.2J UJ ng/L F,H,J,L Permethrin 10 2U UJ ng/L H Tau-Fluvalinate 0.5 0.2U UJ ng/L H,J Tetramethrin 0.5 0.2U UJ ng/L H,J Page 21 of 32


A-33



SDG: P021287

1630 DISCOVERY AQ N Methylmercury 0.05 0.04J J ng/L H,L 1630 FREEPORT AQ N Methylmercury 0.05 0.10 J ng/L H 1630 FREEPORT FD AQ FD Methylmercury 0.05 0.1 J ng/L H 1630 NIMBUS AQ N Methylmercury 0.05 0.03J J ng/L H,L 1630 VETERANS AQ N Methylmercury 0.05 0.11 J ng/L H 614 DISCOVERY AQ N Demeton -O and -S 0.1 0.09U UJ ug/L H,J 614 FREEPORT AQ N Demeton -O and -S 0.1 0.09U UJ ug/L J 614 NIMBUS AQ N Demeton -O and -S 0.1 0.09U UJ ug/L J 614 VETERANS AQ N Demeton -O and -S 0.1 0.09U UJ ug/L J Page 22 of 32


A-34



SDG: P021287

625M DISCOVERY AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L H,J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L H,J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L H,J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L H,J Acenaphthene 0.005 0.0040U UJ ug/L H,J Acenaphthylene 0.005 0.0040U UJ ug/L H,J Benzo(a)pyrene 0.005 0.01 J ug/L H Benzo(b)fluoranthene 0.005 0.02 J ug/L H Benzo(e)pyrene 0.005 0.01 J ug/L H Benzo(g,h,i)perylene 0.005 0.02 J ug/L H Benzo(k)fluoranthene 0.005 0.005 J ug/L J Biphenyl 0.005 0.0040U UJ ug/L H Chrysene 0.005 0.01 J ug/L H Dibenzothiophene 0.005 0.0040U UJ ug/L H,J Fluoranthene 0.005 0.01 J ug/L H Fluorene 0.005 0.0040U UJ ug/L H,J Indeno(1,2,3-c,d)pyrene 0.005 0.01 J ug/L H Naphthalene 0.005 0.0040U UJ ug/L H,J Pyrene 0.005 0.02 J ug/L H 625M EQ. BLNK AQ EB 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Acenaphthylene 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J Page 23 of 32


A-35



SDG: P021287

625M FREEPORT AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Acenaphthylene 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J 625M FREEPORT FD AQ FD 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Acenaphthylene 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J 625M NIMBUS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J Acenaphthene 0.005 0.0040U UJ ug/L J Acenaphthylene 0.005 0.0040U UJ ug/L J Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J Page 24 of 32


A-36



SDG: P021287

625M VETERANS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L G,J 1-Methylphenanthrene 0.005 0.0040U UJ ug/L G 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L G,J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L G,J 2-Methylnaphthalene 0.005 0.0040U UJ ug/L G,J Acenaphthene 0.005 0.0040U UJ ug/L G,J Acenaphthylene 0.005 0.0040U UJ ug/L G,J Anthracene 0.005 0.0040U UJ ug/L G Benz(a)anthracene 0.005 0.0040U UJ ug/L G Benzo(a)pyrene 0.005 0.0040U UJ ug/L G Benzo(b)fluoranthene 0.005 0.0040U UJ ug/L G Benzo(e)pyrene 0.005 0.0040U UJ ug/L G Benzo(g,h,i)perylene 0.005 0.0040U UJ ug/L G Benzo(k)fluoranthene 0.005 0.0040U UJ ug/L G Biphenyl 0.005 0.0040U UJ ug/L G Chrysene 0.005 0.0040U UJ ug/L G Dibenz(a,h)anthracene 0.005 0.0040U UJ ug/L G Dibenzothiophene 0.005 0.0040U UJ ug/L G,J Fluoranthene 0.005 0.0040U UJ ug/L G Fluorene 0.005 0.0040U UJ ug/L G,J Indeno(1,2,3-c,d)pyrene 0.005 0.0040U UJ ug/L G Naphthalene 0.005 0.0040U UJ ug/L G,J Perylene 0.005 0.0040U UJ ug/L G Phenanthrene 0.005 0.0040U UJ ug/L G Pyrene 0.005 0.0040U UJ ug/L G 8015 DISCOVERY AQ N Total Petroleum Hydrocarbons - Gasoline 50 26U UJ ug/L H Page 25 of 32


A-37



SDG: P021287

8270 Mod (GCMS- DISCOVERY AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L H,J Chlorpyrifos 1.0 0.5U UJ ng/L H Diazinon 0.5 0.1U UJ ng/L H L-Cyhalothrin 0.5 0.2U UJ ng/L H,J Tau-Fluvalinate 0.5 0.2U UJ ng/L H,J Tetramethrin 0.5 0.2U UJ ng/L H,J 8270 Mod (GCMS- FREEPORT AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J L-Cyhalothrin 0.5 0.2U UJ ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J Tetramethrin 0.5 0.2U UJ ng/L J 8270 Mod (GCMS- NIMBUS AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J L-Cyhalothrin 0.5 2.7 J ng/L J Tau-Fluvalinate 0.5 0.2U UJ ng/L J Tetramethrin 0.5 0.2U UJ ng/L J 8270 Mod (GCMS- VETERANS AQ N NCI-SIM) Allethrin 0.5 0.1U UJ ng/L J Chlorpyrifos 1.0 0.7J J ng/L L Diazinon 0.5 0.4J J ng/L L L-Cyhalothrin 0.5 0.2J J ng/L J,L Tau-Fluvalinate 0.5 0.2U UJ ng/L J Tetramethrin 0.5 0.2U UJ ng/L J Page 26 of 32


A-38



SDG: P050493

614 DISCOVERY AQ N Demeton -O and -S 0.1 0.09U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J 614 FREEPORT AQ N Demeton -O and -S 0.1 0.09U UJ ug/L H,J Disulfoton 0.1 0.08U UJ ug/L H,J 614 NIMBUS AQ N Demeton -O and -S 0.1 0.09U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J 614 VETERANS AQ N Demeton -O and -S 0.1 0.09U UJ ug/L J Disulfoton 0.1 0.08U UJ ug/L J 625M DISCOVERY AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J,K 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K Acenaphthene 0.005 0.0040U UJ ug/L J,K Acenaphthylene 0.005 0.0040U UJ ug/L J Anthracene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J,K Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J,K Phenanthrene 0.005 0.0040U UJ ug/L J,K Pyrene 0.005 0.004J J ug/L L Page 27 of 32


A-39



SDG: P050493

625M EQ. BLK AQ EB 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J,K 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K Acenaphthene 0.005 0.0040U UJ ug/L J,K Acenaphthylene 0.005 0.0040U UJ ug/L J Anthracene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J,K Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J,K Phenanthrene 0.005 0.0040U UJ ug/L J,K 625M FREEPORT AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L H,J,K 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L H,J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L H,J,K 2-Methylnaphthalene 0.005 0.0040U UJ ug/L H,J,K Acenaphthene 0.005 0.0040U UJ ug/L H,J,K Acenaphthylene 0.005 0.0040U UJ ug/L H,J Anthracene 0.005 0.0040U UJ ug/L H,J Biphenyl 0.005 0.0040U UJ ug/L H,J,K Dibenzothiophene 0.005 0.0040U UJ ug/L H,J Fluorene 0.005 0.0040U UJ ug/L H,J Naphthalene 0.005 0.0040U UJ ug/L H,J,K Phenanthrene 0.005 0.0040U UJ ug/L H,J,K Page 28 of 32


A-40



SDG: P050493

625M NIMBUS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J,K 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K Acenaphthene 0.005 0.0040U UJ ug/L J,K Acenaphthylene 0.005 0.0040U UJ ug/L J Anthracene 0.005 0.0040U UJ ug/L J Biphenyl 0.005 0.0040U UJ ug/L J,K Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J,K Phenanthrene 0.005 0.0040U UJ ug/L J,K 625M VETERANS AQ N 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J,K 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K Acenaphthene 0.005 0.0040U UJ ug/L J,K Acenaphthylene 0.005 0.0040U UJ ug/L J Anthracene 0.005 0.02 J ug/L J,P Biphenyl 0.005 0.0040U UJ ug/L J,K Chrysene 0.005 0.01 J ug/L P Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluoranthene 0.005 0.04 J ug/L P Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J,K Phenanthrene 0.005 0.0040U UJ ug/L J,K Pyrene 0.005 0.03 J ug/L P Page 29 of 32


A-41



SDG: P050493

625M VETERANS FD AQ FD 1-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K 2,3,5-Trimethylnaphthalene 0.005 0.0040U UJ ug/L J 2,6-Dimethylnaphthalene 0.005 0.0040U UJ ug/L J,K 2-Methylnaphthalene 0.005 0.0040U UJ ug/L J,K Acenaphthene 0.005 0.0040U UJ ug/L J,K Acenaphthylene 0.005 0.0040U UJ ug/L J Anthracene 0.005 0.0040U UJ ug/L J,P Biphenyl 0.005 0.0040U UJ ug/L J,K Chrysene 0.005 0.0040U UJ ug/L P Dibenzothiophene 0.005 0.0040U UJ ug/L J Fluoranthene 0.005 0.0040U UJ ug/L P Fluorene 0.005 0.0040U UJ ug/L J Naphthalene 0.005 0.0040U UJ ug/L J,K Phenanthrene 0.005 0.0040U UJ ug/L J,K Pyrene 0.005 0.0040U UJ ug/L P 8015 FREEPORT AQ N Total Petroleum Hydrocarbons - Gasoline 50 26U UJ ug/L H 8270 Mod (GCMS- DISCOVERY AQ N NCI-SIM) Allethrin 1.5 0.1U UJ ng/L J Bifenthrin 1.5 0.1U UJ ng/L J Cyfluthrin 1.5 0.2U UJ ng/L J Cypermethrin 1.5 0.2U UJ ng/L J Deltamethrin:Tralomethrin 3.0 0.2U UJ ng/L J Esfenvalerate:Fenvalerate 1.5 0.2U UJ ng/L J L-Cyhalothrin 1.5 0.2U UJ ng/L J Permethrin 15 2U UJ ng/L J Tau-Fluvalinate 1.5 0.2U UJ ng/L J Tetramethrin 1.5 0.2U UJ ng/L J Page 30 of 32


A-42



SDG: P050493

8270 Mod (GCMS- FREEPORT AQ N NCI-SIM) Allethrin 1.5 0.1U UJ ng/L H,J Bifenthrin 1.5 0.1U UJ ng/L H,J Cyfluthrin 1.5 0.2U UJ ng/L H,J Cypermethrin 1.5 0.2U UJ ng/L H,J Deltamethrin:Tralomethrin 3.0 0.2U UJ ng/L H,J Esfenvalerate:Fenvalerate 1.5 0.2U UJ ng/L H,J L-Cyhalothrin 1.5 0.2U UJ ng/L H,J Permethrin 15 2U UJ ng/L H,J Tau-Fluvalinate 1.5 0.2U UJ ng/L H,J Tetramethrin 1.5 0.2U UJ ng/L H,J 8270 Mod (GCMS- NIMBUS AQ N NCI-SIM) Allethrin 1.5 0.1U UJ ng/L J Bifenthrin 1.5 0.1U UJ ng/L J Cyfluthrin 1.5 0.2U UJ ng/L J Cypermethrin 1.5 0.2U UJ ng/L J Deltamethrin:Tralomethrin 3.0 0.2U UJ ng/L J Esfenvalerate:Fenvalerate 1.5 0.2U UJ ng/L J L-Cyhalothrin 1.5 0.2U UJ ng/L J Permethrin 15 2U UJ ng/L J Tau-Fluvalinate 1.5 0.2U UJ ng/L J Tetramethrin 1.5 0.2U UJ ng/L J Page 31 of 32


A-43



SDG: P050493

8270 Mod (GCMS- VETERANS AQ N NCI-SIM) Allethrin 1.5 0.1U UJ ng/L J Bifenthrin 1.5 0.1U UJ ng/L J Cyfluthrin 1.5 0.2U UJ ng/L J Cypermethrin 1.5 0.2U UJ ng/L J Deltamethrin:Tralomethrin 3.0 0.2U UJ ng/L J Esfenvalerate:Fenvalerate 1.5 0.2U UJ ng/L J L-Cyhalothrin 1.5 0.2U UJ ng/L J Permethrin 15 2U UJ ng/L J Tau-Fluvalinate 1.5 0.2U UJ ng/L J Tetramethrin 1.5 0.2U UJ ng/L J

N = Normal Sample EB = Equipment Blank FD = Field Duplicate

Page 32 of 32

A-44

Table A-14

Data Qualifier Reason Codes

Category Code Category Code

Low Bias Indicator - Initial Calibration High Bias Indicator + Initial Calibration RRF Q Temperature A Initial Calibration RSD R Holding Times Initial Calibration Cor. Coef S

Sampling to Analysis C Initial Calibration Verification Sampling to Extraction D Initial Calibration Verificaton RRF T Extaction to Analysis E Initial CalibrationVerification %D U

Method Blanks F Continuing Calibration Continuing Calibraiton RRF V Surrogate Recovery G Continuing Calibration %D W MS/MSD GC/MS Tune MS/MSD Recovery H GC/MS Tune for Initial Calibration X MS/MSD RPD I GC/MS Tune for Continuing Calibration Y LCS Laboratory Duplicate Z LCS Recovery J Categories not Assessed by LCS RPD K Automated Data Review*

Internal Standards Is Reporting Limits L Calibration Blanks Cb Field QC Resolution Check Mixture Rm Field Blank M Performance Evaluation Mixture Pm Equipment Blank N Professional Judgement Pj Trip Blank O Field Duplicate P

* Qualifiers for data-review categories not assessed by automated data review are manually entered by the user. The application automaticallly adds reason codes listed here when the user manually adds qualifiers for these categories if the option for applying reason codes was selected during automated data review.

Appendix B Time-Series Plots

B-1

Appendix B. Time-Series Plots (December 1992 – June 2014)

Time-series plots representing CMP data from December 1992 through June 2014 are presented in this appendix. These plots were prepared for selected parameters monitored in 2013-2014. However, not all parameters have been included. Time-series plots for a majority of the trace organic parameters were not included because their results were largely below detection. A representative number have been included to demonstrate trends for the various categories (organophosphate pesticides, PAHs, and pyrethroids). The lowest water quality objectives as listed in Table 3-1 have been included on selected plots except that constant Basin Plan objectives for trace metals are indicated rather than the variable (event hardness-dependent) CTR criteria. A log scale is shown where concentrations vary greatly. Plots are grouped by monitoring site and alphabetical by constituent name.


B-1

Appendix B-1 Sacramento River at Veterans Bridge


B-2

0

5

10

15

20

25

30

1993 1995 1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (

deg

C)

Temperature at Veterans Bridge

Below Detection Detected Basin Plan Objective: 20 deg C

0

1

2

3

4

5

6

7

8

9

10

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

mg/L)

Total Organic Carbon at Veterans Bridge

Below Detection Detected


B-3

0

50

100

150

200

250

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

mg/L)

Total Suspended Solids at Veterans Bridge


0

1

2

3

4

5

6

Jan-92 Jan-94 Jan-96 Jan-98 Jan-00 Jan-02 Jan-04 Jan-06 Jan-08 Jan-10 Jan-12 Jan-14

Conc

entra

tion (µ

g/L)

Copper (Dissolved) at Veterans Bridge

Below Detection Detected Basin Plan Objective: 10 µg/L


B-4

0

10

20

30

40

50

60

1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

ng/L

)

Mercury (Unfiltered) at Veterans Bridge

Below Detection Detected Lowest Objective: 50 ng/L

0.00

0.05

0.10

0.15

0.20

0.25

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Methylmercury (Unfiltered) at Veterans Bridge



B-5

0.0

0.5

1.0

1.5

2.0

2.5

3.0

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L

-N)

Nitrate (as NO3-N) at Veterans Bridge

Below Detection Detected Lowest Objective: 10 mg/L-N

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0.16

0.18

2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

Conc

entra

tion (

mg/L

)

Dissolved Ortho-Phosphate at Veterans Bridge



B-6

0.0

0.2

0.4

0.6

0.8

1.0

1.2

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L)

Total Kjeldahl Nitrogen at Veterans Bridge


1

10

100

1,000

10,000

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

MPN

/100

mL)

E. coli at Veterans Bridge

Below Detection Detected Lowest Objective: 235 MPN/100mL


B-7

0.0001

0.001

0.01

0.1

1

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chlorpyrifos at Veterans Bridge


0.0001

0.001

0.01

0.1

1

1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Diazinon at Veterans Bridge

Below Detection Detected Lowest Objective: 0.050 µg/L


B-8

0.0001

0.001

0.01

0.1

1

10

100

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chrysene at Veterans Bridge


0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

1.6

2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Bifenthrin at Veterans Bridge



B-9

Appendix B-2 Sacramento River at Freeport


B-10

0

5

10

15

20

25

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

deg C

)

Temperature at Freeport


0

1

2

3

4

5

6

7

8

9

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

mg/L)

Total Organic Carbon at Freeport



B-11

0

50

100

150

200

250

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

mg/L

)

Total Suspended Solids at Freeport


0

1

2

3

4

5

6

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (µ

g/L)

Copper (Dissolved) at Freeport



B-12

0

10

20

30

40

50

60

70

80

90

100

1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

ng/L)

Mercury (Unfiltered) at Freeport


0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Methylmercury (Unfiltered) at Freeport



B-13

0.0

0.5

1.0

1.5

2.0

2.5

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L-

N)

Nitrate (as NO3-N) at Freeport


0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0.16

2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013

Conc

entra

tion (

mg/L)

Dissolved Ortho-Phosphate at Freeport



B-14

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L

)

Total Kjeldahl Nitrogen at Freeport


1

10

100

1,000

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

MPN

/100

mL)

E. coli at Freeport



B-15

0.0001

0.001

0.01

0.1

1

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chlorpyrifos at Freeport


0.0001

0.001

0.01

0.1

1

1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Diazinon at Freeport



B-16

0.0001

0.001

0.01

0.1

1

10

100

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chrysene at Freeport


0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

1.6

2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Bifenthrin at Freeport



B-17

Appendix B-4 American River at Nimbus


B-18

0

5

10

15

20

25

1993 1995 1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (

deg C

)

Temperature at Nimbus


0

1

2

3

4

5

6

7

1993 1995 1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (

mg/L

)

Total Organic Carbon at Nimbus



B-19

0

10

20

30

40

50

60

70

80

1993 1995 1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (

mg/L

)

Total Suspended Solids at Nimbus


0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

1.6

1.8

2.0

1993 1995 1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Copper (Dissolved) at Nimbus



B-20

0

10

20

30

40

50

60

1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

ng/L

)

Mercury (Unfiltered) at Nimbus


0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Methylmercury (Unfiltered) at Nimbus



B-21

0.0

0.5

1.0

1.5

2.0

2.5

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L

-N)

Nitrate (as NO3-N) at Nimbus


0.00

0.02

0.04

0.06

0.08

0.10

0.12

2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

Conc

entra

tion (

mg/L)

Dissolved Ortho-Phosphate at Nimbus



B-22

0.0

0.2

0.4

0.6

0.8

1.0

1.2

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L)

Total Kjeldahl Nitrogen at Nimbus


1

10

100

1,000

10,000

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

MPN

/100

mL)

E. coli at Nimbus



B-23

0.0001

0.001

0.01

0.1

1

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chlorpyrifos at Nimbus


0.0001

0.001

0.01

0.1

1

1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Diazinon at Nimbus



B-24

0.0001

0.001

0.01

0.1

1

10

100

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chrysene at Nimbus


0.0

0.2

0.4

0.6

0.8

1.0

1.2

1.4

1.6

2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Bifenthrin at Nimbus



B-25

Appendix B-5 American River at Discovery Park


B-26

0

5

10

15

20

25

30

1993 1995 1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (

deg

C)

Temperature at Discovery Park


0

2

4

6

8

10

12

14

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

mg/L

)

Total Organic Carbon at Discovery Park



B-27

0

10

20

30

40

50

60

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

mg/L

)

Total Suspended Solids at Discovery Park


0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

1992 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

ug/L

)

Copper (Dissolved) at Discovery Park



B-28

0.01

0.1

1

10

100

1000

1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014

Conc

entra

tion (

ng/L)

Mercury (Unfiltered) at Discovery Park


0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Methylmercury (Unfiltered) at Discovery Park



B-29

0.0

0.2

0.4

0.6

0.8

1.0

1.2

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L-

N)

Nitrate (as NO3-N) at Discovery Park


0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

Conc

entra

tion (

mg/L)

Dissolved Ortho-Phosphate at Discovery Park



B-30

0.0

0.2

0.4

0.6

0.8

1.0

1.2

2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

mg/L

)

Total Kjeldahl Nitrogen at Discovery Park


1

10

100

1,000

10,000

100,000

2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014

Conc

entra

tion (

MPN/

100 m

L)

E. coli at Discovery Park



B-31

0.0001

0.001

0.01

0.1

1

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chlorpyrifos at Discovery Park


0.0001

0.001

0.01

0.1

1

1997 1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Diazinon at Discovery Park



B-32

0.0001

0.001

0.01

0.1

1

10

100

1999 2001 2003 2005 2007 2009 2011 2013

Conc

entra

tion (µ

g/L)

Chrysene at Discovery Park


0

1

2

3

4

5

6

7

8

2009 2010 2011 2012 2013 2014

Conc

entra

tion (

ng/L)

Bifenthrin at Discovery Park


Appendix CLaboratory Reports

C-1

Appendix C. Laboratory Reports (2013-2014)

[This page intentionally left blank.]

CMP 209


Caltest

Friday, December 20, 2013

Michael CookSacramento County Regional San8521 Laguna Station RoadElk Grove, CA 95758

Lab Order:RE:Project ID:

Dear Michael Cook:

AMP 209N110830 Collected By:

PO/Contract #:Michael Cook81085368

Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, November 21, 2013. Results reportedherein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Enclosures

Project Manager: Todd Albertson

NELAP Accreditation 01103CA ELAP Certification 1664

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of CALTEST ANALYTICAL LABORATORY.

Page 1 of 2412/20/2013 14:29

1885 North Kelly Road • Napa, California 94558(707) 258-4000 • Fax (707) 226-1001 • e-mail: [email protected]

SAMPLE SUMMARY

Project ID:

N110830

AMP 209

Lab Order:

Lab ID Sample ID Matrix Date Collected Date Received

N110830001 VETERANS (131120067) Water 11/20/2013 10:30 11/21/2013 16:50

N110830002 DISCOVERY (131120068) Water 11/20/2013 11:50 11/21/2013 16:50

N110830003 NIMBUS (131120063) Water 11/20/2013 12:00 11/21/2013 16:50

N110830004 FREEPORT (131120065) Water 11/20/2013 13:40 11/21/2013 16:50

N110830005 DISCOVERY FD (131120064) Water 11/20/2013 11:50 11/21/2013 16:50

N110830006 EQ. BLANK (131120066) Water 11/20/2013 12:00 11/21/2013 16:50




Page 2 of 2412/20/2013 14:29


NARRATIVE

Project ID:

N110830

AMP 209

Lab Order:

General Qualifiers and Notes

Caltest authorizes this report to be reproduced only in its entirety. Results are specific to the sample(s) assubmitted and only to the parameter(s) reported.

Caltest certifies that all test results for wastewater and hazardous waste analyses meet all applicable NELACrequirements; all microbiology and drinking water testing meet applicable ELAP requirements, unless statedotherwise.

All analyses performed by EPA Methods or Standard Methods (SM) 20th Edition except where noted(SMOL=online edition).

Caltest collects samples in compliance with 40 CFR, EPA Methods, Cal. Title 22, and Standard Methods.

Dilution Factors (DF) reported greater than '1' have been used to adjust the result, Reporting Limit (RL), andMethod Detection Limit (MDL).

All Solid, sludge, and/or biosolids data is reported in Wet Weight, unless otherwise specified.

Filtrations performed at Caltest for dissolved metals (excluding mercury) and/or pH analysis were notperformed within the 15 minute holding time as specified by 40CFR 136.3 table II.

Results Qualifiers: Report fields may contain codes and non-numeric data correlating to one or more of thefollowing definitions:

ND - Non Detect - indicates analytical result has not been detected.

RL - Reporting Limit is the quantitation limit at which the laboratory is able to detect an analyte. An analyte notdetected at or above the RL is reported as ND unless otherwise noted or qualified. For analyses pertaining tothe State Implementation Plan of the California Toxics Rule, the Caltest Reporting Limit (RL) is equivalent tothe Minimum Level (ML). A standard is always run at or below the ML. Where Reporting Limits are elevateddue to dilution, the ML calibration criteria has been met.

J - reflects estimated analytical result value detected below the Reporting Limit (RL) and above the MethodDetection Limit (MDL). The 'J' flag is equivalent to the DNQ Estimated Concentration flag.

E - indicates an estimated analytical result value.

B - indicates the analyte has been detected in the blank associated with the sample.

NC - means not able to be calculated for RPD or Spike Recoveries.

SS - compound is a Surrogate Spike used per laboratory quality assurance manual.

NOTE: This document represents a complete Analytical Report for the samples referenced herein and shouldbe retained as a permanent record thereof.

Qualifiers and Compound Notes

Analyte(s) reported as 'ND' means not detected at or above the listed Method Detection Limits (MDL).1

Contaminant was detected in the Method Blank.2




Page 3 of 2412/20/2013 14:29


ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830001

VETERANS (131120067)

Matrix: WaterDate Collected:

Date Received:

11/20/2013 10:30

11/21/2013 16:50

DF

Lab ID:

Sample ID:

Prepared Analyzed QualMDL Batch BatchR. L.UnitsResultParameters

Methyl Mercury Analysis Prep Method: Draft EPA 1630 Prep by: JZHAnalytical Method: Draft EPA 1630 Analyzed by: JZH

Methyl Mercury 10.020 MHG 4464MPR 123800.08 ng/L 0.05 12/03/13 00:00 12/03/13 00:00

Total Extractable PetroleumHydrocarbon

Prep Method: SW846 3510C Prep by: ECB

Analytical Method: SW846 8015(MOD) Analyzed by: MDTDiesel Fuel 110 SFL 1594SPR 6215ND ug/L 50 11/27/13 16:59 12/07/13 01:11Motor Oil 1160 SFL 1594SPR 6215ND ug/L 200 11/27/13 16:59 12/07/13 01:11o-Terphenyl (SS) 1 SFL 1594SPR 621584 % 49-124 11/27/13 16:59 12/07/13 01:11

625,PAH+Ext,Triple Quad,Analysis Prep Method: EPA 625M Prep by: RLHAnalytical Method: EPA 625M Analyzed by: RLH

Acenaphthene 1 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Acenaphthylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(b)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(e)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(g,h,i)perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(k)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Biphenyl 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Chrysene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzothiophene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002,6-Dimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluorene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylphenanthrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Naphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Phenanthrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Fluorobiphenyl (SS) 1 SMS 3296SPR 6213102 % 50-150 12/04/13 00:00 12/11/13 00:00Nitrobenzene-d5 (SS) 1 SMS 3296SPR 621388 % 50-150 12/04/13 00:00 12/11/13 00:00Terphenyl-d14 (SS) 1 SMS 3296SPR 6213123 % 50-150 12/04/13 00:00 12/11/13 00:00

12/20/2013 14:29 Page 4 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830001

VETERANS (131120067)


Date Received:

11/20/2013 10:30

11/21/2013 16:50

DF

Lab ID:

Sample ID:


Organophosphorous Pesticides Prep Method: EPA 614 Prep by: ECBAnalytical Method: EPA 614 Analyzed by: NTA

Azinphos methyl (Guthion) 10.04 SMS 3298SPR 6206ND ug/L 0.05 11/25/13 00:00 12/07/13 03:02Chlorpyrifos 10.005 SMS 3298SPR 6206ND ug/L 0.01 11/25/13 00:00 12/07/13 03:02Demeton -O and -S 10.09 SMS 3298SPR 6206ND ug/L 0.1 11/25/13 00:00 12/07/13 03:02Diazinon 10.007 SMS 3298SPR 6206ND ug/L 0.02 11/25/13 00:00 12/07/13 03:02Disulfoton (Di-Syston) 10.08 SMS 3298SPR 6206ND ug/L 0.1 11/25/13 00:00 12/07/13 03:02Ethion 10.005 SMS 3298SPR 6206ND ug/L 0.02 11/25/13 00:00 12/07/13 03:02Malathion 10.005 SMS 3298SPR 6206ND ug/L 0.05 11/25/13 00:00 12/07/13 03:02Parathion (Parathion ethyl) 10.008 SMS 3298SPR 6206ND ug/L 0.05 11/25/13 00:00 12/07/13 03:02Parathion methyl 10.08 SMS 3298SPR 6206ND ug/L 0.1 11/25/13 00:00 12/07/13 03:02Thiobencarb 10.008 SMS 3298SPR 6206ND ug/L 0.05 11/25/13 00:00 12/07/13 03:02Dichlofenthion (SS) 1 SMS 3298SPR 620686 % 45-105 11/25/13 00:00 12/07/13 03:02Triphenylphosphate (SS) 1 SMS 3298SPR 620690 % 61-120 11/25/13 00:00 12/07/13 03:02

Pyrethroids Analysis, NCI, Water Prep Method: SW846 3510C Prep by: ECBAnalytical Method: SW846 8270 Mod (GCMS-

NCI-SIM)Analyzed by: RLH

Allethrin 1 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Bifenthrin 10.1 SMS 3294SPR 6204J0.2 ng/L 1.5 11/23/13 10:24 12/05/13 06:23Chlorpyrifos 10.5 SMS 3294SPR 6204ND ng/L 2.0 11/23/13 10:24 12/05/13 06:23Cyfluthrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Lambda-Cyhalothrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Cypermethrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Diazinon 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Deltamethrin:Tralomethrin 10.2 SMS 3294SPR 6204ND ng/L 3.0 11/23/13 10:24 12/05/13 06:23Esfenvalerate:Fenvalerate 10.2 SMS 3294SPR 6204ND ng/L 3.0 11/23/13 10:24 12/05/13 06:23Fenpropathrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Tau-Fluvalinate 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Permethrin 12 SMS 3294SPR 6204ND ng/L 15 11/23/13 10:24 12/05/13 06:23Tetramethrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:23Esfenvalerate-d6;#1 (SS) 1 SMS 3294SPR 6204111 % 70-130 11/23/13 10:24 12/05/13 06:23Esfenvalerate-d6;#2 (SS) 1 SMS 3294SPR 6204111 % 70-130 11/23/13 10:24 12/05/13 06:23

Total Purgeable PetroleumHydrocarbons

Analytical Method: SW846 5030B/8015(MOD)TPPH Gas

Analyzed by: AN

TPPH - Gasoline Fuel 126 VFL 1496 ND ug/L 50 11/26/13 13:124-Bromofluorobenzene(SS)[FID]

1 VFL 1496 92 % 63-157 11/26/13 13:12

12/20/2013 14:29 Page 5 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830002

DISCOVERY (131120068)


Date Received:

11/20/2013 11:50

11/21/2013 16:50

DF

Lab ID:

Sample ID:








Acenaphthene 1 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Acenaphthylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(b)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(e)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(g,h,i)perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(k)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Biphenyl 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Chrysene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzothiophene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002,6-Dimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluoranthene 10.0040 SMS 3296SPR 62130.008 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluorene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylphenanthrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Naphthalene 1 20.0040 SMS 3296SPR 6213B0.007 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Phenanthrene 10.0040 SMS 3296SPR 62130.008 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Pyrene 10.0040 SMS 3296SPR 62130.008 ug/L 0.005 12/04/13 00:00 12/11/13 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Fluorobiphenyl (SS) 1 SMS 3296SPR 6213103 % 50-150 12/04/13 00:00 12/11/13 00:00Nitrobenzene-d5 (SS) 1 SMS 3296SPR 6213104 % 50-150 12/04/13 00:00 12/11/13 00:00Terphenyl-d14 (SS) 1 SMS 3296SPR 6213108 % 50-150 12/04/13 00:00 12/11/13 00:00

12/20/2013 14:29 Page 6 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830002



Date Received:

11/20/2013 11:50

11/21/2013 16:50

DF

Lab ID:

Sample ID:






Allethrin 1 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:56Bifenthrin 10.1 SMS 3294SPR 6204J1.5 ng/L 1.5 11/23/13 10:24 12/05/13 06:56Chlorpyrifos 10.5 SMS 3294SPR 6204ND ng/L 2.0 11/23/13 10:24 12/05/13 06:56Cyfluthrin 10.2 SMS 3294SPR 6204J0.5 ng/L 1.5 11/23/13 10:24 12/05/13 06:56Lambda-Cyhalothrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:56Cypermethrin 10.2 SMS 3294SPR 6204J0.3 ng/L 1.5 11/23/13 10:24 12/05/13 06:56Diazinon 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:56Deltamethrin:Tralomethrin 10.2 SMS 3294SPR 6204ND ng/L 3.0 11/23/13 10:24 12/05/13 06:56Esfenvalerate:Fenvalerate 10.2 SMS 3294SPR 6204ND ng/L 3.0 11/23/13 10:24 12/05/13 06:56Fenpropathrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:56Tau-Fluvalinate 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:56Permethrin 12 SMS 3294SPR 6204ND ng/L 15 11/23/13 10:24 12/05/13 06:56Tetramethrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 06:56Esfenvalerate-d6;#1 (SS) 1 SMS 3294SPR 620496 % 70-130 11/23/13 10:24 12/05/13 06:56Esfenvalerate-d6;#2 (SS) 1 SMS 3294SPR 620493 % 70-130 11/23/13 10:24 12/05/13 06:56



Analyzed by: AN


1 VFL 1496 94 % 63-157 11/26/13 13:42

12/20/2013 14:29 Page 7 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830003

NIMBUS (131120063)


Date Received:

11/20/2013 12:00

11/21/2013 16:50

DF

Lab ID:

Sample ID:









12/20/2013 14:29 Page 8 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830003

NIMBUS (131120063)


Date Received:

11/20/2013 12:00

11/21/2013 16:50

DF

Lab ID:

Sample ID:






Allethrin 1 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Bifenthrin 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Chlorpyrifos 10.5 SMS 3294SPR 6204ND ng/L 2.0 11/23/13 10:24 12/05/13 07:30Cyfluthrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Lambda-Cyhalothrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Cypermethrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Diazinon 10.1 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Deltamethrin:Tralomethrin 10.2 SMS 3294SPR 6204ND ng/L 3.0 11/23/13 10:24 12/05/13 07:30Esfenvalerate:Fenvalerate 10.2 SMS 3294SPR 6204ND ng/L 3.0 11/23/13 10:24 12/05/13 07:30Fenpropathrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Tau-Fluvalinate 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Permethrin 12 SMS 3294SPR 6204ND ng/L 15 11/23/13 10:24 12/05/13 07:30Tetramethrin 10.2 SMS 3294SPR 6204ND ng/L 1.5 11/23/13 10:24 12/05/13 07:30Esfenvalerate-d6;#1 (SS) 1 SMS 3294SPR 6204110 % 70-130 11/23/13 10:24 12/05/13 07:30Esfenvalerate-d6;#2 (SS) 1 SMS 3294SPR 6204108 % 70-130 11/23/13 10:24 12/05/13 07:30



Analyzed by: AN


1 VFL 1496 97 % 63-157 11/26/13 14:44

12/20/2013 14:29 Page 9 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830004

FREEPORT (131120065)


Date Received:

11/20/2013 13:40

11/21/2013 16:50

DF

Lab ID:

Sample ID:








Acenaphthene 1 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Acenaphthylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(b)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(e)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(g,h,i)perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(k)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Biphenyl 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Chrysene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzothiophene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002,6-Dimethylnaphthalene 10.0040 SMS 3296SPR 62130.006 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluorene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Methylnaphthalene 10.0040 SMS 3296SPR 62130.006 ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylphenanthrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Naphthalene 1 20.0040 SMS 3296SPR 6213BJ0.004 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Phenanthrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Fluorobiphenyl (SS) 1 SMS 3296SPR 6213115 % 50-150 12/04/13 00:00 12/11/13 00:00Nitrobenzene-d5 (SS) 1 SMS 3296SPR 6213101 % 50-150 12/04/13 00:00 12/11/13 00:00Terphenyl-d14 (SS) 1 SMS 3296SPR 6213121 % 50-150 12/04/13 00:00 12/11/13 00:00

12/20/2013 14:29 Page 10 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830004

FREEPORT (131120065)


Date Received:

11/20/2013 13:40

11/21/2013 16:50

DF

Lab ID:

Sample ID:









Analyzed by: AN


1 VFL 1496 92 % 63-157 11/26/13 14:13

12/20/2013 14:29 Page 11 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830005

DISCOVERY FD(131120064)


Date Received:

11/20/2013 11:50

11/21/2013 16:50

DF

Lab ID:

Sample ID:





Acenaphthene 1 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Acenaphthylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(a)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(b)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(e)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(g,h,i)perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Benzo(k)fluoranthene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Biphenyl 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Chrysene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Dibenzothiophene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002,6-Dimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluoranthene 10.0040 SMS 3296SPR 62130.007 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Fluorene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Methylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:001-Methylphenanthrene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Naphthalene 1 20.0040 SMS 3296SPR 6213B0.006 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Perylene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:00Phenanthrene 10.0040 SMS 3296SPR 62130.006 ug/L 0.005 12/04/13 00:00 12/11/13 00:00Pyrene 10.0040 SMS 3296SPR 62130.006 ug/L 0.005 12/04/13 00:00 12/11/13 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3296SPR 6213ND ug/L 0.005 12/04/13 00:00 12/11/13 00:002-Fluorobiphenyl (SS) 1 SMS 3296SPR 6213100 % 50-150 12/04/13 00:00 12/11/13 00:00Nitrobenzene-d5 (SS) 1 SMS 3296SPR 621395 % 50-150 12/04/13 00:00 12/11/13 00:00Terphenyl-d14 (SS) 1 SMS 3296SPR 6213112 % 50-150 12/04/13 00:00 12/11/13 00:00

12/20/2013 14:29 Page 12 of 24





ANALYTICAL RESULTS

Project ID

N110830

AMP 209

Lab Order:

N110830006

EQ. BLANK (131120066)


Date Received:

11/20/2013 12:00

11/21/2013 16:50

DF

Lab ID:

Sample ID:



Methyl Mercury 1 10.020 MHG 4464MPR 12380ND ng/L 0.05 12/03/13 00:00 12/03/13 00:00



12/20/2013 14:29 Page 13 of 24





QUALITY CONTROL DATA

Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

MPR/12380

Draft EPA 1630Analysis Method:

Analysis Description:

Draft EPA 1630

Methyl Mercury Analysis

METHOD BLANK: 553233

Parameter UnitsResult

Blank

Limit

Reporting

QualifiersMDL

Methyl Mercury ND ng/L0.05 0.02

LABORATORY CONTROL SAMPLE:

Parameter Units Conc.

Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

553234

Methyl Mercury 1.1ng/L 1.1 101 67-133

MATRIX SPIKE & MATRIX SPIKE DUPLICATE:


Spike

Result

MS

553236 553237

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830002

Methyl Mercury ng/L 1.1 1.3 106 65-1351.3 107 0.2 350.07

QC Batch:

QC Batch Method:

SPR/6204

SW846 3510CAnalysis Method:


SW846 8270 Mod (GCMS-NCI-SIM)

Pyrethroids Analysis, NCI, Water



Blank

Limit

Reporting

QualifiersMDL

Allethrin ND ng/L1.5 10.1Bifenthrin ND ng/L1.5 0.1Chlorpyrifos ND ng/L2.0 0.5Cyfluthrin ND ng/L1.5 0.2Lambda-Cyhalothrin ND ng/L1.5 0.2Cypermethrin ND ng/L1.5 0.2Diazinon ND ng/L1.5 0.1Deltamethrin:Tralomethrin ND ng/L3.0 0.2Esfenvalerate:Fenvalerate ND ng/L3.0 0.2Fenpropathrin ND ng/L1.5 0.2Tau-Fluvalinate ND ng/L1.5 0.2Permethrin ND ng/L15 2.0Tetramethrin ND ng/L1.5 0.2Esfenvalerate-d6;#1 (SS) 87 %70-130Esfenvalerate-d6;#2 (SS) 83 %70-130




Page 14 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

SPR/6204







Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

551976

Allethrin 20ng/L 16 79 50-150Bifenthrin 20ng/L 19 95 70-165Chlorpyrifos 20ng/L 15 75 45-150Cyfluthrin 20ng/L 20 102 55-140Lambda-Cyhalothrin 20ng/L 14 72 40-120Cypermethrin 20ng/L 20 99 50-130Diazinon 20ng/L 15 76 50-150Deltamethrin:Tralomethrin 40ng/L 38 94 30-105Esfenvalerate:Fenvalerate 40ng/L 35 87 40-140Fenpropathrin 20ng/L 21 105 30-180Tau-Fluvalinate 20ng/L 15 77 30-100Permethrin 100ng/L 96 96 50-160Tetramethrin 20ng/L 17 87 45-140Esfenvalerate-d6;#1 (SS) % 84 70-130Esfenvalerate-d6;#2 (SS) % 83 70-130



Spike

Result

MS

551978 551979

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110820002

Allethrin ng/L 20 15 77 50-150 318 90 15 350Bifenthrin ng/L 20 16 64 70-165 416 68 5 352.9Chlorpyrifos ng/L 20 11 55 45-15013 65 17 350Cyfluthrin ng/L 20 15 68 55-14016 73 6.4 301.6Lambda-Cyhalothrin ng/L 20 13 64 40-12013 63 1.6 350Cypermethrin ng/L 20 15 74 50-13016 78 5.9 300Diazinon ng/L 20 13 65 50-15014 69 5.2 350Deltamethrin:Tralomethrin ng/L 40 25 64 30-10526 66 3.9 400Esfenvalerate:Fenvalerate ng/L 40 26 66 40-14029 72 7.6 350Fenpropathrin ng/L 20 14 70 30-18015 77 10 350Tau-Fluvalinate ng/L 20 12 61 30-10012 63 2.4 400Permethrin ng/L 100 73 73 50-16079 79 8.1 400Tetramethrin ng/L 20 13 64 45-14016 80 22 500Esfenvalerate-d6;#1 (SS) % 64 70-130 569 7.1Esfenvalerate-d6;#2 (SS) % 64 70-130 569 7.3




Page 15 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

SPR/6204







Spike

Result

MS

551980 551981

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830003

Allethrin ng/L 20 25 125 50-15023 113 10 350Bifenthrin ng/L 20 26 130 70-16523 116 11 350Chlorpyrifos ng/L 20 25 122 45-15022 107 13 350Cyfluthrin ng/L 20 28 139 55-14026 128 8.2 300Lambda-Cyhalothrin ng/L 20 23 113 40-12023 114 1.3 350Cypermethrin ng/L 20 28 138 50-130 425 122 12 300Diazinon ng/L 20 25 122 50-15021 106 14 350Deltamethrin:Tralomethrin ng/L 40 51 125 30-105 444 110 13 400Esfenvalerate:Fenvalerate ng/L 40 53 132 40-14046 115 14 350Fenpropathrin ng/L 20 29 142 30-18026 131 7.6 350Tau-Fluvalinate ng/L 20 24 120 30-100 422 107 11 400Permethrin ng/L 100 130 131 50-160120 120 8.7 400Tetramethrin ng/L 20 26 131 45-14020 100 27 500Esfenvalerate-d6;#1 (SS) % 126 70-130109 14Esfenvalerate-d6;#2 (SS) % 125 70-130109 14

QC Batch:

QC Batch Method:

SPR/6213

EPA 625MAnalysis Method:


EPA 625M

625,PAH+Ext,Triple Quad,Analysis



Blank

Limit

Reporting

QualifiersMDL

Acenaphthene ND ug/L0.005 10.004Acenaphthylene ND ug/L0.005 0.004Anthracene ND ug/L0.005 0.004Benzo(a)anthracene ND ug/L0.005 0.004Benzo(a)pyrene ND ug/L0.005 0.004Benzo(b)fluoranthene ND ug/L0.005 0.004Benzo(e)pyrene ND ug/L0.005 0.004Benzo(g,h,i)perylene ND ug/L0.005 0.004Benzo(k)fluoranthene ND ug/L0.005 0.004Biphenyl ND ug/L0.005 0.004Chrysene ND ug/L0.005 0.004Dibenzo(a,h)anthracene ND ug/L0.005 0.004Dibenzothiophene ND ug/L0.005 0.0042,6-Dimethylnaphthalene ND ug/L0.005 0.004Fluoranthene ND ug/L0.005 0.004Fluorene ND ug/L0.005 0.004Indeno(1,2,3-cd)pyrene ND ug/L0.005 0.004




Page 16 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

SPR/6213



EPA 625M



Blank

Limit

Reporting

QualifiersMDL

1-Methylnaphthalene ND ug/L0.005 0.0042-Methylnaphthalene ND ug/L0.005 0.0041-Methylphenanthrene ND ug/L0.005 0.004Naphthalene 0.008 ug/L0.005 20.004Perylene ND ug/L0.005 0.004Phenanthrene ND ug/L0.005 0.004Pyrene ND ug/L0.005 0.0042,3,5-Trimethylnaphthalene ND ug/L0.005 0.0042-Fluorobiphenyl (SS) 94 %50-150Nitrobenzene-d5 (SS) 83 %50-150Terphenyl-d14 (SS) 123 %50-150

LABORATORY CONTROL SAMPLE & LCSD:


Spike

Result

LCS

552475 552476

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

Acenaphthene ug/L 0.02 0.02 84 50-150.02 86 1.8 30Acenaphthylene ug/L 0.02 0.02 82 50-150.02 87 5.9 30Anthracene ug/L 0.02 0.02 77 50-150.02 87 12 30Benzo(a)anthracene ug/L 0.02 0.02 123 50-150.02 114 8 30Benzo(a)pyrene ug/L 0.02 0.02 101 50-150.02 113 12 30Benzo(b)fluoranthene ug/L 0.02 0.02 119 50-150.02 114 4.3 30Benzo(e)pyrene ug/L 0.02 0.02 117 50-150.02 108 8.5 30Benzo(g,h,i)perylene ug/L 0.02 0.02 108 50-150.02 98 10 30Benzo(k)fluoranthene ug/L 0.02 0.02 123 50-150.02 105 16 30Biphenyl ug/L 0.02 0.02 87 50-150.02 93 6.7 30Chrysene ug/L 0.02 0.02 105 50-150.02 97 8.4 30Dibenzo(a,h)anthracene ug/L 0.02 0.03 126 50-150.02 110 13 30Dibenzothiophene ug/L 0.02 0.02 83 50-150.02 86 3.6 302,6-Dimethylnaphthalene ug/L 0.02 0.02 93 50-150.02 94 1.1 30Fluoranthene ug/L 0.02 0.02 108 50-150.02 114 5.4 30Fluorene ug/L 0.02 0.02 86 50-150.02 90 4.6 30Indeno(1,2,3-cd)pyrene ug/L 0.02 0.02 121 50-150.02 108 11 301-Methylnaphthalene ug/L 0.02 0.02 82 50-150.02 90 9.4 302-Methylnaphthalene ug/L 0.02 0.02 88 50-150.02 97 10 301-Methylphenanthrene ug/L 0.02 0.02 98 50-150.02 103 5 30Naphthalene ug/L 0.02 0.02 88 50-150.02 98 11 30Perylene ug/L 0.02 0.02 115 50-150.02 105 9.1 30Phenanthrene ug/L 0.02 0.02 93 50-150.02 96 3.2 30Pyrene ug/L 0.02 0.02 116 50-150.02 122 5.5 302,3,5-Trimethylnaphthalene ug/L 0.02 0.02 85 50-150.02 88 4.1 30




Page 17 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

SPR/6213



EPA 625M




Spike

Result

LCS

552475 552476

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

2-Fluorobiphenyl (SS) % 87 50-15086 1.7Nitrobenzene-d5 (SS) % 82 50-15091 11Terphenyl-d14 (SS) % 125 50-150124 0.8



Spike

Result

MS

552482 552483

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830003

Acenaphthene ug/L 0.02 0.02 92 50-1500.02 87 5 300Acenaphthylene ug/L 0.02 0.02 99 50-1500.02 90 9 300Anthracene ug/L 0.02 0.02 110 50-1500.02 81 29 300Benzo(a)anthracene ug/L 0.02 0.03 132 50-1500.03 144 9.7 300Benzo(a)pyrene ug/L 0.02 0.03 132 50-1500.03 146 11 300Benzo(b)fluoranthene ug/L 0.02 0.03 127 50-1500.03 139 10 300Benzo(e)pyrene ug/L 0.02 0.03 126 50-1500.03 137 9.8 300Benzo(g,h,i)perylene ug/L 0.02 0.02 116 50-1500.03 128 11 300Benzo(k)fluoranthene ug/L 0.02 0.02 124 50-1500.03 134 8.9 300Biphenyl ug/L 0.02 0.02 100 50-1500.02 95 4.1 300Chrysene ug/L 0.02 0.02 110 50-1500.02 120 10 300Dibenzo(a,h)anthracene ug/L 0.02 0.03 129 50-1500.03 143 11 300Dibenzothiophene ug/L 0.02 0.02 100 50-1500.02 87 13 3002,6-Dimethylnaphthalene ug/L 0.02 0.02 107 50-1500.02 99 6.3 300Fluoranthene ug/L 0.02 0.03 135 50-1500.02 110 19 300Fluorene ug/L 0.02 0.02 101 50-1500.02 92 7.8 300Indeno(1,2,3-cd)pyrene ug/L 0.02 0.02 124 50-1500.03 136 10 3001-Methylnaphthalene ug/L 0.02 0.02 102 50-1500.02 91 11 3002-Methylnaphthalene ug/L 0.02 0.02 109 50-1500.02 99 9.1 3001-Methylphenanthrene ug/L 0.02 0.02 119 50-1500.02 103 13 300Naphthalene ug/L 0.02 0.02 112 50-1500.02 101 8.9 300Perylene ug/L 0.02 0.03 126 50-1500.03 139 11 300Phenanthrene ug/L 0.02 0.02 111 50-1500.02 105 4.1 300Pyrene ug/L 0.02 0.03 140 50-1500.03 126 9 3002,3,5-Trimethylnaphthalene ug/L 0.02 0.02 98 50-1500.02 91 6.3 3002-Fluorobiphenyl (SS) % 107 50-15097 8.3Nitrobenzene-d5 (SS) % 106 50-15092 13Terphenyl-d14 (SS) % 116 50-150114 0.9




Page 18 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

SPR/6206

EPA 614Analysis Method:


EPA 614

Organophosphorous Pesticides



Blank

Limit

Reporting

QualifiersMDL

Azinphos methyl (Guthion) ND ug/L0.05 0.04Chlorpyrifos ND ug/L0.01 0.005Demeton -O and -S ND ug/L0.1 0.09Diazinon ND ug/L0.02 0.007Disulfoton (Di-Syston) ND ug/L0.1 0.08Ethion ND ug/L0.02 0.005Malathion ND ug/L0.05 0.005Parathion (Parathion ethyl) ND ug/L0.05 0.008Parathion methyl ND ug/L0.1 0.08Thiobencarb ND ug/L0.05 0.008Dichlofenthion (SS) 84 %45-105Triphenylphosphate (SS) 93 %61-120



Spike

Result

LCS

552125 552126

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

Azinphos methyl (Guthion) ug/L 3 2.5 82 52-1232.7 89 7.8 50Chlorpyrifos ug/L 3 2.3 76 45-1272.5 82 8 50Demeton -O and -S ug/L 3 1.3 44 10-1001.4 45 1.5 50Diazinon ug/L 3 2.2 72 50-1212.3 77 6.3 50Disulfoton (Di-Syston) ug/L 3 1.4 46 10-1141.5 51 8.9 50Ethion ug/L 3 2 65 47-1382.1 69 6 50Malathion ug/L 3 2.3 78 48-1322.5 83 7 50Parathion (Parathion ethyl) ug/L 3 2 66 44-1392.2 72 8.2 50Parathion methyl ug/L 3 2.2 72 49-1242.3 77 7.6 50Thiobencarb ug/L 3 2.3 78 40-1502.6 85 9 50Dichlofenthion (SS) % 73 45-10578 6.9Triphenylphosphate (SS) % 81 61-12086 6.3



Spike

Result

MS

552127 552128

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830003

Azinphos methyl (Guthion) ug/L 3 2 65 52-1232 64 0.5 500Chlorpyrifos ug/L 3 2.6 86 45-1272.5 83 2.7 500Demeton -O and -S ug/L 3 2 65 10-1001.9 62 3.6 500Diazinon ug/L 3 2.4 79 50-1212.4 77 0.4 500




Page 19 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

SPR/6206



EPA 614




Spike

Result

MS

552127 552128

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830003

Disulfoton (Di-Syston) ug/L 3 1.9 64 10-1141.8 60 4.7 500Ethion ug/L 3 2.3 75 47-1382.2 71 4.9 500Malathion ug/L 3 2.7 88 48-1322.6 85 3.4 500Parathion (Parathion ethyl) ug/L 3 1.8 58 44-1391.7 57 1.1 500Parathion methyl ug/L 3 1.9 64 49-1241.9 63 1 500Thiobencarb ug/L 3 2.8 92 40-1502.6 86 5.5 500Dichlofenthion (SS) % 82 45-10580 2Triphenylphosphate (SS) % 91 61-12086 4.7

QC Batch:

QC Batch Method:

SPR/6215



SW846 8015(MOD)

Total Extractable Petroleum Hydrocarbon



Blank

Limit

Reporting

QualifiersMDL

Diesel Fuel ND ug/L50 10Motor Oil ND ug/L200 160o-Terphenyl (SS) 90 %49-124



Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

552606

Diesel Fuel 1000ug/L 907 91 36-120o-Terphenyl (SS) % 97 49-124



Spike

Result

MS

552608 552609

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830003

Diesel Fuel ug/L 1010 901 89 36-120775 78 15 300o-Terphenyl (SS) % 97 49-12490 8.5




Page 20 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:

QC Batch:

QC Batch Method:

VFL/1496

SW846 5030B/8015(MOD)TPPH Gas

Analysis Method:


SW846 5030B/8015(MOD) TPPH Gas

Total Purgeable Petroleum Hydrocarbons



Blank

Limit

Reporting

QualifiersMDL

TPPH - Gasoline Fuel ND ug/L50 264-Bromofluorobenzene (SS)[FID] 100 %80-130



Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

552218

TPPH - Gasoline Fuel 550ug/L 550 100 80-1104-Bromofluorobenzene (SS)[FID] % 103 80-130



Spike

Result

MS

552724 552725

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

N110830003

TPPH - Gasoline Fuel ug/L 550 492 89 80-105508 92 3.2 1804-Bromofluorobenzene(SS)[FID]

% 92 63-15793 1.1




Page 21 of 2412/20/2013 14:29


QUALITY CONTROL DATA QUALIFIERS

Project ID:

N110830

AMP 209

Lab Order:

QUALITY CONTROL PARAMETER QUALIFIERS


NS - means not spiked and will not have recoveries reported for Analyte Spike Amounts

QC Codes Keys: These descriptors are used to help identify the specific QC samples and clarify the report.

MB - Method Blank

Method Blanks are reported to the same Method Detection Limits (MDLs) or Reporting Limits (RLs) as theanalytical samples in the corresponding QC batch.

LCS/LCSD - Laboratory Control Spike / Laboratory Control Spike Duplicate

DUP - Duplicate of Original Sample Matrix

MS/MSD - Matrix Spike / Matrix Spike Duplicate

RPD - Relative Percent Difference

%Recovery - Spike Recovery stated as a percentage



Sample diluted due to a high concentration of non-target analyte(s), resulting in increased reporting limits.3

Matrix Spike recovery(ies) outside control limits: LCS(LCSD) recoveries and RPD are in control. PossibleMatrix interference in QC sample.

4

Due to matrix interferences present in the sample, surrogate recoveries failed to meet the QA/QC acceptancecriteria.

5




Page 22 of 2412/20/2013 14:29


QUALITY CONTROL DATA CROSS REFERENCE TABLE

Project ID:

N110830

AMP 209

Lab Order:

Lab ID Sample ID QC Batch Method Analytical MethodQC Batch BatchAnalytical

N110830001 MPR/12380VETERANS (131120067) MHG/4464Draft EPA 1630 Draft EPA 1630

N110830002 MPR/12380DISCOVERY (131120068) MHG/4464Draft EPA 1630 Draft EPA 1630

N110830003 MPR/12380NIMBUS (131120063) MHG/4464Draft EPA 1630 Draft EPA 1630

N110830004 MPR/12380FREEPORT (131120065) MHG/4464Draft EPA 1630 Draft EPA 1630

N110830005 MPR/12380DISCOVERY FD(131120064)

MHG/4464Draft EPA 1630 Draft EPA 1630

N110830006 MPR/12380EQ. BLANK (131120066) MHG/4464Draft EPA 1630 Draft EPA 1630

N110830001 SPR/6215VETERANS (131120067) SFL/1594SW846 3510C SW846 8015(MOD)

N110830002 SPR/6215DISCOVERY (131120068) SFL/1594SW846 3510C SW846 8015(MOD)

N110830003 SPR/6215NIMBUS (131120063) SFL/1594SW846 3510C SW846 8015(MOD)

N110830004 SPR/6215FREEPORT (131120065) SFL/1594SW846 3510C SW846 8015(MOD)

N110830001 SPR/6204VETERANS (131120067) SMS/3294SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

N110830002 SPR/6204DISCOVERY (131120068) SMS/3294SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

N110830003 SPR/6204NIMBUS (131120063) SMS/3294SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

N110830004 SPR/6204FREEPORT (131120065) SMS/3294SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

N110830001 SPR/6206VETERANS (131120067) SMS/3298EPA 614 EPA 614

N110830002 SPR/6206DISCOVERY (131120068) SMS/3298EPA 614 EPA 614

N110830003 SPR/6206NIMBUS (131120063) SMS/3298EPA 614 EPA 614

N110830004 SPR/6206FREEPORT (131120065) SMS/3298EPA 614 EPA 614

N110830001 SPR/6213VETERANS (131120067) SMS/3296EPA 625M EPA 625M

N110830002 SPR/6213DISCOVERY (131120068) SMS/3296EPA 625M EPA 625M

N110830003 SPR/6213NIMBUS (131120063) SMS/3296EPA 625M EPA 625M

N110830004 SPR/6213FREEPORT (131120065) SMS/3296EPA 625M EPA 625M

N110830005 SPR/6213DISCOVERY FD(131120064)

SMS/3296EPA 625M EPA 625M

N110830006 SPR/6213EQ. BLANK (131120066) SMS/3296EPA 625M EPA 625M

N110830001 VFL/1496VETERANS (131120067) SW8465030B/8015(MOD)TPPH Gas

N110830002 VFL/1496DISCOVERY (131120068) SW8465030B/8015(MOD)TPPH Gas




Page 23 of 2412/20/2013 14:29



Project ID:

N110830

AMP 209

Lab Order:


N110830003 VFL/1496NIMBUS (131120063) SW8465030B/8015(MOD)TPPH Gas

N110830004 VFL/1496FREEPORT (131120065) SW8465030B/8015(MOD)TPPH Gas




Page 24 of 2412/20/2013 14:29


SRCSD

January 02, 2014

Vyomini Upadhyay SRCSD-Policy and Planning 10060 Goethe Rd Sacramento, CA 95827

Work Order No : RE: Project ID:

Dear Vyomini Upadhyay:

AMP 209 53162

Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, November 20, 2013. Results reported herein conform to the most current ELAP standards, where applicable, unless otherwise noted in the body of the report. This report is late and we apologize for any inconvenience this may have caused.


Sincerely,

Michael Cook

[email protected] Program Coordinator

Srividhya Ramamoorthy QA Officer Lab Manager Amy Saylor

Sacramento Regional County Sanitation District

8521 Laguna Station Road Elk Grove, CA 95758

Phone: (916) 875-9000 Fax: (916) 875-9069

SRCSD Environmental Laboratory

REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Sacramento Regional County Sanitation District. ELAP Certification #1100

Print Date: 01/02/2014 Page 1 of 32

SAMPLE SUMMARY

Work Order No:

Project ID:

53162

AMP 209


1311200057 Nimbus Surface Water 11/20/2013 12:00 11/20/2013 13:30

1311200058 Discovery FD Surface Water 11/20/2013 11:50 11/20/2013 15:28

1311200059 Discovery Surface Water 11/20/2013 11:50 11/20/2013 13:30

1311200060 Freeport Surface Water 11/20/2013 13:40 11/20/2013 15:20

1311200061 Veterans Surface Water 11/20/2013 10:30 11/20/2013 13:30

1311200062 Equip Blk Distilled Water 11/20/2013 12:00 11/20/2013 15:28



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200057

Nimbus

Matrix: Surface Water Date Collected:

Date Received:

11/20/2013 12:00

11/20/2013 13:30

Parameter Results RL Units

Lab ID:

Sample ID:

Analyzed MDL By Method DF

BIOLOGICAL

11/20/2013 1.8 MPN/100mL 330 Coliform,Fecal 1 NA JTA SM 9221 E

11/20/2013 1.8 MPN/100mL 330 E.COLI 1 NA JTA SM 9221 F

FIELD ANALYSIS

[1] 11/20/2013 0.10 mg/L 10.4 Dissolved Oxygen,(Field) 1 NA SEF ASTM D888-09

11/20/2013 1.0 umhos/cm 75 EC,Field Measurement 1 NA SEF EPA 120.1

11/20/2013 1.0 NTU 3.7 Turbidity(Field) 1 NA SEF EPA 180.1

11/20/2013 0 degC 13.8 Temperature(C) 1 NA SEF SM 2550 B

11/20/2013 NA Units 6.7 pH,Field Measurement 1 NA SEF SM 4500-H+B

GENERAL WET CHEMISTRY

11/22/2013 0.10 mg/L ND Nitrogen,Ammonia(as N) 1 0.040 KSY EPA 350.1

12/09/2013 0.10 mg/L 0.19 TKN(as N) 1 0.059 KSY EPA 351.2

11/21/2013 0.10 mg/L 0.046J Nitrate(as N) 1 0.0078 JAV EPA 353.2

11/21/2013 0.10 mg/L 0.0013J Nitrite(as N) 1 0.0012 JAV EPA 353.2

12/09/2013 0.050 mg/L ND Phosphorus,Total(as P) 1 0.032 KSY EPA 365.4

11/21/2013 5.0 mg/L ND COD,Total-LowRange 1 NA MJY HA 8000

11/21/2013 5.0 mg/L 28 Alkalinity,Total(as CaCO3) 1 4.0 JDN SM 2320B

11/21/2013 5.0 mg/L 20 Hardness(as CaCO3) 1 2.8 NES SM 2340 C

11/21/2013 20 mg/L 40 TDS 1 NA NES SM 2540 C

11/21/2013 2.5 mg/L 3.5 TSS 1 NA JDN SM 2540 D

12/09/2013 2.0 mg/L 2.0 Chloride 1 0.14 JAV SM 4500-CL E

12/16/2013 0.10 mg/L 0.24 Total Nitrogen (as N) 1 NA MEC SM 4500-N

11/21/2013 2 mg/L ND BOD,5 Day 1 NA NES SM 5210 B

[2] 12/12/2013 0.50 mg/L 3.6 Carbon,Organic,Dissolved 1 0.31 JDN SM 5310 B

12/12/2013 0.50 mg/L 3.2 Carbon,Organic,Total 1 0.15 JDN SM 5310 B



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200057

Nimbus


Date Received:

11/20/2013 12:00

11/20/2013 13:30


Lab ID:

Sample ID:


METALS

12/10/2013 0.00020 ug/L 0.00071 Mercury,Total 1 0.00016 NCH EPA 1631 E

[2] 12/04/2013 0.50 ug/L 0.74 Copper,Dissolved 1 0.35 NCH EPA 200.8

12/05/2013 0.50 ug/L 0.69 Copper,Total Recoverable 1 0.21 NCH EPA 200.8

12/04/2013 0.010 mg/L ND Iron,Dissolved 1 0.0081 NCH EPA 200.8

12/05/2013 10 ug/L 130 Iron,Total Recoverable 1 4.8 NCH EPA 200.8

12/04/2013 0.10 ug/L ND Lead,Dissolved 1 0.062 NCH EPA 200.8

12/05/2013 0.10 ug/L 0.13 Lead,Total Recoverable 1 0.044 NCH EPA 200.8

12/04/2013 1.0 ug/L 1.1 Zinc,Dissolved 1 0.51 NCH EPA 200.8

12/05/2013 1.0 ug/L 2.7 Zinc,Total Recoverable 1 0.71 NCH EPA 200.8

1311200058

Discovery FD


Date Received:

11/20/2013 11:50

11/20/2013 15:28


Lab ID:

Sample ID:



11/22/2013 0.10 mg/L 0.063J Nitrogen,Ammonia(as N) 1 0.040 KSY EPA 350.1


11/21/2013 0.10 mg/L 0.17 Nitrate(as N) 1 0.0078 JAV EPA 353.2


12/09/2013 0.050 mg/L 0.068 Phosphorus,Total(as P) 1 0.032 KSY EPA 365.4

11/21/2013 5.0 mg/L 8.0 COD,Total-LowRange 1 NA MJY HA 8000



11/21/2013 20 mg/L 53 TDS 1 NA NES SM 2540 C



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200058

Discovery FD


Date Received:

11/20/2013 11:50

11/20/2013 15:28


Lab ID:

Sample ID:



11/21/2013 2.5 mg/L 4.2 TSS 1 NA JDN SM 2540 D



11/21/2013 2 mg/L 4.8 BOD,5 Day 1 NA NES SM 5210 B



METALS

[3] 12/10/2013 0.00020 ug/L 0.0016 Mercury,Total 1 0.00016 NCH EPA 1631 E

12/04/2013 0.50 ug/L 1.5 Copper,Dissolved 1 0.35 NCH EPA 200.8


12/04/2013 10 ug/L ND Iron,Dissolved 1 8.1 NCH EPA 200.8

12/05/2013 0.010 mg/L 0.14 Iron,Total Recoverable 1 0.0048 NCH EPA 200.8

12/04/2013 0.10 ug/L 0.081J Lead,Dissolved 1 0.062 NCH EPA 200.8




1311200059

Discovery


Date Received:

11/20/2013 11:50

11/20/2013 13:30


Lab ID:

Sample ID:


BIOLOGICAL

11/20/2013 1.8 MPN/100mL 9,200 Coliform,Fecal 1 NA JTA SM 9221 E

11/20/2013 1.8 MPN/100mL 5,400 E.COLI 1 NA JTA SM 9221 F



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200059

Discovery


Date Received:

11/20/2013 11:50

11/20/2013 13:30


Lab ID:

Sample ID:


FIELD ANALYSIS

11/20/2013 0.10 mg/L 9.6 Dissolved Oxygen,(Field) 1 NA MEC ASTM D888-09

11/20/2013 1.0 umhos/cm 70.0 EC,Field Measurement 1 NA MEC EPA 120.1

11/20/2013 1.0 NTU 11 Turbidity(Field) 1 NA MEC EPA 180.1

11/20/2013 0 degC 13.7 Temperature(C) 1 NA MEC SM 2550 B

11/20/2013 NA Units 7.3 pH,Field Measurement 1 NA MEC SM 4500-H+B


11/22/2013 0.10 mg/L 0.059J Nitrogen,Ammonia(as N) 1 0.040 KSY EPA 350.1








11/21/2013 20 mg/L 49 TDS 1 NA NES SM 2540 C

11/21/2013 2.5 mg/L 4.0 TSS 1 NA JDN SM 2540 D




12/12/2013 0.50 mg/L 5.9 Carbon,Organic,Dissolved 1 0.31 JDN SM 5310 B


METALS

[3] 12/10/2013 0.20 ng/L 2.3 Mercury,Total 1 0.16 NCH EPA 1631 E




Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200059

Discovery


Date Received:

11/20/2013 11:50

11/20/2013 13:30


Lab ID:

Sample ID:


METALS




12/04/2013 0.10 ug/L 0.15 Lead,Dissolved 1 0.062 NCH EPA 200.8




1311200060

Freeport Matrix: Surface Water Date Collected:

Date Received:

11/20/2013 13:40

11/20/2013 15:20


Lab ID:

Sample ID:


BIOLOGICAL



FIELD ANALYSIS


11/20/2013 1.0 umhos/cm 178 EC,Field Measurement 1 NA MEC EPA 120.1

11/20/2013 1.0 NTU 8.4 Turbidity(Field) 1 NA MEC EPA 180.1








Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200060


Date Received:

11/20/2013 13:40

11/20/2013 15:20


Lab ID:

Sample ID:









11/21/2013 20 mg/L 110 TDS 1 NA NES SM 2540 C

11/21/2013 2.5 mg/L 5.2 TSS 1 NA JDN SM 2540 D






METALS

12/10/2013 0.20 ng/L 1.1 Mercury,Total 1 0.16 NCH EPA 1631 E







[3] 12/04/2013 1.0 ug/L 4.1 Zinc,Dissolved 1 0.51 NCH EPA 200.8




Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200061

Veterans


Date Received:

11/20/2013 10:30

11/20/2013 13:30


Lab ID:

Sample ID:


BIOLOGICAL



FIELD ANALYSIS















11/21/2013 20 mg/L 110 TDS 1 NA NES SM 2540 C

11/21/2013 2.5 mg/L 5.7 TSS 1 NA JDN SM 2540 D



11/21/2013 2 mg/L ND BOD,5 Day 1 NA NES SM 5210 B





Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53162

AMP 209

1311200061

Veterans


Date Received:

11/20/2013 10:30

11/20/2013 13:30


Lab ID:

Sample ID:


METALS










1311200062

Equip Blk

Matrix: Distilled Water Date Collected:

Date Received:

11/20/2013 12:00

11/20/2013 15:28


Lab ID:

Sample ID:


METALS

12/10/2013 0.20 ng/L ND Mercury,Total 1 0.16 NCH EPA 1631 E

12/05/2013 0.50 ug/L ND Copper,Total Recoverable 1 0.21 NCH EPA 200.8

12/05/2013 10 ug/L ND Iron,Total Recoverable 1 4.8 NCH EPA 200.8

12/05/2013 0.10 ug/L ND Lead,Total Recoverable 1 0.044 NCH EPA 200.8




Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS QUALIFIERS

Work Order No:

Project ID:

53162

AMP 209

PARAMETER QUALIFIERS

J - The analytical result is below RL but above MDL.

MDL - Method Detection Limit defined in 40 CFR, Sect. 136, Appendix B.

ND - Non Detect - indicates an analytical result that has not been detected below the MDL or, in the absence of a MDL, below the RL.

RL - Reporting limit is the quantitation limit at which the laboratory is able to detect an analyte with a certain degree of confidence. Generally, this represents the parameter's lowest calibration point. This can also define the customer's requirement.

(S) - Surrogates

DF - Dilution Factor

NA - Not Applicable

Sample run outside of holding time due to faulty sensor. [1]

Dissolved greater than total, but within acceptable 20% analytical variation. [2]

Value confirmed by second analysis. [3]



Phone: (916) 875-9000 Fax: (916) 875-9069






Phone: (916) 875-9000 Fax: (916) 875-9069



Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

OD/11330

SM 5210 B

Analysis Method:


SM 5210 B

5-Day BOD Test

Associated Lab Samples: 1311200057 1311200058 1311200059 1311200060 1311200061 1311210037


Parameter LCS

% Rec % Rec Limits

200819

Qualifier

BOD,5 Day 106 85-115



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

OD/11331

HA 8000

Analysis Method:


HA 8000

COD by Colorimetry

Associated Lab Samples: 1311200057 1311200058 1311200059 1311200060 1311200061 1311210038 1311210042 Associated Lab Samples:


Associated Lab Samples: 1311200059 1311200060 1311200058 1311200057 1311200061

Parameter Units Result Blank

Limit Reporting

Qualifier MDL

COD,Total-LowRange ND mg/L 5.0 NA


Parameter LCS

% Rec % Rec Limits

200822

Qualifier

COD,Total-LowRange 96 84-119



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

GEWC/11561

SM 2340 C

Analysis Method:


SM 2340 C

Total Hardness by Titrimetry





Limit Reporting

Qualifier MDL

Hardness(as CaCO3) ND mg/L 5.0 2.8


Parameter LCS

% Rec % Rec Limits

200828

Qualifier

Hardness(as CaCO3) 96 90-110


Parameter

200829 200830

% Rec MS MSD

% Rec % Rec Limits RPD RPD

Max Associated Lab Sample: 1311200057

Qualifier

Hardness(as CaCO3) 100 90-110 100 0 2.38



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

METP/4280

Dissolved Metals

Analysis Method:


Dissolved Metals

Dissolved Metals Prep





Limit Reporting

Qualifier MDL

Copper,Dissolved ND ug/L 0.50 0.35

Iron,Dissolved ND mg/L 0.010 0.0081

Lead,Dissolved ND ug/L 0.10 0.062

Zinc,Dissolved ND ug/L 1.0 0.51


Parameter LCS

% Rec % Rec Limits

200832

Qualifier

Copper,Dissolved 99 85-115

Iron,Dissolved 101 85-115

Lead,Dissolved 111 85-115

Zinc,Dissolved 111 85-115


Parameter

200833 200834

% Rec MS MSD



Qualifier

Copper,Dissolved 95 70-130 96 0.12 13.8

Iron,Dissolved 100 70-130 100 0.23 15



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209


Parameter

200833 200834

% Rec MS MSD



Qualifier

Lead,Dissolved 110 70-130 111 0.5 15

Zinc,Dissolved 111 70-130 112 1.1 12.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

METP/4281

Total Recoverable Metals

Analysis Method:



Total Recoverable Metals Prep





Limit Reporting

Qualifier MDL

Copper,Total Recoverable ND ug/L 0.50 0.21

Iron,Total Recoverable ND ug/L 10 4.8

Lead,Total Recoverable ND ug/L 0.10 0.044

Zinc,Total Recoverable ND ug/L 1.0 0.71


Parameter

200836 200837

% Rec LCS LCSD

% Rec % Rec Limit RPD RPD

Max

Copper,Total Recoverable 97 85-115 97 0.011 16.6

Iron,Total Recoverable 94 85-115 96 1.9 15.4

Lead,Total Recoverable 109 85-115 110 0.45 16.3

Zinc,Total Recoverable 112 85-115 114 1.7 22.3


Parameter

200838 200839

% Rec MS MSD



Qualifier


Iron,Total Recoverable 109 70-130 94 11 15.4



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209


Parameter

200838 200839

% Rec MS MSD



Qualifier

Lead,Total Recoverable 120 70-130 108 10 16.3




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

SLDS/36722

SM 2540 D

Analysis Method:


SM 2540 D

Residue-Nonfilterable,Grav, 103-105C

Associated Lab Samples: 1311200057 1311200058 1311200059 1311200060 1311200061 1311200077 1311200078 1311210041 1311210037 1311200082 1311200080 1311200079 Associated Lab Samples: 1311210043 1311210044




Limit Reporting

Qualifier MDL

TSS ND mg/L 2.5 NA

SAMPLE DUPLICATE:

Parameter Max RPD

200840

1311200057

RPD

Associated Lab Sample:

Qualifier

TSS 10 5.6

SAMPLE DUPLICATE:

Parameter Max RPD

200842

1311210043

RPD


Qualifier

TSS 10 0



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

SLDS/36723

SM 2540 C

Analysis Method:


SM 2540 C

Residue,Filterable,Dried at 180C

Associated Lab Samples: 1311200057 1311200058 1311200059 1311200060 1311200061 1311200077 1311200078 1311200082 1311200080 1311200079 Associated Lab Samples:




Limit Reporting

Qualifier MDL

TDS ND mg/L 20 NA


Parameter LCS

% Rec % Rec Limits

200858

Qualifier

TDS 102 93-110

SAMPLE DUPLICATE:

Parameter Max RPD

200856

1311200057

RPD


Qualifier

TDS 14 7.2

SAMPLE DUPLICATE:

Parameter Max RPD

200857

1311200041

RPD


Qualifier

TDS 14 8.3



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

LACH/5959

EPA 353.2

Analysis Method:


EPA 353.2

Nitrate-Nitrite Nitrogen by Colorimetry

Associated Lab Samples: 1311180053 1311190049 1311190050 1311190051 1311190052 1311200057 1311200058 1311210041 1311200061 1311200060 1311200059 Associated Lab Samples:




Limit Reporting

Qualifier MDL

Nitrite(as N) ND mg/L 0.10 0.0012

Nitrate(as N) ND mg/L 0.10 0.0078


Parameter LCS

% Rec % Rec Limits

200860

Qualifier

Nitrate(as N) 104 90-110


Parameter LCS

% Rec % Rec Limits

200870

Qualifier



Parameter LCS

% Rec % Rec Limits

200871

Qualifier

Nitrite(as N) 109 90-110



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209


Parameter

200862 200863

% Rec MS MSD



Qualifier

Nitrate(as N) 104 90-110 104 0.59 10


Parameter

200864 200865

% Rec MS MSD



Qualifier

Nitrite(as N) 108 90-110 108 0.07

10


Parameter

200866 200867

% Rec MS MSD



Qualifier

Nitrate(as N) 94 90-110 96 1.5 10


Parameter

200868 200869

% Rec MS MSD



Qualifier

Nitrite(as N) 105 90-110 102 2.1 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

GEWC/11562

SM 2320B

Analysis Method:


SM 2320B

Alkalinity by Titrimetry





Limit Reporting

Qualifier MDL

Alkalinity,Total(as CaCO3) ND mg/L 5.0 4.0


Parameter LCS

% Rec % Rec Limits

200880

Qualifier

Alkalinity,Total(as CaCO3) 99 93-105


Parameter

200881 200882

% Rec MS MSD



Qualifier

Alkalinity,Total(as CaCO3) 100 92-105 99 0.5 2.5



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

LACH/5961

EPA 350.1

Analysis Method:


EPA 350.1

Ammonia by Automated Colorimetry

Associated Lab Samples: 1311190049 1311190050 1311190051 1311190052 1311200057 1311200058 1311200059 1311220048 1311210042 1311210038 1311200061 1311200060 Associated Lab Samples:




Limit Reporting

Qualifier MDL

Nitrogen,Ammonia(as N) ND mg/L 0.10 0.040


Parameter LCS

% Rec % Rec Limits

200914

Qualifier

Nitrogen,Ammonia(as N) 99 90-110


Parameter LCS

% Rec % Rec Limits

200916

Qualifier



Parameter

200917 200918

% Rec MS MSD



Qualifier

Nitrogen,Ammonia(as N) 98 90-110 96 2 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

LACH/5990

EPA 351.2

Analysis Method:


EPA 351.2

TKN by Block Digestion & Colorimetry





Limit Reporting

Qualifier MDL

TKN(as N) ND mg/L 0.10 0.059


Parameter LCS

% Rec % Rec Limits

201534

Qualifier

TKN(as N) 106 90-110


Parameter LCS

% Rec % Rec Limits

201537

Qualifier

TKN(as N) 105 90-110


Parameter

201538 201539

% Rec MS MSD



Qualifier

TKN(as N) 96 90-110 104 6.8 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

LACH/5991

EPA 365.4

Analysis Method:


EPA 365.4

Phosphorus by Automated Colorimetry





Limit Reporting

Qualifier MDL

Phosphorus,Total(as P) ND mg/L 0.050 0.032


Parameter LCS

% Rec % Rec Limits

201540

Qualifier

Phosphorus,Total(as P) 102 90-110


Parameter LCS

% Rec % Rec Limits

201542

Qualifier



Parameter

201544 201545

% Rec MS MSD



Qualifier

Phosphorus,Total(as P) 99 90-110 103 3.6 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

LACH/5992

SM 4500-CL E

Analysis Method:


SM 4500-CL E

Chloride by Automated Colorimetry





Limit Reporting

Qualifier MDL

Chloride 0.22J mg/L 2.0 0.14


Parameter LCS

% Rec % Rec Limits

201572

Qualifier

Chloride 93 90-110


Parameter LCS

% Rec % Rec Limits

201575

Qualifier

Chloride 97 90-110


Parameter

201405 201406

% Rec MS MSD



Qualifier

Chloride 99 90-110 97 2 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

CVAF/1577

EPA 1631 E

Analysis Method:


EPA 1631 E

EPA 1631,Mercury,Instrument QC





Limit Reporting

Qualifier MDL

Mercury,Total ND ng/L 0.20 0.16




Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209


Parameter LCS

% Rec % Rec Limits

201641

Qualifier

Mercury,Total 99 79-119


Parameter

201642 201643

% Rec MS MSD



Qualifier

Mercury,Total 99 72-125 98 0.29 16.4



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209

QC Batch:

QC Batch Method:

TOC/1420

SM 5310 B

Analysis Method:


SM 5310 B

Carbon,Organic by Combustion,Oxidation





Limit Reporting

Qualifier MDL

Carbon,Organic,Total ND mg/L 0.50 0.15

Carbon,Organic,Dissolved ND mg/L 0.50 0.31


Parameter LCS

% Rec % Rec Limits

201834

Qualifier

Carbon,Organic,Total 94 81-120

Carbon,Organic,Dissolved 89 87-110


Parameter LCS

% Rec % Rec Limits

201843

Qualifier



Parameter

201839 201840

% Rec MS MSD



Qualifier



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209


Parameter

201839 201840

% Rec MS MSD



Qualifier

Carbon,Organic,Dissolved 84 75-120 84 0.27 7.6


Parameter

201841 201842

% Rec MS MSD



Qualifier

Carbon,Organic,Total 86 68-120 86 0.09

6.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53162

AMP 209


Result Qualifiers:These descriptors are used to help identify the specific QC samples and clarify the report.

MB - Method Blank

LCS - Laboratory Control Standard


MS/MSD - Matrix Spike/Matrix Spike Duplicate

RPD -Relative Percent Difference

% Rec - Spike Recovery stated as a percentage



Phone: (916) 875-9000 Fax: (916) 875-9069





CMP 210


Caltest

Tuesday, March 18, 2014



Dear Michael Cook:

AMP 210P020495 Collected By:

PO/Contract #:Michael Cook81095515

Enclosed are the analytical results for sample(s) received by the laboratory on Friday, February 07, 2014. Results reportedherein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report.


Enclosures


NELAP/ORELAP Certification 4036 CA-ELAP Certification 1664



Page 1 of 253/18/2014 16:43


SAMPLE SUMMARY

Project ID:

P020495

AMP 210

Lab Order:


P020495001 VETERANS (1402060075) Water 2/6/2014 10:30 2/7/2014 12:10

P020495002 DISCOVERY (1402060072) Water 2/6/2014 11:45 2/7/2014 12:10

P020495003 NIMBUS (1402060081) Water 2/6/2014 12:40 2/7/2014 12:10

P020495004 FREEPORT (1402060074) Water 2/6/2014 13:20 2/7/2014 12:10

P020495005 NIMBUS FD (1402060076) Water 2/6/2014 12:40 2/7/2014 12:10

P020495006 EQ. BLK (1402060073) Water 2/6/2014 10:30 2/7/2014 12:10




Page 2 of 253/18/2014 16:43


NARRATIVE

Project ID:

P020495

AMP 210

Lab Order:


















Workorder Notes

Revised to include necessary QC qualifiers.



Spike recovery for this compound was low, outside of Caltest acceptance criteria. Any sample result reportedfor this compound should be considered estimated.

2





Page 3 of 253/18/2014 16:43


NARRATIVE

Project ID:

P020495

AMP 210

Lab Order:


Surrogates did not meet Caltest internal acceptance criteria. The sample passes all pertinent method criteria.4




Page 4 of 253/18/2014 16:43


ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495001

VETERANS (1402060075)


Date Received:

2/6/2014 10:30

2/7/2014 12:10

DF

Lab ID:

Sample ID:





Prep Method: SW846 3510C Prep by: MDT




3/18/2014 16:43 Page 5 of 25


NELAP Accreditation 4036 ELAP Certification 1664



ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495001

VETERANS (1402060075)


Date Received:

2/6/2014 10:30

2/7/2014 12:10

DF

Lab ID:

Sample ID:



Azinphos methyl (Guthion) 1 1,20.04 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 06:39Chlorpyrifos 10.005 SMS 3365SPR 6310ND ug/L 0.01 02/12/14 18:05 02/22/14 06:39Demeton -O and -S 10.09 SMS 3365SPR 6310ND ug/L 0.1 02/12/14 18:05 02/22/14 06:39Diazinon 10.007 SMS 3365SPR 6310ND ug/L 0.02 02/12/14 18:05 02/22/14 06:39Disulfoton (Di-Syston) 10.08 SMS 3365SPR 6310ND ug/L 0.1 02/12/14 18:05 02/22/14 06:39Ethion 10.005 SMS 3365SPR 6310ND ug/L 0.02 02/12/14 18:05 02/22/14 06:39Malathion 10.005 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 06:39Parathion (Parathion ethyl) 10.008 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 06:39Parathion methyl 1 20.08 SMS 3365SPR 6310ND ug/L 0.1 02/12/14 18:05 02/22/14 06:39Thiobencarb 10.008 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 06:39Dichlofenthion (SS) 1 SMS 3365SPR 631054 % 45-105 02/12/14 18:05 02/22/14 06:39Triphenylphosphate (SS) 1 SMS 3365SPR 631063 % 61-120 02/12/14 18:05 02/22/14 06:39

Pyrethroids Analysis, NCI, Water Prep Method: SW846 3510C Prep by: MDTAnalytical Method: SW846 8270 Mod (GCMS-

NCI-SIM)Analyzed by: MDT

Allethrin 1 10.1 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Bifenthrin 10.1 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Chlorpyrifos 10.5 SMS 3357SPR 6300ND ng/L 2.0 02/09/14 12:32 02/12/14 16:55Cyfluthrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Lambda-Cyhalothrin 1 30.2 SMS 3357SPR 6300BJ0.209 ng/L 1.5 02/09/14 12:32 02/12/14 16:55Cypermethrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Diazinon 10.1 SMS 3357SPR 6300J0.4 ng/L 1.5 02/09/14 12:32 02/12/14 16:55Deltamethrin:Tralomethrin 10.2 SMS 3357SPR 6300ND ng/L 3.0 02/09/14 12:32 02/12/14 16:55Esfenvalerate:Fenvalerate 10.2 SMS 3357SPR 6300ND ng/L 3.0 02/09/14 12:32 02/12/14 16:55Fenpropathrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Tau-Fluvalinate 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Permethrin 12 SMS 3357SPR 6300ND ng/L 15 02/09/14 12:32 02/12/14 16:55Tetramethrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 16:55Esfenvalerate-d6;#1 (SS) 1 SMS 3357SPR 630075 % 70-130 02/09/14 12:32 02/12/14 16:55Esfenvalerate-d6;#2 (SS) 1 SMS 3357SPR 630075 % 70-130 02/09/14 12:32 02/12/14 16:55



Analyzed by: AN


1 VFL 1510 101 % 63-157 02/12/14 14:34

3/18/2014 16:43 Page 6 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495002



Date Received:

2/6/2014 11:45

2/7/2014 12:10

DF

Lab ID:

Sample ID:



Methyl Mercury 10.020 MHG 4520MPR 12523J0.04 ng/L 0.05 02/13/14 00:00 02/13/14 00:00





Acenaphthene 1 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Acenaphthylene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Anthracene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Benzo(a)anthracene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Benzo(a)pyrene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Benzo(b)fluoranthene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Benzo(e)pyrene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Benzo(g,h,i)perylene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Benzo(k)fluoranthene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Biphenyl 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Chrysene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Dibenzothiophene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:002,6-Dimethylnaphthalene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Fluoranthene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Fluorene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:001-Methylnaphthalene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:002-Methylnaphthalene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:001-Methylphenanthrene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Naphthalene 10.0040 SMS 3367SPR 6313J0.004 ug/L 0.005 02/13/14 00:00 02/23/14 00:00Perylene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Phenanthrene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:00Pyrene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3367SPR 6313ND ug/L 0.005 02/13/14 00:00 02/23/14 00:002-Fluorobiphenyl (SS) 1 SMS 3367SPR 631385 % 30-150 02/13/14 00:00 02/23/14 00:00Nitrobenzene-d5 (SS) 1 SMS 3367SPR 631374 % 30-150 02/13/14 00:00 02/23/14 00:00Terphenyl-d14 (SS) 1 SMS 3367SPR 6313115 % 30-150 02/13/14 00:00 02/23/14 00:00

3/18/2014 16:44 Page 7 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495002



Date Received:

2/6/2014 11:45

2/7/2014 12:10

DF

Lab ID:

Sample ID:



Azinphos methyl (Guthion) 1 1,20.04 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 08:01Chlorpyrifos 10.005 SMS 3365SPR 6310ND ug/L 0.01 02/12/14 18:05 02/22/14 08:01Demeton -O and -S 10.09 SMS 3365SPR 6310ND ug/L 0.1 02/12/14 18:05 02/22/14 08:01Diazinon 10.007 SMS 3365SPR 6310ND ug/L 0.02 02/12/14 18:05 02/22/14 08:01Disulfoton (Di-Syston) 10.08 SMS 3365SPR 6310ND ug/L 0.1 02/12/14 18:05 02/22/14 08:01Ethion 10.005 SMS 3365SPR 6310ND ug/L 0.02 02/12/14 18:05 02/22/14 08:01Malathion 10.005 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 08:01Parathion (Parathion ethyl) 10.008 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 08:01Parathion methyl 1 20.08 SMS 3365SPR 6310ND ug/L 0.1 02/12/14 18:05 02/22/14 08:01Thiobencarb 10.008 SMS 3365SPR 6310ND ug/L 0.05 02/12/14 18:05 02/22/14 08:01Dichlofenthion (SS) 1 SMS 3365SPR 631051 % 45-105 02/12/14 18:05 02/22/14 08:01Triphenylphosphate (SS) 1 4SMS 3365SPR 631055 % 61-120 02/12/14 18:05 02/22/14 08:01






Analyzed by: AN


1 VFL 1510 113 % 63-157 02/12/14 14:03

3/18/2014 16:44 Page 8 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495003

NIMBUS (1402060081)


Date Received:

2/6/2014 12:40

2/7/2014 12:10

DF

Lab ID:

Sample ID:









3/18/2014 16:44 Page 9 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495003

NIMBUS (1402060081)


Date Received:

2/6/2014 12:40

2/7/2014 12:10

DF

Lab ID:

Sample ID:









Analyzed by: AN


1 VFL 1510 99 % 63-157 02/12/14 13:33

3/18/2014 16:45 Page 10 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495004

FREEPORT (1402060074)


Date Received:

2/6/2014 13:20

2/7/2014 12:10

DF

Lab ID:

Sample ID:









3/18/2014 16:45 Page 11 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495004

FREEPORT (1402060074)


Date Received:

2/6/2014 13:20

2/7/2014 12:10

DF

Lab ID:

Sample ID:






Allethrin 1 10.1 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Bifenthrin 10.1 SMS 3357SPR 6300J0.2 ng/L 1.5 02/09/14 12:32 02/12/14 20:14Chlorpyrifos 10.5 SMS 3357SPR 6300ND ng/L 2.0 02/09/14 12:32 02/12/14 20:14Cyfluthrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Lambda-Cyhalothrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Cypermethrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Diazinon 10.1 SMS 3357SPR 6300J0.4 ng/L 1.5 02/09/14 12:32 02/12/14 20:14Deltamethrin:Tralomethrin 10.2 SMS 3357SPR 6300ND ng/L 3.0 02/09/14 12:32 02/12/14 20:14Esfenvalerate:Fenvalerate 10.2 SMS 3357SPR 6300ND ng/L 3.0 02/09/14 12:32 02/12/14 20:14Fenpropathrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Tau-Fluvalinate 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Permethrin 12 SMS 3357SPR 6300ND ng/L 15 02/09/14 12:32 02/12/14 20:14Tetramethrin 10.2 SMS 3357SPR 6300ND ng/L 1.5 02/09/14 12:32 02/12/14 20:14Esfenvalerate-d6;#1 (SS) 1 SMS 3357SPR 630078 % 70-130 02/09/14 12:32 02/12/14 20:14Esfenvalerate-d6;#2 (SS) 1 SMS 3357SPR 630077 % 70-130 02/09/14 12:32 02/12/14 20:14



Analyzed by: AN


1 VFL 1510 104 % 63-157 02/12/14 13:02

3/18/2014 16:45 Page 12 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495005

NIMBUS FD (1402060076)


Date Received:

2/6/2014 12:40

2/7/2014 12:10

DF

Lab ID:

Sample ID:






P020495006

EQ. BLK (1402060073)


Date Received:

2/6/2014 10:30

2/7/2014 12:10

DF

Lab ID:

Sample ID:


3/18/2014 16:45 Page 13 of 25





ANALYTICAL RESULTS

Project ID

P020495

AMP 210

Lab Order:

P020495006

EQ. BLK (1402060073)


Date Received:

2/6/2014 10:30

2/7/2014 12:10

DF

Lab ID:

Sample ID:






3/18/2014 16:46 Page 14 of 25






Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

MPR/12523



Draft EPA 1630




Blank

Limit

Reporting

QualifiersMDL




Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

565282

Methyl Mercury 1.1ng/L 1 92 67-133



Spike

Result

MS

565284 565285

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001


QC Batch:

QC Batch Method:

SPR/6300







Blank

Limit

Reporting

QualifiersMDL

Allethrin ND ng/L1.5 10.1Bifenthrin ND ng/L1.5 0.1Chlorpyrifos ND ng/L2.0 0.5Cyfluthrin ND ng/L1.5 0.2Lambda-Cyhalothrin J0.3 ng/L1.5 30.2Cypermethrin ND ng/L1.5 0.2Diazinon ND ng/L1.5 0.1Deltamethrin:Tralomethrin ND ng/L3.0 0.2Esfenvalerate:Fenvalerate ND ng/L3.0 0.2Fenpropathrin ND ng/L1.5 0.2Tau-Fluvalinate ND ng/L1.5 0.2Permethrin ND ng/L15 2.0Tetramethrin ND ng/L1.5 0.2Esfenvalerate-d6;#1 (SS) 94 %70-130Esfenvalerate-d6;#2 (SS) 89 %70-130




Page 15 of 253/18/2014 16:46



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

SPR/6300







Spike

Result

LCS

564070 564071

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

Allethrin ng/L 20 13 66 50-15014 69 4.5 35Bifenthrin ng/L 20 18 89 70-16518 90 0.6 35Chlorpyrifos ng/L 20 14 70 45-15015 77 8.9 35Cyfluthrin ng/L 20 16 82 55-14017 86 4.8 30Lambda-Cyhalothrin ng/L 20 14 70 40-12015 77 8.9 35Cypermethrin ng/L 20 17 87 50-13018 90 4 30Diazinon ng/L 20 15 74 50-15016 79 6.6 35Deltamethrin:Tralomethrin ng/L 40 28 69 30-10528 71 2.5 40Esfenvalerate:Fenvalerate ng/L 40 31 77 40-14032 80 4.1 35Fenpropathrin ng/L 20 20 98 30-18020 101 3 35Tau-Fluvalinate ng/L 20 14 71 30-10015 75 5.5 40Permethrin ng/L 100 85 85 50-16092 92 8 40Tetramethrin ng/L 20 14 69 45-14012 61 12 50Esfenvalerate-d6;#1 (SS) % 93 70-13098 71Esfenvalerate-d6;#2 (SS) % 88 70-13094 72



Spike

Result

MS

564489 564490

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001

Allethrin ng/L 20 9.5 47 50-150 59 44 6.2 350Bifenthrin ng/L 20 15 76 70-16515 75 0.7 350Chlorpyrifos ng/L 20 14 71 45-15014 70 2.1 350Cyfluthrin ng/L 20 16 80 55-14016 79 1.2 300Lambda-Cyhalothrin ng/L 20 12 61 40-12012 60 0.8 350.2Cypermethrin ng/L 20 16 81 50-13016 81 0 300Diazinon ng/L 20 15 73 50-15014 68 6.1 350.4Deltamethrin:Tralomethrin ng/L 40 21 52 30-10522 54 4.7 400Esfenvalerate:Fenvalerate ng/L 40 32 78 40-14032 78 0.3 350Fenpropathrin ng/L 20 16 82 30-18016 81 1.2 350Tau-Fluvalinate ng/L 20 15 73 30-10015 72 0.7 400Permethrin ng/L 100 75 74 50-16071 70 5.1 400Tetramethrin ng/L 20 7.6 37 45-140 56.9 34 9.4 500Esfenvalerate-d6;#1 (SS) % 74 70-13073 1.1Esfenvalerate-d6;#2 (SS) % 73 70-13074 0.9




Page 16 of 253/18/2014 16:46



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

SPR/6312



SW846 8015(MOD)




Blank

Limit

Reporting

QualifiersMDL




Spike

Result

LCS

565257 565258

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

Diesel Fuel ug/L 1000 878 88 36-120836 84 4.9 30o-Terphenyl (SS) % 100 49-12494 6.6



Spike

Result

MS

565259 565260

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001


QC Batch:

QC Batch Method:

SPR/6310



EPA 614




Blank

Limit

Reporting

QualifiersMDL

Azinphos methyl (Guthion) ND ug/L0.05 0.04Chlorpyrifos ND ug/L0.01 0.005Demeton -O and -S ND ug/L0.1 0.09Diazinon ND ug/L0.02 0.007Disulfoton (Di-Syston) ND ug/L0.1 0.08Ethion ND ug/L0.02 0.005Malathion ND ug/L0.05 0.005Parathion (Parathion ethyl) ND ug/L0.05 0.008Parathion methyl ND ug/L0.1 0.08Thiobencarb ND ug/L0.05 0.008Dichlofenthion (SS) 58 %45-105Triphenylphosphate (SS) 54 %61-120 4




Page 17 of 253/18/2014 16:46



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

SPR/6310



EPA 614




Spike

Result

LCS

565102 565103

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

Azinphos methyl (Guthion) ug/L 3 1.5 49 52-123 21.6 53 6.5 50Chlorpyrifos ug/L 3 1.5 50 45-1271.5 50 0.7 50Demeton -O and -S ug/L 3 1.1 35 10-100.9 31 14 50Diazinon ug/L 3 1.6 53 50-1211.6 52 2.5 50Disulfoton (Di-Syston) ug/L 3 1.2 38 10-1141 33 14 50Ethion ug/L 3 1.6 52 47-1381.6 54 3.2 50Malathion ug/L 3 1.4 48 48-1321.4 48 0.7 50Parathion (Parathion ethyl) ug/L 3 1.6 52 44-1391.6 54 3.8 50Parathion methyl ug/L 3 1.3 43 49-124 21.3 44 2.3 50Thiobencarb ug/L 3 1.3 45 40-1501.3 44 1.5 50Dichlofenthion (SS) % 56 45-10556 0Triphenylphosphate (SS) % 60 61-120 461 2.3



Spike

Result

MS

565104 565105

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001

Azinphos methyl (Guthion) ug/L 3 1.6 51 52-123 21.4 46 10 500Chlorpyrifos ug/L 3 1.6 54 45-1271.5 48 11 500Demeton -O and -S ug/L 3 1.2 38 10-1000.9 30 23 500Diazinon ug/L 3 1.6 53 50-121 51.4 44 16 500Disulfoton (Di-Syston) ug/L 3 1.2 39 10-1141 33 17 500Ethion ug/L 3 1.6 52 47-138 51.4 47 11 500Malathion ug/L 3 1.5 50 48-132 51.4 44 11 500Parathion (Parathion ethyl) ug/L 3 1.7 55 44-1391.5 50 8.8 500Parathion methyl ug/L 3 1.4 45 49-124 21.2 40 11 500Thiobencarb ug/L 3 1.5 49 40-1501.3 44 9.3 500Dichlofenthion (SS) % 59 45-10550 15Triphenylphosphate (SS) % 63 61-120 457 8.9

QC Batch:

QC Batch Method:

SPR/6313



EPA 625M




Blank

Limit

Reporting

QualifiersMDL

Acenaphthene ND ug/L0.005 10.004




Page 18 of 253/18/2014 16:46



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

SPR/6313



EPA 625M



Blank

Limit

Reporting

QualifiersMDL

Acenaphthylene ND ug/L0.005 0.004Anthracene ND ug/L0.005 0.004Benzo(a)anthracene ND ug/L0.005 0.004Benzo(a)pyrene ND ug/L0.005 0.004Benzo(b)fluoranthene ND ug/L0.005 0.004Benzo(e)pyrene ND ug/L0.005 0.004Benzo(g,h,i)perylene ND ug/L0.005 0.004Benzo(k)fluoranthene ND ug/L0.005 0.004Biphenyl ND ug/L0.005 0.004Chrysene ND ug/L0.005 0.004Dibenzo(a,h)anthracene ND ug/L0.005 0.004Dibenzothiophene ND ug/L0.005 0.0042,6-Dimethylnaphthalene ND ug/L0.005 0.004Fluoranthene ND ug/L0.005 0.004Fluorene ND ug/L0.005 0.004Indeno(1,2,3-cd)pyrene ND ug/L0.005 0.0041-Methylnaphthalene ND ug/L0.005 0.0042-Methylnaphthalene ND ug/L0.005 0.0041-Methylphenanthrene ND ug/L0.005 0.004Naphthalene ND ug/L0.005 0.004Perylene ND ug/L0.005 0.004Phenanthrene ND ug/L0.005 0.004Pyrene ND ug/L0.005 0.0042,3,5-Trimethylnaphthalene ND ug/L0.005 0.0042-Fluorobiphenyl (SS) 63 %30-150Nitrobenzene-d5 (SS) 65 %30-150Terphenyl-d14 (SS) 103 %30-150



Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

565308

Acenaphthene 0.02ug/L 0.01 58 30-150Acenaphthylene 0.02ug/L 0.02 85 30-150Anthracene 0.02ug/L 0.02 96 30-150Benzo(a)anthracene 0.02ug/L 0.02 111 30-150Benzo(a)pyrene 0.02ug/L 0.02 124 30-150Benzo(b)fluoranthene 0.02ug/L 0.02 118 30-150Benzo(e)pyrene 0.02ug/L 0.02 109 30-150Benzo(g,h,i)perylene 0.02ug/L 0.02 111 30-150Benzo(k)fluoranthene 0.02ug/L 0.02 110 30-150




Page 19 of 253/18/2014 16:47



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

SPR/6313



EPA 625M




Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

565308

Biphenyl 0.02ug/L 0.02 77 30-150Chrysene 0.02ug/L 0.02 97 30-150Dibenzo(a,h)anthracene 0.02ug/L 0.03 126 30-150Dibenzothiophene 0.02ug/L 0.01 71 30-1502,6-Dimethylnaphthalene 0.02ug/L 0.01 68 30-150Fluoranthene 0.02ug/L 0.02 107 30-150Fluorene 0.02ug/L 0.01 75 30-150Indeno(1,2,3-cd)pyrene 0.02ug/L 0.03 131 30-1501-Methylnaphthalene 0.02ug/L 0.01 73 30-1502-Methylnaphthalene 0.02ug/L 0.01 71 30-1501-Methylphenanthrene 0.02ug/L 0.02 93 30-150Naphthalene 0.02ug/L 0.01 62 30-150Perylene 0.02ug/L 0.03 127 30-150Phenanthrene 0.02ug/L 0.02 84 30-150Pyrene 0.02ug/L 0.02 110 30-1502,3,5-Trimethylnaphthalene 0.02ug/L 0.01 67 30-1502-Fluorobiphenyl (SS) % 71 30-150Nitrobenzene-d5 (SS) % 71 30-150Terphenyl-d14 (SS) % 114 30-150



Spike

Result

MS

565310 565311

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001

Acenaphthene ug/L 0.02 0.01 59 30-1500.01 68 13 300Acenaphthylene ug/L 0.02 0.02 74 30-1500.02 88 17 300Anthracene ug/L 0.02 0.02 90 30-1500.02 112 21 300Benzo(a)anthracene ug/L 0.02 0.02 104 30-1500.02 112 7.2 300Benzo(a)pyrene ug/L 0.02 0.02 117 30-1500.03 123 5.7 300Benzo(b)fluoranthene ug/L 0.02 0.02 114 30-1500.02 118 3.4 300Benzo(e)pyrene ug/L 0.02 0.02 104 30-1500.02 108 4.2 300Benzo(g,h,i)perylene ug/L 0.02 0.02 101 30-1500.02 104 2.4 300Benzo(k)fluoranthene ug/L 0.02 0.02 101 30-1500.02 107 5.2 300Biphenyl ug/L 0.02 0.01 70 30-1500.02 78 11 300Chrysene ug/L 0.02 0.02 93 30-1500.02 98 4.6 300Dibenzo(a,h)anthracene ug/L 0.02 0.02 115 30-1500.02 117 1.7 300Dibenzothiophene ug/L 0.02 0.01 66 30-1500.02 76 14 3002,6-Dimethylnaphthalene ug/L 0.02 0.01 71 30-1500.02 80 13 300Fluoranthene ug/L 0.02 0.02 98 30-1500.02 109 11 300




Page 20 of 253/18/2014 16:47



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

SPR/6313



EPA 625M




Spike

Result

MS

565310 565311

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001

Fluorene ug/L 0.02 0.01 71 30-1500.02 82 15 300Indeno(1,2,3-cd)pyrene ug/L 0.02 0.02 121 30-1500.02 120 0.8 3001-Methylnaphthalene ug/L 0.02 0.02 75 30-1500.02 86 13 3002-Methylnaphthalene ug/L 0.02 0.02 74 30-1500.02 86 15 3001-Methylphenanthrene ug/L 0.02 0.02 87 30-1500.02 96 9.1 300Naphthalene ug/L 0.02 0.01 66 30-1500.02 82 21 300Perylene ug/L 0.02 0.02 122 30-1500.03 128 5.1 300Phenanthrene ug/L 0.02 0.02 76 30-1500.02 87 14 300Pyrene ug/L 0.02 0.02 101 30-1500.02 113 11 3002,3,5-Trimethylnaphthalene ug/L 0.02 0.01 66 30-1500.02 75 13 3002-Fluorobiphenyl (SS) % 70 30-15081 14Nitrobenzene-d5 (SS) % 69 30-15078 13Terphenyl-d14 (SS) % 105 30-150115 8.5

QC Batch:

QC Batch Method:

VFL/1510


Analysis Method:






Blank

Limit

Reporting

QualifiersMDL




Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

564599

TPPH - Gasoline Fuel 550ug/L 514 94 80-1104-Bromofluorobenzene (SS)[FID] % 98 80-130



Spike

Result

MS

565571 565572

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001

TPPH - Gasoline Fuel ug/L 550 464 84 80-105474 86 2.2 180




Page 21 of 253/18/2014 16:47



Project ID:

P020495

AMP 210

Lab Order:

QC Batch:

QC Batch Method:

VFL/1510


Analysis Method:






Spike

Result

MS

565571 565572

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P020495001

4-Bromofluorobenzene(SS)[FID]

% 94 63-15794 0.3




Page 22 of 253/18/2014 16:47



Project ID:

P020495

AMP 210

Lab Order:





MB - Method Blank








Spike recovery for this compound was low, outside of Caltest acceptance criteria. Any sample result reportedfor this compound should be considered estimated.

2



Matrix Spike recovery(ies) outside control limits: LCS(LCSD) recoveries and RPD are in control. PossibleMatrix interference in QC sample.

5




Page 23 of 253/18/2014 16:47



Project ID:

P020495

AMP 210

Lab Order:


P020495001 MPR/12523VETERANS (1402060075) MHG/4520Draft EPA 1630 Draft EPA 1630

P020495002 MPR/12523DISCOVERY (1402060072) MHG/4520Draft EPA 1630 Draft EPA 1630

P020495003 MPR/12523NIMBUS (1402060081) MHG/4520Draft EPA 1630 Draft EPA 1630

P020495004 MPR/12523FREEPORT (1402060074) MHG/4520Draft EPA 1630 Draft EPA 1630

P020495005 MPR/12523NIMBUS FD (1402060076) MHG/4520Draft EPA 1630 Draft EPA 1630

P020495006 MPR/12523EQ. BLK (1402060073) MHG/4520Draft EPA 1630 Draft EPA 1630

P020495001 SPR/6312VETERANS (1402060075) SFL/1606SW846 3510C SW846 8015(MOD)

P020495002 SPR/6312DISCOVERY (1402060072) SFL/1606SW846 3510C SW846 8015(MOD)

P020495003 SPR/6312NIMBUS (1402060081) SFL/1606SW846 3510C SW846 8015(MOD)

P020495004 SPR/6312FREEPORT (1402060074) SFL/1606SW846 3510C SW846 8015(MOD)

P020495001 SPR/6300VETERANS (1402060075) SMS/3357SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P020495002 SPR/6300DISCOVERY (1402060072) SMS/3357SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P020495003 SPR/6300NIMBUS (1402060081) SMS/3357SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P020495004 SPR/6300FREEPORT (1402060074) SMS/3357SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P020495001 SPR/6310VETERANS (1402060075) SMS/3365EPA 614 EPA 614

P020495002 SPR/6310DISCOVERY (1402060072) SMS/3365EPA 614 EPA 614

P020495003 SPR/6310NIMBUS (1402060081) SMS/3365EPA 614 EPA 614

P020495004 SPR/6310FREEPORT (1402060074) SMS/3365EPA 614 EPA 614

P020495001 SPR/6313VETERANS (1402060075) SMS/3367EPA 625M EPA 625M

P020495002 SPR/6313DISCOVERY (1402060072) SMS/3367EPA 625M EPA 625M

P020495003 SPR/6313NIMBUS (1402060081) SMS/3367EPA 625M EPA 625M

P020495004 SPR/6313FREEPORT (1402060074) SMS/3367EPA 625M EPA 625M

P020495005 SPR/6313NIMBUS FD (1402060076) SMS/3367EPA 625M EPA 625M

P020495006 SPR/6313EQ. BLK (1402060073) SMS/3367EPA 625M EPA 625M

P020495001 VFL/1510VETERANS (1402060075) SW8465030B/8015(MOD)TPPH Gas

P020495002 VFL/1510DISCOVERY (1402060072) SW8465030B/8015(MOD)TPPH Gas




Page 24 of 253/18/2014 16:47



Project ID:

P020495

AMP 210

Lab Order:


P020495003 VFL/1510NIMBUS (1402060081) SW8465030B/8015(MOD)TPPH Gas

P020495004 VFL/1510FREEPORT (1402060074) SW8465030B/8015(MOD)TPPH Gas




Page 25 of 253/18/2014 16:47



SRCSD

March 06, 2014




AMP 210 53864

Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, February 06, 2014. Results reported herein conform to the most current ELAP standards, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Michael Cook


Srividhya Ramamoorthy QA Officer Lab Manager Amy Saylor



Phone: (916) 875-9000 Fax: (916) 875-9069




SAMPLE SUMMARY

Work Order No:

Project ID:

53864

AMP 210



1402060080 Nimbus FD Surface Water 02/06/2014 12:40 02/06/2014 13:55







Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060070

Discovery


Date Received:

2/6/2014 11:45

2/6/2014 14:30


Lab ID:

Sample ID:


BIOLOGICAL



FIELD ANALYSIS







02/14/2014 0.10 mg/L ND Nitrogen,Ammonia(as N) 1 0.040 RLH EPA 350.1

02/26/2014 0.10 mg/L 0.062J TKN(as N) 1 0.059 KSY EPA 351.2

02/07/2014 0.10 mg/L 0.070J Nitrate(as N) 1 0.0078 RLH EPA 353.2

02/07/2014 0.10 mg/L 0.0025J Nitrite(as N) 1 0.0012 RLH EPA 353.2

02/26/2014 0.050 mg/L 0.048J Phosphorus,Total(as P) 1 0.032 KSY EPA 365.4



02/10/2014 5.0 mg/L 26 Hardness(as CaCO3) 1 2.8 SEF SM 2340 C

02/07/2014 20 mg/L 57 TDS 1 NA NES SM 2540 C

02/07/2014 2.0 mg/L ND TSS 1 NA NES SM 2540 D



02/07/2014 2 mg/L ND BOD,5 Day 1 NA JDN SM 5210 B

[2] 02/19/2014 0.50 mg/L 3.7 Carbon,Organic,Dissolved 1 0.31 CEP SM 5310 B

02/19/2014 0.50 mg/L 2.7 Carbon,Organic,Total 1 0.15 CEP SM 5310 B



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060070

Discovery


Date Received:

2/6/2014 11:45

2/6/2014 14:30


Lab ID:

Sample ID:


METALS







02/24/2014 0.10 ug/L 0.094J Lead,Total Recoverable 1 0.043 NCH EPA 200.8



1402060071

Equip Blk


Date Received:

2/6/2014 10:30

2/6/2014 14:30


Lab ID:

Sample ID:


METALS






1402060077

Nimbus


Date Received:

2/6/2014 12:40

2/6/2014 13:55


Lab ID:

Sample ID:




Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060077

Nimbus


Date Received:

2/6/2014 12:40

2/6/2014 13:55


Lab ID:

Sample ID:


BIOLOGICAL


02/06/2014 1.8 MPN/100mL 7.8 E.COLI 1 NA JTA SM 9221 F

FIELD ANALYSIS

02/06/2014 0.10 mg/L 10.6 Dissolved Oxygen,(Field) 1 NA NES ASTM D888-09

02/06/2014 1.0 umhos/cm 79 EC,Field Measurement 1 NA NES EPA 120.1

02/06/2014 1.0 NTU 1.3 Turbidity(Field) 1 NA NES EPA 180.1

02/06/2014 0 degC 9.12 Temperature(C) 1 NA NES SM 2550 B

02/06/2014 NA Units 7.4 pH,Field Measurement 1 NA NES SM 4500-H+B





02/07/2014 0.10 mg/L ND Nitrite(as N) 1 0.0012 RLH EPA 353.2





02/07/2014 20 mg/L 51 TDS 1 NA NES SM 2540 C









Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060077

Nimbus


Date Received:

2/6/2014 12:40

2/6/2014 13:55


Lab ID:

Sample ID:


METALS










1402060078


Date Received:

2/6/2014 13:20

2/6/2014 14:30


Lab ID:

Sample ID:


BIOLOGICAL



FIELD ANALYSIS









Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060078


Date Received:

2/6/2014 13:20

2/6/2014 14:30


Lab ID:

Sample ID:











02/07/2014 20 mg/L 150 TDS 1 NA NES SM 2540 C

02/07/2014 2.5 mg/L 7.0 TSS 1 NA NES SM 2540 D



02/07/2014 2 mg/L 2.2 BOD,5 Day 1 NA JDN SM 5210 B

02/19/2014 0.50 mg/L 7.3 Carbon,Organic,Dissolved 1 0.31 CEP SM 5310 B


METALS




02/24/2014 10 ug/L 9.8J Iron,Dissolved 1 8.1 NCH EPA 200.8







Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060078


Date Received:

2/6/2014 13:20

2/6/2014 14:30


Lab ID:

Sample ID:


METALS


1402060079

Veterans


Date Received:

2/6/2014 10:30

2/6/2014 14:30


Lab ID:

Sample ID:


BIOLOGICAL

02/06/2014 1.8 MPN/100mL 7.8 Coliform,Fecal 1 NA JTA SM 9221 E

02/06/2014 1.8 MPN/100mL 7.8 E.COLI 1 NA JTA SM 9221 F

FIELD ANALYSIS



02/06/2014 1.0 NTU 16 Turbidity(Field) 1 NA MEC EPA 180.1














Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060079

Veterans


Date Received:

2/6/2014 10:30

2/6/2014 14:30


Lab ID:

Sample ID:



02/07/2014 20 mg/L 150 TDS 1 NA NES SM 2540 C

02/07/2014 2.5 mg/L 14 TSS 1 NA NES SM 2540 D






METALS




02/24/2014 10 ug/L 15 Iron,Dissolved 1 8.1 NCH EPA 200.8






1402060080

Nimbus FD


Date Received:

2/6/2014 12:40

2/6/2014 13:55


Lab ID:

Sample ID:






Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

53864

AMP 210

1402060080

Nimbus FD


Date Received:

2/6/2014 12:40

2/6/2014 13:55


Lab ID:

Sample ID:



02/26/2014 0.10 mg/L ND TKN(as N) 1 0.059 KSY EPA 351.2


02/07/2014 0.10 mg/L ND Nitrite(as N) 1 0.0012 RLH EPA 353.2





02/07/2014 20 mg/L 51 TDS 1 NA NES SM 2540 C



03/03/2014 0.10 mg/L ND Total Nitrogen (as N) 1 NA MEC SM 4500-N




METALS



[3] 02/24/2014 0.50 ug/L 0.65 Copper,Total Recoverable 1 0.20 NCH EPA 200.8





[4] 02/24/2014 1.0 ug/L 0.81J Zinc,Dissolved 1 0.51 NCH EPA 200.8

[4] 02/24/2014 1.0 ug/L 1.4 Zinc,Total Recoverable 1 0.70 NCH EPA 200.8



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210




ND - Non Detect - Analyte not detected above the MDL or, in the absence of a MDL, above the RL.


(S) - Surrogates


NA - Not Applicable

Dissolved is greater than total recoverable. Results confirmed by a second analysis. [1]

Dissolved is greater than total due to unknown reason. [2]

Dissolved greater than total, but within the accepted analytical variation. [3]

Field Duplicate RPD verified by second analysis.

[4]



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

LACH/6133

EPA 353.2

Analysis Method:


EPA 353.2


Associated Lab Samples: 1402060050 1402060058 1402060060 1402060062 1402060070 1402060077 1402060078 1402060080 1402060079 Associated Lab Samples:




Limit Reporting

Qualifier MDL




Parameter LCS

% Rec % Rec Limits

204535

Qualifier



Parameter LCS

% Rec % Rec Limits

204541

Qualifier



Parameter LCS

% Rec % Rec Limits

204542

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter

204537 204538

% Rec MS MSD



Qualifier

Nitrate(as N) 98 90-110 99 0.77 10


Parameter

204539 204540

% Rec MS MSD



Qualifier

Nitrite(as N) 98 90-110 100 1.6 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

SLDS/37230

SM 2540 D

Analysis Method:


SM 2540 D






Limit Reporting

Qualifier MDL

TSS ND mg/L 2.5 NA

SAMPLE DUPLICATE:

Parameter Max RPD

204543

1402060079

RPD


Qualifier

TSS 10 2.8

SAMPLE DUPLICATE:

Parameter Max RPD

204545

1402060011

RPD


Qualifier

TSS 10 9.2



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

OD/11487

SM 5210 B

Analysis Method:


SM 5210 B

5-Day BOD Test



Parameter LCS

% Rec % Rec Limits

204551

Qualifier

BOD,5 Day 93 85-115



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

OD/11488

HA 8000

Analysis Method:


HA 8000

COD by Colorimetry





Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

204554

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

SLDS/37232

SM 2540 C

Analysis Method:


SM 2540 C


Associated Lab Samples: 1402060070 1402060077 1402060078 1402060079 1402060080 1402060093 1402060095 1402060097 1402060096 Associated Lab Samples:




Limit Reporting

Qualifier MDL

TDS ND mg/L 20 NA


Parameter LCS

% Rec % Rec Limits

204567

Qualifier

TDS 99 93-110

SAMPLE DUPLICATE:

Parameter Max RPD

204565

1402060079

RPD


Qualifier

TDS 14 3.3



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

GEWC/11698

SM 2320B

Analysis Method:


SM 2320B






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

204569

Qualifier



Parameter

204570 204571

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

GEWC/11699

SM 2340 C

Analysis Method:


SM 2340 C


Associated Lab Samples: 1402050007 1402050074 1402060003 1402060042 1402060043 1402060044 1402060066 1402060080 1402060079 1402060078 1402060077 1402060070 Associated Lab Samples: 1402070064




Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

204617

Qualifier



Parameter

204618 204619

% Rec MS MSD



Qualifier

Hardness(as CaCO3) 102 90-110 102 0 2.38



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

METP/4347


Analysis Method:








Limit Reporting

Qualifier MDL




Zinc,Total Recoverable 0.90J ug/L 1.0 0.70


Parameter

204687 204688

% Rec LCS LCSD


Max






Parameter

204689 204690

% Rec MS MSD



Qualifier





Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter

204689 204690

% Rec MS MSD



Qualifier





Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

METP/4350

Dissolved Metals

Analysis Method:


Dissolved Metals






Limit Reporting

Qualifier MDL


Iron,Dissolved ND ug/L 10 8.1




Parameter

204702 204703

% Rec LCS LCSD


Max


Iron,Dissolved 104 85-115 105 0.81 15

Lead,Dissolved 94 85-115 95 0.56 15

Zinc,Dissolved 96 85-115 96 0.75 12.9


Parameter

204704 204705

% Rec MS MSD



Qualifier


Iron,Dissolved 102 70-130 102 0.42 15



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter

204704 204705

% Rec MS MSD



Qualifier

Lead,Dissolved 92 70-130 92 0.72 15

Zinc,Dissolved 98 70-130 97 0.36 12.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

CVAF/1586

EPA 1631 E

Analysis Method:


EPA 1631 E






Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter LCS

% Rec % Rec Limits

204707

Qualifier



Parameter

204708 204709

% Rec MS MSD



Qualifier

Mercury,Total 101 72-125 102 0.25 16.4



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

LACH/6145

EPA 350.1

Analysis Method:


EPA 350.1


Associated Lab Samples: 1402050055 1402050056 1402050057 1402050058 1402050074 1402050083 1402050087 1402060051 1402060048 1402050099 1402050096 1402050094 Associated Lab Samples: 1402060059 1402060061 1402060064 1402060070 1402060077 1402060078 1402060079 1402060080




Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

204909

Qualifier



Parameter LCS

% Rec % Rec Limits

204913

Qualifier



Parameter

204911 204912

% Rec MS MSD



Qualifier



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter

204911 204912

% Rec MS MSD



Qualifier

Nitrogen,Ammonia(as N) 103 90-110 104 0.2 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

TOC/1424

SM 5310 B

Analysis Method:


SM 5310 B






Limit Reporting

Qualifier MDL




Parameter LCS

% Rec % Rec Limits

205173

Qualifier



Parameter

205178 205179

% Rec MS MSD



Qualifier



Parameter

205180 205181

% Rec MS MSD



Qualifier



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter

205180 205181

% Rec MS MSD



Qualifier

Carbon,Organic,Total 98 67-124 96 1.8 6.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

LACH/6161

SM 4500-CL E

Analysis Method:


SM 4500-CL E






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205198

Qualifier

Chloride 99 90-110


Parameter LCS

% Rec % Rec Limits

205204

Qualifier

Chloride 99 90-110


Parameter LCS

% Rec % Rec Limits

205205

Qualifier

Chloride 94 90-110



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210


Parameter

205200 205201

% Rec MS MSD



Qualifier

Chloride 90 90-110 90 0.27 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

LACH/6176

EPA 351.2

Analysis Method:


EPA 351.2


Associated Lab Samples: 1402060070 1402060077 1402060078 1402060079 1402060080 1402110034 1402110035 1402180043 1402180042 1402180041 1402110037 1402110036 Associated Lab Samples: 1402180044 1402250033 1402250034 1402250035 1402250036




Limit Reporting

Qualifier MDL

TKN(as N) ND mg/L 0.10 0.059


Parameter LCS

% Rec % Rec Limits

205495

Qualifier

TKN(as N) 105 90-110


Parameter LCS

% Rec % Rec Limits

205500

Qualifier

TKN(as N) 102 90-110


Parameter

205498 205499

% Rec MS MSD



Qualifier

TKN(as N) 99 90-110 96 2.8 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210

QC Batch:

QC Batch Method:

LACH/6177

EPA 365.4

Analysis Method:


EPA 365.4






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205501

Qualifier



Parameter LCS

% Rec % Rec Limits

205505

Qualifier



Parameter

205503 205504

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

53864

AMP 210



MB - Method Blank








Phone: (916) 875-9000 Fax: (916) 875-9069





CMP 211


Caltest

Thursday, April 03, 2014



Dear Michael Cook:

AMP 211P021287 Collected By:

PO/Contract #:M. COOK

Enclosed are the analytical results for sample(s) received by the laboratory on Friday, February 28, 2014. Results reportedherein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report.


Enclosures





Page 1 of 244/3/2014 09:19


SAMPLE SUMMARY

Project ID:

P021287

AMP 211

Lab Order:


P021287001 VETERANS (1402270071) Water 2/27/2014 11:50 2/28/2014 15:51


P021287003 NIMBUS (1402270077) Water 2/27/2014 12:15 2/28/2014 15:51

P021287004 FREEPORT (1402270070) Water 2/27/2014 08:35 2/28/2014 15:51

P021287005 FREEPORT FD (1402270072) Water 2/27/2014 08:35 2/28/2014 15:51

P021287006 EQ. BLNK (1402270069) Water 2/27/2014 08:35 2/28/2014 15:51




Page 2 of 244/3/2014 09:19


NARRATIVE

Project ID:

P021287

AMP 211

Lab Order:




















Surrogate recoveries were not within QC Acceptance Criteria.2





Page 3 of 244/3/2014 09:19


ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287001

VETERANS (1402270071)


Date Received:

2/27/2014 11:50

2/28/2014 15:51

DF

Lab ID:

Sample ID:







625,PAH+Ext,Triple Quad,Analysis Prep Method: EPA 625M Prep by: ECBAnalytical Method: EPA 625M Analyzed by: RLH

Acenaphthene 1 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Acenaphthylene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Anthracene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(a)anthracene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(a)pyrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(b)fluoranthene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(e)pyrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(g,h,i)perylene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(k)fluoranthene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Biphenyl 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Chrysene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Dibenzothiophene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002,6-Dimethylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Fluoranthene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Fluorene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:001-Methylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002-Methylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:001-Methylphenanthrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Naphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Perylene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Phenanthrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Pyrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002-Fluorobiphenyl (SS) 1 2SMS 3386SPR 634429 % 30-150 03/05/14 14:29 03/13/14 00:00Nitrobenzene-d5 (SS) 1 2SMS 3386SPR 634427 % 30-150 03/05/14 14:29 03/13/14 00:00Terphenyl-d14 (SS) 1 SMS 3386SPR 634496 % 30-150 03/05/14 14:29 03/13/14 00:00

4/3/2014 09:19 Page 4 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287001

VETERANS (1402270071)


Date Received:

2/27/2014 11:50

2/28/2014 15:51

DF

Lab ID:

Sample ID:


Organophosphorous Pesticides Prep Method: EPA 614 Prep by: EABAnalytical Method: EPA 614 Analyzed by: NTA

Azinphos methyl (Guthion) 1 10.04 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 12:58Chlorpyrifos 10.005 SMS 3390SPR 6347ND ug/L 0.01 03/06/14 00:00 03/18/14 12:58Demeton -O and -S 10.09 SMS 3390SPR 6347ND ug/L 0.1 03/06/14 00:00 03/18/14 12:58Diazinon 10.007 SMS 3390SPR 6347ND ug/L 0.02 03/06/14 00:00 03/18/14 12:58Disulfoton (Di-Syston) 10.08 SMS 3390SPR 6347ND ug/L 0.1 03/06/14 00:00 03/18/14 12:58Ethion 10.005 SMS 3390SPR 6347ND ug/L 0.02 03/06/14 00:00 03/18/14 12:58Malathion 10.005 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 12:58Parathion (Parathion ethyl) 10.008 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 12:58Parathion methyl 10.08 SMS 3390SPR 6347ND ug/L 0.1 03/06/14 00:00 03/18/14 12:58Thiobencarb 10.008 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 12:58Dichlofenthion (SS) 1 SMS 3390SPR 6347100 % 45-105 03/06/14 00:00 03/18/14 12:58Triphenylphosphate (SS) 1 SMS 3390SPR 6347108 % 61-120 03/06/14 00:00 03/18/14 12:58



Allethrin 1 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Bifenthrin 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Chlorpyrifos 10.5 SMS 3397SPR 6339J0.7 ng/L 2.0 03/02/14 18:06 03/22/14 15:26Cyfluthrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Lambda-Cyhalothrin 10.2 SMS 3397SPR 6339J0.2 ng/L 1.5 03/02/14 18:06 03/22/14 15:26Cypermethrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Diazinon 10.1 SMS 3397SPR 6339J0.4 ng/L 1.5 03/02/14 18:06 03/22/14 15:26Deltamethrin:Tralomethrin 10.2 SMS 3397SPR 6339ND ng/L 3.0 03/02/14 18:06 03/22/14 15:26Esfenvalerate:Fenvalerate 10.2 SMS 3397SPR 6339ND ng/L 3.0 03/02/14 18:06 03/22/14 15:26Fenpropathrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Tau-Fluvalinate 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Permethrin 12 SMS 3397SPR 6339ND ng/L 15 03/02/14 18:06 03/22/14 15:26Tetramethrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 15:26Esfenvalerate-d6;#1 (SS) 1 SMS 3397SPR 633975 % 70-130 03/02/14 18:06 03/22/14 15:26Esfenvalerate-d6;#2 (SS) 1 SMS 3397SPR 633973 % 70-130 03/02/14 18:06 03/22/14 15:26



Analyzed by: AN


1 VFL 1514 93 % 63-157 03/05/14 19:54

4/3/2014 09:19 Page 5 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287002



Date Received:

2/27/2014 10:25

2/28/2014 15:51

DF

Lab ID:

Sample ID:








Acenaphthene 1 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Acenaphthylene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Anthracene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(a)anthracene 10.0040 SMS 3386SPR 63440.007 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(a)pyrene 10.0040 SMS 3386SPR 63440.01 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(b)fluoranthene 10.0040 SMS 3386SPR 63440.02 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(e)pyrene 10.0040 SMS 3386SPR 63440.01 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(g,h,i)perylene 10.0040 SMS 3386SPR 63440.02 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Benzo(k)fluoranthene 10.0040 SMS 3386SPR 63440.005 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Biphenyl 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Chrysene 10.0040 SMS 3386SPR 63440.01 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Dibenzo(a,h)anthracene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Dibenzothiophene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002,6-Dimethylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Fluoranthene 10.0040 SMS 3386SPR 63440.01 ug/L 0.005 03/05/14 14:29 03/13/14 00:00Fluorene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Indeno(1,2,3-cd)pyrene 10.0040 SMS 3386SPR 63440.01 ug/L 0.005 03/05/14 14:29 03/13/14 00:001-Methylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002-Methylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:001-Methylphenanthrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Naphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Perylene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Phenanthrene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:00Pyrene 10.0040 SMS 3386SPR 63440.02 ug/L 0.005 03/05/14 14:29 03/13/14 00:002,3,5-Trimethylnaphthalene 10.0040 SMS 3386SPR 6344ND ug/L 0.005 03/05/14 14:29 03/13/14 00:002-Fluorobiphenyl (SS) 1 SMS 3386SPR 634455 % 30-150 03/05/14 14:29 03/13/14 00:00Nitrobenzene-d5 (SS) 1 SMS 3386SPR 634457 % 30-150 03/05/14 14:29 03/13/14 00:00Terphenyl-d14 (SS) 1 SMS 3386SPR 6344110 % 30-150 03/05/14 14:29 03/13/14 00:00

4/3/2014 09:20 Page 6 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287002



Date Received:

2/27/2014 10:25

2/28/2014 15:51

DF

Lab ID:

Sample ID:



Azinphos methyl (Guthion) 1 10.04 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 13:25Chlorpyrifos 10.005 SMS 3390SPR 6347ND ug/L 0.01 03/06/14 00:00 03/18/14 13:25Demeton -O and -S 10.09 SMS 3390SPR 6347ND ug/L 0.1 03/06/14 00:00 03/18/14 13:25Diazinon 10.007 SMS 3390SPR 6347ND ug/L 0.02 03/06/14 00:00 03/18/14 13:25Disulfoton (Di-Syston) 10.08 SMS 3390SPR 6347ND ug/L 0.1 03/06/14 00:00 03/18/14 13:25Ethion 10.005 SMS 3390SPR 6347ND ug/L 0.02 03/06/14 00:00 03/18/14 13:25Malathion 10.005 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 13:25Parathion (Parathion ethyl) 10.008 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 13:25Parathion methyl 10.08 SMS 3390SPR 6347ND ug/L 0.1 03/06/14 00:00 03/18/14 13:25Thiobencarb 10.008 SMS 3390SPR 6347ND ug/L 0.05 03/06/14 00:00 03/18/14 13:25Dichlofenthion (SS) 1 3SMS 3390SPR 6347106 % 45-105 03/06/14 00:00 03/18/14 13:25Triphenylphosphate (SS) 1 SMS 3390SPR 6347112 % 61-120 03/06/14 00:00 03/18/14 13:25






Analyzed by: AN


1 VFL 1514 87 % 63-157 03/05/14 21:26

4/3/2014 09:20 Page 7 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287003

NIMBUS (1402270077)


Date Received:

2/27/2014 12:15

2/28/2014 15:51

DF

Lab ID:

Sample ID:









4/3/2014 09:20 Page 8 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287003

NIMBUS (1402270077)


Date Received:

2/27/2014 12:15

2/28/2014 15:51

DF

Lab ID:

Sample ID:






Allethrin 1 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Bifenthrin 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Chlorpyrifos 10.5 SMS 3397SPR 6339ND ng/L 2.0 03/02/14 18:06 03/22/14 18:18Cyfluthrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Lambda-Cyhalothrin 10.2 SMS 3397SPR 63392.7 ng/L 1.5 03/02/14 18:06 03/22/14 18:18Cypermethrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Diazinon 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Deltamethrin:Tralomethrin 10.2 SMS 3397SPR 6339ND ng/L 3.0 03/02/14 18:06 03/22/14 18:18Esfenvalerate:Fenvalerate 10.2 SMS 3397SPR 6339ND ng/L 3.0 03/02/14 18:06 03/22/14 18:18Fenpropathrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Tau-Fluvalinate 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Permethrin 12 SMS 3397SPR 6339ND ng/L 15 03/02/14 18:06 03/22/14 18:18Tetramethrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:18Esfenvalerate-d6;#1 (SS) 1 SMS 3397SPR 633984 % 70-130 03/02/14 18:06 03/22/14 18:18Esfenvalerate-d6;#2 (SS) 1 SMS 3397SPR 633983 % 70-130 03/02/14 18:06 03/22/14 18:18



Analyzed by: AN


1 VFL 1514 90 % 63-157 03/05/14 20:24

4/3/2014 09:20 Page 9 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287004

FREEPORT (1402270070)


Date Received:

2/27/2014 08:35

2/28/2014 15:51

DF

Lab ID:

Sample ID:









4/3/2014 09:20 Page 10 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287004

FREEPORT (1402270070)


Date Received:

2/27/2014 08:35

2/28/2014 15:51

DF

Lab ID:

Sample ID:






Allethrin 1 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Bifenthrin 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Chlorpyrifos 10.5 SMS 3397SPR 6339J1.2 ng/L 2.0 03/02/14 18:06 03/22/14 18:52Cyfluthrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Lambda-Cyhalothrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Cypermethrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Diazinon 10.1 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Deltamethrin:Tralomethrin 10.2 SMS 3397SPR 6339ND ng/L 3.0 03/02/14 18:06 03/22/14 18:52Esfenvalerate:Fenvalerate 10.2 SMS 3397SPR 6339ND ng/L 3.0 03/02/14 18:06 03/22/14 18:52Fenpropathrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Tau-Fluvalinate 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Permethrin 12 SMS 3397SPR 6339ND ng/L 15 03/02/14 18:06 03/22/14 18:52Tetramethrin 10.2 SMS 3397SPR 6339ND ng/L 1.5 03/02/14 18:06 03/22/14 18:52Esfenvalerate-d6;#1 (SS) 1 SMS 3397SPR 633984 % 70-130 03/02/14 18:06 03/22/14 18:52Esfenvalerate-d6;#2 (SS) 1 SMS 3397SPR 633981 % 70-130 03/02/14 18:06 03/22/14 18:52



Analyzed by: AN


1 VFL 1514 85 % 63-157 03/05/14 20:55

4/3/2014 09:20 Page 11 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287005

FREEPORT FD(1402270072)


Date Received:

2/27/2014 08:35

2/28/2014 15:51

DF

Lab ID:

Sample ID:






4/3/2014 09:20 Page 12 of 24





ANALYTICAL RESULTS

Project ID

P021287

AMP 211

Lab Order:

P021287006

EQ. BLNK (1402270069)


Date Received:

2/27/2014 08:35

2/28/2014 15:51

DF

Lab ID:

Sample ID:






4/3/2014 09:20 Page 13 of 24






Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

MPR/12600



Draft EPA 1630




Blank

Limit

Reporting

QualifiersMDL




Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

571050

Methyl Mercury 1.1ng/L 1.2 110 67-133



Spike

Result

MS

571052 571053

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002


QC Batch:

QC Batch Method:

SPR/6343



SW846 8015(MOD)




Blank

Limit

Reporting

QualifiersMDL




Spike

Result

LCS

569646 569647

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers





Page 14 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

SPR/6343



SW846 8015(MOD)




Spike

Result

MS

569648 569649

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002

Diesel Fuel ug/L 1090 958 88 36-1201060 100 10 300o-Terphenyl (SS) % 97 49-124105 6.5

QC Batch:

QC Batch Method:

SPR/6344



EPA 625M




Blank

Limit

Reporting

QualifiersMDL

Acenaphthene ND ug/L0.005 10.004Acenaphthylene ND ug/L0.005 0.004Anthracene ND ug/L0.005 0.004Benzo(a)anthracene ND ug/L0.005 0.004Benzo(a)pyrene ND ug/L0.005 0.004Benzo(b)fluoranthene ND ug/L0.005 0.004Benzo(e)pyrene ND ug/L0.005 0.004Benzo(g,h,i)perylene ND ug/L0.005 0.004Benzo(k)fluoranthene ND ug/L0.005 0.004Biphenyl ND ug/L0.005 0.004Chrysene ND ug/L0.005 0.004Dibenzo(a,h)anthracene ND ug/L0.005 0.004Dibenzothiophene ND ug/L0.005 0.0042,6-Dimethylnaphthalene ND ug/L0.005 0.004Fluoranthene ND ug/L0.005 0.004Fluorene ND ug/L0.005 0.004Indeno(1,2,3-cd)pyrene ND ug/L0.005 0.0041-Methylnaphthalene ND ug/L0.005 0.0042-Methylnaphthalene ND ug/L0.005 0.0041-Methylphenanthrene ND ug/L0.005 0.004Naphthalene ND ug/L0.005 0.004Perylene ND ug/L0.005 0.004Phenanthrene ND ug/L0.005 0.004Pyrene ND ug/L0.005 0.0042,3,5-Trimethylnaphthalene ND ug/L0.005 0.0042-Fluorobiphenyl (SS) 75 %30-150Nitrobenzene-d5 (SS) 69 %30-150Terphenyl-d14 (SS) 95 %30-150




Page 15 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

SPR/6344



EPA 625M




Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

569651

Acenaphthene 0.02ug/L 0.01 62 30-150Acenaphthylene 0.02ug/L 0.01 74 30-150Anthracene 0.02ug/L 0.02 115 30-150Benzo(a)anthracene 0.02ug/L 0.02 115 30-150Benzo(a)pyrene 0.02ug/L 0.02 115 30-150Benzo(b)fluoranthene 0.02ug/L 0.02 109 30-150Benzo(e)pyrene 0.02ug/L 0.02 112 30-150Benzo(g,h,i)perylene 0.02ug/L 0.02 96 30-150Benzo(k)fluoranthene 0.02ug/L 0.02 122 30-150Biphenyl 0.02ug/L 0.02 84 30-150Chrysene 0.02ug/L 0.02 102 30-150Dibenzo(a,h)anthracene 0.02ug/L 0.02 109 30-150Dibenzothiophene 0.02ug/L 0.02 75 30-1502,6-Dimethylnaphthalene 0.02ug/L 0.01 67 30-150Fluoranthene 0.02ug/L 0.02 107 30-150Fluorene 0.02ug/L 0.01 71 30-150Indeno(1,2,3-cd)pyrene 0.02ug/L 0.02 106 30-1501-Methylnaphthalene 0.02ug/L 0.01 64 30-1502-Methylnaphthalene 0.02ug/L 0.01 65 30-1501-Methylphenanthrene 0.02ug/L 0.02 97 30-150Naphthalene 0.02ug/L 0.01 70 30-150Perylene 0.02ug/L 0.02 110 30-150Phenanthrene 0.02ug/L 0.02 91 30-150Pyrene 0.02ug/L 0.02 108 30-1502,3,5-Trimethylnaphthalene 0.02ug/L 0.01 68 30-1502-Fluorobiphenyl (SS) % 64 30-150Nitrobenzene-d5 (SS) % 71 30-150Terphenyl-d14 (SS) % 117 30-150



Spike

Result

MS

569655 569656

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002

Acenaphthene ug/L 0.02 0.01 65 30-1500.02 74 11 300Acenaphthylene ug/L 0.02 0.02 72 30-1500.02 83 11 300Anthracene ug/L 0.02 0.02 118 30-1500.02 118 2.1 300Benzo(a)anthracene ug/L 0.02 0.02 83 30-1500.03 93 6.4 300.007Benzo(a)pyrene ug/L 0.02 0.02 57 30-1500.03 70 8.8 300.01Benzo(b)fluoranthene ug/L 0.02 0.02 38 30-1500.03 50 9.6 300.02




Page 16 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

SPR/6344



EPA 625M




Spike

Result

MS

569655 569656

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002

Benzo(e)pyrene ug/L 0.02 0.02 44 30-1500.03 58 11 300.01Benzo(g,h,i)perylene ug/L 0.02 0.02 23 30-1500.02 33 9.2 300.02Benzo(k)fluoranthene ug/L 0.02 0.02 91 30-1500.02 83 8.7 300.005Biphenyl ug/L 0.02 0.02 93 30-1500.01 63 40 300Chrysene ug/L 0.02 0.02 52 30-1500.02 67 12 300.01Dibenzo(a,h)anthracene ug/L 0.02 0.02 103 30-1500.02 112 6.3 300Dibenzothiophene ug/L 0.02 0.02 73 30-1500.02 77 3.2 3002,6-Dimethylnaphthalene ug/L 0.02 0.01 70 30-1500.02 84 16 300Fluoranthene ug/L 0.02 0.02 48 30-1500.03 67 16 300.01Fluorene ug/L 0.02 0.02 72 30-1500.02 88 17 300Indeno(1,2,3-cd)pyrene ug/L 0.02 0.02 53 30-1500.02 63 8.2 300.011-Methylnaphthalene ug/L 0.02 0.01 67 30-1500.02 74 8.9 3002-Methylnaphthalene ug/L 0.02 0.01 69 30-1500.02 75 6.1 3001-Methylphenanthrene ug/L 0.02 0.02 92 30-1500.02 100 6.5 300Naphthalene ug/L 0.02 0.01 71 30-1500.01 72 0 300Perylene ug/L 0.02 0.02 113 30-1500.03 126 8.9 300Phenanthrene ug/L 0.02 0.02 85 30-1500.02 94 7.6 300Pyrene ug/L 0.02 0.02 33 30-1500.02 47 12 300.022,3,5-Trimethylnaphthalene ug/L 0.02 0.01 68 30-1500.02 77 11 3002-Fluorobiphenyl (SS) % 67 30-15078 13Nitrobenzene-d5 (SS) % 75 30-15080 4.4Terphenyl-d14 (SS) % 112 30-150120 4.2

QC Batch:

QC Batch Method:

SPR/6347



EPA 614




Blank

Limit

Reporting

QualifiersMDL

Azinphos methyl (Guthion) ND ug/L0.05 0.04Chlorpyrifos ND ug/L0.01 0.005Demeton -O and -S ND ug/L0.1 0.09Diazinon ND ug/L0.02 0.007Disulfoton (Di-Syston) ND ug/L0.1 0.08Ethion ND ug/L0.02 0.005Malathion ND ug/L0.05 0.005Parathion (Parathion ethyl) ND ug/L0.05 0.008Parathion methyl ND ug/L0.1 0.08Thiobencarb ND ug/L0.05 0.008




Page 17 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

SPR/6347



EPA 614



Blank

Limit

Reporting

QualifiersMDL

Dichlofenthion (SS) 100 %45-105Triphenylphosphate (SS) 106 %61-120



Spike

Result

LCS

Qualifiers

LCS

% Rec

% Rec

Limits

570105

Azinphos methyl (Guthion) 3ug/L 3 98 52-123Chlorpyrifos 3ug/L 2.6 87 45-127Demeton -O and -S 3ug/L 2 65 10-100Diazinon 3ug/L 2.6 86 50-121Disulfoton (Di-Syston) 3ug/L 2.5 84 10-114Ethion 3ug/L 3.1 103 47-138Malathion 3ug/L 2.9 96 48-132Parathion (Parathion ethyl) 3ug/L 2.6 85 44-139Parathion methyl 3ug/L 2.9 95 49-124Thiobencarb 3ug/L 2.8 94 40-150Dichlofenthion (SS) % 93 45-105Triphenylphosphate (SS) % 103 61-120



Spike

Result

MS

570107 570108

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002

Azinphos methyl (Guthion) ug/L 3.2 3 93 52-1233.3 102 12 500Chlorpyrifos ug/L 3.2 2.9 92 45-1273.2 100 10 500Demeton -O and -S ug/L 3.2 2.4 75 10-1002.5 77 4.5 500Diazinon ug/L 3.2 2.9 91 50-1213.2 99 9.8 500Disulfoton (Di-Syston) ug/L 3.2 2.8 89 10-1143 93 6.8 500Ethion ug/L 3.2 3.4 106 47-1383.8 117 12 500Malathion ug/L 3.2 3.2 102 48-1323.6 109 9.4 500Parathion (Parathion ethyl) ug/L 3.2 2.8 87 44-1393 93 9.3 500Parathion methyl ug/L 3.2 3.1 97 49-1243.4 105 10 500Thiobencarb ug/L 3.2 3.1 98 40-1503.5 107 11 500Dichlofenthion (SS) % 96 45-105102 8.8Triphenylphosphate (SS) % 101 61-120112 13




Page 18 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

SPR/6339







Blank

Limit

Reporting

QualifiersMDL

Allethrin ND ng/L1.5 10.1Bifenthrin ND ng/L1.5 0.1Chlorpyrifos ND ng/L2.0 0.5Cyfluthrin ND ng/L1.5 0.2Lambda-Cyhalothrin ND ng/L1.5 0.2Cypermethrin ND ng/L1.5 0.2Diazinon ND ng/L1.5 0.1Deltamethrin:Tralomethrin ND ng/L3.0 0.2Esfenvalerate:Fenvalerate ND ng/L3.0 0.2Fenpropathrin ND ng/L1.5 0.2Tau-Fluvalinate ND ng/L1.5 0.2Permethrin ND ng/L15 2.0Tetramethrin ND ng/L1.5 0.2Esfenvalerate-d6;#1 (SS) 81 %70-130Esfenvalerate-d6;#2 (SS) 82 %70-130



Spike

Result

LCS

568939 568940

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

Allethrin ng/L 20 12 61 50-15014 70 14 35Bifenthrin ng/L 20 20 100 70-16519 94 6.2 35Chlorpyrifos ng/L 20 16 82 45-15018 89 8.2 35Cyfluthrin ng/L 20 17 85 55-14018 89 4.6 30Lambda-Cyhalothrin ng/L 20 14 68 40-12014 71 5.1 35Cypermethrin ng/L 20 18 88 50-13019 96 9.3 30Diazinon ng/L 20 16 82 50-15018 88 7.7 35Deltamethrin:Tralomethrin ng/L 40 33 83 30-10538 96 15 40Esfenvalerate:Fenvalerate ng/L 40 32 81 40-14035 89 9.2 35Fenpropathrin ng/L 20 20 102 30-18020 101 1 35Tau-Fluvalinate ng/L 20 14 68 30-10015 75 9.1 40Permethrin ng/L 100 84 84 50-16091 91 7.8 40Tetramethrin ng/L 20 13 63 45-14013 67 5.4 50Esfenvalerate-d6;#1 (SS) % 80 70-13087 7.9Esfenvalerate-d6;#2 (SS) % 80 70-13086 7




Page 19 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

SPR/6339







Spike

Result

MS

568941 568942

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002

Allethrin ng/L 22 14 65 50-15016 76 14 350Bifenthrin ng/L 22 20 93 70-16520 95 0 350Chlorpyrifos ng/L 22 15 70 45-15020 95 28 350Cyfluthrin ng/L 22 21 96 55-14020 94 3.9 300Lambda-Cyhalothrin ng/L 22 17 79 40-12021 97 19 350Cypermethrin ng/L 22 21 97 50-13022 101 1.9 300Diazinon ng/L 22 14 65 50-15020 94 35 350Deltamethrin:Tralomethrin ng/L 44 41 93 30-10538 89 6.1 400Esfenvalerate:Fenvalerate ng/L 44 39 90 40-14040 92 0.8 350Fenpropathrin ng/L 22 24 109 30-18024 112 0.4 350Tau-Fluvalinate ng/L 22 15 70 30-10017 78 9.3 400Permethrin ng/L 110 99 90 50-160100 94 2.4 400Tetramethrin ng/L 22 14 65 45-14016 74 12 500Esfenvalerate-d6;#1 (SS) % 80 70-13084 3.4Esfenvalerate-d6;#2 (SS) % 77 70-13081 1.9

QC Batch:

QC Batch Method:

VFL/1514


Analysis Method:






Blank

Limit

Reporting

QualifiersMDL




Spike

Result

LCS

570099 570100

LCSD

Result % Rec

LCS LCSD

% Rec

% Rec

Limit RPD RPD

Max

Qualifiers

TPPH - Gasoline Fuel ug/L 550 508 92 80-110518 94 2 164-Bromofluorobenzene (SS)[FID] % 104 80-130105 0.7




Page 20 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:

QC Batch:

QC Batch Method:

VFL/1514


Analysis Method:






Spike

Result

MS

570120 570121

MSD

Result % Rec

MS MSD

% Rec

% Rec

Limit RPD RPD

Max

QualifiersResult

P021287002

TPPH - Gasoline Fuel ug/L 550 367 67 80-105 6453 82 21 1804-Bromofluorobenzene(SS)[FID]

% 100 63-157100 0.4




Page 21 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:





MB - Method Blank








Low Matrix Spike recovery(ies) due to possible matrix interferences in the QC sample. QC batch accepted5 Matrix Spike recovery(ies) outside of control limits. Sample result accepted based on LCS, LCS/LCSD RPDand Method Blank.

6




Page 22 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:


P021287001 MPR/12600VETERANS (1402270071) MHG/4556Draft EPA 1630 Draft EPA 1630

P021287002 MPR/12600DISCOVERY (1402270068) MHG/4556Draft EPA 1630 Draft EPA 1630

P021287003 MPR/12600NIMBUS (1402270077) MHG/4556Draft EPA 1630 Draft EPA 1630

P021287004 MPR/12600FREEPORT (1402270070) MHG/4556Draft EPA 1630 Draft EPA 1630

P021287005 MPR/12600FREEPORT FD(1402270072)

MHG/4556Draft EPA 1630 Draft EPA 1630

P021287006 MPR/12600EQ. BLNK (1402270069) MHG/4556Draft EPA 1630 Draft EPA 1630

P021287001 SPR/6343VETERANS (1402270071) SFL/1609SW846 3510C SW846 8015(MOD)

P021287002 SPR/6343DISCOVERY (1402270068) SFL/1609SW846 3510C SW846 8015(MOD)

P021287003 SPR/6343NIMBUS (1402270077) SFL/1609SW846 3510C SW846 8015(MOD)

P021287004 SPR/6343FREEPORT (1402270070) SFL/1609SW846 3510C SW846 8015(MOD)

P021287001 SPR/6339VETERANS (1402270071) SMS/3397SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P021287002 SPR/6339DISCOVERY (1402270068) SMS/3397SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P021287003 SPR/6339NIMBUS (1402270077) SMS/3397SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P021287004 SPR/6339FREEPORT (1402270070) SMS/3397SW846 3510C SW846 8270 Mod(GCMS-NCI-SIM)

P021287001 SPR/6344VETERANS (1402270071) SMS/3386EPA 625M EPA 625M

P021287002 SPR/6344DISCOVERY (1402270068) SMS/3386EPA 625M EPA 625M

P021287003 SPR/6344NIMBUS (1402270077) SMS/3386EPA 625M EPA 625M

P021287004 SPR/6344FREEPORT (1402270070) SMS/3386EPA 625M EPA 625M

P021287005 SPR/6344FREEPORT FD(1402270072)

SMS/3386EPA 625M EPA 625M

P021287006 SPR/6344EQ. BLNK (1402270069) SMS/3386EPA 625M EPA 625M

P021287001 SPR/6347VETERANS (1402270071) SMS/3390EPA 614 EPA 614

P021287002 SPR/6347DISCOVERY (1402270068) SMS/3390EPA 614 EPA 614

P021287003 SPR/6347NIMBUS (1402270077) SMS/3390EPA 614 EPA 614

P021287004 SPR/6347FREEPORT (1402270070) SMS/3390EPA 614 EPA 614

P021287001 VFL/1514VETERANS (1402270071) SW8465030B/8015(MOD)TPPH Gas

P021287002 VFL/1514DISCOVERY (1402270068) SW8465030B/8015(MOD)TPPH Gas




Page 23 of 244/3/2014 09:21



Project ID:

P021287

AMP 211

Lab Order:


P021287003 VFL/1514NIMBUS (1402270077) SW8465030B/8015(MOD)TPPH Gas

P021287004 VFL/1514FREEPORT (1402270070) SW8465030B/8015(MOD)TPPH Gas




Page 24 of 244/3/2014 09:21


SRCSD

March 25, 2014



Dear Vyomin Upadhyay:

AMP 211 54049

Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, February 27, 2014. Results reported herein conform to the most current ELAP standards, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Michael Cook


Srividhya Ramamoorthy QA Officer Lab Manager

Amy Saylor



Phone: (916) 875-9000 Fax: (916) 875-9069




SAMPLE SUMMARY

Work Order No:

Project ID:

54049

AMP 211







1402270076 Freeport FD Surface Water 02/27/2014 08:35 02/27/2014 14:44



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270066

Discovery


Date Received:

2/27/2014 10:25

2/27/2014 14:30


Lab ID:

Sample ID:


BIOLOGICAL

02/27/2014 1.8 MPN/100mL 20 Coliform,Fecal 1 NA LLC SM 9221 E

02/27/2014 1.8 MPN/100mL 20 E.COLI 1 NA LLC SM 9221 F

FIELD ANALYSIS

02/27/2014 0.10 mg/L 10.7 Dissolved Oxygen,(Field) 1 NA JDN ASTM D888-09

02/27/2014 1.0 umhos/cm 91.0 EC,Field Measurement 1 NA JDN EPA 120.1

02/27/2014 1.0 NTU 1.5 Turbidity(Field) 1 NA JDN EPA 180.1

02/27/2014 0 degC 13.3 Temperature(C) 1 NA JDN SM 2550 B

02/27/2014 NA Units 7.5 pH,Field Measurement 1 NA JDN SM 4500-H+B


03/04/2014 0.10 mg/L ND Nitrogen,Ammonia(as N) 1 0.040 JAV EPA 350.1


02/28/2014 0.10 mg/L 0.23 Nitrate(as N) 1 0.0078 RLH EPA 353.2






02/28/2014 20 mg/L 50 TDS 1 NA NES SM 2540 C

02/28/2014 0.50 mg/L 0.84 TSS 1 NA NES SM 2540 D



02/28/2014 2 mg/L ND BOD,5 Day 1 NA MJY SM 5210 B


[2] 03/12/2014 0.50 mg/L 3.5 Carbon,Organic,Total 1 0.15 JDN SM 5310 B



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270066

Discovery


Date Received:

2/27/2014 10:25

2/27/2014 14:30


Lab ID:

Sample ID:


METALS








03/06/2014 1.0 ug/L 6.0 Zinc,Dissolved 1 0.51 NCH [1] EPA 200.8


1402270067

Equip Blk


Date Received:

2/27/2014 08:35

2/27/2014 14:44


Lab ID:

Sample ID:


METALS


03/18/2014 0.50 ug/L ND Copper,Total Recoverable 1 0.16 NCH EPA 200.8




1402270073

Nimbus


Date Received:

2/27/2014 12:15

2/27/2014 13:15


Lab ID:

Sample ID:




Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270073

Nimbus


Date Received:

2/27/2014 12:15

2/27/2014 13:15


Lab ID:

Sample ID:


BIOLOGICAL



FIELD ANALYSIS







03/04/2014 0.10 mg/L 0.086J Nitrogen,Ammonia(as N) 1 0.040 JAV EPA 350.1








02/28/2014 20 mg/L 47 TDS 1 NA NES SM 2540 C

02/28/2014 2.5 mg/L 4.1 TSS 1 NA NES SM 2540 D








Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270073

Nimbus


Date Received:

2/27/2014 12:15

2/27/2014 13:15


Lab ID:

Sample ID:


METALS




03/06/2014 10 ug/L 8.3J Iron,Dissolved 1 8.1 NCH EPA 200.8






1402270074


Date Received:

2/27/2014 08:35

2/27/2014 14:30


Lab ID:

Sample ID:


BIOLOGICAL

02/27/2014 1.8 MPN/100mL 4.5 Coliform,Fecal 1 NA LLC SM 9221 E

02/27/2014 1.8 MPN/100mL 2.0 E.COLI 1 NA LLC SM 9221 F

FIELD ANALYSIS

02/27/2014 0.10 mg/L 10 Dissolved Oxygen,(Field) 1 NA JDN ASTM D888-09

02/27/2014 1.0 umhos/cm 239 EC,Field Measurement 1 NA JDN EPA 120.1

02/27/2014 1.0 NTU 8.3 Turbidity(Field) 1 NA JDN EPA 180.1






Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270074


Date Received:

2/27/2014 08:35

2/27/2014 14:30


Lab ID:

Sample ID:



03/04/2014 0.10 mg/L 0.056J Nitrogen,Ammonia(as N) 1 0.040 JAV EPA 350.1








02/28/2014 20 mg/L 140 TDS 1 NA NES SM 2540 C

02/28/2014 2.5 mg/L 12 TSS 1 NA NES SM 2540 D






METALS








[1] 03/06/2014 1.0 ug/L 14 Zinc,Dissolved 1 0.51 NCH EPA 200.8



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270074


Date Received:

2/27/2014 08:35

2/27/2014 14:30


Lab ID:

Sample ID:


METALS


1402270075

Veterans


Date Received:

2/27/2014 11:50

2/27/2014 14:30


Lab ID:

Sample ID:


BIOLOGICAL

02/27/2014 1.8 MPN/100mL 7.8 Coliform,Fecal 1 NA LLC SM 9221 E

02/27/2014 1.8 MPN/100mL 7.8 E.COLI 1 NA LLC SM 9221 F

FIELD ANALYSIS


02/27/2014 1.0 umhos/cm 252 EC,Field Measurement 1 NA JDN EPA 120.1

02/27/2014 1.0 NTU 16 Turbidity(Field) 1 NA JDN EPA 180.1














Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270075

Veterans


Date Received:

2/27/2014 11:50

2/27/2014 14:30


Lab ID:

Sample ID:



02/28/2014 20 mg/L 150 TDS 1 NA NES SM 2540 C

02/28/2014 2.5 mg/L 26 TSS 1 NA NES SM 2540 D

03/17/2014 2.0 mg/L 11 Chloride 1 0.14 JAV SM 4500-CL E





METALS





03/18/2014 10 ug/L 1,200 Iron,Total Recoverable 1 8.4 NCH EPA 200.8





1402270076

Freeport FD


Date Received:

2/27/2014 08:35

2/27/2014 14:44


Lab ID:

Sample ID:






Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54049

AMP 211

1402270076

Freeport FD


Date Received:

2/27/2014 08:35

2/27/2014 14:44


Lab ID:

Sample ID:










02/28/2014 20 mg/L 140 TDS 1 NA NES SM 2540 C

02/28/2014 2.5 mg/L 12 TSS 1 NA NES SM 2540 D




03/12/2014 0.50 mg/L 7.5 Carbon,Organic,Dissolved 1 0.31 JDN [2] SM 5310 B


METALS












Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211






(S) - Surrogates


NA - Not Applicable

The '<' values are reported when the measured value is less than the RL value, per customer request.

Value confirmed by a second analysis. [1]

Dissolved greater than total, but within acceptable 20% analytical variation. [2]

Field Duplicate RPD verified by second analysis. [3]



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

GEWC/11724

SM 2340 C

Analysis Method:


SM 2340 C


Associated Lab Samples: 1402260058 1402270073


Associated Lab Samples: 1402270073


Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205647

Qualifier



Parameter

205648 205649

% Rec MS MSD



Qualifier

Hardness(as CaCO3) 100 90-110 102 1.4 2.38



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

METP/4365

Dissolved Metals

Analysis Method:


Dissolved Metals






Limit Reporting

Qualifier MDL






Parameter

205664 205665

% Rec LCS LCSD


Max


Iron,Dissolved 98 85-115 100 1.4 15

Lead,Dissolved 94 85-115 95 0.52 15

Zinc,Dissolved 94 85-115 94 0.55 12.9


Parameter

205666 205667

% Rec MS MSD



Qualifier


Iron,Dissolved 96 70-130 95 0.18 15



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter

205666 205667

% Rec MS MSD



Qualifier

Lead,Dissolved 94 70-130 93 1.1 15

Zinc,Dissolved 92 70-130 91 0.78 12.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

METP/4366


Analysis Method:








Limit Reporting

Qualifier MDL

Copper,Total Recoverable 0.24J ug/L 0.50 0.16





Parameter

206608 206609

% Rec LCS LCSD


Max






Parameter

205671 205672

% Rec MS MSD



Qualifier





Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter

205671 205672

% Rec MS MSD



Qualifier





Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

LACH/6185

EPA 353.2

Analysis Method:


EPA 353.2






Limit Reporting

Qualifier MDL




Parameter LCS

% Rec % Rec Limits

205689

Qualifier



Parameter LCS

% Rec % Rec Limits

205695

Qualifier



Parameter LCS

% Rec % Rec Limits

205696

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter

205691 205692

% Rec MS MSD



Qualifier

Nitrate(as N) 99 90-110 97 1.3 10


Parameter

205693 205694

% Rec MS MSD



Qualifier

Nitrite(as N) 99 90-110 99 0.06

10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

OD/11531

SM 5210 B

Analysis Method:


SM 5210 B

5-Day BOD Test

Associated Lab Samples: 1402270047 1402270050 1402270062 1402270066 1402270073 1402270074 1402270075 1402270088 1402270085 1402270080 1402270078 1402270076 Associated Lab Samples: 1402280045 1402280047 1402280049 1402280057 1402280062 1402280065 1402280071


Parameter LCS

% Rec % Rec Limits

205697

Qualifier

BOD,5 Day 100 85-115



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

OD/11532

HA 8000

Analysis Method:


HA 8000

COD by Colorimetry





Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205700

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

SLDS/37399

SM 2540 D

Analysis Method:


SM 2540 D






Limit Reporting

Qualifier MDL

TSS ND mg/L 2.5 NA

SAMPLE DUPLICATE:

Parameter Max RPD

205706

1402270066

RPD


Qualifier

TSS 10 4.9

SAMPLE DUPLICATE:

Parameter Max RPD

205707

1402270016

RPD


Qualifier

TSS 10 7.8



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

SLDS/37401

SM 2540 C

Analysis Method:


SM 2540 C






Limit Reporting

Qualifier MDL

TDS ND mg/L 20 NA


Parameter LCS

% Rec % Rec Limits

205720

Qualifier

TDS 100 93-110

SAMPLE DUPLICATE:

Parameter Max RPD

205718

1402270066

RPD


Qualifier

TDS 14 7.7



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

GEWC/11726

SM 2320B

Analysis Method:


SM 2320B






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205735

Qualifier



Parameter

205736 205737

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

GEWC/11728

SM 2340 C

Analysis Method:


SM 2340 C


Associated Lab Samples: 1402270066 1402270074 1402270075 1402270076


Associated Lab Samples: 1402270066 1402270075 1402270074 1402270076


Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205845

Qualifier



Parameter

205846 205847

% Rec MS MSD



Qualifier

Hardness(as CaCO3) 100 90-110 102 1.5 2.38



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

LACH/6194

EPA 350.1

Analysis Method:


EPA 350.1






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

205862

Qualifier



Parameter LCS

% Rec % Rec Limits

205864

Qualifier



Parameter

205865 205866

% Rec MS MSD



Qualifier



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter

205865 205866

% Rec MS MSD



Qualifier

Nitrogen,Ammonia(as N) 101 90-110 105 3.5 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

CVAF/1591

EPA 1631 E

Analysis Method:


EPA 1631 E






Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter LCS

% Rec % Rec Limits

206000

Qualifier



Parameter

206001 206002

% Rec MS MSD



Qualifier

Mercury,Total 103 72-125 102 0.71 16.4



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

LACH/6219

SM 4500-CL E

Analysis Method:


SM 4500-CL E






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

206333

Qualifier

Chloride 96 90-110


Parameter LCS

% Rec % Rec Limits

206337

Qualifier

Chloride 94 90-110


Parameter LCS

% Rec % Rec Limits

206338

Qualifier

Chloride 91 90-110



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter

206335 206336

% Rec MS MSD



Qualifier

Chloride 90 90-110 91 0.98 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

TOC/1425

SM 5310 B

Analysis Method:


SM 5310 B






Limit Reporting

Qualifier MDL






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

206437

Qualifier



Parameter LCS

% Rec % Rec Limits

206438

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211


Parameter LCS

% Rec % Rec Limits

206446

Qualifier



Parameter LCS

% Rec % Rec Limits

206447

Qualifier



Parameter

206441 206442

% Rec MS MSD



Qualifier



Parameter

206443 206444

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

LACH/6235

EPA 351.2

Analysis Method:


EPA 351.2






Limit Reporting

Qualifier MDL

TKN(as N) ND mg/L 0.10 0.059


Parameter LCS

% Rec % Rec Limits

206803

Qualifier

TKN(as N) 103 90-110


Parameter LCS

% Rec % Rec Limits

206808

Qualifier

TKN(as N) 99 90-110


Parameter

206806 206807

% Rec MS MSD



Qualifier

TKN(as N) 91 90-110 92 0.08

10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211

QC Batch:

QC Batch Method:

LACH/6236

EPA 365.4

Analysis Method:


EPA 365.4






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

206809

Qualifier



Parameter LCS

% Rec % Rec Limits

206813

Qualifier



Parameter

206811 206812

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54049

AMP 211



MB - Method Blank








Phone: (916) 875-9000 Fax: (916) 875-9069




CMP 212


Caltest

Tuesday, June 24, 2014


Re Lab Order: Project ID:

P050493AMP 212

Collected By: PO/Contract #:

Michael Cook81105680

Dear Michael Cook:

Enclosed are the analytical results for sample(s) received by the laboratory on Friday, May 09, 2014. Results reported herein conform to the mostcurrent NELAC standards, where applicable, unless otherwise narrated in the body of the report.


Enclosures


Page 1 of 21


(707) 258-4000 • Fax (707) 226-1001 • e-mail: [email protected] North Kelly Road • Napa, California 94558

without the written consent of CALTEST ANALYTICAL LABORATORYThis report shall not be reproduced, except in full,

REPORT OF LABORATORY ANALYSIS6/24/2014 10:44

SAMPLE SUMMARY Lab Order: Project ID:

P050493AMP 212


P050493001 VETERANS (1405060070) Water 05/08/2014 12:15 05/09/2014 15:00


P050493003 NIMBUS (1405060066) Water 05/08/2014 11:45 05/09/2014 15:00

P050493004 FREEPORT (1405060069) Water 05/08/2014 09:25 05/09/2014 15:00

P050493005 VETERANS FD(1405060071) Water 05/08/2014 12:15 05/09/2014 15:00

P050493006 EQ. BLK (1405060068) Water 05/08/2014 09:20 05/09/2014 15:00

Page 2 of 21





NARRATIVE Lab Order: Project ID:

P050493AMP 212


Caltest authorizes this report to be reproduced only in its entirety. Results are specific to the sample(s) as submitted and only tothe parameter(s) reported.

Caltest certifies that all test results for wastewater and hazardous waste analyses meet all applicable NELAC requirements; allmicrobiology and drinking water testing meet applicable ELAP requirements, unless stated otherwise.

All analyses performed by EPA Methods or Standard Methods (SM) 20th Edition except where noted (SMOL=online edition).


Dilution Factors (DF) reported greater than '1' have been used to adjust the result, Reporting Limit (RL), and Method DetectionLimit (MDL).


Filtrations performed at Caltest for dissolved metals (excluding mercury) and/or pH analysis are not performed within the 15minute holding time as specified by 40CFR 136.3 table II.

Results Qualifiers: Report fields may contain codes and non-numeric data correlating to one or more of the following definitions:


RL - Reporting Limit is the quantitation limit at which the laboratory is able to detect an analyte. An analyte not detected at orabove the RL is reported as ND unless otherwise noted or qualified. For analyses pertaining to the State Implementation Plan ofthe California Toxics Rule, the Caltest Reporting Limit (RL) is equivalent to the Minimum Level (ML). A standard is always run at orbelow the ML. Where Reporting Limits are elevated due to dilution, the ML calibration criteria has been met.

J - reflects estimated analytical result value detected below the Reporting Limit (RL) and above the Method Detection Limit (MDL).The 'J' flag is equivalent to the DNQ Estimated Concentration flag.





NOTE: This document represents a complete Analytical Report for the samples referenced herein and should be retained as apermanent record thereof.



Page 3 of 21





ANALYTICAL RESULTS Lab Order: Project ID:

P050493AMP 212

Lab ID

Sample ID

P050493001 Date CollectedDate Received

5/8/2014 12:155/9/2014 15:00

Matrix Water

Parameters Result Units R. L. MDL DF Prepared Batch Analyzed Batch Qual

VETERANS (1405060070)

Prep Method: Draft EPA 1630 JZHPrep by:Methyl Mercury Analysis

Analytical Method: Draft EPA 1630 JZHAnalyzed by:

0.13 ng/L 0.05 0.020 1 05/27/14 00:00 MPR 12803 05/27/14 00:00 MHG 4641Methyl Mercury

Prep Method: SW846 3510C EABPrep by:Total Extractable PetroleumHydrocarbon

Analytical Method: SW846 8015(MOD) MDTAnalyzed by:

ND ug/L 50 10 1 05/13/14 00:00 SPR 6449 05/23/14 19:32 SFL 1622Diesel FuelND ug/L 200 160 1 05/13/14 00:00 SPR 6449 05/23/14 19:32 SFL 1622Motor Oil87 % 49-124 1 05/13/14 00:00 SPR 6449 05/23/14 19:32 SFL 1622o-Terphenyl (SS)

Prep Method: EPA 625M RLHPrep by:625,PAH+Ext,Triple Quad,Analysis

Analytical Method: EPA 625M RLHAnalyzed by:

ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthene 1ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthylene

0.02 ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AnthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(b)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(e)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(g,h,i)peryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(k)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Biphenyl

0.01 ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473ChryseneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Dibenzo(a,h)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473DibenzothiopheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,6-Dimethylnaphthalene

0.04 ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluoreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Indeno(1,2,3-cd)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylphenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473NaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PeryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Phenanthrene

0.03 ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,3,5-Trimethylnaphthalene74 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-Fluorobiphenyl (SS)55 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Nitrobenzene-d5 (SS)

115 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Terphenyl-d14 (SS)

Prep Method: EPA 614 EABPrep by:Organophosphorous Pesticides

Analytical Method: EPA 614 NTAAnalyzed by:

ND ug/L 0.05 0.04 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Azinphos methyl (Guthion) 1ND ug/L 0.01 0.005 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455ChlorpyrifosND ug/L 0.1 0.09 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Demeton -O and -S

Page 4 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 12:155/9/2014 15:00

Matrix Water


VETERANS (1405060070)

ND ug/L 0.02 0.007 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455DiazinonND ug/L 0.1 0.08 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Disulfoton (Di-Syston)ND ug/L 0.02 0.005 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455EthionND ug/L 0.05 0.005 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455MalathionND ug/L 0.05 0.008 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Parathion (Parathion ethyl)ND ug/L 0.1 0.08 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Parathion methylND ug/L 0.05 0.008 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Thiobencarb92 % 45-105 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Dichlofenthion (SS)

108 % 61-120 1 05/14/14 00:00 SPR 6453 05/28/14 13:41 SMS 3455Triphenylphosphate (SS)

Prep Method: SW846 3510C EABPrep by:Pyrethroids Analysis, NCI, Water

Analytical Method: SW846 8270 Mod MDTAnalyzed by:

ND ng/L 1.5 0.1 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Allethrin 1ND ng/L 1.5 0.1 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462BifenthrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462CyfluthrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Lambda-CyhalothrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462CypermethrinND ng/L 3.0 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Deltamethrin:TralomethrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Esfenvalerate:FenvalerateND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462FenpropathrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Tau-FluvalinateND ng/L 15 2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462PermethrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Tetramethrin85 % 70-130 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Esfenvalerate-d6;#1 (SS)82 % 70-130 1 05/10/14 00:00 SPR 6446 06/04/14 03:41 SMS 3462Esfenvalerate-d6;#2 (SS)

Analytical Method: SW846 5030B/8015(MOD) ANAnalyzed by:Total Purgeable PetroleumHydrocarbons

ND ug/L 50 26 1 05/12/14 16:53 VFL 1523TPPH - Gasoline Fuel80 % 63-157 1 05/12/14 16:53 VFL 15234-Bromofluorobenzene

(SS)[FID]

Lab ID

Sample ID


5/8/2014 11:005/9/2014 15:00

Matrix Water









Page 5 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 11:005/9/2014 15:00

Matrix Water





ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthene 1ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AcenaphthyleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AnthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(b)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(e)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(g,h,i)peryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(k)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473BiphenylND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473ChryseneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Dibenzo(a,h)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473DibenzothiopheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,6-DimethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluoreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Indeno(1,2,3-cd)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylphenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473NaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PeryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Phenanthrene

J0.004 ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,3,5-Trimethylnaphthalene72 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-Fluorobiphenyl (SS)59 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Nitrobenzene-d5 (SS)




ND ug/L 0.05 0.04 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Azinphos methyl (Guthion) 1ND ug/L 0.01 0.005 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455ChlorpyrifosND ug/L 0.1 0.09 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Demeton -O and -SND ug/L 0.02 0.007 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455DiazinonND ug/L 0.1 0.08 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Disulfoton (Di-Syston)ND ug/L 0.02 0.005 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455EthionND ug/L 0.05 0.005 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455MalathionND ug/L 0.05 0.008 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Parathion (Parathion ethyl)ND ug/L 0.1 0.08 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Parathion methylND ug/L 0.05 0.008 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Thiobencarb93 % 45-105 1 05/14/14 00:00 SPR 6453 05/28/14 14:08 SMS 3455Dichlofenthion (SS)


Page 6 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 11:005/9/2014 15:00

Matrix Water








(SS)[FID]

Lab ID

Sample ID


5/8/2014 11:455/9/2014 15:00

Matrix Water


NIMBUS (1405060066)



ND ng/L 0.05 0.020 1 05/27/14 00:00 MPR 12803 05/27/14 00:00 MHG 4641Methyl Mercury 1






ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthene 1ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AcenaphthyleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AnthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(b)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(e)pyrene

Page 7 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 11:455/9/2014 15:00

Matrix Water


NIMBUS (1405060066)

ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(g,h,i)peryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(k)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473BiphenylND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473ChryseneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Dibenzo(a,h)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473DibenzothiopheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,6-DimethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluoreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Indeno(1,2,3-cd)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylphenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473NaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PeryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PhenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,3,5-Trimethylnaphthalene65 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-Fluorobiphenyl (SS)49 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Nitrobenzene-d5 (SS)








ND ng/L 1.5 0.1 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Allethrin 1ND ng/L 1.5 0.1 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462BifenthrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462CyfluthrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Lambda-CyhalothrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462CypermethrinND ng/L 3.0 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Deltamethrin:TralomethrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Esfenvalerate:Fenvalerate

Page 8 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 11:455/9/2014 15:00

Matrix Water


NIMBUS (1405060066)

ND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462FenpropathrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Tau-FluvalinateND ng/L 15 2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462PermethrinND ng/L 1.5 0.2 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Tetramethrin92 % 70-130 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Esfenvalerate-d6;#1 (SS)89 % 70-130 1 05/10/14 00:00 SPR 6446 06/04/14 04:50 SMS 3462Esfenvalerate-d6;#2 (SS)



(SS)[FID]

Lab ID

Sample ID


5/8/2014 09:255/9/2014 15:00

Matrix Water


FREEPORT (1405060069)









ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthene 1ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AcenaphthyleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AnthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(b)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(e)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(g,h,i)peryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(k)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473BiphenylND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473ChryseneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Dibenzo(a,h)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473DibenzothiopheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,6-DimethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Fluorene

Page 9 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 09:255/9/2014 15:00

Matrix Water


FREEPORT (1405060069)

ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Indeno(1,2,3-cd)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylphenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473NaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PeryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PhenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,3,5-Trimethylnaphthalene65 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-Fluorobiphenyl (SS)50 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Nitrobenzene-d5 (SS)










ND ug/L 50 26 1 05/12/14 18:25 VFL 1523TPPH - Gasoline Fuel

Page 10 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 09:255/9/2014 15:00

Matrix Water


FREEPORT (1405060069)

77 % 63-157 1 05/12/14 18:25 VFL 15234-Bromofluorobenzene(SS)[FID]

Lab ID

Sample ID


5/8/2014 12:155/9/2014 15:00

Matrix Water


VETERANSFD(1405060071)






ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthene 1ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AcenaphthyleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AnthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(b)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(e)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(g,h,i)peryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(k)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473BiphenylND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473ChryseneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Dibenzo(a,h)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473DibenzothiopheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,6-DimethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluoreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Indeno(1,2,3-cd)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylphenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473NaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PeryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PhenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,3,5-Trimethylnaphthalene68 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-Fluorobiphenyl (SS)57 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Nitrobenzene-d5 (SS)


Page 11 of 21






P050493AMP 212

Lab ID

Sample ID


5/8/2014 09:205/9/2014 15:00

Matrix Water


EQ. BLK (1405060068)



ND ng/L 0.05 0.020 1 05/27/14 00:00 MPR 12803 05/27/14 00:00 MHG 4641Methyl Mercury 1



ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Acenaphthene 1ND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AcenaphthyleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473AnthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(a)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(b)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(e)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(g,h,i)peryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Benzo(k)fluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473BiphenylND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473ChryseneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Dibenzo(a,h)anthraceneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473DibenzothiopheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,6-DimethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluorantheneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473FluoreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Indeno(1,2,3-cd)pyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-MethylnaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34731-MethylphenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473NaphthaleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PeryleneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PhenanthreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473PyreneND ug/L 0.005 0.0040 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732,3,5-Trimethylnaphthalene81 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 34732-Fluorobiphenyl (SS)72 % 30-150 1 05/14/14 00:00 SPR 6458 06/11/14 00:00 SMS 3473Nitrobenzene-d5 (SS)


Page 12 of 21





QUALITY CONTROL DATA Lab Order: Project ID:

P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:


Draft EPA 1630

MPR/12803

Draft EPA 1630


Parameter Result

Blank Reporting

Limit MDL Units Qualifiers

Methyl Mercury ND 0.05 0.02 ng/L

LABORATORY CONTROL SAMPLE: 584572

Parameter Units

Spike

Conc.

LCS

Result

LCS

% Rec

% REC

Limits Qualifier

Methyl Mercury ng/L 1.1 1 92 67-133

MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 584574 584575

Parameter Units Result Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers

P050493004 Spike MS MSD MS MSD % Rec Max

Methyl Mercury ng/L 0.07 1.1 1.2 1.2 98 102 65-135 4 35


Analysis Method:

QC Batch:

QC Batch Method:


SW846 8015(MOD)

SPR/6449

SW846 3510C


Parameter Result

Blank Reporting


Diesel Fuel ND 50 10 ug/LMotor Oil ND 200 160 ug/Lo-Terphenyl (SS) 93 49-124 %

LABORATORY CONTROL SAMPLE & LCSD: 582490 582491

Parameter Units

Spike

Conc.

LCS

Result

LCSD

Result

LCS

% Rec

LCSD

% Rec

% REC

Limits RPD

Max

RPD Qualifier

Diesel Fuel ug/L 1000 899 859 90 86 36-120 4.6 30o-Terphenyl (SS) % 109 101 49-124 7.6




Diesel Fuel ug/L 0 1050 984 941 93 90 36-120 4.5 30o-Terphenyl (SS) % 108 104 49-124 5.4

Page 13 of 21






P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:


SW846 8015(MOD)

SPR/6449

SW846 3510C


Analysis Method:

QC Batch:

QC Batch Method:


EPA 614

SPR/6453

EPA 614


Parameter Result

Blank Reporting


Azinphos methyl (Guthion) ND 2.0 0.04 ug/LChlorpyrifos ND 0.05 0.005 ug/LDemeton -O and -S ND 0.5 0.09 ug/LDiazinon ND 0.05 0.007 ug/LDisulfoton (Di-Syston) ND 1.0 0.08 ug/LEthion ND 0.50 0.005 ug/LMalathion ND 0.05 0.005 ug/LParathion (Parathion ethyl) ND 0.50 0.008 ug/LParathion methyl ND 1.0 0.08 ug/LThiobencarb ND 0.20 0.008 ug/LDichlofenthion (SS) 102 45-105 %Triphenylphosphate (SS) 115 61-120 %


Parameter Units

Spike

Conc.

LCS

Result

LCSD

Result

LCS

% Rec

LCSD

% Rec

% REC

Limits RPD

Max

RPD Qualifier

Azinphos methyl (Guthion) ug/L 3 3.1 3.5 104 117 52-123 12 50Chlorpyrifos ug/L 3 2.7 2.7 91 89 45-127 1.8 50Demeton -O and -S ug/L 3 1.6 1.7 53 57 10-100 7.2 50Diazinon ug/L 3 2.7 2.7 91 91 50-121 0.7 50Disulfoton (Di-Syston) ug/L 3 1.9 2 64 67 10-114 5.1 50Ethion ug/L 3 3 3.1 99 105 47-138 5.2 50Malathion ug/L 3 3 3 100 101 48-132 1.3 50Parathion (Parathion ethyl) ug/L 3 2.6 2.7 85 90 44-139 5.3 50Parathion methyl ug/L 3 2.5 2.6 84 86 49-124 3.1 50Thiobencarb ug/L 3 2.7 2.8 91 92 40-150 0.7 50Dichlofenthion (SS) % 87 83 45-105 4.2Triphenylphosphate (SS) % 103 109 61-120 5.3




Azinphos methyl (Guthion) ug/L 0 3.1 4 4 129 127 52-123 1.3 50 6Chlorpyrifos ug/L 0 3.1 2.9 2.8 96 90 45-127 3.1 50Demeton -O and -S ug/L 0 3.1 2.2 1.9 72 61 10-100 12 50Diazinon ug/L 0 3.1 3 2.9 100 93 50-121 3.7 50

Page 14 of 21






P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:


EPA 614

SPR/6453

EPA 614




Disulfoton (Di-Syston) ug/L 0 3.1 2.4 2.2 79 69 10-114 10 50Ethion ug/L 0 3.1 3.4 3.3 113 105 47-138 4.1 50Malathion ug/L 0 3.1 3.4 3.3 110 105 48-132 1.8 50Parathion (Parathion ethyl) ug/L 0 3.1 3 2.9 99 92 44-139 4 50Parathion methyl ug/L 0 3.1 3 2.9 98 92 49-124 3.7 50Thiobencarb ug/L 0 3.1 3 2.9 97 92 40-150 2.7 50Dichlofenthion (SS) % 95 88 45-105 5.3Triphenylphosphate (SS) % 109 105 61-120 0.9


Analysis Method:

QC Batch:

QC Batch Method:



SPR/6446

SW846 3510C


Parameter Result

Blank Reporting


Allethrin ND 1.5 0.1 ng/L 1,2Bifenthrin ND 1.5 0.1 ng/LCyfluthrin ND 1.5 0.2 ng/LLambda-Cyhalothrin ND 1.5 0.2 ng/LCypermethrin ND 1.5 0.2 ng/LDeltamethrin:Tralomethrin ND 3.0 0.2 ng/LEsfenvalerate:Fenvalerate ND 3.0 0.2 ng/LFenpropathrin ND 1.5 0.2 ng/LTau-Fluvalinate ND 1.5 0.2 ng/LPermethrin ND 15 2.0 ng/LTetramethrin ND 1.5 0.2 ng/LEsfenvalerate-d6;#1 (SS) 71 70-130 %Esfenvalerate-d6;#2 (SS) 66 70-130 % 3


Parameter Units

Spike

Conc.

LCS

Result

LCSD

Result

LCS

% Rec

LCSD

% Rec

% REC

Limits RPD

Max

RPD Qualifier

Allethrin ng/L 20 13 13 65 66 50-150 2.3 35Bifenthrin ng/L 20 15 16 76 78 70-165 2.6 35Cyfluthrin ng/L 20 14 15 72 76 55-140 4.7 30Lambda-Cyhalothrin ng/L 20 14 15 70 74 40-120 6.3 35Cypermethrin ng/L 20 15 15 75 77 50-130 3.3 30Deltamethrin:Tralomethrin ng/L 40 25 24 64 59 30-105 6.9 40Esfenvalerate:Fenvalerate ng/L 40 29 29 72 72 40-140 0 35Fenpropathrin ng/L 20 18 18 89 90 30-180 1.1 35

Page 15 of 21






P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:



SPR/6446

SW846 3510C


Parameter Units

Spike

Conc.

LCS

Result

LCSD

Result

LCS

% Rec

LCSD

% Rec

% REC

Limits RPD

Max

RPD Qualifier

Tau-Fluvalinate ng/L 20 14 14 68 68 30-100 0 40Permethrin ng/L 100 69 78 69 78 50-160 12 40Tetramethrin ng/L 20 13 14 67 68 45-140 1.5 50Esfenvalerate-d6;#1 (SS) % 74 71 70-130 4.3Esfenvalerate-d6;#2 (SS) % 72 74 70-130 2.5




Allethrin ng/L 0 21 15 14 71 67 50-150 4.8 35Bifenthrin ng/L 0 21 17 17 80 78 70-165 1.8 35Cyfluthrin ng/L 0 21 16 16 76 73 55-140 3.8 30Lambda-Cyhalothrin ng/L 0 21 13 16 60 76 40-120 24 35Cypermethrin ng/L 0 21 17 16 79 78 50-130 0.6 30Deltamethrin:Tralomethrin ng/L 0 42 25 27 60 63 30-105 4.6 40Esfenvalerate:Fenvalerate ng/L 0 42 30 32 72 74 40-140 3.9 35Fenpropathrin ng/L 0 21 40 20 190 94 30-180 67 35 4Tau-Fluvalinate ng/L 0 21 14 15 66 70 30-100 6.3 40Permethrin ng/L 0 110 65 74 61 69 50-160 13 40Tetramethrin ng/L 0 21 15 14 71 66 45-140 6.2 50Esfenvalerate-d6;#1 (SS) % 72 75 70-130 6.2Esfenvalerate-d6;#2 (SS) % 74 77 70-130 5.1


Analysis Method:

QC Batch:

QC Batch Method:


EPA 625M

SPR/6458

EPA 625M


Parameter Result

Blank Reporting


Acenaphthene ND 0.005 0.004 ug/L 1Acenaphthylene ND 0.005 0.004 ug/LAnthracene ND 0.005 0.004 ug/LBenzo(a)anthracene ND 0.005 0.004 ug/LBenzo(a)pyrene ND 0.005 0.004 ug/LBenzo(b)fluoranthene ND 0.005 0.004 ug/LBenzo(e)pyrene ND 0.005 0.004 ug/LBenzo(g,h,i)perylene ND 0.005 0.004 ug/LBenzo(k)fluoranthene ND 0.005 0.004 ug/LBiphenyl ND 0.005 0.004 ug/LChrysene ND 0.005 0.004 ug/L

Page 16 of 21






P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:


EPA 625M

SPR/6458

EPA 625M

Parameter Result

Blank Reporting


Dibenzo(a,h)anthracene ND 0.005 0.004 ug/LDibenzothiophene ND 0.005 0.004 ug/L2,6-Dimethylnaphthalene ND 0.005 0.004 ug/LFluoranthene ND 0.005 0.004 ug/LFluorene ND 0.005 0.004 ug/LIndeno(1,2,3-cd)pyrene ND 0.005 0.004 ug/L1-Methylnaphthalene ND 0.005 0.004 ug/L2-Methylnaphthalene ND 0.005 0.004 ug/L1-Methylphenanthrene ND 0.005 0.004 ug/LNaphthalene ND 0.005 0.004 ug/LPerylene ND 0.005 0.004 ug/LPhenanthrene ND 0.005 0.004 ug/LPyrene ND 0.005 0.004 ug/L2,3,5-Trimethylnaphthalene ND 0.005 0.004 ug/L2-Fluorobiphenyl (SS) 95 30-150 %Nitrobenzene-d5 (SS) 74 30-150 %Terphenyl-d14 (SS) 121 30-150 %


Parameter Units

Spike

Conc.

LCS

Result

LCSD

Result

LCS

% Rec

LCSD

% Rec

% REC

Limits RPD

Max

RPD Qualifier

Acenaphthene ug/L 0.02 0.01 0.007 50 36 30-150 33 30 7Acenaphthylene ug/L 0.02 0.01 0.008 49 39 30-150 23 30Anthracene ug/L 0.02 0.02 0.01 79 70 30-150 11 30Benzo(a)anthracene ug/L 0.02 0.02 0.02 111 115 30-150 4 30Benzo(a)pyrene ug/L 0.02 0.02 0.02 114 124 30-150 8.8 30Benzo(b)fluoranthene ug/L 0.02 0.02 0.02 107 110 30-150 2.8 30Benzo(e)pyrene ug/L 0.02 0.02 0.02 110 112 30-150 1.8 30Benzo(g,h,i)perylene ug/L 0.02 0.03 0.02 140 120 30-150 15 30Benzo(k)fluoranthene ug/L 0.02 0.02 0.03 125 140 30-150 11 30Biphenyl ug/L 0.02 0.01 0.007 49 37 30-150 27 30Chrysene ug/L 0.02 0.02 0.02 101 107 30-150 5.8 30Dibenzo(a,h)anthracene ug/L 0.02 0.02 0.02 121 117 30-150 3.8 30Dibenzothiophene ug/L 0.02 0.01 0.01 66 57 30-150 15 302,6-Dimethylnaphthalene ug/L 0.02 0.01 0.008 56 40 30-150 34 30 7Fluoranthene ug/L 0.02 0.02 0.02 105 104 30-150 1 30Fluorene ug/L 0.02 0.01 0.01 63 49 30-150 25 30Indeno(1,2,3-cd)pyrene ug/L 0.02 0.02 0.02 97 104 30-150 7 301-Methylnaphthalene ug/L 0.02 0.01 0.008 55 42 30-150 27 302-Methylnaphthalene ug/L 0.02 0.01 0.008 54 39 30-150 33 30 71-Methylphenanthrene ug/L 0.02 0.02 0.02 87 87 30-150 0.6 30Naphthalene ug/L 0.02 0.01 0.008 53 40 30-150 29 30Perylene ug/L 0.02 0.02 0.02 109 115 30-150 5.8 30Phenanthrene ug/L 0.02 0.008 0.01 43 67 30-150 44 30 7

Page 17 of 21






P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:


EPA 625M

SPR/6458

EPA 625M


Parameter Units

Spike

Conc.

LCS

Result

LCSD

Result

LCS

% Rec

LCSD

% Rec

% REC

Limits RPD

Max

RPD Qualifier

Pyrene ug/L 0.02 0.02 0.02 104 103 30-150 1.5 302,3,5-Trimethylnaphthalene ug/L 0.02 0.01 0.009 58 46 30-150 24 302-Fluorobiphenyl (SS) % 51 37 30-150 31Nitrobenzene-d5 (SS) % 46 38 30-150 19Terphenyl-d14 (SS) % 110 112 30-150 1.4




Acenaphthene ug/L 0 0.02 0.01 0.009 60 44 30-150 30 30Acenaphthylene ug/L 0 0.02 0.01 0.01 58 48 30-150 21 30Anthracene ug/L 0 0.02 0.02 0.02 89 73 30-150 20 30Benzo(a)anthracene ug/L 0 0.02 0.02 0.02 110 105 30-150 5.3 30Benzo(a)pyrene ug/L 0 0.02 0.03 0.02 128 119 30-150 7.3 30Benzo(b)fluoranthene ug/L 0 0.02 0.02 0.02 106 107 30-150 0.9 30Benzo(e)pyrene ug/L 0 0.02 0.03 0.02 119 114 30-150 4.5 30Benzo(g,h,i)perylene ug/L 0 0.02 0.03 0.03 156 143 30-150 8.9 30 8Benzo(k)fluoranthene ug/L 0 0.02 0.03 0.03 158 133 30-150 18 30 8Biphenyl ug/L 0 0.02 0.01 0.009 55 44 30-150 22 30Chrysene ug/L 0 0.02 0.02 0.02 113 109 30-150 3.9 30Dibenzo(a,h)anthracene ug/L 0 0.02 0.03 0.03 144 133 30-150 7.9 30Dibenzothiophene ug/L 0 0.02 0.01 0.01 71 54 30-150 27 302,6-Dimethylnaphthalene ug/L 0 0.02 0.01 0.01 61 48 30-150 23 30Fluoranthene ug/L 0 0.02 0.02 0.02 118 116 30-150 1.6 30Fluorene ug/L 0 0.02 0.02 0.01 72 60 30-150 17 30Indeno(1,2,3-cd)pyrene ug/L 0 0.02 0.02 0.02 118 109 30-150 7.5 301-Methylnaphthalene ug/L 0 0.02 0.01 0.01 61 46 30-150 29 302-Methylnaphthalene ug/L 0 0.02 0.01 0.009 57 43 30-150 29 301-Methylphenanthrene ug/L 0 0.02 0.02 0.02 95 83 30-150 14 30Naphthalene ug/L 0 0.02 0.01 0.009 60 45 30-150 29 30Perylene ug/L 0 0.02 0.02 0.02 118 105 30-150 11 30Phenanthrene ug/L 0 0.02 0.01 0.009 56 42 30-150 28 30Pyrene ug/L 0 0.02 0.02 0.02 114 108 30-150 4.7 302,3,5-Trimethylnaphthalene ug/L 0 0.02 0.01 0.01 67 50 30-150 28 302-Fluorobiphenyl (SS) % 65 47 30-150 31Nitrobenzene-d5 (SS) % 57 46 30-150 21Terphenyl-d14 (SS) % 116 124 30-150 6.7

Page 18 of 21






P050493AMP 212


Analysis Method:

QC Batch:

QC Batch Method:



VFL/1523



Parameter Result

Blank Reporting


TPPH - Gasoline Fuel ND 50 26 ug/L4-Bromofluorobenzene (SS)[FID] 86 80-130 %

LABORATORY CONTROL SAMPLE: 582276

Parameter Units

Spike

Conc.

LCS

Result

LCS

% Rec

% REC

Limits Qualifier

TPPH - Gasoline Fuel ug/L 550 572 104 80-1104-Bromofluorobenzene (SS)[FID] % 93 80-130




TPPH - Gasoline Fuel ug/L 0 550 440 416 80 76 80-105 5.5 18 54-Bromofluorobenzene % 86 96 63-157 10

Page 19 of 21





QUALITY CONTROL DATA QUALIFIERS Lab Order: Project ID:

P050493AMP 212


Results Qualifiers: Report fields may contain codes and non-numeric data correlating to one or more of the followingdefinitions:



MB - Method Blank

Method Blanks are reported to the same Method Detection Limits (MDLs) or Reporting Limits (RLs) as the analyticalsamples in the corresponding QC batch.







The data is acceptable when no more than one surrogate is outside the acceptance limits.2

Surrogate recoveries were not within QC Acceptance Criteria.3

Matrix spike recovery(ies) and RPD outside control limit. Sample result accepted based on LCS and Method Blank.4

Matrix Spike recovery(ies) outside of control limits. Sample result accepted based on LCS, RPD and Method Blank.5

Matrix Spike recovery(ies) outside control limits: LCS(LCSD) recoveries and RPD are in control. Possible Matrixinterference in QC sample.

6

RPD outside control limit. Sample result accepted based on LCS recoveries and Method Blank.7

High Matrix Spike recovery(ies) due to possible matrix interferences in the QC sample. QC batch accepted based onLCS and RPD results.

8

Page 20 of 21





QUALITY CONTROL DATA CROSS REFERENCE TABLE Lab Order: Project ID:

P050493AMP 212

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch

P050493001 VETERANS (1405060070) Draft EPA 1630 MPR/12803 Draft EPA 1630 MHG/4641

P050493002 DISCOVERY (1405060067) Draft EPA 1630 MPR/12803 Draft EPA 1630 MHG/4641

P050493003 NIMBUS (1405060066) Draft EPA 1630 MPR/12803 Draft EPA 1630 MHG/4641

P050493004 FREEPORT (1405060069) Draft EPA 1630 MPR/12803 Draft EPA 1630 MHG/4641

P050493005 VETERANS FD(1405060071) Draft EPA 1630 MPR/12803 Draft EPA 1630 MHG/4641

P050493006 EQ. BLK (1405060068) Draft EPA 1630 MPR/12803 Draft EPA 1630 MHG/4641

P050493001 VETERANS (1405060070) SW846 3510C SPR/6449 SW846 8015(MOD) SFL/1622

P050493002 DISCOVERY (1405060067) SW846 3510C SPR/6449 SW846 8015(MOD) SFL/1622

P050493003 NIMBUS (1405060066) SW846 3510C SPR/6449 SW846 8015(MOD) SFL/1622

P050493004 FREEPORT (1405060069) SW846 3510C SPR/6449 SW846 8015(MOD) SFL/1622

P050493001 VETERANS (1405060070) SW846 3510C SPR/6446 SW846 8270 Mod SMS/3462

P050493002 DISCOVERY (1405060067) SW846 3510C SPR/6446 SW846 8270 Mod SMS/3462

P050493003 NIMBUS (1405060066) SW846 3510C SPR/6446 SW846 8270 Mod SMS/3462

P050493004 FREEPORT (1405060069) SW846 3510C SPR/6446 SW846 8270 Mod SMS/3462

P050493001 VETERANS (1405060070) EPA 614 SPR/6453 EPA 614 SMS/3455

P050493002 DISCOVERY (1405060067) EPA 614 SPR/6453 EPA 614 SMS/3455

P050493003 NIMBUS (1405060066) EPA 614 SPR/6453 EPA 614 SMS/3455

P050493004 FREEPORT (1405060069) EPA 614 SPR/6453 EPA 614 SMS/3455

P050493001 VETERANS (1405060070) EPA 625M SPR/6458 EPA 625M SMS/3473

P050493002 DISCOVERY (1405060067) EPA 625M SPR/6458 EPA 625M SMS/3473

P050493003 NIMBUS (1405060066) EPA 625M SPR/6458 EPA 625M SMS/3473

P050493004 FREEPORT (1405060069) EPA 625M SPR/6458 EPA 625M SMS/3473

P050493005 VETERANS FD(1405060071) EPA 625M SPR/6458 EPA 625M SMS/3473

P050493006 EQ. BLK (1405060068) EPA 625M SPR/6458 EPA 625M SMS/3473

P050493001 VETERANS (1405060070) SW846 VFL/1523

P050493002 DISCOVERY (1405060067) SW846 VFL/1523

P050493003 NIMBUS (1405060066) SW846 VFL/1523

P050493004 FREEPORT (1405060069) SW846 VFL/1523

Page 21 of 21






SRCSD

June 05, 2014




AMP 212 54665

Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, May 08, 2014. Results reported herein conform to the most current ELAP standards, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Michael Cook


Dan Diehl for Srividhya Ramamoorthy QA Officer Lab Manager Amy Saylor



Phone: (916) 875-9000 Fax: (916) 875-9069




SAMPLE SUMMARY

Work Order No:

Project ID:

54665

AMP 212







1405060065 Veterans FD Surface Water 05/08/2014 12:15 05/08/2014 15:00



Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060060

Nimbus


Date Received:

5/8/2014 11:45

5/8/2014 13:27


Lab ID:

Sample ID:


BIOLOGICAL



FIELD ANALYSIS


05/08/2014 1.0 umhos/cm 87.9 EC,Field Measurement 1 NA JDN EPA 120.1

05/08/2014 1.0 NTU 1.1 Turbidity(Field) 1 NA NES EPA 180.1












05/09/2014 20 mg/L 52 TDS 1 NA NES SM 2540 C

05/09/2014 1.0 mg/L 1.6 TSS 0.4 NA MSE SM 2540 D

05/16/2014 2.0 mg/L 3.1 Chloride 1 0.17 RLH SM 4500-CL E







Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060060

Nimbus


Date Received:

5/8/2014 11:45

5/8/2014 13:27


Lab ID:

Sample ID:


METALS



[1] 05/16/2014 0.50 ug/L 0.92 Copper,Total Recoverable 1 0.16 NCH EPA 200.8







1405060061

Discovery


Date Received:

5/8/2014 11:00

5/8/2014 15:00


Lab ID:

Sample ID:


BIOLOGICAL

05/08/2014 1.8 MPN/100mL 20 Coliform,Fecal 1 NA GKC SM 9221 E

05/08/2014 1.8 MPN/100mL 20 E.COLI 1 NA GKC SM 9221 F

FIELD ANALYSIS









Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060061

Discovery


Date Received:

5/8/2014 11:00

5/8/2014 15:00


Lab ID:

Sample ID:











05/09/2014 20 mg/L 43 TDS 1 NA NES SM 2540 C

05/09/2014 1.4 mg/L 6.9 TSS 0.571 NA MSE SM 2540 D



05/09/2014 2 mg/L 2.5 BOD,5 Day 1 NA MJY SM 5210 B



METALS











Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060061

Discovery


Date Received:

5/8/2014 11:00

5/8/2014 15:00


Lab ID:

Sample ID:


METALS


1405060062

Equip Blk


Date Received:

5/8/2014 09:20

5/8/2014 15:00


Lab ID:

Sample ID:


METALS


05/16/2014 0.50 ug/L 0.22J Copper,Total Recoverable 1 0.16 NCH EPA 200.8




1405060063


Date Received:

5/8/2014 09:25

5/8/2014 15:00


Lab ID:

Sample ID:


BIOLOGICAL

05/08/2014 1.8 MPN/100mL 6.8 Coliform,Fecal 1 NA GKC SM 9221 E

05/08/2014 1.8 MPN/100mL 6.8 E.COLI 1 NA GKC SM 9221 F

FIELD ANALYSIS







Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060063


Date Received:

5/8/2014 09:25

5/8/2014 15:00


Lab ID:

Sample ID:


FIELD ANALYSIS





05/09/2014 0.10 mg/L ND Nitrate(as N) 1 0.0078 JAV EPA 353.2

05/09/2014 0.10 mg/L ND Nitrite(as N) 1 0.0012 JAV EPA 353.2





05/09/2014 20 mg/L 82 TDS 1 NA NES SM 2540 C

05/09/2014 1.3 mg/L 6.3 TSS 0.529 NA MSE SM 2540 D






METALS









Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060063


Date Received:

5/8/2014 09:25

5/8/2014 15:00


Lab ID:

Sample ID:


METALS



05/16/2014 1.0 ug/L 2.8 Zinc,Total Recoverable 1 0.82 NCH [1] EPA 200.8

1405060064

Veterans


Date Received:

5/8/2014 12:15

5/8/2014 15:00


Lab ID:

Sample ID:


BIOLOGICAL

05/08/2014 1.8 MPN/100mL 4.5 Coliform,Fecal 1 NA GKC SM 9221 E

05/08/2014 1.8 MPN/100mL 4.5 E.COLI 1 NA GKC SM 9221 F

FIELD ANALYSIS















Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060064

Veterans


Date Received:

5/8/2014 12:15

5/8/2014 15:00


Lab ID:

Sample ID:





05/09/2014 20 mg/L 110 TDS 1 NA NES SM 2540 C

05/09/2014 1.8 mg/L 8.2 TSS 0.714 NA MSE SM 2540 D






METALS



05/16/2014 0.50 ug/L 1.8 Copper,Total Recoverable 1 0.16 NCH [1] EPA 200.8







1405060065

Veterans FD


Date Received:

5/8/2014 12:15

5/8/2014 15:00


Lab ID:

Sample ID:




Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060065

Veterans FD


Date Received:

5/8/2014 12:15

5/8/2014 15:00


Lab ID:

Sample ID:






05/09/2014 0.10 mg/L ND Nitrite(as N) 1 0.0012 JAV EPA 353.2





05/09/2014 20 mg/L 100 TDS 1 NA NES SM 2540 C

05/09/2014 1.9 mg/L 7.7 TSS 0.775 NA MSE SM 2540 D






METALS











Phone: (916) 875-9000 Fax: (916) 875-9069




ANALYTICAL RESULTS

Work Order No:

Project ID:

54665

AMP 212

1405060065

Veterans FD


Date Received:

5/8/2014 12:15

5/8/2014 15:00


Lab ID:

Sample ID:


METALS




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212






(S) - Surrogates


NA - Not Applicable

Dissolved is greater than total recoverable, but within the acceptable analytical variation. [1]

Dissolved is greater than total recoverable. Results confirmed by a second analysis. [2]

Dissolved greater than total possibly due to filter contamination. [3]



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

SLDS/37999

SM 2540 C

Analysis Method:


SM 2540 C






Limit Reporting

Qualifier MDL

TDS ND mg/L 20 NA


Parameter LCS

% Rec % Rec Limits

209499

Qualifier

TDS 97 93-110

SAMPLE DUPLICATE:

Parameter Max RPD

209497

1405070046

RPD


Qualifier

TDS 14 7.7

SAMPLE DUPLICATE:

Parameter Max RPD

209498

1405060063

RPD


Qualifier

TDS 14 1.2



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

LACH/6371

EPA 353.2

Analysis Method:


EPA 353.2


Associated Lab Samples: 1405060060 1405060061 1405060063 1405060064 1405060065 1405080045 1405080050 1405080068 1405080067 1405080060 1405080057 1405080052 Associated Lab Samples: 1405080075 1405080076 1405080077 1405080078




Limit Reporting

Qualifier MDL




Parameter LCS

% Rec % Rec Limits

209508

Qualifier



Parameter LCS

% Rec % Rec Limits

209514

Qualifier



Parameter LCS

% Rec % Rec Limits

209515

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter

209510 209511

% Rec MS MSD



Qualifier

Nitrate(as N) 106 90-110 106 0.26 10


Parameter

209512 209513

% Rec MS MSD



Qualifier

Nitrite(as N) 105 90-110 104 1.5 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

LACH/6372

EPA 350.1

Analysis Method:


EPA 350.1






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

209516

Qualifier



Parameter LCS

% Rec % Rec Limits

209520

Qualifier



Parameter

209518 209519

% Rec MS MSD



Qualifier

Nitrogen,Ammonia(as N) 96 90-110 96 0.05

10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

GEWC/11848

SM 2340 C

Analysis Method:


SM 2340 C


Associated Lab Samples: 1405060012 1405060060 1405060061 1405060063 1405060064 1405060065 1405070008 1405080009 1405080008 1405080007 1405080006 1405070011 Associated Lab Samples: 1405080044 1405090044




Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

209522

Qualifier



Parameter

209523 209524

% Rec MS MSD



Qualifier

Hardness(as CaCO3) 100 94-107 100 0 2.95



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

OD/11676

SM 5210 B

Analysis Method:


SM 5210 B

5-Day BOD Test



Parameter LCS

% Rec % Rec Limits

209525

Qualifier

BOD,5 Day 91 85-115



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

OD/11677

HA 8000

Analysis Method:


HA 8000

COD by Colorimetry





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

209528

Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

GEWC/11849

SM 2320B

Analysis Method:


SM 2320B






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

209531

Qualifier



Parameter

209532 209533

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

SLDS/38002

SM 2540 D

Analysis Method:


SM 2540 D


Associated Lab Samples: 1405060060 1405060061 1405060063 1405060064 1405060065 1405080079 1405080080 1405090032 1405080084 1405080083 1405080082 1405080081 Associated Lab Samples: 1405090045 1405090047 1405090055




Limit Reporting

Qualifier MDL

TSS ND mg/L 2.5 NA

SAMPLE DUPLICATE:

Parameter Max RPD

209535

1405060060

RPD


Qualifier

TSS 10 0.69

SAMPLE DUPLICATE:

Parameter Max RPD

209536

1405090032

RPD


Qualifier

TSS 10 4.7



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

METP/4442

EPA 1631 E

Analysis Method:


EPA 1631 E

BrCl Digestion for Total Mercury





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

METP/4443

EPA 200.8

Analysis Method:


EPA 200.8






Limit Reporting

Qualifier MDL






Parameter

209558 209559

% Rec LCS LCSD


Max


Iron,Dissolved 100 85-115 100 0.79 15

Lead,Dissolved 94 85-115 95 0.58 15

Zinc,Dissolved 88 85-115 89 1.4 12.9


Parameter

209560 209561

% Rec MS MSD



Qualifier


Iron,Dissolved 98 70-130 98 0.02

15



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter

209560 209561

% Rec MS MSD



Qualifier

Lead,Dissolved 93 70-130 93 0.19 15

Zinc,Dissolved 92 70-130 92 0.27 12.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

METP/4444

EPA 200.8

Analysis Method:


EPA 200.8






Limit Reporting

Qualifier MDL






Parameter

209563 209564

% Rec LCS LCSD


Max






Parameter

209565 209566

% Rec MS MSD



Qualifier





Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter

209565 209566

% Rec MS MSD



Qualifier





Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

LACH/6376

EPA 365.4

Analysis Method:


EPA 365.4






Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

209612

Qualifier



Parameter LCS

% Rec % Rec Limits

209616

Qualifier



Parameter

209614 209615

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

CVAF/1601

EPA 1631 E

Analysis Method:


EPA 1631 E






Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter LCS

% Rec % Rec Limits

209765

Qualifier



Parameter

209766 209767

% Rec MS MSD



Qualifier

Mercury,Total 84 72-125 81 3.1 16.4



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

LACH/6390

SM 4500-CL E

Analysis Method:


SM 4500-CL E


Associated Lab Samples: 1404280063 1404280064 1405060060 1405060061 1405060063 1405060064 1405060065 1405140100 1405140098 1405140096 1405140092 1405140090 Associated Lab Samples: 1405150051 1405150052 1405150054 1405150055




Limit Reporting

Qualifier MDL



Parameter LCS

% Rec % Rec Limits

209906

Qualifier

Chloride 97 90-110


Parameter LCS

% Rec % Rec Limits

209912

Qualifier

Chloride 93 90-110


Parameter LCS

% Rec % Rec Limits

209913

Qualifier

Chloride 93 90-110



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter

209908 209909

% Rec MS MSD



Qualifier

Chloride 95 90-110 95 0.33 10


Parameter

209910 209911

% Rec MS MSD



Qualifier

Chloride 91 90-110 91 0.26 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

TOC/1428

SM 5310 B

Analysis Method:


SM 5310 B






Limit Reporting

Qualifier MDL






Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL





Limit Reporting

Qualifier MDL




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter LCS

% Rec % Rec Limits

210139

Qualifier




Parameter LCS

% Rec % Rec Limits

210151

Qualifier



Parameter LCS

% Rec % Rec Limits

210159

Qualifier



Parameter

210144 210145

% Rec MS MSD



Qualifier

Carbon,Organic,Dissolved 95 75-120 95 0.02

7.6


Parameter

210146 210147

% Rec MS MSD



Qualifier




Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212


Parameter

210148 210149

% Rec MS MSD



Qualifier



Parameter

210152 210153

% Rec MS MSD



Qualifier

Carbon,Organic,Total 98 67-124 99 1 6.9



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212

QC Batch:

QC Batch Method:

LACH/6421

EPA 351.2

Analysis Method:


EPA 351.2






Limit Reporting

Qualifier MDL

TKN(as N) ND mg/L 0.10 0.059


Parameter LCS

% Rec % Rec Limits

210583

Qualifier

TKN(as N) 98 90-110


Parameter LCS

% Rec % Rec Limits

210587

Qualifier

TKN(as N) 95 90-110


Parameter

210585 210586

% Rec MS MSD



Qualifier

TKN(as N) 97 90-110 97 0.51 10



Phone: (916) 875-9000 Fax: (916) 875-9069





Work Order No:

Project ID:

54665

AMP 212



MB - Method Blank








Phone: (916) 875-9000 Fax: (916) 875-9069




Documents

August 29, 2014