“Atomic Structure” Chemistry- power point adapted from Charles Page High School Stephen L. Cotton /R Wolfendale/ Derek Stacy

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Atomic Structure Chemistry- power point adapted from Charles Page High School Stephen L. Cotton /R Wolfendale/ Derek Stacy Slide 2 Defining the Atom OBJECTIVES: OBJECTIVES: Describe the structure of an atom Describe the structure of an atom Outline development of atomic models Outline development of atomic models Atoms/ions-the difference Atoms/ions-the difference Using chemical formulas to identify ionic compounds Using chemical formulas to identify ionic compounds Distinguish between chemical and nuclear reactions Distinguish between chemical and nuclear reactions Compare protons, neutrons and electrons Compare protons, neutrons and electrons Describe how Alpha and Beta particles and Gamma radiation are released from unstable atoms Describe how Alpha and Beta particles and Gamma radiation are released from unstable atoms Slide 3 The Atom- SW pg69 + P 4+ Everything is made of atoms -WOOD, GLASS, SKIN Everything is made of atoms -WOOD, GLASS, SKIN They are so small you cannot see them even with a microscope They are so small you cannot see them even with a microscope There are 118 known types of atoms, 91 that are natural on earth, the other 27 made in the lab There are 118 known types of atoms, 91 that are natural on earth, the other 27 made in the lab Atoms are listed smallest to largest on the periodic table Atoms are listed smallest to largest on the periodic table Each square has the atom, its chemical name and symbol Each square has the atom, its chemical name and symbol (students to receive periodic table to stick in book and blank one to label later (students to receive periodic table to stick in book and blank one to label later Slide 4 Elements Pure substances can be further classified as elements and compounds. Pure substances can be further classified as elements and compounds. Elements are the building blocks of all other substances. Elements are the building blocks of all other substances. Elements consist of atoms of the same type and are represented separately on the periodic table. Elements cannot be broken down further by chemical processes. E.g. calcium, oxygen, zinc, chlorine, carbon, iron, etc Year 9 Science 4 Slide 5 Slide 6 Common elements Phosphorus-P4 Oxygen-O2 Buckyball- carbon 60 Made of 60 Carbon atoms in the shape of a soccer ball Slide 7 Molecules Elements are made up of characteristic atoms and they can join together to form discrete groups of atoms called molecules. It is often in a grid or crystal lattice like structure Two hydrogen atoms can join with an oxygen atom to form a water molecule. H 2 O Year 9 Science 7 Slide 8 Crystal Lattice Silicon and oxygen atoms form crystal lattices to make beach sand! Depending on how big the sand grain-determines how many atoms Silicon and oxygen atoms form crystal lattices to make beach sand! Depending on how big the sand grain-determines how many atoms Slide 9 Compounds Compounds are pure substances that can be broken down further by chemical reactions. E.g. water, sugar, polythene, propane, sodium chloride, etc, Water (H 2 O) can be broken down into the elements hydrogen and oxygen by the process of electrolysis. waterhydrogen + oxygen Year 9 Science 9 electricity Slide 10 Compounds Sodium chloride (NaCl) a compound, called a crystal lattice, can be broken down into the elements sodium and chlorine, also by electrolysis. sodium chloridesodium + chlorine Year 9 Science 10 electricity Slide 11 Compounds Compounds can also be synthesised (man made) by reacting elements together. A compound is defined as having more than one type of atom. When hydrogen is burned in oxygen water is produced. hydrogen + oxygen water Year 9 Science 11 Slide 12 Compounds Compounds have very different properties to those of the elements that make them up. Sodium (Na) : very active metal Chlorine (Cl 2 ): a poisonous gas Sodium chloride (NaCl): our bodies need for cellular processes. + + sodiumchlorinesodium chloride Year 9 Science 12 Slide 13 Inside the Atom Slide 14 Atoms Protons and neutrons exist in the central part of the atom called the nucleus. Electrons orbit the nucleus in energy levels called shells. Electrons cannot exist in the nucleus. They are much smaller and move very fast This speed of the electrons forms an electron cloud Year 9 Science 14 Slide 15 Subatomic Particles ParticleCharge Mass (g) Location Electron (e - ) (e - ) 9.11 x 10 -28 9.11 x 10 -28 Electron cloud Proton (p + ) +1 1.67 x 10 -24 1.67 x 10 -24Nucleus Neutron (n o ) (n o )0 1.67 x 10 -24 1.67 x 10 -24Nucleus Slide 16 Atoms The number of protons in the nucleus is characteristic of the element and is called the atomic number. All hydrogen atoms have 1 proton. All uranium atoms have 92 protons. Etc. Year 9 Science 16 Slide 17 Atomic Number The number of protons in the nucleus of an atom= Atomic Number the number you see on the periodic table above the symbol/name Number of protons and neutrons in the atoms nucleus is the MASS number Slide 18 Isotopes Frederick Soddy (1877-1956) proposed the idea of isotopes in 1912 Frederick Soddy (1877-1956) proposed the idea of isotopes in 1912 Isotopes are atoms of the same element having different masses, due to varying numbers of neutrons. Soddy won the Nobel Prize in Chemistry in 1921 for his work with isotopes and radioactive materials. Soddy won the Nobel Prize in Chemistry in 1921 for his work with isotopes and radioactive materials. Slide 19 Isotopes Sometimes atoms of the same element have different numbers of neutrons from one another- e.g. Helium has generally 2 protons/2 neutrons Mass number = 4 in this case However there is a HELIUM 3 2 PROTONS AND 1 NEUTRON Mass= 3 When the atomic number is the same but mass number different for the same element- it is called an Isotope Slide 20 Isotopes cont: Almost all elements have two isotopes Almost all elements have two isotopes Some have many more Some have many more Most common isotope is Hydrogen 1 = 1 proton in nucleus and no neutron Most common isotope is Hydrogen 1 = 1 proton in nucleus and no neutron Makes up 99.98 % of the hydrogen on earth-called protium Makes up 99.98 % of the hydrogen on earth-called protium Hydrogen 2 is deuterium, and Hydrogen 3 = tritium Hydrogen 2 is deuterium, and Hydrogen 3 = tritium It is the isotopes of hydrogen that are used in nuclear power plants to generate power more efficiently It is the isotopes of hydrogen that are used in nuclear power plants to generate power more efficiently Slide 21 Isotopes are atoms of the same element having different masses, due to varying numbers of neutrons. IsotopeProtonsElectronsNeutronsNucleus Hydrogen1 (protium) (protium)110 Hydrogen-2(deuterium)111 Hydrogen-3(tritium)112 Slide 22 A look back then!Defining the Atom The Greek philosopher Democritus (460 B.C. 370 B.C.) was among the first to suggest the existence of atoms (from the Greek word atomos) The Greek philosopher Democritus (460 B.C. 370 B.C.) was among the first to suggest the existence of atoms (from the Greek word atomos) He believed that atoms were indivisible and indestructible He believed that atoms were indivisible and indestructible His ideas did agree with later scientific theory, but did not explain chemical behaviour, and was not based on the scientific method but just philosophy His ideas did agree with later scientific theory, but did not explain chemical behaviour, and was not based on the scientific method but just philosophy Slide 23 Thomsons Atomic Model Thomson believed that the electrons were like plums embedded in a positively charged pudding, thus it was called the plum pudding model. J. J. Thomson Slide 24 Daltons Atomic Theory (experiment based!) 3)Atoms of different elements combine in simple whole-number ratios to form chemical compounds 4)In chemical reactions, atoms are combined, separated, or rearranged but never changed into atoms of another element. 1)All elements are composed of tiny indivisible particles called atoms 2)Atoms of the same element are identical. Atoms of any one element are different from those of any other element. John Dalton (1766 1844) Slide 25 Sizing up the Atom Elements are able to be subdivided into smaller and smaller particles these are the atoms, and they still have properties of that element If you could line up 100,000,000 copper atoms in a single file, they would be approximately 1 cm long Despite their small size, individual atoms are observable with instruments such as scanning tunneling (electron) microscopes Slide 26 Section 4.2 Structure of the Nuclear Atom One change to Daltons atomic theory is that atoms are divisible into subatomic particles: One change to Daltons atomic theory is that atoms are divisible into subatomic particles: Electrons, protons, and neutrons are examples of these fundamental particles Electrons, protons, and neutrons are examples of these fundamental particles There are many other types of particles, but we will study these three There are many other types of particles, but we will study these three Slide 27 Discovery of the Electron In 1897, J.J. Thomson used a cathode ray tube to deduce the presence of a negatively charged particle: the electron Slide 28 Modern Cathode Ray Tubes Cathode ray tubes pass electricity through a gas that is contained at a very low pressure. TelevisionComputer Monitor Slide 29 Mass of the Electron 1916 Robert Millikan determines the mass of the electron: 1/1840 the mass of a hydrogen atom; has one unit of negative charge The oil drop apparatus Mass of the electron is 9.11 x 10 -28 g Slide 30 Conclusions from the Study of the Electron: a)Number of electrons = number of protons: This means atoms have a neutral charge because = +ve charges = - ve charges b)Electrons have so little mass = they are so small that atoms contain electron clouds (all the electrons flying round the nucleus) these can be huge -1000 X wider than the nucleus c)Most of an atom is therefore empty space Slide 31 Conclusions from the Study of the Electron: In New Zealand a scientist Earnest Rutherford discovered that the nucleus took up such a small space inside the atom He fired a beam of helium nuclei)alpha particles, into a piece of gold foil most passed through to his surprise! Some deflected back Up till now most scientist thought atoms were quite solid Slide 32 Ernest Rutherfords Gold Foil Experiment - 1911 Alpha particles are helium nuclei - The alpha particles were fired at a thin sheet of gold foil Particles that hit on the detecting screen (film) are recorded Slide 33 Electrons.. The electrons are attracted to the nucleus by the protons in the nucleus because of their opposite charges Why dont they fall into the nucleus?....they are trapped in electron shells These are a little like layers on an onion Many of the shells in an atom are empty as obviously many atoms do not have many electrons Electrons have set numbers than can be held in each shelli.e the first shell and smallest holds two The next can hold 8, the third is 18, 4 th is 32 and so onworks on a formula 2n squared The number of electrons in each shell is the ELECTRON CONFIGURATION I.E Sodium is 2:8:1 as it has 11 electrons.. Slide 34 Structure of the Nuclear Atom Practical pg 11 (P) Experimenting like Rutherford Practical pg 11 (P) Experimenting like Rutherford Describe the structure of atoms, according to the Rutherford atomic model. Describe the structure of atoms, according to the Rutherford atomic model. Slide 35 Some revision- before Ions! Complete Symbols Element, the mass number and the atomic number. Element, the mass number and the atomic number. X Mass number Atomic number Subscript Superscript Slide 36 Symbols n Find each of these: a) number of protons b) number of neutrons c) number of electrons d) Atomic number e) Mass Number Br 80 35 Slide 37 Symbols n If an element has an atomic number of 34 and a mass number of 78, what is the: a) number of protons b) number of neutrons c) number of electrons d) complete symbol Slide 38 Symbols n If an element has 91 protons and 140 neutrons what is the a) Atomic number b) Mass number c) number of electrons d) complete symbol Slide 39 Symbols n If an element has 78 electrons and 117 neutrons what is the a) Atomic number b) Mass number c) number of protons d) complete symbol