Ardsley. New York 10502-2699 Telephone 914 478 3131 … · D. Adais - Kiiber Hall Suiiary of Analytical Data far Doiestic Hell and Carbon Systei All concentrations ug/1, parts per

CIBA-GEIGY CorporationArdsley. New York 10502-2699Telephone 914 478 3131

CIBA-GEIGYCERTIFIED MAILRETURN RECEIPT REQUESTED09-11-87-2

September 11, 1987

Mr. Eugene W. PineHydrogeologist and Project OfficerRemedial Response Section _Division of Emergency and Remedial Response Our 1 4 1987Department of Environmental ResourcesP.O. Box 2063Harrisburg, Pennsylvania 17120 EPA,Rei»aliI

Re: Kimberton, PA - Quarterly Sampling 3

Dear Gene:

Please find enclosed the remaining analytical summaries and QA/QCpackages for the quarterly sampling event conducted in Kimberton in lateJuly and early August 1987. Additionally, analtyical summaries and QA/ACpackages are enclosed for the seven carbon systems rebedded during theearly August period. Collectively, these enclosures complete the datacollection and reporting for the quarterly event with the following V _ /exception. The detection of Trans-l,2-Dichlorocthenc at the J. Mooneylocation after rebedding is unexplained. ERM initiated a second exchangeat this location and has re samp led the system. I will forward theseresults as soon as they are available. Additionally, please findenclosed the analytical spread sheet for the Kimberton Country House(MID A/MIDB sampling) under the alternative sampling and analysis programfor this location.

If you have any questions concerning the enclosed information, please donot hesitate to give me a call at 914-478-3131, X-2028.

Yours trul

Jj Stewart JohnsonManager, Environmental Protection

JSJll:gg:19Enc.

cc: J. Doyle, Monsey xP. Tan, US EPA Region III S

AR30I52U

J. Effgen/Alttaojt - Kuotrten Country HouuSutiary of Analytical Data for Vcatstic till and Carton Sy*tts

All conctntrationi ug/1, parti fir Billion, ppb.Analysts ky EM iittodt 401 and 402, M 624 (intficattd IT II.

MID A fuplti rtftr to bftntn pruary and stcondary tanks, left hand train as you fact th» syitti.HID I satplts rtftr to tttitin priairy and ncoadary tanli, right hand train at you fact tkt tyttta.

ftfi • indicatts first tupliij ptrforttd foil wing rtfctdding.

^ ** \ Ca.«tli«i« Tik^*li satpung Totallatt Sill on

1 8/12/131/10/84 44571/17/84 302921/27/14 4539711 3/84 147332/17/14 128470

II

M

onu

n

2/24/14 1521333/ 3/14 1747573/10/84 1943073/17/14 2189023/24/84 2433723/31/84 2724504/ 7/84 2983224/14/84 3235404/21/84 3315824/2B/I4 3814435/ 3/14 4095905/12/84 4404415/19/84 —3/22/841 498411i/ 3/84 5303484/ 9/84 5774404/14/84 4106734/23/14 4343374/30/84 64471 I11 7/84 6909187/14/84 7185207/21/84 7477708/21/841 1729408/23/84 68960011 1/86 9401889/23/64 10044809/30/84 103174710/28/84 115176011/24/641 12455202/29/64 139643011 2/67 152498021 4/671 15344402/16/871 13855103/ f/S7 14727804/ 1/87 1749470

R8 4/ 2/87 1773710B/ 8/871 19448*0B/22/17 2020100

H E/24/87 2040810K/23/87 2149120P/21/87 2313870

R8 p/22/87 23193001/14/871 2433320B/1B/87 2433030

f— -kl*ittr flrnip* • •«* i

RAM Saaplt Tap

A 8 C 0 E f 6

290 340 6 1 3 4 MOISO 180 4 1 2 4 13_„._._._..._— — . — — . — — —— , — . — — . — — —. — — — — — ._ —— . — — — . — . — —. — — — . — . — . — —— . — . — _..„_.„— „ . — — — . — . —. — . — — „ „. — —— ™ ... — — ... ~— _-—-_-_. — . —240 310 3 NO ND 2 ND. — . — — — _. — , . —— — — — _ — —. — — — — . — . — —— — — — — — , —— . — — — — — —150 200 MBL NO NO BHOL NO— . — — — . — . . — —— . — — .__._. ...— — . — — — . — —— . — — — — _ .... — — . — — _ — m— . . — — . — . — — . . —

300 260 6HDL MO RD 6HDL RO... .__-__- — —— — . — . — — ... — .— — — — — . — —— — — . — — — —— — _ — . — „ ~.200 260 IHDL RO HO WOL HO— — — — — — . —— . — — — — . — _. — — — — _ ... . —1(0 270 MDL RO RO IHDl HD— . — — „„_.... — — . — — — — —— — — — — — —200 2701)011 RD HD IHOL HD— _ _ ™ _ _ —

— — — — _ _ —

~- — ~. — _ „ ~~.220 3006HOI MD KD INDl KD

KID A Sawlt Tap .' RID I Satplt Tap i AFTER CARBON Sup It Tap........... ..• ...............A I C 0 E F H I i l O E F ! A I C D E F S H l

J- • u n HO KO NI KO KO RO: KO no KO KO: — — — — — — — — —KD HD HD MO MO 6 NO NO: KO w ID 6: HO a ID KO NO 10 HO KO *KD i n w u MO n HD: n no m n: n w n us RD m w n Hr 2 w ID NO n 3 n: n u n u: n NO ID n NO KD n HO • •

HD s n HO n no n RD: s ID HO KD: no MO ID MO HI HO n n HI10 7 RD 10 19 HO MO HI! II RO RD HO! RD MO MD KO MO ND KO RD N!HO 14 KD RD HI ND HO NO! 25 KO HO HO! KD KO KD NO MO NO ND NO MND M MD RD RO NO NO NO! 57 MO I MO! ND ND ND NO NO ND NO ND NIHO tt, -U 1 t KD HO HO! (7 HD 1 KO! HD HD KO HO RO RO HD KO HIKD KO ~NO HD RO RD RO HO! HO RO HO HO! RO HD HO ND KO HO KD MO HINO ' NO NO NO MO HO HO HO! HO HO ND KD! KO KD RO KD KO ND KO ND MIKO 2 .HO* RO RD NO NO HO! 1 MO NO HO! HO NO ND NO MD MD MO HD MDRO 13 NO NO ND NO MO HO! 4 KO KD HD! — — — — — — — — —HO 46 HD ND 1 HO HD HDi 24 KD KO HO! KD KD KO HD KO HO KO RD HOHD 130 KO NO NO HO 4 KD! 77 1 2 HO! KD KO KD NO HO KO KO NO NONO 170 2 1 2 MO NO NO! 120 I 2 HO! KD RO HO HO HD NO ND NO NOKD 210 2 HO 2 KO HD HO! 170 1 2 KO! RO HD KD RO NO HO KO HO HORD RO KD RO RD HO KD KD! HO HO KO HD.' NO MO ND ND ND MO NO NO NDK O K O K D K O H D K O R O R O : K O K O H O H O i N D K D H O K D K O N D K O N O N DND ND KD HO HO NO ND MB! 1 ND HD KD! KD HD KO HO KO HO HO RD RD:KD KO HO HD HD KD KO HO! 2 KO KD HO! HD HO HO KO HD HD HO NO KO:KD MD HO MD NO KD MO MO! 14 MD NO HO! ' MO NO ND MO MD KD KO KD «:HO 4 N O N D N D N O N D K D : 2 3 N O K O K O ; RO RD RO HD RO HO NO MO KO:ID 2! HO NO MD NO KO RD! IS KO HO HO! KO RO RD HO RO KD HO KD KD:RO 73 HD 1 2 HO HD HDi 93 HD 1 HO! KD KO KD RD KD RD NO KD NO:HD 120 RD NO 1 MO MO NO! 130 ID 1 NO! NO MO ND NO MD NO ND MD NO!KD ND HD HO HO HO KO HO! HD KD KO HO! HD RD NO KD NO HD NO HO HOIHD RD KO NO NO NO ND HO! IDOL NO MO NO! HD ND MO NO ND RD RO HD HDiRD 2 HD HO KO HD HD MO! 7 HD RO HO! — — — — — — — — — !RO 28 HD RD HD RO ND NO! 47 NO ND HO! — — — — — — — — — )— — — — — — — — • — ... — _j MD KO NO HD ND KD KD RO HOIKD ND NO KD ND ND HO RD! NO RD RO HO! RO RO NO ND NO ND ND NO NO!ND i NO NO HO KO KD HO! 3 KD KO HO! — — — — — — — — —rHO n n n KO HD RD HD: KD KD RO RD: RO KO HD a RD KO RD KD n:KO 3 KD H) NO KD KO HO! 1 NO RO KOi — — — — — — — — — :— — — — — — — — . — — — — ; m u u) KO n MD MO NO HO!KD HO KD HD HD HD MD MO! KO KD HD NO.' HD HO HD RD RO HO MD MD HD:RD RO HD ID ID ND ND KOi RO RD KO K0i RO RD KD KD RO NO NO KD NO!NO 4 KO KO HO HO HO HD! * KD KO HO! — — — — — — — — — i— — — — — — — — . — — — — • a m « Kg n n RO RD HD:NO NO HD RO MB ND ND 2! R O N O K O K O : K D K O K O M D N O K D K O H D K O :NO WDL HD HO ID ID KO KD! WOL KD KO KD! HD HD KO KO ND NO HD KD HO!KO 130 HO HO 2 KD HD HO! M HD 1 HOi KO HO HD HO KO KD KO KO HO!HO RD RD HD RD ID HO 2! ID ID KD HO! RD HD RO RO RO MD ND NO ND>ND 3 HO HD KD KO HO 13! 2 KO HD HO! — — — — — — — — — •

KD HD KO HD HD RD HD HO! KO HD KD HO! KD HD KO HO HD KD KD RD HO!... — ... — — ...— .j — .— — ^.j — ~, — . — . — — . — — . — •HD 5 HD HD HO KD HD 2! 2 |0 KD HO! — — — — — — — — —i

Ktbtd (alien—— Datt hiding»>l(1 I »»»h 1 • •H__»»M_»«jr»_a_»j__n__ix_L

4- • Udicatts not tatplcd I/ 9/64 - installation «attd - tont Ottcttd 3/21/66 231613 Ipriairiti rtiovtd, ucondariti rotattd to pritirittlA - Trichlorotthent 3/14/84 413540II- trans-l,2,-0ichlorottntnt 7/14/14 725720Cj- 1,1-DicBloretthtnt 9/25/64 1004770»[• l.t-licMoroitnant 11/24/64 1254243E I- 1,2-Jichlorotthant II 2/87 1524980FM,l,l-Tric«orottlunt 4/1/17 174747011- Ctilorofori 3/22/17 2020830K I- ToltttBt 7/21/87 2313870I t Ktthylint Chlroidt <tl 2/17 HA fl R 3 0 I 5 ? 5

IllUt[Ditti_ ii!i ;5

D. Adais - Kiiber HallSuiiary of Analytical Data far Doiestic Hell and Carbon Systei

All concentrations ug/1, parts per billion, ppb.Analyses by EPA lethods 60! and 602, OR 624 (indicated by I).

HID A saiples refer to between priiary and secondary tanks, left hand train as you face the systei. - —HID B saiples refer to between priiary and secondary tanks, right hand train as you face the systei.

SaiplingDate

9/14/8510/ 4/B52/19/865/21/8618/20/86111/20/8612/11/8713/13/8718/14/371

TotalSal Ions

274957027?110313153440203260263080315300

RAHSaipli Tap

A B

2 B2 3— — .BHDL 10NO 10

BKDL BNOLBltDL EHDLBHDL BHDLBHDL 10

£

NDNO—NONDNONOND

HID ASaiple Tap

.A

NDNONONONOND

NO! ND

B

NDNDNDNDNDNDND

c

12NDNDNDNDNDND

HID BSaiple Tap

A B

ND NDND NOND NDND NONO NDND NOND BNDL

p

NDNONO

AFTERCARBON Tap

A

NDNDNO

NO! NDNO! NDNO! NDNO! ND

B C

ND NDNO NOND NDND NDNO NDNO NDND ND

0

1NONDNONO:NO:NO:

KEY

blank space - not applicable• — - indicates not saipledNO - none detectedA - l,H)ich!oroetheneB - 1,1,1-TrichloroethaneF - Trichloroethene

'etrachloroethene

I«ue Date,

AR30I526

I. Ooran - Raugers (tartarsSmeary of Analytical lata for tomtit fell and Carton Systti

All concentration! uj/1, parts per killien, ppb.Analysts ky EM ittheds 401 and 402, OR 424 (indicated ky II.

HID A saiplts refer to kttMtn iriury and secondary tanks, Itft hand trail as you fact the systti.HID I uiplts rtttr to kttMtn prinry and secondary tanks, right kand train as you fact tit systei.

RB - indicate* the first satplino. perferied fellMino. rebrtdinj.

Satpliao,Date

1/12/8310/14/8511/14/8311/27/8511/27/8511/27/85

. 12/06/1312/13/8512/20/8312/27/851/3/861/10/861/17/841/27/862/3/162/10/862/17/162/24/163/3/863/10/863/17/863/24/863/31/864/7/164/14/164/21/864/28/163/12/869/22/8614/3/864/16/8611 7/867/21/168/ 4/86

M 8/23/84111/20/8612/10/171

KB 3/ 2/87SKB 3/27/171

S/ 8/8717/27/171

IB 8/18/871

KEY

TotalGallon

243043554365437385969500106501183014001136981718619467210122232022920251332655628135295833225233670354973693838948420204683749905328803637342677465537037077530100400117835122630128980142860147380173750

RAK latplt Tap !

A 1 C 0 E !

410 460 KD KD HO!700 480 13 2 KDi490 460 12 2 2!___._. _•

. — _ _. _ _ ;«.__... .j_ „ _ _ _;— — . ... _ .i— _ ~ _ _j_. ... — . _ _•„__... _j_ — . ... _ _». — _ . — _. _•__..__ -*~.\_ _. — , _ ^.j-.. . — — . — — j. — . — ~ _ _•_ „ ~ — _i. — ... „ _ _j— . — . — _ .«.;___..„ .j

I

——— ___ ——. ~. ___•

460 430 10 KD HO!. — ... _ _ _|

„ „ _ _ _j-_ _ _ _ _|710 490 10 M OS430 440 10 MX. CD!920 590 10 MX. Ml

mm i mmm mm* mmm mm ml

940 430 10 MX. ID!430 470 10 MX. KD!

HID ASatple Tap

A S

HD 21 2

KD KDHD KDHO 2ID 2HO 2ID 2HD 34 9I 4HD 43 i1 41 4KD 4KD 4KO 93 9ID 4HD 4HD 4HO 4KO 13 1010 6HO BKDlID 72 91 104 13i eKD KD•DimKDkmHD HDHO tmCD MILHO 10CDkW

6

HOHDKDHOKOKDKOKDKDHOHOKDKO2HOHDKOKOKDKDHDKDKDKDKOKDIDKDKOKDKOKDKDKDnKDHOHOKBKD

KDKD:KB!KD:HO;KO:HD:KD:KDin:KO!KD:no:ID!1!i:n:n:HO:KB!HD:KD:KO:n;n:KD:KD!KD!Ml

1

HDiKD:KD:KD:n:HO!KD:KD:a:KO:HI:

RillSaiplo Tap i

— ^_KO 3KD IKD HD1 42 9KD 2KD 31 2

KD 3KD 3ID 4HO 3KD 3KO 4KO 71 6

KO 9KO 9KO 3HD 73 91 7CD 9ID 6ID 9HDtmHD 4HO 92 112 t1 9

KO KDHO MX.

MX. 1020 30KD KOKOMX.

MX. 20HDttOK.

,)

— !KD:n;n:HO:HO:HD:KD:KO:KD!n;KD:KO:no:KD:n:KO:KD:n

KB;1!KO:n:n:KO!u:KD!KD!HD:HD:KDin:a:n:HO!KD:n;KD:KD:n:

KBKDKDKOHOHDKOCDHOHDHDHOHOKDKDKDKOCDHOKDKDKDaKOKDHDKDKDHOHDKDKDKDKDHD

KDKD

AFTER CARBOH tuple Tap

KOKDHOHOKDKDKDCDHDHDKDKDKDKDKOKDKOHOHOKOKDKOHOCOHOKDKDKDKOKDKOKDHIHOKB

kmMX.

KOHDHOHDKDKOHOKDMHDHDKDKOHOHDKDKOHOKDKDKOHOKOKDKDKDKDCDKDKOKOHDKDKDKD

KDHO

0 E

HD KOKD HDKD KDKD KDHO HDHD KDKD HDKD KDKO KDID KDKD HOHO CDKD KDKO HOKO HDCD HOKD HDCO KDKO KOKD KDHO KOKD KDHO HDKD KDKO KDHD HDKD HDHO KDHO HOKD KDKD KOKO HOHD KDHO KDHD KD

KD KDHO KD

F

KOKDKDKOHOKDKDKDKOKDKOUKO10HOHOKDCOKDKDKDKDHDKDKDKOKDIDHDKDKDKOKDKOKB

KDKO

G

KOHOKBKDHIKDKOCOKOKOHOKO10KDHOKDKDKDHIHDHOKDHDKDKDKDHOHDHOKDHOHOKDKDHO

HOM

H

HIKDKOCOKOKDKOKDKDKDHDKDKDCDKDKDKDIDIDKDKDKDKOKOHDKDKDKOHDKDKOKOKDKDM

'KDKD

Rebttf Gallon•""""" J —————————————— • Ml* H*«tUHg

— • indicates not sate led 8/21/86 74000KD - none detected 3/2/87 122510A • Trickloroetktni 3/26/87 128610 (Secondary unit, I train rotated to Frisary position andI - trans-J,2,-Diclilcroethene a virgin unit installed into the secondary position.)C- I.Hienlereetktnt 1/17/87 173250B - 1,2-OichloroethaniE • 1,2-lickloropropantF - Htthyltnt Oilcridei - TolueneK - Tttrschlorottntnt

Issue Datt:

5. EppsSuiiary of Analytical Data for Doiestic Well and Carbon SysAH concentrations ug/1, parts per billion, ppbAnalyses by EPA tethods 60! and 602, OR 624 (indicated by *HID A saiples refer to between priiary and secondary tanks.RB - indicates first saipling perfoned following rebedding ,

RAH ! HID A ! AFTER CARBONSaiple Tap! Saiple Tap

Saipling Total !Date Gallons A B ! A B

.15

03/14/S5 3 12!10/03/BS 4 15!1/27/86 1467 — —! NO ND5/22/961 42722 BHDL 20! ND NOB/21/S6! 102S97 BflDL 10! ND NO11/20/361 13B470BNOL 10! NO ND2/10/B7S I696B9 BHDL 10! ND ND5/ 4/B7t 199706 ND BHDLI NO BHDL7/27/371 236950 ND BflDLi ND 10

RB B/IB/871 244BOO — —! NO ND

Saiple Tap

B

ND NONO NDND KDND NDND NDNO NDND NO

KEY Rebed gallon•————«« «•••»-««••—• — Ditc KiidinQblank space - not applicable— - indicates not saipled 8/17/87 244500ID - none detected- 1,1-Oichloroethene1,1,1-Trichloroethane

Issue Date:

J. EffgenSuiiary of Analytical Date for Boiestic Nell and Carbon Systei

All concentrations ug/1, parts peri billion, ppb.Analyses by EPA 601 and 602, OR 624 (indicated by t).

HID A saiples refer to between priiary and secondary tanks, left hand train as you face the systei.KID B sup 1 cs refer to between priiary and secondary tanks, right hand train as you face the systei.

KB - indicates first sup ling perforied foil cuing rebedding,

SatplingolteB/23/65111/22/65J17/B68p/B6tIlf26/86t

RB 12r23/66l2 16/6715 4/6717 27/671

RB 8 14/671

TotalGallons

400981430172—60020645327284165243105220110375

RAV SaiplcA G

580 680... «-.

660 700630 680710 600

400 540610 700650 690— —

Tap

C D

15 NO... ...

10 ND10GHDL10 BHOL

10 BHOL10 GHOL10 GHOL— —

E

2

NDNOND

NDNDNO...

C

F !

ND!1

NO:NO!NO!

NO!NO!NO!• — !

HID ASaiple TapA B

•NO NO2 6NO 10ND BHDL

GHOL 20NO NOND BHOLNO BHDLND GHDLND BHOL

HIDEi Saiple Tap

A B11

t ND 1! 2 ND! NO 10! BHDL 10

10 30i NO NDi ND BHDL! ND BHOL! 6HDL 10! NO ND

A

NDNONONOND

NONONO—

AFTER

B

2NDNONONO

NONDNO—

CARBON Saiple TapC 0

ND NONO NDND NDND NDNO NO

NO NDNO NDND ND... ._

E F

NO 3ND 2NO NOND BHDLNO ND

ND NDNO NONO NO— —

KE4-blink •space - not applicableRebed GallonDate Reading

"6CHEF H

- indicates not saipled 12/22/66 64240- none detected B/13/67 110330Trichloroethenetrans-l,2,-Dichloroethene1,1-Dichloroethene1,2-Dichloroethane1,2-OichloropropaneHetbylene Chloride

Issue late:

/1R30I529

C. fi. Divis i SonsSuuary of Analytical Data for Doiestic Hell and Carbon Systei

AH concentrations ug/1, parts per billion, ppta.Analyses by EPA uthods 601 and 602, or 624 (Indicated by t).

HID A saiples refer to between pritary and secondary tanks, left hand train as you face the systei.HID B saiples refer to between priiary and secondary tanks, right hand train as you face the systei.

RB - indicates first saipling perforied following rebedding.

! HID A | H1DB ! !RAN Saiple Tap ! Saiple Tap ! Saiple Tap

Saipling Total - - - - - - - - - - - ! - - - - - - ....Date gallons A 3 C D E F 6 ! A 9 F i A B F

8/14/83 670 7BO 14 3 1 ND NO! il/17/Bi(l) 4BO 620 10 ND ND ND NO! !1/27/86(1) 500 730 ND ND ND ND NO! !II 3/B6 39730 — — — — — — —! ND 1 NO! MD 1 ND2/17/B6 43950 — — — — — — —! ND ND ND! ND ND NO5/22/36* 69990 350 620 BHDl ND NO BHDL NO! ND ND NO! ND ND NO3/21/B&) 100550 530 770 BHDL NO ND BHDL NO! ND ND NO! ND ND ND

AFTER CARBON Saiple Tap i

B C 0 E F B

2 2 ND ND ND ND NO!1 3 NO NO ND ND NO!

ND ND ND ND ND NO NO!NO NO ND ND NO ND NO!

11/20/361 131010 490 750 10 ND ND ND BHDL! ND ND NO! ND ND NO! ND ND ND ND NO ND NO!2/10/871 (2) 490 720 BHDL ND NO BHDL BHOL! NO ND NO! ND NO NO! NO ND N9 ND NO ND NO!5/ 4/871 (3) 79BO 520 710 BHDL ND NO BHDL BRDL! ND ND BHOL! ND ND BHDL! ND ND NO ND ND ND ND!7/27/871 29B90 600 760 10 NO ND BHDL BHDL! ND ND BHOL! ND NO 10! NO ND ND NO NO ND NO!

RB 8/17/871 43000 — — — — — — —! ND ND ND! ND ND ND! — — — — — — —I

KEY Retaed SalIonDate Reading

1 - signifies ne» Nell installed in 1/86.' - floN ieter us reioved froi service by owner. 3/14/97 42810

net) ieter was installed on 4/14/87.uiank space - not applicable— - indicates not saipledND - none detectedA - TrichloroetheneB - trans-l,2,-DichloroetheneC - 1,1-OUhloroethene0 - 1,2-DichloropropaneE - 1,1,1-TrichloroethaneF - Vinyl Chloride6 - 1,2-Dicnioroetnane

AR30I530

V. Kopraod / H. E. PiftrSutaary of Analytical lata for Holistic Kill tod Carbon SyitttAll concwitratiOM «g/l, parti pir billion, pjtti.

Analysts ly PA Kthods 401 and M2, OR 124 (indicatid ty •'•RID A laiplts rtfr to iitttw priiary ind itcondary tank*, lift hand trim is you face tdi systtt.MO I uiplts riftr to IttHfii priury and ucondary tinti, rjjftt iianit train as you fact tkt tyitn.

M • IndicatM firit (iipliig perform) folloimg

WK : ' RID « ; RIO i : AFTER CAMONSaiplt Tap ! Saipli Tap ! Satpli Tap ! Savlc Tap

Saipling Total - - - • - - - • - - ! ........; ......... ......(ati bllont A l C D E F i A I C D E ! A I C O E ! A l C———————————————————————— j ———————————— . ———————————— . —————————i/u/es no 470 n M m mi : :10/M/J5 440 »20 7 2 J M; ~ ~. ~- _ —; ~.~___; 2 2 IB M KJ11/22/85 3^0 — — — — — n: M 2 w w w: i 4 M M w: n n n n n1/27/86 12314 — — — ~ — O! 1 4 KC RD KO! 1 t R S R O I D : »0 M M M ROS/21/Ut 27297 740 470IW KB WOL 0! ' WDL 10 HO RB ffi! IKOL 20 RD W RJ! RB M KT W RBI/20/S4I J9220 470 740§m RDWBL RB! WBL M RO RO RB! MK. 20 RO RD RO! RD tt RD M RB Iu/20/ut 90230 «70 780 tm tm nm. n: IHDL to RD RB n: m. 20 RB RB RB: RB RB RB n RB i

»l 12/23/841 S4182 — — — — — — S RB RB M RB RB! RB RD RD RB RB! — — — ~- — -2/10/871 40221 740 830 im RB WW. Rj: RB WtBL RB RB RB! RB MBL RB RB RB! RB RB RD RD RB IS/ 8/171 70770 750 770 WDL RB MDL RB! RB IfflH. RB RD RB! RD WtDL RB RD RD! RD RD RD RD RD IB/ 4/871 82000 980 780 8HDL BHBL MDL HUH.: BWL 20 RD RD RB! IKBL 20 RD RB RB! RD RD RD RD RD I

(B 8/18/871 84500 — ~ — — — —I RD RB RD RD RD! RD RD RD RB RD! — __. _. — -

KEY lUotd CallnDatt Rcadiig

slant (pact - tot applicant— • iidicattt »ot tatpltd 12/22/84 93990R9 - dent dttRttd 8/17/87 84390• TricklorMthtflt• trani-l,2,-BicMorofth«i- 1,1-CicnlorHtkMt- l,2*lidilerfleropaiii• 1,1,1-Tridilerottfeant- 1,2-IicMrMtlunt

L

J. MooneySuiiary oi Analytical Data for Doiestic Kill and Carbon SysteiAll concentrations ug/1, parts per billion, ppb.Analyses by EPA tethods Ml and 602, OR 624 (indicated by t),

HID A saiples refer to between priiary and secondary tanks, left hand train as you face the systei.HID B saiplss refer to between priiary and secondary tanks, right hand train as you face the systei.

RB - indicates first saipling perforied following rebedding.

RB

RB

RB

SaiplingDate

12/27/85I/ 3/361/27/362/19/863/ 3/863/10/863/17/363/24/363/31/864/14/364/21/364/28/865/ 3/365/22/8416/ 9/366/30/36V14/867/28/863/11/86B/25/B4I11/26/86112/23/8612/18/3715/ 3/9717/27/8718/17/B71

STotalGallons

40209047210013217737540400114401947482506665807461673652557042078156—94484100719107363113265120270159190170110194730226030227540(1) 140

RAHiiple Tap

A B

20 460— . —— —— —— —— —— —— —— „—— —— . . —— —— —110 1200.-_ — .— —— __„— . —— —100 180050 760— —

HID A !Saiple Tap!

A

NONONDNONDNDNDNDNDNDNONONDNDNDNDNONDNDNONDND

50 660! NO80 1400! NDl&O 2500! ND— — ! NO

B :»••*«*'

i:NO:1!2!2!2!3!3!5!6!6!4!8!

BHDL:8!11!17!28!21!

BHDL:10!NO!

BHOL!BHDLi30!20!

HID B !Saiple Tap!

A

NDNDNDNDNDNONONONDNDNDNONONDNONDNDNDNDNDNDNDNDNDNDND

B !1

6!NO!1!4!3!3!3!3!13!7S7!s:5!

BNDL!10!13!17!IS!25!

BHDL!10!ND:

BHDL:BHDL:20!

BHDL:

AFTER CARBONSaiple Tap

A

NONDNDNDNDNDNDNONONONDNDNDNDNDNONONDNDNDND

NDNO

B

NDNDNDNDNONONDNDNONDNONONONONONDNDNDNONOND

NOND

11120111700— .—

KEY Rebed Gallon

blank space - not applicable ————————— - indicates not saipled 8/19/86 117800ND - none detected 12/22/86 169600tt - results indicate an analytical 8/14/87 (II 0

discrepancy froi an undetermined error.(1) - A ne» Mater liter was

installed with 150930 gallonsalready recorded.

A - TricnloroetheneB - trans-t,2,-0ichloroethene

. / • . _ - * * •_,__

AR30I532

E. Hint • ttrt«rt«n toocoSutury tf lailrtical Bit* for fcmtic Kill tnt Cirbon Syttti

All conctntrition uj/l, pirti ptr Billion, ppt.Aflilyus ly EM utkotft 401 ud 402, K 424 fiidicittd ky II.

Hit * uiolM roftr to tttittn priury tnd ficondiry ttoki, left kind triin u you fict tftiystii.KIO I uiplK rtftr to titwtn priury end ncendiry Unit, rigftt dud triin is you fict thi tystt*.

U - ifldicittt first u liif follMitf rrtMdinj.

(UNSuplfTis ! HIS A luplf T*p (III B Suplf Tip ! AFTER CMBON Suplt TipHig Totil

:c 6*1 Ions * I700 840700 1000

14 ID10 ID

IDID

1ID

4IB

11

1

R8

Rl

1/12/850/24/8311/22/8S 700 340 440 4 4 2 2 KB! HI 3 KB KB KB NB KB! — — „._„-„_• Ng | NB KB KB KB U2/17/84 3340 370 700 I 4 1 1 KB! IB 1 ID ID ID ID ID! 7 13 ID U) 10 U) IB! — — — — — — —3/3/84 Jen — — — — — — —!— — ~ — — — —!— — — — — — —! KB ID KB KB ID KB IB5/22/841 7314 370 330 8KDL'IKOL KB ID 8HBL! KD BIBL KB IB KB IB KB! 8WH. 8WH. KO IB IB IB KB! ID ID ID M ID ID IDB/20/84J 10440 370 530 IDOL NB IB KB 8HDL! NB 8HDL KB KB KB KD KB! 10 20 IB MB NB IB IB! ID ID ID ID M ID ID11/20/841 27270 220 380 8MH. 8NBL 19 IB 8KDU ID IRDL ID ID ID ID ID! IWL 20 ID ID ID ID ID! ID ID ID ID ID ID IDJP/23/84J 29240 — — — — — — —! NB ID Nfi W ID -IB ID! KD MX. KB NB KO KB ID! — — — — — — —/10/87I 32494 MO SOO ID «I ID ID ID: WDL MDL ID ID ID ID ID! IHDL WDL ID ID ID ID U! ID ID ID ID ID ID ID/ 1/871 39110 200 400 MB!. KB NB KB DIDl! (ML 20 KO KB KB KB IB! 30 40 ID KB KB NB IB! NB KB KB KB KB KB KB/22/87I 40800 — — — — — — ~j ID ID KD ID ID ID ID! ID KB KB KB KB ID KB!— — — — — — —!/ 4/871 4S970 270 420 WBL IHDL NB KB WDL! KB 10 KB KB KB KB KB! MIL 10 KB KB KB KB KB! NB NB KB KB KB KB KD/14/n 44900 — — — — — — —! 8JfflL8Hfll. 10 D IB KB KB! 8HBL 8HBL KD KB KB KB IB! — — — — — — —

RtbH iillon————————— Balf

tfink tptci - notindicitis wt tupltd 12/22/84 29240

; • M«l OtKtttJ 5/21/87 40700Trickloroitktni 1/13/87 44840trwi-l,2,-0icaldro«tlitfli

C h 1,1-Didilorotthntl.J-Bichlorotthtnt1,2-Oichloropropinilil,l-TricliiorotthintVinyl Chloridt

Iiwi

AR30I533

Page 1 of 2

Sample Data Package Review For CIBA-GEiGY, INC. - KimbertonProject:

• -" • ' """ '"Reviewed by. / J-tl A -O -tyy-. Date A-K.4tiLl ZJ7 /Y-VT'7-? , ,Review for Samples; v

1183930 - Lowry Raw1183981 - Lowry Mid A1183982 - Lowry Mid B1183983 - Lowry A. Carbon1133984 - Phillips Raw1183935 - Phillips Raw1183986 - Phillips A. Carbon1183987 - Marchionne Raw1183938 - Marchionne Mid A1133989 - Marchionne A. Carbon1183994 - Soloman Raw1193995 - Soloman Mid A1193996 - Soloman A. Carbon1193999 - Travel Blank1194000 - Method Blank

Quality Control Data Review;

BFB tuning Ion Abundance Criteria were all within allowablelimits.

Surrogate recovery valvas were in specification for allsamples.

Percent recovery data was in specification for the matrixspike duplicate analyses.

RPD data was in specification for all spiking compounds.

Trace levels «1 ug/1) of methylene chloride were detectedin the travel blank and method blank.

- All quality control data is in acceptable limits.

AR30I531* TIM

Page 2 of 2

Data Package Review:

Title page/chain-of-custody - sample description correct/field and lab chain-of-custody documentation correct and insequence.

Laboratory chronicle - volatile organic analysis holdingtime of 14 days was met for all samples.

Methodology summary - all analyses were performed accordingto EPA Method 624 as referenced in the data package.

Sample data package - analysis report, raw ionchroma tog rams, guantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.Methylene chloride was detected at trace levels in manysamples, but its presence is considered qualitativelyquestionable due to its detection in the method and travelblanks at similar levels.

Summary:

All data reported for these samples are validated by the qualitycontrol information.

As : .....

AR30I535

Page 1 of 2*

Sample Data Package Review For CIBA GEIGY, INC. - KimbertonProject;

Reviewed Toy* /x '.trtf / J^fj-____ Date A - f t,»/T M-' . /'/)' "?

Review for Samples;

1181403 - R. Adams Mid A1181404 - R. Adams A. Carbon1181405 - R. Adams Raw1181406 - Epps Mid A1181407 - Epps A. Carbon1131408 - Epps Raw1181409 - Doran Mid A1181410 - Doran Mid 31181411 - Doran A. Carbon1181412 - Doran Raw1181413 - Effgen Mid A1181414 - Effgen Mid 31181415 - riffgen A. Carbon1181416 - Effgen Raw1181417 - Munz Mid A1181413 - Munz Mid 31181419 - Munz A. Carbon1181420 - Munz Raw1181421 - Moore/Yeager Mid A1181424 - Moore/Yeager Mid B1181425 - Moore/Yeager A. Carbon1181426 - Moore/Yeager Raw1181427 - Pfau Mid A1131428 - Method Blank1181458 - Travel Blank



Surrogate recovery valves were in specification for allsamples.


AR30I536

Page 2 or 2


Trace levels (£1 ug/1) of Methylene Chloride was detected inthe travel blank and method blank.

All quality control data is in acceptable limits.

Data Package Review;

Title page/chain-of-custody - sample description correct,field and lab chain-of-custody documentation correct and insequence.


Methodology summary - - all analyses were performed accordingto SPA Method 624 as referenced in the data package.

S am ple data package - analysis report, raw ionchrbmatograms, quantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.Methylene Chloride was reported in many samples on the rawquantitation reports at trace levels and are consideredqualitatively questionable due to their presence in the

and travel blank. .- a • .J';~ .. - • '

Summary :2t •

All data reported for these samples are validated by the qualitycontrol .information.

/hs ia- . - . i*' < .. .-.• :,

a56

flR30IS37

Page 1 of 2

Sample Data Package Review For CiflA-GEIGY/ INC. - KimbertonProject:

.•" 'Reviewed by. ' / JL SJ A. DJ — Date———————— ——— if ———Review for Samples.

1181434 - Pfau A. Carbon1181435 - Ptau Raw1131436 - Rittenbaugh Mid A1181437 - Rittenbaugh A. Carbon1181438 - Rittenbaugh Raw1181439 - Swier Raw1131440 - Weaver Raw1131441 - Hooney Mid A1181442 - Mooney Mid 31181443 - Mooney A. Carbon1181444 - Mooney Raw1181445 - C.R. Davis Mid A1181446 - C.R. Davia Mid B1181447 - C.R. Davis A. Carbon1181448 - C.R. Davis Raw1181449 - Hawkes Mid A1181450 - Hawkes A Carbon1181451 - Hawkes Raw1181452 - Wilson Mid A1181453 - Wilson Mid B1181456 - Wilson A. Carbon1181457 - Wilson Raw1181458 - Travel Blank1181459 - Method Blank

Quality Control Data Review:

BPB tuning Ion Abundance Criteria were all within allowablelimits.



AR3GI538 Tht

Page 2 of 2


Trace levels (<2 ug/i) of mechylene chloride was detected inthe travel blank and method blank.




Laboratory chronicle - volatile organic analysis Holdingtime of 14 days was met for all samples.

Methodology summary - ali analyses were performed accordingto EPA Method 624 as referenced in the data package.

- Sample data pacxage - analysis report, raw ionchroma tog rams, quantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.A transcription error was found in sample analysis report1181448. Chloroethane was incorrectly reported as BMDL.Review of the ion chromatogram and mass spectral dataindicated vinyl chloride was detected at BMDL. A correctedreport was resubmitted by the laboratory.

Detection of methylene chloride at trace levels in many ofthe samples raw quantitation reports are qualitativelyquestionable due to its presence in the method and travelblanks.

Summary:


/hs

AWOI539Ttw

Page 1 of 2

Sample Data Package Review For CIBA-GEIGY, INC. - KimbertonProjects

Reviewed by: a cf- J*f,i~ Date 3T - ' —Review for Samples.

1133808 - Sands Raw1183809 - Sands A. Carbon1133810 - Sands Mid A1183811 - Blank Raw1183312 - Blank Mid A1183313 - Blank Mid B1183314 - Blank A. Carbon1183315 - Ludwick Raw1183816 - Ludwick Mid A1183817 - Ludwick Mid B1183313 - Ludwick A. Carbon1183819 - Pifer Raw1183820 - Pifer Mid A1183821 - Pifer Mid B1183822 - Pifer Carbon1183823 - Ferrell Raw1183824 - Edinger/Little Raw1183827 - Cricket Corner Raw1133323 - Cricket Corner Mid A1183829 - Cricket Corner Mid B1183330 - Cricket Corner A. Carbon1133331 - Method Blank1183999 - Travel Blank




Percent recovery daca was in specification for the matrixspike duplicate analyses.

Jh... r

it: t!.'. f. • 'f * '•

Page 2 of 2

RPO data was in specification for all spiking compounds.

Methylene Chloride was detected at trace «2 ug/1) levels inthe travel blank and method blank.



Title page/chain-of-custody - sample description correct:,field and lab chain-of-custody documentation correct and insequence.



Sample data package - analysis report, raw ionchroma tog rams, quantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.Methylene Chloride was reported BMDL in sample 1183816 andis considered qualitatively questionable due to its presenceat similar levels in the method and travel blank.

Summary:


/hs

AR3DISM

Page 1 of 2

Sample Data Package Review For CIBA-GE1GY, INC. - KimbertonProject:

Reviewed by. l,'**-' 4-ij -rjL_____ Dace 1 -£;#££'.'W-* /7SO___- 7 ' ~T~ —"' ————

Review for Samples;

1187217 - Travel Blank1187218 - Bffgen Mid A1187219 - Effgen Hid B1187220 - Blank Mid A1187221 - Blank Mid B1187224 - Method Blank


BP3 tuning Ion Abundance Criteria were all within allowablelimits.

- Surrogate recovery valves were in specification for allsamples.


RPD data was in specification for all spiking compounds.(The QA/QC summary sheet incorrectly had the soil acceptancecriteria for % recovery and RPD. The reviewer compared thevalues to the water acceptance criteria).

The travel blank and metnod blank both detected trace «2ug/1) of methylene chloride.




AR30I5«*2

Page 1 of 2



Sample data package - analysis report, raw ionchroma tog rams, quantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.Trace levels of methylene chloride were reported on the rawquantitation report, and its presence is qualitativelyquestionable due to its detection at similar levels in themethod and travel blank.

Summary:


/hs

AR30I5WGroup

Page 1 of 2

Sample Data Package Review For CI3A-GEIGY, INC. - KimbertonProject:

Reviewed by: !/<***£ /- >____ Date__3 5 ^ -' ///",?-^ _^- ——,———-Review for Samples:

1187158 - Travel Blank1187159 - K.C. House Raw1187160 - D. Adams Raw1187163 - D. Adams A. Carbon1187164 - D. Adams Mid B1187165 - D. Adams Mid A1187166 - Method Blank


3FB tuning Ion Abundance Criteria were all within allowablelimits.




Trace levels of raethylene chloride (3 ug/1) was detected inthe travel blank. The method blank detected Acrylonitrileat an estimated 3 ug/1.




AR3015H TIM

Page 1 of 2



Sample data package - analysis report, raw ionchromatograms, quantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.Trace Methylene Chloride and acrylonitrile blankcontamination had no influence on sample results.

Summary:


/hs

*•- 1 ,AR361SI»5

Page 1 of 2

Sample Data Package Review For CIBA-GEIGY, INC. - KimbertonProject:

Reviewed by: ]/ flo X. fcAZ Date 3

Review for Samples.

1138043 - Pifer Hid A1188044 - Pifer Mid B1183045 - Ooran Hid A1133046 - Doran Hid B1188047 - C.R. Uavis Hid A1188050 - C.R. Davis Mid B1183051 - Hooney Mid A1183052 - Hooney Mid 31188053 - Travel Blank1133054 - Epps Mid A1133055 - Method Blank



Surrogate recovery valves were in specification for allsamples .



The travel blank and method blank were reported non-detectedfor all target compounds.




Th«

AR301.51*6

Page 1 of 2



Sample data package - a n a l y s i s r e p o r t , raw ionchroma tog rams, quantitation reports, and mass spectrum arepresent with raw data supporting the analysis report.

Summary:


/hs

Documents

Ardsley. New York 10502-2699 Telephone 914 478 3131 … · D. Adais - Kiiber Hall Suiiary of Analytical Data far Doiestic Hell and Carbon Systei All concentrations ug/1, parts per