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17/3/2016 RDR - µSR in superconductors DEPARTMENT OF MATHEMATICAL, PHYSICAL AND COMPUTER SCIENCES Applicaon of µSR Superconductors Roberto De Renzi Dept. SMFI, University of Parma ITER Persistent eddy currents: screening Levitation Kamerlingh Onnes 1911 Hg zero resistance N S

Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

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Page 1: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

17/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Application of µSRSuperconductors

Roberto De Renzi

Dept. SMFI, University of Parma

ITER

Persistent eddy currents:screening

Levitation

KamerlinghOnnes 1911Hg zero resistance

N

S

Page 2: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

17/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

µSR in superconductors

Q0: who did not have any superconductivity in their Syllabus?

Page 3: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

317/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Outline

• Superconductors– Meissner effect: magnetic field expulsion– London penetration of the field– Pairs and free energy– The gap and the coherence length– Type I and type II – Abrikosov flux lattice

• Experimental examples– bulk isotropic case– anisotropic superconductors– LE muons– gap fits– Uemura plot– phase diagrams

TC

Year of discovery

Page 4: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

417/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Meissner - Ochsenfeld effect

Shielding

http://www.superconductors.org/Type1.htm

t

B

Field expulsion: cool a sample below Tc

Meissner-Ochsenfeld effect

Page 5: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

517/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

London model: the penetration depth

A first lengthscale

Ampere Maxwell law

Guess the solution

Right!

Page 6: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

617/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Imagine

Q1: Implant muons in a Meissner state superconductor. What do you detect?

µSµ

Above Tc a precession

When cooling below Tc the precessiondisappears

cooling

Page 7: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

717/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Summary of superconductor facts

• Only for T < TC (pretty low)

• Only below a critical field (H < HC)

• Zero electrical resistance

• Magnetic field expulsion, requires a lenghtscale

How can this be explained?

Page 8: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

817/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Microscopic modelPrototype: BCS

Attraction

Cooper pair, compound bosoncondensation energy (binding) Δ

k

-k

normal metal

Δ

Page 9: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

917/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Mean free energy

Ginzburg-Landau

order parameter

magnetic free energy easy to add

supercurrents

Page 10: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1017/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

The gap:a second lengthscale

k

-k Coherence length ξ

● how far can you pull a pair apart?

Cooper pair

Inject an electron in a superconductor

● how far from the surface does it starts

to pair (feel the attraction)?

● Ginzburg Landau definition

Page 11: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1117/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Type I and Type II superconductors

Ginzburg Landau parameter

-M

H

Type I:

Hc

-M

H

Type II:

Hc

Hc1

Hc2

Page 12: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1217/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Abrikosov flux lattice

H

Hc1

Hc2

-M

H > Hc1

partial field penetration

H = Hc1

magnetic flux quantum

for

periodic solution

of GL equations

H > Hc1

flux lattice

H = Hc2

ΔF = 0

Page 13: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1317/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Imagine

µ

B

µ

B

Q2: Homogeneously implant muons in a bulk FL. What do you expect to measure?

Page 14: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1417/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Field distribution in the FL

• the Flux Lattice is incommensurate to the crystal lattice

• whereas muons are interstitials in the crystal lattice

→ dense random sampling

Page 15: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1517/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Field distribution in the FL

• GL equations predict

a

bB maxima

B minima

saddle point

Page 16: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1617/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Experimental caseVanadium

p(B

) arb

. un

its

0.16 T

0.20 T

0.24 T

0.29 T

Page 17: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1717/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Quck and dirtymultigaussian fit

Comparison with polycrystal data Second moment

is it worth while?

Page 18: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1817/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Anisotropic penetrationYBa2Cu3O6.9

E.M. Forgan et al. Hyperfine Interactions 63, 71

B

θ

Page 19: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

1917/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

La1.83

Sr0.17

CuO4 crystal

s-wave ns

σ(T): gap fits

YBCO6.95

crystal

Field cool, then shift field down(pinned flux lattice)

d-wave: lines of nodes

PRB42 8019 (1990)

YBCO6.95

powders (!)

0.05 T

Page 20: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2017/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

LaO0.5F0.5BiS

La Mura et al. Phys. Rev. B 88, 180509(R)

BiS2 ≈ CuO

2: conventional or unconventional superconductor?

s-wave, not d-wave

gap, i.e cost to break a Cooper pair

s-wave gap

p-wave gap

Page 21: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2117/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Low Energy muonsLondon penetration depth

B=Be−rλ z

µ0H

Field parallel to the surfacedecays exponentially witha penetration depth λ

R. Kiefl et al. PRB 81 180502 (2010)

Single crystal YBa2Cu

3O

6.92

Page 22: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2217/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

MgB2: two gaps

Two gaps, two fluids,with different effective B

c2

PRB42 8019 (1990)

S. Serventi Phys. Rev. Lett. 93 217003

YBa2Cu

3O

7

Page 23: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2317/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Uemura plot

σμ=γμ(⟨B2⟩−⟨B ⟩2)

12 ∝

1

λ2∝nsm∗

unconventional

conventional

σ ns T

F

At T=0:

Y.J Uemura et al. Phys Rev Lett. 62, 2317 (1989) 500 cit.

Y.J Uemura et al. Phys Rev Lett. 66, 2665 (1991) 300 cit.

Page 24: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2417/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Phase diagrams

S. Sanna Phys Rev Lett. 93 207001 (2004) Y.J. Uemura Nature Materials 8 253 (2009)

Page 25: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2517/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Imagine

Q3: How do we subtract the nuclear relaxation rate σn?

Tc

σn

σ(T)

In quadrature:

Page 26: Application of µSR Superconductors · • Superconductors – Meissner effect: magnetic field expulsion – London penetration of the field – Pairs and free energy – The gap

2617/3/2016 RDR - µSR in superconductorsDEPARTMENT OF MATHEMATICAL, PHYSICALAND COMPUTER SCIENCES

Recap

• Muons map the internal field distribution

• Two length scales, λ (currents, fields) and ξ (gap, wave function)

• Refined model (full distribution) for single crystal studies

• Rough model (second moment) for comparative studies

• σ(T) µ λ-2(T): gap(s), symmetries

• coexistence with magnetism

That's it ...