Annexure: I Land Possession Document · " Rosuvaslatin calCium -'-c-" 100 Strontium 150 (l1 9. , 20 Tazarotene -2 " Telmisartan 300 22. Trospium 50 23 Ezetlmibe 40 24 Citalopram hydrobromide

Annexure: I Land Possession Document

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Annexure: II Consent to Establish (CTE)

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..... , ... ur NTROL BOA • '111/:t4 4'01 ~,., "",24D68J24044531

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RodlLSI Consunt NO,BOISRQ·NashlklASlnIEIC.NK-9748-11fEl ce- Q...lO Dato:2f:" 110 /2011

Consent to Establish undor Section 25 of the Water {PrevenUon & Control of Pollution) Act, 1974 & under Sec tion 21 of the Air (Prevention & Cont ro l of Pollution) Act, 1981 and Author ization under Rule 5 of the Hazardous Wastes (MaJ"l"gement, Handling & Transboundary Movement) Rule',2008. [To be reforred as Wato~ Act , Ai r Act and HW(M,H & TM) Rules Nlilpec ti voly].

CONSENT is hereby gf'8nted to t.'lJs. Vadivarh& Spech,l ily Chemicals (Expansion),

Gut 00. 204, At Post: Vaavarhe. Tal-lg3Ipun, Oisl-Nashik.

located In the area declared under the provisions of the Water Act, Air act and Authorization under the prOVIsions of HW{M&H) Rules and amendmeotslhereto subject to the porovl$rons of the Act and the Rules and the Ordef$that may be made ItJrther (lnd subject to the followng terms and conditions.

1. The Consent to Establish Is granted for a period up to -Commissioning of the Unit or 5 years which Is earlier.

" Consent to Establish will be opera ti ona l only after obtainina Environmental Clearance from Competent Authority by the applicant and subject to the compliance of conditions stipulated in an Environmental Clearance Includina conditions wh ich may be more strinaent if stioulated , by I in the Env ironmental Clearance. " , Tha Consent 18 va lid for the manufacture of-

S, . Product Max. Qty. (Kg/M)

1 Adapalene 5 -,- I .e.!orvastatin 800 , -, 8rimonidine 5

4 Bromfenac 2 , ~s!ortad:ne 25 t--, EscitaJopram Oxl.te 100

7. Febuxootat 40

• Gabapentin 100

9 Ghmepride 120

10 Montelukasl No 100

11 MOKifloxacin 700

12 Nrtazoxanlde 500

13 010patadine 2

14 Otanzapine 100

15 Olmesarlan 25 - -16 Prasugrel /q,,·.l .. ..:i,,·'r~ " 17 Risperidone __ -;/' \>."i 25 ,

-- -- f{ nl~."'· ~.J . ,

~, .. ,

Rosuvaslatin calCium -" 100 '-c-" Strontium 150

(l1 9. ,

20 Tazarotene 2 -

" Telmisartan 300

22. Trospium 50

23 Ezetlmibe 40

24 Citalopram hydrobromide 50

25 Phenytephrine Hydrochloride 5000

26 Niacinamide 10 - 27 Fnlctopyranose Sulfa mate fTopiramate

500

3. CONDITIONS UNDER WATER (PREVENTION 8. CO NTROL OF POLLUTION ) ACT, 1974;

(i) The daily Quantity of trade effluent (including boiler blow down) from the factory shalt not exceed JJ M3.

(ii) The daily quantity of sewage effluent trom the factory shall not excee<l1.6 M~.

(iii ) Trade Efrluent Treatment; The applicant shall operate comprehensive treatment system consisilng of primary and seCondary! tertiary treatment as is warranted with reference to Innuent quality and operate and maintain the same continuously so as to achieve the quality of the treated effluent to the fol lowing standards.

I pH Between 6.5 to 8.5 2 Suspended Solids Not to exceed 100 mgn 3. BOO 3 days 27 Deg. C Not to exceed 100 mgn , COD Not to exceed 250 mgn 5. Oil & Grease Not to exceed 10 mgn 6. TOS Not to exceed "00 mgn 7 Chlorides Not to exceed 600 mgn 8. Sulphates Not 10 exceed 1000 mgn 9 TAN. ~ot to exceed 50 mgn 10 % Sodium Not to exceed 60% mgn 11 Phenolic Compound Not to exceed 5 m911• (IV) Trade Effluent Disposal: The treated effluent shalt be reused ill lt1e process to ". maximum extent and romalning shall be used on land for gardening

(v) Sewage EfflUent Treatment : The applicant shall provide comprehensive treatment system as is warranted with reference to innuent quality and operate and maintain the same continuously so as to achieve the quality of treated effluent to the fo llowing standards:

(1) SUspended Solids Not to exceed 100 mg!1. (2) 800 3 days 270 C. Not to e;.;ceed 100 mg/l.

(vi) Sewage Effluent Disposal : The treated .domestlc effluent Shall be soaked into soak pit which shall be got cleaned periodically Overflow if any shall be used on land for gardening I plantation only.

(vii) NOn·Hazardous SoHd Wastes ; Sr. No. ~ Qf w aste

1 Empty drums 2. Plastic bags

Quantity 500 NOs/Yr 300 KglYr

Treatment

(viii) Other condi tions: The industry Should monitor effluent quality regul<:lr1y.

Disposal Sale Sale

4. The applicant shal l COmply with lt1e prOVisions of the Water ( Prevention & Control of Pollution ) Cess Act, 1977 (to be referred as Cess Ac t ) and amendment Rules. 2003 thereunder

The daily water consumption tor the followm9 categories IS as under' (i) DomesllC 2.0 CMD (I) IndUSlTla! Processing 480 CMD

Industrial COOhngJBoller 5.0 CMD A9"lC1J':urelGardemng ~. CMD

;.-;(o\1uf;o~ ..

/~ .... r'- ~ "' ~;-'l ~ ( ',_. - ~~~; ~

The applica"t shall regularly submit to the Board th" returns of wOlle.' consumption In Ihe preSCflbed form and pay the Cess as specified undel Section 3 of the s<lid Act

5 CONDITIONS UNDER AIR (PREVENTION &. CONTROL OF POLLUTION) ACT, 1981:

(,) The applicant shall ins!(lll a comprehenSive control system consistlflg of control equ!pments as is warranted With reference to generation of emission and operate and r..alntalfl the Same continuously so as to <lchieve the level of pollutants to the foHowlng standards

(ii)

AI Control Equipment; Air pollution controt eQJipments of SuffiCient capacity shall be provided to limit the emissions

B) St .. ndards fo r Emissions of Air Pollutants : (i) SPMfTPM Not to exceed Iii} SOl Not to exceed {iii} HCt Not to exceed (iv) Cil Not to exceed (v) NOx Not to el(ceed

150 mg/Nml

18.0 kglday 35 mg/Nm 3

3 ppm 35 ppm

(C) Con ditions for DG Sets; -1 Noise from DG Sets Shall be controlled by provic'ing acoustic enclosure or by treating the

foom acoustically. 2. Applicant should provkle acoustic enclosure for control of noise. The acoustic enclosurel

acoustic treatment of the room shall be designed for minimum 25 dB(A) insertion loss or for meeting the ambient noise standards, whichever is on higher side, A SUitable exhaust muffler with insertion loss of 25 dB(AJ shall also be provided_ The measurement of insertion loss shall be done at different points at 0.5 meters from aCOlJstic enclosurel

3.

4.

5.

6.

7 .

8.

room and then average. The Applicant should make efforts to bring down noise level due to OG Set, ou tside the premises. with ambient noise level requirements by proper setting and control measures Installation of OG Set must be strictly in compliance with recommendations 0/ OG set manufacl1Jrer, A proper routine an" preventive maintenance procedure for DG Set shall be set and followed in consultation with the OG manufacturers, which would help to prevent noise levels of DG Sets from deteriorating witll use. The DG set shall be operated only in case of power failure The appl icant shall make arrangement fOf regu lar electrical power. The Applicant shall oot cause any nuisance in the surrounding area due to operation of DG sets. In case of problems, the O.G. set shall not be operated until it is set back to satisfactory position.

The applicant shall observo the following fuel pattern :-.fu:l::!Q. ~ ill Fuel Quanl"ty 1. LDO 20 LitrlHr. 2. Diesel ':0 LitrlHr.

(iii) 1-he applicant shall erect the chimlley(s) of the following specifications :_ ~ Chimney attachea ill Height iD M~rs_ 1. 80iler 15 2. DG set (250 KVA) 5'

(. above the height of building where the DG set is installed)

(iv) T,he applicant shall provide ports in the chimney/(s) and facilities such as ladder, platform etc. for monitoring Ihe air emissions and the same shall be open for inspection to/and for use of the Board's Staff. The chimney(s) vents attached to variOus sources of emission shall be deSignated by numbers such as 8-1. 8·2. etc and these Shall be painted/displayed to facilitate Identificatioll

(v) The industry shall take adequate measures for control of noise levels from its own sources within the premises so as to maintain ambient air quality standard in respect of noise to less than 75 dS{A} during day time and 70 dB(A) during night time. Day time Is reckoned in between 6 a.m and 10 p m and nigh: time is reckoned between 10 pm, and 6, m

= -

(vi) Other Conditions : 1) The mdustrv should nOi cause any Ilulsance in sUf/oulldll1g area 2) The mduslry should IT1OO1tor stack emissions and ambient air quality regularly

6 CONDITIONS UNDER HAZARDOUS WASTE (MANAGEMENT, HANDLING & TRANSSOUNDARY MOVEMENT) RULES, 2008. ·\The applicant shall handle hazardous wastes as speofied below

SI Item No of process Type of Waste Quanhty Oisposal gel'lP.l"atmg HW as - oer SChedule-I

1 343 ETP sludge 0.2 MTlYr CHWTSD FJ (II)The aulhorl/!atlon IS hereby granted 10 operate a facility for collection. storage. transport and

disposal 01 hazardous waste

1. VVhenever due to any accideflt or other uflforeseen act or even. SUCh emissions occur or IS apprehended 10 occur in excess of slalldards laid dowll. such infonTl8lioo shall be forthwith Reported 10 Soard, concerned Police SlaOOIl. offiCe of Directorate of Health SefVices. Department of Explosives. Inspectorate of Factories and Local Body. In case of failure 01 pollution control equipments, the production process connected to it shall be slopped.

s. , b.

o.

d.

•• f.

g.

h.

j

Gener.1 Conditions:

The applicant shall maintain good house keeping and take adequate measures for control of poIlutlon from an sources so a~ not to cause nuisance to surrounding areafinhabitants. The applicant shall bring minimum 33% of the available open land under green coveragef plantation. The appliCant shall submit a yearly statement by 30'" September every year on available open plot area, number 01 trees sUfViving as on 31" March of the year and number of trees planted by Sepetember end. Solid Waste - The non-hazardOUs solid waste arising in the factory premises, sweepings, etc be disposed of scientifically so as not to cause any nuisance I pollution. The applicant shall take necessarv permiSSions from civic authorities for disposal 10 dumping ground .

. The applicant shall provide for an alternale electric power sOurce sufficient to 'operate all pollution control facilities installed by the applicant to maintain COI'IIpllarice with the terms and conditions of the consent. In the absence, the applicant shall stop. rejuce or otherwise. control production to abide by terms and conditions of this consent regarding pollution levels. The applicant shall not change or after'!he quantity, quality, the rate of discharge, tempef3\urc or the mode of the effluenUemissions Of hazardous wastes or control equipments provided for without previous written permission of the Board. The applicant Shall provide facility for collection of environmental samples and samples of trade and sewage effluents, air emissions and ha<:ardous waste to the Board staff at the terminal or d .. "ignated points and shall pay to the Board for the sefVices rendered In this behalf The applicant shall make an applicatioll for renewal of the consent at leasl60 days before tho date of expiry to the consenL The firm Shall submit to this office. the 30'" day of Sop:ember every year, Ihe Environmental Statement Report for the financial year ending 31 01 Mardi in the prescribed Form-Vas per the provisions of I'\lIe 14 of the Environment (Protection) (Secolld Amendment) Rules, 1992. An Inspection book shaU be opened and made available to the Board'S officers during thell viSit to the applicant. The applicant snail ins~1I a separate meter showing tile consumption of energy tor operabon of domestic and industrial effluent treatment plants and air pollutIOn control system A register showing consumplion of chemicals used for treatment shall be maintained.

k. Separate drainage system shalt be provided for coIlectiOll of trade and sewage effluents Terminal manholes shall be provided at the end of the conection system w~h arrangement lor measuring Ihe now. No effluent shall be admitted In the pipes/sewers down stream 01 the terminal manholeS. No effluent shaW ~nd its way other than in designed and provided collection system

t. Neither storm Vlater nor discharge from other premises shall be allowed to mix With the effluents from the lactory

m. The industry shall ensure that h.lgitiYe emissions from the activity are controlled so as to maintain clean and safe environment in and around the factory premises.

9. The applicant s hall obtain Consent to Operate before Actual Commencement for the production activity.

-

~ e 5fflps 'or Implementation of the projec tIeIor.o • ~ ... .:arance as per ErA Notification 2006 anc ilR'i!:1IdI;4»WS ~o ~ .1"'11 "OI'I-<;OlI'!phance of the Conditions of consent to estab lSI! ob5en-ed_ the Board will Initiate appropriate legal action including forfeiture ot SanO<" Guarantee. revocation of Consent & furthel action.

11 Industry .$han submit additional consent fees of Rs.5000/. as pcr the revised fee Slrocture dated 25/08/2011 to the Regional Offi ce, Nashik.

12 This Board reserves the right to amend or add any conditions in this consent and the same shall be binding on the Applicant

13 The capital investment of this eXpansion IS r 4 53 Crs. and total capital inves/menl of the indl.Jstr)l

i"1479C~. ~._* "",

To,

MIs. Vadivarhc Speciality Chemicals {ExpanSion) Gut no. 204, At Post Vadivarhe, Tal -lgatpul'i,Dis/.-Nashik.

Copy to:

{Milind Mhaiskar, lAS) Member Secrelary

RO-Nashik ISRO-Nashik - They are directed to obtain additional consent fees of Rs.50001_ from the industry as per new GR dated 25108/2011 . , CAO I Cess Branch I Master File

Received Consent fee of -

Amount Rs_10,OOO/_

0 ,0 , No. 044617

Date 1210812011

Drawn on Axis Bank

I

, Visit At

• \SII .1. '= '\ P Ol . r' " ,{f- .o• " " " J .Jl.~L~,.AtJ.

3714')2-, ''''~3, 124140J~27 2~044532/4024008 1402351 6

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S'OI, ~ .~ Ch""'C ', Q;e d ! ':C,_ 3, Opp Cine f:'i".~~· L,"<'<':'la '~e .r S~c,;' eirc,I", Sion (E) ,

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Cons'!'! 1 No: IJOIJD-PJllIfS/EIC NQ.NJ(-(j(jO 7-ll/WeC_ '2. "l...."L

Co nse nt to Estnl,lish und er SccUun 25 of th e Water (Pnol"cll l ioli &: COll i rol of Pollution) Act. 1974 & und e r Scctioll 2 t of the Ai ,- (P '-cvclIt iOn & CO nll"(, j of Po llution) Ac t, 1981 an d Aut.h orization I Renewal of A lt th01'i~,\tion u nde r R u le 5 .,[ t he Ha za r dous Was t (!S (l\'fall ll ,~cment, Ha ndling & 'l'ra"sboundry Move ment) Rules 2008

ITo be ref~ned Il.s iVOI ter Act, Ai r Act and HW (1\1&H) Rule) e~-;:veIYI .

CONSEN T is h ere by granted ,t o .,

Mis. V"di va r h e Sp ecilialitx.,Ph cmica ls Ltd; (I~Ot n1crly Fem Caxe Ph a.-ma Ltd.) . GUt No. 2tt4, NP, V.ad~"t.l'ho 'I'ld. Iga(l>ll~ i

. Dist. Nashik. located in the ul'lla decla red under the prov i"Ho~ of t he WutJ.1 r Act, Air act and A utho~lzation lIode r. tho provisions of H\X,d?S..tn Rules and amcndmcnt$ t.hereto

s ubject to the provisions of the Act ~Il~~i"ftules and the Orders that may be made further (lnd ,! ubj~t to the fOll~~g;erms and conditions: ' .

1. The Cons:cnt to. Estnb.FSl\ is g~an~ed for .a lle~iod up to:Coin rnissio.ning Of the UnIt or FIV!': Yttars.whlch -:: \ 0:1' ts earlier.

2. 'I11C Co n.scilt is valid fu r the m an nfacture'of ....

., '1

I

I

~-----

l~ ,

PranlucaSI Hydrate 20 ctr!: Melhdilazine Hydrochloride 50 ._.

14 Larnolrizine 50 15 ~ !3rcgabalin 100

16 , Brimonidine Tar1arafe 2

17 Dorzolamide Hydrochloride 20 18 Betmelhasone Dipropionate 20 19 8etmelhasooe Valerate .

20 20 .} Ambroxol HydrOChloride 500 ')..

- '\. '" 3. WNDITIONS UNDER WATER ACT: <:",.~'?$ (ij '1'he uaily CJ~antity of trade efi1uenL from the facwry shall n~ e\~.8J\13.

(ii) The dilily quantity of sewage effluent from the factory sha~'),exceed O.R M',

. ~ (iii) Trade Effluen t:': .. _' .. r ('\,~ . ', ..

l'reaunent: Thll ilj'l ;'ih cant shal,l p roVl(le COIl'.pyehenSlVe treatment ~y5tcJ1l oonsj ~!'ng of pdma,ry I secondary andlor ~iarY'treatmenl as is warran~d-with wference. to influent ?,mlity ana op~m!(~~d~maillt"in the, same contin~ous Jy so as to achIeve the C/uahty of the trea:~fQuent to 1111, folIowmg.standank .

~ ~ <-> ....

1 pH , , Between 5.5 10 90 2 Oil& Grease ·t .... Not to exceed 10 rug/I , Suspended So id~ Nol to exceed 100 mg/l. 4 COD

"" Not to exceed 250 mgtl 5 BOD 3 daY~:i!7 Oeg. C 1\'0110 exceed 30mg/l. 6 Tg~, Not 10 exceed 2100 mg/J. 7 pQ!~'pes NOllo exceed 600 Illg!1 8 Sulphates Not to exceed lOpO Illgl1 , % SOdium -~~.

Not to exceed 60% IU&"fJ "

10 Phenolic Compound Not to exceed 5 mgtl. I

(i,.) 'I',·ade Efil llcnt DiSposal: The treated industrial effiuent shaU be reused/recycled to the m""imum extent and remaining ~ha rI lise on laud for gardcIlIng within Own pl"Cmises. There shall not be any tlisch"rge outJ;ide tim factury pre mises.

(v) . Sewage Eflluen t Tre"tmen t; The applica nt ehall pro·,ide C("lIuprehensive treatment syStem as is warranted ,vith reference to infl uent qUlIlity · and operate ulld maintain the same continuously· so as to <U..."liove til" quality of treated em"ent to I.he foliuwing Standards.

2

6,

----- - - ----

(0 Suspended :5olids (2) BOD 3 dnys 270 C.

Not to exceed Not to exceed

100 mg/1. 100 Illg/l.

(vi) Sewage Effluellt Disposa.l: The treated domestic eronent shall be 'Waked in a soak pit. which shall b.: got cleaned periociicall:,. Overnow, if ,IllY, shall be used on hind for g"rdening I plantrltion only.

(vii) Non-H"ZD;n!ous Solid \V"stes:

4 . The ~pplical:t shall comply with the p:-ovisions :O~f'f,'~~h~;':,~~~~I~r~~'~,'~G;' & Contl"Ol of POll ution) Cess Act, 1977 (to be .Act) and amendm en t Ru les, 2003 there under

The daily IVllter consuloption for the following ",,,,,,:,:\,~ '~, under:

(i) Domestic PUfjlOSS

(ii1 Woltel"_gets Pollh • .:.i & POlluUtnts are Biodegradable

(iii) Water gets Polluted, Pollutanu; N ll.re not Biodegradable & Toi,,,",

(iv) Industrial Cooling. Spra{il~"\} in mine pits 0 .. boi.Jer f~e7.l.,~ ..

The applicant shull re\'.iIa~ "'\ubmit consulUption in the l?rescn.bedfo;rn and Scetion:1 of the said Act

. ,

1.0 eMu

0.00 CMD

0.00 eMU to t he Board the retul"Us of water pay the Cess as specified .under

5.· r.ONDITIONS UNDER AIR ACT;

(i) The f:ap~kant 'shall install a comprel,ensive control system C¢llsis fltl g of contro) equipments as is warranted with ref()rence to

'i~b:~'bo" of I1mission and operate and maintuin the sam~ ilIDhlinllously so as to achieve th(devel ofpollutunts lo tho following

'standQrds

a. Conn'ol Equipment;

InduSLey sha ll provine Air pollution control eq.uipments of sufficient capacity to control the emissions .

. 8) Standards for Emissions 6r Air Pollutants: (i) SPMrrPM Not to exceed (iiJ 502 Not to exceed

150.0 mgfNm1

- Kg/Day

51(0 Nashi kllndIRedlLSI,OJ0272W

3

l

I

(I) The ;lpplic .... nl s hall observe t he follo wing fuel patlern:-(NO Chll.llge In Ex i sting)

Sr.No. " __ TypcOfFtieI :0-Quantity ~ e " UO;U -

" .,.-- .!.,,-=":-".;:,., "'r:-~t-;-'- '" " ,- . -

I LDO 20 Litr/hr.

2 Diesel 40.00 Litrlhr. for DG

(ii) 'rile :Ipp lican t ~hllll e rect th e c hinmcy (s) of the fo l owing

~ --ladder. platform l!~. tv: m~llil.onltg l!u",a:)' the slime shall be open (01 lI'lspeCLion toland fo r use o( the ""Board's attached to various 'OU~5 of ~~)QIl shall be deSIgnated by numbers such as So l , 8·2, etc. an? t~" ~all be pailltedl d~played to [uclhUlte

' Identlficatlon (iv) The lOdustl1' shall takEl)qe~a measures for control of nOI SC levels from

Its own sources IV l1huI tTk:),remlSCS so as to maintain ambwnt mr quality standard !II respect ~no),e ' to, less than 75 dll(A) durmg day time 91lJ 70 dB(A) dUri ng I1Ight time Day time is reckoned ll1 between 6 II 01 and to p.m . . alld nighlfr l~is 'li!ckollcd between to p.m .. and ti a.In ...

(v i) Other Condition!!: . . • 1) Tho i1l:dll~~OUld n~t cause allY nuisance in surrounding area. 2) The i d\~Lry should ~onitoT stack emissbns and amb\onL OiT quality

~g~J"!Y, 7. CONDITIONS . UNDEn HAZARDOUS WASTE (MANAGEMENT,

HANDlJN~ & TnANSBOU NDRY MOVt:f\-IENT) RU LES, 2008:

.~

(li) 'l'r'l<Itment: . NlL

It. Whenever duc to ony accident or otIH.'"1" UnfOreSCffi IICt. 01' cvcn, such cm:"sion8 occur or is app,.~hemled to occur in execs.; of slanill!rds laid

SItO Nash,"kIIndlRedIlSIlOL027280 ,

" .

I (\

du" n. lIuch Information shall be forthwith Reported to Board. concerned roliC(! Statu'm, office of Diroctorute of Health Services, DC,wU:l.ment of E:<pl06ivC8, Inspectorate of Factories and Locnl Body. In case of failure of pollution control eqlUpments, the productIOn process connected tD it sha II be stopped.

b. The unit has to display and m!linUlin the dflt3 online outside the fa ctor)' uwin i:aI.C in Marathi & EuSlish both 011 a 6'x4' display board in the mannel' and the rc]lOrt of the oolUplLunco nlong with photograph shall be submitted to thia office & ooru::erne'1 Regional Office! Sub Regional OlTice.

c. It shall be ensured that the Hawrdolls waste IS lwndled, ~all;~ged & disposed of strictly In ,accordance with t he Haza~Oiht.rwast.e (Management & Handbng) Rules, 2008 and shown &~~ tod to the Board ti S & when ASked for. :\...'.J

S. Ind ustr y :.ha ll comply wi~h followmg additional conditions\)

i. The apphcant shdl maintain good housekeeping a~ talCe adequate measures for contro! of pollution (ronl all ,oun:e~ 50 ns lib-l to cause nuuanOO to surrounding area' inhabitan~,

H, The a:p\;liCalit s hall hring uiini.': ... u. 3J% or the avaIlable open land under green coverage' tree plantation, . ~

iii. Solid waste - The non hazardous s~~'aste arising in the factolj' premises, sweepings, etc., he ~i5p08ed of -v:l~It~auy so 9S not to cause any nui8an~c I pollution. The applicant shall t.a~e ~saary )lIIrmiMiolU\ from civic authorities for disposal too dumpmg g~" ,

iv. The applicant s hall provi al.ternat.e electric power source sufficient to operate all pollution ~£ dlities installed by he applicant te maintain compliancc with the ter s -and condit ions of tbe covsent. In the absencc, the applic. .... n~ shall s~~u or oth'~rwise, ~.nt."U1 !Il"Od uction to abide 'by t.erms & conditIOns of'thI~L·(~I;tent ro!l"nhng poUuyon le,· .... 15. - .

v. The applica~\ siJiu. ot change or alter quantity , quulity, the rate of discharge, temperatllr(.Qf'J,\e mode of th\! effluent' emissions Ol· hazardou3 wastes or control ,~iffi1t:nts provided .t~r wi:.hout previou:i written perllli88ion of the Board . ..,.,~, '

'vi. l' "p~J,U:ant ahall provide facility for collection otenvironmenul samples IlIId p.mpl'es of trade and sewage effluents, air emiuioll$ and hllzurdous wastos to tI,t B'oard staff at tile k:rminul or d('~ignated points nnd ~hlill pa,y to the Romil mr the ,ervioes rendered in tllla behnlf.

,jj. The applicant ~hall mali!l 1111 application for renewal of the consent at teast 60 days before' the date of the eXI?Uy of the oonsent. .

viii. The firm ahall submit to this office, the 30th day of September every year, the Environmental Statement Report for the £inan~ial year ending 3t" Marl:h in the prescribed F'orru.v as pro the provisions of rule 14 of the Enviro.nm~nt (Protection) (SecOnd Amendment) Rules, 1992.

ix. As inspection book 611:111 be opeoed a nd ulade available to the 803.1·d'8 officers during thl'i r visit to the applicant. '

x. The appli~lnt shall install a separate electric: meter silowjng the consumption uf enOI'gy fOI" opemtiol~ of dOOlestic and indust";a l cflluent t l'eatment plams llnd

SRO l'I..t.ilJlnd!RoHl.S 1101021210 j

- - --~---- ---.

'''. poU'tion 'on"o' '''''m. A .. ",",. ,"ow,,,, Nn",,,,,,",,,, of ""'01"" '"d [or trelltment shaH be luaifllail\cd.

XI. Scparate drainage sYStem shall be prOvided for cOllection of trade and sewilgo.>

efflucnts . Terminal manhol~s shall be pro,vided at the end of cOllection system With

arrango.>m"'nt for meaSuring the flow. No effluent shall be admitto.>d in the pipes /sewers down_ stream of the terminal milnholes. No effluent Shall find Its Way Other than in designed and prOVided collection system.

"'.N,,,,,,, '''''m w,'" n", ""'"'' ''Om 0,"" "'ml,,> ,h,,, b, "'ow," '" ml, wi>" p" ""OOn" ''Om 'h, I,ao~ . ~

9. Th, Ind",,,, ,h"'id no< "', On, ,ff""" "," I", 'm",m"'''''n 01 Ih~~~) b"o" obi"mn, '''''mnm",,,, CI""n"" '" ElA NO<III""o" "06, S. 0-'" amendments thereto. If ~nV nOn_ COmpliance of the Conditions of cO~i~'4$establish Observed, the Board will Initiate aPl!'opriate legal aetion Inciuding{ orfei.tYl"e of Bank Guarantee, revocatiOn of conSent & further "'etlon

, "~"'--""""-"'~,,~ ~ 1ft II! ' ._'1 Cfuc: . . _ to;'

::'~ o~ '-' At. ,L.. ~ ~ ~ " r',.-t\ ( hnd Mh>lISka., lAS) ~~ ~".)< • ~'\.,,}' Mefnbcl"Sccre t,u'Y ">. ,,,,,,"" ~ ~ '\; .

T~ ~~~ !\-1Is. Vndiva'-l!e SpecilialitY\Q},Clllica.ls Ltd; (Formedy Fem CaJ'e Plla" la"ttd.)

a lit No. 204, AlP. Va di vtrlle Tal. Il:"tltPl~l"i Dis t. N" s hik. ""'-"'\" Copy to; ~~ '\

I) R'gl"" om"~,,!"C8, N"'I1k J. Th.y 'CO dk"ted to eo,"c. the 2) Sob-R,glon" Of'!", MPCS, N""1k J compll,n,e of oon":,, OOodillon, 3) Chief Accounts Officer, MPCB, Mumbai Received Consent fee of _

R~CEivcd Con snnt fcc of_

Annexure: III Consent to Operate (CTO)

Annexure: IV ToR Letter

Annexure: V Plant Layout

Annexure: VI Court Order

Annexure: VII MPCB Petition Letter

Annexure: VIII Environmental Policy

Annexure: IX TSDF Membership

Annexure: X Raw Data for Ambient Air

Location – 1 _Project site

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(ppm)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 73.9 35.47 9.61 21.43 0.53 9.61 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

04/10/16 1 72.3 34.70 9.40 20.97 0.52 9.40 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

10/10/16 2 69.9 33.55 9.09 20.27 0.50 9.09 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

11/10/16 2 68.8 33.02 8.94 19.95 0.50 8.94 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

17/10/16 3 76 36.48 9.88 22.04 0.55 9.88 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

18/10/16 3 61.3 29.42 7.97 17.78 0.44 7.97 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

24/10/16 4 68.7 32.98 8.93 19.92 0.49 8.93 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

25/10/16 4 66.4 31.87 8.63 19.26 0.48 8.63 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

07/11/16 5 97.9 46.99 12.73 28.39 0.70 12.73 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

08/11/16 5 66.9 32.11 8.70 19.40 0.48 8.70 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

14/11/16 6 66 31.68 8.58 19.14 0.48 8.58 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

15/11/16 6 58.8 28.22 7.64 17.05 0.42 7.64 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

21/11/16 7 60.1 28.85 7.81 17.43 0.43 7.81 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

22/11/16 7 59 28.32 7.67 17.11 0.42 7.67 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

29/11/16 8 65.1 31.25 8.46 18.88 0.47 8.46 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

30/11/16 8 99.7 47.86 12.96 28.91 0.72 12.96 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

05/12/16 9 79 37.92 10.27 22.91 0.57 10.27 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

06/12/16 9 79.9 38.35 10.39 23.17 0.58 10.39 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

12/12/16 10 72.1 34.61 9.37 20.91 0.52 9.37 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

13/12/16 10 63.1 30.29 8.20 18.30 0.45 8.20 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

19/12/16 11 66.8 32.06 8.68 19.37 0.48 8.68 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

20/12/16 11 73.5 35.28 9.56 21.32 0.53 9.56 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

26/12/16 12 67.4 32.35 8.76 19.55 0.49 8.76 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

27/12/16 12 62.9 30.19 8.18 18.24 0.45 8.18 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

Max 99.70 47.86 12.96 28.91 0.72 99.70

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Min 58.80 28.22 7.64 17.05 0.42 58.80

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Average 70.65 33.91 9.18 20.49 0.51 70.65

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

98percentile 98.87 47.46 12.85 28.67 0.71 98.87 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Location – 2

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 97.9 46.01 8.81 28.39 0.69 16.35 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

04/10/16 1 85.2 47.71 9.37 24.71 0.60 14.23 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

10/10/16 2 94.4 52.86 10.38 27.38 0.66 15.76 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

11/10/16 2 98.7 55.27 10.86 28.62 0.69 16.48 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

17/10/16 3 85.5 47.88 9.41 24.80 0.60 14.28 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

18/10/16 3 84.8 47.49 9.33 24.59 0.59 14.16 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

24/10/16 4 73.4 41.10 8.07 21.29 0.51 12.26 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

25/10/16 4 78.4 43.90 8.62 22.74 0.55 13.09 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

07/11/16 5 68.5 38.36 7.54 19.87 0.48 11.44 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

08/11/16 5 87.4 48.94 9.61 25.35 0.61 14.60 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

14/11/16 6 94 52.64 10.34 27.26 0.66 15.70 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

15/11/16 6 81.4 45.58 8.95 23.61 0.57 13.59 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

21/11/16 7 99.2 55.55 10.91 28.77 0.69 16.57 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

22/11/16 7 93.8 52.53 10.32 27.20 0.66 15.66 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

29/11/16 8 65.6 36.74 7.22 19.02 0.46 10.96 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

30/11/16 8 84.7 47.43 9.32 24.56 0.59 14.14 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

05/12/16 9 81.4 45.58 8.95 23.61 0.57 13.59 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

06/12/16 9 78.5 43.96 8.64 22.77 0.55 13.11 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

12/12/16 10 80.7 45.19 8.88 23.40 0.56 13.48 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

13/12/16 10 84.5 47.32 9.30 24.51 0.59 14.11 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

19/12/16 11 91.9 51.46 10.11 26.65 0.64 15.35 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

20/12/16 11 94 52.64 10.34 27.26 0.66 15.70 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

26/12/16 12 99.4 55.66 10.93 28.83 0.70 16.60 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

27/12/16 12 97.2 54.43 10.69 28.19 0.68 16.23 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Max 99.40 55.66 10.93 28.83 0.70 16.60 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.2 Min 65.60 36.74 7.22 19.02 0.46 10.96 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.2 Average 86.69 48.18 9.45 25.14 0.61 14.48 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.2 98percentile 99.31 55.61 10.92 28.80 0.70 16.58 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.2

Location – 3

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 72.4 33.30 6.52 13.76 0.40 7.75 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

04/10/16 1 70.9 32.61 6.38 13.47 0.39 7.59 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

10/10/16 2 68.5 31.51 6.17 13.02 0.38 7.33 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

11/10/16 2 67.5 31.05 6.08 12.83 0.37 7.22 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

17/10/16 3 74.4 34.22 6.70 14.14 0.41 7.96 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

18/10/16 3 60.1 27.65 5.41 11.42 0.33 6.43 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

24/10/16 4 67.4 31.00 6.07 12.81 0.37 7.21 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

25/10/16 4 65.1 29.95 5.86 12.37 0.36 6.97 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

07/11/16 5 72.4 33.30 6.52 13.76 0.40 7.75 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

08/11/16 5 65.5 30.13 5.90 12.45 0.36 7.01 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

14/11/16 6 64.7 29.76 5.82 12.29 0.36 6.92 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

15/11/16 6 57.6 26.50 5.18 10.94 0.32 6.16 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

21/11/16 7 58.9 27.09 5.30 11.19 0.32 6.30 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

22/11/16 7 57.9 26.63 5.21 11.00 0.32 6.20 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

29/11/16 8 63.8 29.35 5.74 12.12 0.35 6.83 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

30/11/16 8 70.1 32.25 6.31 13.32 0.39 7.50 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

05/12/16 9 67.4 31.00 6.07 12.81 0.37 7.21 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

06/12/16 9 68.3 31.42 6.15 12.98 0.38 7.31 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

12/12/16 10 70.7 32.52 6.36 13.43 0.39 7.56 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

13/12/16 10 61.8 28.43 5.56 11.74 0.34 6.61 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

19/12/16 11 48.5 22.31 4.37 9.22 0.27 5.19 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

20/12/16 11 72 33.12 6.48 13.68 0.40 7.70 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

26/12/16 12 66.1 30.41 5.95 12.56 0.36 7.07 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

27/12/16 12 61.6 28.34 5.54 11.70 0.34 6.59 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Max 74.40 34.22 6.70 14.14 0.41 7.96

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Min 48.50 22.31 4.37 9.22 0.27 5.19

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Average 65.57 30.16 5.90 12.46 0.36 7.02

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

98percentile 73.48 33.80 6.61 13.96 0.40 7.86 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Location – 4

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 71 32.66 6.39 13.49 0.39 7.60 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

04/10/16 1 69.5 31.97 6.26 13.21 0.38 7.44 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

10/10/16 2 67.1 30.87 6.04 12.75 0.37 7.18 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

11/10/16 2 66.2 30.45 5.96 12.58 0.36 7.08 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

17/10/16 3 72.9 33.53 6.56 13.85 0.40 7.80 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

18/10/16 3 58.9 27.09 5.30 11.19 0.32 6.30 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

24/10/16 4 66.1 30.41 5.95 12.56 0.36 7.07 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

25/10/16 4 63.8 29.35 5.74 12.12 0.35 6.83 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

07/11/16 5 71 32.66 6.39 13.49 0.39 7.60 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

08/11/16 5 64.2 29.53 5.78 12.20 0.35 6.87 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

14/11/16 6 63.4 29.16 5.71 12.05 0.35 6.78 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

15/11/16 6 56.4 25.94 5.08 10.72 0.31 6.03 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

21/11/16 7 57.7 26.54 5.19 10.96 0.32 6.17 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

22/11/16 7 56.7 26.08 5.10 10.77 0.31 6.07 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

29/11/16 8 62.5 28.75 5.63 11.88 0.34 6.69 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

30/11/16 8 68.7 31.60 6.18 13.05 0.38 7.35 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

05/12/16 9 66.1 30.41 5.95 12.56 0.36 7.07 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

06/12/16 9 66.9 30.77 6.02 12.71 0.37 7.16 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

12/12/16 10 69.3 31.88 6.24 13.17 0.38 7.42 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

13/12/16 10 60.6 27.88 5.45 11.51 0.33 6.48 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

19/12/16 11 47.5 21.85 4.28 9.03 0.26 5.08 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

20/12/16 11 70.6 32.48 6.35 13.41 0.39 7.55 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

26/12/16 12 64.8 29.81 5.83 12.31 0.36 6.93 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

27/12/16 12 60.4 27.78 5.44 11.48 0.33 6.46 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Max 72.90 33.53 6.56 13.85 0.40 7.80

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Min 47.50 21.85 4.28 9.03 0.26 5.08

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Average 64.26 29.56 5.78 12.21 0.35 6.88

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

98percentile 72.03 33.13 6.48 13.68 0.40 7.71 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Location – 5

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 68.2 32.05 8.18 19.10 0.48 8.66 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

04/10/16 1 72.3 33.98 8.68 20.24 0.51 9.18 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

10/10/16 2 69.9 32.85 8.39 19.57 0.49 8.88 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

11/10/16 2 52.3 24.58 6.28 14.64 0.37 6.64 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

17/10/16 3 76 35.72 9.12 21.28 0.53 9.65 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

18/10/16 3 61.3 28.81 7.36 17.16 0.43 7.79 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

24/10/16 4 68.7 32.29 8.24 19.24 0.48 8.72 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

25/10/16 4 87.4 41.08 10.49 24.47 0.61 11.10 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

07/11/16 5 84.1 39.53 10.09 23.55 0.59 10.68 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

08/11/16 5 66.9 31.44 8.03 18.73 0.47 8.50 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

14/11/16 6 66 31.02 7.92 18.48 0.46 8.38 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

15/11/16 6 58.8 27.64 7.06 16.46 0.41 7.47 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

21/11/16 7 60.1 28.25 7.21 16.83 0.42 7.63 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

22/11/16 7 59 27.73 7.08 16.52 0.41 7.49 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

29/11/16 8 65.1 30.60 7.81 18.23 0.46 8.27 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

30/11/16 8 81.7 38.40 9.80 22.88 0.57 10.38 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

05/12/16 9 79 37.13 9.48 22.12 0.55 10.03 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

06/12/16 9 79.9 37.55 9.59 22.37 0.56 10.15 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

12/12/16 10 72.1 33.89 8.65 20.19 0.50 9.16 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

13/12/16 10 63.1 29.66 7.57 17.67 0.44 8.01 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

19/12/16 11 49.5 23.27 5.94 13.86 0.35 6.29 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

20/12/16 11 73.5 34.55 8.82 20.58 0.51 9.33 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

26/12/16 12 67.4 31.68 8.09 18.87 0.47 8.56 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

27/12/16 12 62.9 29.56 7.55 17.61 0.44 7.99 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Max 87.40 41.08 10.49 24.47 0.61 11.10

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Min 49.50 23.27 5.94 13.86 0.35 6.29

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Average 68.55 32.22 8.23 19.19 0.48 8.71

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

98percentile 85.88 40.36 10.31 24.05 0.60 10.91 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Location – 6

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 80 37.60 9.60 22.40 0.56 10.16 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

04/10/16 1 69.7 32.76 8.36 19.52 0.49 11.85 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

10/10/16 2 83.9 39.43 10.07 23.49 0.59 14.26 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

11/10/16 2 87.4 41.08 10.49 24.47 0.61 14.86 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

17/10/16 3 69.9 32.85 8.39 19.57 0.49 11.88 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

18/10/16 3 69.3 32.57 8.32 19.40 0.49 11.78 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

24/10/16 4 60 28.20 7.20 16.80 0.42 10.20 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

25/10/16 4 64.1 30.13 7.69 17.95 0.45 10.90 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

07/11/16 5 56 26.32 6.72 15.68 0.39 9.52 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

08/11/16 5 71.4 33.56 8.57 19.99 0.50 12.14 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

14/11/16 6 90.3 42.44 10.84 25.28 0.63 15.35 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

15/11/16 6 66.5 31.26 7.98 18.62 0.47 11.31 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

21/11/16 7 87.8 41.27 10.54 24.58 0.61 14.93 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

22/11/16 7 76.7 36.05 9.20 21.48 0.54 13.04 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

29/11/16 8 46.8 22.00 5.62 13.10 0.33 7.96 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

30/11/16 8 69.3 32.57 8.32 19.40 0.49 11.78 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

05/12/16 9 66.5 31.26 7.98 18.62 0.47 11.31 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

06/12/16 9 64.2 30.17 7.70 17.98 0.45 10.91 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

12/12/16 10 66 31.02 7.92 18.48 0.46 11.22 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

13/12/16 10 85.9 40.37 10.31 24.05 0.60 14.60 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

19/12/16 11 75.1 35.30 9.01 21.03 0.53 12.77 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

20/12/16 11 83.6 39.29 10.03 23.41 0.59 14.21 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

26/12/16 12 87.3 41.03 10.48 24.44 0.61 14.84 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

27/12/16 12 79.4 37.32 9.53 22.23 0.56 13.50 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

Max 90.30 42.44 10.84 25.28 0.63 15.35 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

Min 46.80 22.00 5.62 13.10 0.33 7.96 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

Average 73.21 34.41 8.79 20.50 0.51 12.30 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

98percentile 89.15 41.90 10.70 24.96 0.62 15.16 <0.01 <20 <0.1 <1 <0.5 <0.1 <0.10

Location – 7

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 74.21 34.88 6.68 16.33 0.30 8.16 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

04/10/16 1 72.42 34.04 6.52 15.93 0.29 7.97 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

10/10/16 2 69.72 32.77 6.27 15.34 0.28 7.67 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

11/10/16 2 68.44 32.17 6.16 15.06 0.27 7.53 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

17/10/16 3 76.57 35.99 6.89 16.85 0.31 8.42 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

18/10/16 3 59.91 28.16 5.39 13.18 0.24 6.59 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

24/10/16 4 68.33 32.12 6.15 15.03 0.27 7.52 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

25/10/16 4 65.69 30.87 5.91 14.45 0.26 7.23 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

07/11/16 5 85.84 40.34 7.73 18.88 0.34 9.44 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

08/11/16 5 66.2 31.11 5.96 14.56 0.26 7.28 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

14/11/16 6 65.24 30.66 5.87 14.35 0.26 7.18 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

15/11/16 6 60.1 28.25 5.41 13.22 0.24 6.61 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

21/11/16 7 68.48 32.19 6.16 15.07 0.27 7.53 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

22/11/16 7 67.28 31.62 6.06 14.80 0.27 7.40 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

29/11/16 8 64.19 30.17 5.78 14.12 0.26 7.06 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

30/11/16 8 83.1 39.06 7.48 18.28 0.33 9.14 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

05/12/16 9 80 37.60 7.20 17.60 0.32 8.80 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

06/12/16 9 81.01 38.07 7.29 17.82 0.32 8.91 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

12/12/16 10 82.22 38.64 7.40 18.09 0.33 9.04 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

13/12/16 10 71.92 33.80 6.47 15.82 0.29 7.91 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

19/12/16 11 56.44 26.53 5.08 12.42 0.23 6.21 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

20/12/16 11 83.72 39.35 7.53 18.42 0.33 9.21 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

26/12/16 12 76.83 36.11 6.91 16.90 0.31 8.45 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

27/12/16 12 69.25 32.55 6.23 15.24 0.28 7.62 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Max 85.84 40.34 7.73 18.88 0.34 9.44

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Min 56.44 26.53 5.08 12.42 0.23 6.21

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Average 71.55 33.63 6.44 15.74 0.29 7.87

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

98percentile 84.86 39.89 7.64 18.67 0.34 9.34 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Location – 8

Monitoring

Date Week

PM10

(µg/

m3)

PM2.5

(µg/

m3)

SO2

(µg/

m3)

NOX

(µg/

m3)

CO

(mg

/m3)

NH3

(µg

/m3

Pb

(µg/

m3)

O3

(µg/

m3)

C6H6

(µg

/m3)

VOC

(pp

m)

HBr

(ppm)

Cl2

(pp

m)

HCL

03/10/16 1 77.6 36.47 9.31 21.73 0.54 9.86 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

04/10/16 1 75.9 35.67 9.11 21.25 0.53 12.90 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

10/10/16 2 73.4 34.50 8.81 20.55 0.51 12.48 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

11/10/16 2 72.3 33.98 8.68 20.24 0.51 12.29 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

17/10/16 3 79.8 37.51 9.58 22.34 0.56 13.57 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

18/10/16 3 64.4 30.27 7.73 18.03 0.45 10.95 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

24/10/16 4 72.2 33.93 8.66 20.22 0.51 12.27 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

25/10/16 4 69.7 32.76 8.36 19.52 0.49 11.85 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

07/11/16 5 88.3 41.50 10.60 24.72 0.62 15.01 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

08/11/16 5 70.2 32.99 8.42 19.66 0.49 11.93 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

14/11/16 6 69.3 32.57 8.32 19.40 0.49 11.78 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

15/11/16 6 61.7 29.00 7.40 17.28 0.43 10.49 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

21/11/16 7 63.1 29.66 7.57 17.67 0.44 10.73 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

22/11/16 7 62 29.14 7.44 17.36 0.43 10.54 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

29/11/16 8 68.4 32.15 8.21 19.15 0.48 11.63 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

30/11/16 8 85.8 40.33 10.30 24.02 0.60 14.59 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

05/12/16 9 82.9 38.96 9.95 23.21 0.58 14.09 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

06/12/16 9 83.8 39.39 10.06 23.46 0.59 14.25 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

12/12/16 10 75.7 35.58 9.08 21.20 0.53 12.87 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

13/12/16 10 66.3 31.16 7.96 18.56 0.46 11.27 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

19/12/16 11 52 24.44 6.24 14.56 0.36 8.84 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

20/12/16 11 77.1 36.24 9.25 21.59 0.54 13.11 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

26/12/16 12 70.8 33.28 8.50 19.82 0.50 12.04 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

27/12/16 12 66 31.02 7.26 18.48 0.46 11.22 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Max 88.30 41.50 10.60 24.72 0.62 15.01

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Min 52.00 24.44 6.24 14.56 0.36 8.84

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Average 72.03 33.85 8.62 20.17 0.50 12.11

<0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

98percentile 87.15 40.96 10.46 24.40 0.61 14.82 <0.01 <20 <0.1

<1 <0.5 <0.1 <0.10

Annexure: XI Emergency Management

Plan

Annexure: XII Fire Detection and Alarm

System

Annexure: XIII MSDS

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Revision Date 07.02.2017 Version 1.6

The Safety Data Sheets for catalogue items are available at www.merckgroup.com

Page 1 of 18

SECTION 1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Catalogue No. 106044

Product name Dichloromethane for liquid chromatography LiChrosolv®

REACH Registration Number A registration number is not available for this substance as the

substance or its use are exempted from registration according to

Article 2 REACH Regulation (EC) No 1907/2006, the annual tonnage

does not require a registration or the registration is envisaged for a

later registration deadline.

CAS-No. 75-09-2

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses Analytical and preparative chromatography

For additional information on uses please refer to the Merck Chemicals

portal (www.merckgroup.com).

1.3 Details of the supplier of the safety data sheet

Company Merck Life Science Private Limited * 8th Floor, Godrej One,

Pirojshanagar, Eastern Express HighwayVikhroli (E),Mumbai – 400079

India * Tel: 0091 22 6210 9000

Responsible Department Quality Assurance * Merck Life Science Private Limited *

e-mail: [email protected] *

Tel : +91-2267863131-6

1.4 Emergency telephone

number

Please contact the regional company representation in your country.

SAFETY DATA SHEET





Page 2 of 18

SECTION 2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Skin irritation, Category 2, H315

Eye irritation, Category 2, H319

Carcinogenicity, Category 2, H351

Specific target organ toxicity - single exposure, Category 3, Central nervous system, H336

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms

Signal word

Warning

Hazard statements

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

H351 Suspected of causing cancer.

Precautionary statements

Response

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P308 + P313 IF exposed or concerned: Get medical advice/ attention.

SAFETY DATA SHEET





Page 3 of 18

Reduced labelling (≤125 ml)

Hazard pictograms

Signal word

Warning

Hazard statements




Contains: Dichloromethane

CAS-No. 75-09-2

2.3 Other hazards

None known.

SECTION 3. Composition/information on ingredients

3.1 Substance

Formula CH₂Cl₂ CH₂Cl₂ (Hill)

EC-No. 200-838-9

Molar mass 84.93 g/mol

Hazardous components (REGULATION (EC) No 1272/2008)

Chemical name (Concentration)

CAS-No. Registration number Classification

Dichloromethane (>= 50 % - <= 100 % )

Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

75-09-2 *)




SAFETY DATA SHEET





Page 4 of 18

Specific target organ toxicity - single exposure, Category 3, H336

*) A registration number is not available for this substance as the substance or its use are exempted from registration according to Article

2 REACH Regulation (EC) No 1907/2006, the annual tonnage does not require a registration or the registration is envisaged for a later

registration deadline.


3.2 Mixture

Not applicable

SECTION 4. First aid measures

4.1 Description of first aid measures

After inhalation: fresh air. Call in physician.

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/

shower. Consult a physician.

After eye contact: rinse out with plenty of water. Call in ophthalmologist.

After swallowing: caution if victim vomits. Risk of aspiration! Keep airways free. Pulmonary

failure possible after aspiration of vomit. Call a physician immediately. Subsequently administer:

activated charcoal (20 - 40 g in 10% slurry).

4.2 Most important symptoms and effects, both acute and delayed

irritant effects, Drowsiness, somnolence, Dizziness, inebriation, Nausea, Vomiting, CNS

disorders, Unconsciousness, Cough, depressed respiration, Shortness of breath, respiratory

paralysis

Risk of corneal clouding.

The following applies to aliphatic halogenated hydrocarbons in general: systemic effect:

narcosis, cardiovascular disorders. Toxic effect on liver, kidneys.

4.3 Indication of any immediate medical attention and special treatment needed

No information available.

SAFETY DATA SHEET





Page 5 of 18

SECTION 5. Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding

environment.

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

5.2 Special hazards arising from the substance or mixture

Not combustible.

Ambient fire may liberate hazardous vapours.

Fire may cause evolution of:

Hydrogen chloride gas, Phosgene

5.3 Advice for firefighters

Special protective equipment for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by

keeping a safe distance or by wearing suitable protective clothing.

Further information

Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing

water from contaminating surface water or the ground water system.

SECTION 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance

contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency

procedures, consult an expert.

Advice for emergency responders:

Protective equipment see section 8.

6.2 Environmental precautions

SAFETY DATA SHEET





Page 6 of 18

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see

sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of

properly. Clean up affected area.

6.4 Reference to other sections

Indications about waste treatment see section 13.

SECTION 7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Observe label precautions.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and

face after working with substance.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to

qualified or authorised persons. Protected from light.

Recommended storage temperature see product label.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

SECTION 8. Exposure controls/personal protection

8.1 Control parameters

SAFETY DATA SHEET





Page 7 of 18

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Engineering measures

Technical measures and appropriate working operations should be given priority over the use of

personal protective equipment.

See section 7.1.

Individual protection measures

Protective clothing needs to be selected specifically for the workplace, depending on

concentrations and quantities of the hazardous substances handled. The chemical resistance of

the protective equipment should be enquired at the respective supplier.

Eye/face protection

Safety glasses

Hand protection

splash contact:

Glove material: Viton (R)

Glove thickness: 0.70 mm

Break through time: > 120 min

The protective gloves to be used must comply with the specifications of EC Directive

89/686/EEC and the related standard EN374, for example KCL 890 Vitoject® (splash contact).

The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374

with samples of the recommended glove types.

This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied

by us and for the designated use. When dissolving in or mixing with other substances and under

conditions deviating from those stated in EN374 please contact the supplier of CE-approved

gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Other protective equipment

protective clothing

SAFETY DATA SHEET





Page 8 of 18

Respiratory protection

required when vapours/aerosols are generated.

Recommended Filter type: Filter AX (EN 371)

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective

devices are carried out according to the instructions of the producer. These measures have to be

properly documented.

Environmental exposure controls


SECTION 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Form liquid

Colour colourless

Odour sweet

Odour Threshold 24.9 - 611.7 ppm

pH at 20 °C

neutral

Melting point -95 °C

Boiling point/boiling range 40 °C

at 1,013 hPa

Flash point does not flash

Evaporation rate 1.9

SAFETY DATA SHEET





Page 9 of 18

Flammability (solid, gas) Not applicable

Lower explosion limit 13 %(V)

Upper explosion limit 22 %(V)

Vapour pressure 475 hPa

at 20 °C

Relative vapour density 2.93

Density 1.33 g/cm3

at 20 °C

Relative density No information available.

Water solubility 20 g/l

at 20 °C

Partition coefficient: n-

octanol/water

log Pow: 1.25

(experimental)

(Lit.) Bioaccumulation is not expected.

Auto-ignition temperature No information available.

Decomposition temperature > 120 °C

Viscosity, dynamic 0.43 mPa.s

at 20 °C

Explosive properties Not classified as explosive.

Oxidizing properties none

9.2 Other data

SAFETY DATA SHEET





Page 10 of 18

Ignition temperature 605 °C

DIN 51794

SECTION 10. Stability and reactivity

10.1 Reactivity

See section 10.3

10.2 Chemical stability

Sensitivity to light

Stabilizer

2-methyl-2-butene

10.3 Possibility of hazardous reactions

Risk of explosion with:

Alkali metals, nitrogen oxides, nitrogen dioxide, Potassium, sodium azide, perchloric acid, Nitric

acid, aluminium chloride, Amines, Oxygen, (as liquefied gas), powdered aluminium, sodium

aromatic hydrocarbons, with

powdered aluminium

Exothermic reaction with:

Alkaline earth metals, Powdered metals, amides, alcoholates, nonmetallic oxides, potassium tert-

butanolate, sodium amide

10.4 Conditions to avoid

no information available

10.5 Incompatible materials

rubber, various plastics, Light metals, Metals, Mild steel

10.6 Hazardous decomposition products

in the event of fire: See section 5.

SAFETY DATA SHEET





Page 11 of 18

SECTION 11. Toxicological information

11.1 Information on toxicological effects

Acute oral toxicity

LD50 Rat: > 2,000 mg/kg

OECD Test Guideline 401

Symptoms: Nausea, Vomiting, Risk of aspiration upon vomiting., Aspiration may cause

pulmonary oedema and pneumonitis.

Acute inhalation toxicity

LC50 Rat: 60.14 mg/l17250 ppm; 4 h ; vapour

(Lit.)

Symptoms: Possible damages:, mucosal irritations

Acute dermal toxicity

LD50 Rat: > 2,000 mg/kg


Skin irritation

Rabbit

Result: Irritations


Causes skin irritation.

Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing

properties of the product.

Eye irritation

Rabbit

Result: Eye irritation

(ECHA)

Causes serious eye irritation.

SAFETY DATA SHEET





Page 12 of 18


Sensitisation

Local lymph node assay (LLNA) Mouse

Result: negative

Method: OECD Test Guideline 429

Germ cell mutagenicity

Genotoxicity in vivo

In vivo micronucleus test

Mouse

male and female

Oral

Bone marrow

Result: negative


Genotoxicity in vitro

Mutagenicity (mammal cell test): chromosome aberration.

Result: positive


Ames test

Salmonella typhimurium

Result: positive


Carcinogenicity

This information is not available.

Reproductive toxicity


Teratogenicity


SAFETY DATA SHEET





Page 13 of 18

CMR effects

Carcinogenicity:

Suspected of causing cancer.

Specific target organ toxicity - single exposure

May cause drowsiness or dizziness.

Exposure routes: Inhalation

Target Organs: Central nervous system

Specific target organ toxicity - repeated exposure


Aspiration hazard


11.2 Further information

Systemic effects:

After absorption of large quantities:

CNS disorders, Drowsiness, Dizziness, drop in blood pressure, Cardiac irregularities, depressed

respiration, inebriation, Unconsciousness, narcosis, respiratory paralysis

Swallowing may result in damage to the following:

Liver, Kidney



Other dangerous properties can not be excluded.

This substance should be handled with particular care.

SECTION 12. Ecological information

12.1 Toxicity

Toxicity to fish

flow-through test LC50 Pimephales promelas (fathead minnow): 193 mg/l; 96 h

Analytical monitoring: yes

US-EPA

SAFETY DATA SHEET





Page 14 of 18

Toxicity to daphnia and other aquatic invertebrates

static test EC50 Daphnia magna (Water flea): 27 mg/l; 48 h

US-EPA

Toxicity to algae

static test EbC50 Pseudokirchneriella subcapitata (green algae): > 662 mg/l; 96 h


Toxicity to bacteria

static test EC50 activated sludge: 2,590 mg/l; 40 min



Toxicity to fish (Chronic toxicity)

flow-through test NOEC Pimephales promelas (fathead minnow): 83 mg/l; 28 d


(ECHA)

12.2 Persistence and degradability

Biodegradability

68 %; 28 d; aerobic

OECD Test Guideline 301D

Readily biodegradable

12.3 Bioaccumulative potential

Partition coefficient: n-octanol/water

log Pow: 1.25

(experimental)


12.4 Mobility in soil

Distribution among environmental compartments

Adsorption/Soil

log Koc: 1.00

(experimental)

Mobile in soils (Lit.)

SAFETY DATA SHEET





Page 15 of 18

12.5 Results of PBT and vPvB assessment

Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No

1907/2006, Annex XIII.

12.6 Other adverse effects

Henry constant

329 Pa*m³/mol

Method: (experimental)

(Lit.) Distribution preferentially in air.

Discharge into the environment must be avoided.

SECTION 13. Disposal considerations

Waste treatment methods

Waste material must be disposed of in accordance with the national and local regulations. Leave

chemicals in original containers. No mixing with other waste. Handle uncleaned containers like

the product itself.

See www.retrologistik.com for processes regarding the return of chemicals and containers, or

contact us there if you have further questions.

SECTION 14. Transport information

Land transport (ADR/RID)

14.1 UN number UN 1593

14.2 Proper shipping name DICHLOROMETHANE

14.3 Class 6.1

14.4 Packing group III

14.5 Environmentally hazardous --

14.6 Special precautions for

user

yes

Tunnel restriction code E

Inland waterway transport (ADN)

SAFETY DATA SHEET





Page 16 of 18

Not relevant

Air transport (IATA)



14.3 Class 6.1




user

no

Sea transport (IMDG)



14.3 Class 6.1




user

yes

EmS F-A S-A

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not relevant

SECTION 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

National legislation

Storage class 6.1 D

15.2 Chemical safety assessment

For this product a chemical safety assessment was not carried out.

SAFETY DATA SHEET





Page 17 of 18

SECTION 16. Other information

Full text of H-Statements referred to under sections 2 and 3.





Training advice

Provide adequate information, instruction and training for operators.

Labelling

Hazard pictograms

Signal word

Warning

Hazard statements






Response





SAFETY DATA SHEET





Page 18 of 18


Key or legend to abbreviations and acronyms used in the safety data sheet

Used abbreviations and acronyms can be looked up at www.wikipedia.org.

The information contained herein is based on the present state of our knowledge. It characterises the product with

regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.

SAFETY DATA SHEET




Page 1 of 20




Product name Methanol hypergrade for LC-MS LiChrosolv®






CAS-No. 67-56-1


Identified uses Reagent for analysis, Solvent, Analytical and preparative

chromatography






India * Tel: 0091 22 6210 9000



Tel : +91-2267863131-6


number




SAFETY DATA SHEET





Page 2 of 20


Flammable liquid, Category 2, H225

Acute toxicity, Category 3, Oral, H301

Acute toxicity, Category 3, Inhalation, H331

Acute toxicity, Category 3, Dermal, H311

Specific target organ toxicity - single exposure, Category 1, Eyes, H370


Classification (67/548/EEC or 1999/45/EC)

F Highly flammable R11

T Toxic R23/24/25 - 39/23/24/25

For the full text of the R-phrases mentioned in this Section, see Section 16.

2.2 Label elements


Hazard pictograms

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour.

H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled.

H370 Causes damage to organs (Eyes).


Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No

smoking.

P240 Ground/bond container and receiving equipment.

P280 Wear protective gloves/ protective clothing.

Response


P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

SAFETY DATA SHEET





Page 3 of 20

breathing.

P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.


Hazard pictograms

Signal word

Danger

Hazard statements




P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.


P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.


CAS-No. 67-56-1

2.3 Other hazards

None known.


3.1 Substance

Formula CH₃OH CH₄O (Hill)

EC-No. 200-659-6


SAFETY DATA SHEET





Page 4 of 20


Chemical Name (Concentration)


Methanol (<= 100 % )


67-56-1 *)


Acute toxicity, Category 3, H301








Hazardous components (1999/45/EC)


CAS-No. Classification


67-56-1 F, Highly flammable; R11

T, Toxic; R23/24/25-39/23/24/25


3.2 Mixture

Not applicable



General advice

First aider needs to protect himself.

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply

artificial respiration, if necessary also oxygen.


shower. Call a physician immediately.

SAFETY DATA SHEET





Page 5 of 20


After swallowing: fresh air. Make victim drink ethanol (e.g. 1 drinking glass of a 40% alcoholic

beverage). Call a doctor immediately (mention methanol ingestion). Only in exceptional cases, if

no medical care is available within one hour, induce vomiting (only in fully conscious persons)

and make victim drink ethanol again (approx. 0.3 ml of a 40% alcoholic beverage/kg body

weight/hour).


irritant effects, Drowsiness, Dizziness, narcosis, agitation, spasms, inebriation, Nausea,

Vomiting, Headache, blindness, Impairment of vision, Coma

Drying-out effect resulting in rough and chapped skin.






Foam, Carbon dioxide (CO2), Dry powder




Combustible.

Forms explosive mixtures with air at ambient temperatures.

Pay attention to flashback.

Vapours are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire.





Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from

contaminating surface water or the ground water system.

SAFETY DATA SHEET





Page 6 of 20




contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the

danger area, observe emergency procedures, consult an expert.




Do not let product enter drains. Risk of explosion.



sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose

of properly. Clean up affected area.








Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary

measures against static discharge.

Hygiene measures




Storage conditions

SAFETY DATA SHEET





Page 7 of 20

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and

sources of ignition. Keep locked up or in an area accessible only to qualified or authorised

persons.






Methanol (67-56-1)

IN OEL Skin designation: Can be absorbed through the skin.

Short Term Exposure

Limit (STEL):

250 ppm

310 mg/m³

Time Weighted Average

(TWA):

200 ppm

260 mg/m³





See section 7.1.





Eye/face protection

Safety glasses

Hand protection

full contact:

Glove material: butyl-rubber

SAFETY DATA SHEET





Page 8 of 20



splash contact:





89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (full contact), KCL

890 Vitoject® (splash contact).








Flame retardant antistatic protective clothing.









Risk of explosion.



Form liquid

Colour colourless

SAFETY DATA SHEET





Page 9 of 20

Odour characteristic

Odour Threshold 10 - 20000 ppm

pH No information available.


Boiling point/boiling range 64.5 °C

at 1,013 hPa

Flash point 10 °C

Method: c.c.


Reference substance: Diethylether

1.9

Reference substance: n-butyl acetate

Flammability (solid, gas) No information available.

Lower explosion limit 5.5 %(V)



at 20 °C


Density 0.792 g/cm3

at 20 °C


Water solubility at 20 °C

soluble

SAFETY DATA SHEET





Page 10 of 20


octanol/water

log Pow: -0.77

(experimental)


Auto-ignition temperature 455 °C

Decomposition temperature Distillable in an undecomposed state at normal pressure.


at 20 °C



9.2 Other data


DIN 51794

Minimum ignition energy 0.14 mJ

Conductivity < 1 µS/cm


10.1 Reactivity

Vapours may form explosive mixture with air.


The product is chemically stable under standard ambient conditions (room temperature) .



Oxidizing agents, perchloric acid, perchlorates, salts of oxyhalogenic acids, chromium(VI) oxide,

halogen oxides, nitrogen oxides, nonmetallic oxides, chromosulfuric acid, chlorates, hydrides, zinc

diethyl, halogens, magnesium, hydrogen peroxide, Nitric acid


SAFETY DATA SHEET





Page 11 of 20

acid halides, Acid anhydrides, Reducing agents, acids

Generates dangerous gases or fumes in contact with:

Alkaline earth metals, Alkali metals


Warming.


various plastics, magnesium, zinc alloys





Acute oral toxicity

LDLO human: 143 mg/kg

(RTECS)

Symptoms: Nausea, Vomiting

absorption


LC50 Rat: 131.25 mg/l; 4 h ; vapour

(ECHA)

Symptoms: Irritation symptoms in the respiratory tract.

absorption


LD50 Rabbit: ca. 17,100 mg/kg

(External MSDS)

absorption

SAFETY DATA SHEET





Page 12 of 20

Skin irritation

Rabbit

Result: No skin irritation

(ECHA)


Eye irritation

Rabbit

Result: No eye irritation

(ECHA)

Irritations of mucous membranes

Sensitisation

Sensitisation test: Guinea pig

Result: negative




Micronucleus test

Mouse

male and female

Intraperitoneal injection

Bone marrow

Result: negative



Ames test


Result: negative


In vitro mammalian cell gene mutation test

Result: negative


SAFETY DATA SHEET





Page 13 of 20

Carcinogenicity




Teratogenicity


CMR effects

Carcinogenicity:

Did not show carcinogenic effects in animal experiments.

Mutagenicity:

Based on available data the classification criteria are not met.

Teratogenicity:


Reproductive toxicity:



Target Organs: Eyes

Causes damage to organs.



Repeated dose toxicity

Rat

male and female

Inhalation

vapour

28 d

daily

NOAEL: 6.66 mg/l


Subacute toxicity

Rat

male and female

Inhalation

365 d

daily

NOAEL: 0.13 mg/l

SAFETY DATA SHEET





Page 14 of 20

LOAEL: 1.3 mg/l


Aspiration hazard



Systemic effects:

acidosis, drop in blood pressure, agitation, spasms, inebriation, Dizziness, Drowsiness,

Headache, Impairment of vision, blindness, narcosis, Coma

Symptoms may be delayed.

Damage to:

Liver, Kidney, Cardiac, Irreversible damage of the optical nerve.



12.1 Toxicity

Toxicity to fish

flow-through test LC50 Lepomis macrochirus (Bluegill sunfish): 15,400 mg/l; 96 h

US-EPA


EC5 E.sulcatum: > 10,000 mg/l; 72 h

(Lit.)

EC50 Daphnia magna (Water flea): > 10,000 mg/l; 48 h

(IUCLID)

Toxicity to algae

static test EC50 Pseudokirchneriella subcapitata (green algae): ca. 22,000 mg/l; 96 h



EC5 Pseudomonas fluorescens: 6,600 mg/l; 16 h

(IUCLID)

static test IC50 activated sludge: > 1,000 mg/l; 3 h



SAFETY DATA SHEET





Page 15 of 20


NOEC Oryzias latipes (Orange-red killifish): 7,900 mg/l; 200 h

(External MSDS)


Biodegradability

99 %; 30 d



Biochemical Oxygen Demand (BOD)

600 - 1,120 mg/g (5 d)

(IUCLID)

Chemical Oxygen Demand (COD)

1,420 mg/g

(IUCLID)

Theoretical oxygen demand (ThOD)

1,500 mg/g

(Lit.)

Ratio BOD/ThBOD

BOD5 76 %

Closed Bottle test



log Pow: -0.77

(experimental)








SAFETY DATA SHEET





Page 16 of 20

Surface tension

22.6 mN/m

at 20 °C

Stability in water

2.2 yr

reaction with hydroxyl radicals (IUCLID)






the product itself.






14.2 Proper shipping name METHANOL

14.3 Class 3 (6.1)

14.4 Packing group II



user

yes

Tunnel restriction code D/E


Not relevant


SAFETY DATA SHEET





Page 17 of 20



14.3 Class 3 (6.1)




user

no




14.3 Class 3 (6.1)




user

yes

EmS F-E S-D


Not relevant




Storage class 3

15.2 Chemical Safety Assessment


SAFETY DATA SHEET





Page 18 of 20




H301 Toxic if swallowed.

H311 Toxic in contact with skin.

H331 Toxic if inhaled.

H370 Causes damage to organs.

Full text of R-phrases referred to under sections 2 and 3

R11 Highly flammable.

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R39/23/24/25 Toxic: danger of very serious irreversible effects through

inhalation, in contact with skin and if swallowed.

Training advice


Labelling

Hazard pictograms

Signal word

Danger

Hazard statements





Prevention

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.



SAFETY DATA SHEET





Page 19 of 20

Response



breathing.


Storage


Labelling (67/548/EEC or 1999/45/EC)

Symbol(s) F

T

Highly flammable

Toxic

R-phrase(s) 11-23/24/25-

39/23/24/25

Highly flammable. Toxic by inhalation, in contact with skin

and if swallowed. Toxic: danger of very serious irreversible

effects through inhalation, in contact with skin and if

swallowed.

S-phrase(s) 7-16-36/37-45 Keep container tightly closed. Keep away from sources of

ignition - No smoking. Wear suitable protective clothing and

gloves. In case of accident or if you feel unwell, seek medical

advice immediately (show the label where possible).

Further information

Experience with human exposure

EC-No. 200-659-6


Symbol(s) F

T

Highly flammable

Toxic

R-phrase(s) 23/24/25-39/23/24/25 Toxic by inhalation, in contact with skin and if swallowed. Toxic:

danger of very serious irreversible effects through inhalation, in

contact with skin and if swallowed.

S-phrase(s) 36/37-45 Wear suitable protective clothing and gloves. In case of accident or if

you feel unwell, seek medical advice immediately (show the label

where possible).



SAFETY DATA SHEET





Page 20 of 20



SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006



Page 1 of 13




Product name 2-Propanol EMPLURA®






CAS-No. 67-63-0


Identified uses Solvent, Chemical for synthesis






India * Tel: 0091 22 6210 9000



Tel : +91-2267863131-6


number











Xi Irritant R36

R67


SAFETY DATA SHEET





Page 2 of 13

2.2 Label elements


Hazard pictograms

Signal wordDanger

Hazard statementsH225 Highly flammable liquid and vapour.



Precautionary statementsPrevention


smoking.


Response



Storage



Hazard pictograms

Signal wordDanger

Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Index-No. 603-117-00-0

2.3 Other hazards

None known.


3.1 Substance

Formula CH₃CH(OH)CH₃ C₃H₈O (Hill)

Index-No. 603-117-00-0

EC-No. 200-661-7


SAFETY DATA SHEET





Page 3 of 13


Chemical Name (Concentration) CAS-No. Registration number Classification

2-Propanol (<= 100 % ) Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

67-63-0 *)









Chemical Name (Concentration) CAS-No. Classification

2-Propanol (<= 100 % ) 67-63-0 F, Highly flammable; R11

Xi, Irritant; R36

R67


3.2 Mixture

Not applicable



After inhalation: fresh air. Consult doctor if feeling unwell.


shower.



failure possible after aspiration of vomit. Call a physician immediately.


irritant effects, respiratory paralysis, Drowsiness, Dizziness, Unconsciousness, narcosis,

inebriation, Headache, somnolence, Coma






Suitable extinguishing mediaFoam, Carbon dioxide (CO2), Dry powder, Water

Unsuitable extinguishing mediaFor this substance/mixture no limitations of extinguishing agents are given.

SAFETY DATA SHEET





Page 4 of 13


Combustible.






Special protective equipment for firefightersIn the event of fire, wear self-contained breathing apparatus.

Further informationRemove container from danger zone and cool with water. Prevent fire extinguishing water from



















Advice on safe handlingObserve label precautions.


Advice on protection against fire and explosionKeep away from open flames, hot surfaces and sources of ignition. Take precautionary


Hygiene measuresChange contaminated clothing. Wash hands after working with substance.


Storage conditionsKeep container tightly closed in a dry and well-ventilated place. Keep away from heat and

sources of ignition.

Protected from light.

SAFETY DATA SHEET





Page 5 of 13











See section 7.1.





Eye/face protectionSafety glasses

Hand protection

full contact:

Glove material: Nitrile rubber



splash contact:

Glove material: polychloroprene




89/686/EEC and the related standard EN374, for example KCL 730 Camatril® -Velours (full

contact), KCL 720 Camapren® (splash contact).







Other protective equipmentFlame retardant antistatic protective clothing.

Respiratory protectionrequired when vapours/aerosols are generated.

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds




SAFETY DATA SHEET





Page 6 of 13



Risk of explosion.



Form liquid

Colour colourless

Odour alcohol-like


pH at 20 °C

neutral

Melting point -89.5 °C


at 1,013 hPa

Flash point 12 °C

Method: c.c.

Evaporation rate No information available.



Upper explosion limit 13.4 %(V)


at 20 °C


Density 0.786 g/cm3

at 20 °C



soluble


octanol/water

log Pow: 0.05


Bioaccumulation is not expected.



SAFETY DATA SHEET





Page 7 of 13


at 20 °C



9.2 Other data


Method: DIN 51794


Conductivity < 0.1 µS/cm


10.1 Reactivity


Formation of peroxides possible.



Sensitive to air.


Risk of ignition or formation of inflammable gases or vapours with:

Alkali metals, Alkaline earth metals, chromium(VI) oxide


Oxidizing agents, Nitric acid, Aldehydes, Amines, fuming sulfuric acid, Iron, Aluminium, Chlorine,

PHOSPHORUS TRICHLORIDE, Strong acids


chlorates, Phosgene, organic nitro compounds, hydrogen peroxide, nitrogen oxides, perchlorates


Warming.


rubber, various plastics, oils


Peroxides

SAFETY DATA SHEET





Page 8 of 13



Acute oral toxicityLDLO human: 3,570 mg/kg

(RTECS)

LD50 Rat: 5,045 mg/kg

(RTECS)

Symptoms: Risk of aspiration upon vomiting., Aspiration may cause pulmonary oedema and

pneumonitis.

Acute inhalation toxicityLC50 Rat: 37.5 mg/l; 4 h ; vapour



Acute dermal toxicityLD50 Rabbit: 12,800 mg/kg

(RTECS)

Skin irritationRabbit




Eye irritationRabbit




SensitisationBuehler Test Guinea pig

Result: negative



Genotoxicity in vivoIn vivo micronucleus test

Mouse

male and female


Bone marrow

Result: negative


Genotoxicity in vitroAmes test


Result: negative


SAFETY DATA SHEET





Page 9 of 13


Result: negative


CarcinogenicityMethod: OECD Test Guideline 451


Reproductive toxicityNo impairment of reproductive performance in animal experiments. (IUCLID)

TeratogenicityDid not show teratogenic effects in animal experiments. (IUCLID)

Specific target organ toxicity - single exposureTarget Organs: Central nervous system


Specific target organ toxicity - repeated exposureThis information is not available.

Repeated dose toxicityRat

male and female

Inhalation

vapour

90 d

daily

NOAEL: 12.5 mg/l



Subchronic toxicity

Aspiration hazardThis information is not available.


Systemic effects:

After absorption:

Headache, Dizziness, inebriation, Unconsciousness, narcosis

After uptake of large quantities:

respiratory paralysis, Coma

Handle in accordance with good industrial hygiene and safety practice.


12.1 Toxicity

Toxicity to fishflow-through test LC50 Pimephales promelas (fathead minnow): 9,640 mg/l; 96 h

US-EPA

Toxicity to daphnia and other aquatic invertebratesEC5 E.sulcatum: 4,930 mg/l; 72 h

(maximum permissible toxic concentration) (Lit.)

EC50 Daphnia magna (Water flea): 13,299 mg/l; 48 h

(IUCLID)

Toxicity to algaeIC50 Desmodesmus subspicatus (green algae): > 1,000 mg/l; 72 h

(IUCLID)

SAFETY DATA SHEET





Page 10 of 13

Toxicity to bacteriaEC5 Pseudomonas putida: 1,050 mg/l; 16 h

(Lit.)


Biodegradability95 %; 21 d; aerobic

OECD Test Guideline 301E


Theoretical oxygen demand (ThOD)2,400 mg/g

(Lit.)

Ratio BOD/ThBODBOD5 49 %

(IUCLID)

Ratio COD/ThBOD96 %

(Lit.)


Partition coefficient: n-octanol/waterlog Pow: 0.05


Bioaccumulation is not expected.








SAFETY DATA SHEET





Page 11 of 13


Waste treatment methodsWaste material must be disposed of in accordance with the national and local regulations. Leave


the product itself.






14.2 Proper shipping name ISOPROPANOL

14.3 Class 3




user

yes



Not relevant




14.3 Class 3




user

no




14.3 Class 3




user

yes

EmS F-E S-D


Not relevant

SAFETY DATA SHEET





Page 12 of 13




Storage class 3


A Chemical Safety Assessment has been carried out according to regulation (EC) No.

1907/2006 (REACH) for this substance.








R36 Irritating to eyes.

R67 Vapours may cause drowsiness and dizziness.

Training advice


Labelling Hazard pictograms

Signal wordDanger







Response



Storage


SAFETY DATA SHEET





Page 13 of 13


Symbol(s) F

Xi

Highly flammable

Irritant

R-phrase(s) 11-36-67 Highly flammable. Irritating to eyes. Vapours may cause

drowsiness and dizziness.


ignition - No smoking. Avoid contact with skin and eyes. In

case of contact with eyes, rinse immediately with plenty of

water and seek medical advice.

EC-No. 200-661-7 EC Label


Symbol(s) F

Xi

Highly flammable

Irritant

S-phrase(s) 24/25 Avoid contact with skin and eyes.





SAFETY DATA SHEET




Page 1 of 18










CAS-No. 75-09-2


Identified uses Analytical and preparative chromatography






India * Tel: 0091 22 6210 9000



Tel : +91-2267863131-6


number


SAFETY DATA SHEET





Page 2 of 18









2.2 Label elements


Hazard pictograms

Signal word

Warning

Hazard statements






Response





SAFETY DATA SHEET





Page 3 of 18


Hazard pictograms

Signal word

Warning

Hazard statements





CAS-No. 75-09-2

2.3 Other hazards

None known.


3.1 Substance

Formula CH₂Cl₂ CH₂Cl₂ (Hill)

EC-No. 200-838-9



Chemical name (Concentration)


Dichloromethane (>= 50 % - <= 100 % )


75-09-2 *)




SAFETY DATA SHEET





Page 4 of 18






3.2 Mixture

Not applicable





shower. Consult a physician.




activated charcoal (20 - 40 g in 10% slurry).


irritant effects, Drowsiness, somnolence, Dizziness, inebriation, Nausea, Vomiting, CNS

disorders, Unconsciousness, Cough, depressed respiration, Shortness of breath, respiratory

paralysis






SAFETY DATA SHEET





Page 5 of 18




Use extinguishing measures that are appropriate to local circumstances and the surrounding

environment.




Not combustible.

Ambient fire may liberate hazardous vapours.

Fire may cause evolution of:

Hydrogen chloride gas, Phosgene





Further information

Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing

water from contaminating surface water or the ground water system.




contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency

procedures, consult an expert.




SAFETY DATA SHEET





Page 6 of 18













Hygiene measures




Storage conditions

Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to

qualified or authorised persons. Protected from light.






SAFETY DATA SHEET





Page 7 of 18






See section 7.1.





Eye/face protection

Safety glasses

Hand protection

splash contact:





89/686/EEC and the related standard EN374, for example KCL 890 Vitoject® (splash contact).








protective clothing

SAFETY DATA SHEET





Page 8 of 18











Form liquid

Colour colourless

Odour sweet


pH at 20 °C

neutral



at 1,013 hPa

Flash point does not flash


SAFETY DATA SHEET





Page 9 of 18





at 20 °C


Density 1.33 g/cm3

at 20 °C


Water solubility 20 g/l

at 20 °C


octanol/water

log Pow: 1.25

(experimental)



Decomposition temperature > 120 °C


at 20 °C



9.2 Other data

SAFETY DATA SHEET





Page 10 of 18


DIN 51794


10.1 Reactivity

See section 10.3



Stabilizer

2-methyl-2-butene



Alkali metals, nitrogen oxides, nitrogen dioxide, Potassium, sodium azide, perchloric acid, Nitric

acid, aluminium chloride, Amines, Oxygen, (as liquefied gas), powdered aluminium, sodium

aromatic hydrocarbons, with

powdered aluminium


Alkaline earth metals, Powdered metals, amides, alcoholates, nonmetallic oxides, potassium tert-

butanolate, sodium amide




rubber, various plastics, Light metals, Metals, Mild steel


in the event of fire: See section 5.

SAFETY DATA SHEET





Page 11 of 18



Acute oral toxicity

LD50 Rat: > 2,000 mg/kg


Symptoms: Nausea, Vomiting, Risk of aspiration upon vomiting., Aspiration may cause

pulmonary oedema and pneumonitis.


LC50 Rat: 60.14 mg/l17250 ppm; 4 h ; vapour

(Lit.)



LD50 Rat: > 2,000 mg/kg


Skin irritation

Rabbit

Result: Irritations


Causes skin irritation.

Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing

properties of the product.

Eye irritation

Rabbit


(ECHA)


SAFETY DATA SHEET





Page 12 of 18


Sensitisation

Local lymph node assay (LLNA) Mouse

Result: negative




In vivo micronucleus test

Mouse

male and female

Oral

Bone marrow

Result: negative




Result: positive


Ames test


Result: positive


Carcinogenicity




Teratogenicity


SAFETY DATA SHEET





Page 13 of 18

CMR effects

Carcinogenicity:

Suspected of causing cancer.



Exposure routes: Inhalation




Aspiration hazard



Systemic effects:

After absorption of large quantities:

CNS disorders, Drowsiness, Dizziness, drop in blood pressure, Cardiac irregularities, depressed

respiration, inebriation, Unconsciousness, narcosis, respiratory paralysis

Swallowing may result in damage to the following:

Liver, Kidney



Other dangerous properties can not be excluded.



12.1 Toxicity

Toxicity to fish

flow-through test LC50 Pimephales promelas (fathead minnow): 193 mg/l; 96 h


US-EPA

SAFETY DATA SHEET





Page 14 of 18


static test EC50 Daphnia magna (Water flea): 27 mg/l; 48 h

US-EPA

Toxicity to algae

static test EbC50 Pseudokirchneriella subcapitata (green algae): > 662 mg/l; 96 h



static test EC50 activated sludge: 2,590 mg/l; 40 min




flow-through test NOEC Pimephales promelas (fathead minnow): 83 mg/l; 28 d


(ECHA)


Biodegradability

68 %; 28 d; aerobic





log Pow: 1.25

(experimental)



Distribution among environmental compartments

Adsorption/Soil

log Koc: 1.00

(experimental)

Mobile in soils (Lit.)

SAFETY DATA SHEET





Page 15 of 18





Henry constant

329 Pa*m³/mol

Method: (experimental)

(Lit.) Distribution preferentially in air.






the product itself.







14.3 Class 6.1




user

yes

Tunnel restriction code E


SAFETY DATA SHEET





Page 16 of 18

Not relevant




14.3 Class 6.1




user

no




14.3 Class 6.1




user

yes

EmS F-A S-A


Not relevant




Storage class 6.1 D

15.2 Chemical safety assessment


SAFETY DATA SHEET





Page 17 of 18







Training advice


Labelling

Hazard pictograms

Signal word

Warning

Hazard statements






Response





SAFETY DATA SHEET





Page 18 of 18






SAFETY DATA SHEET




Page 1 of 20










CAS-No. 67-56-1


Identified uses Reagent for analysis, Solvent, Analytical and preparative

chromatography






India * Tel: 0091 22 6210 9000



Tel : +91-2267863131-6


number




SAFETY DATA SHEET





Page 2 of 20



Acute toxicity, Category 3, Oral, H301

Acute toxicity, Category 3, Inhalation, H331

Acute toxicity, Category 3, Dermal, H311

Specific target organ toxicity - single exposure, Category 1, Eyes, H370




T Toxic R23/24/25 - 39/23/24/25


2.2 Label elements


Hazard pictograms

Signal word

Danger

Hazard statements





Prevention


smoking.



Response



SAFETY DATA SHEET





Page 3 of 20

breathing.


Storage



Hazard pictograms

Signal word

Danger

Hazard statements




P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.


P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.


CAS-No. 67-56-1

2.3 Other hazards

None known.


3.1 Substance

Formula CH₃OH CH₄O (Hill)

EC-No. 200-659-6


SAFETY DATA SHEET





Page 4 of 20






67-56-1 *)












CAS-No. Classification


67-56-1 F, Highly flammable; R11

T, Toxic; R23/24/25-39/23/24/25


3.2 Mixture

Not applicable



General advice

First aider needs to protect himself.

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply

artificial respiration, if necessary also oxygen.


shower. Call a physician immediately.

SAFETY DATA SHEET





Page 5 of 20


After swallowing: fresh air. Make victim drink ethanol (e.g. 1 drinking glass of a 40% alcoholic

beverage). Call a doctor immediately (mention methanol ingestion). Only in exceptional cases, if

no medical care is available within one hour, induce vomiting (only in fully conscious persons)

and make victim drink ethanol again (approx. 0.3 ml of a 40% alcoholic beverage/kg body

weight/hour).


irritant effects, Drowsiness, Dizziness, narcosis, agitation, spasms, inebriation, Nausea,

Vomiting, Headache, blindness, Impairment of vision, Coma







Foam, Carbon dioxide (CO2), Dry powder




Combustible.









Further information

Remove container from danger zone and cool with water. Prevent fire extinguishing water from


SAFETY DATA SHEET





Page 6 of 20












sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose

of properly. Clean up affected area.








Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition. Take precautionary


Hygiene measures




Storage conditions

SAFETY DATA SHEET





Page 7 of 20


sources of ignition. Keep locked up or in an area accessible only to qualified or authorised

persons.






Methanol (67-56-1)

IN OEL Skin designation: Can be absorbed through the skin.

Short Term Exposure

Limit (STEL):

250 ppm

310 mg/m³

Time Weighted Average

(TWA):

200 ppm

260 mg/m³





See section 7.1.





Eye/face protection

Safety glasses

Hand protection

full contact:


SAFETY DATA SHEET





Page 8 of 20



splash contact:





89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (full contact), KCL

890 Vitoject® (splash contact).








Flame retardant antistatic protective clothing.









Risk of explosion.



Form liquid

Colour colourless

SAFETY DATA SHEET





Page 9 of 20

Odour characteristic

Odour Threshold 10 - 20000 ppm




at 1,013 hPa

Flash point 10 °C

Method: c.c.


Reference substance: Diethylether

1.9

Reference substance: n-butyl acetate





at 20 °C


Density 0.792 g/cm3

at 20 °C



soluble

SAFETY DATA SHEET





Page 10 of 20


octanol/water

log Pow: -0.77

(experimental)


Auto-ignition temperature 455 °C



at 20 °C



9.2 Other data


DIN 51794


Conductivity < 1 µS/cm


10.1 Reactivity



The product is chemically stable under standard ambient conditions (room temperature) .



Oxidizing agents, perchloric acid, perchlorates, salts of oxyhalogenic acids, chromium(VI) oxide,

halogen oxides, nitrogen oxides, nonmetallic oxides, chromosulfuric acid, chlorates, hydrides, zinc

diethyl, halogens, magnesium, hydrogen peroxide, Nitric acid


SAFETY DATA SHEET





Page 11 of 20

acid halides, Acid anhydrides, Reducing agents, acids

Generates dangerous gases or fumes in contact with:

Alkaline earth metals, Alkali metals


Warming.


various plastics, magnesium, zinc alloys





Acute oral toxicity

LDLO human: 143 mg/kg

(RTECS)

Symptoms: Nausea, Vomiting

absorption


LC50 Rat: 131.25 mg/l; 4 h ; vapour

(ECHA)

Symptoms: Irritation symptoms in the respiratory tract.

absorption


LD50 Rabbit: ca. 17,100 mg/kg

(External MSDS)

absorption

SAFETY DATA SHEET





Page 12 of 20

Skin irritation

Rabbit


(ECHA)


Eye irritation

Rabbit

Result: No eye irritation

(ECHA)

Irritations of mucous membranes

Sensitisation

Sensitisation test: Guinea pig

Result: negative




Micronucleus test

Mouse

male and female


Bone marrow

Result: negative



Ames test


Result: negative



Result: negative


SAFETY DATA SHEET





Page 13 of 20

Carcinogenicity




Teratogenicity


CMR effects

Carcinogenicity:


Mutagenicity:


Teratogenicity:


Reproductive toxicity:



Target Organs: Eyes

Causes damage to organs.



Repeated dose toxicity

Rat

male and female

Inhalation

vapour

28 d

daily

NOAEL: 6.66 mg/l


Subacute toxicity

Rat

male and female

Inhalation

365 d

daily

NOAEL: 0.13 mg/l

SAFETY DATA SHEET





Page 14 of 20

LOAEL: 1.3 mg/l


Aspiration hazard



Systemic effects:

acidosis, drop in blood pressure, agitation, spasms, inebriation, Dizziness, Drowsiness,

Headache, Impairment of vision, blindness, narcosis, Coma

Symptoms may be delayed.

Damage to:

Liver, Kidney, Cardiac, Irreversible damage of the optical nerve.



12.1 Toxicity

Toxicity to fish

flow-through test LC50 Lepomis macrochirus (Bluegill sunfish): 15,400 mg/l; 96 h

US-EPA


EC5 E.sulcatum: > 10,000 mg/l; 72 h

(Lit.)

EC50 Daphnia magna (Water flea): > 10,000 mg/l; 48 h

(IUCLID)

Toxicity to algae

static test EC50 Pseudokirchneriella subcapitata (green algae): ca. 22,000 mg/l; 96 h



EC5 Pseudomonas fluorescens: 6,600 mg/l; 16 h

(IUCLID)

static test IC50 activated sludge: > 1,000 mg/l; 3 h



SAFETY DATA SHEET





Page 15 of 20


NOEC Oryzias latipes (Orange-red killifish): 7,900 mg/l; 200 h

(External MSDS)


Biodegradability

99 %; 30 d



Biochemical Oxygen Demand (BOD)

600 - 1,120 mg/g (5 d)

(IUCLID)

Chemical Oxygen Demand (COD)

1,420 mg/g

(IUCLID)

Theoretical oxygen demand (ThOD)

1,500 mg/g

(Lit.)

Ratio BOD/ThBOD

BOD5 76 %

Closed Bottle test



log Pow: -0.77

(experimental)








SAFETY DATA SHEET





Page 16 of 20

Surface tension

22.6 mN/m

at 20 °C

Stability in water

2.2 yr

reaction with hydroxyl radicals (IUCLID)






the product itself.







14.3 Class 3 (6.1)




user

yes



Not relevant


SAFETY DATA SHEET





Page 17 of 20



14.3 Class 3 (6.1)




user

no




14.3 Class 3 (6.1)




user

yes

EmS F-E S-D


Not relevant




Storage class 3



SAFETY DATA SHEET





Page 18 of 20




H301 Toxic if swallowed.

H311 Toxic in contact with skin.

H331 Toxic if inhaled.

H370 Causes damage to organs.



R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R39/23/24/25 Toxic: danger of very serious irreversible effects through

inhalation, in contact with skin and if swallowed.

Training advice


Labelling

Hazard pictograms

Signal word

Danger

Hazard statements





Prevention




SAFETY DATA SHEET





Page 19 of 20

Response



breathing.


Storage



Symbol(s) F

T

Highly flammable

Toxic

R-phrase(s) 11-23/24/25-

39/23/24/25

Highly flammable. Toxic by inhalation, in contact with skin

and if swallowed. Toxic: danger of very serious irreversible

effects through inhalation, in contact with skin and if

swallowed.


ignition - No smoking. Wear suitable protective clothing and

gloves. In case of accident or if you feel unwell, seek medical

advice immediately (show the label where possible).

Further information

Experience with human exposure

EC-No. 200-659-6


Symbol(s) F

T

Highly flammable

Toxic

R-phrase(s) 23/24/25-39/23/24/25 Toxic by inhalation, in contact with skin and if swallowed. Toxic:

danger of very serious irreversible effects through inhalation, in

contact with skin and if swallowed.

S-phrase(s) 36/37-45 Wear suitable protective clothing and gloves. In case of accident or if

you feel unwell, seek medical advice immediately (show the label

where possible).



SAFETY DATA SHEET





Page 20 of 20



SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006



Page 1 of 12




Product name Ethyl acetate for analysis EMSURE® ACS,ISO,Reag. Ph Eur






CAS-No. 141-78-6


Identified uses Reagent for analysis, Chemical production






India * Tel: 0091 22 6210 9000



Tel : +91-2267863131-6


number











Xi Irritant R36

R66

R67


SAFETY DATA SHEET





Page 2 of 12

2.2 Label elements


Hazard pictograms

Signal wordDanger




EUH066 Repeated exposure may cause skin dryness or cracking.




Response



Storage



Hazard pictograms

Signal wordDanger

CAS-No. 141-78-6

2.3 Other hazards

None known.


3.1 Substance

Formula CH₃COOC₂H₅ C₄H₈O₂ (Hill)

EC-No. 205-500-4


SAFETY DATA SHEET





Page 3 of 12


Chemical Name (Concentration) CAS-No. Registration number Classification

ethyl acetate (<= 100 % ) Substance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII.

141-78-6 *)









Chemical Name (Concentration) CAS-No. Classification

ethyl acetate (<= 100 % ) 141-78-6 F, Highly flammable; R11

Xi, Irritant; R36

R66

R67


3.2 Mixture

Not applicable




After skin contact: wash off with plenty of water. Remove contaminated clothing.




activated charcoal (20 - 40 g in 10% slurry). Laxative: Sodium sulfate (1 tablespoon/1/4 l water).


irritant effects, respiratory paralysis, Drowsiness, narcosis, Nausea, Vomiting, Headache,

somnolence, Salivation, Dizziness

Repeated exposure may cause skin dryness or cracking.


After swallowing of large amounts: Gastric lavage.



Suitable extinguishing mediaCarbon dioxide (CO2), Dry powder, Foam

SAFETY DATA SHEET





Page 4 of 12

Unsuitable extinguishing mediaFor this substance/mixture no limitations of extinguishing agents are given.


Combustible.






Special protective equipment for firefightersStay in danger area only with self-contained breathing apparatus. Prevent skin contact by


Further informationRemove container from danger zone and cool with water. Prevent fire extinguishing water from







Advice for emergency responders: Protective equipment see section 8.


Do not empty into drains. Risk of explosion.


Cover drains. Collect, bind, and pump off spills.

Observe possible material restrictions (see sections 7 and 10).

Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up

affected area.





Advice on safe handlingWork under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.


Advice on protection against fire and explosionKeep away from open flames, hot surfaces and sources of ignition. Take precautionary


Hygiene measuresImmediately change contaminated clothing. Apply preventive skin protection. Wash hands and



Storage conditions

SAFETY DATA SHEET





Page 5 of 12


sources of ignition. Protected from light.






ethyl acetate (141-78-6)IN OEL Time Weighted Average

(TWA):

400 ppm

1,400 mg/m³





See section 7.1.





Eye/face protectionSafety glasses

Hand protection

splash contact:





89/686/EEC and the related standard EN374, for example KCL 898 Butoject® (splash contact).







Other protective equipmentFlame retardant antistatic protective clothing.

Respiratory protectionrequired when vapours/aerosols are generated.

Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds




SAFETY DATA SHEET





Page 6 of 12


Do not empty into drains.

Risk of explosion.



Form liquid

Colour colourless

Odour like fruit





at 1,013 hPa

Flash point -4 °C

Method: c.c.

Evaporation rate No information available.



Upper explosion limit 11.5 %(V)


at 20 °C


Density 0.90 g/cm3

at 20 °C


Water solubility 85.3 g/l

at 20 °C


octanol/water

log Pow: 0.73

(experimental)




SAFETY DATA SHEET





Page 7 of 12


at 20 °C



9.2 Other data


Method: DIN 51794



10.1 Reactivity




Sensitive to air.


Risk of ignition or formation of inflammable gases or vapours with:


Fluorine, chlorosulfonic acid, Strong oxidizing agents, fuming sulfuric acid


lithium aluminium hydride, Alkali metals, hydrides, Alkaline earth metals

Violent reactions possible with:

Strong acids and strong bases


Warming.


various plastics





Acute oral toxicityLD50 Rat: 5,620 mg/kg

(RTECS)

Symptoms: Risk of aspiration upon vomiting., Aspiration may cause pulmonary oedema and

pneumonitis., Irritations of mucous membranes in the mouth, pharynx, oesophagus and

gastrointestinal tract.

SAFETY DATA SHEET





Page 8 of 12



Acute dermal toxicityLD50 Rabbit: > 18,000 mg/kg

(External MSDS)

Skin irritationRabbit


(IUCLID)

Repeated exposure may cause skin dryness or cracking.

Eye irritationCauses serious eye irritation.

SensitisationMaximisation Test (GPMT) Guinea pig

Result: negative


After long-term exposure to the chemical: Sensitisation possible in predisposed persons.


Genotoxicity in vitroAmes test


Result: negative



Result: negative

(National Toxicology Program)

CarcinogenicityThis information is not available.

Reproductive toxicityThis information is not available.

TeratogenicityThis information is not available.

Specific target organ toxicity - single exposureTarget Organs: Central nervous system


Specific target organ toxicity - repeated exposureThis information is not available.

Aspiration hazardThis information is not available.


Systemic effects:

lack of appetite, Headache, Drowsiness, Dizziness

In high concentrations:

Salivation, Nausea, Vomiting, narcosis, respiratory paralysis

Handle in accordance with good industrial hygiene and safety practice.

SAFETY DATA SHEET





Page 9 of 12


12.1 Toxicity

Toxicity to fishLC50 Pimephales promelas (fathead minnow): 230 mg/l; 96 h

(IUCLID)

Toxicity to daphnia and other aquatic invertebratesEC50 Daphnia magna (Water flea): 717 mg/l; 48 h

(IUCLID)

Toxicity to algaeIC50 Desmodesmus subspicatus (green algae): 3,300 mg/l; 48 h

(IUCLID)

Toxicity to bacteriaEC10 Pseudomonas putida: 2,900 mg/l; 16 h

(IUCLID)


Biodegradability100 %; 28 d



Theoretical oxygen demand (ThOD)1,820 mg/g

(Lit.)


Partition coefficient: n-octanol/waterlog Pow: 0.73

(experimental)









SAFETY DATA SHEET





Page 10 of 12


Waste treatment methodsWaste material must be disposed of in accordance with the national and local regulations. Leave


the product itself.






14.2 Proper shipping name ETHYL ACETATE

14.3 Class 3




user

yes



Not relevant




14.3 Class 3




user

no




14.3 Class 3




user

yes

EmS F-E S-D


Not relevant

SAFETY DATA SHEET





Page 11 of 12




Storage class 3










R36 Irritating to eyes.

R66 Repeated exposure may cause skin dryness or cracking.

R67 Vapours may cause drowsiness and dizziness.

Training advice


Labelling Hazard pictograms

Signal wordDanger




EUH066 Repeated exposure may cause skin dryness or cracking.




Response



Storage


SAFETY DATA SHEET





Page 12 of 12


Symbol(s) F

Xi

Highly flammable

Irritant

R-phrase(s) 11-36-66-67 Highly flammable. Irritating to eyes. Repeated exposure may

cause skin dryness or cracking. Vapours may cause

drowsiness and dizziness.

S-phrase(s) 16-26-33 Keep away from sources of ignition - No smoking. In case of

contact with eyes, rinse immediately with plenty of water and

seek medical advice. Take precautionary measures against

static discharges.

EC-No. 205-500-4


Symbol(s) F

Xi

Highly flammable

Irritant





Annexure: XIV

Work Zone Monitoring

Date: 02/02/2017

ANALYSIS REPORT

Sr. No. Parameter Unit Results Permissible Limit as per

Factory Act 1. Chlorine ppm 0.8 3.0

2. Toluene ppm 26.2 150

3. Sodium Hydroxide mg/m3 0.1 NS

4. Ethyl acetate ppm 16.3 NS

5. Benzene ppm 0.9 2.5

6. Acetone ppm 56.3 1000

7. Phenol ppm 1.1 5.0

8. Ammonia ppm 2.1 35

9. Hydrogen Chloride ppm 1.2 N.S.

10. Formaldehyde ppm 0.2 2.0

11. Methanol ppm 12.3 250 NS: Not specified

Authorized Signatory

Client Details Sample Details Name M/s Vadivarhe Specialty Chemicals Ltd. Sample Code GCI/15/I10/PA1

Address Gat No. 204, Nashik-Mumbai Highway,

Vadivarhe, Taluka: Igatapuri, District:

Nashik, Maharashtra, India

Location Near Process Area

Sampling Method Indian standard

Sampling Duration 15 Minutes Date of Sampling 31/01/2017

Sampling Done By Mr. Pragnesh Sampling Instrument Personal Sampler &

Handy Sampler Date of Sample Received 01/02/2017

• Analysis is subject to the condition In Which the Sample Is received at our Laboratory. • Reports can not be used as evidence anywhere including judiciary purpose without our prior permission. • Sample will be retained till one month from the date of sampling.

Annexure: XV

Health Status of Workers

Documents

Annexure: I Land Possession Document · " Rosuvaslatin calCium -'-c-" 100 Strontium 150 (l1 9. , 20 Tazarotene -2 " Telmisartan 300 22. Trospium 50 23 Ezetlmibe 40 24 Citalopram hydrobromide