29
Unclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION STATEMENT A. Approved for public release; unlimited public distribution. Disclaimer: Reference herein to any specific commercial company, product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or the Department of the Army (DoA). The opinions of the authors expressed herein do not necessarily state or reflect those of the United States Government of the DoA, and shall not be used for advertising or product endorsement purposes.

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Page 1: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

ALTERNATIVE FUELS

Pat Muzzell, Alternative Fuels Team Leader

June 19, 2009

Unclassified

UNCLASSIFIED. DISTRIBUTION STATEMENT A. Approved for

public release; unlimited public distribution.

Disclaimer: Reference herein to any specific commercial company,

product, process, or service by trade name, trademark,

manufacturer, or otherwise, does not necessarily constitute or imply

its endorsement, recommendation, or favoring by the United States

Government or the Department of the Army (DoA). The opinions

of the authors expressed herein do not necessarily state or reflect

those of the United States Government of the DoA, and shall not be

used for advertising or product endorsement purposes.

Page 2: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Report Documentation Page Form ApprovedOMB No. 0704-0188

Public reporting burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering andmaintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information,including suggestions for reducing this burden, to Washington Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, ArlingtonVA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if itdoes not display a currently valid OMB control number.

1. REPORT DATE 19 JUN 2009

2. REPORT TYPE N/A

3. DATES COVERED -

4. TITLE AND SUBTITLE Alternative Fuels

5a. CONTRACT NUMBER

5b. GRANT NUMBER

5c. PROGRAM ELEMENT NUMBER

6. AUTHOR(S) Pat Muzzell

5d. PROJECT NUMBER

5e. TASK NUMBER

5f. WORK UNIT NUMBER

7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) US Army RDECOM-TARDEC 6501 E 11 Mile Rd Warren, MI 48397-5000

8. PERFORMING ORGANIZATION REPORT NUMBER 19972RC

9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES) 10. SPONSOR/MONITOR’S ACRONYM(S) TACOM/TARDEC

11. SPONSOR/MONITOR’S REPORT NUMBER(S) 19972RC

12. DISTRIBUTION/AVAILABILITY STATEMENT Approved for public release, distribution unlimited

13. SUPPLEMENTARY NOTES The original document contains color images.

14. ABSTRACT

15. SUBJECT TERMS

16. SECURITY CLASSIFICATION OF: 17. LIMITATIONOF ABSTRACT

SAR

18. NUMBEROF PAGES

28

19a. NAME OFRESPONSIBLE PERSON

a. REPORT unclassified

b. ABSTRACT unclassified

c. THIS PAGE unclassified

Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18

Page 3: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Topics

2

• Introduction

– Transportation Market Evolution

– Tactical Mobility Fuel

• Single Fuel in the Battlefield

– What is the Single Fuel?

– Certification / Qualification Pipeline

– DARPA Alternative Jet Fuels Program

• Coordinating the Overall Alternative Fuel Qualification Process

– Tri-Service POL Users Group

– Notional Qualification Process

• Army Alternative Fuels Qualification

– Overall

– Army Aviation Qualification

– Army Ground Qualification

• Army Fuel Requirements and the JP-8 Spec

• Commercial Aviation Alternative Fuels Initiative (CAAFI)

– Roadmaps

– Fuel Readiness Levels

Page 4: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Transportation Market Evolution

3

21st

Century

Transportation market evolution continues,

shaped by heightened concerns about

energy security and the environment.

• Alternative fuels desired in the jet/diesel fuel supply

• Changes in fuels supply driven by – Legislation [EPAct 2005, EISA 2007], Exec Orders [EO 13423]

– USAF Alternative Jet Fuels Program with goal to certify aircraft on

alternative jet fuels by 2011

– Commercial Aviation Alternative Fuels Initiative (CAAFI)

– Various initiatives to manufacture alternative fuels from diverse sources

• Army active in assessing emerging changes

– Tri-department coordination of alternative fuels qualification efforts

Page 5: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

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Tactical Mobility Fuel

4

Naval Research

Advisory

Committee

Panel* Report

(April 2006)

• Tactical vehicle

designs impose

severe limitations on

volume and weight

• Energy density is

therefore the primary

consideration for fuel

• Hydrogen presently

unsuitable as a

tactical mobility fuel

– made from other

fuels/resources

– containment

reduces energy

density by 10-20X

Liquid hydrocarbons –

ideal fuel for tactical mobility

* Dr. Walt Bryzik panel

member, Chief

Scientist, TARDEC

(Retired)

DOD SINGLE FUEL POLICY

AVIATION KEROSENE GRADE (JP-8)

MIL-DTL-83133

JP-8 (Jet A-1 plus additives) is the primary fuel

used for both air and ground equipment in all

theaters, overseas and Continental U.S.

Page 6: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

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What is the Single Fuel?

5

Alternative Fuels RDT&E:

Expand technical database

on alternative fuels

Engage in specifications

development for alternative

fuels

Qualify alternative fuels for

use in Army tactical / combat

equipment and systems

Alternative jet, diesel fuels

Produced for dual-use (military and commercial)

Meet specs used by military

Often blends with petroleum-based fuels

TARDEC Alternative Fuels Focus

Various conversion processes

Upgraded to meet fuel specs

Diverse

energy

sources

Petroleum Crude Oil

Petroleum

based

Single Fuel in the Battlefield (SFB)*:

Kerosene-type (jet) fuels, whether

petroleum-based or not, allowed under

specs for JP-8 / JP-5 / Jet A-1

(declining

discovery / production)

Non-Petroleum

based

Biomass Energy(renewable)

tallow. fats, lard

wood waste &by-products

agri-wastenon-

food

crops

algae

Fossil Energy(large U.S. resource)

coal

petcokeoil shale

* SFB Policy allows diesel fuel in ground equipment when

supplying jet fuel not practicable or cost effective

Page 7: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Certification / Qualification

Pipeline

6

R&D

Potential

alternative

fuels

HRJ*

50/50

?

TRL 1 TRL 5-6

CertificationTRL 9

Jet

A/A-1

JP-8/5

100%

F-T

100%

bio

Fuels may travel along conveyor at different rates!

moving fast, “drafting” F-T SPKDARPA

Approved fuels, DXXXX

(Commercial Jet Fuel, ASTM Spec)

incubator

non-

HRJ

bio

Courtesy AFRL,

Dr. Tim Edwards

USAF Alternative Fuels Certification Office (AFCO)

is initiating certification for Biojet

(*Hydrogenated Renewable Jet)

Page 8: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Hydrogenated Renewable Jet

(HRJ) Properties Study - AFRL

7

• HRJ properties indistinguishable from F-T SPK

– Spec properties (density, freeze, flash, heat of combustion, etc.)

– Contaminants (metals, oxygenates, etc)

– Fit-for-purpose properties (lubricity, dielectric, cetane, etc.) (in progress)

– Combustion operability and emissions (in progress)

– Material compatibility (in progress)

– Blend properties (in progress)

• Issues (same as SPK!)

– Density of blend

– Aromatic content of blend

– GHG footprint/sustainability

– Cost (feedstock for HRJ, plant cost for F-T)

Courtesy AFRL,

Dr. Tim Edwards

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• Agricultural crop oils (canola,

jatropha, soy, palm, etc.)

– University of North Dakota

EERC

– UOP

– General Electric (GE)

– Swedish Biofuels AB

• Cellulosic and algal

feedstocks that are non-

competitive with food material

– General Atomics ($19.9M)

– SAIC ($25M)

• Acceptable coal-derived fuels

– $8.4M total

– proposals due 02 Jun 2009

DARPA Alternative Jet Fuels

8

Can alternative jet fuels

be made on large-scale and

be cost competitive?P

roduction C

ost

Scale of Production

Alternative fuels

Traditional fuels

HRJ

(Biojet)

Page 10: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Coordinating Overall Process for

Alternative Fuel Qualification

9

• Tri-Service POL Users Group

– Developing DoD qualification process

• Includes all stakeholders (e.g., aircraft, ground vehicles/GSE, infrastructure . . .), OEMs

• Process specified and mandated for alt fuel producers independent of feedstock

• Requires process be recognized by major fuel specifications, standard agreements

– Synthetic fuels database populated (85%)

– JP-8 specification FT wording coordinated

– Continued liaison with DESC SynFuels Working Group

– Shared Lessons Learned, data and resources

– Conduct gap analysis – synfuel efforts, expand to biofuels, ID potential joint efforts

– Increase visibility outside SCP world

– More awareness needed that group exists, recognition as key OSD asset

– Development of framework for DoD test and certification process

• Within Army

– Currently in evaluation phase (see process flow chart next slide)

– Coordination with AMRDEC, need to expand to other key RDEC stakeholders

FY08

Focus

FY09

Challenges

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Unclassified

Alternative Fuel Evaluation & Approval

(Notional Qualification Process)

10

Specification Change

Revised

STANAG &

National Spec

Issued

Ap

pro

ve

d

Modify

STANAG &

National Spec

Additional

Data As

Required

Specification

PropertiesFail

Fit For

Purpose

Properties

(FFP)

Comp / Rig

Testing

Further

Evaluation?

Engine

Testing

Fail

Fail

Fail Pass

Pass

Pass

Pass

No

Start

Yes

Yes

No

No

Evaluation

Further

Evaluation?

Further

Evaluation?

Report

Recommending

Approval

Yes

PM / OEM Review

PM / OEM

Review

Pending

Platform Trials

(if required)

Concur

PM / OEM

Review

Field Trial

(if required)

PM / OEM

Final Review

Concur

Pen

ding

National

Review

Approved

Non-Concur

PendingAdditional

Data As

Required

Non-Concur

Page 12: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Army Alternative Fuels Qualification

11

DemonstrationsSystem

Evaluations

Component

Evaluations

Laboratory

Evaluations

Build user knowledge of and

confidence in use of fuel.

• Completed

– Fuel chemical composition and properties

– Materials compatibility evaluations

– Fuel lubricity evaluations (rotary fuel injection pump)

– Fuel blends studies

– Limited component/engine/system testing (ground equipment)

• In Progress

– Engine performance / durability testing (NATO test cycle)

– Test track evaluation – HMMWV

– Tactical wheeled vehicle (5x5) pilot field demo

– Fuel lubricity evaluations (common rail injection system)

– Cetane - Volatility window studies

• Planned

– Component/engine/system testing and demos (Army Aviation)

Develop data needed to assess fuel’s suitability for use.

* Synfuel Blends: blends of Fischer-Tropsch Synthetic Paraffinic

Kerosene and JP-8 meeting MIL-DTL-83133F

Synfuel Blends

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Army Aviation Qualification

12

* Synfuel Blends: blends of Fischer-Tropsch Synthetic Paraffinic

Kerosene and JP-8 meeting MIL-DTL-83133F(JP-8 spec)

• Alternative fuels under development for aviation: USAF is lead Service

• Certification complete for 50/50 F-T /JP-8 blend on several AF main

engines, APUs, and ground support equipment

• Streamlined, knowledge-based fuels certification process codified in

MIL-HDBK-510

– Sufficient for all future aviation fuel certification efforts

– Maximizes data reuse – streamlines platform certification effort/reduces

time & cost

• MIL-DTL-83133F revised to allow F-T fuels to be a part of the single

battlespace fuel (same process can potentially be used new alternative

fuels in future)

• Alternative fuel blend (up to 50% F-T) to be certified for use in all AF

systems by 2011 (SecAF goal)

• Army Aviation will leverage AF work to enable reduced certification time

and costs for Army Aviation platforms.

• Limited alternative fuels testing performed on Army relevant aircraft

engines to date: T700-GE-701C

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Unclassified 13

AH-64 Apache UH-60 Blackhawk

Tests on one T700 and two

T701C engines

Emissions tests on T701C with

JP-8 and neat F-T fuel

Test under SERDP Project

Army Aviation Relevant Engine

Testing

Page 15: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Army Aviation Relevant Engine

Testing

14

0.0

0.2

0.4

0.6

0.8

1.0

1.2

Idle Cruise Max

Engine Setting

Part

icle

Mass E

I (g

/kg

-fu

el)

T700

T701C

T701C-FT

T700-GE-T701C operated with JP-8 and neat FT fuel

Approximately 50% lower particle mass emissions with T701C compared to T700

Reductions of ~75% in particle mass emissions for T701C with neat FT fuel

Page 16: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Properties of Synthetic

Paraffinic Kerosene (SPK)

15

*Synthetic-Paraffinic Kerosene:

Hydrocarbons distributed across the full jet fuel boiling range and

having on whole properties suitable for use as an aviation fuel.

• Nothing in FT SPK that is not in JP-8

• Not all compounds in JP-8 are necessarily

in FT SPK, results in some differences in

fuel characteristics

AFRL Data

Con

ce

ntr

atio

n

5 10 15 20 25 300Time-->

C11C12

C13

C14

C15

C16

C17C18

C10

C9

C8

C7

C19

JP-8

Fischer-Tropsch (FT) SPK*

Aromatics:

Lower fuel density and

volumetric energy density,

higher Cetane No., less

solvency

Sulfur:

No exhaust SOx

Trace compounds:

Less inherent fuel lubricity

• Can impact component or

engine performance and

durability

Page 17: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

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Fuel Blends Are

Implementation Path

16

• TARDEC elastomer compatibility

evaluations* supported a “blends

implementation path”

• Blends of up to 50% by volume FT

SPK with JP-8

– Blends minimize/eliminate risk of

fuel leaks due to change in fuel

aromatic content

• Other aspects supporting a

blends implementation path

– Production capacity will build

slowly

– Lower energy density of FT SPK

Nitrile Elastomer Coupon & O-Ring

Volume Changes With Switches Between

Synthetic FT "JP-8" & JP-8

-5

0

5

10

15

Switch #

Avera

ge V

olu

me C

han

ge (

%)

1 2 3 4 5 6

Coupon Data

O-Ring

Data

FT

"JP-8"FT

"JP-8"

FT

"JP-8"

FT

"JP-8"JP-8 JP-8 JP-8

Fuel Aromatic Content

FT "JP-8" = 0% vol.

JP-8 = 18% vol.

• Nitrile components swell in JP-8, then shrink when

switched into FT SPK (FT “JP-8”)

• O-ring shrinkage increases risk of sealing failures

• Using unaffected o-ring elastomers or FT SPK in

blends with JP-8 are ways to reduce this risk

*SAE Paper 2007-01-1453

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Blends Study

17

• FT SPK/JP-8 Blend Properties

– Compared properties of blends with typical properties of JP-8 (CONUS,

2004)

– Determined properties of blends (up to 50% FT SPK) generally fell within

typical “property box” of JP-8

– Study documented in SAE Paper 2006-01-0702

• Follow-on study looked at typical JP-8 in use at five Army installations

in CONUS

– Determined that at four of the five installations blends with the maximum

reduction of 50% by volume petroleum content (JP-8) are possible

– Study results documented in 2007 IASH Conference Poster (see next slide)

International Association of the Stability, Handling and Use of Liquid

Fuels (IASH)

Page 19: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

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FORT HOOD

(Region 3)

FORT CARSON

(Region 4)

FORT LEWIS

(Region 5)

JP-8

0.798 kg/L density

13.9 vol. % aromatics

42:58 Blend

(FT IPK:JP-8)

0.778 kg/L density

8.0 vol. % aromatics

JP-8

0.801 kg/L density

21.6 vol. % aromatics

50:50 Blend

(FT IPK:JP-8)

0.776 kg/L density

10.8 vol. % aromatics

JP-8

0.815 kg/L density

20.0 vol. % aromatics

50:50 Blend

(FT IPK:JP-8)

0.783 kg/L density

10.0 vol. % aromatics

FORT BRAGG

(Region 1)

FORT RILEY

(Region 2)

JP-8

0.803 kg/L density

19.7 vol. % aromatics

FT IPK

0.751 kg/L density

0.0 vol. % aromatics

50:50 Blend

(FT IPK:JP-8)

0.777 kg/L density

9.9 vol. % aromatics

JP-8

0.806 kg/L density

16.5 vol. % aromatics

50:50 Blend

(FT IPK:JP-8)

0.779 kg/L density

8.3 vol. % aromatics

Synfuel Blends Study

18

– Fischer-Tropsch Iso-Paraffinic (FT IPK) properties based on previously reported data

– JP-8 typical properties based on DESC data for several fuel deliveries during April 2006 – March 2007

LESS VARIATION IN PROPERTIES FOR SYNTHETIC FUEL BLENDS

AS COMPARED TO PETROLEUM-ONLY DERIVED FUEL

FORT BRAGG

(Region 1)

FORT RILEY

(Region 2)

FORT CARSON

(Region 4)

FORT HOOD

(Region 3)

FORT LEWIS

(Region 5)

DETERMINING MAXIMUM PERCENTAGE OF FT IPK

POSSIBLE IN BLEND WITH GIVEN BATCH OF JP-8

50% REDUCTION IN PETROLEUM FUEL (JP-8) POSSIBLE

AT FOUR OF THE FIVE FORTS IN STUDY

FUEL BLENDS STUDY BASED ON JP-8 USED AT

FIVE U.S. ARMY FORTS

ONE IN EACH DEFENSE ENERGY SUPPORT CENTER (DESC) DEFENSE REGION IN CONTINENTAL U.S.

0.74 0.76 0.78 0.80 0.82

DE NS IT Y (kg /L )

F OR T

B R AG G

F OR T

R IL E Y

F OR T

HOOD

F OR T

C AR S ON

F OR T

L E WIS

F T IP K /J P -8 B lendJ P -8

0.0

5.0

10.0

15.0

20.0

25.0

AR

OM

AT

ICS

(vo

l. %

)

F OR T

B R AG G

F OR T

R IL E Y

F OR T

HOOD

F OR T

C AR S ON

F OR T

L E WIS

J P -8F T IP K /J P -8 B lend

How to Use Chart:

1) Start at left Y-axis with density for given JP-8, read

across to density curve (blue) and down to X-axis,

note percentage.

2) Then, at right Y-axis with aromatics for given JP-8,

read across to aromatics curve (green) and down

to X-axis, note percentage.

3) The lower value noted is the maximum FT IPK

possible to result in a blend with density ≥ 0.775

kg/L and aromatics ≥ 8.0 vol. %.

Example:

Given batch of JP-8 with density of 0.798 kg/L and

aromatics of 13.9 vol. %.

1) Based on JP-8 density, percentage is 49 vol. %.

2) Based on JP-8 aromatics, percentage is 42 vol. %.

3) For this given batch of JP-8, the maximum FT IPK

possible in blend is 42 vol. % (lower value).

0.770

0.775

0.780

0.785

0.790

0.795

0.800

0.805

0.810

0.815

0.820

0.825

0.830

0.835

0.840

0.845

0% 10% 20% 30% 40% 50% 60% 70% 80%

FT IPK Blend Percent - Max. Possible

JP

-8 D

en

sit

y (

kg

/L)

0.0

5.0

10.0

15.0

20.0

25.0

30.0

JP

-8 A

rom

ati

cs (

vo

l. %

)

Chart Basis

FT IPK: density = 0.751 kg/L, aromatics = 0.0 vol. %

Curves can be re-plotted to accommodate FT IPK

property values differing from those on which

this chart is based.

Allowed

(≤ 50 vol. %)

Allowed

(≤ 50 vol. %)

Not Allowed

(> 50 vol. %)

Not Allowed

(> 50 vol. %)

0.798 kg/L

49 vol. %

13.9 vol. %

42 vol. %

FT IPK max. in

blend with JP-8

in this example.

>> Blends to be no more than half synthetics

by volume.

>> If both percentages > 50 vol. %, then

maximum possible FT IPK is 50 vol. %.

Poster presented at 2007 Conference of the International Association for the Stability,

Handling, and Use of Liquid Fuels (IASH), 10/8/2007

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Property Values of Synfuel Blends*

Fit Within Range for JP-8

19

EXAMPLE: Volumetric Energy Density (see chart)

(1) JP-8 batches procured in 2007 worldwide, range and distribution, wt. mean.**

(2) Test fuels, GEP engine evaluation. JP-8 and synfuel blend

(3) Minimum shown is calculated from what is allowed by JP-8 spec. for minimum

density and minimum net heat of combustion.

0.0%

0.2%

0.4%

0.6%

0.8%

1.0%

1.2%

33.0 33.5 34.0 34.5 35.0 35.5 36.0 36.5

Pe

rce

nt

of

Wo

rld

Vo

lum

e

Volumetric Energy Density (MJ/L)

Energy Density of JP-8 Worldwide (PQIS 2007 Data)min wt mean

synfuel blend

JP-8

* Synfuel Blends: blends of Fischer-Tropsch Synthetic Paraffinic

Kerosene and JP-8 meeting MIL-DTL-83133F(JP-8 spec)

** Calculated values; batches missing data not included

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Lubricity Testing

TARDEC F&L Research Facility

20

• Bench-top lubricity evaluations

– BOCLE, SLBOCLE, and HFRR battery

– BOCLE indicated improved lubricity of FT fuel

treated with CI/LI additive per QPL-25107

• Rotary fuel injection pump test rig testing

– Showed FT SPK with lubricity improved to a level

indicative of acceptable field performance

– Both at min. and max. treat rates per QPL-25017

– Results documented in SAE Paper 2004-01-2961

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“Early Demo” – Tactical Generators

TARDEC F&L Research Facility

21

• Objective: Operate tactical equipment using 50:50 FT synthetic fuel blend

• Test Protocol

– Three 10 kW generator sets

– Gen sets “broken-in” using Ultra-Low Sulfur Diesel (ULSD)

– Gen sets fueling during test, operating cycles (% of total time)

• Gen sets #1 & # 3

10% – ULSD

45% – JP-8

45% – 50:50 blend of FT SPK:JP-8

• Gen set # 2

100% – FT SPK

– Tests conducted for 1000 hrs at 50% load

• Some Results (final report in DTIC)

– No reliability issues encountered

– Power generation unchanged for all fuel cases

– Exhaust emission checked; NOx lower using fuel blend than for JP-8

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Unclassified

TWV Pilot Field Demo

TARDEC F&L Research Facility

22

• Determine effects of using fuel blend in a subset Army legacy ground

vehicles

• Field demonstration fleet (variety of wheeled vehicles) at Ft. Bliss, TX

– (2) M998 HMMWV – (2) M1089 A1 FMTV

– (9) M925 A2 5-Ton truck – (1) M984 A1 HEMTT

– (10) M1075 LMTV – (1) M978 HEMTT

– (10) M1083 A1 FMTV – (10) M915 A4 TRAC

– Control vehicles of the same type, operated on JP-8 will be included

• Data generation

– Monthly fleet performance monitoring and fuel analyses

– Vehicle fuel injection systems pre-test inspections for operation / fuel

leaks

– Up to 10 fuel injection system (blend fueled vehicles) post-test

inspections (or earlier if needed) to check operation / fuel leaks

• No recordable issues to-date

• Field demo expected to finish in July 2009

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Unclassified

Army Fuel Requirements and the

JP-8 Specification

23

• Army started conversion from diesel fuel to Single Fuel in the Battlefield

(SFB) in 1980s, implemented in 1988

– Done on “no-harm” premise basis for use of aviation turbine engine fuel in

Army equipment typically having compression ignition (CI) engines

• Army equipment has generally maintained acceptable levels of

performance and durability using SFB, but have been some issues

• Requirements in diesel fuel specs not in JP-8 spec

– Minimum viscosity at 40 C (1.3 mm2/s, No. 1-D)

Low fuel viscosity could lead to increased wear rates in some types of fuel

injectors and injection pumps

– Minimum Cetane No. (40, No. 1-D and 2-D)

Better cold-starting of CI engines

Better CI engine performance, namely less misfire/combustion instability, for light

to medium load operation

– Army request to add these two requirements, to Table A-1 for FT SPK,

during last revision to MIL-DTL-83133F was dismissed, will try again for

next revision

• Different lubricity specification for DF-2 (HFRR) vs. JP-8

Page 25: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Aviation Alternate Fuels Roadmap

24

Category 2010 2015 20302007 20502005

Market Drivers

Environmental,

Political,

Resources

Anticipated

• Fuel Price

• Availability (%

Demand Filled)

AlternativeFuel Products(VolumeAnticipated /Required)

World crude oil production reaches its peak

Concerns about Global Warming dictates addressing worldwide carbon dioxide emissions

Security of crude oil questioned

Qatar GTLProduction

* Fuels produced from seeds and other organic sources such as Soybean Methyl Ester

SASOL Jet Fuel Qatar GTL

Syntroleum Jet fuel in B-52

Nigeria GTL

China Coal GTL

Shell Bintulu GTL

Cellulose ethanol for ground use

Ocean Bio-fuel Factories

Bio-butanol for ground use

Future EnergySource

Resurgence in Nuclear Power

2006 “base” price/gallon with continued volatility

US CTL BiomassCo-fired

Start of Hydrogen Economy

Industrial SolarEnergy

Status as of July 27, 2007

US CTLProduction

Boeing/VirginTest

US CoalCTL

Bio-jet fuel

approved

Level 1 / Scenario

1

Courtesy –

Mark Rumizen, FAA

May 4, 2009

Page 26: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Aviation Alternate Fuels Roadmap

25

Level 2 / Scenario 1

Courtesy –

Mark Rumizen, FAA

Category 2010 2015 20302007 20502005

B-52 syn-fuel flight test

1st bio-jetLab tested

F/T swell lubricity issues solved

Synthetic biology jet fuels developed

Advanced aviation fuel dev

AlternativeFuel Products

Economics& Business

Certification

Environmental

R&D

DOE Step Gain in CO2 Sequestration Efficiency

70% USAF Domestic CTL Sourcing (2025)

200M Gals F/T Prod Future Aircraft for Advanced Fuel

ASTM Spec for SASOL SSJF

ASTM Spec Generic FT Fuel

Advanced Aviation Fuel Spec

MIL-HNDBK-510

ASTM Spec SASOL FSJF

Low emissionsBio-fuel certified

F-T Fuel Carbon Sequester

Bio-fuel EmissionsTest

SASOL Jet Fuel Qatar GTL

Syntroleum Jet Fuel in B-52

Nigeria GTL

China Coal GTL

Shell Bintulu GTL

Ocean Bio-fuel Factories

Bio-butanolfor ground use

Future Energy Source

Resurgence in Nuclear Power

Bio-jet tests done

ASTM Spec HRJ xx% Blend

Boeing/ Virgin 747 Test

ASTM DXXXXSpec

Generic FT Blend

Industrial SolarEnergy

Start of HydrogenEconomy

US CTLBiomassCo-fired

High energy deoxygenated bio-jet fuel from algae

PSU coal derived JP-8

B-52 emissions

Scoping study

HBR TFemissions

New bio-fuel impacts

Adv bio fuel emissions

Operational assessment

Impactsassessment

Benefits assessment

GE/cruise ships burn biofuel in turbines

Generic mat. Compat list

F-T and biojet blend tests done

Jet fuel spec revis

US CTLProduction

50% USAFSyn fuel use

CTL Economics –Scully Financial

ACRP Handbook complete

Boeing/Virgin Test

Cellulose ethanol for ground use

Bio-jet fuel approved

Bio-jet fuel approved

US Coal CTL

Qatar GTLProduction

Coal to liquids

Tar SandsOnline

BiofuelTested

USAF App’l Generic FT Fuel

CRJ xx% ASTM App’d

PRJ xx% ASTM App’dFRJ xx% ASTM App’d

May 4, 2009

Page 27: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Aviation Alternate Fuels Roadmap

26

FRJ Research Rpt

HRJ Research Rpt

50/50 FT in JP8 MIL Spec

ASTM DXXXX App’dBy D.02 Com

2008 20092007

Generic FT Blend USAF Fleet Certification

Sasol FSJF ASTM App’l

2010 2011 2012 2013

Generic 100% FT Fuel ASTM

App’d

Sasol FSJF UK AFC App’l

Generic 50/50 FT

Research Rpt

HRJ

FRJ

HRJ 100% Approved

HRJ 50% Blend App’d in DXXXX

DRAFT

Fermented Renewable Jet (FRJ)

Pyrolytic Renewable Jet (PRJ)

Catalytic Renewable Jet (CRJ)FRL 6.1 FFP Testing

FRLs 6.2 & 6.3 Turbine Hot Section & Component/Rig Testing

FRL 6.4 Engine/APU Testing

PRJ

CRJ

FRJ PRJ

CRJ

FRL 7 Fuel Class Listed in Specification

FRL 6 Full Scale Technical Evaluation

ASTM DXXXX App’dBy Av Fuel Subcom

Courtesy –

Mark Rumizen, FAA

Level 3 / Certification and Qualification

May 4, 2009

Page 28: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Fuel Readiness Level (FRL)

27

Commercial Fuel Readiness Level (FRL) - Alternative Aviation Fuels

FRL Description CAAFI Toll Gate FRL Description CAAFI Toll Gate Fuel Qty MRL USAF TRL

1 Basic Principles

Observed and

Reported

Feedstock and process basic principles

identified

1

2 Technology

Concept

Formulated

Feedstock and complete process concept

identified

2

3 Proof of Concept Small Fuel Sample Available from Lab

Basic Fuel Properties Validated

(Thermal Stability/Freezing Point)

500 ml 3 1. Basic Fuel Properties Observed

and Reported

4.1

4.2

Preliminary

Technical

Evaluation

System Perf. & Integration Studies

Entry Criteria/Specification Properties

Evaluated (MSDS/D1655/MIL 83133)

10 gal

4

2. Fuel Specification Properties

5.1

5.2

5.3

5.4

Process Validation Laboratory Production Development

Subscale Production Demonstrated

Scalability of Production Demonstrated

Pilot Plant Capability Enabled

6.1

6.2

6.3

6.4

Full-Scale

Technical

Evaluation

Fit-For-Purpose Prop’s Evaluated

Turbine Hot Section

Component/Rig/Emissions Testing

Engine/APU Testing

80 gal

4K gal

20K gal

225K gal

5

6

7

8

3. Fit for Purpose

4. Extended Lab Fuel Property Test

5. Component Rig Testing

6. Small Engine Testing

6.5 7. Pathfinder

7 Fuel

Approval

Fuel Class/Type Listed in Int’l Fuel

Standards

8. Validation/Certification

9. Field Service Evaluations

8 Commercialization

Validated

Business Model Validated for Production

Go-Ahead

Airline/Military Purchase Agreements

9 Production

Capability

Established

Full Scale Plant Operational 9-10

Legend: R & D Certification/Qualification Business & Economics

Slide 1 of 2

see

next

slide

for

rest

of

chart

Courtesy –

Mark Rumizen, FAA

Commercial Fuel Readiness Level (FRL) - Alternative Aviation Fuels

Page 29: ALTERNATIVE FUELS - Defense Technical Information · PDF fileUnclassified ALTERNATIVE FUELS Pat Muzzell, Alternative Fuels Team Leader June 19, 2009 Unclassified UNCLASSIFIED. DISTRIBUTION

Unclassified

Fuel Readiness Level (FRL)

28

Commercial Fuel Readiness Level (FRL) - Alternative Aviation Fuels

FRL Description CAAFI Toll Gate FRL Description CAAFI Toll Gate Fuel Qty MRL USAF TRL

1 Basic Principles

Observed and

Reported

Feedstock and process basic principles

identified

1

2 Technology

Concept

Formulated

Feedstock and complete process concept

identified

2

3 Proof of Concept Small Fuel Sample Available from Lab

Basic Fuel Properties Validated

(Thermal Stability/Freezing Point)

500 ml 3 1. Basic Fuel Properties Observed

and Reported

4.1

4.2

Preliminary

Technical

Evaluation

System Perf. & Integration Studies

Entry Criteria/Specification Properties

Evaluated (MSDS/D1655/MIL 83133)

10 gal

4

2. Fuel Specification Properties

5.1

5.2

5.3

5.4

Process Validation Laboratory Production Development

Subscale Production Demonstrated

Scalability of Production Demonstrated

Pilot Plant Capability Enabled

6.1

6.2

6.3

6.4

Full-Scale

Technical

Evaluation

Fit-For-Purpose Prop’s Evaluated

Turbine Hot Section

Component/Rig/Emissions Testing

Engine/APU Testing

80 gal

4K gal

20K gal

225K gal

5

6

7

8

3. Fit for Purpose

4. Extended Lab Fuel Property Test

5. Component Rig Testing

6. Small Engine Testing

6.5 7. Pathfinder

7 Fuel

Approval

Fuel Class/Type Listed in Int’l Fuel

Standards

8. Validation/Certification

9. Field Service Evaluations

8 Commercialization

Validated

Business Model Validated for Production

Go-Ahead

Airline/Military Purchase Agreements

9 Production

Capability

Established

Full Scale Plant Operational 9-10

Legend: R & D Certification/Qualification Business & Economics

see

previous

slide

for

rest

of

chart

Courtesy –

Mark Rumizen, FAA

Slide 2 of 2

Commercial Fuel Readiness Level (FRL) - Alternative Aviation Fuels