ACE Industrial Processes

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    2011, Academic Competition Enterprises

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    INDUSTRIAL

    PROCESSESIndustrial processes come up as tossups and, oftentimes, as bonus parts. Here are a few of the

    most commonly asked industrial processes with brief descriptions of each.(Study Guide by Mostafa Bhuiyan)

    Bayer Process: (1887, Karl Bayer)

    Most common way of producing alumina, the oxide of aluminum. The process involves refining (removing impurities from) bauxite, an ore of aluminum,

    by soaking the bauxite in sodium hydroxide (NaOH). This refined bauxite becomes

    alumina, which is later smelted into aluminum.

    It typically involves four stages: Digestion, clarification, precipitation, andcalcination.Bessemer Process: (1855, Henry Bessemer and 1857, William Kelly)

    Became the first worldwide way of mass-producing steel, an alloy of iron. It involves highly compressed, hot air being blown through molten iron, after which the

    oxygen in the airreacts with the impurities (which can include sulfur and manganese)

    in the molten iron. This causes the impurities to burn out of the now purified metal.

    The air flows through small holes calledtuyeres.Contact Process: (1831, Peregrine Phillips)

    The contact process is the industrial process used to produce sulfuric acid (H2SO4 In the past, the catalyst used in the contact process was platinum, but after it was

    discovered that the platinum could lead to poisoning, a transition was made to a

    vanadium oxide catalyst.

    ). It

    replaced the now defunct lead-chamber process.

    Other products of the contact process include sulfur trioxide andoleum.Electrolysis:

    As its name suggests, the process involves making use of an electric current todecompose a chemical, whose parts form at both the anode and the cathode.

    One of the most common applications of electrolysis is on water; that process breaksdown water into oxygen and hydrogen gas.

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    British chemist Sir Humphrey Davy made use of electrolysis to discover barium,calcium, potassium, and sodium.

    Haber Bosch Process: (1909, Fritz Haber)

    Industrial process that carries out nitrogen fixation via the reaction ofnitrogen andhydrogen. Used to produce ammonia (NH3

    The ammonia is produced from the one nitrogen atom and the three hydrogen atoms bymeans of an iron catalyst.)

    One of the most common uses of the Haber process is the production offertilizer.Hall Hroult Process: (1886, Charles Martin Hall and Paul Hroult)

    The most common way of producing aluminum, unlike the Bayer process whichproduces alumina. It follows the Bayer process in the steps to produce aluminum.

    A typical procedure in the Hall-Hroult process is the use of a cryolite bath, in whichalumina is dissolved. Afterwards, an electric current is sent through the mixture of

    cryolite and alumina.

    Kroll Process: (1940, William J. Kroll)

    Industrial process that is currently used to produce metallic titanium. It replaced the nowdefunct Hunter process.

    Titanium is produced from reducing titanium tetrachloride (TiCl4

    ) by using

    magnesium. The process makes use offractional distillation to separate different

    substances.

    Ostwald Process: (1902, William Ostwald)

    Most common process used to product nitric acid (HNO3 Oxidizes the ammonia produced from the Haber process by using a catalyst that

    contains the element rhodium.

    ). It replaced the now defunctBirdeland-Eyde Arc process.

    Aqua regia can be formed by using the Ostwald process because the aqua regia iscomprised of nitric acid and hydrochloric acid.

    Siemens Process: (Siemens)

    Process that is used to purify silicon by reacting it with hydrochloric acid (HCl). The reaction between the HCL and the silicon creates Trichlorosilane (HCl3

    Si); at hightemperatures, the trichlorosilane melts and yields silicon rods, which are in a purer form

    than the silicon the process started with.

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