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7/25/2019 A Mnemonic Aid for Aldoses
http://slidepdf.com/reader/full/a-mnemonic-aid-for-aldoses 1/1
JOURNAL OF CHEMICAL EDUCATION
A MNEMONIC AID FOR ALDOSES
WILL 8 . DELOACH AND ANN BRANDON
Arkansas tate
eachers
College, Conway, Arkansas
IF
THE D-aldoses (through the hexoses) are built down
from n-glyceric aldehyde, there is formed a pyramid
consisting of one triose, two tetroses, four pentoses, and
eight hexoses. If, in each pair of compounds formed
by adding one carbon atom to the one above it, the
formula of the one with the
OH
group of the new
asymmetric carhon atom on the left is written on the
left and the other on its right, the names of the com-
pounds will be in this order:
Glyceric aldehyde
Threose Erythrose
Lyxope Xylose Arabinose Ribose
Talose Galactose Idose Gulose Mannose Glucose Altrose Allose
The position of each compound in this table is related
in
a
regular manner to the configurations of the
asymmetric carbon atoms. For example, the com-
Presented at the Southeastern Regional Meeting of the
American Chemical Societv. Birrnineham. Alabama. October.
pound at the right end of each row has all of the
OH
groups on the right, and the compound at the left end
has all O groups on the left, except the bottom one.
The following can be used to help remember the order
of the names:
(1)
Write
GATE GA
B
(2)
Write
L X A R L
X A R
(This might be remembered as
LIAR,
with a stroke across the
I
to make it
X .
(3) Write TIM
T
I d l
4 )Add a
G
afte r each of these
G G G
(5) Add two A s at the end
A A
The complete form is then
G A
T 7?
L X A R
T G I G M G A A
If there is difficulty n remembering which A stands
for altrose and which for allose, it might be noted that
when the last letter is reached, that's all (allose).