95825208 Thiede Vasconcelos Parana Flood Basalts Rapid Extrusion Hypothesis Confirrmed Geo38!8!2010 4

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    GEOLOGY, August 2010 747

    INTRODUCTION

    Continental flood basalts (CFB) are infre-quent and extraordinarily large volcanic accu-

    mulations (Courtillot and Renne, 2003; Kelley,

    2007; Renne et al., 1992; Wignall, 2001) that

    often have extrusion volumes in excess of 1

    106 km3. Modern high-resolution 40Ar/39Ar geo-

    chronology (Courtillot and Renne, 2003) for

    four of the largest CFB provinces (i.e., Emei-

    shan Traps, Siberian Traps, Central Atlantic

    Magmatic Province, Deccan Traps) show both

    rapid extrusion rates and temporal overlaps

    between volcanism and major mass extinction

    events, leading to suggestions (Courtillot and

    Renne, 2003; Kelley, 2007; Wignall, 2001) of a

    causal relationship between CFB volcanism and

    mass extinction. However, the comparably sized

    Paran CFB, 2.35 106 km3 (Gladczenko et al.,

    1997), appears to be an exception, as no major

    extinction event overlaps the proposed time of

    volcanism. The age and duration of Paran vol-

    canism, however, are disputed due to conflicting

    sets of40Ar/39Ar geochronology data. One set of

    results (Renne et al., 1992, 1996a, 1996b, 1997)

    indicates that the Paran flood volcanism began

    at 134.7 1 Ma and lasted

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    748 GEOLOGY, August 2010

    0

    100

    80

    120

    160

    200

    Apparentage(Ma)

    %Rad.

    50 100

    Cumulative %39

    Ar released

    0

    0.001

    100

    K/Ca

    3446-01 (DSM23)(A)

    Integrated age = 142 3 Ma

    134.9 1.7 Ma

    3446-02 (DSM23)(B)0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    134.8 1.7 Ma

    Integrated age = 136 5 Ma

    0 50 100

    Cumulative %39

    Ar released

    0.001

    100

    K/Ca

    0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    3446-03 (DSM23)(C)

    134.0 1.7 Ma

    0.001

    100

    K/Ca

    0 50 100

    Cumulative %39

    Ar released

    Integrated age = 138 4 Ma

    Atm

    3446-01, -02, and -03(DSM23)(D)

    36

    40

    0

    0.001

    0.002

    0.003

    Ar/Ar

    039Ar/40Ar

    Age = 134.4 1.1 Ma

    MSWD = 0.89, P = 0.63, n = 27

    40Ar/36Ar Intercept = 301 5

    0.05

    0

    100

    80

    120

    160

    200

    Apparentage(Ma)

    %Rad.

    0.001

    100

    K/Ca

    0 50 100

    Cumulative %39

    Ar released

    133.7 1.4 Ma

    3447-01 (DSM05A)(E)

    Integrated age = 139.2 1.5 Ma

    0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    0 50 100

    Cumulative %39

    Ar released

    0.001

    100

    K/Ca

    Integrated age = 135.6 1.6 Ma

    134.3 1.0 Ma

    3447-02 (DSM05A)(F)

    0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    3447-03 (DSM05A)(G)

    0.001

    100

    K/Ca

    0 50 100

    Cumulative %39

    Ar released

    134.3 1.1 Ma

    Integrated age = 138.5 1.4 Ma

    0

    0.001

    0.002

    0.003

    36Ar/

    40Ar

    Atm

    039Ar/40Ar

    Age = 134.6 1.4 Ma

    MSWD = 1.8, P = 0.02, n = 18

    40Ar/36Ar Intercept = 286 34

    3447-01, -02 and -03

    (DSM05A)(H)

    0.05

    0.001

    0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    0 50 100

    Cumulative %39

    Ar released

    Integrated age = 137.4 1.1 Ma

    134.8 1.1 Ma

    100

    K/Ca

    3448-01 (PAR-1)(I)

    0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    0 50 100

    Cumulative %39

    Ar released

    Integrated age = 137.5 1.3 Ma

    100

    K/Ca

    134.8 1.1 Ma

    3448-02 (PAR-1)(J)

    0

    100

    80

    120

    160

    200

    %Rad.

    Apparentage(Ma)

    0 50 100

    Cumulative %39

    Ar released

    100

    K/Ca

    134.9 1.0 Ma

    Integrated age = 138.0 1.1 Ma

    3448-03 (PAR-1)(K)

    Atm

    0

    0.001

    0.002

    0.003

    36Ar/

    40Ar

    3448-01, -02 and -03(PAR-1)

    (L)

    039Ar/40Ar

    MSWD = 1.6, P = 0.05, n = 22

    Age = 134.8 0.8 Ma40Ar/36Ar Intercept = 310 90

    0.05

    0

    1

    2

    3

    4

    Probability

    100 170Age (Ma)

    0

    80

    Analysis#0

    0.8

    Mol39Ar

    3446-01,-02 and -03 (DSM23)3447-01,-02 and -033448-01,-02 and -03

    (DSM05A)(PAR-1)

    134.6 1.1MaMSWD = 0.74Prob. = 0.83

    134.2 0.8 MaMSWD = 1.61

    Prob. = 0.05134.8 0.7 MaMSWD = 1.28Prob. = 0.18

    135.3

    135.0134.7

    (M)0

    80

    Analy

    sis#

    0

    2

    4

    6

    8

    Probability

    10

    100 170Age (Ma)

    0

    0.8

    Mol39Ar

    134.6 0.6 MaMSWD = 1.15Prob. = 0.19

    135.0

    (N)

    3446-01,-02 and -03 (DSM23)3447-01,-02 and -033448-01,-02 and -03

    (DSM05A)(PAR-1)

    0.001

    0.001

    Figure 2 (continued on following page).

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    GEOLOGY, August 2010 749

    for DSM05A, and 134.8 0.7 Ma for PAR-1,

    which we consider our best estimate for the age

    for each sample. A probability density plot for

    all the plateau steps from the nine grains ana-lyzed yields an age of 134.6 0.6 Ma (Fig. 2N),

    our best estimate for the age of the extrusion

    and possible duration (0.6 m.y. or 1.2 m.y.) of

    volcanism for the Paran CFB. All nine grains

    analyzed in this study are within error from each

    other and correspond, within error, to the narrow

    range of ages reported by the first group (Renne

    et al., 1992), confirming that the duration of the

    Paran volcanism was

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    750 GEOLOGY, August 2010

    and Stewart et al. (1996), would result in much

    lower eruption rates for the Paran as compared

    to other CFB provinces, and it has provided a

    convenient solution for the lack of a tempo-

    ral relation between the Paran CFB and any

    major extinction event (Wignall, 2001; Cour-

    tillot and Renne, 2003). However, the new

    results presented here reveal a minimum aver-

    age magma eruption rate of ~2.0 km3/yr, calcu-

    lated from a Paran-Etendeka volume of 2.35

    106 km3 (Gladczenko et al., 1997) extruded over

    1.2 m.y., which is comparable with extrusion

    rates of CFBs (e.g., Emeishan Traps, Siberian

    Traps, Central Atlantic Magmatic Province,

    Deccan Traps) correlated with mass extinctions.

    These new results invalidate the interpretation

    that the lack of extinction events associated with

    the Paran CFB province results from its pur-

    portedly lower eruption rates, and suggest that

    the direct environmental consequences of CFB

    volcanism, at least those equal to or smaller in

    volume than the Paran CFB, may not be drastic

    enough to drive mass extinction. Drastic envi-

    ronmental effects of CFB volcanism may be afunction of degassing of associated sedimen-

    tary deposits, as recently proposed (Ganino and

    Arndt, 2009), but not the direct effect of volca-

    nism. Alternatively, the Valanginian Weissert

    OAE may actually represent a mass extinction

    event, and its age must be revised in light of the

    new results for the Paran CFB volcanism.

    ACKNOWLEDGMENTSWe thank K. Knesel, A. Ewart, B. Cohen, and G.

    Rosenbaum for comments, and Marcell Regelousfor providing the samples from the Open Universitycollection. Construction of the 40Ar/39Ar laboratoryat the University of Queensland was partially funded

    by Australian Research Council Equipment GrantA39531815; this project was funded by the Universityof Queensland Argon Geochronology in Earth Sci-ences laboratory (UQ-AGES).

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    Manuscript received 1 December 2009Revised manuscript received 23 March 2010Manuscript accepted 25 March 2010

    Printed in USA

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