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14.4 Concentration Changes over Time Graphical Determination of Reaction Order

14.4 Concentration Changes over Time Graphical

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Page 1: 14.4 Concentration Changes over Time Graphical

14.4 Concentration Changes over TimeGraphical Determination of Reaction Order

Page 2: 14.4 Concentration Changes over Time Graphical

14.4 Concentration Changes over TimeReaction Half-Life

Page 3: 14.4 Concentration Changes over Time Graphical

14.4 Concentration Changes over TimeReaction Half-Life

Nitrogen-13 is used in tracers injected into the bloodstream forpositron emission tomography (PET). The half-life of nitrogen-13 is 10.0 minutes. How much time is required for the mass of a sample of nitrogen-13 to fall to 6.25 percent of its original value? Since the decomposition is a radioactive decay reaction, it is first order.

Page 4: 14.4 Concentration Changes over Time Graphical

14.5 Activation Energy and TemperatureReaction Coordinate Diagrams

Page 5: 14.4 Concentration Changes over Time Graphical

14.5 Activation Energy and TemperatureThe Arrhenius Equation

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14.5 Activation Energy and TemperatureThe Arrhenius Equation

The activation energy for the gas phase decomposition of acetic anhydride is 144 kJ/mol.

(CH3CO)2O = CH2=C=O + CH3COOHThe rate constant for this reaction is 6.02x10-4 s-1 at 495 K. What is the rate constant at 531 K?

Page 7: 14.4 Concentration Changes over Time Graphical

14.5 Activation Energy and TemperatureGraphical Determination of Ea

Page 8: 14.4 Concentration Changes over Time Graphical

14.5 Activation Energy and TemperatureGraphical Determination of Ea