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AKB48 N-(5-fluoropentyl) analogSAFETY DATA SHEET

Please refer to Section 7 for Storage and Section 13 for Disposal information.GHS Storage and Disposal Phrases:

Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? Yes Other: InjectionRoute(s) of Entry:

Cannot be made nonpoisonous.Harmful vapors.Material may be irritating to the mucous membranes and upper respiratory tract.May be fatal or cause blindness if swallowed.May cause eye, skin, or respiratory system irritation.

Toxic if swallowed, inhaled, or absorbed through the skin.Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.

Potential Health Effects (Acute and Chronic):

Central nervous system, Eyes, Gastrointestinal System, Respiratory system, Skin.Target Organs:

Please refer to Section 11.LD 50 / LC 50:

Overexposure may cause: confusion, dermatitis, headache, drowsiness, dizziness, gastrointestinaldisturbance, optic nerve damage (blindness), nausea, unconsciousness, vomiting, visualdisturbance, weakness.May cause convulsions.Once methanol is absorbed into the body, it is very slowly eliminated.To the best of our knowledge, the toxicological properties have not been thoroughly investigated.

Signs and Symptoms Of Exposure:

No data available.Medical Condit ions Generally Aggr avated ByExposure:

3. Composition/Information on Ingredients

No phrases apply.NA NA

Hazardous Components (Chemical Name)

AKB48 N-(5-fluoropentyl) analog NA

CAS #

1.0 %

Concentration EC# Risk Phrases RTECS #

1.

R11-23/24/25-39/23/24/25

200-659-6 PC1400000Methanol 67-56-1 99.0 %2.

4. First Aid MeasuresEmergency and First Ai d Procedures:

Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Get immediate medical attention.

In Case of Inhalation:

Immediately wash skin with soap and plenty of water for at least 20 minutes. Removecontaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse.

In Case of Skin Contact:

Hold eyelids apart and flush eyes with plenty of water for at least 20 minutes. Have eyesexamined and tested by medical personnel.

In Case of Eye Contact:

Wash out mouth with water provided person is conscious. Never give anything by mouth to anunconscious person. Get medical attention. Do NOT induce vomiting unless directed to do so bymedical personnel.

In Case of Ingestion:

No data available.Indication of any i mmediate medicalattention and s pecial treatment needed:

5. Fire Fighting MeasuresUse alcohol-resistant foam, carbon dioxide, water, or dry chemical spray.Use water spray to cool fire-exposed containers.

Suitable Extingui shing Media:

A solid water stream may be inefficient.Unsuitable Extinguishing Media:

Can release vapors that form explosive mixtures at temperatures at or above the flashpoint.Container explosion may occur under fire conditions.Emits toxic fumes under fire conditions.Sensitive to static discharge.Vapors can travel to a source of ignition and flash back.

Flammable Properties and Hazards:

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11.00 C Method Used: Closed CupFlash Pt:

385.00 C Aut oignit ion Pt:

LEL: 6.0% at 25.0 C UEL: 36.0% at 25.0 CExplosive Limits:

No data available.Hazardous Combustio n Products:

As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes.

Note: Flammable as diluted in methanol.

Fire Fighting Instructions:

6. Accidental Release MeasuresAvoid breathing vapors and provide adequate ventilation.As conditions warrant, wear a NIOSH approved self-contained breathing apparatus, or respirator,and appropriate personal protection (rubber boots, safety goggles, and heavy rubber gloves).

Protective Precautions, ProtectiveEquipment and Emergency Procedures:

Take steps to avoid release into the environment, if safe to do so.Environmental Precautions:

Contain spill and collect, as appropriate.Transfer to a chemical waste container for disposal in accordance with local regulations.

Steps To Be Taken In Case Material IsReleased Or Spilled:

7. Handling and StorageAvoid breathing dust/fume/gas/mist/vapours/spray.Avoid prolonged or repeated exposure.Keep away from sources of ignition.Take precautionary measures against static discharge.

Precautions To Be Taken in Handling:

Keep away from heat, sparks, and flame.Keep container tightly closed.Store in accordance with information listed on the product insert.

Precautions To Be Taken in Storing:

Avoid contact with skin and eyes. Do not reuse this container. Use with adequate ventilation.Wash thoroughly after handling.

Hazard Label Infor mation:

8. Exposure Controls/Personal Protection

No data.No data. No data.

Hazardous Components (Chemical Name) ACGIH TWA


CAS # OSHA PEL Other Limits

1.TLV: 200 ppmSTEL: 250 ppm

PEL: 200 ppm No data.Methanol 67-56-12.

No data.No data. No data.

Hazardous Components (Chemical Name) France VL


CAS # Britain EH40 Europe

1.

TWA: 260 mg/m3 (200 ppm)STEL: 1300 mg/m3 (1000ppm)

TWA: 266 mg/m3 (200 ppm)STEL: 333 mg/m3 (250 ppm)

TWA: 260mg/m3

Methanol 67-56-12.

Compatible chemical-resistant gloves Eye wash station in work area Lab coat Safetyglasses Safety shower in work area Vent Hood

Protective Equipment Summary - HazardLabel Information:

Use process enclosures, local exhaust ventilation, or other engineering controls to control airbornelevels below recommended exposure limits.

Engineering Controls (Ventilation etc.):

Safety glassesEye Protection:

Compatible chemical-resistant glovesProtective Gloves:

Lab coatOther Protective Clothin g:

NIOSH approved respirator, as conditions warrant.Respiratory Equipment (Specify Type):

Do not take internally.Facilities storing or utilizing this material should be equipped with an eyewash and a safetyshower.Wash thoroughly after handling.

Work/Hygienic/Maintenance Practices:

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Methanol - Investigated as a mutagen and reproductive effector.Only select Registry of Toxic Effects of Chemical Substances (RTECS) data is presented here.See actual entry in RTECS for complete information.Methanol RTECS Number: PC1400000

Chronic Toxicological Effects:

n.a.n.a. n.a.



CAS #

n.a.

NTP IARC ACGIH OSHA

1.

n.a.n.a. n.a.Methanol 67-56-1 n.a.2.

NTP? No IARC Monographs? No OSHA Regulated? NoCarcinogenicity:

12. Ecological InformationAvoid release into the environment.Runoff from fire control or dilution water may cause pollution.

General Ecological Information :

13. Disposal ConsiderationsDispose in accordance with local, state, and federal regulations.Waste Disposal Method:

14. Transport InformationGlobally Harmonized System of Classificatio n and Labelling

Flammable Liquids, Category 2 - Danger! Highly flammable liquid and vapor

Acute Toxicity: Oral, Category 3 - Danger! Toxic if swallowed Acute Toxicity: Skin, Category 3 - Danger! Toxic in contact with skinAcute Toxicity: Inhalation, Category 3 - Danger! Toxic if inhaled Target Organ Systemic Toxicity (single exposure), Category 1 - Danger! Causes damage to eyes

LAND TRANSPORT (US DOT)

Methanol Solution DOT Proper Shipping Name

3 (6.1) DOT Hazard Class:

FLAMMABLE LIQUID, POISON DOT Hazard Label:

1230 UN/NA Number:

II Packing Group:

LAND TRANSPORT (European ADR/RID)

Methanol Solution ADR/RID Shipp ing Name

1230 UN Number:

3 (6.1) - FLAMMABLE LIQUID, POISON Hazard Class:

II Packing Group:

AIR TRANSPORT (ICAO/IATA)

Methanol Solution ICAO/IATA Shipp ing Name

1230 UN Number:

3 (6.1) - FLAMMABLE LIQUID, POISON Hazard Class:

II Packing Group:

3, 6.1 IATA Classification:

Transport in accordance with local, state, and federal regulations. Add it ional Trans port In for mati on:

15. Regulatory InformationF: Highly Flammable; T: ToxicEuropean Community Hazard Symbol codes

European Community Risk and Safety Phrases

R11 - Highly flammable.R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.

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R39/23/24/25 - Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed.S7 - Keep container tightly closed.S16 - Keep away from sources of ignition.S24/25 - Avoid contact with skin and eyes.S33 - Take precautionary measures against static discharges.S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

US EPA SARA Tit le III

NoNo NoHazardous Components (Chemical Name)

AKB48 N-(5-fluoropentyl) analog NACAS #

NoSec.302 (EHS) Sec.304 RQ Sec.313 (TRI) Sec.110

1.

YesYes 5000 LB NoMethanol 67-56-1 No2.

Other US EPA or State Lists

NoNo No



CAS #

No

CAA HAP,ODC CWA NPDES TSCA CA PROP.65

1.

InventoryNo NoMethanol 67-56-1 HAP2.

This SDS was prepared in accordance with 29 CFR 1910.1200, Regulation (EC) No.1272/2008,and European Directive 67/548/EEC as amended.

Regulatory Information Statement:

16. Other Information10/24/2012Revision Date:

Company Policy or Disclaimer

For research use only, not for human or veterinary use.

DISCLAIMER: This information is believed to be accurate and represents the best information currently available to us. However, we make no warranty of

merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should

make their own investigations to determine the suitability of the information for their particular purposes.

N.A.=Not available, N.P.=Not applicable, N.D.=Not determined, N.E.=Not established, N.R.=Not required

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