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Carbon Steels
(1 000, 11 00, 1200, and 1500 Series)
IntroductionCarbon steels are now classified in four distinct series, in accordance
with the AISI system of designations: the 1000 series, which are plaincarbon steels containing not more than 1.00 Mn maximum; the 1100 series,which are resulfurized carbon steels; the 1200 series, which are resulfurized and rephosphorized carbon steels; and the 1500 series, which arehigh-manganese (up to 1.65) carbon steels and are nonresulfurized. Thesefour series differ in certain fundamental properties, thus justifying theseries differentiation. However, in terms of their response to heat treatment,all four series can be discussed in terms of their carbon content, theprincipal controlling factor in heat treating. Other factors are considered forthe individual steels on the pages that follow. To simplify consideration ofthe treatments for various applications, the steels in this discussion areclassified as follows: Group I, 0.08 to 0.25 C; Group Il, 0.30 to 0.50 C;Group ill, 0.55 to 0.95 C. A relatively few steels, such as 1026 and 1029,can be assigned to more than one group, depending on their carbon content.
Group I (0.08 to 0.25% C). The three principal types of heat treatmentused on these low-carbon steels are: (a) process treating of material toprepare it for subsequent operations; (b) treating of finished parts toimprove mechanical properties; and (c) case hardening, notably by carburizing or carbonitriding, to develop a hard, wear-resistant surface. It isoften necessary to process anneal drawn products between operations, thusrelieving work strains in order to permit further working. This operation isnormally carried out at temperatures between the recrystallization temperature and the lower transformation temperatures. The effect is to soften byrecrystallization of the grain growth of ferrite. It is desirable to keep therecrystallized grain size relatively fine. This is promoted by rapid heatingand short holding time at temperature. A similar practice may be used inthe treatment of low-carbon, cold-headed bolts made from cold-drawnwire. Sometimes the strains introduced by cold working so weaken theheads that they break through the most severely worked portion underslight additional strain. Process annealing is used to overcome this condition. Stress relieving at approximately 540°C (1000 "F) is more effectivethan annealing in retaining the normal mechanical properties of the shankof the cold-headed bolt.
Heat treating is frequently used to improve machinability. The generallypoor machinability of the low-carbon steels, except those containing sulfuror other alloying elements, results principally from the fact that the proportion of free ferrite to carbide is high. This situation can be modified byputting the carbide into its most voluminous form, pearlite, and dispersingfine particles of this pearlite evenly throughout the ferrite mass. Normalizing is commonly used with success, but best results are obtained byquenching the steel in oil from 815 to 870°C (1500 to 1600 OF). With theexception of steels containing a carbon content approaching 0.25%, littleor no martensite is formed, and the parts do not require tempering.
Group II (0.30 to 0.50% C). Because of the higher carbon content,quenching and tempering become increasingly important when steels ofthis group are considered. They are the most versatile of the carbon steels,because their hardenability (response to quenching) can be varied over awide range by suitable controls. In this group of steels, there is a continuouschange from water-hardening to oil-hardening types. Hardenability is verysensitive to changes in chemical composition, particularly to the content ofmanganese, silicon, and residual elements, as well as grain size. Thesesteels are also very sensitive to changes in section.
The medium-carbon steels should be either normalized or annealedbefore hardening in order to obtain the best mechanical properties afterhardening and tempering. Parts made from bar stock are frequently givenno treatment prior to hardening (the prior treatment having been performedat the steel mill), but it is common practice to normalize or anneal forgings.
These steels, whether hot finished or cold finished, machine reasonablywell in bar stock form and are machined as received, except in the highercarbon grades and small sizes that require annealing to reduce the as-received hardness. Forgings are usually normalized to improve machinabilityover that encountered with the fully annealed structure. These steels arewidely used for machinery parts for moderate duty. When the parts are tobe machined after heat treatment, the maximum hardness is usually held to320 HB and is frequently much lower.
In hardening, the selection ofquenching medium will vary with the steelcomposition, the design of the part, the hardenability of the steel, and thehardness desired in the finished part. Water is the quenching medium mostcommonly used, because it is best known and is usually least expensive andeasiest to install. Caustic soda solution (5 to 10% NaOH) is used in someinstances with improved results. It is faster than water and may producebetter mechanical properties in all but light sections. It is hazardous,however, and operators must be protected against contact with it. Saltsolutions (brine) are often successfully used. They are not dangerous tooperators, but their corrosive action on iron or steel parts or equipment ispotentially serious. When the section is light or the properties required afterheat treatment are not very high, oil quenching is often used. Finally, themedium-carbon steels are readily case hardened by flame or inductionhardening.
Group III(0.55 to 0.95% C). Forged parts made of these steels shouldbe annealed because:
• Refmement of the forged structure is important in producing a highquality, hardened product .
• The parts come from the forging operation too hard for cold trimming ofthe flash or for any machining operations
Ordinary annealing practice, followed by furnace cooling to approximately 600°C (1110 OF) is satisfactory for most parts.
Hardening by conventional quenching is used on most parts made fromsteels in this group. However, special techniques are required at times. Bothoil and water quenching are used: water, for heavy sections of the lowercarbon steels and for cutting edges; oil, for general use. Austempering andmartempering are often successfully applied. The principal advantages ofsuch treatments are considerably reduced distortion, elimination of breakage, and, in many instances, greater toughness at high hardness.
Tools with cutting edges are sometimes heated in liquid baths to thelowest temperatures at which the part can be hardened and are thenquenched in brine. The fast heating of the liquid bath plus the low temperature fail to put all of the available carbon into solution. As a result, thecutting edge consists of martensite containing less carbon than indicated bythe chemical composition of the steel and containing many embeddedparticles of cementite. In this condition, the tool is at its maximum toughness relative to its hardness, and the embedded carbides promote long lifeof the cutting edge. Final hardness is 55 to 60 HRC. Steels in this group arealso commonly hardened by flame or induction methods.
122/ Heat Treater's Guide
Effectof massand sectionsize on coolingcurvesobtained for the waterquenching of plaincarbonsteels
200
600
1600
1400
6543
1035 steel125-mm (5·in.) diam
Weight, approx 40 kg (S5 lb)
2
-+---+---""""'-...!::,--""""""'=----!400
OL----'------'--------L------L---L----Jo
200
800 I----~--_+--___.---..__--__r_--_;
400 /----+-~.._+_--___P.._-_j__--_+--___I
1000,-----,------y--------.---,..----,--------,
oU 1200~~. 600 1-----'\--+----1~--_r__--___;_---+_--__l i,a 1000 ,a~ ~Q) Q)
~ 800 ~~ ~
200
600
1200 LLo~.
1000 ,a~Q)0.E~
1400
1600
12108
-1-__+-__--1 800
6
1020 steel150-mm (6-in.) diam
Weight, approx 65 kg (142 lb)
42O'-------'-----'-----'---------'-----L-----'
o
8001-\''r''Y''k----+---+---_j__--_+---------j
1000 ,..----.-----,-------,----,-------,------,
Uo~. 6001----\---i';.-T-lHf--
,a~Q)0.
E 400 f---J----'l.-----~~~
200 1----+---_+-----''''''''''---.3Oj.......:---+---_+_----j 400
Time, min Time, min
600
200
1400
1600
2420161284O'------'-------JL----..L..------'-----L----'
o
1000r---..__---.----~----::_::_:_~----:--~--_,
200 1----+---+-~.?"'.:---__I_--_+--_==1400
1040 steel
210·mm (Si - ln.) diam
800 I-TY''''''''''::-t-------JL.--_Weight, approx IS5 kg (410 Ib)
105 mm (4i in.) below surface
U 1 1200 LLo 600 /----\--t-''r--\-\f-\SO mm (3 8" in.) _+-__-+__---j 0
i i,a 55 mm (2 -Sl in.) 1000 ,a~ ~Q) Q)
~. 400 30 mm (l-Sl in.) 800 ~
~ ~
200
600
1600
1400
12108642
Water at 55 °c (130 of)No agitation
O'------'------'--------L-----'----..L----'o
200 /----+---+_---1""........?'-..,£!~-_+--__t 400
1040 steel175-mm (7-in.) diam
Weight, approx 105 kg (230 lb)800 tr-'~----1I---'~..-t--- 1
90 mm (32 in.) below surface
65 mm (2j ln.)
45 mm (1 W, in.)
25mm(*in.)
1000,-----.------.--------.---r-----.------,
Uo
Time, min Time, min
600
1400
1600
200
65432
13 mm (~in.)
below surface -i------"'''=---t----t-----1 400I
Water at 45 °c (115 of)No agitation
OL----'-----'------'--------L----..L----'o
200
1045 steel
100·mm (4-in.) diam800 ~----"~_+_---t--Weight, approx 20 kg (43 Ib)
I50 mm (2 tn.) belowsurface
1000 ,-----.------.----,---r-----,--------,
Time, min
600
1400
1600
24201612Time, min
84
1--__+-------=~...p..,.___I_*--__I_--_+--___I800
O'-------'--__--' --'---__---..L .L...-__-'
o
1000,-----,------y--------.---r------r------,
2001----+---+---+-="""""~.a_...---_+--~400
1040 steel
265-mm (10~ -In.) diam
800 H~----..::>~O::::------;--Weight, approx 335 kg (735 Ib)I I I
135 mm (51 in.) below surfaceU 1200 LLo. 600/---+-+-"c-_-1~~c.160 mm (4 in.)__-+__---t 0
~ I i::::J 1000 ,a~ 70 mm (2-
43 in.] ~
~ 8.E 400 E~ ~
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Carbon Steels (1000,1100,1200, and 1500 Series) /123
Effect of mass and section size on cooling curves obtained for the oil quenching of plain carbon steels
1000 r----,-----.....-----.----,-----.-------, 1000 r---.-------.----.------,-----,------,
600
200
1600
1035 steel125-mm (5-in.) diam
Weight, approx 40 kg (S5Ib)
Time, min
Oil at 30°C (90 of)
200 I---I---I--~R:::___;;;;;::_I--____ll--_______j 400
65 mm (2 t in.) below surface
o 1 1200 u,o .. 600 f----lt-~_\______F 30 mm (1 -S in.)-----1----!-----1 °~ ii:! 13mm(-21 in.) 1000 i:!~ ~~ ~
E400 800 E~ ~
600
1600
302520
T=-~~-J200
800-+----+----j
1020 steel150-mm (6-in.) diam
Weight, approx 65 kg (142 Ib)
15Time, min
105
Oil at 40°C (100 OF)
01--.--...L..------'--------1----'----...L-------'o
800 I-\\~-+__--+_--_+_-----t-----t--------i1400
200 I------+----+---~~_=_+--_+--___"i 400
75 mm (3 ln.) below surface
!;J 55 mm (2 i~ ln.) 1200 !;Li 600 I-----\~~r_I- --+---1------1 i.3 40 mm (1-
21 in.) 1000 .3
~ ~
~ 400 20 mm (~in.) ~~ ~
200
600
1400
1600
60504030
Time, min2010
Oil at 40°C (100 of)
oL_---ll-._---l__-L__---.L__---l- __
1000r---,-----,---,---,---,-------,
200I--t--t-~'f~~~~;;;;t~::::~ 400
1040 steel
210·mm (st - in.) diam
800I-H~--+---I--Weight, approx lS5 kg (410 Ib)
105 mm (4i in.) below surfaceo 1200 0'"0", 600I--+--"o-~---F SOmm (3i in.)--+----t-----j ~!'i 1 1000 i:!~ 55 mm (2 8 in.) ~
~ 400 30 mm (l-Sl in.) 800 ~
~ ~600
200
1600
605040
1040 steel175-mm (7-in.) diam
Weight, approx 105 kg (230 lb)
30Time, min
20100L---...L..------'--------1---.L...---...L----
o
800 M,,.---+----+---+----+----+----i1400
1000 r---...,.----,-----,---r----,------,
200 1-----+----~~E::""+_--+---+--""""'""I400
90 mm (3t in.) below surface
5 1200 u,aU. 600 I-+---\-!\\--lf- 65 mm (2 8 in.) -1-__-+ +-__-; °m i~ 45 mm (1~ ln.) 1000 ~
~
~ 400 25 mm (~ ln.] 800 ~~ ~
600
200
1600
1400
242016
1045 steel100-mm (4-in.) diam
Weight, approx 20 kg (43 lb)
12Time, min
84
Oil at 35°C (95 of)
Ol---..I.---...L-----L---.L------'---o
1000r---,---,---,---,---,------,
50 mm (2 in.) below surfaceI 1200 ...
oU 600 f-\-~1"--¥-25 mm (1 in.) 4 +-__+ __---1 o~.
~ 13 mm (t in.) 1000 ~ro ~
~ 800 ~E 400I---~~--+_--+---+----+------j E~ ~
200I----+---~~:t:s::::__+---+----+----=t 400
200
600
1600
1400
605040302010
Time, min
Ol--.--L..----'-----'-----'-----'-----o
Oil at 29°C (S5 ° F)
1040 steel
265-mm (lOt -In.) diam
800 ~--.3iii~-+---------1I---Weight, approx 335 kg (735 lb]
135 mm (5t ln.) below surface
1000r---.-----.....-----.------,--------r--~
200 1--t--t--t-.......::::1O:::::!::::::~~~~400
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124/ Heat Treater's Guide
Influence of tempering temperature on room-temperature hardness of quenched carbon steels
Tempering temperature, of Tempering temperature, of Tempering temperature, of
750650
1200
550
1000
450
800600
100 '---_---'-__.1.-_---'-__-'-_---'
250 350
700,.--,---r--,-...,....--,-,---,-----,
co:r: 5001---_I---I-----,------r-----lu;V)Q)c'E'":r:
700
1200
600
1000
500
800
400
600
10303.2-6.4 mm thick
100 '---_---'-__.1.-_---'-__-'-_---'
200 300
300 1------+---=---I.O~_u'/--,-c-r-_I----1
400700 n----,--r----r--r---r--r--,--,--,
>:r: 5001t-----c:>----f-o---+u;V)Q)c'E'":r:
700
1200
600
1000
500
800
400
600
10263.2-6.4 mm thick
400700 n----,--r----r--r---r--r---r--r--,
100 '---------'------'-----'200 300
>:r:u;V)Q)c
~ 300 1----l'---I--I:Ir-lW+-~-_+_--l:r:
Tempering temperature, °C Tempering temperature, °C Tempering temperature, °C
700600500400100 '-_---'-__.1.-_---'-__-'-_---'
200 300
300 1----1---~i@@j~
Tempering temperature, of
400 600 800 1000 1200700
m:r: 500 h=--I---_+_--,-----,-----1u;V)Q)c'E'":r:
700
1200
600
1000
500
800
400
60040070 rr---,--r----r-,--,-,--,--,---,
10'---'------'----'--------'----'200 300
Ua::r: 50 ..........._I---I-----,-----r-----lu;V)Q)c~ 30 I---_I---I-----''''''''~-_+_----l
:r:
Tempering temperature, of
700600500400
c" 4 h... 24 h
300
100 '-_---'-__.1.-_---'-__-'-_---'
200 300
Tempering temperature, of
400 600 800 1000 1200700
>:r: 500'lot-----I'f-+O--li-------.-----.----lu;V)Q)c'E'":r:
Tempering temperature, °C Tempering temperature, °C Tempering temperature, °C
Tempering temperature, OF
800 900
700600500400300
300 \---+---=
100 '-_---'-__.1......_---'-__-'----_---'
200
Tempering temperature, °C
Tempering temperature, of
400 600 800 1000 1200700
rn:r: 500 \---1---_+_--,---,-----1u;V)Q)c'E'":r:
700
1200
600
1000
500
800
400
600
300
Tempering time:
010 min c" 4 h.1 h ... 24 h
100 '--~-~----'--------'----'200
300
400700 rr----r,--...,....,--,-,--,--,---,
Tempering temperature, OF
Tempering temperature, °C
>:r: 500iF-----"'-----1-V-_I-----.-----.----1u;V)Q)c'E'":r:
600
r I I INumbers represent
number aftests
54 - Average
76 0 0 54[] 10414111.1 mm bolts
800
200As-quenched 450 500 550
Tempering temperature, °C
rn:r: 600u;V)Q)c'E 400'":r:
Carbon Steels (1000,1100,1200, and 1500 Series)/125
Influence of tempering temperature on room-temperature hardness of quenched carbon steels (continued)
600 70050040010 '-------'----'-----'---'------'
200 300
Tempering temperature, OF
400 600 800 1000 120070
Ua::I 501---='=;-«:----\---,--:....,----j
liQ)c"E 301----+---+---I---" -t----\co
I
600 700500400
400
200 L-_-'-_----'__-'-_----'-_------'
200 300
400800 ...----nr----,,-.,.-'-'r-,--'--.:....,
coI 6001---+---+---y-----,----\<henQ)c:"E'"I
600 700500400
Tempering time: ---lIl+--W----o----\
010 min /;. 4 h.1 h ... 24 h
300
100 '--_--'--__L-_-'-_----'_----'
200 300
400700 ...----nr----,,-.,.~..:-,--'__,:....,
>I 5001----tl;!-----rr+---,------,----jliQ)c:"E'"I
Tempering temperature, °C Tempering temperature, °C Tempering temperature, °C
800 r-.,.-r-""T"'T--rr-----,-----,
600 700500400100 '--_---'--__.1..-_----'-__-'-_---'
200 300
300 1---+------1-----'
Tempering temperature, of
400 600 800 1000 1200700
coI 5001----+--'1<henQ)c
"E'"I
600 70050040010 L-_--'--_----'__-'-_---L_------'
200 300
Tempering temperature, of
600 800 1000 1200
Ua::I
liQ)c
"E'"I
650 750550450
Tempering temperature, OF
600 800 1000 1200
400
200 L---l_-l--=::E~~----.J250 350
coI 6001---+--+--.,.--,--'----1<hl3c:"E'"I
Tempering temperature, °C Tempering temperature, °C Tempering temperature, °C
600 700500400
Tempering time: ~»----o------,+------t
010 min o: 4 h.1 h ... 24 h
300
100 L..-_~__~_----'-__-'-_---'200 300
Tempering temperature, OF
400 600 800 1000 1200700
>I 5001"'-------T.:Hcrr---+---.---,------\liQ)c
"Eco
I
600 700500400
Tempered 1 h
Tempering temperature, OF
400 600 800 1000 120070
10 L..-_--'--_----'__...l.-_---L_-----'
200 300
ua::I 501-----/---"'ha:--y-----,----1<h~c:~ 30 1-----/---+--+----=-f"""'=::---1I
700 80060050040010 '-------'----'---"------'----'-------'
200 300
Ua::I
<henQ)c:
"E'"I
Tempering temperature, °C Tempering temperature, °C Tempering temperature, °C
126/ Heat Treater's Guide
Room-temperature hardness of three carbonsteelsafter production tempering. (a) Automotivesteering-armforgings made of finegrain 1035steel. Sectionthicknessvaried from 16to 29 mm (% to 1%in.). Forgingswereaustenitizedat 825°C (1520OF) in oil-firedpusherconveyor furnace, held45 min, quenched in waterat 21°C (70 OF), and tempered45 min at 580 to 625°C (1080 to 1160OF) in oil-fired Iinkbelt furnaceto requiredhardnessrangeof217 to 285 HB.Hardnesswascheckedhourlywith a 5%sample; readingswere takenon polishedflash line of 29 mm (1 %in.) section. Survey of furnace revealedtemperaturevariationat 605°C (1120OF) of 8, -4°C (15, -7 OF). Data represent forgings from four mill heats of steel and cover a 6-week period. (b) Woodworkingcutting tools forged from 1045 steel. Sectionofcutting lip was hardened locally by gas burners that heated the steel to 815°C (1500 OF). Toolswere oil quenched and tempered at 305 to325 °C (585 to 615 OF) for 10 min in electrically heated recirculating-airfurnace to a desired hardness range of 42 to 48 HRC. Data wererecordedduringa 6-monthperiodand representforgingsfrom 12 mill heats. (c) Platesections, 19to 22 mm (%to 7Ja in.) thick, of 1045steelwerewater quenchedto a hardness rangeof 534to 653 HRBandtempered1hat 475°C (890OF) incontinuous roller-hearthfurnaces.Datarepresenta 2-month productionperiod. (d) Forged1046steel heatedto 830°C (1525 OF), and quenched in caustic. Forgingswere heatedin a continuousbelt-type furnace and individuallydumpquenched in agitatedcaustic. Forgingsweighed 9 to 11 kg (20to 241b)each; maximumsection, 38 mm (1%ln.). (e) As-quenchedforged 1046steel shown in (d), temperedat 510°C (950 OF) for 1 h. (f)As-quenchedforged1046steel shown in (d), tempered at 525°C (975 OF) for 1 h. Average hardnessdata for all but (c) obtained by calculatingaverage of highand low extremes of hardnessspecification rangefor each batch.
Average hardness, HB(f)
331340
340 350 360 370 380
Hardness, H8
281- 291- 301- 311-290 300 310 320
Average hardness, HB
24
~ 20E'g 16Q.
.: 120~
8'".0E 4:JZ
0290
(e)
10..---------------, ~---------,I
(e)
11 81----------------i 1----------11s~ 61----------------i 1----------11...o~ 41------1.0E~ 2 1------rT77r-V/
Average hardness, HRC(b)
591- 601- 611- 621600 610 620 630
Average hardness, HB
Average hardness, H8
12
ID 10s:u... 8'".0...0 6~
'".0E 4:JZ
0
(a)
10
'"'" 8s:
~.0 6...0~ 4'".0E:J 2z
0561-570
(d)
Carbon Steels (1000,1100,1200, and 1500 Series)/127
1062: Heat-to-Heat Variations in Depth of Hardness. Heat-toheat variations in depth of hardness among three heats. Hubswere flame hardened on the inside diameter to a minimum of 59HRC at 1.9 mm (0.075 in.) below the surface. Parts were heated12 s and quenched in oil. Hardness was measured on cross sections of heated area.
1062 steelhub
12r--------------tHeat A
Heat , I
~ 8 [----------------1.L;
'0 4[---------1:1-------1~ 0
~ ':I:======:::':=:'=~~===~1 0 -----~----jL~----
j~I===='=~~~====1.8 2.3 2.8 3.3
Maximum depth of hardnessto 60 HRC, mm
12~1 II IIIIBJIm8 Measurement of diameter A
~ : Heat l~ Heat a
'0
i '~n:1l.fEnmE'rtWJlo 25 50 75 100 125 0 25 50 75100125 0 25 50 75 100125
A = 54.3mm B = 54.3mm54.4 mm 54.4 mm
Hub 1062 steel79 84 89 119.94
20
10Converter gear hub1052 steel
1052 and 1062: Flame hardening hubs. Distribution of dimensional change as a result of flame hardening. (a) Change in pitch diameter ofconverter gear hubs made of 1052 steel. Gear teeth on inside diameter were heated for a total of 9.5 s, before being quenched in oil to provide a depth of hardness of 0.9 mm (0.035 in.) above the root. (b) Close-in of inside diameters of converter hubs made of 1062 steel. Insidediameter was heated for a total of 12 s and then oil quenched to harden to 59 HRC min at a depth of 1.9 mm (0.075 in.) below the surface.Inside diameter was finish ground after hardening.
30 r-.--.--.--.--r-r-l
(a)Variation of pitch diameter, mm
(blAmount of close-in of inside diameter, p.m
128/ Heat Treater's Guide
1018 and 1024: Gas carburizing. Effect of tempering on hardness of 1018 and 1024 steel. Parts were carburized at 925°C (1700 OF) for4.5 h, then oil quenched and tempered.
Distance below surface, 0.001 in. Distance below surface, 0.001 in.
1.25
40
1.00
30
0.75
20
0.50
10
0.25
o70 r---,----,,-----.r-----rr--~
102425·mm (1-in.i diam bar
60 ;---"-+-~'f>----t;As quen~hed----l-----I
20 '--__'--__'--__'--__L-_-----l
o
30 1-----t----t----t---1'>--I2'J------l
..c'EI 40r-,-,;-.,.....,.-+---;;-::-+-+-~-f--'\..:zlO~+_--__l
1.25
40
1.00
30
0.75
20
0.50
10
0.25
o70 r---,-----.-----or-----rr-----,
50 I-----+--~d-----'~----I-----l
60+-""'-_"'-=-p..~-t---I--_l
20 '---__-'-__-'---__--'---__--'-__---J
o
30 I-----+---+_---+------""""'~_--l
Ua:I
Distance below surface, mm Distance below surface, rnm
Distance below surface, 0.001 in. Distance below surface, 0.001 in.
1.251
40
1.00
30
0.75
20
0.50
10
0.25
o70 .-------.-------.-------.--------,.--------,
40 1-----*---:+-+----1I-------".....+-~>___l
20 '------'-------'-------'-------'------'o
30 I-----+---+----+---+-----l
Ua:I
1.25
40
1.00
30
0.75
20
0.50
10
0.2520 L-_--.JL-_--.JL-_--.JL-_-----'__-----'
o
40 1-------1I-------1f--f---''''''d'------'~:------j
30 1-------1I-------1I-------1----;I------j---==-------j
60 h ....._+-=----"''''--j-------j!-------j
ua:I
Distance below surface. mm Distance below surface. mm
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Carbon Steels (1000,1100,1200, and 1500 Series) /129
Effect of time and temperature on case depth of liquidcarburizedsteels
10.001.00
45 HRC1020
25-mm diam by 152 mm 50 HRC
{t-in. diam by 6 in.1200 0.50 205.00 -
E Oil quenched 925 °C(1700 of) .~E aill 0 .£ci E11
~E 0.25 10 g(; 100 5 ci-6 2.00 (; 5~ s: (;-e g
~ -6 (;0 50 -e 0-
'" -6f- ~ 0 0.10 0-1.00 0 '"f- 0
0.50 20 0.0500 10 15 20 25 30 Carburized at 900 °C(1650 OF),
Time at carburizingtemperature, h water quenched
0.025 10 8
1.00 1020 Time at carburizing temperature, ht l-rnrn diam by 6.35 mm(O.4·in. diam
0.50 by 0.2 in.) 20 .CO2.50
E g 1117E ci
~ 10 ~u
(; (; 50E. Carburized at 855 °C(1575 of), s: 1.00'" E.
0 brinequenched, ~tempered al150 °C(300 of)
0.10 0.50 200 c
ETime at carburizingtemperature. h E ;;
~0ci
c 0.25 ~.
1.00 's 11
t 's-60~
200
0.500.10
E .~E s~ 0.25 10:;
"0~
0.050s:E. "00 .cg 0.025 1
0.10 0 0 8
Carburized at 925 °C11700 °Fl, Time at carburizingtemperature, hwater quenched
0.050 20 8
2.50Time at carburizing temperature, h 1117
12.7-mm (0.5-in.) diam bars
E .52.50
E ;;E 1118 .~ ill
50 0E ;; 1.00 ci
5 11 50 (;ci(; 50 ill E. (;s: 1.00 11 '" 0.50 Depth of case to 50 HRC 20 -6g ~
0I I 0-
0 '"0 -6 Carburized at 900 °C(1650 OF), 0Carburized at 855°C 11575 of). 0-
quenched in 10% brineslow cooled '"00.50 20 0.25 10
0 10 0 5
Time at carburizing temperature, h Time at carburizing temperature, h
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130 I Heat Treater's Guide
Nitriding Carbon Steels. Effect of carbon content in carbonsteels on the nitrogen gradient obtained in aerated bath nitriding
Distance below surface. 0.001 in.
0 10 20 300.20 I I I I I
, Equal processing time<f. 0.15
~"--1010-
c'Q) - -1015e0.10
......~- - -1035-
~...... ~
""', - - - - - 1060-....:::0.05 --..:; ~""'--""'-L -
0-------::r-
0 200 400 600 800
Distance below surface, 11m
Typical Normalizing Temperatures for Standard CarbonSteels
Temperature(a)Grade °C of
Plain carbon steels
1015 915 16751020 915 16751022 915 16751025 900 16501030 900 16501035 885 16251040 860 15751045 860 15751050 860 15751060 830 15251080 830 15251090 830 15251095 845 15501117 900 16501137 885 16251141 860 15751144 860 1575
(a) Based on production experience. normalizing temperature may vary from as muchas 27°C (50 "F) below. to as much as 55°C (100°F) above, indicated temperature. Thesteel should be cooled in still air from indicated temperature.
Properties of Selected Carbon Steels in the Hot-Rolled, Normalized, and Annealed Conditions
IzodimpactAISI Tensile strength Yield strength Reduction Hardness, strengthgrade(a) Condition or treatment MPa ksi MFa ksi Elongation(b), % in area, % HB J ft ·Ibf
1015 As-rolled 420 61 315 46 39.0 61 126 111 82Normalized at 925°C (1700 oF) 425 62 325 47 37.0 70 121 115 85Annealed at 870 °C (1600 oF) 385 56 285 41 37.0 70 111 115 85
1020 As-rolled 450 65 330 48 36.0 59 143 87 64Normalized at 870°C (1600 oF) 440 64 345 50 35.8 68 131 118 87Annealed at 870 °C (1600 oF) 395 57 295 43 36.5 66 111 123 91
1022 As-rolled 505 73 360 52 35.0 67 149 81 60Normalized at 925°C (1700 oF) 485 70 360 52 34.0 68 143 117 87Annealed at 870 °C (1600 oF) 450 65 315 46 35.0 64 137 121 89
1030 As-rolled 550 80 345 50 32.0 57 179 75 55Normalizedat925 °C (1700 oF) 525 76 345 50 32.0 61 149 94 69Annealed at 845°C (1550 oF) 460 67 345 50 31.2 58 126 69 51
1040 As-rolled 620 90 415 60 25.0 50 201 49 36Normalized at 900 °C (1650 oF) 595 86 370 54 28.0 55 170 65 48Annealed at 790°C (1450 oF) 520 75 350 51 30.2 57 149 45 33
1050 As-rolled 725 105 415 60 20.0 40 229 31 23Normalized at 900 °C (1650 oF) 750 109 430 62 20.0 39 217 27 20Annealed at 790°C (1450 oF) 635 92 365 53 23.7 40 187 18 13
1060 As-rolled 815 118 485 70 17.0 34 241 18 13Normalized at 900 °C (1650 oF) 775 113 420 61 18.0 37 229 14 10Annealed at 790°C (1450 "P) 625 91 370 54 22.5 38 179 11 8
1080 As-rolled 965 140 585 85 12.0 17 293 7 5Normalized at 900 °C (1650 oF) 1015 147 525 76 11.0 21 293 7 5Annealed at 790°C (1450 oF) 615 89 380 55 24.7 45 174 7 5
1095 As-rolled 965 140 570 83 9.0 18 293 4 3Normalized at 900 °C (1650 oF) 1015 147 505 73 9.5 14 293 5 4Annealed at 790°C (1450 oF) 655 95 380 55 13.0 21 192 3 2
1117 As-rolled 490 71 305 44 33.0 63 143 81 60Normalized at 900 °C (1650 oF) 470 68 305 44 33.5 54 137 85 63Annealed at 860°C (1575 oF) 430 62 285 41 32.8 58 121 94 69
1118 As-rolled 525 76 315 46 32.0 70 149 109 80Normalized at 925 °C (1700 oF) 475 69 315 46 33.5 66 143 103 76Annealed at 790°C (1450 oF) 450 65 285 41 34.5 67 131 107 79
1137 As-rolled 625 91 380 55 28.0 61 192 83 61Normalized at 900 °C (1650 oF) 670 97 400 58 22.5 49 197 64 47Annealed at 790°C (1450 "P) 585 85 345 50 26.8 54 174 50 37
(continued)
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Carbon Steels (1000,1100,1200, and 1500 Series) /131
Properties of Selected Carbon Steels in the Hot-Rolled, Normalized, and Annealed Conditions (continued)
hod impactAISI Tensile strength Yield strength Reduction Hardness, strengthgrade(a) Condition or treatment MPa ksi MPa ksi Elongation(b), % in area, % HB J ft ·lbf
1141 As-rolled 675 98 360 52 22.0 38 192 11 8Normalized at 900°C(1650 oF) 710 103 405 59 22.7 56 201 53 39Annealedat 815°C(1500 oF) 600 87 355 51 25.5 49 163 34 25
1144 As-rolled 705 102 420 61 21.0 41 212 53 39Normalized at 900°C(1650 oF) 670 97 400 58 21.0 40 197 43 32Annealed at 790°C(1450 oF) 585 85 345 50 24.8 41 167 65 48
(a) All grades arefine grained except for those in the 1100 series, which are coarse grained. (b) In 50nunor 2 in.
Effect of Mass on Hardness of Normalized Carbon andAlloy Steels
Grade
Normalizingtemperature
°C OF
Hardness, HB, for barwith diameter, mm (in.), of
13(lh) 25(1) 50(2) 100(4)
Carbon steels, carburizing grades
1015 925 1700 126 121 116 1161020 925 1700 131 131 126 1211022 925 1700 143 143 137 1311117 900 1650 143 137 137 1261118 925 1700 156 143 137 131
Carbon steels, direct-hardening grades
1030 925 1700 156 149 137 1371040 900 1650 183 170 167 1671050 900 1650 223 217 212 2011060 900 1650 229 229 223 2231080 900 1650 293 293 285 2691095 900 1650 302 293 269 2551137 900 1650 201 197 197 1921141 900 1650 207 201 201 2011144 900 1650 201 197 192 192
Note: All data arebased on single heats.
Approximate Critical Temperatures for Selected Carbon Steels
Critical temperatures on heating at 28 °C/h (50°F/h) Critical temperatures on cooling at28 °Cfh (50°F/h)Ac. Ac, Ar) Ar.
Steel °C OF °C OF °C OF °C OF
1010 725 1335 875 1610 850 1560 680 12601020 725 1335 845 1555 815 1500 680 12601030 725 1335 815 1495 790 1450 675 12501040 725 1335 795 1460 755 1395 670 12401050 725 1335 770 1415 740 1365 680 12601060 725 1335 745 1375 725 1340 685 12651070 725 1335 730 1350 710 1310 690 12751080 730 1345 735 1355 700 1290 695 1280
132/ Heat Treater's Guide
Recommended Temperatures and Cooling Cycles for Full Annealing of Small Carbon Steel ForgingsData are for forgings up to 75 mm (3 in.) in section thickness. Time at temperature usually is a minimum of 1 h for sections up to 25 mm (1 in.)thick; %h is added for each additional 25mm (1 in.) of thickness.
Cooling cycle(a)Annealing temperature °C of Hardness
Steel °C of From To From To range,HB
1018 855-900 1575-1650 855 705 1575 1300 111-1491020 855-900 1575-1650 855 700 1575 1290 111-1491022 855-900 1575-1650 855 700 1575 1290 111-1491025 855-900 1575-1650 855 700 1575 1290 111-1871030 845-885 1550-1625 845 650 1550 1200 126-1971035 845-885 1550-1625 845 650 1550 1200 137-2071040 790-870 1450-1600 790 650 1450 1200 137-2071045 790-870 1450-1600 790 650 1450 1200 156-2171050 790-870 1450-1600 790 650 1450 1200 156-2171060 790-845 1450-1550 790 650 1450 1200 156-2171070 790-845 1450-1550 790 650 1450 1200 167-2291080 790-845 1450-1550 790 650 1450 1200 167-2291090 790'830 1450-1525 790 650 1450 1200 167-2291095 790-830 1450-1525 790 655 1450 1215 167-229
(a) Furnace cooling at 28 °CIb (50 °FIb)
Approximate Grossmann Quenching Severity Factor ofVarious Media in the Pearlite Temperature Range
Circulationor agitation
Grossmann quench severity factor, HBrine Water Oil and salt Air
NoneMildModerateGoodStrongViolent
22-2.2
5
0.9-1.01.0-1.11.2-1.31.4-1.51.6-2.0
4
0.25-0.300.30-0.350.35-0.400.4-0.50.5-0.80.8-1.1
0.02
Grossmann Numbers and Film Coefficients for Selected Quenchants
GrossmannQuenchant temperature Quenchant velocity number, Effective mm coefficient
Quenchant °C OF mls ft/min (H=hl2k) w/m2 · K Btu/ft2. h . OF
Water 32 90 0.00 0 1.1 5000 8800.25 50 2.1 9000 16000.51 100 2.7 12000 21000.76 150 2.8 12000 2100
55 130 0.00 0 0.2 1000 1800.25 50 0.6 2500 4400.51 100 1.5 6500 11000.76 150 2.4 10500 1850
Fast oil 60 140 0.00 0 0.5 2000 3500.25 50 1.0 4500 7900.51 100 1.1 5000 8800.76 150 1.5 6500 1200
25% polyvinyl pyrrolidone 43 110 0.00 0 0.8 3500 6200.25 50 1.3 6000 11000.51 100 1.5 6500 12000.76 150 1.8 7500 1300
Conventional oil 65 150 0.51 100 0.7 3000 530Martempering oil 150 300 0.51 100 1.2 5000 880Air 27 80 0.00 0 0.05 200 35
2.54 500 0.06 250 445.08 1000 0.08 350 62
Carbon Steels (1000,1100,1200, and 1500 Series)/133
Comparison of the Cooling Power of Commercially Available Quenching and Martempering Oils According toMagnetic Quenchometer Test Results
Types of quenching oil
Conventional
Fast
Martempering, without speed improvers
Martempering, with speed improvers
Quenching duration from 885°C (1625 oF)Viscosity to 355°C (670 oF), sat400C At 27°C (80 oF) At 120°C (2S0 oF)
Oil (100°F) Flash point Chromized Chromizedsample SUS (a) °C of Ni-ball Ni-ball Ni-ball Ni-ball
1 102 190 375 22.5 27.22 105 195 380 17.8 27.93 107 170 340 16.0 24.84 50 145 290 7.0 (a)5 94 170 335 9.0 15.06 107 190 375 10.8 17.07 110 185 370 12.7 19.68 120 190 375 13.3 17.89 329 235 455 19.2 27.6 18.4 22.1
10 719 245 475 26.9 29.0 25.1 30.411 2550 300 575 31.0 32.0 31.7 32.812 337 230 450 15.3 (b) 12.8 (b)13 713 245 475 16.4 17.9 14.0 15.614 2450 300 570 19.7 17.0 15.1 15.4
(a) SUS, Saybolt universal seconds. (b) Not available
Comparison of the Ranges of Cooling Power of Commercially Available Quenching and Martempering Oils Accordingto Magnetic Quenchometer Test Results using Pure Nickel Balls
Quenching duration from 88S °C (1625 oF) to 355°C (670 oF)
Type of quenching oilAt 120 °C At175°C(2S0 oF) (3S0 oF)
ConventionalFastMartempering, without speed improversMartempering, with speed improvers
14-227-1418-3414-20
14-227-1418-3413-18
22-3816-22
=47=33
Typical Hardnesses of Various Carbon Steels after Tempering
Carbon Hardness, HRC, after tempering for 2 h atcontent, 20SoC 260°C 31SoC 370°C 42SoC 480°C 540°C 595°C 650°C
Grade % (400°F) (SOO°F) (600°F) (700°F) (800°F) (900°F) (1000 oF) (1100 oF) (1200 oF) Heat treatment
Carbon steels, water hardening
1030 0.30 50 45 43 39 31 28 25 22 95(a) Normalized at 900 °C (1650 "F), water quenchedfrom 830-845 °C (1525-1550 oF); average dewpoint, 16°C (60 oF)
1040 0.40 51 48 46 42 37 30 27 22 94(a)1050 0.50 52 50 46 44 40 37 31 29 221060 0.60 56 55 50 42 38 37 35 33 26 Normalized at 885°C (1625 "F), water quenched
from 800-815 °C (1475-1500 "F); average dewpoint, 7 °C (45 oF)
1080 0.80 57 55 50 43 41 40 39 38 321095 0.95 58 57 52 47 43 42 41 40 331137 0.40 44 42 40 37 33 30 27 21 91(a) Normalized at 900 °C (1650 "F), water quenched
from 830-855 °C (1525-1575 "F); average dewpoint, 13 °C (55 oF)
1141 0.40 49 46 43 41 38 34 28 23 94(a)1144 0.40 55 50 47 45 39 32 29 25 97(a)
Data were obtained on 25 mrn (l in.) bars adequately quenched to develop full hardness. (a) Hardness, HRB
134/ Heat Treater's Guide
Carbon Steels: Typical Austempering ApplicationsParts listed in order of increasing section thickness
Maximum sectionthickness Parts per unit weight Salt temperature Immersion Hardness,
Part Steel mm in. kg-I lb-I °C of time, min HRC
Plain carbon steel parts
Clevis 1050 0.75 0.030 770fkg 350lIb 360 680 15 42Follower ann 1050 0.75 0.030 412fkg 187IIb 355 675 15 42Spring 1080 0.79 0.031 220fkg 100lIb 330 625 15 48Plate 1060 0.81 0.032 88fkg 40/lb 330 630 6 45-50Cam lever 1065 1.0 0.040 62fkg 28IIb 370 700 15 42Plate 1050 1.0 0.040 0.5 kg 1!.1lb 360 675 15 42Type bar 1065 1.0 0.040 141fkg 64IIb 370 700 15 42Tabulator stop 1065 1.22 0.048 440fkg 200lIb 360 680 15 45Lever 1050 1.25 0.050 345 650 15 45-50Chain link 1050 1.5 0.060 573fkg 260lIb 345 650 15 45Shoe-last link 1065 1.5 0.060 86fkg 39/1b 290 550 30 52Shoe-toe cap 1070 1.5 0.060 18fkg 8IIb 315 600 60 50Lawn mower 1065 3.18 0.125 1.5 kg 2!:llb 315 600 15 50
bladeLever 1075 3.18 0.125 24fkg 1lI1b 385 725 5 30-35Fastener 1060 6.35 0.250 110fkg 50/lb 310 590 25 50Stabilizer bar 1090 19 0.750 22 kg 10Ib 370 700 6-9 40-45Boron steel bolt lOB20 6.35 0.250 100fkg 45IIb 420 790 5 38-43
Typical Operating Conditions for Through Hardening Carbon Steel Parts by Induction Process
Total Work temperature InductorSection size Frequency(a), Power(b), heating Scan time Entering coil Leaving coil Production rate input(c)
mm in. Material Hz kW time,s slcm s/in. °C OF °C OF kg/h lb/h kW/cm2 kW/in.2
Rounds
19 % 1035 mod 180 28.5 68.4 0.71 1.8 75 165 620 1150 113 250 0.062 0.409600 20.6 28.8 0.71 1.8 620 1150 955 1750 113 250 0.085 0.55
25 1041 180 33 98.8 1.02 2.6 70 160 620 1150 141 311 0.054 0.359600 19.5 44.2 1.02 2.6 620 1150 955 1750 141 311 0.057 0.37
29 11;8 1041 180 36 114 1.18 3.0 75 165 620 1150 153 338 0.053 0.349600 19.1 51 1.18 3.0 620 1150 955 1750 153 338 0.050 0.32
Flats
16 % 1038 3000 300 11.3 0.59 1.5 20 70 870 1600 1449 3194 0.361 2.3319 % 1038 3000 332 15 0.79 2.0 20 70 870 1600 1576 3474 0.319 2.0622 7/s 1043 3000 336 28.5 1.50 3.8 20 70 870 1600 1609 3548 0.206 1.3325 1 1036 3000 304 26.3 1.38 3.5 20 70 870 1600 1595 3517 0.225 1.4529 11;8 1036 3000 344 36.0 1.89 4.8 20 70 870 1600 1678 3701 0.208 1.34
Irregular shapes
17.5-33 11/16_151)6 1037mod 3000 580 254 0.94 2.4 20 70 885 1625 2211 4875 0.040 0.26
(a) Note use of dual frequencies for round sections. (b) Power transmitted by the inductor at the operating frequency indicated. This power is approximately 25% less than the powerinput to the machine. because of losses within the machine. (c) At the operating frequency of the inductor
Carbon Steels (1000, 1100, 1200, and 1500 Series)/135
Operating and Production Data for Progressive Induction Tempering
VVorktemperatureTotal Entering Leaving Production Inductor
Section size Frequency, Power(a), heating Scan time coil coil rate input(b)mm in. Material Hz kVV time,s s/cm s/in. °C OF °C OF kg/h Ib/h kVV/cm1 kVV/in.1
Rounds
19 % 1035mod 9600 12.7 30.6 0.71 1.8 50 120 510 950 113 250 0.050 0.3225 1 1041 9600 18.7 44.2 1.02 2.6 50 120 565 1050 141 311 0.054 0.3529 11/s 1041 9600 20.6 51 1.18 3.0 50 120 565 1050 153 338 0.053 0.34
Flats16 % 1038 60 88 123 0.59 1.5 40 100 290 550 1449 3194 0.014 0.08919 % 1038 60 100 164 0.79 2.0 40 100 315 600 1576 3474 0.013 0.08122 7/8 1043 60 98 312 1.50 3.8 40 100 290 550 1609 3548 0.008 0.05025 1 1043 60 85 254 1.22 3.1 40 100 290 550 1365 3009 0.011 0.06829 IVs 1043 60 90 328 1.57 4.0 40 100 290 550 1483 3269 0.009 0.060
Irregular shapes17.5-33 11/16- 15/16 1037mod 9600 192 64.8 0.94 2.4 65 150 550 1020 2211 4875 0.043 0.2817.5-29 11/16- 1'Is 1037mod 9600 154 46 0.67 1.7 65 150 425 800 2276 5019 0.040 0.26
(a) Power transmittedby the inductorat theoperatingfrequencyindicated.For convertedfrequencies. thispoweris approximately 25% less than the powerinput to themachine.becauseoflosses within themachine.(b)At theoperatingfrequencyof theinductor
1062: Spot Flame Hardening of a Free-Wheel Cam
Preliminary operation
Turn on water,air, oxygen,power,andpropane. Linepressures: water,205kPa(30psi); air, 550kPa (80psi);oxygen,825kPa (120psi);propane,205kPa (30psij.Ignitepilots.
Loading and positioning
Mountcamonflamehead.Campositioned onlocatingplateand twowearpads,andagainstthree locatingpins thatareintegralpartsofflamehead.Distancefromflamehead to camsurface,approximately 7.9mm e!J6 in.)
Cycle start and heating cycle
Propaneandoxygensolenoidvalvesopen(oxygenflow delayedslightly). Mixtureofpropaneandoxygenignitedatflameheadsby pilots.Checkpropaneandoxygenpressures.Adjustflamebyregulatingpropane. Heatingcyclecontrolledbytimer. Timepredetermined toobtainspecifiedhardening depth.Propaneandoxygensolenoidvalvesclose(propaneflowdelayedslightly). Ejectorplate (air operated) advancesand stripscamfromflamehead.
Propaneregulatedpressure, 125kPa (18psi);oxygenregulatedpressure, 585kPa (85psi);oxygenupstreampressure, 425kPa(62psi);oxygendownstream pressure, 110kPa (16psi).Flamevelocity(approximate), 135mls (450ft/s). Gasconsumption (approximate): propane,0.01m3(0.4ft3) perpiece;oxygen.0.04m3 (1.3 ft3) perpiece.Totalheatingtime, II s
Flame portdesign:nineportsperrow; eightrows;portsize,No.69 (0.74mm,or0.0292in.),withNo.56 (1.2mm,or0.0465in.)counterbore
Quench cycle
Cam dropsintoquenchoil,is removedfromtankby conveyor. Oil temperature, 54±5.6 °C (130± 10"F), Timein oil (approximate), 30s
Hardness and pattern aim
Hardness, 60HRCminimumatsurfaceand59HRCminimum at adepthof 1.3mm(0.050in.)belowsurface,for widthof8.8 mm (0.345in.)oncamrollersurface.Dimensionsbelowgivenininches
Depth of pattern,0.050 min for 0.345
o.o".",i~o.~
Hardness pattern
136/ Heat Treater's Guide
Flame Hardening Response of Carbon Steels Gas Carburizing: Carburizing Steel Compositions
MaterialTypical hardness, HRC, as affected by quenchant
Air(a) Oil(b) Water (b) Steel C MnComposition, %
Ni Cr Mo Other
52-5850-60 58-6255-62 58-62
45-55 52-57(c)50-55 55-60
Plain carbon steels
1025-10351040-10501055-10751080-1095I125-I137I138-I144I146-I151
Carburized grades of plain carbon steels(d)
1010-1020 50-60 58-62II 08-I120 50-60 60-63
33-5055-6060-6362-6545-5555-6258-64
62-6562-65
Carbon steels
1010 0.08-0.13 0.30-0.601018 0.15-0.20 0.60-0.901019 0.15-0.20 0.70-1.001020 0.18-0.23 0.30-0.601021 0.18-0.23 0.60-0.901022 0.18-0.23 0.70-1.001524 0.19-0.25 1.35-1.651527 0.22-0.29 1.20-1.50
Resulfurized steels
III7 0.14-0.20 1.00-1.30
(a), (b)(a), (b)(a), (b)(a), (b)(a), (b)(a), (b)(a), (b)(a), (b)
0.08-0.13 S
(a)Toobtain the hardness results indicated, those areas not directlyheated must be keptrelatively cool during the heating process. (b) Thin sections are susceptible to crackingwhen quenched with oil or water. (c) Hardness is slightly lower for material heated byspinning or combination progressive-spinning methods than it is for material heated byprogressive or stationary methods. (d) Hardness values of carburized cases containing0.90 to I.l0% C
(a) 0.04Pmax. 0.05 S max. (b) 0.15-0.35 Si
Effect of Cyaniding Temperatures and Time on Case Depth and Carbon and Nitrogen ContentsMaterial thickness, 2.03 mm (0.080 in.); cyanide content of bath, 20 to 30%
Case depth after cyaniding for: Analysis after 100 min at15 min 100 min temperature(a)
Steel mm in. mm in. Carbon, % Nitrogen, %
Cyanided at 760.oC (1400 oF)
1008 0.038 0.0015 0.152 0.006 0.68 0.511010 0.038 0.0015 0.152 0.006 0.70 0.501022 0.051 0.0020 0.203 0.008 0.72 0.51
Cyanided at 845°C (1550 oF)
1008 0.076 0.0030 0.203 0.008 0.75 0.261010 0.076 0.0030 0.203 0.008 0.77 0.281022 0.089 0.0035 0.254 0.010 0.79 0.27
(a) Carbon and nitrogen contents were determined from analysis of the outermost 0.076 nun (0.003 in.) of cyanided cases.
Carbon Steels (1000, 1100,1200, and 1500 Series)/137
Liquid Carburizing Carbon Steels in Cyanide BathsTypical application of carbon steel and resulfurized steel
Weight Depth ofcase Temperature SubsequentPart kg lb Steel mm in. °C of Time,h Quench treatment Hardness, HRC
Carbon steel
Adapter 0.9 2 CR 1.0 0.040 940 1720 4 AC (a) 62-63Arbor, tapered 0.5 1.1 1020 1.5 0.060 940 1720 6.5 AC (a) 62-63Bushing 0.7 1.5 CR 1.5 0.060 940 1720 6.5 AC (a) 62-63Die block 3.5 7.7 1020 1.3 0.050 940 1720 5 AC (a) 62-63
1.1 2.5 CR 1.3 0.050 940 1720 5 AC (a) 59-61Disk 1.4 3 1020 1.3 0.050 940 1720 5 (b) (b) 56-57Flange 0.Q3 0.06 1020 0.4-0.5 0.015-0.020 845 1550 4 Oil (c) 55min(d)Gage rings, knurled 0.09 0.2 1020 1.5 0.060 940 1720 6.5 AC (a) 62-63Hold-down block 0.9 2 CR 1.0 0.040 940 1720 4 AC (a) 62-63Insert, tapered 4.75 10.5 1020 1.3 0.050 940 1720 5 AC (a) 62-63Lever 0.05 0.12 1020 0.13-0.25 0.005-0.010 845 1550 1 Oil (c) (e)Link 0.007 0.015 1018 0.13-0.25 0.005-0.010 845 1550 1 ACPlate 0.007 0.015 1010 0.25-0.4 0.010-0.015 845 1550 2 Oil (c) (e)Plug 0.7 1.6 CR 1.5 0.060 940 1720 6.5 AC (a) 62-63Plug gage 0.45 1 1020 1.5 0.060 940 1720 6.5 AC (a) 62-63Radius-cutoutroll 7.7 17 CR 1.5 0.060 940 1720 6.5 AC (a) 62-63Torsion-bar cap 0.05 0.1 1022 0.02-0.05 0.001-0.002 900 1650 0.12 Caustic (f) 45-47
Resulfurized steel
Bushing 0.04 0.09 1118 0.25-0.4 0.010-0.015 845 1550 2 Oil (c) (e)Dash sleeve 3.6 8 1117 1.1 0.Q45 915 1675 7 AC (g) 58-63Disk 0.0009 0.002 1118 0.13-0.25 0.005-0.010 845 1550 1 Brine (c) (e)Driveshaft 3.6 8 1117 1.1 0.Q45 915 1675 7 AC (h) 58-63Guide bushing 0.2 0.5 1117 0.75 0.030 915 1675 5 (i) 58-63Nut 0.04 0.09 1113 0.13-0.25 0.005-0.010 845 1550 1 Oil (c) (e)Pin 0.003 0.007 1119 0.13-0.25 0.005-0.010 845 1550 1 Oil (c) (e)Plug 0.007 0.015 1113 0.075-0.13 0.003-0.005 845 1550 0.5 Oil (c) (e)Rack 0.34 0.75 1113 0.13-0.25 0.005-0.010 845 1550 1 Oil (c) (e)Roller 0.01 0.03 1118 0.25-0.4 0.010-0.015 845 1550 2 Oil (c) (e)Screw 0.003 0.007 1113 0.Q75-0.13 0.003-0.005 845 1550 0.5 Oil (c) (e)Shaft 0.08 0.18 1118 0.25-0.4 0.010-0.015 845 1550 2 Oil (c) (e)Spring seat 0.009 0.02 1118 0.25-0.4 0.010-0.015 845 1550 2 Oil (c) (e)Stopcollar 0.9 2 1117 1.1 0.045 925 1700 6.5 AC (g) 60-63Stud 0.007 0.015 1118 0.13-0.25 0.005-0.010 845 1550 1 Oil (c) (e)Valve bushing 0.02 0.05 1117 1.3 0.050 915 1675 8 AC (g) 58-63Valve retainer 0.45 1 1117 1.1 0.045 915 1675 7 (i) 58-63Washer 0.007 0.015 1118 0.25-0.4 0.010-0.015 845 1550 2 Oil (c) (e)
(a) Reheated at 790°C (1450 "F), quenched in caustic, tempered at 150 °C (300 "F), (b) Transferred to neutral salt at 790°C (1450 "F), quenched in caustic, tempered at 175°C (350oF). (c) Tempered at 165 °C (325 oF). (d) Or equivalent. (e) File-hard. (f) Tempered at 205°C (400 oF). (g) Reheated at 845 °C (1550 oF), quenched in salt at 175°C (350 oF). (h)Reheated at 775 °C (1425 "F), quenched in salt at 195°C (380 oF). (i) Tempered at 165°C (325 "P) and treated at-85°C (-120 "F)
Liquid Carburizing Carbon Steels in Noncyanide BathsTypical applications of carbon steels
Weight Case depth Temperature Subsequent Hardness,Part kg lb Steel mm in. °C OF Time,h Quench treatment HRC
Production tools 0.5-2.0 1.1-4.4 1018 0.375 0.015 925 1700 0.5-1.0 Brine 50-60Bicycle forks 1.4 3.1 10l7(a) 0.05-0.08 0.002-0.003 925 1700 0.085 Brine Temper at 425°C 60
(795 oF)Shift lever and ball -1.5 -3.3 1040,1017(b) 0.25 0.010 925 1700 0.67 Air cool 30 s in brine File hardClock screws and studs 0.005 0.011 1006,1113 0.08-0.10 0.003-0.004 955 1750 0.2 Brine 62-64Flat head screws 0.015 0.033 1122 0.15 0.006 925 1700 0.33 Molten salt, 290°C 56
(550°F)
(a) Partial immersion. (b) Carburizer brass braze
138/ Heat Treater's Guide
Carbonitriding Carbon SteelsTypical applications and production cycles
Case depth Furnace temperature TotaItimePart Steel mm 0.001 in. °C of in furnace Quench
Carbon steels
Adjusting yoke. 25 by 9.5 nun (1 by 0.37 in.) 1020 0.05-0.15 2-6 775 and 745 1425 and 1375 64 min OilBearing block, 64 by 32 by 3.2 rnrn (2.5 by 1.3 by 0.13 in.) 1010 0.05-0.15 2-6 775 and 745 1425 and 1375 64 min OilCam, 2.3 by 57 by 64 nun (0.1 by 2.25 by 2.5 in.) 1010 0.38-0.45 15-18 855 1575 2 1/2h OilCup, 13 g (0.46 oz) 1015 0.08-0.13 3-5 790 1450 Y2 h OilDistributor drive shaft, 125 nun OD by 127 rnrn (5 by 5 in.) 1015 0.15-0.25 6-10 815 and 745 1500 and 1375 108 min Gas(a)Gear, 44.5 nun diarn by 3.2 nun (1.75 by 0.12S in.) 1213(b) 0.30-0.38 12-15 855 1575 l%h Oil(c)Hex nut, 60.3 by 9.5 nun (2.4 by 0.37 in.) 1030 0.15-0.25 6-10 815 and 745 1500 and 1375 64 min OilHood-latch bracket, 6.4 rnrn diarn (0.25 in.) 1015 0.05-0.15 2-6 775 and 745 1425 and 1375 64 min OilLink, 2 by 38 by 38 rnrn (0.079 by 1.5 by 1.5 in.) 1022 0.30-0.38 12-15 855 1575 11/2h OilMandrel, 40 g (1.41 oz) 1117 0.20-0.30 8-12 845 1550 lY2h OilPaper-cutting tool, 410 rnrn long 1117 -0.75 -30Segment, 2.3 by 44.5 by 44.5 mrn(0.09 by 1.75 by 1.75 in.) 1010 0.38-0.45 15-18 855 1575 2 1/2h OilShaft, 4.7 nun diam by 159 nun (0.19 by 6.25 in.) 1213(b) 0.30-0.38 12-15 815 1500 2Y2h Gas(a)(d)Shift collar, 59 g (2.1 oz) 1118 0.30-0.36 12-14 775 1430 SI/2h Oil(e)Sliding spur gear, 66.7 rnrn OD (2.625 in.) 1018 0.38-0.50 15-20 870 1600 2h(0 Oil(g)Spring pin, 14.3 mrnODby 114mm (0.56 by 4.5 in.) 1030 0.25-0.50 10-20 815 and 745 1500 and 1375 144min OilSpur pinion shaft, 41.3 mm OD (1.625 in.) 1018 0.38-0.50 15-20 870 1600 2h(0 0i1(h)Transmission shift fork, 127 by 76 mrn(5 by 3 in.) 1040 0.25-0.50 10-20 815 and 745 1500 and 1375 162 min Gas(a)
(a) Modified carbonitriding atmosphere. (b) Leaded. (c) Tempered at 190°C (375 "F), (d) Tempered at 150 °C (300 "F), (e) Tempered at 165°C (325 "F), (0 Time at temperature.(g) Oil at 150 °C (300 oF): tempered at 150°C (300 OF); for 1 h. (h) Oil at 150°C (300 oF); tempered at 260 °C (500 oF) for 1 h
Applications for Boride Carbon Steels
Substrate materialAISI BSI
10201043
11381042
DIN
S137
C15 (CkI5)C45
S150-145S20Ck45
Application
Bushes. bolts, nozzles, conveyer tubes, baseplates, runners, blades, thread guides
Gear drives, pump shaftsPins, guide rings. grinding disks. boltsCasting inserts, nozzles, handlesShaft protection sleeves, mandrelsSwirl elements, nozzles (for oil burners),
rollers, bolts, gate plates
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