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In 1909, an undergraduate, Ernest Marsden, was being trained by Dr. Hans Geiger. To quote Rutherford (in a lecture he gave much later):
"I had observed the scattering of alpha-particles, and Dr. Geiger in my laboratory had examined it in detail. He found, in thin pieces of heavy metal, that the scattering was usually small, of the order of one degree. One day Geiger came to me and said, "Don't you think that young Marsden, whom I am training in radioactive methods, ought to begin a small research?" Now I had thought that too, so I said, " Why not let him see if any alpha-particles can be scattered through a large angle?" I may tell you in confidence that I did not believe that they would be, since we knew the alpha-particle was a very fast, massive particle with a great deal of energy, and you could show that if the scattering was due to the accumulated effect of a number of small scatterings, the chance of an alpha-particle's being scattered backward was very small. Then I remember two or three days later Geiger coming to me in great excitement and saying, "We have been able to get some of the alpha-particles coming backward …" It was quite the most incredible event that ever happened to me in my life. It was almost as incredible as if you fired a 15-inch shell at a piece of tissue paper and it came back and hit you."
“Electrons are distributed uniformly within a continuous distribution of spherical positive charges, like plums in a Plum Pudding”
J.J. Thompson discovered electrons in 1897
Thompson’s Model: a sphere of positive charge embedded
with electrons
In 1898 Thompson proposed a model for the atom
10-10m
The positively charged matter accounts for the
neutrality of the atom, and for most of its mass
Rutherford decided to fire
alpha particles
at thin pieces of gold foil
in order
to investigate
Atomic Structure
particles are Helium nuclei and have a double positive
charge, He2+
What Rutherford Expected
The alpha particle projectiles were very fast, high energy, positively charged He nuclei. They should be only slightly deflected by gold atoms .
Rutherford expected all of the particles to be deflected just a bit as they passed through the
plum pudding, like a bullet being fired through a snow ball
particles, He2+
alpha source in lead box
lead collimator
light flash
(scintillation)
vacuum
thin Au foil
Rutherford’s Apparatus• Most particles passed straight through the gold foil• A small percentage were deviated through a small angle• 1 in 8000 were back scattered
zinc sulphide screen
microscope
Contrary to expectations, Rutherford found that a significantly large fraction (~1/8000) of the alpha particles “bounced back” in the same direction in which they came…The calculation, based on the plum-pudding model, was that fewer than
1/10 000 000 000 should do this !!!!!!
In Rutherford’s words…“It was quite the most incredible event that ever happened to me in my life. It was as if you fired a 15-inch naval shell at a piece of tissue paper and the shell came right back and hit you.”
GOSH !GOSH !
+
+
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+
+ + +
+
Atoms in gold foil most alpha particle pass
straight through
+ +
++
++ +
+
+
ALPHA PARTICLES ONLY FEEL A REPULSIVE FORCE WHEN THEY ARE CLOSE TO THE
NUCLEUS
THE (ONLY) INTERPRETATION
The atom must have a solid core capable of imparting large electric forces onto an
incoming charged particle.
From the angles of scatter, Rutherford deduced that an Inverse Square Law was operating
+ nucleus
Rutherford concludes in 1911:
1) Scattering of the alphas must be due to encounters with charged …atomic particles that are much smaller than the atom.
2) There must be some positive electric charges inside the atom to ….compensate for the negative charges of the electrons.
3) There must be something in the atom much heavier than an …electron to account for the mass of the atom.
4) Atoms must be mostly empty space.
5) Thus, an atom has a small central core (the nucleus) which …contains most of the mass of the atom, and carries a positive …electric charge. This charge attracts the negative electrons and …keeps them in orbit
Rutherford was able to calculate that the radius of the nucleus was about 1 x 10-15 m
The radius of an atom is about 1 x 10-10 m, so the atom’s radius is 100,000 times greater than the
radius of the nucleus.
1:101
000100
3434
153
3
3
3
3
nucleus
atom
nucleus
atom
nucleus
atom
r
r
r
r
V
V
Hence the nucleus is 1015 times denser than the atom itself, as virtually all of the atom’s mass resides within the nucleus.