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1 PHYSICAL AND CFD MODELS OF PM SEPARATION AND SCOUR IN HYDRODYNAMIC UNIT OPERATIONS By HWAN CHUL CHO A DISSERTATION PRESENTED TO THE GRADUATE SCHOOL OF THE UNIVERSITY OF FLORIDA IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY UNIVERSITY OF FLORIDA 2012

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Page 1: ufdcimages.uflib.ufl.edu...4 ACKNOWLEDGMENTS First and foremost, I express my deep appreciation to my advisor, Dr. John J. Sansalone, who gave me the best chance to …

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PHYSICAL AND CFD MODELS OF PM SEPARATION AND SCOUR IN

HYDRODYNAMIC UNIT OPERATIONS

By

HWAN CHUL CHO

A DISSERTATION PRESENTED TO THE GRADUATE SCHOOL

OF THE UNIVERSITY OF FLORIDA IN PARTIAL FULFILLMENT

OF THE REQUIREMENTS FOR THE DEGREE OF

DOCTOR OF PHILOSOPHY

UNIVERSITY OF FLORIDA

2012

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© 2012 Hwan Chul Cho

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To my parents who always stand behind me, supporting me,

and believing there is nothing that I cannot achieve,

and to everyone who has encouraged and

supported me to achieve a Ph.D.

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ACKNOWLEDGMENTS

First and foremost, I express my deep appreciation to my advisor, Dr. John J. Sansalone,

who gave me the best chance to work in this great academic area. He has consistently guided,

encouraged and supported me throughout the journey to my Ph.D. program. His patient

elucidation, enlightening ideas and precious comments have contributed a lot to my

understanding of this research area and shaping my concept of scientist and engineer. It was and

will be great fortune and enormous inspiration for me in my life.

I also extend my sincere appreciation to the distinguish professors on my committee: Dr.

Ben Koopman, Dr. James Heaney, and Dr. Jennifer Curtis. I am also very grateful to my

committee members for their helpful advice on the dissertation work.

I express my thanks to my colleagues: Dr. Jong-Yeop Kim, Dr. Natalie Magill-Winberry,

Dr. Gaoxiang Ying, Dr. Christian Berretta, Dr. Joshua Dickenson, Dr. Ruben Kertesz and Dr.

Tingting Wu, who shared me with their knowledge and helpful discussion. My appreciation also

extends to my colleagues including, Mr. Karl Seltzer, Ms. Christina Herr-Joiner, Mr. Adam

Marquez, Ms. Valarie Thorsen, Ms. Aniela Burant, Mr. Gregory Brenner, Ms. Sowmya Sankaran,

Mr. Saurabh Raje, Ms. Giuseppina Garofalo, Dr. Young-min Cho, Dr. Se-jin Youn, Dr. Myung-

heui Woo and Mr. Rascal Cho for their valuable assistance and help. Their friendships have been

one of my important accomplishments in the past five years.

I would like to express my special and warmest thanks to my best friend, Dr. Subbu-

Srikanth Pathapati, for not only his enormous help, but also his sincere friendship.

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TABLE OF CONTENTS

page

ACKNOWLEDGMENTS ...............................................................................................................4

LIST OF TABLES ...........................................................................................................................8

LIST OF FIGURES .........................................................................................................................9

LIST OF ABBREVIATIONS ........................................................................................................11

ABSTRACT ...................................................................................................................................16

CHAPTER

1 INTRODUCTION ..................................................................................................................18

2 PHYSICAL MODELING OF PARTICULATE MATTER WASHOUT FROM A

HYDRODYNAMIC SEPARATOR .......................................................................................22

Overview .................................................................................................................................22

Methodology ...........................................................................................................................24

Physical Model Configuration .........................................................................................24

Flow Velocity Measurement ...........................................................................................25

Pre-deposited PM ............................................................................................................25

RTD Test ..................................................................................................................26

Scour Thresholds ......................................................................................................28

Results.....................................................................................................................................29

In-Situ Velocity Profiles ..................................................................................................29

Washout PM Granulometry .....................................................................................30

Residence Time Distributions (RTDs) .....................................................................31

Densimetric Froude Number ....................................................................................32

Time Rate of Washout ..............................................................................................33

Initiation of Scour ............................................................................................................34

Summary .................................................................................................................................38

3 PHYSICAL AND CFD MODELING OF PM SEPARATION AND SCOUR IN

HYDRODYNAMIC SEPARATORS ....................................................................................53

Overview .................................................................................................................................53

Objectives ...............................................................................................................................56

Methodology ...........................................................................................................................56

Physical Clarification and Re-suspension Function Modeling .......................................56

CFD Modeling .................................................................................................................59

CFD Governing Equations ..............................................................................................59

Particulate Phase Modeling .............................................................................................61

Re-suspension and Washout Modeling ...........................................................................63

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Numerical Procedure .......................................................................................................63

Volumetric Efficiency Calculation ..................................................................................63

Results.....................................................................................................................................64

Comparison Physical and CFD Modeling .......................................................................64

Physical Modeling of Separation and washout Function ................................................64

PSD Result .......................................................................................................................66

PM Dynamics ..................................................................................................................68

Fluid Velocity Magnitude ................................................................................................69

Probability of PM Separation and Washout ....................................................................70

Summary .................................................................................................................................71

4 STEPWISE STEADY CFD MODELING OF UNSTEADY FLOW AND PM

LOADING TO UNIT OPERATIONS ...................................................................................82

Overview .................................................................................................................................82

Objectives ...............................................................................................................................84

Methodology ...........................................................................................................................84

Watershed and Three Hydrodynamic Separator Configurations .....................................84

Physical Modeling Methodology ....................................................................................85

CFD Modeling Methodology ..........................................................................................86

Particulate Phase Modeling .............................................................................................89

Modeling of Static Screen and Cartridge ........................................................................90

CFD Parameters ...............................................................................................................91

Stepwise Step Modeling Removal and PM Separation ...................................................91

Result ......................................................................................................................................93

Event Hydrology Indices .................................................................................................93

Probabilities of PM Separation by the BHS, SHS, and VCF ..........................................95

Stepwise Steps Comparison to Measured Data ...............................................................96

Summary .................................................................................................................................98

5 REMOVAL AND PARTITIONING OF NITROGEN AND PHOSPHORUS OF

NUTRIENTS IN HYDRODYNAMIC SEPARATOR ON URBAN RAINFALL-

RUNOFF PARTICULATE MATTER GENERATED FROM IMPERVIOUS

SURFACE CARPARK ........................................................................................................111

Overview ...............................................................................................................................111

Objectives .............................................................................................................................112

Methodology .........................................................................................................................113

Catchment ......................................................................................................................113

Data Acquisition, Management, and Sampling .............................................................113

PM Separation ...............................................................................................................114

Water Chemistry Analysis .............................................................................................115

Nitrogen and Phosphorus Analysis ...............................................................................115

Partitioning Indices for Nitrogen and Phosphorus ........................................................116

Hydrologic and Loading Parameters .............................................................................117

Analysis of Recovered Sediment Deposit from Hydrodynamic Separator ...................117

Results...................................................................................................................................117

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Event Hydrology ...........................................................................................................117

Overall Treatment Efficiency of BHS as a Function of Hydrology ..............................118

PM fraction and PM-based N and P fraction masses distribution .................................119

Event based Nitrogen and Phosphorus Loadings ..........................................................119

Nutrients Removal Efficiency as a function of Hydrology ...........................................120

Nutrients Partitioning ....................................................................................................121

Nutrient from the Recovered Sediment Deposit ...........................................................123

Summary ...............................................................................................................................125

6 CONCLUSION.....................................................................................................................139

APPENDIX

A CHAPTER 3. PHYSICAL AND CFD MODELING OF PM SEPARATION AND

SCOUR IN HYDRODYNAMIC SEPARATORS ...............................................................142

B CHAPTER 4. STEPWISE STEADY CFD MODELING OF UNSTEADY FLOW AND

PM LOADING TO UNIT OPERATIONS ...........................................................................146

LIST OF REFERENCES .............................................................................................................159

BIOGRAPHICAL SKETCH .......................................................................................................169

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LIST OF TABLES

Table page

2-1 Medianwashout rate and effluent mass load as a function of flow rates. SM is sandy

silt in the Unified Soil Classification System (USCS). SM I is a SCS 75, SM II is a

SCS 106, and SM III is NJDEP gradation .........................................................................40

2-2 d10, d50, d90 for effluent SM I, SM II, and SM III as a function of flow rates. ...................41

2-3 d10, d50, d90 for pre-deposited PM. .....................................................................................42

2-4 The summary of RTD tests as a function of flow rate.Qd is hydraulic design flow

rate for baffled HS. Flow beyond 100% Qd over flows inlet weir and is not treated. .......43

3-1 Summary of measured and modeled separation and washout function result with

RPD. ...................................................................................................................................73

4-1 Hydrologic indices across storm events for BHS, SHS, and VCF. .................................101

4-2 CFD model comparisons to measured data across storm events for BHS, SHS, and

VCF. .................................................................................................................................102

4-3 CFD parameters for BHS, SHS, and VCF. ......................................................................103

5-1 Hydrologic characterization of the 10 rainfall-runoff events monitored between May

24, 2010 and August 21, 2010 in Gainesville, FL ...........................................................126

5-2 Summary of EMCs and ΔMass for total dissolved nitrogen (TDN), total nitrogen

(TN), total dissolved phosphorus (TDP), and total phosphorus (TP). .............................127

5-3 Summary of event mean value and range of variation of the dissolved fraction (fd)

and partition coefficient (Kd) of nitrogen and phosphorus for influent and effluent

runoff................................................................................................................................128

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LIST OF FIGURES

Figure page

2-1 A plan view schematic of the baffled HS testing facility, across-sectional profile of

the HS, and PSDs for pre-deposited PM. ...........................................................................44

2-2 Velocity as a function of ADV height at (A) location in baffled HS and the mean

flow velocity in the baffled HS as a function of flow rate and SOR.. ...............................45

2-3 Effluent PSDs for the range of flow rates as a function of flow rate. Gamma

parameters as a function of surface overflow rate. Design SOR = 464.5 L/min-m2. ........46

2-4 The relationships between turbidity and SORand PND as a function of SOR. The

relationships between turbidity and effluent PM and PND.. .............................................47

2-5 Median washout rate (g/min) and ti / τ as a function of surface overflow rate. Each

linear relationship in plot A and B as a function of SOR has a R2 ≥ 0.97. ........................48

2-6 Effluent PM as a function of densimetric Froude number, flow rates, and SOR.R2 is

0.96 for SM I, 0.96 for SM II, and 0.97 for SM III as a function of Froude number. .......49

2-7 Effluent mass load range of flow rates as a function of time normalized to maximum

duration. Washoff model parameters as a function of surface overflow rate. ...................50

2-8 Measured and modeled washout rate in g/minas a function of time normalized to

maximum duration and volume normalized to 7.6 turnover volume.................................51

2-9 Shield’s parameters for SM I, SM II, and SM III as a function of particle Reynolds

number. (u* is shear velocity, and v is kinematic viscosity of water). ...............................52

3-1 Modeled PSD plots of treated and washout PM from BHS, VHS, and SHS. ...................74

3-2 Plots of measured and modeled Δ mass and washout rate at constant SOR for BHS,

VHS, and SHS units. ..........................................................................................................75

3-3 Effluent PM trajectories inside the BHS, VHS, and SHS for particle with diameters

of 25 μm, 106 μm, and 300 μm, respectively. Particle density (ρp) is 2.65 g/cm3.............76

3-4 Washed out PM trajectories inside the BHS, VHS, and SHS for particle with

diameters of 10 μm, 25 μm, and 75 μm. Particle density (ρp) is 2.65 g/cm3. ....................77

3-5 Fluid velocity magnitude as a function of flow rates in BHS, VHS, and SHS. .................78

3-6 Probability of PM separation and washout by the BHS, VHS, and SHS. .........................79

3-7 Gamma parameters as a function of flow rates for BHS, VHS, and SHS (Qd for BHS

is 9.1 L/s, Qd for VHS is 79.3 L/s, and Qd for SHS is 31.2 L/s). .......................................80

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3-8 Volumetric efficiency (VE) as a function of flow rates in BHS, VHS, and SHS. .............81

4-1 Plot A is a plan view schematic of a BHS testing watershed in Gainesville, FL. Plot

B is a plan view schematic of SHS and MFS testing watershed in Baton Rouge, LA. ...104

4-2 Isometric views of the geometries of unit operations. .....................................................105

4-3 Probability of PM separation by unit operations. γ and β represent shape factor and

scaling factor. ...................................................................................................................106

4-4 A) is a CDF for the range of rainfall-runoff flow rate (L/s) in BHS. B) is flow rates

(L/s) and effluent PM mass (g) as a function of elapsed time in BHS.. ..........................107

4-5 A) is a CDF for the range of rainfall-runoff flow rate (L/s) in SHS. B) is flow rates

(L/s) and effluent PM mass (g) as a function of elapsed time in SHS.. ...........................108

4-6 A) is a CDF for the range of rainfall-runoff flow rate (L/s) in VCF. B) is flow rates

(L/s) and effluent PM mass (g) as a function of elapsed time in VCF.. ..........................109

4-7 Mean and variation of the stepwise steady model absolute RPD for BHS, SHS, and

VCF. The lower right quartile box plot is the variation of absolute RPDs. ....................110

5-1 Profile section of 1.21 m diameter BHS deployed for physical modeling loaded by

urban source area catchment. ...........................................................................................129

5-2 PM fraction and PM-based N and P fraction masses distribution within each

monitored rainfall-runoff event........................................................................................130

5-3 Separation for TN, and TP in different fractions as a function of PM fractions. Range

bars represent standard deviation. ....................................................................................131

5-4 Phosphorus mass concentration distributions for each PM fractions. ............................132

5-5 Nitrogen mass concentration distributions for each PM fractions. ..................................133

5-6 fd values and equilibrium coefficient, Kd values of nitrogen and phosphorus in

influent and effluent.. .......................................................................................................134

5-7 Granulometric equilibrium distribution of ammonium-nitrogen, nitrate-nitrogen,

TKN, phosphate and TP. ..................................................................................................135

5-8 The fd of influent and effluent TN (TP) as a function of cumulative treated rainfall-

runoff volume...................................................................................................................136

5-9 The cumulative gamma distribution parameters (ɤ for shape factor and β for scaling

factor) for event-based normalized particle size distributions (PSD)... ...........................137

5-10 Cumulative influent and effluent mass of PM, phosphorus (P), and nitrogen (N)

through the entire monitoring campaign for BHS in Gainesville, FL. ............................138

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LIST OF ABBREVIATIONS

ADM Axial Dispersion Model

ADV Acoustic Doppler Velocimetry

AOCMP Monodispersed AL-Ox Coated Granular Media

BHS Baffled Hydrodynamic Separator

BMP Best Management Practices

CDF Cumulative Density Function

CFD Computational Fluid Dynamics

COD Chemical Oxygen Demand

CSO Combined Sewer Overflows

CV Control Volume

D.O Dissolved Oxygen

DPM Discrete Particle Modeling

EMC Event Mean Concentration

FVM Finite Volume Method

HS Hydrodynamic Separator

ICP-MS Inductively Coupled Plasma – Mass Spectrometry

IPRT Initial Pavement Residence Time

MBE Mass balance Error

MS4 Municipal Separate Storm Sewer System

N Nitrogen

NJDEP New Jersey Department of Environment Protection

P Phosphorus

PAH Polycyclic Aromatic Hydrocarbon

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PDH Previous Dry Hours

PLC Programmable Logic Controller

PM Particulate Matter

PSD Particle Size Distribution

QA Quality Assurance

QC Quality Control

RANS Reynolds Averaged Navier-Stokes

RCF Radial Cartridge Filter

RPD Relative Percent Difference

RTD Residence Time Distribution

SHS Screened Hydrodynamic Separator

SIMPLE Semi-Implicit Method for Pressure Linked Equation

SOR Surface Overflow Rate

SM Non-Cohesive Sandy Silt

SSC Susupended Sediment Concentration

SSE Sum of Squared Errors

SWMM Storm Water Management Model

TDN Total Dissolved Nitrogen

TDP Total Dissolved Phosphorus

TDS Total Dissolved Solid

TISM Tanks in Series model

TKN Total Kjehldahl Nitrogen

TN Total Nitrogen

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TP Total Phosphorus

TSS Total Suspended Solid

UOPs Unit Operations and Processes

USCS Unified Soil Classification System

VCF Volumetric Clarifying Filtration

VE Volumetric Efficiency

VHS Vortex Hydrodynamic Separator

drain Rainfall Depth

irain-max Maximum Rainfall Intensity

ninf Number of Influent Samples

neff Number of Effluent Samples

Qd Hydraulic Design Flow Rate

Qmed Median Flow Rate

Qp Peak Flow Rate

ti The time at which tracer initially appears

tp The time at which peak concentration is observed

train Rainfall Runoff Duration

tt Theoretical residence time

t50 The time at which 50 % of tracer had passed through the reactor

t90 The time at which 90 % of tracer had passed through the reactor

MDI Morrill Dispersion Index

1 / MDI Volumetric Efficiency

ti/tt Index of short-circuiting

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tp /tt Index of modal retention time

t50/tt Index of average retention time

(t50)/(t50-tp) Hazen’s N

σ2 The variance

tΔmean Mean detention time based on discrete time step measurements, T

Ci Concentration at ith measurement, ML-3

Δti Time increment about Ci, T

σ2Δc Variance based on discrete time measurements, T

2

d Diameter of the soil particle

ρs Mass density of the soil

d Diameter of the soil particle

g Acceleration due to gravity

φ Angle of friction of the soil

SS Specific gravity of soil

*u The shear velocity

Shields parameter

Vrunoff Volume of Runoff

Cd Dissolved fraction concentration

Cp Particulate-bound fraction concentration

Cs Particulate-bound mass (mg/g of dry particulate mass)

fd Dissolved fraction

fp Particulate-bound fraction

Kd Partitioning coefficient

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Md Dissolved mass

Mp Particulate-bound mass

MS Normalized Cumulative Mass Loading for PM

MTN Normalized Cumulative Mass Loading for Total Nitrogen

MTP Normalized Cumulative Mass Loading for Total Phosphorus

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Abstract of Dissertation Presented to the Graduate School

of the University of Florida in Partial Fulfillment of the

Requirements for the Degree of Doctor of Philosophy

PHYSICAL AND CFD MODELS OF PM SEPARATION AND SCOUR IN

HYDRODYNAMIC UNIT OPERATIONS

By

Hwan Chul Cho

May 2012

Chair: John J. Sansalone

Major: Environmental Engineering Sciences

A hydrodynamic separator (HS) is commonly used as a preliminary unit operation for

separation of particulate matter (PM) and PM-associated constituents transported by urban

rainfall-runoff. Advantages of HS units are passivity, small treatment footprint, ease of

retrofitting into existing sewer or treatment system infrastructure, efficacy for neutrally-buoyant

substances and detritus, low head loss, and capacity for hydraulic bypass beyond a given flow

rate. Although the small footprint of an HS is advantageous for integration into sewer (storm or

combined) or drainage systems, it also concentrates flow energy. In many HS units where PM

sludge is not isolated or in units not maintained (cleaned) frequently, washout of previously

separated PM sludge can result in short periods of net export of PM.

The purpose of this study was to increase understanding of the hydrodynamic and

clarification response of best management practices (BMPs) for urban rainfall-runoff

management. Four types of unit operations were investigated by means of a coupled

experimental and numerical approach. Additionally, this study investigates PM washout from

three HS units as a function of steady flow rates and particle size distributions (PSDs), using a

computational fluid dynamics (CFD) modeling framework for “scour” assessment. CFD is a

branch of fluid mechanics that uses numerical methods to integrate the Navier-Stokes equations

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to solve fluid flow problems. Four types of full-scale HS units were modeled in 3D using

FLUENT v 6.0. A finite volume method (FVM) was applied to discretize the governing

equations into the physical space directly. Modeling in 3-D is less susceptible to the

complications from the lack of geometric symmetry, complex static screen geometry, vortex

flow and gravitational forces on the motion of particles in unit operations. Post-processing the

CFD predictions provided insight into the mechanistic behavior of the HS by means of three

dimensional hydraulic profiles, particle trajectories and pressure distributions. A stepwise steady

flow model effectively predicts the monitored storm events data in UOPs.

This study examines the inter- and the intra- event nitrogen and phosphorus removal as a

function of particle size, hydrology and partitioning for an urban carpark, treated by unit

operations with significant biogenic loadings.

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CHAPTER 1

INTRODUCTION

Impervious surface area and urban runoff can impair receiving waters. Many sources of

PM, nutrients (N, and P), metals, and anthropogenic chemicals are present and exposed to

rainfall-runoff in urban areas (Lee and Bang 2000). PM is a significant vehicle in the transport of

these constituents by urban runoff (Sansalone 2002). PM delivered by rainfall-runoff varies

temporally within a storm event and across storm events and can vary spatially within the same

watershed (Sansalone 2002). Hydrodynamic separators (HS) are commonly used urban unit

operations to remove oil and inorganic materials including PM in urban stormwater runoff and

combined sewer overflows (CSOs) (Brombach 1987, Brombach et al. 1993, Pisano et al. 1994,

USEPA 1999, Andoh and Saul 2003). In North America there are over 50,000 HS operating HS

units. The advantages of HS are that they are passive devices, often have a small footprint, and

can be easily retrofitted to existing infrastructure. However, many of these systems are left

unattended for long stretches of time (e.g., a minimum range of 1 to 47 days between rainfall

events in Gainesville, FL). An estimation of long term performance of detention basins has been

derived by storm water management model (SWMM) simulation (Nix et al. 1988). Minimizing

scour from a HS was recently added to the essential elements of best management practices

(BMPs) design (EPA 2004). Therefore, management of scour from HS is a challenge that need to

be addressed.

Sediment transport and re-suspension has been widely studied by many researchers,

however, most of research has focused on sediment re-suspension and transport mechanisms for

open channel flow (Cellino and Lemmin 2004, Gargett et al. 2004, Orlins, and Gulliver, 2003)

not in a HS. There is a need to quantify scour in a baffled HS (BHS) to provide designers with an

understanding of scour as function of particle diameter, and flow rates. In this study, a series of

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scour tests was performed on BHS with two different sediment pre-loaded conditions with

particle size distributions (PSDs) defined prior to testing across six flow rates representing 25 %

(0.91 L/s) to 125 %(11.31 L/s) of the maximum hydraulic operating flow rate (Q) or design flow

rate (Qd) of the unit tested. The tests are conducted under steady flow regimes, to better

distinguish the effects of different pre-loaded PM and flow rates.

Residence time distribution (RTD) testing is conducted to characterize the flow mixing

behavior in a baffled HS. The experimental RTD testing is performed with pulse input method.

The flow rate (Q), and the geometry of a HS influences the flow mixing behavior of a HS. A

primary component of this study is a comparison of multi-phase physical modeling to CFD

modeling of HS. CFD approaches are increasingly utilized to model particle-laden flows (Curtis

et al. 2004; van Wachem et al. 2003). CFD can predict fluid flow, mass transfer, chemical

reactions, and related phenomena by solving governing fluid equations using numerical methods.

CFD modeling has been used for describing the behavior of rainfall-runoff unit operations and

processes (UOPs) (Pathapati and Sansalone 2009).

In urban stormwater, CFD has enhanced the modeling of PM separation for transient

flows (Sansalone and Pathapati 2009; Garofalo and Sansalone 2011) and heterodisperse particle

size distributions (Dickenson and Sansalone 2009) as well as re-entrainment of PM by scouring

mechanisms (Pathapati and Sansalone 2012). However, a 3-D numerical model to simulate the

transient hydrodynamics with variable PSDs needs longer computational time than a model

simulating steady state flow (Pathapati and Sansalone 2011). The unsteady computational time

for the hydrodynamic separator (HS) is approximately 3±0.5 days using a workstation equipped

with dual quad-core 2.6 GHz processors and 32 GB of random access memory (Pathapati and

Sansalone 2011). Stepwise step flow modeling can be used to reduce computational time.

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Stepwise steady CFD modeling utilizes a series of discretized steady flow steps of rainfall-runoff

events. Identifying numbers of stepwise flow steps is necessary to ensure efficient use of

computational time.

Excessive phosphorus loading to natural waters has been known for decades to accelerate

eutrophication and lead to decline in water quality of rivers, lakes and oceans (Weon et al. 2002).

In urban rainfall-runoff, phosphorus partitions from PM into dissolved phases. Rainfall-runoff

characteristics, including water chemistry, unit residence time, and unsteady loading, dictate the

partitioning of phosphorus and nitrogen. Additionally, oxidation-reduction, mixing, particulate

composition and particulate bound concentration gradients can affect the extent of partitioning of

phosphorus and metals (Sansalone and Buchberger 1997). PM-based phosphorus distributes

across the PSDs (Ma et al. 2010). Particulate-bound phosphorus is distributed across sediment (>

75 μm), settleable (25 ~ 75 μm) and suspended (< 25 μm) fractions. Phosphorus predominantly

found in urban rainfall runoff is associated with particles greater than 75 µm (Sansalone et al.

1998). Physical unit operations typically only target the particulate bound fraction of phosphorus

(Barrett et al. 1998, Bartone and Uchrin 1999, Comings et al. 2000, Dechesne et al. 2005). For

this reason, the phosphorus control in physical unit operations may be ineffective without

knowledge of the partitioning. Phosphorus partitioning is important not only to understand

phosphorus fate and transport, but also to select appropriate unit operation in the watershed.

Elevated nitrogen is ubiquitous in urban watersheds (Hopkinson and Vallino 1995).

Nitrate-nitrogen leaching from biogenic material is a source of contamination of surface and

groundwater (Broschat 1995, Ku and Hershey1997). Total nitrogen in runoff is associated with

dissolved and particulate phases as well as biogenic material. Nutrient uptake is greatly

influenced by environmental variables such as water availability and temperature (Marschner

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21

1995). Characterization of nitrogen in urban runoff is necessary not only for improving treatment

strategies for nitrogen reduction, and but also for identifying viable treatment.

This dissertation focuses on the examination of scour, PM separation mechanisms,

partitioning of nitrogen and phosphorus, and behavior of a BHS to separate PM, nitrogen and

phosphorus. The performance of a BHS is evaluated and studied by controlled and uncontrolled

physical models. Models are subjected to steady conditions with regulated PSD gradation and

actual rainfall-runoff treatment under stepwise steady step conditions as well as CFD modeling.

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CHAPTER 2

PHYSICAL MODELING OF PARTICULATE MATTER WASHOUT FROM A

HYDRODYNAMIC SEPARATOR1

Overview

Particulate matter (PM) serves as a vehicle for the transport of chemicals, acting as a

substrate to which chemicals reversibly partition (Berretta and Sansalone 2011a; Brezonik 2002;

Dean 2005). Beyond being a substrate for chemicals, PM also impacts the turbidity and oxygen

demand of receiving waters (Sansalone 2002, Shinya et al. 2000). Screened hydrodynamic

separator (HS) units are commonly used as preliminary unit operations for publicly-owned-

treatment-works (POTWs), followed by primary clarification (sedimentation) and filtration. For

baffled HS units, PM is separated by settling, although the original design intent was primarily

for oil and grease separation (OGS). Historically, screened forms of HS units have been applied

to preliminary and high-rate treatment of combined sewer overflows (CSOs) (Brombach et al.,

1987; Brombach et al.; 1993; Pisano et al., 1994; USEPA 1999; Andoh et al., 2003). Advantages

of HS units are passivity, small treatment footprint, ease of retrofitting into existing sewer or

treatment system infrastructure, efficacy for neutrally-buoyant substances and detritus, low head

loss, and capacity for hydraulic bypass beyond a given flow rate. Nonetheless, commensurate

with these advantages are disadvantages. For instance, while a small footprint provides economy

and integration into standard drainage structures, the limited spatial footprint and volume results

in concentration of hydraulic energy, short residence times and limited PM separation whether

for Type I (discrete) or II (flocculent) settling. One challenge associated with HS units is the

need for frequent maintenance (cleaning) so that, as an HS collects PM, the unit neither functions

1 Re-printed with permission from Cho, H., and Sansalone, J.J., (2012), Physical modeling of particulate matter

washout from a hydrodynamic separator, Journal of Environmental Engineering

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23

as a source of PM and chemicals through washout, nor generates anaerobic conditions in the

stored PM sludge (USEPA 2002, Sansalone et al. 2010).

There has been a long history of scour research, with a specific interest in bridge

foundation scour under the influence of flood flows, the study of which dates back over a half

century (Shields 1936; Vanoni 1946). More recently, there have been questions regarding the

applicability of approaches such as Shields scour diagram across different flows regimes

(Buffington 1999). Although HS units are subject to open-channel flow, they are small footprint

units subject to highly unsteady flows, high velocities and complex intra-unit hydrodynamics.

Because these units are infrequently (on the order of once a year) maintained (Sansalone and

Pathapati 2009) high fluid velocities at the PM sludge interface generate scour and washout.

Hence, there is a need to characterize these phenomena. In this study, PM washout is specifically

examined through controlled physical modeling supported by PM, flow and velocity monitoring.

Velocity monitoring uses Acoustic Doppler Velocimetry (ADV) to measure fluid velocities and

vectors (Kraus et al. 1994; Lohrman et al.1994;Voulgaris et al. 1998). In addition, residence time

distribution (RTD) curves are used to characterize the hydrodynamic behavior of systems

operating at steady flow (Fernandez-Semprere 1994). The RTD methodology is well-

documented and therefore not reproduced herein (Levenspiel 1962; Froment and Bischoff 1979;

Smith 1981; Denbigh and Turner 1984; Fogler 1992; Westerterp et al. 1993).

In this study, physical model load-response experiments are performed on a full-scale

baffled HS subject to the following conditions: (1) pre-deposited PM of differing PSDs and (2)

differing steady flow rates representing 10 % (0.91 L/s) to 125 % (11.31 L/s) of the maximum

design flow rate (Qd). For the HS unit, washout is hypothesized to be a function of the PSD of

the pre-loaded PM and of the flow rate (or SOR) at a given PM deposit (sludge) depth. In order

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to test this hypothesis, data, including effluent PM and PSDs, velocity profiles in the HS and

RTDs, are determined at each flow rate and for each batch of pre-loaded PM. It is hypothesized

that washout of the pre-loaded PM can be explained using these data to illustrate effluent PM

load generated from previously settled PM deposited in the HS. It is further hypothesized that

effluent PM concentration is a function of the densimetric Froude number and SOR for each

PSD. These results are contrasted with the open-channel approach using the Shields’ criterion.

Methodology

Physical Model Configuration

A schematic of the HS component of the physical model system is presented in Figure 2-

1 along with the HS profile view. While the HS unit was initially developed as a

commercial/industrial OGS unit, (hence the inverted horizontal baffle design), for over a decade

the baffled HS has primarily served as a small urban watershed settling unit for PM (USEPA

1999). In this controlled physical model study the source influent for each model run is potable

water (PM < 0.1 mg/L as suspended sediment concentration (SSC) turbidity <0.3 NTU and 20°

C ± 2°C) stored in two 45 m3 tanks. The flow delivery system consists of two centrifugal pumps

(19 L/s – 3 HP and 75.6 L/s– 10 HP). The flow monitoring system consists of dual monitoring

meters in parallel, an electromagnetic meter for flows from 1 to 272 L/s and a volumetric flow

meter for flow from 0.1 L/s to 10 L/s. The diameter of the baffled HS is 1.22 m.

The distance from the bottom of the HS lower chamber to the invert of the HS outlet is

1.52 m (Hmax). The surface area of the unit is 1.17 m2. At the design flow rate, one unit volume

(one turnover volume) is approximately 1780 L. The inlet and outlet diameters are 0.2 m each.

The design flow rate (Qd) is 9.05 L/s, which is observed to represents 90% of the hydraulic

capacity of the unit (defined as the flow rate at which bypass over the overflow weir begins).

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Flow Velocity Measurement

All ADV-based velocity measurements are taken within the HS. The velocity

measurements are monitored using a 10 MHz-ADV (velocity range: 1 mm/s – 2.5 m/s)

(Sontek/YSI). The velocity determination is based on the Doppler shift principle, which is

implemented with a bistatic (focal point) acoustic Doppler system and consists of a transmitter

and three receivers (Voulgaris 1998). The ADV is a multi-function (sound emitter, sound

receiver, and signal conditioning electronic module) water velocity monitoring device for

precise, in-situ measurement of velocity.

Fluid velocities are measured at 10 locations in the HS. In a horizontal plane at the water-

PM bed interface, (0.17Hmax; Hmax = 1.52 m), there are seven measurement points. In addition,

velocity measurements are made at the center of the unit, location (A) at 3 different heights

(0.34, 0.50, and 0.67Hmax). A schematic of the velocity measurement locations is shown in

Figure 2-1A. Fluid velocity is measured at each flow rate during the washout and RTD runs.

Pre-deposited PM

Three hetero-disperse and non-cohesive sandy silts (SM) are utilized in three series of

separate but equivalent testing conditions to examine HS washout. The Unified Soil

Classification System (USCS) is utilized for textural classification of each gradation of PM

(Coduto 1999). The mass-based PSDs of the pre-loaded PM are measured utilizing wet

dispersion laser diffraction based on the principle of Mie small-angle light scattering and

diffraction due to the presence of particles between the laser emitter and detector (Finlayson-Pitts

and Pitts 2000). Diffraction patterns are dependent on particle sizes, with larger scattering angles

associated with smaller size particles. Although the siliceous silts are sub-rounded, Mie theory

applies not only to spherical but also non-spherical particles (Jonasz 1991). Scattering patterns

are utilized to determine the % volume of particle sizes of the PSD through an optical method in

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26

which the detectors and windows are integral parts of the measurement zone. The particle

analyzer used is a Malvern Mastersizer with a measurement range of ~0.02 to 2000 μm. The

three PM gradations are designated as SM I, SM II and SM III, with a d50m of 15 μm, 22 μm and

67 μm, respectively. PM gradations are generated from standard gradations available from U.S.

Silica.

As part of the testing matrix summarized in Table 2-1, PM washout testing is performed at

0.91 (10), 2.26 (25), 4.78 (50), 6.79 (75), 9.05 (100), and 11.31 L/s (125% of Qd). Each washout

run is conducted by first pluviating PM across the entire surface area (1.17 m2) of the HS bottom

chamber to a level depth of 0.17Hmax. The HS is then filled with water at a flow rate of less than

0.5 L/s to avoid any flow scouring of the PM bed. Since HS units store runoff between runoff

events, runs are conducted with the HS unit filled with water to the outflow invert. Flow is

diverted around the HS until a steady-state flow is achieved. Once flow is directed into the HS,

sampling is initiated and discrete 1L samples are manually taken in duplicate at equal volume

sampling intervals, calculated based on flow rate and time. Run duration is chosen such that

approximately 7 volumetric turnovers are achieved (each HS volume is 1.78 m3). Ten duplicate

samples are collected for PSD and PM analysis (as SSC). Studies have demonstrated that SSC is

a representative gravimetric index for hetero-disperse PSDs, which include sand-size or coarser

PM (Gray et al. 2000). SSC analysis is carried out by filtering the entire volume of each replicate

through a nominal 1.0 μm filter (ASTM 1999; Ying and Sansalone 2008).

RTD Test

The RTD quantifies the hydrodynamic characteristics of a unit operation at a given flow

rate (Fogler 1992). In this study, the friction velocity at the water-PM interface (0.17Hmax)

generated at a given flow rate is indexed by the SOR of the HS unit. The RTD of the baffled HS

is determined by using NaCl as non-reactive tracer and measuring conductivity as a function of

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flow rate and time. A concentrated NaCl solution is injected as a pulse input. The RTD analysis

time is approximately 3-4 times the theoretical mean residence time (Nauman and Buffham

1983). Effluent conductivity is monitored with a calibrated conductivity probe (600 OMS-O)

manufactured by YSI Inc. Each tracer test is validated by a mass balance check with the error

tolerance set at ± 5% by mass. The inert tracer (NaCl: 200 g/500 mL) is prepared in 1-L

polypropylene (PP) bottle, and injected in the influent drop box as a single pulse. The tracer

concentration is measured at the effluent pipe for each fully-developed flow rate from 2.26 to

11.31 L/s. The conductivity probe is fully submerged at the outfall of the effluent pipe.

Conductivity measurements are taken at 1 second intervals. The mean residence time is defined

as follows (Hazen 1904; Tchobanoglous et al. 2003):

0

0

)(

)(

dttC

dttCttmean (2-1)

The RTD function E(t) is related to the concentration, C(t) while the cumulative RTD

curve is designated as the F curve. E(t) and F(t) are expressed as follows.

0)(

)()(

dttC

tCtE (2-2)

t

tEtF0

)()( (2-3)

The following RTD indices are reported in this study: tt,, the theoretical residence time,

(defined as tt = V/Q, where V is the volume of the HS unit, and Q is the flow through the system);

the Morrill dispersion index (MDI := t90/t10, where tx is the time at which x% of the tracer had

eluted from the HS); 1/MDI, the ‘volumetric efficiency’; tΔmean, the mean detention time based

on discrete time steps and Hazen’s N; N = (t50)/(t50-tp) (Levenspiel 1972; Letterman 1999), an

index of short-circuiting used for overflow models (Magill and Sansalone 2010); and tp, the time

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at which peak concentration is observed. The values of tx (x=10, 50, 90, etc) and tp are obtained

from measured tracer data. The mass balance error with respect to the mass of tracer injected was

± 5 %. The variance of tracer concentration as a function of time is approximated as follows.

(2-4)

In this expression, σ2

c is the variance and is based on discrete time measurements (T2); ti

is the time at which tracer initially appears.

Scour Thresholds

The applicability of the Shields approach to scour thresholds in the HS unit and

commensurate PM washout is tested in this study. Scour of non-cohesive PM at the water-PM

deposit interface is induced when the effective vertical and lateral confining stresses acting on

PM at this interface are less than the shear stress generated by the flow at this interface

(Annandale 2006). Common parameters to estimate PM transport capacity include the critical

shear stress, shear stress, and shear velocity. The critical shear stress, (τc) needed to generate the

incipient motion of a particle is expressed as follows (Beheshti and Ataie-Ashtiani 2008).

tan)(3

2 sc gd (2-5)

In this expression, d is particle diameter, ρs is mass density of PM or soil, g is acceleration

due to gravity, and is the internal angle of friction of the PM or soil. Peck (1974) determined

a range of 29 < < 41 for very loose to very densely packed non-cohesive sediment. The critical

shear stress cannot be predicted directly from a Shields curve and requires an iterative procedure.

(Beheshti and Ataie-Ashtiani 2008). Shear stress can be defined based on the shear velocity.

2

*u (2-6)

2

2

2)( m e a n

ii

iii

c ttC

tCt

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/* u is the shear velocity. The Shields parameter, , which is widely used to predict

the initiation of particle motion, is not measured directly but rather derived from shear stress and

velocity. When τ = τc, the shear stress is expressed in dimensionless form as the Shields

parameter.

gdS

u

s )1(

2

*

(2-7)

In this expression, Ss is the relative viscosity (=γs/γ, where γs is the sediment viscosity

[ML-1T-1]; γ is the water viscosity [ML-1T-1]); and g is the acceleration due to gravity [L/T2].

Scour occurs when the dimensionless shear stress τ0 is larger than θ.

Results

In-Situ Velocity Profiles

Tables 2-1 and 2-2 summarize the physical model conditions and the results of 18

washout experiments performed on the baffled HS with SM I, SM II and SM III pre-loaded PM

deposits. As illustrated in Figure 2-2, the flow velocities in the HS range from 0.7 to 44.6 mm/s

for all locations, depths and flow rates. Spatial symmetry does not consistently translate into

velocity profile symmetry. For example, when comparing symmetric locations (D) and (E) or (F)

and (G) in Figure 2-1A, the velocity profiles are not symmetric. However, there is an

approximately linear relationship between flow rate and mean velocity at each spatial location

and at each depth along the central axis of the HS. Maximum velocities consistently occur near

the effluent drop pipe which is located between locations (B) and (C) in Figure 2-1. Given the

requirements of continuity and the smaller 102 mm diameter of the effluent drop-pipe, higher

velocities are expected due to the pressure increase at the effluent drop-pipe. Based on the spatial

distribution of these velocities with a minimum mean velocity occurring at (A), all further

velocity measurements are performed with the ADV fixed at location (A) for each depth.

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Washout PM Granulometry

The granulometry of eluted PM is represented as mass-based PSDs, particle number

density (PND), turbidity and PM measured as SSC. Washout response of the HS is examined as

a function of SOR and pre-deposited PM gradation based on measured effluent PSDs. The PSD

results in Figure 2-3 indicate that PM washout is predominately fine PM for all gradations of pre-

deposited PM. Upon converting the PSD into a mass distribution, the effluent mass-based d50m

ranged from 0.8 to 1.0 μm for SM I, from 1.2 to 3.1 μm for SM II, and from 5.0 μm to 15.0 μm

for SM III for the range of flow rates tested in Figure 2-2. Higher flow rates generate consistently

higher values of d50m for all gradations. In Figures 2-3A, C, and E, the mass-based PSDs are

plotted. These graphs take the form of a two-parameter gamma distribution. The probability

density function of a gamma distribution is given by the following expression.

)(

)(

)(

1

x

ex

xg (2-8)

In this expression, Γ is the gamma function; γ is the shape factor and β is the scaling

factor. Below, G(x) is the cumulative gamma distribution and x represents particle diameter.

x

dxxgxG0

)()( (2-9)

Representation of PM size scale is through the scaling parameter, β, while the

representation of the shape (hetero-dispersivity or decreasing uniformity of the size) of the PSD

is parameterized by the shape parameter, γ. These parameters are displayed as a function of SOR

in Figures 2-3B, D and F for each eluted PSD. Figures 2-3B, D and F illustrate an increasing γ

which indicates a finer PSD at a constant β; whereas an increasing β indicates a coarser PSD at

constant γ. The increased uniformity of the eluted PSD as compared to the heterogeneity of the

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pre-deposited PM gradation.. The shape parameter remains relatively constant across the range

of SORs in particular for the coarser hetero-disperse PM, SM III. In contrast, the scaling

parameters for the eluted PSDs generated from the much finer and nominally more uniform SM I

and II remain essentially constant and equal. The β values are up to an order of magnitude lower

than for the eluted PM generated from SM III.

As seen in Figures 2-4A and C the phenomenon of turbidity, which is primarily generated

by fine PM, displays linear trends with SOR. These trends are unique for each pre-deposited

gradation. Figure 2-4 also illustrates the linear relationship between effluent PM as a gravimetric

concentration and turbidity. The results in Figures 2-4B and D do not illustrate distinctly

different linear relationships for SM I and II due to the primary influence of eluted fine PM on

concentration and turbidity. In contrast, while the eluted PND and turbidity are also linearly

related for SM III as shown in Figure 2-4B and D this coarser and hetero-disperse gradation

produces an elution with lower PND and turbidity.

Residence Time Distributions (RTDs)

Table 2-3 illustrates the RTD indices of the HS as a function of flow rates. At lower flow

rates the low volumetric efficiency values indicate that the entire HS volume is not utilized. For a

given HS unit size the flow rate (or SOR) is seen to be a primary factor in determining washout

behavior of the HS unit. SOR is calculated as follows.

A

QSORrateoverflowSurface )( (2-10)

In this expression Q (L3/T) is flow rate and A (L

2) is the surface area. Ideal discrete

settling theory (Tchobonaglous et al. 2003) suggests that if a particle has a settling velocity

greater than the SOR, then the particle is separated as in a clarification basin. PM separation is

calculated as follows.

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dxQ

AuXseparatedPM

CX p

C 0

)1( (2-11)

The first term on the right of this expression represents the mass fraction of particles with

settling velocity (up) greater than SOR and the second term represents the mass fraction of

particles with settling velocity (up) less than Q/A. SOR was used as an index which allows a

direct comparison to Type I (discrete) settling velocities.

Measured residence times are lower than theoretical residence times for flow rates lower

than the design flow rate (9.05 L/s), and higher than theoretical residence times for flow rates

higher than the design flow rate. At lower flow rates, volumetric zones of the HS are not

mobilized, while at higher flow rates these “dead zones” are mobilized. Table 2-3 provides

indices such as σ2/ tt

2 and volumetric efficiency based on MDI, t50/tt, and the modal retention

time index tp/tt. Measured and theoretical residence times did not differ significantly at the design

flow rate of 9.05 L/s, suggesting that at the design flow these zones are mobilized.

Figure 2-5 illustrates the median washout rate and short circuiting index as a function of

SOR. Median washout rates increase linearly with increasing SOR for each of the PM

gradations. Figure 2-5A illustrates that SM I, the finest gradation, has the highest median

washout rate of the three gradations. The index of short circuiting, ti/tt also increases linearly with

increasing SOR, similarly to the behavior of the median washout rate. With increasing SOR

there is higher washout rate from the HS as the volume at the PM-water interface is increasingly

mobilized.

Densimetric Froude Number

Previous research (Aguirre-Pe et al. 2003) has suggested using a modified form of the

Froude number, the densimetric Froude number, to relate flow characteristics to scour (in this

case washout). The densimetric Froude number as a function of PM diameter is useful as an

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independent variable in predicting the washout, as shown in Figure 2-6. This Froude number

relates flow velocity to the PSD granulometric and gravimetric characteristics as follows:

2/1

50 ])1[( mgds

VFr

(2-12)

In this expression, s is the specific gravity, d50m is from the effluent PM and V is the flow

velocity in the baffled HS. The flow velocity, V, in the baffled HS is measured using ADV. To

evaluate sedimentation for a particle subject to Type I settling, SOR as a function of PM size is a

commonly used design index parameter for wastewater and stormwater detention/retention

basins. SOR has units of velocity (L/T). The upward overflow velocity is compared with the

nominal downward velocity of each particle size to determine sedimentation.

Time Rate of Washout

As the flow ranged from 10 to 125% of Qd, the median SSC eluted ranged from 8.2 mg/L

to 20.6 mg/L for SM I, from 7.3 mg/L to 13.2 mg/L for SM II, and from 2.0 mg/L to 10.4 mg/L

for SM III. For SM I at a flow of 0.1Qd, the eluted SSC increased by 13% as compared to SM II

and by 310% as compared to SM III. The effluent d50 values summarized in Table 2-2 illustrate

that the eluted PM was dominated by PM in the suspended range. Figure 2-7 shows that mass

washout decreases exponentially with time. For each gradation, the net-eluted mass approaches a

low asymptotic equilibrium value after approximately 0.7(t/tmax), which equates to approximately

9500 L or 5.3 turnover volumes for this unit. The initial exponential decline lasting up to

0.4(t/tmax) is likely a result of scouring the pre-deposited non-cohesive PM interface where the

effective confining stress is essentially zero and there is negligible interlocking between

particles. As a saturated non-cohesive bed, the primary source of shear strength is frictional and

the surface layer does not benefit from a confining stress. There is a clear dependence of the

initial washout magnitude on the corresponding magnitude of the influent flow rate. However,

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irrespective of the flow rate and PM gradation, a first-order exponential washout model similar

to that employed by Sartor and Boyd (1974), Alley (1981), and Alley and Smith (1981) for

washoff of PM from pavement by runoff is observed. Analogous to these washoff models where

PM availability is not limiting, the evolution of washout can be expressed as follows.

n

ktn

n

dtemM0

0

0

(2-13)

In this expression, t is the effluent sampling time (min); M is the mass load (g); m0 is M

for the initial washout rate (g/min), and k is inverse washout time scale (1/min). The mass and

rate of washout are modeled by this equation. Eluted mass rates as a function of volume are

shown in Figure 2-8 for each flow rate.

Initiation of Scour

The resolution of the ADV utilized in this study ranged from 1 mm/s to 2.5 m/s. Fluid

velocities were measured at a level within 5 mm of the sediment surface, providing an

approximation of the velocity at the water-PM interface that induced shear. To account for

fluctuations of velocities at each measurement location all velocities were obtained as a mean of

seven equally distributed locations across the area of the HS at a given level as shown in Figure

2-1. In addition, at each location, velocities in the x, y and z direction were recorded in triplicate

at 1 second intervals, for each steady flow rate, for run times ranging from a minimum of 20

minutes to a maximum of 100 minutes. The open volume encompassed by the three small legs of

the ADV is approximately 3000 mm3. The impact of the ADV legs and cable on the flow field

were assumed to be negligible as the HS volume is much larger (1.78 m3).

Shear stresses are determined using measured velocities adjacent to the water-PM

interface. The results are shown in Figure 2-9 for each deposited PM gradation. SM I, SM II and

SM III illustrate similar trends for shear stress and critical shear stress at the water-PM interface.

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Based on physically measured velocities, PSDs and flow rates, the PM bed interface shear stress

does not provide a clear relationship with the observed washout rates. Currently, there is no shear

stress criterion for HS units. The dimensionless shear stress in the HS at each flow rate is

significantly lower than the Shields criterion, suggesting that there should not be scouring.

However, even with low shear stresses measured washout occurs. Using the Shields criterion the

washout rate cannot be inferred directly from the calculated shear stress at the PM-water

interface of the baffled HS. Given that the baffled HS is a circular Type I settling tank, a

modified form of the scour velocity formula derived from Stoke’s Law by Swamee and Tyagi

(1996) is used to calculate scour velocity in settling tanks and it is also tested against the

measured results.

125.02

3

)1(

B

QgdskV sc

sc

(2-14)

In this expression, Vsc is the scour velocity; s is the specific gravity of the PM deposit; g

is the acceleration due to gravity; d is the scoured PM size; Q is the flow rate; B is equivalent

width of the settling tank, and k ranges from 0.5 and 0.8 depending upon the specific geometry of

the configuration (Ingersoll and McKee 1956). Resulting scour velocity ranged from 0.003 to

0.01 mm/s, across the SOR range. These velocities are sufficiently smaller than measured

velocities, indicating that washout should not be generated; a result not supported by the

observed washout.

The results of this study have several practical implications. One implication relates to

the frequency of maintenance to minimize washout. For instance, for the baffled HS it is shown

that washout occurs when separated PM reaches a given depth. This depth can be calibrated for

the HS unit with catchment PM loading data and annual rainfall-runoff volume either as

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36

measured data or from continuous simulation models such as the Stormwater Management

Model (SWMM). While HS units are all predominately Type I settling units, there are a number

of internal configurations for HS units. For example, in contrast to the horizontally-baffled HS

unit of this study, a screened HS consisting of a screened and volute chamber is only capable of

separating coarser PM size (> 75 μm) from stormwater, in the range of the coarser sand-size

fraction of SM III. The screened HS design directs flow energy in a downward spiral towards the

sump that collects these PM deposits, allowing for mobilization and washout of PM (Pathapati

and Sansalone 2009). The standard 2400 μm screen provides apertures capable of passing PM as

coarse as gravel-size. In contrast, results from this study illustrate that the design of the baffled

HS unit volumetrically isolates the deposited PM. There is a tradeoff between hydraulic capacity

(flow rate or SOR), dissipation of flow energy and the propensity for washout. The horizontally-

baffled HS unit provides dissipation of incoming flow energy with depth and, correspondingly,

creates an isolation zone for deposited PM. In comparison, in the screened HS flow energy is

directed circumferentially downward and into the vertically-screened area to the sump containing

deposited PM, before exiting upward and outward through the screen, the volute chamber, and

finally from the unit.

This study illustrates that washout is a function of the PSD of deposited PM and also of

SOR. While deposited PSDs and SOR can be controlled to a degree by HS unit sizing and

design, results of this study suggest that isolation of the deposited PM is critical. Even with

isolation above the deposited PM, many studies have demonstrated that water chemistry can

change significantly in unit operations that store submerged or wet PM deposits between runoff

events. For example, sumps with stored runoff and PM can go anaerobic within two days; far

shorter than the mean time between runoff events for nearly all climatic regions of the USA

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37

(Sansalone et al. 2010). Additionally, PM sludge deposits in wet sumps are habitat for microbial

growth and a source for chemical leaching from PM (Ying and Sansalone 2008). Frequent

cleaning is not practiced for de-centralized unit operations (manufactured or non-proprietary).

Yet the tradeoff is that unmaintained unit operations can be unintended sources of PM,

pathogens and chemicals thereby degrading their intended role as temporary sinks between

maintenance points. While there are environmental benefits from more frequent maintenance,

stakeholders can also benefit through generation of load credit programs to offset maintenance

costs. States such as Florida are providing nutrient load credits for quantifiable and documented

maintenance practices of unit operations and drainage appurtenances (Berretta et al. 2011b).

If consideration is given to on-line versus off-line installation of HS units, from these

results, the baffled HS unit provided isolation of deposited PM. With isolation, effluent indices

of the baffled HS for each PM gradation tested were nominal but demonstrable at the design flow

rate with gravimetric concentrations of 9 to 18 mg/L, effluent turbidity ranged from 10 to 40

NTUs and PND was in the range of 109 #/L. While these results can allow on-line application

with maintenance of the baffled HS, other HS configurations are more prone to washout. By

comparison, at the design flow rate of the screened HS described above, the PM washout

concentration for the coarsest PM gradation (SM III) is 51 mg/L. Therefore on-line versus offline

applications require washout evaluations as conducted in this study. Additionally, while the

PSDs used are reproducible certification gradations, these are inorganic (siliceous) particles and

the aqueous matrix is a reproducible potable water matrix. This provides a reproducible and

precise testing metric for washout comparisons but may not accurately reproduce field conditions

of varying runoff chemistry, a mixture of biogenic and anthropogenic PM, microbial growth and

anaerobic conditions in unit operation sumps and sludge zones.

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38

Summary

Hydrodynamic separator (HS) units are commonly deployed in small developed

watersheds to provide stormwater PM separation. A baffled HS unit, one common HS type, was

analyzed for washout of pre-deposited PM as a function of surface overflow rates (SOR) indexed

as flow rates from 10 to 125% of the HS design flow. Washout was also examined for three pre-

deposited hetero-disperse PSDs of sandy silt PM (SM I at < 75 μm, SM II at < 100 μm, and SM

III at < 1000 μm). Velocity measurements and an RTD analysis were utilized to obtain a

hydrodynamic ‘signature’ of the HS. Results indicate that the spatial symmetry of the baffled HS

does not consistently translate to spatially-similar velocities at the water-PM interface. Results

from RTD analysis with an inert tracer demonstrated that the mean and theoretical residence

times did not differ significantly at the design flow rate. Only as the flow approached design

flow rate was the volume of the HS mobilized towards the depth of the water-PM interface. As a

function of SOR, the median rate of washout ranged from 0.4 to 13.3 g/minute for SM I, from

0.3 to 4.9 g/minute for SM II, and from 0.2 to 3.1 g/minute for SM III and were statistically

significantly different.

A densimetric Froude number, relating flow velocity to gravimetric and granulometric

PM indices of the washout PM, reproduced modeled PM washout as a mass concentration for all

PSDs across the SOR range. During washout the finer PM at or near the water-PM interface

subject to negligible effective confining stress was preferentially mobilized and eluted. The

unmobilized coarser PM fraction of the PSD functioned to confine lower PM and attenuate

continued PM elution. For each PM gradation there was an exponential decline in PM washout

on a gravimetric basis as a function of washout time. In contrast to gravimetric-based washout,

eluted turbidity and particle number density (PND) primarily influenced by finer suspended PM,

both displayed a linearly increasing washout trend as a function of SOR and PSD. Washout, as

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39

measured by turbidity and PND, differed markedly between the coarsest (SM III) and the finer

PSDs (SM I and II). Irrespective of the basis used, washout indices are a function of SOR and

PSD for a given depth of PM deposits.

Using the Shields criterion, an open channel approach to washout, negligible washout

was predicted, which did not replicate the measured washout from the HS unit. The scour

velocity method for settling tanks of Swamee and Tyagi (1996) also did not reproduce the

measured washout results of this study. Results suggest the investigation of models capable of

coupling hydrodynamics and PSD/PND such as computational fluid dynamics (CFD).

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40

Table 2-1. Medianwashout rate and effluent mass load as a function of flow rates. SM is sandy

silt in the Unified Soil Classification System (USCS). SM I is a SCS 75, SM II is a

SCS 106, and SM III is NJDEP gradation

Texture

Classification

of PM

Target

flow

rate

(L/s)

Operating

flow

rate

(L/s)

Surfaceover

flow rate

(L/min-m2)

Volume

of

flow

(L)

Time

duration

of run

(min)

Median

washout

rate

(g/min)

Median

SSC

[mg/L]

Effluent

mass

load

(g)

SM I

(Sandy silt

< 75 µm)

γ = 0.8,

β = 28.9

0.91 0.90 46.7 12902 250.0 0.43 8.2 298.5

2.26 2.46 126.3 14205 100.0 1.06 9.8 386.5

4.78 4.80 245.3 14394 50.0 2.81 11.0 485.4

6.79 7.00 348.5 13861 33.3 4.89 13.9 644.0

9.05 9.30 464.5 13936 25.0 7.33 17.8 742.5

11.31 11.60 580.5 13931 20.0 10.28 20.6 897.6

SM II

(Sandy silt

< 100µm)

γ = 0.7,

β = 157.0

0.91 0.90 46.7 12955 250.0 0.28 7.3 167.6

2.26 2.42 126.3 14538 100.0 0.81 7.7 247.7

4.78 4.73 245.3 14205 50.0 1.64 8.5 286.0

6.79 6.98 348.5 13824 33.3 2.35 9.4 431.6

9.05 9.37 464.5 14072 25.0 3.11 11.0 559.3

11.31 11.65 580.5 13992 20.0 4.88 13.2 692.2

SM III

(Sandy silt

< 1000 µm)

γ = 0.6,

β = 232.6

0.91 0.90 46.7 13142 250.0 0.18 2.0 168.7

2.26 2.45 126.3 14214 100.0 0.52 2.5 226.2

4.78 4.79 245.3 14316 50.0 1.89 5.4 263.7

6.79 6.88 348.5 13842 33.3 2.60 7.5 387.5

9.05 9.21 464.5 13358 25.0 2.80 8.8 428.6

11.31 11.61 580.5 13607 20.0 3.11 10.4 536.6

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41

Table 2-2. d10, d50, d90 for effluent SM I, SM II, and SM III as a function of flow rates.

Effluent PM

Operating

flow

rate

(L/s)

SM I

(Sandy silt < 75 µm)

SM II

(Sandy silt < 100µm)

SM III

(Sandy silt < 1000 µm)

d10

(µm)

d50

(µm)

d90

(µm)

d10

(µm)

d50

(µm)

d90

(µm)

d10

(µm)

d50

(µm)

d90

(µm)

0.91 0.6 0.8 1.6 1.7 1.2 9.3 6.7 5.0 34.7

2.26 0.7 0.8 2.0 1.9 2.0 15.6 7.9 5.9 51.7

4.78 0.8 0.8 2.0 2.2 2.3 16.4 8.3 6.2 54.6

6.79 0.8 0.9 2.2 2.4 2.3 17.3 9.0 8.6 60.4

9.05 0.8 1.0 2.2 2.5 2.5 17.7 10.2 10.6 65.4

11.31 0.8 1.0 2.3 2.5 3.1 17.3 10.6 15.0 74.6

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42

Table 2-3. d10, d50, d90 for pre-deposited PM.

Pre-deposited bed PM

Pre-

deposited

PM depth

(m)

SM I

(Sandy silt < 75 µm)

γ = 0.8, β = 28.9

SM II

(Sandy silt < 100µm)

γ = 0.7, β = 157.0

SM III

(Sandy silt < 1000 µm)

γ = 0.6, β = 232.6

d10

(µm)

d50

(µm)

d90

(µm)

d10

(µm)

d50

(µm)

d90

(µm)

d10

(µm)

d50

(µm)

d90

(µm)

0.25 1.6 15.0 70.3 1.8 22.0 75.2 7.2 67.0 335.9

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43

Table 2-4. The summary of RTD tests as a function of flow rate.Qd is hydraulic design flow rate

for baffled HS. Flow beyond 100% Qd over flows inlet weir and is not treated.

RTD statistics

Q

(L/s) 2.26

(L/s)

4.78

(L/s)

6.79

(L/s)

9.05

(L/s)

11.31

(L/s)

% of Qd 25% 50% 75% 100% 125%

τ 786.1 372.3 261.9 196.5 157.2

tmean (s) 749.1 337.3 222.9 197.0 182.1

ti (s) 45.0 34.0 32.0 28.0 26.0

tp (s) 68.0 52.0 53.0 52.0 46.0

t10 (s) 81.0 69.0 61.0 49.0 45.0

t50 (s) 495.0 209.0 159.0 137.0 125.0

t90 (s) 1587.0 687.0 521.0 407.0 323.0

MDI 19.6 10.0 8.5 8.3 7.2

1/MDI 0.05 0.10 0.12 0.12 0.14

ti/tt 0.06 0.09 0.12 0.14 0.17

tp/tt 0.09 0.14 0.20 0.26 0.29

σ2/tt

2 1.36 0.27 0.31 0.27 0.09

t50/tt 0.63 0.56 0.61 0.70 0.80

Hazen's N 1.16 1.33 1.50 1.61 1.58

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44

Diameter, d (m)

0.11101001000

Per

cen

t fi

ner

by m

ass

(%)

0

20

40

60

80

100

SM I

SM II

SM III

Pre-deposited PM

Figure 2-1. Plot A) is a plan view schematic of the baffled HS testing facility and the velocity

meters placement in the baffled HS is shown. Plot B) illustrates across-sectional

profile of the HS through the centerline of the unit. Plot C) PSDs for pre-deposited

PM.

A) Plan view of HS testing system

B) Section view of Baffled HS

Pre-deposited

PM

C) PSDs for pre-deposited PM

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45

Flow rate (L/s)

0 2 4 6 8 10 12

Mea

n v

eloci

ty (

mm

/s)

0

20

40

60

80(a) 0.17 H

max

(a) 0.33 Hmax

(a) 0.50 Hmax

(a) 0.67 Hmax

Flow rate (L/s)

0 2 4 6 8 10 12

Mea

n v

eloci

ty (

mm

/s)

0

20

40

60

80(b) 0.17 H

max

(c) 0.17 Hmax

Surface overflow rate (L/min-m2)

0 20 40 60 80 100 120

Mea

n v

eloci

ty (

mm

/s)

0

20

40

60

80(d) 0.17 H

max

(e) 0.17 Hmax

Surface overflow rate (L/min-m2)

0 20 40 60 80 100 120M

ean

vel

oci

ty (

mm

/s)

0

20

40

60

80(f) 0.17 H

max

(g) 0.17 Hmax

Figure 2-2. Velocity as a function of ADV height at (A) location in baffled HS and the mean

flow velocity in the baffled HS as a function of flow rate and SOR. (Hmax = 1.52 m;

the distance from the bottom of the unit to the invert of the outlet is 1.52m).

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46

Diameter, d (m)

0.11101001000

Per

cent

Fin

er b

y M

ass

(%)

0

20

40

60

80

100

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Per

cent

Fin

er b

y M

ass(

%)

0

20

40

60

80

100

Pre-deposited

sediment SM II

( = 0.7, = 24.6)

Pre-deposited

sediment SM I

( = 0.8,

= 18.6)

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

0

1

2

3

4

0

10

20

30

40

0

1

2

3

4

0

10

20

30

40

SM I ( = 0.8, = 18.6)

SM II ( = 0.7, = 24.6)

A)

C)

B)

D)

Diameter, d (m)

0.11101001000

Per

cent

Fin

er b

y M

ass(

%)

0

20

40

60

80

100 Pre-deposited

sediment SM III

( = 0.6, = 232.6)

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

0

1

2

3

4

0

10

20

30

40

SM III ( = 0.6, = 232.6)

E)

F)

Figure 2-3. Effluent PSDs for the range of flow rates as a function of flow rate (A –SM I, C –

SM II, E – SM III).Gamma parameters as a function of surface overflow rate (B – SM

I, D – SM II, F – SM III). Design SOR = 464.5 L/min-m2.

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47

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600T

urb

idit

y (

NT

U)

0

10

20

30

40

50

60

70

SM I

SM II

SM III

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

Par

ticl

e num

ber

den

sity

(#/L

)

0.0

2.0e+9

4.0e+9

6.0e+9

8.0e+9

1.0e+10

1.2e+10

1.4e+10

SM I

SM II

SM III

Effluent PM [mg/L]

0 10 20 30 40 50 60 70

Turb

idit

y (

NT

U)

0

10

20

30

40

50

60

70

SM I

SM II

SM III

Particle number density (#/L)

0.0

2.0

e+9

4.0

e+9

6.0

e+9

8.0

e+9

1.0

e+10

1.2

e+10

1.4

e+10

Turb

idit

y (

NT

U)

0

10

20

30

40

50

60

70

SM I

SM II

SM III

A) B)

C) D)

Figure 2-4. For each non-cohesive PSD (SM I at < 75 μm, SM II at < 100 μm, and SM III at <

1000 μm), plots A and C illustrate the relationships between turbidity and surface

overflow rate (SOR)and PND (particle number density) as a function of SOR,

respectively. For these PSDs, plots B and D illustrate the relationships between

turbidity and effluent PM and PND respectively. All R2 values exceed 0.94 and p =

0.05.

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48

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

Med

ian w

ash

out

rate

(g/m

in)

0

4

8

12

16

SM I ( = 0.8, = 18.6)

SM II ( = 0.7, = 24.6)

SM III ( = 0.6, = 232.6)

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

Short

cir

cuit

ing i

ndex

, t i /

0.00

0.05

0.10

0.15

0.20

Index of Short circuiting (ti / )

A)

B)

Figure 2-5. Median washout rate (g/min) and ti / τ as a function of surface overflow rate. Each

linear relationship in plot A and B as a function of SOR has a R2 ≥ 0.97.

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49

Froude number

0.0 0.5 1.0 1.5 2.0

Eff

luen

t P

M [

mg/L

]

0

20

40

60

80

100

Flow rate (L/s)

SM I

SM II

SM III

Surface overflow rate

(L/min-m2)

0 100 200 300 400 500 600

Eff

luen

t P

M [

mg/L

]

0

20

40

60

80

100

Flow rate (L/s)

2.9 6.0 9.1 12.2 2.0 3.9 5.9 7.8 9.7

3.1 5.9 8.8 11.6SM II

SM I

4.4 8.8 13.1 17.5 21.9 26.3

11.7

SM III

SM I, II

6.2 13.4 21.5 28.7SM III

(Fr=V / [(s - 1)gd50m

]1/2

)

SM I

SM II

SM III

Figure 2-6. Effluent PM as a function of densimetric Froude number, flow rates, and SOR.R2 is

0.96 for SM I, 0.96 for SM II, and 0.97 for SM III as a function of Froude number. R2

is 0.98 for SM I, 0.97 for SM II, and 0.98 for SM III as a function of surface overflow

rate.

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50

t / tmax

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Eff

luen

t m

ass

load

(g)

0

100

200

300

400

500

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Eff

luen

t m

ass

load

(g)

0

100

200

300

400

500

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

m (

g)

0

300

600

900

1200

1500

k (

1/m

in)

0.0

2.5

5.0

7.5

10.0

12.5

m

k

m (

g)

0

300

600

900

1200

1500

k (

1/m

in)

0.0

2.5

5.0

7.5

10.0

12.5

m

k

SM I ( = 0.8, = 28.9)

SM II ( = 0.7, = 24.6)

SM I ( = 0.8, = 28.9)

SM II ( = 0.7, = 24.6)C)

A) B)

D)

t / tmax

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Eff

luen

t m

ass

load

(g)

0

100

200

300

400

500

Surface overflow rate (L/min-m2)

0 100 200 300 400 500 600

m (

g)

0

300

600

900

1200

1500

k (

1/m

in)

0.0

2.5

5.0

7.5

10.0

12.5

m

k

SM III ( = 0.6, = 232.6)

SM III ( = 0.6, = 232.6)E) F)

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Figure 2-7. Effluent mass load range of flow rates as a function of time normalized to maximum

duration (A – SM I, C – SM II, E – SM III). Washoff model parameters as a function

of surface overflow rate (B – SM I, D – SM II, F – SM III).

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51

t/tmax

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Was

ho

ut

rate

(g

/min

)

0.1

1

10

100

1000

SM I

SM II

SM III

Modeled (SM I)

Modeled (SM II)

Modeled (SM III)

Was

ho

ut

rate

(g

/min

)

0.1

1

10

100

1000

t/tmax

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Was

ho

ut

rate

(g

/min

)

0.1

1

10

100

1000

Was

ho

ut

rate

(g

/min

)

0.1

1

10

100

1000

V/Vmax

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Was

ho

ut

rate

(g

/min

)

0.1

1

10

100

1000

V/Vmax

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Was

ho

ut

rate

(g

/min

)

0.1

1

10

100

1000

Q = 0.91 L/s

Q = 4.78 L/s

Q = 2.26 L/s

Q = 6.79 L/s

Q = 11.31 L/s

tmax

= 250 min

tmax

= 100 min

tmax

= 50 min tmax

= 33 min

tmax

= 20 min

Q = 9.05 L/s

tmax

= 25 min

Figure 2-8. Measured and modeled washout rate in g/minas a function of time normalized to

maximum duration and volume normalized to 7.6 turnover volume.

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52

Reynolds number (Rep* = u

*d/v

0.0001 0.001 0.01 0.1 1 10 100 1000

Cri

tica

l S

hie

lds

stre

ss (

c

c/(S

Sg

d)

1e-4

1e-3

1e-2

1e-1

1e+0

1e+1

1e+2

1e+3

d10

d50

d90

d10

d50

d90

d10

d50

d90

SM I

SM II

SM III

Figure 2-9. Shield’s parameters for SM I, SM II, and SM III as a function of particle Reynolds

number. (u* is shear velocity, and v is kinematic viscosity of water).

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53

CHAPTER 3

PHYSICAL AND CFD MODELING OF PM SEPARATION AND SCOUR IN

HYDRODYNAMIC SEPARATORS

Overview

Rainfall-runoff (stormwater) transports a mixture of hetero-disperse particulate matter

(PM) and chemicals that partition to and from PM (Sheng et al 2008; Lee and Bang 2000). Once

entrained in stormwater, PM separation is challenging in an urban environment due to

uncontrolled variable of flow rates, spatially-distributed loadings and land area or infrastructure

constraints to support stormwater control. Therefore, small-footprint devices such as

hydrodynamic separators (HS) units (U.S. EPA 1999; Rushton 2004) have been deployed

specifically as preliminary unit operations for PM where larger scale retention basins that

provide hydrologic and PM control are not needed (Rushton 2004). A unique feature of HS units

is that the particle trajectory can potentially approach that of much larger basins (Field and

O’Connor 1996). While HS units have been in use for decades, modeling their PM separation is

fairly recent whether as a function of steady flow (Sansalone and Pathapati 2009) or for storm

events with varying flow rates and hetero-disperse particle size distributions (PSD) (Sansalone

and Pathapati 2009; Kim and Sansalone 2008). While unit operation models can reproduce PM

fate with physically-based methods such as combining SOR and PM phenomena, intra-event

data are critical to couple unsteady flow rates with PSDs, PM granulometry, and partitioning

(Sansalone et al. 2010). Therefore many unit operations models remain as steady flow

approaches. On the other hand, models such as the Stormwater Management Model (SWMM)

were designed for the complexity of fully unsteady flow in complex urban systems (Huber and

Dickenson 1988), with a focus on modeling how the urban interface modified rainfall-runoff

relationships.

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54

In recent years, computational fluid dynamics (CFD) has been applied to environmental

engineering. For example, CFD has been used to model the behavior of a screened HS under

steady flow and constant PSDs (Faram and Harwood 2003). CFD modeling can provide detailed

information regarding the unit operation load-response, including velocity profiles, particle

tracks, pressure gradients, species transport, density and thermal gradients and turbulence

(Versteeg and Malalasekera 1995). Similarly regulatory agencies (State of Pennsylvania 2003)

require HS units to be physically modeled at steady flow rates and constant PSDs.

Over the last several decades studies of PM separation by HS units have been examined

through physical and numerical models. Field and O’Connor (1996) reported that swirl and

vortex feature of HS units give longer magnitude of particle trajectory than in traditional unit

operations. Fenner et al. (1997, 1998) have suggested that no single dimensionless group can be

used in describing, and scaling the PM separation performance. Li et al. (1999) in their study of a

partial exfiltration system determined that 2-D numerical model has been applied to simulate

variably saturated flow. U.S. EPA (1999) report of HS concluded that HS mostly rely on

gravitational force as well as centrifugal forces in order to separate PM. Andoh et al. (2003)

studied a hydrodynamic vortex separator (HDVS) and found that CFD simulation could be

applied for the assessment of the efficiency of a HDVS intended for PM separation. Luyckx and

Berlamont (2004) considered a vortex separator and their modeling indicated that a vortex

separator is based on settling velocity of PM. Cates et al. (2009) monitored 26 storm events with

HS unit and overall TSS removal was 59%, while turbidity results show a median EMC

reduction of 57%. A baffled HS (BHS), which functions primarily as a sedimentation device,

has been tested to assess the performance of PM removal and a function has been developed

linking PM removal to Péclet number (Pe) (Wilson et al. 2009).

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55

More recently, studies of HS units have examined PM washout (commonly as scour

testing) through physical and numerical models. From a monitoring campaign that encompassed

seven rainfall-runoff events, Yu and Stopinski (2001) reported that effluent concentrations

exceeded influent PM concentrations for a VHS. Ruston (2004) carried out a monitoring

campaign for a SHS loaded by a 54 hectare surface parking area and demonstrated that 51% of

the events produced higher effluent than influent PM concentrations as total suspended solid

(TSS). Kim et al. (2007) tested a SHS for PM washout (scour testing) and documented that the

pre-deposited PM height in the sump had the most dominant impact on the degree of scour

during the duration of each run. A screened HS (SHS), which combines vortex separation,

screening and sedimentation, has been tested for PM separation and washout using a pre-

deposited heterodisperse particle size distribution (0.1 to 2000 μm) as a function of steady flow

rates (Pathapati and Sansalone 2012). Washout from a BHS has been physically modeled as a

function of SOR and PSDs for a fixed depth of PM deposits (Cho and Sansalone 2012). Results

indicated that a densimetric Froude number reproduced modeled PM washout as a mass

concentration.

HS units have been tested physically (Jianghua et al. 2009; Wilson et al. 2009) as well as

numerically using CFD (Andoh et al. 2003) to quantify PM separation. Cellino and Lemmin

(2004) demonstrated that the burst cycle plays an important role in PM suspension mechanics in

open channel flow. Gargett et al. (2004) investigated PM transport and re-suspension in shallow

seas. Research related to PM transport and re-suspension has predominantly focused on open

channel flow such as clear-water and shallow seas, however, modeling of PM washout (re-

suspension) has not been done much for unit operations in urban watershed area. In this study the

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56

complexity of PM separation and washout in HS units can be quantified by a physically

validated CFD modeling approach.

Objectives

This study applies the methodology to three mechanistically unique HS, each with a

unique geometry. The three HS are modeled so as to have the same SOR. This provides basis for

comparison that is independent of the geometry. In this study, physical model of PM separation

and washout experiments are performed on a full-scale BHS, VHS, and SHS subject to the

following conditions: (1) PM injection and pre-deposited PM of PSDs known a priori across a

range of SOR and (2) differing steady flow regimes representing 10 to 125 % of the design flow

rate (Qd) for each HS units. The physical models are then compared with CFD modeling. This

study then develops a separation function for each HS as a function of particle diameter which

can be utilized to predict washout under different pre-deposited PM conditions, flow rates and

PSDs.

Methodology

Physical Clarification and Re-suspension Function Modeling

This study was performed with three different types of commercial HS units: BHS, VHS,

and SHS. The hydraulic design flow rate (Qd) for BHS, VHS, and SHS are 9.1 L/s, 79.3 L/s, and

31.2 L/s, respectively. The Qd for the 3 types of HS unit are provided by the manufacturer. The

BHS has a diameter of 1.2 m, a sedimentation chamber height of 1.5 m, surface area of 1.2 m2,

and a volume of 1.8 m3. The BHS is made for specifically oil and grease and floatables

separation and consists of a sedimentation chamber, drop tee inlet and outlet pipes, and an

overflow weir. PM separation is dominated by gravitational separation. Ranges of SOR are from

47.3 to 590.9 L/min-m2, which is between 0.10 and 1.25 of the BHS Qd. The VHS has a

rectangular chamber, a width of 3.1 m, a depth of 1.2 m, a height of 2.1 m, surface area of 3.7 m2,

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57

and volume of a 7.0 m3. The VHS consists of a swirl chamber and two baffles. PM separation is

predominantly due to vortex and gravitational separation. Ranges of SOR are from 128.0 to

1280.2 L/min-m2, or, between 0.10 and 1.00 of the VHS Qd. The SHS has a diameter of 2.1 m, a

screened chamber height of 1.7 m, surface area of 3.6 m2, and a volume of 6.1 m

3. The SHS

consists of static-screen of 2400 μm in width and vortex gravitational separation chamber.

Vortex and gravitational separation are the dominate PM separation mechanisms despite the

static-screen installed in the unit. Ranges of SOR are from 52.3 to 653.5 L/min-m2, or, between

0.10 and 1.25 of the SHS Qd.

The influent and pre-deposited PM consists of hetero-dispersed and non-cohesive sandy

silt (SM). The mass-based PSDs of influent and pre-deposited PM are shown in Figure 3-1. The

d50m of SM is 67 μm. Over 50% of the influent gradation consists of particles finer than75 μm.

Based on Unified Soil Classification System (USCS) standard, this gradation is classified as

‘well-graded sandy silt’ and denoted as ML (Liu et al 2008; ASTM 2006). The duration of each

run is chosen for a volumetric turnover of approximately 7.6 (BHS volume is 13.7 m3, VHS

volume is 53.2 m3, and SHS volume is 46.4 m

3). BHS and SHS are analyzed under six different

flow rates ranging from 0.10 to 1.25 Qd. VHS is analyzed under five different flow rates (0.1 Qd

– 1.00 Qd) for separation and washout function.

For the separation function, the PM injection tank had to be cleaned thoroughly using

potable water with a hose and brush such that no PM was present in the slurry tank prior to the

run. The pipes leading to the BHS, and SHS units were flushed with potable water to remove any

PM or biogenic material in the unit. The PM injection tank was filled with 180 liters of clean

water into which the prepared SM gradation was added. The programmable logic control (PLC)

was set with the target flow rate and the PM injection pump was set with the steady injection rate

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58

in Hz. The data logger (CR3000) was compiled to start logging the flow rate every second. Ten

duplicate 1 L samples were collected for PSD, and PM analysis, (as suspended solid

concentration (SSC)). Previous studies have demonstrated that SSC is a representative

gravimetric index for hetero-disperse gradations that include sand-size or coarser PM (Gray et al

2000). SSC analysis is carried out by filtering the entire sample volume of each replicate through

a nominal 1.0 µm filter (ASTM 2007; Ying and Sansalone 2008). Separation function is

measured by SSC removal (%), which is computed as a percentage (by mass) of particles

captured by the HS (MHS) relative to the particles (MINF) added into the system.

100(%) INF

HS

M

MPSD (3-1)

A mass balance analysis is also conducted after every event to ensure mass conservation

based on influent, effluent and recovered mass in HS. A criterion is set by requiring the

magnitude of the mass balance error (MBE) to be equal to 10 by dry mass.

(3-2)

Washout function tests are performed at 5 and 6 different flow rates for VHS (0.10 Qd –

1.00 Qd) and BHS (0.10 Qd – 1.25 Qd). The SHS was performed with 2 different flow rates (1.00

Qd and 1.25 Qd). Each re-suspension run is conducted by first pluviating the entire surface area

of the bottom chamber of the HS with PM to a pre-deposited PM. Since HS units store runoff

between runoff events, each run is conducted with an HS unit filled with water above an

undisturbed pre-deposited PM bed. Flow is diverted around the HS until a steady-state flow is

achieved. Once re-suspension flows are directed into the HS, sampling is initiated and discrete1

L samples are manually taken in duplicate at equal sampling intervals, calculated based on flow

rate and time. PSDs and SSC are analyzed for washout function. Washout rate is measured by

100(%)

INF

EFFHSINF

M

MMMMBE

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59

washout mass load (g), which has been computed as a ratio of mass of particles washed out by

the HS (WHS) to the duration time (T) of the system.

T

WrateWashout HS (3-3)

The intensity of washout is expressed as washout rate (g/min) while the magnitude of

washout can be evaluated by effluent mass load (or effluent concentration in this specific case

because total influent volume was set as a constant per each run).

CFD Modeling

The Navier-Stokes equations can define any single-phase fluid flow, but are non-linear

partial differential equations. It is difficult to solve them directly, so we need numerical methods.

CFD is a branch of fluid mechanics that uses numerical methods to integrate the Navier-Stokes

equations in order to solve fluid flow problems. Three types of full-scale HS units are modeled in

3D using FLUENT v 6.0. A finite volume method (FVM) is applied to discretize the governing

equations into the physical space directly. Modeling in 3-D is less susceptible to the

complications which arise from the lack of geometric symmetry, complex static screen geometry,

vortex flow and gravitational forces on the motion of particles in HS.

A k-ε model is suited for separation and washout function (Morin et al 2008; Liang et al

2005; Pathapati and Sansalone 2011). Two-equation Reynolds Averaged Navier-Stokes (RANS)

models are applied to swirling multiphase flows in the HS (Pathapati and Sansalone 2009;

Garofalo and Sansalone 2011). The standard k-ε model has been applied to turbulent flow model

in HS successfully (Pathapati and Sansalone 2009; Garofalo and Sansalone 2011).

CFD Governing Equations

The governing equations are derived for incompressible flow. The conservation of mass

and momentum are determined using the RANS equations as following

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60

0

z

w

y

v

x

u (3-4)

The momentum equations are as follows:

x momentum:

xg

z

u

y

u

x

u

x

p

z

uw

y

uv

x

uu

)()(

2

2

2

2

2

2

(3-5)

y momentum: ygz

v

y

v

x

v

y

p

z

uw

y

uv

x

uu

)()(

2

2

2

2

2

2

(3-6)

z momentum:

zg

z

w

y

w

x

w

z

p

z

uw

y

uv

x

uu

)()(

2

2

2

2

2

2

(3-7)

In these equation, is fluid density, u, v, and w are Reynolds averaged fluid velocities, g

is sum of body forces, and p is the Reynolds averaged pressure. The momentum continuity

equation for the x, y and z directions can be obtained by assigning values of u correspondingly,

where u is combining of the x, y, and z velocity vector component, since the hydrodynamics of

HS vary as a function of x, y, and z spatial coordinates. The 3-D Navier Stokes equations for a

Newtonian fluid are determined by 3-D velocity vector components.

Turbulence modeling is widely applied the two-equation k-ε model. k and ε equations

allow one to determine the turbulent velocity and length scales independently. The transport

equations of the standard k-ε model are expressed by the following equations.

For k and ε:

k

jk

t

j

i

i

Gx

k

xku

xk

t)()(

(3-8)

kCG

kC

xxu

xtk

j

t

i

i

i

2

21)()(

(3-9)

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In this expression, is the generation of due to the mean velocity gradients; is the

generation of due to buoyancy; , , are constants; , are turbulent Prandtl

numbers for and ; , are user-defined source terms. The values of C1ε, C2ε, C3ε, σk and σε

used in this model are 1.44, 1.92, 0.09, 1.0 and 1.3 respectively (Launder and Spalding 1974).

Newton’s law of viscosity is applied to illustrate the relationship between viscous stresses and

“Reynolds stresses”. It should be noted that eddy viscosity (µ) is a non-physical quantity, and is

expressed by the following equation.

(3-10)

In this expression, is turbulent kinetic energy per unit mass, [L2T

-2] and is the rate of

dissipation of turbulent kinetic energy per unit mass, [L2T

-3].

As an assumption of the standard k-ε model, μ is taken to be isotropic,. From the standard

k-ε model equations, the information regarding the flow field and turbulent field, such as

velocity profiles, kinetic energy, eddy energy and eddy diffusivity, are generated. The standard

k-ε model with standard wall functions is found to be an effective approach to modeling flow

through the BHS.

Particulate Phase Modeling

For the both separation and washout function studies, the Euler-Lagrangian approach is

applied to model the particle behavior in the HS. This approach is valid for dilute multiphase

flows when PM volume fraction is less than 10% (Elgobashi 1991). A Lagrangian discrete

particle model (DPM) is applied to track particles. Due to the extremely dilute nature of the flow,

the DPM assumes there are no particle-particle interactions. Particle trajectories are calculated by

kG kbG

k1C

2C 3C k

k kS S

2kf

k

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62

integrating the particle force balance equation. The Lagrangian DPM is derived from force

balances based on Newton’s law describing particle settling (Pathapati and Sansalone 2009).

p

p

pD

p guuF

dt

du

)()(

(3-11)

24

Re182

pD

pp

D

C

dF

(3-12)

pp

DR

a

R

aaC

2

321 (3-13)

uud pp

p

Re (3-14)

where, up is a particle velocity, u is fluid velocity; ρp is particle density, ρ is fluid density; dp is a

particle diameter; µ is viscosity; a1, a2, and a3 are empirical constants that apply to smooth

spherical particles as a function of the Reynolds number (Morsi and Alexander 1972); and Rep is

a particle Reynolds number.

The PSD is divided into 18 classes of particles based on a standard sieve. The particle

diameter is constant within same class. Particles are tracked for each steady flow rate. The

particles that become trapped in the HS are considered to have been removed through HS. The

particle removal efficiency is calculated by the following equation.

(3-15)

In this expression, is the number of particles that remain in the baffled HS, and NI is

the number of particles injected at the inlet.

100*I

HS

N

Np

H SN

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Re-suspension and Washout Modeling

The method for modeling re-suspension from a flat PM bed is performed. An Eulerian-

Lagrangian approach is used for modeling. First, turbulence modeling is used to obtain a steady

state flow field. Following this, a series of plane surfaces is created in the PM deposit region of

each HS. The interval between these plane surfaces is equal to at least one particle diameter for

each particle size tracked. Particles are then placed (velocity = 0, to simulate particles at rest) at

grid points across these surfaces. With mesh size of ranging from 1.5 cm to 2.0 cm, each layer

has 37802, 9586, and 45472 points available for tracking particles for BHS, VHS, and SHS units,

respectively. Particles are then tracked for tracking lengths obtained by a simulated tracer study

using ‘massless’ particles. The error of tracer study is calculated to be ± 1%. This provides an

unbiased tracking length that can be used to predict PM washout. The particles that exit the HS

through the outlet are considered to be re-suspended.

Numerical Procedure

The geometries are spatially discretized into 3.2, 5.5, and 2.1 million units for the BHS,

VHS, and SHS. As mentioned in previous sections, FVM and a second order upwind scheme are

applied in this study. In addition, the Semi-Implicit Method for Pressure Linked Equation

(SIMPLE) algorithm (Patankar 1980) is applied.. Through convergence of the numerical process,

a numerical method can meet pre-designated standards of consistency and stability. Convergence

is achieved when the error residuals fall below the preset convergence criteria (10-4

).

Volumetric Efficiency Calculation

Results of the tracer study are then compared with different units’ results from validated

CFD models for residence time distribution (RTD) and complete hydrodynamic profiles of HS,

including the spatial frequency distribution of velocities. The following RTD indices are reported

in this study: tt,,the theoretical residence time, (defined as tt = V/Q, where V is the volume of the

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64

HS unit, and Q is the flow through the system); the volumetric efficiency (VE) (VE := t10/t90,

where tx is the time at which x% of the tracer had eluted from the HS) (Levenspiel 1972;

Letterman 1999).

Results

Comparison Physical and CFD Modeling

Results of separation and washout function for the three HS units are compared with

results from experimentally validated CFD models, as shown in shown in Table 3-1 and Figure

3-2 as a function of flow rates. The absolute relative percent difference (RPD) is used to evaluate

CFD model results with respect to the full-scale physical model. Absolute RPD is calculated by

the following equation.

100datameasured

data)modeleddata(measuredRPDabsolute

(3-16)

Results indicate that the CFD model predictions of PM removal and re-suspension rate

reproduce the measured data with an absolute RPD less than 10% across inflow rate (0.10 Qd to

1.25 Qd).

Physical Modeling of Separation and washout Function

Results for separation and washout function are measured as Δ mass (% and g) for BHS,

VHS, and SHS units as a function of flow rates ranging from 10 to 100% of Qd for each unit.

BHS and SHS were also tested at 1.25 Qd. The same results for separation and washout function

are summarized in Table 3-1, along with SOR. For separation function, PM removal for the

tested gradation ranged from 52.3 to 77.6%, at 0.10 to 1.25 for the BHS Qd, and for the SHS it

ranged from 42.3 to 70.0%, at 0.10 to 1.25 Qd. On the other hand, the CFD results showed PM

removal for BHS ranging from 51.7 to 74.6%, with RPD less than 5.1% for all flow rates (up to

9.1 L/s in BHS). CFD results for SHS show PM removal ranging from 42.0 to 69.9%, with RPD

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less than 8.6% (up to 31.2 L/s in SHS). Physical modeling of separation function was not

conducted for the VHS. However, the CFD results indicate that PM removal has a decreasing

trend as flow rate is increasing, ranging from 42.8 to 62.3%, under the specified operating range

of flow rate. PM removal varies slightly for the three HS units in the SOR range of 47.3 to

1280.2 L/min-m2 which indicates that the PM removal significantly depends on SOR.

In order to describe this phenomenon, the fundamental separation mechanisms utilized by

BHS, VHS, and SHS are identified. The influent flow is directed into the lower chamber of

system by the head created at the weir and orifice configuration in BHS. This system

incorporates gravitational settling. The cylindrical design of the BHS is to avoid turbulent eddies

and dead zones during high flow rates which might re-suspension the settled PM from the

bottom of the system. The influent flow in VHS is directed to the swirl chamber where it forms,

a vortex. Vortex makes coarser PMs to settle down in the swirl chamber. Then, flow goes into

second settling chamber containing baffles. The internal hydraulic geometry of SHS is designed

such that the entire influent flow enters the volute area by passing through the screen. Therefore,

the overall particle separation in a SHS is accomplished by two serial UOPs. This conceptual

process flow model also requires that the particle gradation entering the volute area be directly

influenced by the separation performance in the screen area.

Figure 3-2 illustrates the variation of mean effluent SSC and washout rate for HS units as a

function of flow rates. Both the mean washout mass load and washout rate show a generally

linear increase with increasing flow rate for all units. There was higher washout and a wider

range in PM washout from the VHS, and SHS than BHS – ranging from 1.1 to 25.1 g/min (from

47.3 L/min-m2 to 590.9 L/min-m

2 in BHS), from 20.8 to 964.9 g/min (from 128.0 L/min-m

2 to

1280.2 L/min-m2 in VHS), and from 2227.3 to 3046.0 g/min (from 52.3 L/min-m

2 to 653.5

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66

L/min-m2 in BHS), at 100% of pre-deposited PM capacity. In contrast, the CFD results showed

washout rates for BHS ranging from 1.0 to 25.5 g/min, with RPD less than 9.1% for all flow

rates (up to 590.9 L/min-m2). CFD result for VHS indicates that washout rate has an increasing

trend while flow rate increases, ranging from 19.4 to 977.0 g/min (up to 1280.2 L/min-m2).

Physical modeling for washout function was not conducted at low flow rates for the SHS,

however, CFD results for SHS showed PM removal ranged from 263.3 to 3299.9 g/min, with

RPD less than 8.3% (up to 653.5 L/min-m2) under the specified SOR. The washout rates vary

slightly for the three units in the SOR range of 47.3 to 1280.2 L/min-m2 which means that the

PM removal significantly depends on SOR. Also, comparing the types of HS units, it is clear that

the geometry of HS has a significant impact on washout, especially in regards to VHS and SHS.

SHS has more than 9 times higher washout rate at similar SORs. Overall, BHS had lower

washout than VHS, and SHS across operating flow rates. One reason for this is that in BHS unit,

hydraulic energy is dissipated as the flow hits the drop tee inlet pipe, thereby creating a more

quiescent environment. On the other hand, the VHS, and SHS units have no energy dissipation

and also have the added washout due the vortex in the swirl chamber.

PSD Result

A comparison was made among the performance of the HS units (BHS, VHS, and SHS)

to evaluate the impact of changing the flow rate on PSD. Figure 3-1 illustrates the variations in

the effluent and washed out d50m across flow rates. CFD results show that the absolute RPDs for

each flow rate in all the HS units are less than 10%. Results clearly demonstrate that the effluent

d50m becomes coarser with increasing flow rate for all 3 HS units. The d50m increased linearly

from 4 to 17 μm through 10 to 125% of Qd in BHS, from 21 to 43 μm through 10 to 125 %of Qd

in VHS, and from 15 to 21 μm through 10 to 125% of Qd in SHS for separation function.

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67

Compared to changes in the d50m for effluent PSD, the particle size variability is more

pronounced as shown in Figure 3-1 which illustrates the d50m for PSD gradations.

Figure 3-1 illustrates PSDs in the effluent at constant flows from 10 to 125% of design

flow rate with SM gradations. As hypothesized, the HS unit discharged finer PSDs when the

effluent flow had lower flow rates. Except for a few discrepancies, the results indicate that the

effluent PSD became increasingly coarser with increasing flow rate. The general trends of PSDs

in Figure 3-1 for VHS and SHS did not vary as much as BHS across the range of flow rates.

Effluent PSDs were more significantly influenced by the geometry of the HS.

Washout PSD data obtained from each experimental run is compared to investigate the

performance of each unit as function of flow rates. Results demonstrate that washout PSDs from

the BHS consist predominantly of fine particles, indicating that coarse particles are not washed

out from the BHS. Washout PSDs are finer at low flow rates than at higher flow rates due to the

correspondingly smaller stream power available to suspend particles. This translates into a

relatively stable washout rate at these flow rates, which agrees with the overall system washout

rate previously discussed. It appears as if the mildly increasing washout rates possibly vary

linearly over the range of flow rates studied. The minimum particle diameter not washout from

the BHS was approximately 38 μm at 100% PM capacity at the Qd. A larger fraction of coarse

particles (> 75 μm) was not washout in the BHS, in contrast with the VHS and SHS in Figure 3-

1. Plot (D) in Figure 3-1 illustrates PSDs in the washout at constant flows from 10% to 100 % of

design flow rate at 100% of PM capacity for the SM gradation in VHS. The results from the

VHS show that a larger gradation of particles was eluted from the unit with increasing flow rates.

Washout PSDs were closer to the SM gradation with increasing flow rates. The minimum

particle diameter not washout from the VHS was 425 μm at 100% PM capacity at Qd. Washout

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PSDs from SHS are illustrated on plot (F) in Figure 3-1 from 100 to 125% of Qd at 100% PM

capacity for the SM gradation in SHS. The PSD results from the SHS were in between those of

BHS and VHS, with an increasing sizes eluted at increasing flow rates. The minimum particle

diameter not washout from the SHS was 180 μm at 100% PM capacity at Qd. Therefore, the

washout particle gradations in VHS and SHS were coarser than that in the BHS.

PM Dynamics

The particle trajectories were calculated by a Lagrangian DPM for 3 different HS units

for separation and washout function, across a range inflow rates. Figure 3-3 and 3-4 compare

trajectories of treated and re-suspended discrete particles of selected diameters for three different

hydrodynamic separators: BHS, VHS, and SHS. For separation function, (A), (B) and (C) in

Figure 3-3 correspond to particle diameters of 25, 106, 300 μm, respectively. For washout

function in Figure 3-4, (A), (B) and (C) correspond to particle diameters of 10, 25, 75 μm,

respectively.

Figure 3-3 illustrates the dynamics of a specific PM size for separation function in HS

units. Three different PM diameters of 25, 106, and 300 μm are chosen for illustration. The

dependence of particle separation on particle size is clear. It can be observed for the coarse end

of the size spectrum that particles are influenced predominantly by gravitational forces from all

three HS units, whereas for the fine end of the size spectrum the suspended particle behavior is

largely a function of inertial hydrodynamic forces.

As illustrated in plot (A), and (B) of Figure 3-4, 10, and 25 μm, PMs (suspended and

settleable) are significantly washed out from the HS units. However, in plot (C) of Figure 3-4,

there is no movement of pre-deposited PM detected. The BHS showed significantly less PM re-

suspension than did the VHS or SHS. Compared to BHS and SHS, VHS has significant re-

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suspension and washout, because VHS has about 2 times higher Qd than SHS, and 7 times higher

Qd than BHS.

Fluid Velocity Magnitude

In order to understand the hydrodynamics within the three HS units, CFD results were

examined in the form of graphical representations of fluid velocities in the HS by means of fluid

pathlines, and fluid velocity frequency distributions.

Figure 3-5 provides fluid velocity magnitude frequency distributions in the BHS, inner

swirl and outer chamber of the VHS, and the sump and volute chamber of SHS. As shown in

Figure 3-5, the BHS has the lowest fluid mean velocities. Figure 3-5 (A) depicts mean fluid

velocities in the BHS. As may be seen, low magnitude velocities necessary for quiescent

conditions and discrete settling dominate this distribution. Figure 3-5 can be utilized to determine

the possible separation mechanisms in the three HS units. Figure 3-5 (B) and (C) depict the

higher magnitude of velocities which result in the swirl chamber and outer chamber of the VHS,

and SHS, respectively. This is due to the presence of a swirling forced vortex in the chamber.

Separation within the swirl chamber of the VHS tends to rely upon inertial separation due to the

presence of vortics in a small swirl chamber with high SOR (128.0 to 1280.2 L/min-m2). It is

noted that while the swirl chamber diameter in the VHS is identical to that of the BHS, the Qd of

VHS is 2.7 times higher than that of BHS. The correspondingly higher SOR results in higher

washout rates in the VHS as compared to the BHS. The same comparison gives different results

when compared to the SHS, which has a similar range of SOR. The fluid velocity profile shows

that SHS has higher velocities in the unit. The inlet configuration and sedimentation chamber

configuration also affect the hydraulic behavior of the HS.

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Probability of PM Separation and Washout

Modeled PM separation and washout probabilities as a function of PM diameter and flow

rate are illustrated in Figure 3-6 via 3-D graphs. Plots (A), (C) and (E) show separation function

for BHS, VHS, and SHS. BHS has the most efficient PM removal as a function of flow rates.

BHS separates PM diameters larger than 25 µm at 0.10 Qd, and larger than 150 µm at 1.25 Qd.

VHS separates PM diameter larger than 150 µm at 0.10 Qd, and larger than 500 µm at 1.00 Qd.

SHS separates PM diameter larger than 106 µm at 0.10 Qd, and larger than 250 µm at 1.25 Qd.

The washout function of modeled PM washout probabilities are shown in plots (B), (D)

and (F) in Figure 3-6. As shown in plot (B), BHS has significantly lower PM washout probability

compared to VHS, and SHS. PM diameters larger than 25 µm in BHS do not re-suspension at all

at the highest flow rate, 1.25 Qd. In contrast, PM diameters around 300 µm were re-suspended

from VHS at 1.00 Qd, and PM diameters of 250 µm were re-suspended from the SHS as well. A

gamma distribution function is used to model PM separation and washout.

)(

)(

)(

1

x

ex

xf (3-17)

In this expression, Γ is the gamma function; γ is the shape factor and β is the scaling

factor. f(x) is the cumulative gamma distribution. These parameters are shown in Figure 3-7 as a

function of flow rates for each eluted PSD. Conceptually, the shape factor may be thought of as

uniformity of the eluted PSD as compared to the heterogeneity of the influent PM and pre-

deposited PM gradation. The shape factor values are decreasing as the flow rate is increased

while the scaling factor values are increasing across the flow rates. It is observed that a more

hetero-disperse PSD is eluted from the VHS, with the effluent PM approaching to influent PM

and pre-deposited PM gradations as the flow rate increases.

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Summary

This study examined the PM separation capacity of two types of HS units across a range

of influent loading conditions, with the SOR ranging from 47.3 to 590.9 L/min-m2 for BHS, and

from 52.3 to 653.5 L/min-m2 for SHS. Measured effluent PM removal ranged from 52.3 to

77.6%, for BHS, and SOR ranged from 47.3 to 590.9 L/min-m2. PM removal for SHS ranged

from 42.3 to 70.0% and SOR ranged from 52.3 to 653.5 L/min-m2. Results indicate that SOR has

a significant influence on PM removal in HS units. Comparing among effluent PSDs from the

three HS units, PSD from VHS is consistently coarser across flow rates than in the other two HS

units.

Secondly, physical modeling of washout from three types of HS units was performed

with same SM gradation of 100% pre-deposited PM. SOR ranges were same condition as

separation function. Washout rates ranged from 1.1 to 25.1 g/min from BHS; from 20.8 to 964.9

g/min from VHS; and from 2227.3 to 3046.0 g/min from SHS. BHS has significantly lower

washout rate than other two HS units. The interesting thing is that SHS has the highest washout

rate for the same SOR, which ranged from 128.0 to 590.9 L/min-m2. The BHS has significantly

lower washout rates than other two HS units. Even though SHS has lower Qd than VHS, the SHS

has a significantly higher washout rate. The reason that SHS has such a high washout rate is that

the geometry of the SHS directs, inflow from the screened area to the pre-deposited PM, causing

PM re-suspension.

Three different HS units are successfully modeled in terms of PM behavior with CFD,

using FVM, a standard k-ε model for turbulent conditions, and a Lagrangian DPM to track

particles. CFD models are validated for PM concentration, mass and PSDs with less than 10%

RPD. Lagrangian particle trajectory results show that VHS has coarsest eluted and washout PM,

as well as, the highest washout rates. The vortexing inner chamber results in a higher rate of re-

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72

suspension of finer PM in the SHS. A CFD based probability function is developed for each HS

for particle elution as function of flow rate and diameter. Such probability functions, combined

with any available physical modeling data can provide a reliable method of predicting PM yield

from a HS, thereby reducing error in subsequent operations in treatment trains.

The volumetric efficiency of the three HS units is illustrated in Figure 3-8. It is noted that

the BHS behaves differently from the SHS and VHS. The primary hydraulically distinguishing

aspect of the BHS is the absence of a turbulent vortexing region. Volumetric efficiency, while

commonly used as an index to determine the deviation of a given flow regime from plug flow,

can misrepresent the dynamics of particles in a HS. Clearly, for a similar volumetric efficiency,

the VHS exhibits more washout than the SHS.

In consideration of these results, the use of CFD to quantify treatment and washout from

HS units is validated and holds great promise for future studies.

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Table 3-1. Summary of measured and modeled separation and washout function result with RPD.

Type

of

HS

Surface

overflow

rate

(L/min-m2)

Separation

function

(Δ Mass - %)

RPD

(%)

Washout

function

(Δ Mass - g)

RPD

(%) Measured Modeled Measured Modeled

BHS

47.3 77.6 74.6 3.9 1.1 1.0 9.1

118.2 67.3 63.9 5.1 3.2 3.0 5.9

236.4 61.5 58.4 5.0 7.8 7.2 7.9

354.5 58.6 55.8 4.7 18.6 18.4 1.1

472.7 53.7 53.1 1.1 22.1 21.7 1.9

590.9 52.3 51.7 1.1 25.1 25.5 1.7

VHS

128.0 N/A 62.3 N/A 20.8 19.4 6.8

320.1 N/A 57.0 N/A 59.0 62.7 6.3

640.1 N/A 46.0 N/A 235.4 243.7 3.5

960.2 N/A 39.8 N/A 635.4 642.5 1.1

1280.2 N/A 42.8 N/A 964.9 977.0 1.2

SHS

52.3 70.0 69.9 0.2 N/A 263.3 N/A

130.7 62.1 65.8 5.9 N/A 556.4 N/A

261.4 52.4 56.7 8.3 N/A 1214.3 N/A

392.1 46.8 50.8 8.6 N/A 1596.8 N/A

522.8 43.9 46.0 4.8 2227.3 2408.3 8.1

653.5 42.3 42.0 0.7 3046.0 3299.9 8.3

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Per

cent

finer

by m

ass

(%)

0

20

40

60

80

100

PM diameter (m)

0.11101001000

Per

cent

finer

by m

ass

(%)

0

20

40

60

80

100

Washout function

0.11101001000

Per

cent

finer

by m

ass

(%)

0

20

40

60

80

100

Per

cent

finer

by m

ass

(%)

0

20

40

60

80

100

PM diameter (m)

0.11101001000

Per

cent

finer

by m

ass

(%)

0

20

40

60

80

100

Effluent Washout

Separation Washout

Separation Washout

BHS

Separation function

0.11101001000

Per

cent

finer

by m

ass

(%)

0

20

40

60

80

100

Influent

BHS

(Qd = 9.1 L/s)

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Separation

Q

BHS

(Qd = 9.1 L/s)

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Q

Influent

VHS

(Qd = 79.3 L/s)

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

Q

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

VHS

(Qd = 79.3 L/s)

Q

SHS

(Qd = 31.2 L/s)

SHS

(Qd = 31.2 L/s)

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Q

Influent

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Q

Pre-deposited

Pre-deposited

Pre-deposited

(a)

(c)

(e)

(b)

(d)

(f)

Figure 3-1. Modeled PSD plots of treated and washout PM from BHS, VHS, and SHS.

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Surface overflow rate (L/min-m2)

0

200

400

600

800

1000

1200

1400

Sep

arat

ion f

unct

ion (

mas

s (%

))

40

50

60

70

80

90

100

BHS

VHS

SHS

Surface overflow rate (L/min-m2)

0

200

400

600

800

1000

1200

1400

Was

hout

rate

(g/m

in)

0

1000

2000

3000

4000

BHS

SHS

Modeled

Measured

BHS

VHS

SHS

BHS

VHS

SHS

Modeled

Measured

Figure 3-2. Plots of measured and modeled Δ mass and washout rate at constant SOR for BHS,

VHS, and SHS units.

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Figure 3-3. Effluent PM trajectories inside the BHS, VHS, and SHS for particle with diameters

of 25 μm, 106 μm, and 300 μm, respectively. Particle density (ρp) is 2.65 g/cm3.

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Figure 3-4. Washed out PM trajectories inside the BHS, VHS, and SHS for particle with

diameters of 10 μm, 25 μm, and 75 μm, respectively. Particle density (ρp) is 2.65

g/cm3.

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Cu

mu

lati

ve

freq

uen

cy d

istr

ibu

tio

n (

%)

0

20

40

60

80

100

Fluid velocity magnitude (m/s)

0.001 0.01 0.1 1

Cu

mu

lati

ve

freq

uen

cy d

istr

ibu

tio

n (

%)

0

20

40

60

80

100

Fluid velocity magnitude (m/s)

0.001 0.01 0.1 1

Cu

mu

lati

ve

freq

uen

cy d

istr

ibu

tio

n (

%)

0

20

40

60

80

100

BHS

Qd = 79.29 L/s

Qd = 31.15 L/s

Qd = 9.05 L/s

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

VHS

SHS

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

0.10 Qd

0.25 Qd

0.50 Qd

0.75 Qd

1.00 Qd

1.25 Qd

Q

Q

Q

Figure 3-5. Fluid velocity magnitude as a function of flow rates in BHS, VHS, and SHS.

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Figure 3-6. Probability of PM separation and washout by the BHS, VHS, and SHS.

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Percent of Qd

0 20 40 60 80 100 120 140

0.7

0.8

0.9

1.0

1.1

1.2

1.3

BHS (Qd = 9.1 L/s)

VHS (Qd = 79.3 L/s)

SHS (Qd = 31.2 L/s)

Percent of Qd

0 20 40 60 80 100 120 140

0

20

40

60

80

100

120

Percent of Qd

0 20 40 60 80 100 120 140

0

1

2

3

4

BHS (Qd = 9.1 L/s)

VHS (Qd = 79.3 L/s)

SHS (Qd = 31.2 L/s)

Percent of Qd

0 20 40 60 80 100 120 140

0

10

20

30

40

SM ( = 0.56,

= 232.64)

Separation function Separation function

Washout function Washout function

SM ( = 0.56,

= 232.64)

Figure 3-7. Gamma parameters as a function of flow rates for BHS, VHS, and SHS (Qd for BHS

is 9.1 L/s, Qd for VHS is 79.3 L/s, and Qd for SHS is 31.2 L/s).

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Percent of Qd

20 40 60 80 100 120 140

Volu

met

ric

effi

cien

cy (

%)

0

10

20

30

40

BHS (Qd = 9.1 L/s)

VHS (Qd = 79.3 L/s)

SHS (Qd = 31.2 L/s)

Figure 3-8. Volumetric efficiency (VE) as a function of flow rates in BHS, VHS, and SHS.

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CHAPTER 4

STEPWISE STEADY CFD MODELING OF UNSTEADY FLOW AND PM LOADING TO

UNIT OPERATIONS

Overview

Rainfall-runoff transports nutrients, particulate matter (PM), and organic materials that

affect the water volume and quality of a water body (Pathapati and Sansalone 2009; Kim and

Sansalone 2008; Wang et al. 2003; Lee and Bang 2000). Designing treatment systems or unit

operations (UOP) in urban areas is further challenged by unsteady hydrologic loads, complexity

of PM and chemical constituents (Liu et al. 2008). Traditional treatment options such as

detention/retention basins are often difficult to implement in urban areas, due to lack of available

land area.

Typically, the performance of UOPs has been assessed by physical modeling. Wilson et

al. (2009) assessed PM removal in baffled hydrodynamic separator (BHS) by pilot-scale testing.

Hunt et al. (2008) tested bioretention pollutant removal and peak flow mitigation. Physical

modeling, while valuable for global performance assessment, is not easily amenable to

retrofitting and iterative design; physical modeling at various scales for UOPs is often limited by

available funds and infrastructure. In recent years, a coupled physical and numerical modeling

approach has proved effective in describing the separation mechanisms of UOPs. Computational

fluid dynamics (CFD) has been applied for both controlled steady flows and particle size

distributions and fully transient rainfall runoff events. Lee et al. (2010) physically tested a vortex

hydrodynamic separator (VHS) under steady flow conditions and applied CFD modeling to

predict PM removal for particle size and flow rates. Dickenson and Sansalone (2009) examined

PM discretization requirements with a CFD model for selected levels of granulometric size

hetero-dispersivity. Pathapati and Sansalone (2009) report that a CFD model was able to

accurately reproduce physical model data for PM separation for a screened HS for steady flow

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rates. This was then extended to unsteady flows and PM loadings (Sansalone and Pathapati

2009), comparing storm event-based captured and effluent PM from a monitored empty bed-

SHS to unsteady CFD model predictions of PM fate. Garofalo and Sansalone (2011)

demonstrated that CFD model accuracy for simulating elution of hetero-disperse PM under

transient hydraulic loadings is dependent on time resolution of the flow field, spatial

discretization of the computational domain, and the PSD size discretization.

CFD can predict fluid flow, mass transfer, chemical reactions, and related phenomena by

solving governing fluid equations using numerical methods. In urban stormwater, CFD has

enhanced the modeling of PM separation for transient flows (Sansalone and Pathapati 2009;

Garofalo and Sansalone 2011) and heterodisperse particle size distributions (Dickenson and

Sansalone 2009) as well as re-entrainment of PM by washout mechanisms (Pathapati and

Sansalone 2012). However, a 3-D numerical model needs longer computational time to simulate

the transient hydrodynamics with variable PSDs than steady state flow (Pathapati and Sansalone

2011). For example, the unsteady computational time for the hydrodynamic separator (HS) is

approximately 3±0.5 days using a workstation equipped with dual quad-core 2.6 GHz processors

and 32 GB of random access memory (Pathapati and Sansalone 2011). To minimize

computational time, a stepwise-steady flow model is suggested as a possible solution. Stepwise-

steady CFD modeling is a series of discretized steady flow steps of rainfall-runoff events.

Identifying numbers of flow steps needed for economical computational time is crucial.

In this manuscript, the PM separation is characterized for stepwise-steady flow, for three

commonly used UOPs: BHS, SHS, and a volumetric clarifying filter (VCF) unit. The main

purpose of this study is to demonstrate modeling of unsteady flow utilizing a series of discretized

Stepwise-steady flow rainfall-runoff model.

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Objectives

There primary objective are addressed in this manuscript. The first objective is to

characterize the PM separation by three HS units across 4 discrete storm events from an urban

impervious surface area. The second objective is to develop a CFD model for stepwise step flow

rates and influent PSDs for three UOPs. The third objective is to compare the results of the

numerical model to paired experimental results and to quantify the differences in the two

approaches.

Methodology

Watershed and Three Hydrodynamic Separator Configurations

The first area of interest is the University of Florida Reitz Union paved surface parking

facility catchment in Gainesville, FL. The schematic plan view of catchment with BHS is shown

in Figure 4-1(A). Considering the minimal slope values characterizing the monitored area,

particularly the paved surface parking facility area (approximate E-W 3% and N-S 1.5% slope),

and the contributing area has the potential to be influenced by rainfall intensity and wind

direction. Depending on the storm event the watershed area is approximately 500 m2.

The second area of interest is directly adjacent to Interstate-10 and City Park Lake in

urban Baton Rouge, Louisiana. Rainfall-runoff directed to SHS and VCF system. A schematic

plan view of the catchment with SHS and VCF is shown in Figure 4-1(A). The drainage system

was designed to intercept the lateral pavement sheet flow from the concrete-paved watershed.

The watershed area is approximately 1088 m2.

Isometric views of three different UOPs are shown in Figure 4-2: BHS, SHS, and VCF.

The design hydraulic operating volumetric flow rates (Qd) are 9.1 L/s for BHS, 15.9 L/s for SHS,

and 5.7 L/s for VCF based on the manufactures specifications. The BHS consists of a bypass

weir and drop tee for directing flow into the sedimentation chamber. The SHS consists of static

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85

cross-flow cylindrical screen (2.4 mm screen opening diameter). The VCF consists of five

gravity-driven radial cartridge filters (RCF) in a vault. Each RCF contains approximately 49.8 kg

of mono-dispersed Al-Ox coated granular media (AOCM)p with a median diameter of 3.5 mm ±

0.8 mm and specific gravity of 2.35 ± 0.01. The total porosity of each RCF is 0.71 ± 0.041. The

five cartridges with filled (AOCM)P are housed in a 1.17 m by 2.12 m detention vault structure.

Detailed description of these three UOPs can be found elsewhere (Cho and Sansalone 2012;

Pathapati and Sansalone 2011; Sansalone et al. 2009). These UOPs operate primarily based on

gravitational PM separation, however, the SHS also performs size-separation screening and VCF

performs filtration through (AOCM)P cartridge.

Physical Modeling Methodology

Monitoring station design was driven by monitoring procedures related to the physical

processes investigated; in particular representative monitoring that requires manual sampling.

Rainfall-runoff PM is monitored across the inlet and outlet of the treatment unit during rainfall

events. Two different watershed areas were investigated: carpark loading in Gainesville, FL, and

highway loading in Baton Rouge, LA. Table 4-1 shows hydrologic indices across storm events

for BHS, SHS, and VCF. Detailed results regarding the watershed, hydrology, pollutant loads

and water chemistry for SHS and VCF are available elsewhere (Sansalone et al. 2009: Kim and

Sansalone 2008). Four events for the each UOPs were monitored and modeled. Table 4-1 and 4-

2 show the hydrologic indices, influent/effluent PM data and PSD data. 10 to 18 samples were

manually taken from influent and effluent drop boxes depending on duration and rainfall-

intensity of each event. The flow rate at the time of sampling, and throughout the storm duration,

was recorded automatically by the flow meter. The mean numbers of sample sets are 13, 13 and

11 for the VCF, PC and HS respectively.

After collecting all the rainfall-runoff samples from the events, the samples were taken

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back to the laboratory for immediate analyses. The efficiency of the system was assessed using

laboratory analyses for suspended sediment concentration (SSC) (ASTM 1999), PSD, and mass

balance. PSD was determined using a laser diffraction particle analyzer (Malvern Instruments:

Hydro 2000G) in a batch mode analysis. SSC analysis was performed to quantify particle

concentration for each effluent sample collected from each run and calculate the effluent mass

load for each storm event. Laboratory analyses were conducted for the replicate influent and

effluent samples consisting of the individual replicate (A or B) samples. Analyses are conducted

within a few hours of the run completion to maintain the same conditions (temperature) and

minimize flocculation.

In order to define unsteadiness of storm events, a unsteadiness parameter ( ) is defined

in this study. The calculation of is as follows:

50

1

mediQdt

dV (4-1)

In this expression dV represents derivative of inflow volume [L3]; dt represents derivative

of time [T]; and Qmed represents median flow rate of storm event [L3/T].

CFD Modeling Methodology

CFD is a branch of fluid mechanics that uses numerical methods to integrate the Navier-

Stokes equations in order to solve fluid flow problems. Three types of full-scale UOPs are

modeled in 3-D using FLUENT v 6.0. A finite volume method (FVM) is applied to discretize the

governing equations into the physical space directly. Modeling in 3-D is less susceptible to the

complications which arise from the lack of geometric symmetry, complex static screen geometry,

vortex flow and gravitational forces on the motion of particles in UOP.

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The governing equations are derived for incompressible flow. The conservation of mass

and momentum are determined using the RANS equations as following

0

z

w

y

v

x

u (4-2)

The momentum equations are as follows:

x momentum:

xg

z

u

y

u

x

u

x

p

z

uw

y

uv

x

uu

)()(

2

2

2

2

2

2

(4-3)

y momentum: ygz

v

y

v

x

v

y

p

z

uw

y

uv

x

uu

)()(

2

2

2

2

2

2

(4-4)

z momentum:

zg

z

w

y

w

x

w

z

p

z

uw

y

uv

x

uu

)()(

2

2

2

2

2

2

(4-5)

In these equation, is fluid density, u, v, and w are Reynolds averaged fluid velocities, g

is sum of body forces, and p is the Reynolds averaged pressure. The momentum continuity

equation for the x, y and z directions can be obtained by assigning values of u correspondingly,

where u is combining of the x, y, and z velocity vector component, since the hydrodynamics of

HS vary as a function of x, y, and z spatial coordinates. The 3-D Navier Stokes equations for a

Newtonian fluid are determined by 3-D velocity vector components.

A k-ε model is suited for clarification and re-suspension function (Morin et al 2008;

Liang et al 2005; Pathapati and Sansalone 2011). Two-equation Reynolds Averaged Navier-

Stokes (RANS) models are applied to swirling multiphase flows in the HS (Pathapati and

Sansalone 2009; Garofalo and Sansalone 2011). The standard k-ε model has been applied to

turbulent flow model in HS successfully (Pathapati and Sansalone 2009; Garofalo and Sansalone

2011).

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Turbulence modeling is widely applied using the two-equation k-ε model. k and ε

equations allow one to determine the turbulent velocity and length scales independently. The

transport equations of the standard k-ε model are expressed by the following equations.

For k and ε:

k

jk

t

j

i

i

Gx

k

xku

xk

t)()(

(4-6)

kCG

kC

xxu

xtk

j

t

i

i

i

2

21)()(

(4-7)

In this expression, is the generation of due to the mean velocity gradients; ,

, are constants; , are turbulent Prandtl numbers for and . The values of C1ε, C2ε, C3ε,

σk and σε used in this model are 1.44, 1.92, 0.09, 1.0 and 1.3 respectively (Launder and Spalding

1974). Newton’s law of viscosity is applied to illustrate the relationship between viscous stresses

and “Reynolds stresses”. It should be noted that eddy viscosity (µ) is a non-physical quantity,

and is expressed by the following equation.

(4-8)

In this expression, is turbulent kinetic energy per unit mass, [L2T

-2] and is the rate of

dissipation of turbulent kinetic energy per unit mass, [L2T

-3].

Per standard application of k-ε model, μ is assumed to be isotropic. Information regarding

flow field and turbulent field, such as velocity profiles, kinetic energy, eddy energy and eddy

diffusivity, are generated from standard k-ε model equations. The standard k-ε model with

standard wall functions is an effective approach to modeling flow through the BHS.

kG k1C

2C

3C k k

2kf

k

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Particulate Phase Modeling

The Euler-Lagrangian approach is applied to model the particle behavior in the UOPs.

This approach is valid for dilute multiphase flows when PM volume fraction is less than 10%

(Elgobashi 1991). A Lagrangian discrete particle model (DPM) is applied to track particles. Due

to the extremely dilute nature of the flow, the DPM assumes there are no particle-particle

interactions. Particle trajectories are calculated by integrating the particle force balance equation.

The Lagrangian DPM is derived from force balances based on Newton’s law describing particle

settling (Pathapati and Sansalone 2009).

p

p

pD

p guuF

dt

du

)()(

(4-9)

24

Re182

pD

pp

D

C

dF

(4-10)

pp

D

aaaC

2

321

ReRe (4-11)

uud pp

p

Re (4-12)

where, up is a particle velocity, u is fluid velocity; ρp is particle density, ρ is fluid density; dp is a

particle diameter; µ is viscosity; a1, a2, and a3 are empirical constants that apply to smooth

spherical particles as a function of the Reynolds number (Morsi and Alexander 1972); and Rep is

a particle Reynolds number.

The PSD is divided into 22 classes of particles based on a standard sieve. The particle

diameter is constant within same class. Particles are tracked for each steady flow rate. The

particles that become trapped in the HS are considered to have been removed through HS. The

particle removal efficiency is calculated by the following equation.

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90

(4-13)

In this expression, is the number of particles that remain in the baffled HS, and is

the number of particles injected at the inlet.

Modeling of Static Screen and Cartridge

The static screen and cartridge filter are modeled as a porous perforated plate with the

addition of a momentum source term to the standard fluid flow equations (Pathapati and

Sansalone 2009). The source term is composed of two parts: a viscous loss term and an inertial

loss term. For simple homogeneous media and surficial filter, the sink term equation is as

follows:

imagiii vvCvS

2

12

(4-14)

In this expression, S i is the source term for the i th momentum equation, α is permeability,

C2i is the inertial resistance factor, v i is the velocity in the i th momentum equation, and vi is the

velocity in a computational cell. The momentum sink contributes to the pressure gradient in the

porous computational cell, creating a pressure drop that is proportional to the fluid velocity in the

cell.

Flow in porous media has traditionally been modeled analytically using comparisons to

pipe/conduit flow and specifying analogous parameters such as the hydraulic diameter and

roughness coefficient. Laminar flow (Re < 10) through porous media has been successfully

modeled by applying Darcian-type equations. Models such as Blake-Plummer and Carman-

Kozeny equations were developed to account for transitional flow regimes. These models were

extended by Ergun (1952) to account for turbulent flow. The Ergun equation for packed beds

applies to flow regimes from laminar to turbulent and is expressed by the following equation.

100*I

HS

N

Np

H SNIN

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91

2

33

2

2

)1(75.1)1(150S

m

S

m ddL

p

(4-15)

In this expression, Δp is the pressure drop across the media, L is the length of the packed

bed, μ is the fluid viscosity, dm is media particle diameter, η is the total porosity of the packed

bed, v is the superficial velocity through the packed bed and ρ is fluid density.

The permeability (α) and the inertial resistance coefficient (C2) can be expressed as

follows.

2

32

)1(150

md

(4-16)

32

)1(5.3

mdC

(4-17)

CFD Parameters

CFD parameters for three UOPs are shown in Table 4-3. The volume fraction of

secondary phase (particle) is less than 0.1% in Table 4-3 and can be applied to a Lagrangian

particle tracking approach. Second order tetrahedrons element type is utilized to discretizing the

computational domain (Qi and Lin 2006). The standard k-ε model was applied in this study. A

secondary-order upwind scheme was utilized to solve for flow parameters (Barth and Jespersen

1989; Pathapati and Sansalone 2009). The operating pressure was 14.7 psi (atmospheric). DPM

particle density is 2.65 g/cm3, and particle diameters range from 1 micron to 9750 micron. DPM

boundary conditions include a ‘reflection” at the wall and an ‘escape’ at the effluent outlet. The

iterative convergence limit was set at 10-3

and applied to continuity, momentum, turbulent

kinetic energy, and dissipation rate (Ranade 2002).

Stepwise Step Modeling Removal and PM Separation

The number of stepwise-steady steps is determined based on creating a cumulative

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92

distribution function (CDF) of flow rates entering the UOPs. The first step was to develop a CDF

for flow for each storm event. Following this step, the influent samples and effluent samples are

plotted on the CDF. This provides an idea of the number of discretization steps needed. The

number of stepwise-steady steps required to accurately represent the transient PM clarification

varied predominantly as a function of the fluctuation of influent flow rates – monitored by

correlating volumes, peak flow rates, elapsed time and sampling time.

Influent PSD was input into the model at the appropriate flow rate for the stepwise steady

model. The influent particles were tracked through the UOP after tracking for a given tracking

length. An unbiased tracking length was obtained by tracking massless ‘tracer’ particles through

the UOP and iteratively increasing tracking length until no more tracer particles would exit the

system. Typically, this was done with a ± 1% particle balance error.

Since rainfall-runoff flow is discretized with CDF throughout entire storm event duration,

PM separation can be calculated at the each stepwise steady flow rate. PM separation at the ith

stepwise-steady flow rate, ηPM(i) is calculated as follows.

100)( Inf

UOPiPM

N

N (4-18)

Ni is the number of particles injected in the influent and NUOP is the number of particles

that incomplete in the unit operation after the specified tracking length. Overall PM separation,

ΣηPM is calculated as follows.

InfiPM

nn

n

tq

q

PM M )(

)(

)1(

)(

)0(

(4-19)

In this expression, q(0) and q(t) are the influent flow rates, n(t1) and n(tn) are influent

samples at time t1 and tn respectively. MInf is the influent PM mass.

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93

Result

Event Hydrology Indices

Event-based hydrological indices including PDH, drain, trunoff, as well as Vin and Qp and

Qmed,, were monitored and recorded for a total of 4 storm events for each UOPs as shown in

Table 4-1. Observed events varied in duration from 31 to 415 min, total rainfall-runoff volume

ranged from 594 to 48306 L, median flow rate ranged from 0.1 to 2.4 L/s, peak flow rate ranged

from 0.6 to 25.3 L/s, and rainfall depths ranged from 2.5 to 71.4 mm. The watersheds had the

dominant anthropogenic activity of traffic resulting from the highway and parking lot.

The values of for each hydrographs are summarized in Table 4-1. Unsteadiness

parameter equation was modified from Garofalo and Sansalone (2011). The normalized value of

time with respect to the peak time was not applied to this study due to the difference of peak time

among all storm events. Based on measured data of Pathapati and Sansalone (2009) as well as

Garofalo and Sansalone (2011), the of actual hydrographs from a watershed are typically

ranging from 0 to 6; considered quasi-steady, 6 to 14; considered unsteady, and 14 or greater;

considered highly unsteady.

The values of for each hydrographs are summarized in Table 4-1. The values of for

BHS ranged from 2.99 to 15.73. These values indicate that the storm events for BHS have from

quasi-steady to highly unsteady influent flows. The values of for SHS ranged from 1.42 to 8.24.

These values indicate that the storm events for SHS have from quasi-steady to unsteady influent

flows. The values of for VCF ranged from 3.59 to 17.46. The quasi-steady value ranged from

0 to 6 is comparable to 3.59 and 4.25 for the physical model hydraulic and PM loading (Garofalo

and Sansalone 2011). Also, unsteadiness of two storm events for VCF, which ranged from 11.89

to 17.46, are considered unsteady to highly unsteady.

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94

)(

)(

)(

1

x

ex

xf (4-20)

In this expression, Γ is the gamma function; γ is the shape factor and β is the scaling

factor. γ and β parameters were estimated by minimizing the sum of squared errors (SSE),

resulting in maximizing the coefficient of determination between the measured and modeled data.

Below, F(x) is the cumulative gamma distribution and x represents flow rate in Table 4-1.

x

dxxfxF0

)()( (4-21)

Influent and effluent flow rates are heterodisperse throughout all storm events for the

three UOPs, BHS and SHS have same influent and effluent flow rates. Table 4-2 summarizes the

influent PM mass of each storm event, modeled effluent PM mass comparison with measured

effluent PM mass, the median influent and effluent PSDs across runoff events monitored for the

BHS, SHS, and VCF as a mass-based cumulative PSD. Cumulative PSDs were examined and

results were described by an optimized cumulative gamma distribution function summarized in

Table 4-2. The runoff median PM diameter (d50m) ranged from 72 to 182 μm for BHS, from 43 to

300 μm for SHS, from 15 to 99 μm for VCF.

Results indicated that BHS has same shape and scaling factor from both influent and

effluent. The influent and effluent flow rates are equal in the BHS since it does not have a screen

or cartridge in the unit. The drop tee section splits the inflow to the sediment chamber providing

dissipation of turbulence and flow velocity.

SHS consists of screen area with 2400 μm aperture size. The screen area did not result in

change in a difference in influent and effluent flow rates. The dominant mechanism of PM

separation of SHS is gravitational although the inertial separation occurs at low flow rates.

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95

VCF consists of a sedimentation chamber with five RCF. The RCF results in dissipation

of turbulent energy and flow velocity (Pathapati 2009). The RCF generates 5 mm median head

loss (Sansalone et al. 2009) resulting in a lag between inflow and outflow from the VCF unit.

Gamma parameter values are different between inflow and outflow. The mechanisms of PM

separation for VCF are gravitational separation and filtration. Filtration with (AOACM)P

increases PM removal.

Probabilities of PM Separation by the BHS, SHS, and VCF

Modeled stepwise PM separation as a function of PM diameter and flow rate is illustrated

in Figure 4-4 via 3-D surface plots. The upper limit flow rate was chosen as the maximum

monitored flow rate among UOPs. The maximum flow rate was approximately 25 L/s from April

26, 2009 storm event. BHS and VCF separated all PM larger than 300 µm across the entire

range of flow rates up to 25 L/s. BHS displays a fairly consistent probability of PM separation

throughout the entire flow rate range (0 to 25 L/s). One advantage of the BHS The prevention of

separated PM from being re-suspended due to the internal bypass and drop tee configuration.

In contrast, the SHS tends to separate coarser particles (> 800 µm) across the entire range

of flow rates up to 25 L/s. At the highest flow rate (25 L/s), all three UOPs separated PM larger

than 2000 µm.

Table 4-2 summarizes PM separated by each UOPs modeled with a cumulative gamma

distribution function. In this section, the gamma probability density function represents PM

separation as a function of flow rate, Q, and particle diameter, symbolized as x in equation 4-17.

Γ is the gamma function; γ is the shape factor and β is the scaling factor. Also, F(x) is the

cumulative gamma distribution in the equation. These parameters are shown in Figure 4-3 as a

function of flow rates for each eluted PSD. Conceptually, the shape factor may be thought of as

uniformity of the eluted PSD as compared to the heterogeneity of the influent PM and pre-

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96

deposited PM gradation. These parameter trends illustrate that BHS and VCF are able to separate

a large range of PM throughout entire flow rate ranges. In contrast, SHS depends on coarser PM

removed according to widely ranged γ.

Stepwise Steps Comparison to Measured Data

The stepwise steady flow CFD model was performed with each discretized steady flow

level. The discretized steady flow steps were determined using a cumulative density function

(CDF) across flow rates during the unsteady storm events, illustrated in Figure 4-4 to 4-6. The

CDFs show the frequency of flow rates entering the UOPs. Results of stepwise steady flow

modeling for the three UOPs are compared with results from experimentally validated CFD

models, as shown in shown in Figure 4-4 to 4-6. The CFD model results of PM mass are

compared to measured data throughout 4 storm events for the three UOPs in Table 4-2. There is

a significant difference in PM removal among the three UOPs, especially between SHS and the

two other UOPs (BHS and VCF). BHS has 64.7 to 95.1% PM removal; SHS has 38.3 to 62.0%

PM removal; and VCF has 84.0 to 97.1% PM removal. Results shows that PM removal is a

significantly less for the SHS, while VCF has the highest PM removal.

The absolute relative percent difference (RPD) is used to evaluate the CFD model results

with respect to the full-scale physical model. RPDs are shown in each Figure for the three UOPs.

Absolute RPD is calculated by the following equation.

100datameasured

data)modeleddata(measuredRPDabsolute

(4-22)

Results from the lowest flow rate to the highest flow rates indicate that the stepwise steady

CFD model predictions of PM removal reproduce the measured data with an absolute RPD less

than 10% across 12 total events. The separated PM mass and RPD between measured and

modeled PM separated in the three UOPs is provided for each event in Table 4-2.

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97

Hydrographs are shown in Figure 4-4 to 4-6, and stepwise steady models to monitored

effluent PM mass cumulatively are shown utilizing rainfall-runoff PSDs. In additional analyses

the discretization steps for the stepwise steady flow model are further increased by utilizing flow

rates and event duration time between monitoring points of PSDs. The mean number of steps is

is 35 for BHS, 38 for SHS, and 38 VCF. According to numbers of stepwise steady steps, BHS

had mild storms than other two UOPs since the more steps needed depending on fluctuation of

runoff flow rates. The solid and dashed lines represent effluent PM mass predicted by the

stepwise steady and monitored PM mass, respectively. All three figures are representative of

monitored storm event PM loads. These results illustrate that the stepwise steady model for the

three UOPs is representative of monitored PM across each events.

The error at each step is calculated relative to the monitored PM separation for each UOP.

Figure 4-7 depicts overall stepwise steady CFD modeling error as a function of integrating over

an increasing number of stepwise steps predictions for PM separation. The RPDs for each UOP

has a steep decreasing trend in error, with increasing discretization of flow rates. Due to the

inherent effect of the filters on dissipating turbulent energy, the effect of changing flow rates on

the PM separation response is lower for the VCF compared to the BHS and SHS. This is

evidenced by the lower RPD for the VCF compared to the BHS and SHS. Stepwise-step CFD

modeling for three UOPs reproduce measured PM within 10% RPD ranges as well as

significantly lower computational time.

According to previous studies (Pathapati and Sansalone 2011), the computational times

of the unsteady flow CFD simulations for HS is a factor of approximately 16 times greater than

for the stepwise steady CFD model. Stepwise steady flow modeling was used to successfully

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98

reproduce unsteady flow results and PM loadings in this study. Stepwise steady steps modeling

will therefore be utilized for unsteady HS modeling with less computational times in the future.

Summary

Unsteady flow events and PM separations with three UOPs in urban source area water

sheds were examined, providing variable volumetric control. In this study, four source area

rainfall-runoff events are monitored and treated real time by the three UOPs. The BHS unit is

installed in a carpark area in Gainesville, FL, and the other two UOPs are installed in a high way

area in Baton Rouge, LA. The main source constituent from both watershed areas is primarily

influenced by traffic.

The main parameters in the CFD model that can be "tuned" are standard Morsi and

Alexander drag coefficients and the wall functions in the k-epsilon turbulence model. Stepwise

steady modeling was able to successfully reproduce experimental data s utilizing standard values

for the drag coefficients and wall functions. No calibration or "tuning" was required.

The main purpose of this study was to model unsteady flow PM separation across a

rainfall-runoff event by utilizing CFD model predictions at discrete steady flow rates. Stepwise

steady CFD modeling was conducted without any tunable parameters. The only thing that can be

changed as CFD parameters was the standard Morsi and Alexander drag coefficient; however,

this drag coefficient was not tuned. The standard Morsi and Alexander drag coefficient was

given in Table SI-1 (Morsi and Alexander (1972).

Stepwise steady modeling showed that if PM separation data as a function of particle

diameter is available at steady flow rates, this can be integrated at a fine degree of discretization

to predict PM separation for unsteady rainfall-runoff events. Once a steady flow CFD database is

established across a wide range of flow rates, this can be used to predict fully transient rainfall-

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99

runoff events. This results in faster modeling time for predicting unsteady behavior, compared to

transient modeling for an entire storm.

CFD modeling of PM separation is based on the assumption of discrete particle settling.

In order to check if this assumption holds true across different flow configurations, validation of

models with experimental data is advised. Physical modeling of UOPs with careful QA/QC is

required to be carried at at least representative flow rates, with the required PSDs.

This study accomplished that each stepwise steady flow results compared to monitored

data of PM separation with RPD less than 10% for three UOPs. Stepwise steady steps are

determined by based on CDF. The number of stepwise steps depends on volume, storm duration

time, and strength of storm events. Comparing PM mass from each three UOPs, the modeled

data consistently match with the monitored data although runoff flow rates are randomly

distributed through storm duration time. Results indicate that the stepwise steady flow model

effectively predicts the monitored storm event data in UOPs.

Fully unsteady CFD modeling can provide more accurate results than other modeling

results; however, a stepwise steady flow CFD model gives less than 10% error for monitored

unsteady storm events with more than 35 flow steps. All three devices show a steep decrease in

error with increasing steady steps in Figure 4-7. The error is hypothesized to theoretically reach

zero as the number of steady flow steps approaches infinity. Overall we see that the VCF has the

lowest range of error. In general, the effect of unsteady flow on the VCF is mitigated by the

presence of filters - which act like a resistance, and reduce the impact of smaller fluctuations in

flow rates. This study concludes that a stepwise steady approach is able to successfully model

PM separation, across 3 mechanistically different UOPs, and is validated with representative

monitored data. The stepwise-steady step model reproduced PM separation with significantly

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100

more efficient computational time than a fully unsteady CFD model. This stepwise-steady CFD

modeling approach can reduce simulation time approximately 14-18 times when compared to a

fully transient analysis.

In consideration of these results, the use of stepwise steady CFD modeling to quantify

PM separation from UOPs is validated with unsteady hydrologic indices and infers economic

with reducing computational time as well as holding a great promise for future implication.

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101

Table 4-1. Hydrologic indices across storm events for BHS, SHS, and VCF.

Type of

UO

Storm

event

Vin

(L)

PDH

(hr)

drain

(mm)

Qmed

(L/s)

Qpeak

(L/s)

trunoff

(min)

Gamma distribution

parameters

Influent

hydrograph

Effluent

hydrograph

γ β γ β

BH

S

(2010)

29 June 7504 192 20.6 1.5 17.6 15.73 40 0.74 3.26 0.74 3.26

11 July 2362 261 11.7 0.3 5.2 9.47 42 0.34 23.37 0.34 23.37

28 July 8316 36 19.1 1.2 16.0 7.87 50 0.36 7.82 0.36 7.82

14 August 594 28 2.5 0.3 2.5 2.99 31 0.61 0.32 0.61 0.32

SH

S

(2004 –

Ju

ne

30,

2005)

14 March 28464 204 26.2 0.7 6.4 2.66 415 0.74 1.46 0.74 1.46

20 August 17687 26 17.3 0.3 17.5 7.82 60 0.22 18.56 0.22 18.56

14 October 1672 84 2.6 0.1 0.6 1.42 201 0.40 0.41 0.40 0.41

30 June 5856 143 19.1 0.3 9.4 8.24 57 0.46 7.23 0.46 7.23

VC

F

(2006)

21 April 2927 927 4.1 0.1 13.4 17.46 49 0.12 3.16 0.87 0.26

29 April 48306 84 71.4 2.4 25.3 11.89 177 0.69 6.45 0.88 4.35

04 July 2779 352 3.8 0.2 6.2 3.59 68 0.31 2.40 0.46 1.42

05 July 3838 25 5.6 0.2 7.9 4.25 94 0.25 2.77 0.21 3.26

Vin, PDH, drain, Qmed, Qpeak, turnoff represent volume of rainfall-runoff, previous dry hours, event

duration, median flow rate, peak flow rate, rainfall-runoff duration, respectively.

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Table 4-2. CFD model comparisons to measured data across storm events for BHS, SHS, and

VCF.

Type of

UO

Storm

event

Influent

PM

Effluent

PM d50m

Gamm distribution

parameters

Influent PM Effluent PM

Measured

(g)

Measured

(g)

Modeled

(g)

Influent

(μm)

Effluent

(μm) γ β γ β

BH

S

(2010) 29 June 6997.6 1285.1 1218.8 72 49 1.18 78.17 1.26 50.89

11 July 1001.6 195.4 202.2 113 36 0.90 196.99 1.13 45.17

28 July 2404.5 848.8 769.9 110 48 0.90 193.13 0.99 98.09

14 August 195.1 9.6 10.3 182 43 0.85 336.20 0.79 99.73

SH

S

(2004 –

Ju

ne

30,

2005)

14 March 4949.1 2539.3 2441.9 43 20 0.70 137.02 1.42 18.41

20 August 10591.0 4022.4 3774.7 300 52 0.44 2740.89 1.06 69.92

14 October 541.3 266.5 246.1 45 13 0.63 124.07 1.88 8.83

30 June 4043.8 2494.5 2328.8 69 39 0.73 212.51 1.28 39.94

VC

F

(2006) 21 April 4161.7 119.7 123.8 15 5 0.70 34.93 1.26 5.27

29 April 10466.2 1678.7 1622.6 99 24 0.48 452.09 0.65 71.68

04 July 831.8 100.8 91.6 26 21 0.67 63.14 1.23 27.34

05 July 1065.1 138.7 148.6 18 18 0.68 56.14 1.51 16.64

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Table 4-3. CFD parameters for BHS, SHS, and VCF.

CFD parameters BHS SHS VCF

Mesh size of geometry 3.2e+06 2.1 e+06 5.2e+06

Element type Second order tetrahedrons

Turbulence model Standard -

Wall functions Realizable

Solution method SIMPLE, segregated

Momentum Second order upwind

Turbulent kinetic energy Second order upwind

Turbulent dissipation rate Second order upwind

Operating pressure (kPa) 101.35

Operating temperature (K) 288.16

Volumetric design flow rate (L/s) 9.1 15.9 5.7

Volume fraction of

secondary phase (%) 0.01-0.07 0.01-0.05 0.01-0.03

DPM particle density (g/cm3) 2.65

DPM particle diameter (µm) 1-9750

DPM drag coefficients Morsi and Alexander

DPM boundary conditions Walls – ‘reflect’ polynomial, Outlets – ‘escape’

Conver

-

gen

ce

lim

its

Continuity 10-3

Momentum 10-3

Turbulent kinetic energy 10-3

Dissipation rate 10-3

SIMPLE represents semi-implicit method for pressure linked equation. (Baffled hydrodynamic

separator – BHS, screened hydrodynamic separator – SHS, volumetric clarify filtration – VCF)

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Figure 4-1. Plot A is a plan view schematic of a BHS testing watershed in Gainesville, FL. Plot

B is a plan view schematic of SHS and MFS testing watershed in Baton Rouge, LA.

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Figure 4-2. Isometric views of the geometries of A) baffled hydrodynamic separator (BHS), B)

screened hydrodynamic separator (SHS), and C) volumetric clarifying filtration

system (VCF).

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0.0

0.2

0.4

0.6

0.8

1.0

110

1001000

05

1015

2025

Pro

bab

ilit

y o

f P

M s

epar

atio

n

dp (m)Q (L

/s)

0.0

0.2

0.4

0.6

0.8

1.0

110

1001000

05

1015

2025

Pro

bab

ilit

y o

f P

M s

epar

atio

n

dp (m)Q (L

/s)

0.0

0.2

0.4

0.6

0.8

1.0

110

1001000

05

1015

2025

Pro

bab

ilit

y o

f P

M s

epar

atio

n

dp (m)Q (L

/s)

BHS

Qd = 9.1 L/s

SHS

Qd = 15.9 L/s

VCF

Qd = 5.7 L/s

VCF

Q (L/s)

0 5 10 15 20 25

1

10

100

0

50

100

150

200

250

300

1.67Q-0.05

= 0.87Q1.56

SHS

0 5 10 15 20 25

1

10

100

0

50

100

150

200

250

300

= 2.66Q-0.17

= 18.45Q0.83

BHS

0 5 10 15 20 25

Q (L/s)

0 5 10 15 20 25

1

10

100

0

50

100

150

200

250

300

= 5.63Q-0.26

= 0.26Q1.91

Figure 4-3. Probability of PM separation by the baffled hydrodynamic separator (BHS), screened

hydrodynamic separator (SHS), and volumetric clarify filtration (VCF). γ and β

represent shape factor and scaling factor.

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Elapsed Time (min)

0 10 20 30 40F

low

rat

es (

L/s

)

0

4

8

12

16

20

Eff

luen

t P

M m

ass

(g)

0

400

800

1200

1600

2000Runoff

Modeled

Measured

= 15.73

Vin = 5704 L

Qmed = 1.5 L/s

Qpeak = 17.6 L/s

RPD = 5.4%

29 June 2010

Flow Rate (L/s)

0 3 6 9 12 15

CD

F (

%)

0

20

40

60

80

100

Runoff

Influent Sample

(n = 10)

Effluent Sample

(n = 10)

BHS

(Qd = 9.05 L/s)

Figure 4-4. Plot A) is a cumulative distribution function (CDF) for the range of rainfall-runoff

flow rate (L/s) in baffled hydrodynamic separator (BHS). Plot B) is flow rates (L/s)

and effluent PM mass (g) as a function of elapsed time in BHS (Number of flow steps

= 37). , Vin, Qmed, Qpeak, and RPD represent unsteadiness parameter, median flow

rate, peak flow rate, and relative percentage difference.

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Elapsed Time (min)

0 10 20 30 40 50 60F

low

rat

es (

L/s

)

0

4

8

12

16

20

Eff

luen

t P

M m

ass

(g)

0

1000

2000

3000

4000

5000

Runoff

Modeled

Measured = 7.82V

in = 17687 L

Qmed

= 0.3 L/s

Qpeak

= 17.5 L/s

RPD = 6.2%

20 August 2004

Flow Rate (L/s)

0 3 6 9 12 15 18

CD

F (

%)

0

20

40

60

80

100

Runoff

Influent Sample

(n = 15)

Effluent Sample

(n = 14)

SHS

(Qd = 15.9 L/s)

Figure 4-5. Plot A) is a cumulative distribution function (CDF) for the range of rainfall-runoff

flow rate (L/s) in screened hydrodynamic separator (SHS). Plot B) is flow rates (L/s)

and effluent PM mass (g) as a function of elapsed time in SHS (Number of flow steps

= 40). , Vin, Qmed, Qpeak, and RPD represent unsteadiness parameter, median flow

rate, peak flow rate, and relative percentage difference.

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Elapsed Time (min)

0 30 60 90 120 150 180F

low

rat

es (

L/s

)

0

6

12

18

24

30

Eff

luen

t P

M m

ass

(g)

0

400

800

1200

1600

2000Runoff

Modeled

Measured

29 April 2006

Flow Rate (L/s)

0 5 10 15 20 25

CD

F (

%)

0

20

40

60

80

100

runoff

Influent Sample

(n = 18)

Effluent Sample

(n = 18)

VCF

(Qd = 5.7 L/s)

= 11.89

Vin

= 48306 L

Qmed

= 2.4 L/s

Qpeak

= 25.3 L/s

RPD = 5.7%

Figure 4-6. Plot A) is a cumulative distribution function (CDF) for the range of rainfall-runoff

flow rate (L/s) in volumetric clarify filtration (VCF). Plot B) is flow rates (L/s) and

effluent PM mass (g) as a function of elapsed time in VCF (Number of flow steps =

49). , Vin, Qmed, Qpeak, and RPD represent unsteadiness parameter, median flow rate,

peak flow rate, and relative percentage difference.

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(A) BHS

Number of steady flow steps (#)

0 10 20 30 40 50

Abso

lute

RP

D (

%)

10

100

Mean of error

(B) SHS

Number of steady flow steps (#)

0 10 20 30 40 50

Abso

lute

RP

D (

%)

10

100

Mean of error

(C) VCF

Number of steady flow steps (#)

0 10 20 30 40 50

Abso

lute

RP

D (

%)

10

100

Mean of error

BHS

Abso

lute

RP

D (

%)

10

100

SHS VCF

(D) Variation of absolute RPD

Figure 4-7. Mean and variation of the stepwise steady model absolute relative percentage

difference (RPD) with increasing number of monitoring points for BHS, SHS, and

VCF. The lower right quartile box plot is the variation of absolute RPDs across the

number of steps.

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CHAPTER 5

REMOVAL AND PARTITIONING OF NITROGEN AND PHOSPHORUS OF NUTRIENTS

IN HYDRODYNAMIC SEPARATOR ON URBAN RAINFALL-RUNOFF PARTICULATE

MATTER GENERATED FROM IMPERVIOUS SURFACE CARPARK

Overview

Stormwater runoff can be a significant source of Nitrogen (N) and Phosphorus (P)

leading to eutrophication (Field and Sullivan, 2002; Heaney et al., 1999; Lee and Bang, 2000;

Novotny and Witte, 1997). Sources of N (P) include non-point sources in non-urban areas such

as biogenic materials and fertilizers (Turner et al., 1999; Zhang and Jørgense 2004) as well as

urban pavements (Wang et al. 2003). Partitioning controls the transport and cyclic dynamics of P

in land/water ecosystems and is key to understanding impacts on aquatic ecosystems (Brezonik

and Stadelmann 2002). The export of N in stormwater runoff poses several threats to

environmental and human health and consumes a large share of public resources (Parker et

al.2000, NRC 2001). Nitrogen loading is primarily a function of processes that affect

concentrations rather than of the geometry of the catchment which conveys precipitation into

runoff (Lewis and Grimm 2007).

In addition to the partitioning of total nitrogen (TN) and total phosphorus (TP) into the

dissolved phase, N (P) distributes across the PM size spectrum ranging from less than 1 μm to

greater than 4,750 μm in rainfall-runoff. Partitioning, mobility and fate of P are dependent on

PM size ranges (Shinya et al. 2003; Zhou et al. 2005; Berretta and Sansalone 2011). Several N

and P treatment methods were investigated by previous studies, such as infiltration and detention

basins (Bartone and Uchrin 1999; Dechesne et al. 2005); constructed wetland systems (Gervin

and Brix 2001; Seo et al. 2005); sedimentation tank systems (Stenstrom et al. 2002); vegetative

controls (Barrett et al. 1998); filtration with floating media filters (Visvanathan et al. 1996); and

urban wet detention ponds (Wu et al. 1996; Comings et al. 2000; Wang et al. 2004).

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Control of PM is challenging in an urban environment, due to complex hydrology, and

constraints of land availability and infrastructure. Many of treatment methods are based on

volumetric control and therefore may not be applicable in situations where land availability is

limited. In such situations, hydrodynamic separators (HS) are commonly used to treat runoff

(Kim and Sansalone 2008). However, while HSs can be effective in removing particulate bound

N (P), they face the problems of re-uptake of N (P) from captured PM deposited during previous

storm events. Additionally, because HS are not designed to capture the entire runoff volume of a

storm, determining efficiency is dependent on understanding the transport and partitioning of N

(P) during an individual storm event. Understanding efficiency and P and N distributions as a

function of particle size is necessary for appropriate sizing, retrofitting and optimizing of HS

type units.

In this study, separation and partitioning of particulate matter (PM) bound nitrogen (N)

and phosphorus (P) in a baffled hydrodynamic separator (BHS) located in an urban car park with

an impervious surface are investigated during 10 storm events. The results are examined as a

function of hydrology. A wide gradation of captured PM from BHS was analyzed after 10 storm

events were completed.

Objectives

The first objective is to determine the distribution of N and P across suspended, settleable

and sediment fractions in rainfall-runoff for 10 discrete storm events from an urban carpark with

an impervious surface. The second objective is to examine equilibrium partitioning of N and P

between dissolved and particulate phases in rainfall-runoff. The last objective is to investigate

the N and P separation in BHS as a function of particle size distribution (PSD) and treated

volume.

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Methodology

Catchment

The experimental site is illustrated in Figure 5-1. The site is located at an urban

impervious surface area (Parking lot in University of Florida). Depending on the intensity of the

storm event, the catchment area ranges around ~500 m2. The catchment area slope is

approximately 3% E-W and 1.5% N-S. There are vegetated islands between parking spaces in

the watershed which can contribute biogenic materials to impervious surface area. The overall

experimental setup consists of the following components: a system pipe to deliver the rainfall-

runoff from the catchment to a BHS (10.1 m), a Parshall flume equipped with an ultrasonic

sensor for measuring flow rates, a drop box for influent sampling, and a gate valve to divert flow

to BHS. This make it possible to monitor the performance of each device for a given storm or

series of storms. The installation is shown in Figure 5-1.

Data Acquisition, Management, and Sampling

The rainfall depth was collected by tipping bucket rain gauges manufactured by Texas

Electronics Inc. (0.254 mm bucket capacity). Flow measurement from the watershed was

monitored with 25.4 mm Parshall flume. A 30 kHz ultrasonic sensor (model Shuttle Level

Transmitter, MJK Inc.) connected to a Campbell-Scientific CR 1000 (Campbell Scientific, Inc.)

is used for flow depth monitoring in the Parshall flume and for real-time data logging.

Both influent and effluent samples from each event were sealed within five separate

Nalgene polypropylene screw closure bottles. Three of the bottles were 1-L bottles and were

used for the particle size distribution (PSD) analysis, PM separation and analysis, nutrient (N and

P) analysis and metal analysis. The other two bottles were 0.5-L and were both used for the

probe analysis and some of the PM analysis. All of the bottles were taken in succession of one

another and thus considered identical in composition. Influent samples were taken manually by

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114

the grab method following the parshall flume and before the runoff reached the dropbox.

Effluent samples were also taken manually by the grab method immediately following the

effluent pipe located on the side of the BHS unit.

PM Separation

The 1.1-L samples were used to recover a sizeable quantity of sediment particles by

passing the stormwater through the 75 μm (No. 200) sieve. All the sediment particles recovered

on the sieve for each sample were carefully collected using a spatula and a stainless-steel pick

and then placed in a clean, labeled and tared Petri dish. The 1.0-L samples are also used for

turbidity analysis and then screened to separate the sediment size particles by using the 75 μm

(No. 200) sieve. The actual volume of the nominal 1-L runoff sample was first measured (since

approximately 100-mL were utilized) using a graduated cylinder. The 1.0 L of solution that was

passed through the sieve was recovered and placed into an Imhoff Cone without the loss of any

additional PM. Each Imhoff Cone with a nominal 1-L of stormwater was set aside for a quiescent

settling of 60 minutes. The settleable PM settled to the bottom of the Imhoff cone and these

particles were carefully recovered from the Imhoff Cones by slowly decanting the supernatant

from the cone and obtaining the particles from the bottom of the cone in clean, labeled and tared

Petri dishes. Replicate samples were obtained for each sample; hence all particle fractions were

recovered from the replicate (A and B) runoff samples. Part of the supernatant recovered from

each Imhoff Cone (almost 50 mL) was then passed through a fractionation column using an air

pump. The filtrate was directly used to determine concentrations of Ions (50 mL) like Nitrate

(NO3-), Phosphate (PO4

3-) and dissolved COD. All these constituents were measured by

spectrophotometer (Hach - DR/5000).

The remaining supernatant for each sample replicate was then used to determine the

suspended PM fraction. 100 mL from the well-mixed supernatant was used to separate the

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suspended PM through a vacuum pump and membrane filters. The 0.45 μm membrane filters

were then dried in the oven at 105 °C. The filters were prepared in advance and tare-weighed

before use. The difference in weight gives the mass of the PM. A sub-sample of the supernatant

was used to calculate the suspended particulate-bound total nitrogen (TN) (Suspended-TN). As

for the measurement of metals, the Inductively Coupled Plasma - Mass Spectrometry (ICP-MS)

was used.

Water Chemistry Analysis

Water quality parameters, such as pH, salinity, dissolved oxygen (D.O), redox,

conductivity, total dissolved solids (TDS), and alkalinity were measured on rainfall-runoff

samples within 24 hrs. Alkalinity was measured in triplicate using Method 2320B (APHA 1998).

Conductivity and TDS were measured with a conductivity meter in replicate. The probes are

standardized with a 3-point curve prior to analyses. A pH meter with a 3-point calibration was

used to measure the pH of the samples in replicate. The samples were filtered through a pre-

weighed 1.2 µm glass-fiber filter and dried to determine the suspended solid concentration

(SSC).

Nitrogen and Phosphorus Analysis

Samples were fractionated into dissolved and particulate phases. The particulate bound

phosphorus and nitrogen analyses are performed using the method from Standard Methods for

Water and Wastewater (APHA et al. 1998). After acid digestion of particles and the filtrate, the

concentration values of total dissolved and particulate bound phosphorus and nitrogen were

obtained by Cadmium Reduction Method # 8039. To determine the concentration of nitrate and

phosphate, a spectrophotometer (Hach - DR/5000) is used.

The quantity of suspended PM bound N is obtained by subtracting the total dissolved

nitrogen (TDN) fraction from the supernatant N fraction. In particular a sample from the

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supernatant obtained after the removal of the sediment and settleable particles from the 1.0 L

sample solutions is acid-digested. Similarly a sample from the filtrate is also acid-digested as

mentioned. The TN from both the supernatant and filtrate samples is obtained and the difference

of these values gives the TN bound to suspended particles.

Partitioning Indices for Nitrogen and Phosphorus

The TN and Total Phosphorus (TP) are the sums of the dissolved fraction concentration

and particulate-bound fraction concentration of N (P), respectively. Therefore TN and TP can be

expressed with dissolved and particulate-bound fraction, as in the following equations:

pd

d

pd

dd

MM

M

CC

Cf

(5-1)

pd

p

pd

p

pMM

M

CC

Cf

(5-2)

In this expression, Md is dissolved mass; and Mp is the particulate-bound mass. If fd > 0.5, N or P

is mainly in dissolved form, otherwise N (P) is predominantly in particulate-bound form

(Sansalone and Buchberger 1997).

The partitioning coefficients, Kd, is defined as the ratio of the equilibrium concentration

of a dissolved fraction mass with respect to particulate-bound fraction mass. The equation is as

follows.

d

Sd

C

CK (5-3)

In this expression Kd is the equilibrium partitioning coefficient between particulate bound mass

and dissolved mass (L/Kg) while Cs is the particulate bound N (P) mass (mg/g of dry particulate

mass). The partitioning coefficient can be used to evaluate the distribution between dissolved and

particulate bound N (P).

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Hydrologic and Loading Parameters

Hydrologic and transport parameters were measured for each rainfall event, and are

shown in Table 5-1. The parameters include previous dry hours (PDH), event duration (train),

rainfall depth (drain), maximum rainfall intensity (irain-max), initial pavement residence time

(IPRT), runoff volume (Vrunoff), maximum flow rate (Qp), median flow rate (Qmed), runoff

coefficient (C), and number of samples (n).

Analysis of Recovered Sediment Deposit from Hydrodynamic Separator

Sieve analysis is used to determine the particle size distribution as required or gradation

of an aggregate. Analysis followed ASTM D422-63 with additional sieve sizes (ASTM 1993;

Sansalone et al. 1998). After being air-dried at a constant temperature of 40°C and having their

dry proper weights measured PM, dried PM samples are disaggregated and sieved through a set

of graded mechanic sieves. The aggregates are placed in the top of the sieve stack and covered

with a lid. The sieves are properly secured in the mechanical shaker and then the shaker is

turned on for five minutes. The materials retained on each of the sieves are weighed, including

the weight retained on the pan, and the results are recorded. The Fineness Modulus for each PM

Sample is then computed. Sieve analysis follows the standard procedure ASTM D422 (ASTM

1998). Dry PM separated on each of the stainless steel sieves is weighed and stored separately in

round clear sample bottles. A 95 to 98% recovery of PM is required for sieve analysis.

Results

Event Hydrology

Event-based hydrological indices including PDH, drain, irain-max, as well as Vrunoff and Qp

and Qmed, (both influent and effluent), were monitored and recorded for a total of 10 storm events

occurring between May 24th

, 2010 and August 21th

, 2010 as shown in Table 5-1. Monitored

storm events during the field test program varied in duration from 25 minutes on August 24th

,

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118

2010 to 60 minutes on July 31st, 2010. The storm events ranged from 1.8 mm on May 24

th, 2010

to 23.6 mm of rainfall depth on July 31st, 2010. The PDH was from 15 hours to 261 hours in

between storm events. The volume of event runoff was from 79 L to 2386 L. Resulting peak

flow rates ranged from 1.2 L/s on May 24th

, 2010 to 17.6 L/s on June 29th

, 2010, while the

median flow rates ranged from 0.03 to 1.52 L/s as shown in Table 5-1. The IPRT referred to in

Table 5-1 is the time required for rainfall to satisfy certain conditions including pavement surface

wetting and depression storage filling, as well as airborne re-suspension, and atmospheric

evaporation. In comparing all 10 storm events, IPRT results varied from 0.4 minutes to 7.3

minutes as shown in Table 5-1. In addition, IPRT is controlled by a combination of PDH and

abstractions during each storm (Sansalone et al. 2005). The site hydrology is described for each

of the 10 events by runoff hydrographs plotted with fd and fp in Figures 5-6 to 5-7. The

hydrographs were observed to respond quickly to fluctuations in rainfall intensity.

Overall Treatment Efficiency of BHS as a Function of Hydrology

A total of ten storm events, encompassing a wide range of flow rates, were routed

through the BHS between May 24th

, 2010 and August 21st, 2010 and with total volume of

approximately 32407 L of rainfall-runoff from the experimental watershed located in the

University of Florida. Each of the storms was unique in regards to their natural and

anthropogenic pollutant loadings. All ten storms had wide variations of drain (1.8 mm – 23.6

mm), period of PDH (0.4 min. – 7.3 min.), Vrunoff (871 L – 9031 L), Qp (1.2 L/s – 16.0 L/s), irain-

max (7.6 mm/hr – 137.2 mm/hr), and train (25 min. – 60 min.). These results are summarized in

Table 5-1, along with PDH, train, drain, irain-max, IPRT, Vrunoff, Qp, Qmed, number of influent/effluent

samples (ninf/neff), sampling coverage, and percent of hydraulic design utilized at Qp. Removal

efficiency for the 9 TARP qualified storm events ranged from 47% to 98%. The most significant

factor in determining the amount captured by the BHS unit was the peak flow intensity of

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119

influent heading into the unit, which has a hydraulic design capacity (Qd) of 9.05 L/s. In each

high intensity storm, the level of total suspended solid (TSS), SSC, TN and TP removal dropped

significantly, resulting in a range of -46% to 98% removal. The negative values are shown

because of re-suspension in the unit. Results for PM separation, and TN, TP and SSC removal

efficiencies measured for the BHS unit with ten different runoff events are summarized in from

Table 5-1.

PM fraction and PM-based N and P fraction masses distribution

A summary of the relative fractions of the suspended, settleable, and sediment PM for

each event are shown in Figure 5-2. Sediment PM (>75 μm) gravimetrically dominates these

results in rainfall-runoff, ranging from 76.0 to 99.5% with a mean of 89.0%. The settleable PM

ranges from 0.03 to 12.9% with a mean of 6.3%, while the suspended PM fraction ranged from

0.02 to 17.7% with a mean of 4.7% in rainfall-runoff.

The fractions of N (P) in rainfall-runoff are compared to the fraction of PM mass. The

results are plotted in Figure 5-2 on an event basis for each PM fraction (suspended, settleable,

sediment, TSS and SSC). A 1:1 line of equal separation behavior is illustrated as a reference.

Results indicate that there is less than a 1:1 ratio between N (P) associated with settleable PM

and suspended PM with a few events deviating from this trend. However, N (P) fractions for

sediment PM have a larger than 1:1 ratio.

Event based Nitrogen and Phosphorus Loadings

Each storm event was analyzed for N (P) loadings across PM fractions. The

concentrations of total dissolved and total N (P) are presented in Table 5-2. The concentrations

of N (P) varied across 10 storm events. TDN of rainfall-runoff ranged from 240 μg/L to 2104

μg/L with a median value of 1321 μg/L across the 10 storm events while, effluent TDN ranged

from 177 μg/L to 1901 μg/L with a median value of 1072 μg/L. TN of rainfall-runoff ranged

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from 668 μg/L to 7542 μg/L with a median value of 2709 μg/L, while effluent TN ranged from

528 μg/L to 2383 μg/L with a median value of 1581 μg/L. The median value of TN from this

experiment was higher than that found in previous studies within the local watershed (Rushton

2001; Passeport and Hunt 2009). For instance, TN loadings in the urban areas were previously

found to be 1.63, 0.556, and 0.548 mg/L (Rushton 2001; Passeport and Hunt 2009). TN

concentrations were higher than in previous studies because this research was performed during

the summer, during which time more biogenic materials from vegetated islands in the watershed

area are generated.

TDP of rainfall-runoff ranged from 123 μg/L to 854 μg/L with a median value of 303

μg/L across the 10 storm events, while effluent TDP ranged from 77 μg/L to 469 μg/L with a

median value of 257 μg/L. TP of rainfall-runoff ranged from 668 μg/L to 23640 μg/L with a

median value of 2459 μg/L, while effluent TP ranged from 527 μg/L to 1807 μg/L with a median

value of 1046 μg/L. From the previous research (Rushton 2001; Kayhanian et al. 2007; USEPA

1983; Brown et al. 2003), TP loadings in urban areas were found to be 0.21, 0.29, 0.33 and 0.30

mg/L. This specific carpark transports higher magnitudes of event mean concentration (EMC)

than observed in previous research. Approximately 700 vehicles per day pass by this watershed

area (Berretta and Sansalone 2011) which also has a significant load of biogenic materials from

vegetated areas in the parking lot. Leaves falling from trees and grass cuttings, also contribute to

the biogenic loads on the pavement and these are eventually conveyed to the BHS unit with the

runoff.

Nutrients Removal Efficiency as a function of Hydrology

Based upon the measurements described above, frequency distributions of N (P) fractions

were examined for both influent and effluent. The measured N (P) of total dissolved, suspended,

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121

settleable, sediment, and total fraction concentrations are presented in Table 5-2 as EMC values.

Median, mean and standard deviation values are also presented.

The percentage of TP separation varied from 42% to 97% for storms that had a peak flow

below the design flow capacity of the unit and not including the first storm which had no

effluent. As a comparison, the percentage of TP separation in storms that had a peak flow above

the design flow capacity of the unit varied from 22% to 60%. Similar results were observed for

TN. The percentage of TN separation in storms that had a peak flow below the design flow

capacity of the unit and not including the first storm varied from 12% to 84%. In comparison, the

percentage of TN separation in storms that had a peak flow above the design flow capacity of the

unit varied from 7% to 59%. It is clear that the unit does perform better, when the peak flow does

not exceed the hydraulic design capacity.

The BHS unit separation behavior for PM-bound N (P) fractions is compared to

separation of PM in Figure 5-3 on an event basis for each PM fraction (suspended, settleable, and

sediment). A 1:1 line of equal separation behavior is presented as a reference. Results indicate

there is less than a 1:1 relationship between N (P) separation associated with settleable PM,

sediment PM and smaller than 25 μm PM, with a few events deviating from this trend. All

frequency distributions for N (P) are well described by a log-normal distribution (α ≤ p = 0.05).

The medians of each frequency distribution for N (P) were significantly reduced between

influent and effluent as illustrated in Figure 5-4 and 5-5.

Nutrients Partitioning

In rainfall-runoff, nutrients such as N (P) are partitioned into dissolved and particulate

bound fractions. The partitioning of N (P) in urban rainfall-runoff influenced by primary IPRT,

rainfall pH, oxidation reduction potential (ORP), conductivity and the quantity of solids present

in rainfall-runoff (Sansalone et al., 1997). The dissolved fraction (fd) and equilibrium partitioning

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distribution (as Kd, L/Kg) between dissolved and particulate N (P) phases were examined in both

the influent and effluent. Figure 5-6 summarizes the trends in fd of TN and TP and the magnitude

of TDN and TDP concentrations as a function of hydrology for all events. The trend of variation

in fd does not correspond to each event’s hydrology. The traffic loadings and biogenic nutrients

from the catchment area are the main factor causing the variation of fd through all the events. The

role of suspended, settleable, and sediment PM based N (P) were examined with respect to fd and

Kd. Table 5-3 shows that event mean fd values for N ranged from 0.54 to 0.85, indicating that the

majority of N was associated with the dissolved gradation in the rainfall-runoff. Event mean fd

values for P ranged from 0.08 to 0.42 indicating that the majority of P was associated with the

particulate gradation in the rainfall-runoff. Results are illustrated in Figure 5-6, note that all

frequency distribution are modeled as log-normal (α ≤ p = 0.05). The SSC method provides a

gravimetric index based on all PM in the sample. Partitioning was examined based on suspended,

settleable, and sediment PM fractions of N (P). Initial TDP concentrations are greater than

concentrations at the end of event. The results indicated that the BHS unit was effective in

separation of the suspended, settleable, and sediment PM fractions of N (P). The initial TDP has

higher concentrations as compared to the end of the event. The results showed that the effluent

from the unit has a statistically significant increase in the dissolved fraction. Additionally, fd

varied by over an order of magnitude between events (which is potentially related to previous

dry hours).

Kd values in Table 5-3 are also shown in order of decreasing median value. P exhibits

much higher Kd values than N. Kd values ranged from 180.5 L/Kg to 17649.7 L/Kg for N, while

values ranged from 8408.2 L/Kg to 37625.2 L/Kg for P. Kd values are statistically significantly

higher for effluent as compared to influent for all the PM fractions for N (P).

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Nutrient from the Recovered Sediment Deposit

Figure 5-7 illustrates the distribution of dry granulometric mass for a given particle

diameter on an incremental and cumulative basis for each PM fraction from less than 25 µm to

coarser than 9500 µm. This analysis was performed to evaluate the gradation of N (P) mass as a

function of particle diameter. Figure 5-7 illustrates a general trend for different N (P) species for

NO3-N, NH3-N, total kjeldahl nitrogen (TKN), PO43-

-P, and TP, nutrients mass is predominantly

associated with the coarse fraction of PM (coarser than 63 µm). The cumulative NO3-N, NH3-N,

and TKN recovered mass was 32 mg, 679 mg, and 45086 mg respectively. The cumulative PO43-

-P, and TP recovered mass was 1886 mg, and 24695 mg. The mass recovery for each of NO3-N,

NH3-N, and TKN significantly increased for particle sizes greater than 75 µm. The percentage of

NO3-N, NH3-N, and TKN between 75 µm and 2000 µm was 82%, 88%, and 85%, respectively.

For PO43-

-P, and TP, the percentages between 75 µm and 2000 µm were 92% and 93%. Most of

the nutrients in recovered PM deposits are from the sediment PM fraction. According to data

from recovered deposited mass, NH3-N is a less abundant species of dissolved nitrogen in runoff;

the ratio of NO3-N to NH3-N was about 22:1, which means nitrite concentration can be

neglected. NH3-N includes both ammonium and ammonia in the equilibrium aqueous phase.

Based on the neutral pH of 7 for rainfall-runoff in catchment, the major form of NH3-N is

expected to be ammonium (NH4+).

Figure 5-8 summarized the trend in the fd of TN (TP) as a function of cumulative treated

rainfall-runoff volume. The variation trend of the fd does not follow the changing of treated

volume exactly due to the hydrologic complexity. The mean fd values of influent and effluent TN

are 0.57 and 0.68, and the mean fd values of influent and effluent TP are 0.28 and 0.36. The

mean fd values of influent and effluent TP are significantly lower than TN. This result indicates

that the predominance of TP is associated with the PMs.

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124

The influent and effluent PSDs were modeled as gamma distributions on an event basis.

Influent and effluent PSD differences were shown with the probability density function of a

gamma distribution as follows:

)(

)(

)(

1

x

ex

xf (5-4)

In this expression, Γ is the gamma function; γ is the shape factor and β is the scaling

factor. γ and β parameters were estimated by minimizing the sum of squared errors (SSE),

resulting in maximizing the coefficient of determination between the measured and modeled

data. Below, F(x) is the cumulative gamma distribution and x represents flow rate in Figure 5-7

and 5-9.

x

dxxfxF0

)()( (5-5)

Figure 5-9 shows that the PMs are heterodisperse through all 10 storm events.

Cumulative PSDs were examined and results were described by an optimized cumulative gamma

distribution function summarized in Figure 5-9. The runoff median PM diameter (d50m) ranged

from 72 to 182 μm for BHS. For all 10 storm events, the recovered PM mass balance error was

within 3%. Interestingly, Influent P mass trend was similar to influent PM mass as a function of

cumulative treated volume in BHS. This result indicates that P mass is associated with PM mass.

Figure 5-10 illustrates that cumulative total mass separations for PM, TP and TN were 79.0, 60.2

and 39.4% from BHS. TP mass separation follows PM mass separation; however, TN has

significantly lower mass separation efficiency. This result indicates P is associated with PM than

N.

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125

Summary

For the given BHS configuration, operating under the loading conditions of the 10

rainfall-runoff events considered in this study, sediment PM bound N (P) concentrations ranged

from 76.0 to 99.5%, settleable PM bound N (P) concentrations ranged from 0.03 to 12.9%, and

suspended PM bound N (P) concentrations ranged from 0.02 to 17.7% in rainfall-runoff.

The coarser fraction of PM generated the highest N (P) concentrations and mass, because

most of N (P) is associated with PM (> 75 µm). Sediment PM (> 75 µm) represents a significant

source area inventory and requires frequent maintenance and management for in-situ unit

operations to ensure proper function.

The PM-bound N separation efficiency for rainfall intensities between 0.07 inches and

0.95 inches ranged from 5 to 100%, with an arithmetic mean of 49%, based on Δ Mass of TN.

The event mean PM bound N separation efficiency ranged from 17 to 100%, with an arithmetic

mean of 56%, based on Δ Mass of TP. The event mean PM separation for the BHS unit was

81%. Compared to PM separation, the events mean PM-bound N (P) separation efficiencies were

lower throughout all storm events. The cumulative total mass separation of PM, TP and TN are

79.0, 60.2 and 39.4% from BHS. PM and TP separation efficiencies are significantly higher than

TN, which indicate that P is predominantly associated with PM than N. Results indicate that the

partitioning of N in BHS units is one of the reasons for lower mass separation efficiencies of N.

HS type devices, while reasonably effective for removing nutrients that associate with coarser

PM, are ineffective at targeting other fractions. The effects of re-suspension of removed

sediment should not be underestimated.

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126

Table 5-1. Hydrologic characterization of the 10 rainfall-runoff events monitored between May

24, 2010 and August 21, 2010 in Gainesville, FL

Event date

(2010)

PDH

(hr)

train

(min)

drain

(mm)

irain-max

(mm/hr)

IPRT

(min)

Vrunoff

(L)

Qp

(L/s)

Qmed

(L/s)

C

(-)

n

(-)

24-May 17 36 1.8 7.6 7.3 871 1.2 0.18 0.98 12

04-June 164 42 11.2 106.7 1.2 2952 13.2 0.32 0.53 20

17-June 26 36 7.1 30.5 1.5 1946 6.1 0.76 0.55 20

29-June 192 40 20.6 106.7 0.4 5704 17.6 1.52 0.34 20

11-July 261 42 11.7 76.2 5.6 2377 5.2 0.32 0.41 20

28-July 36 50 19.1 137.2 1.0 8316 16.0 1.20 0.75 20

31-July 15 60 23.6 76.2 5.2 9031 13.2 0.60 0.76 20

13-August 112 25 2.8 55.9 2.0 314 3.2 0.06 0.23 20

14-August 28 31 2.5 22.9 1.6 594 2.5 0.25 0.47 20

21-August 83 31 2.8 45.7 2.1 299 1.5 0.03 0.21 20

Median 60 38 9.2 66.1 1.8 2162 5.7 0.32 0.50 20

Mean 93 39 10.3 66.6 2.8 3240 8.0 0.52 0.52 19

SD 87 10 8.3 41.7 2.3 3295 6.4 0.50 0.25 2.5

PDH, train, drain, irain-max, IPRT, Vrunoff, Qp, Qmed, C and n represent previous dry hours, event

duration, rainfall depth, maximum rainfall intensity, initial pavement residence time, runoff

volume, maximum flow rate, median flow rate, runoff coefficient and number of samples,

respectively.

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Table 5-2. Summary of EMCs and ΔMass for total dissolved nitrogen (TDN), total nitrogen

(TN), total dissolved phosphorus (TDP), and total phosphorus (TP).

Event

Date

(2010)

TDN TN TDP TP

EMCi EMCe ΔM EMCi EMCe ΔM EMCi EMCe ΔM EMCi EMCe ΔM

[μg/L] [μg/L] (%) [μg/L] [μg/L] (%) [μg/L] [μg/L] (%) [μg/L] [μg/L] (%)

24-May 1688 N/A 100 2709 N/A 100 854 N/A 100 3186 N/A 100

04-June 1188 1098 8 1384 1316 5 209 257 -23 2367 1487 37

17-June 1454 1547 -6 3859 1897 51 123 77 37 5807 610 90

29-June 1787 491 73 3840 1581 59 275 221 20 4564 1807 60

11-July 2104 1901 10 2709 2383 12 424 425 0 1793 1046 42

28-July 939 656 30 2005 1599 20 238 228 4 2379 1366 43

31-July 240 177 26 668 528 21 240 177 26 668 527 17

13-Aug 1159 1072 8 7542 1239 84 331 451 -36 23640 654 98

14-Aug 572 715 -25 2502 978 61 349 469 -35 1869 866 54

21-Aug 1674 1104 34 3708 1995 46 437 415 5 2538 1085 57

Mean 1281 973 26 3093 1502 46 348 302 10 4881 1050 60

Median 1321 1072 18 2709 1581 49 303 257 5 2459 1046 56

SD. 578 532 37 1884 561 31 203 141 40 6751 436 28

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Table 5-3. Summary of event mean value and range of variation of the dissolved fraction (fd) and

partition coefficient (Kd) of nitrogen and phosphorus for influent and effluent runoff.

Event

date

(2010)

Nitrogen Phosphorus

fd Kd fd Kd

Influent Effluent Influent Effluent Influent Effluent Influent Effluent

24-May 0.85 N/A 1476.5 N/A 0.42 N/A 21290.9 N/A

04-June 0.66 0.92 180.5 873.1 0.08 0.28 8453.6 36181.5

17-June 0.42 0.79 1065.3 5793.9 0.06 0.20 20187.8 154042.6

29-June 0.54 0.38 1606.2 21301.1 0.11 0.18 14247.5 64775.9

11-July 0.79 0.87 957.2 3093.3 0.37 0.42 8408.2 42781.4

28-July 0.47 0.66 3288.1 9490.3 0.15 0.27 20769.4 51380.6

31-July 0.44 0.40 11232.5 38769.2 0.40 0.34 11023.3 68619.6

13-August 0.66 0.83 3575.5 19817.1 0.27 0.66 29570.7 47462.9

14-August 0.27 0.67 17649.7 38361.7 0.21 0.52 23770.1 78332.8

21-August 0.58 0.58 7654.8 91307.3 0.26 0.35 37625.2 206288.3

Median 0.56 0.67 4868.6 25423.0 0.24 0.34 19534.7 83318.4

Mean 0.57 0.68 2447.2 19817.1 0.23 0.36 20478.6 64775.9

SD 0.18 0.20 5673.3 28449.9 0.13 0.15 9416.0 57964.4

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Figure 5-1. Profile section of 1.21 m diameter BHS deployed for physical modeling loaded by

urban source area catchment.

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130

Fraction of P mass (%)

0 20 40 60 80 100

Fra

ctio

n o

f P

M m

ass

(%)

0

20

40

60

80

100

Suspended

Settleable

Sediment

Fraction of N mass (%)

0 20 40 60 80 100

Fra

ctio

n o

f P

M m

ass

(%)

0

20

40

60

80

100

Suspended

Settleable

Sediment

Susp

ended

Set

tlea

ble

Sed

imen

t

Fra

ctio

n o

f m

ass

(%)

0

20

40

60

80

100

B. Phosphorus C. PM

Fra

ctio

n o

f m

ass

(%)

0

20

40

60

80

100

Susp

ended

Set

tlea

ble

Sed

imen

t

E. Nitrogen F. PM

Susp

ended

Set

tlea

ble

Sed

imen

t

Susp

ended

Set

tlea

ble

Sed

imen

t

n = 102 n = 102

n = 102n = 102

A

D

Figure 5-2. PM fraction and PM-based N and P fraction masses distribution within each

monitored rainfall-runoff event. Each symbol represents a rainfall-runoff event.

Range bars represent standard deviation.

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131

PM fraction separation (%)

-200 -100 0 100 200

PM fraction separation (%)

-200 -100 0 100 200

PM

bas

ed T

P s

epar

atio

n (

%)

-200

-100

0

100

200

Suspended PM

Settleable PM

Sediment PM

PM fraction separation (%)

-200 -100 0 100 200

PM fraction separation (%)

-200 -100 0 100 200

PM

bas

ed T

N s

epar

atio

n (

%)

-200

-100

0

100

200

Figure 5-3. Separation for TN, and TP in different fractions as a function of PM fractions. Range

bars represent standard deviation.

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132

Sediment [mg/L]

P fraction [mg/L]

pdf

0.00

0.05

0.10

0.15

0.20

0.25

0.30

Suspended [mg/L]

P fraction [mg/L]

pdf

0.0

0.1

0.2

0.3

0.4

0.5

Settleable [mg/L]

pdf

0.00

0.05

0.10

0.15

0.20

0.25

0.30

= 6.69

= 19.98

= 0.14

= 0.47

I = 0.22

I = 0.60

E = 0.07

E = 0.09

I = 0.53

I = 0.52

E = 0.45

E = 0.31

Dissolved [ mg/L]

P fraction [mg/L]pdf

0.0

0.1

0.2

0.3

0.4

0.5

I = 0.52

I = 0.62

E = 0.32

E = 0.17

103

102

101

100

10-1

10-2

10-3

10-4

103

102

101

100

10-1

10-2

10-3

10-4

103

102

101

100

10-1

10-2

10-3

10-4

103

102

101

100

10-1

10-2

10-3

10-4

Total phosphorus [mg/L]

P fraction [mg/L]

pdf

0.0

0.1

0.2

0.3

0.4

0.5

I = 7.98

I = 20.63

E = 1.00

E = 0.73

Influent

Effluent

Figure 5-4. Phosphorus mass concentration distributions for each PM fractions. All data are

modeled as log-normal distributions (p < 0.05). Influent and effluent distributions are

statistically significantly different (p < 0.05) for each PM fractions.

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133

Sediment [mg/L]

N fraction [mg/L]

pdf

0.00

0.05

0.10

0.15

0.20

0.25

0.30

Suspended [mg/L]

N fraction [mg/L]

pdf

0.00

0.05

0.10

0.15

0.20

0.25

0.30

Settleable [mg/L]

pdf

0.00

0.05

0.10

0.15

0.20

0.25

0.30

Dissolved [mg/L]

N fraction [mg/L]pdf

0.00

0.05

0.10

0.15

0.20

0.25

0.30

I = 1.63

I = 1.25

E = 1.07

E = 0.55

= 2.38

= 6.36

= 0.07

= 0.22

= 0.22

= 0.41

= 0.07

= 0.06

= 0.33

= 0.50

= 0.37

= 0.33

103

102

101

100

10-1

10-2

10-3

10-4

103

102

101

100

10-1

10-2

10-3

10-4

103

102

101

100

10-1

10-2

10-3

10-4

103

102

101

100

10-1

10-2

10-3

10-4

Total nitrogen [mg/L]

N fraction [mg/L]

pdf

0.0

0.1

0.2

0.3

0.4

0.5

I = 4.55

I = 7.46

E = 1.59

E = 0.61

Influent

Effluent

Figure 5-5. Nitrogen mass concentration distributions for each PM fractions. All data are

modeled as log-normal distributions (p < 0.05). Influent and effluent distributions are

statistically significantly different (p < 0.05) for each PM fractions.

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134

Phosphorus [mg/L]

Kd (L/Kg)

pdf

0.00

0.05

0.10

0.15

0.20

0.25

= 19.57

= 19.75

= 83.32

= 90.57

Phosphorus [mg/L]

fd

pdf

0.00

0.05

0.10

0.15

0.20

0.25

= 0.24

= 0.18

= 0.36

= 0.19

Nitrogen [mg/L]

fd

pdf

0.00

0.05

0.10

0.15

0.20

0.25

Nitrogen [mg/L]

Kd (L/Kg)

pdf

0.00

0.05

0.10

0.15

0.20

0.25

= 4.80

= 8.08

= 25.42

= 37.99

= 0.57

= 0.26

= 0.68

= 0.23

1010.10.010.001 10 102

103

104

105

106

1010.10.010.001 10 102

103

104

105

106

Influent

Effluent

Figure 5-6. fd values and equilibrium coefficient, Kd values of nitrogen and phosphorus in

influent and effluent. There are statistically significant difference between infludent fd

and Kd value and effluent fd and Kd value (p <0.05).

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Particle diameter (m)

15

25

38

45

53

63

75

10

61

50

18

02

50

30

04

25

60

08

50

20

00

47

50

95

00

NH

4-N

(m

g)

0

30

60

90

120

150

Cum

mu

lati

ve

per

cent

NH

4-N

(%

)

0

20

40

60

80

100

NO

3-N

(m

g)

0

2

4

6

8

10

Cum

mu

lati

ve

per

cent

NO

3-N

(%

)

0

20

40

60

80

100

Particle diameter (m)

15

25

38

45

53

63

75

10

61

50

18

02

50

30

04

25

60

08

50

20

00

47

50

95

00

TK

N (

mg)

0

2400

4800

7200

9600

12000

Cum

mu

lati

ve

per

cent

TK

N (

%)

0

20

40

60

80

100

= 10.95

= 1.04

= 12.29

= 1.02

= 18.00

= 0.73

Particle diameter (m)

15

25

38

45

53

63

75

10

61

50

18

02

50

30

04

25

60

08

50

20

00

47

50

95

00

PO

4

3- -P

(m

g)

0

90

180

270

360

450

Cum

mu

lati

ve

per

cent

P (

%)

0

20

40

60

80

100

Particle diameter (m)

15

25

38

45

53

63

75

10

61

50

18

02

50

30

04

25

60

08

50

20

00

47

50

95

00

TP

(m

g)

0

1000

2000

3000

4000

5000

Cum

mu

lati

ve

per

cent

TP

(%

)

0

20

40

60

80

100

= 13.05

= 0.86

= 13.02

= 0.87

Figure 5-7. Granulometric equilibrium distribution of ammonium-nitrogen, nitrate-nitrogen,

TKN, phosphate and TP.

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136

Cumulative treated volume (L)

0 5000 10000 15000 20000 25000 30000

f d o

f in

flu

ent

TN

0.0

0.2

0.4

0.6

0.8

1.0fd (A)

f d o

f in

flu

ent

TP

0.0

0.2

0.4

0.6

0.8

1.0fd

f d o

f ef

flu

ent

TN

0.0

0.2

0.4

0.6

0.8

1.0fd (B)

Cumulative treated volume (L)

0 5000 10000 15000 20000 25000 30000

f d o

f ef

flu

ent

TP

0.0

0.2

0.4

0.6

0.8

1.0

fd

(C)

(D)

fd50

= 0.57

fd50

= 0.68

fd50

= 0.28

fd50

= 0.36

Figure 5-8. The fd of influent and effluent TN (TP) as a function of cumulative treated rainfall-

runoff volume. A – fd of influent TN, B- fd of effluent TN, C- fd of influent TP, D- fd

of effluent TP. fd50 represents the mean dissolved fraction.

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Cumulative treated volume (m3)

0 5 10 15 20 25 30 35

0.0

0.5

1.0

1.5

2.0

Influent

Effluent

Cumulative treated volume (m3)

0 5 10 15 20 25 30 35

10

100

1000

Influent

Effluent

0.0

0.5

1.0

1.5

2.0

10

100

1000

Influent

Effluent(A)

(B)

(C) (D)

Figure 5-9. The cumulative gamma distribution parameters (ɤ for shape factor and β for scaling

factor) for event-based normalized particle size distributions (PSD). Each point is

representative of an event..

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138

Cumulative treated volume (L)

0 5000 10000 15000 20000 25000 30000

Cu

mu

lati

ve

PM

mas

s (K

g)

0

5

10

15

20

25

30

Influent PM

Effluent PM

Cu

mu

lati

ve

P m

ass

(g)

0

20

40

60

80

100

Influent P

Effluent P

Cumulative treated volume (L)

0 5000 10000 15000 20000 25000 30000

Cu

mu

lati

ve

N m

ass

(g)

0

20

40

60

80

100

Influent N

Effluent N

Influent PM mass = 26.7 Kg

Effluent PM mass = 5.6 Kg

Influent P mass = 85.6 g

Effluent P mass = 34.1 g

Influent N mass = 80.9 g

Effluent N mass = 49.0 g

(A)

(B)

(C)

Figure 5-10. Cumulative influent and effluent mass of PM, phosphorus (P), and nitrogen (N)

through the entire monitoring campaign for baffled hydrodynamic separator (BHS)

in Gainesville, FL.

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139

CHAPTER 6

CONCLUSION

This dissertation focused on a coupled experimental and numerical approach to

characterize particulate matter (PM) separation and scour by stormwater unit operations and

processes (UOPs) for steady and transient hydrologic, hydraulic and pollutant loadings. Four

UOPs were modeled physically and numerically, inclcuding a baffled hydrodynamic separator

(BHS), a vortex hydrodynamic separator (VHS), a screened hydrodynamic separator (SHS), and

a volumetric clarifying filtration system (VCF). This study examined the inter- and intra- event

N and P removal as a function of particle size, hydrology and partitioning for an urban carpark,

treated by a BHS, with significant biogenic loadings.

A commonly used BHS was analyzed for washout of pre-deposited PM as a function of

surface overflow rates indexed as flow rates from 10 to 125% of the HS design flow. The CFD

model was validated with experimental data across a range of flow rates and particle size

distributions, PSDs. Furthermore, a SHS and a VHS were physically and numerically compared

to a BHS unit. Three different HS units were successfully modeled with CFD to access PM

behavior, using finite volume method (FVM), a standard k-ε model for turbulent conditions, and

a Lagrangian discrete phase model (DPM) to track particles. CFD models were validated for PM

concentration, mass and PSDs with less than 10% RPD. Lagrangian particle trajectory results

show that VHS has coarsest eluted and washout PM, as well as, the highest washout rates. The

vortexing inner chamber results in a higher rate of re-suspension of finer PM in the screened

hydrodynamic separator. A CFD based probability function was developed for each

hydrodynamic separator (HS) for particle elution as function of flow rate and diameter. Such

probability functions, combined with available physical modeling data can provide a reliable

method of predicting PM yield from a HS.

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PM separation by a BHS, SHS, and VCF system for transient hydraulic and particulate

loads observed in a real-time rainfall-runoff event was modeled with stepwise steady flow CFD

model by the application of the standard k-ε turbulence model and a Lagrangian discrete phase

model. Four discrete rainfall-runoff events for each UOPs were modeled. The modeled results

agreed with the measured data (Absolute RPD <10%).

This study successfully applied stepwise steady step CFD modeling of three HS units as

validated by matching the physically observed PM mass data. Instead of computing a fully

unsteady CFD model, the stepwise steady step model provides an efficient method of simultation.

The stepwise steady CFD modeling reduces the required computing time by more than 16 times.

Even with complex unsteady flow in urban area can be representative with stepwise steady

simulation. A calibrated/validated CFD-based iterative approach to design of unit operations has

the potential to provide reduced prototyping costs with improved performance, as a result of

carefully designed experimental matrices, focused on PM control requirements for effluent

discharges. A CFD approach to modeling the PM removal characteristics and PM washout of

UOPs is a state-of-the-art approach to reducing the uncertainty that results from assuming ideal

conditions, thus providing a more effective method for pollution control.

Urban rainfall can be a significant source of N and P, both in particulate bound and

dissolved forms. Results indicate that partitioning in rainfall-runoff resulted predominantly in N

(P) binding to sediment PM (> 75 μm). Not only does the coarser PM (> 75 μm) fraction absorb

the highest concentrations of N (P), but the highest mass is also associated with the coarser PM

(> 75 μm) fraction. PM bound N removal ranged from 5 to 100 % from the BHS with a median

49%, and PM bound P removal ranged from 17 to 100 % from the BHS with a median 56%.

Results indicate that there is generally less than a 1:1 relationship between the removal of N (P)

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141

and associated removal of settleable PM, sediment PM and suspended PM (< 25 μm). There are

a few events deviating from this trend. This study concludes that while particulate P and N

constitute a large portion of the total removal by the BHS, the long-term effects of re-uptake and

re-partitioning need to be studied in addition to particulate scour, as part of a maintenance

program.

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142

APPENDIX A

CHAPTER 3. PHYSICAL AND CFD MODELING OF PM SEPARATION AND SCOUR IN

HYDRODYNAMIC SEPARATORS

Figure A-1. Schematic view and dimensions of baffled hydrodynamic separator (BHS). The

effective volume of the unit indicates the volume occupied of water without any

influent flow.

Baffled hydrodynamic separator (BHS) Dimensions

Unit diameter 1.22 m

Unit height 1.52 m

Effective volume of unit 1.78 m3

Bypass baffle height 0.23 m

Diameter of influent pipe 0.30 m

Diameter of effluent pipe 0.30 m

Length of influent droplet pipe 0.43 m

Length of effluent droplet pipe 0.41 m

Overall unit surface area 1.17 m2

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143

Figure A-2. Schematic view and dimensions of vortex hydrodynamic separator (VHS). The

effective volume of the unit indicates the volume occupied of water without any

influent flow.

Vortex hydrodynamic separator (VHS) Dimensions

Inner vortex chamber diameter 2.13 m

Unit height 2.13 m

Unit depth 1.22 m

Unit width 1.74 m

Effective volume of unit 7.00 m3

Diameter of effluent pipe 0.30 m

Diameter of effluent pipe 0.30 m

Overall unit surface area 3.70 m2

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Figure A-3. Schematic view and dimensions of screened hydrodynamic separator (SHS). The

effective volume of the unit indicates the volume occupied by a static column of

water without any influent flow

Screened hydrodynamic separator (SHS) Dimensions

Unit diameter 2.13 m

Unit height 1.68 m

Effective volume of unit 2.96 m3

Volume of cylindrical sump 0.15 m3

Diameter of sump 0.64 m

Diameter of effluent pipe 0.25 m

Diameter of screen 0.64 m

Aperture opening 2400 μm

Screened area 1.27 m2

Overall unit surface area 3.58 m2

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Table A-1. Morsi and Alexander ‘a’ – values as function of Reynolds number are reported

below. (Morsi and Alexander 1972)

Re a1 a2 a3

<0.1 24.0 0 0

0.1 < Re < 1 22.73 0.0903 3.69

1 < Re < 10 29.1667 -3.8889 1.222

10 < Re < 100 46.5 -116.67 0.6167

100 < Re < 1000 98.33 -2778 0.3644

1000 < Re < 5000 148.62 -4.75 × 104 0.357

5000 < Re < 10,000 -490.546 57.87 × 104 0.46

10,000 < Re < 50,000 -1662.5 5.4167 × 106 0.5191

Figure A-4. Reynolds number for three hydrodynamic separators (HS) as a function of flow rate.

Flow rate (L/s)

0 20 40 60 80 100

Re

0

2000

4000

6000

8000

10000

12000

BHS

VHS

SHS

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146

APPENDIX B

CHAPTER 4. STEPWISE STEADY CFD MODELING OF UNSTEADY FLOW AND PM

LOADING TO UNIT OPERATIONS

Figure B-1. Schematic view and dimensions of baffled hydrodynamic separator (BHS). The

effective volume of the unit indicates the volume occupied of water without any

influent or effluent flow.

Baffled hydrodynamic separator (BHS) Dimensions

Unit diameter 1.22 m

Unit height 1.52 m

Effective volume of unit 1.78 m3

Bypass baffle height 0.23 m

Diameter of influent pipe 0.30 m

Diameter of effluent pipe 0.30 m

Length of influent droplet pipe 0.43 m

Length of effluent droplet pipe 0.41 m

Overall unit surface area 1.17 m2

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Figure B-2. Schematic view and dimensions of screened hydrodynamic separator (SHS). The

effective volume of the unit indicates the volume occupied by a static column of

water without any influent or effluent flow.

Baffled hydrodynamic separator (BHS) Dimensions

Unit outer diameter 0.89 m

Unit inner diameter 0.50 m

Unit height 1.23 m

Effective volume of unit 0.65 m3

Diameter of influent pipe 0.15 m

Diameter of effluent pipe 0.20 m

Distance from top to screened area 0.33 m

Aperture opening 2400 μm

Screened area 0.52 m2

Overall unit surface area 0.62 m2

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Figure B-3. Schematic view and dimensions of volumetric clarifying filter (VCF). The effective

volume of the unit indicates the volume occupied of water without any influent or

effluent flow.

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AOCM represents Aluminum oxide coated media

Volumetric clarifying filter (VCF) Dimensions

Cartridge outer diameter 0.46 m

Cartridge inner diameter 0.08 m

Cartridge height 0.53 m

Cartridge media size (d50) 3.56 mm

Cartridge media specific gravity 2.35 g/cm3

Cartridge media specific surface area 0.94 m2/g

Cartridge media porosity 36.7%

Cartridge media dry bulk density 0.68 g/cm3

Filter media AOCM

Unit height (influent) 1.69 m

Unit height (effluent) 1.87 m

Unit depth 1.17 m

Unit width 2.12 m

Effective volume of unit 1.92 m3

Diameter of influent pipe 0.15 m

Diameter of effluent pipe 0.15 m

Bottom to V-notch weir on baffle 0.39 m

Overall unit surface area 2.25 m2

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Table B-1. Morsi and Alexander ‘a’ – values as function of Reynolds number are reported

below. (Morsi and Alexander 1972)

Re a1 a2 a3

<0.1 24.0 0 0

0.1 < Re < 1 22.73 0.0903 3.69

1 < Re < 10 29.1667 -3.8889 1.222

10 < Re < 100 46.5 -116.67 0.6167

100 < Re < 1000 98.33 -2778 0.3644

1000 < Re < 5000 148.62 -4.75 × 104 0.357

5000 < Re < 10,000 -490.546 57.87 × 104 0.46

10,000 < Re < 50,000 -1662.5 5.4167 × 106 0.5191

Figure B-4. Reynolds number for three hydrodynamic separators (HS) as a function of flow rate.

Flow rate (L/s)

0 20 40 60 80 100

Re

0

2000

4000

6000

8000

10000

12000

BHS

VHS

SHS

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Table B-2. The injection particulate matter (PM) size.

Injection PM size

(μm)

2000

850

600

425

300

250

180

150

106

75

63

53

45

38

25

10

7

5

3

1

Table B-3. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 1 (29

June 2010) - BHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.00 0.00 0.0 0.00 0.00

2.3 2.21 2444.3 133.2 50.5 0.70 117.88

4.1 5.67 1488.5 538.2 78.6 0.70 201.67

5.6 1.59 863.9 548.6 78.1 1.09 91.57

7.3 4.97 756.6 510.8 108.5 0.87 199.71

9.6 4.15 428.9 198.9 74.6 1.37 67.53

12.6 2.28 487.9 201.0 62.3 0.98 80.08

15.6 2.42 396.9 63.2 71.8 1.32 67.72

20.6 1.24 522.8 36.7 62.8 1.09 75.85

26.6 0.48 136.3 75.0 85.2 1.57 61.26

35.6 0.07 4929.9 22.4 68.8 1.24 73.97

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Table B-4. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 2 (11

July 2010) - BHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

6.0 0.16 1760.1 18.2 124.8 0.57 493.56

8.0 0.46 445.9 6.6 109.8 0.84 192.01

10.0 0.35 195.7 8.0 125.6 0.83 220.96

12.0 0.43 1001.6 14.5 109.1 1.10 138.28

15.0 3.21 223.2 57.9 41.0 0.95 63.93

18.3 1.54 49.5 66.9 61.3 1.39 55.97

22.5 2.94 231.5 65.5 145.9 1.24 152.58

25.5 2.76 996.8 143.7 150.8 1.70 105.02

28.3 0.55 391.4 101.1 191.2 1.68 127.81

34.3 0.02 1573.6 29.5 190.3 0.66 496.34

Table B-5. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 3 (29

June 2010) - BHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

4.4 2.47 8088.6 52.1 187.4 0.67 484.48

5.9 2.14 782.8 17.0 125.6 0.57 498.67

7.3 2.83 419.7 192.8 86.4 0.81 155.24

10.7 3.82 207.9 107.0 125.6 0.83 220.96

17.2 0.04 3137.0 39.1 109.2 1.09 139.65

20.3 2.20 567.9 62.0 41.5 0.95 64.27

23.3 3.74 549.0 64.4 61.2 1.40 55.25

28.3 13.63 260.5 163.8 146.9 1.22 157.01

38.5 0.97 78.5 41.9 150.9 1.71 103.87

48.7 0.98 20.4 12.7 191.5 1.67 128.35

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Table B-6. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 4 (11

July 2010) - BHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

8.8 0.23 977.8 8.4 249.0 1.88 165.55

10.2 0.46 267.1 8.1 170.6 0.88 314.32

11.9 2.30 739.7 15.8 183.8 0.83 371.15

12.7 2.14 240.1 25.7 171.8 0.82 357.48

13.6 0.38 108.1 25.2 129.7 0.76 321.84

14.6 0.46 700.4 29.1 428.9 1.18 474.71

15.5 0.38 115.9 43.2 406.4 1.00 541.59

16.7 0.38 56.7 63.9 182.1 0.74 398.36

22.0 0.35 33.3 18.1 85.4 0.56 324.19

27.1 0.06 13.8 16.8 50.4 0.83 97.48

Table B-7. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 1 (13

March 2004) - SHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

7.0 0.01 230.9 0.4 45.2 0.77 35.36

22.0 0.05 10.6 1.5 28.4 0.56 132.35

101.0 0.02 1421.8 6.4 52.2 0.85 20.95

105.0 0.25 863.8 1.1 60.3 0.79 15.67

109.0 0.76 62.6 0.2 43.9 0.81 24.72

113.0 1.16 164.8 8.1 52.8 0.82 22.43

117.0 2.73 402.0 21.6 49.0 0.84 16.46

121.0 2.19 0.1 6.6 45.0 0.85 11.39

125.0 1.93 36.2 6.2 41.5 0.86 17.95

129.0 1.99 3.7 2.7 56.4 0.83 14.13

133.0 0.89 12.7 6.6 43.6 0.87 18.78

148.0 0.41 51.2 0.5 55.4 0.95 10.21

163.0 0.55 34.6 0.2 46.1 0.88 13.64

208.0 1.07 1.5 0.1 51.4 0.85 18.34

253.0 0.88 12.6 0.1 44.6 0.77 19.63

283.0 1.55 4.2 0.1 51.2 0.88 15.46

393.0 1.81 17.1 0.1 38.1 0.79 22.34

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Table B-8. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 2 (20

August 2004) - SHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.00 0.0 0.0 0.00 0.00

10.0 0.01 4259.82 334.20 255.9 1.19 289.68

12.0 1.13 3859.64 866.17 232.0 0.98 341.91

14.0 3.71 374.87 307.82 188.8 1.45 169.73

17.0 5.08 2798.83 215.85 195.0 1.70 142.08

21.0 15.80 375.64 111.78 199.8 1.66 145.46

26.0 15.85 445.04 115.89 211.5 1.05 273.43

29.0 7.18 206.69 105.61 541.2 3.98 152.60

31.0 3.71 161.64 50.82 735.3 4.15 194.53

33.0 1.61 108.08 60.53 547.4 3.37 187.00

34.0 1.01 138.77 51.59 551.0 3.71 168.52

36.0 0.74 66.95 43.42 288.7 1.22 188.29

38.0 0.46 63.99 48.66 264.2 1.42 165.37

40.0 0.29 65.60 45.63 256.7 1.38 155.91

43.0 0.19 92.46 34.02 297.3 1.45 152.50

46.0 0.12 127.12 334.20 285.0 1.21 132.76

Table B-9. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 3 (14

October 2004) - SHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

31.0 0.01 230.9 0.0 94.4 0.90 174.45

63.0 0.04 618.5 379.5 13.6 0.97 21.33

69.0 0.31 849.2 347.9 38.5 0.58 156.25

73.0 0.43 604.3 303.5 28.5 0.74 71.45

79.0 0.42 458.4 283.0 116.2 1.02 172.27

86.0 0.46 384.1 257.7 133.4 0.71 350.89

106.0 0.43 332.5 232.2 64.7 0.78 116.59

122.0 0.27 256.8 209.6 115.4 2.04 62.12

132.0 0.11 200.2 198.1 85.3 1.54 63.79

140.0 0.06 197.2 200.4 22.4 0.72 58.61

155.0 0.09 237.0 210.6 90.7 0.71 152.71

165.0 0.08 236.0 218.5 80.3 0.56 175.31

176.0 0.03 192.8 217.1 60.2 0.66 133.25

197.0 0.01 194.0 217.1 54.3 0.54 116.82

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Table B-10. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 4

(30 June 2005) - SHS.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

9.0 0.01 3075.7 0.0 133.3 0.92 226.78

11.0 0.57 1753.3 462.9 268.8 0.76 561.33

12.0 2.18 1016.7 424.3 102.1 0.54 443.80

14.0 4.03 681.9 394.4 77.7 0.57 319.00

15.0 6.81 405.8 323.3 40.0 0.59 171.56

17.0 11.06 265.0 207.7 38.9 0.56 190.10

19.0 13.21 166.5 136.4 44.6 0.53 220.46

21.0 13.53 153.5 120.2 106.0 0.53 410.79

23.0 12.75 142.8 94.5 45.7 0.55 207.91

29.0 10.22 104.6 81.9 83.4 0.66 278.95

33.0 2.50 74.9 69.7 39.8 0.58 181.34

36.0 0.59 118.1 62.2 42.9 0.53 175.11

42.0 0.54 332.8 95.8 45.1 0.57 170.60

48.0 1.50 301.3 114.2 48.2 0.58 180.12

58.0 2.30 105.4 103.1 46.3 0.58 190.47

68.0 1.97 113.0 99.9 37.1 0.56 182.15

Table B-11. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 1

(21 April 2006) - VCF.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

1.0 1.72 5805.5 158.9 33.1 0.57 132.80

3.0 3.64 2695.4 130.9 24.5 0.66 78.85

6.0 4.30 931.9 122.7 18.3 0.66 54.28

10.0 0.43 767.6 116.1 11.5 0.67 34.13

13.0 0.25 603.0 108.9 12.1 0.68 33.75

16.0 0.10 254.9 109.1 7.5 0.69 21.07

19.0 0.04 183.3 108.6 7.3 0.65 23.32

23.0 0.01 174.1 100.5 35.7 1.13 41.27

27.0 0.02 247.3 118.0 25.1 0.71 52.74

32.0 0.02 227.4 112.6 5.8 0.67 18.49

37.0 0.01 161.0 126.2 6.2 0.95 11.97

42.0 0.02 183.1 106.4 33.7 0.98 47.23

49.0 0.01 183.0 117.7 16.3 0.60 43.08

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Table B-12. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 1

(29 April 2006) - VCF.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

5.0 0.20 5036.4 58.8 11.5 0.70 34.37

9.0 8.74 769.4 100.6 8.7 0.51 60.66

13.0 6.38 325.3 77.8 19.4 0.84 41.10

17.0 3.14 272.7 49.4 123.5 0.91 207.60

21.0 1.66 256.1 41.2 49.0 0.47 373.64

25.0 1.28 192.1 44.6 315.6 24.55 12.89

31.0 1.69 150.7 39.6 13.7 0.74 37.23

37.0 1.78 124.2 38.3 248.2 1.54 164.52

43.0 0.94 135.3 26.9 20.1 0.48 169.53

49.0 0.96 152.5 30.8 299.9 15.44 19.40

60.0 0.60 165.3 26.0 24.0 0.50 179.53

69.0 0.38 112.7 20.0 297.4 9.80 30.01

76.0 0.39 99.9 17.0 31.8 0.49 242.11

87.0 0.24 77.1 23.6 97.0 0.51 386.80

104.0 0.21 60.1 25.7 47.6 0.49 332.80

134.0 0.54 58.3 19.0 309.7 19.99 15.51

143.0 0.58 42.4 19.4 13.5 0.87 25.39

159.0 0.17 37.9 19.8 75.9 0.94 100.69

Table B-13. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 1

(04 July 2006) - VCF.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

6.0 0.06 2236.3 40.5 40.6 0.64 139.16

8.0 0.80 631.6 46.4 76.4 0.59 250.61

10.0 0.94 253.4 34.2 22.5 0.77 55.68

12.0 0.60 245.0 45.4 129.9 0.58 332.81

13.0 0.26 211.7 43.4 19.9 0.78 45.24

15.0 0.21 328.2 39.9 40.4 0.60 174.43

18.0 0.16 166.2 45.6 17.7 1.03 23.35

20.0 0.08 171.2 41.1 23.2 2.93 9.41

26.0 0.10 477.0 42.0 14.9 0.74 34.67

29.0 0.14 154.1 48.7 47.3 0.91 93.35

31.0 0.07 111.0 39.6 16.0 0.82 30.03

34.0 0.05 87.6 39.9 27.8 0.61 183.36

37.0 0.02 87.0 32.8 13.2 0.82 23.57

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Table B-14. Particle injection time (min), flow rate (L/s), influent and effluent PM concentration,

median particle diameter (d50m), γ – shape factor, and β – scaling factor of storm 1

(04 July 2006) - VCF.

Injection

time (min)

Flow rate

(L/s)

PMinf

[mg/L]

PMeff

[mg/L]

d50m

(μm) γ β

0.0 0.00 0.0 0.0 0.0 0.00 0.00

6.0 0.05 219.6 23.1 15.2 0.76 36.34

9.0 0.19 79.3 21.6 27.1 0.53 149.70

12.0 0.12 45.9 26.0 9.3 0.83 19.54

15.0 0.06 74.4 30.5 25.7 0.85 45.93

19.0 0.08 49.8 32.7 7.8 0.70 23.77

22.0 0.04 61.9 30.3 56.6 0.67 183.79

26.0 0.05 182.8 38.9 10.7 0.69 32.52

29.0 0.41 237.8 45.0 103.3 0.59 315.56

32.0 0.59 159.7 37.6 8.3 0.79 18.83

36.0 0.23 150.7 31.7 28.8 1.87 19.19

40.0 0.23 60.6 35.0 7.0 0.79 16.56

48.0 0.14 35.4 25.7 25.0 0.93 33.17

58.0 0.02 29.8 26.8 13.3 0.72 35.95

65.0 0.09 12.9 12.5 64.2 0.79 121.15

Table B-15. Computing time for stepwise steady CFD modeling and fully transient flow as a

function of number of steady steps.

# of steady steps

Stepwise steps

computing time

(hrs.)

Fully transient flow

computing time

(hrs.)

10 1.5 ± 1 72 ± 12

20 3.0 ± 1 72 ± 12

30 4.5 ± 1 72 ± 12

40 6.0 ± 1 72 ± 12

50 7.5 ± 1 72 ± 12

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158

Table B-15. Computing time for stepwise steady CFD modeling and fully transient flow as a

function of number of steady steps.

UOP Storm

event

BHS

(2010)

29 June 15.73

11 July 9.47

28 July 7.87

14 August 2.99

SHS

(2004-2005)

14 March 2.66

20 August 7.82

14 October 1.42

30 June 8.24

VCF

(2006)

21 April 17.46

29 April 3.59

04 July 11.89

05 July 4.25

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159

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BIOGRAPHICAL SKETCH

Hwan Chul Cho was born in Daegu, South Korea and he came to the United States in Fall

2007 after receiving his Bachelor of Engineering degree in Department of Environmental

Engineering at Ajou University, South Korea. He received his Ph.D. in environmental

engineering from University of Florida in April 2012. His doctoral research was focused on

physical and computational fluid dynamics (CFD) models of PM separation and scour in

hydrodynamic unit operations. He completed his research under the guidance of Dr. John J.

Sansalone in the Department of Environmental Engineering and Sciences. Hwan Chul pursues

life to the fullest, loves his family deeply, and enjoys deep and intimate relationships.