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NATO Science SeriesA Series presenting the results of scientific meetings supported under the NATO ScienceProgramme.
The Series is published by IOS Press, Amsterdam, and Springer in conjunction with the NATO Public Diplomacy Division
Sub-Series
I. Life and Behavioural Sciences IOS PressII. Mathematics, Physics and Chemistry SpringerIII. Computer and Systems Science IOS PressIV. Earth and Environmental Sciences Springer
The NATO Science Series continues the series of books published formerly as the NATO ASI Series.
The NATO Science Programme offers support for collaboration in civil science between scientists ofcountries of the Euro-Atlantic Partnership Council. The types of scientific meeting generally supportedare “Advanced Study Institutes” and “Advanced Research Workshops”, and the NATO Science Seriescollects together the results of these meetings. The meetings are co-organized bij scientists fromNATO countries and scientists from NATO’s Partner countries – countries of the CIS and Central andEastern Europe.
Advanced Study Institutes are high-level tutorial courses offering in-depth study of latest advancesin a field.Advanced Research Workshops are expert meetings aimed at critical assessment of a field, andidentification of directions for future action.
As a consequence of the restructuring of the NATO Science Programme in 1999, the NATO ScienceSeries was re-organised to the four sub-series noted above. Please consult the following web sites forinformation on previous volumes published in the Series.
http://www.nato.int/sciencehttp://www.springer.comhttp://www.iospress.nl
Series II: Mathematics, Physics and Chemistry – Vol. 242
edited by
and
Published in cooperation with NATO Public Diplomacy Division
Soft Matter under Exogenic Impacts
Sylwester J. Rzoska
Victor A. Mazur
Institute of Physics, Silesian University, Katowice, Poland
Odessa, Ukraine
Department of Biophysics and Molecular Physics,
State Academy of Refrigeration,Department of Thermodynamics, Institute of Energy and Ecology,
A C.I.P. Catalogue record for this book is available from the Library of Congress.
Published by Springer,P.O. Box 17, 3300 AA Dordrecht, The Netherlands.
www.springer.com
Printed on acid-free paper
All Rights Reserved© 2007 SpringerNo part of this work may be reproduced, stored in a retrieval system, or transmitted inany form or by any means, electronic, mechanical, photocopying, microfilming,recording or otherwise, without written permission from the Publisher, with the exceptionof any material supplied specifically for the purpose of being entered and executed on acomputer system, for exclusive use by the purchaser of the work.
Soft Matter under Exogenic Impacts: Fundamentals and Emerging TechnologiesProceedings of the NATO Advanced Research Workshop on
Odessa, Ukraine, 8--12 October 2005
ISBN 978-1-4020-5871-4 (PB)ISBN 978-1-4020-5870-7 (HB)ISBN 978-1-4020-5872-1 (e-book)
Part I: General Issues Asteroid impact in the black sea; a black scenario
The conductivity of hydrogen in extreme conditions
in the TIP5P model of water
Amorphization of ice by collapse under pressure,
Coupled ordering in soft matter: competition of mesoscales and dynamics of coupled fluctuations
All standard theories and models of glass transition appear to be inadequate: missing some essential physics
Part II: Glass forming liquids Positron annihilation lifetime spectroscopy
the disordered condensed systems characterization
V. T. Shvets, S. V. Savenko, J. K. Malynovski................................................... 9
1
P. Kumar, S. V. Buldyrev, H. E. Stanley...........................................................
vibrational properties, and ultraviscous water at 1 GPa
Segmental and chain dynamics in polymers
K. L. Ngai..........................................................................................................
S. Pawlus, M. Paluch, M. Mierzwa, S. Hensel-Bielowka,
23
M. A. Anisimov.................................................................................................. 75
91
and atomistic modeling – effective tools for
J. Bartoš, D. Ra ko, O.Šauša, J. Krištiak.........................................................113
R. Casalini, C. M. Roland................................................................................141
...........................................149
C. M. Roland, R. Casalini.................................................................................133
R. D. Schuiling, R. B. Cathcart, V. Badescu.....................................................
TABLE OF CONTENTS
G. P. Johari, O. Andersson............................................................................... 35
Isobaric and isochoric properties of glass-formers,
Dynamic crossover and liquid–liquid critical point
Influence of Differences in Molecular structure on Behavior of and Relaxation Processes in Diisooctyl Phthalate and Diisooctyl Maleate
E. Kami sha, K. Kami ski, S. J. Rzoska, S. Ma lanka ń ń
Orientationally disordered glassy phases
Part III: Liquid Crystals
the influence of molecular structure
mixture of liquid crystals
Annihilation of defects in liquid crystals
Part IV: Critical Liquids
environmentally significant organic chemicals mixtures
Properties of water near its critical point
Nonlinear dielectric spectroscopy near smectic A–smectic C*
Waves at the nematic–isotropic interface: nematic–non-nematic and polymer–nematic mixtures
Fluctuational equation of state and slopes of critical curves near the critical point of solvent
vi TABLE OF CONTENTS
J. Ll. Tamarit, S. Pawlus, A. Drozd-Rzoska, S. J. Rzoska.................................161
A. Drozd-Rzoska, S.J. Rzoska, M. Janik...........................................................189
M. Mierzwa, M. Paluch, S. J. Rzoska, J. Zio o, U. Maschke............................201
Glassy dynamics of rod-like liquid crystals:
M. Svetec, M. Ambroži , S. Kralj......................................................................239
V. Popa-Nita, T. J. Sluckin................................................................................253
S. V. Artemenko, V. A. Mazur.........................................................................269
V. Kulinskii, N. Malomuzh................................................................................287
V. Rogankov, O. Byutner..................................................................................305
Ordering effect on dynamics in glass-forming
Space – Preliminary Dielectric Relaxation Study
Global phase behavior of supercritical water –
A. Drozd-Rzoska, S. J. Rzoska, J. Zio o............................................................215 transition in ferroelectric liquid crystal DOBAMBC
Confined liquid crystaline 5CB in 2D Thermodynamic
S. Pawlus, J. Osinska, S. J. Rzoska, S. Kralj, G. Cordoyiannis........................229
Combined models of thermophysical properties along the coexistence curve
Intermolecular potential for simple liquids and gases
in the high pressure region
Homogeneous nucleation and growth from highly
How to generate and measure negative pressure in liquids?
in binary liquids under negative pressure
Critical properties of soft matter at restricted geometry as emerging problem: fundamentals and biological applications
Recent progresses in understanding of water interacting with biomolecules, and inside living cells and tissues
supersaturated vapor by molecular dynamics simulation
Part V: Bio-liquids and related problems
Water–biomolecule systems under extreme conditions: from confinement to pressure effects
Self-assembly of polypeptides. The effect of thermodynamic confinement
viiTABLE OF CONTENTS
V. Yu. Bardic, L. A. Bulavin, V. M. Sysoev,
Indirect methods to study liquid–liquid miscibility
A. V. Chalyi, L. A. Bulavin, K. A. Chalyy,
E. E. Ustjuzhanin, B. F. Reutov, V. F. Utenkov, V. A. Rykov...........................325
N. P. Malomuzh, K. S. Shakun..........................................................................339
N. Lümmen, B. Fischer, T. Kraska....................................................................351
A. R. Imre..........................................................................................................379
A. R. Imre, A. Drozd-Rzoska, S. J. Rzoska, T. Kraska. ..................................... 389
L. M. Chernenko, A. N. Vasil’ev, E. V. Zaitsev................................................ 399
M.-C. Bellissent-Funel......................................................................................413
R. C. Ford, J. Li................................................................................................433
G. Floudas, P. Papadopoulos...........................................................................447
Coulomb liquids under electric field – application of a new computer simulation method
viii TABLE OF CONTENTS
E. S. Yakub........................................................................................................457
A. Onuki............................................................................................................467 Solvation effects in near-critical polar fluids
Directors:
Sylwester J. Rzoska
Victor M. Mazur
Key speakers:
Gyan P. Johari
Christiane M. Alba-Simionesco
Marie-Claire-Bellisent
Thomas Kraska
Department of Biophysics and Molecular Physics,Institute of Physics, Silesian University, Katowice, Poland.
Department of Thermodynamics, Institute of Energy and Ecology,
Department of Materials Science and Engineering, McMaster University, Canada.
Lab. Chimie Physique, C.N.R.S, Université Paris-Sud Orsay, France.
Laboratoire Leon Brillouin, Gif-Dur-Yvette, France.
Institute for Physical Chemistry, University at Cologne, Köln, Germany.
Department of Physics, Univ. of Ioannina, Ioannina, and FORTH-BRI George Floudas
Attila R. Imre
Simone Capaccioli Istituto Nazionale per la Fisica della Materia and Dip. di. Fisica Univ. di Pisa,
Aleksandra Drozd-Rzoska
KFKI Atomic Energy Institute, Budapest, Hungary.
Italy.
Utrecht University, Utrecht, The Netherlands.
Institute of Physics, Silesian University, Katowice, Poland.
PARTICIPANTS
State Academy of Refrigeration, Odessa 65026, Ukraine.
Greece.
Roelof D. Schuiling
ix
A. Mickiewicz University, Department of Macromolecular Physics, Poznan,
Jerzy Zio o
Samo Kralj
Josep Lluís Tamarit
Jichen. C. Li
Mikhail A. Anisimov
Institute of Physics, Silesian University, Katowice, Poland.
Poland.
Institute of Physics, Silesian University, Katowice, Poland.
Univerza v Mariboru, Oddelek za fiziko, Maribor, Slovenia.
ETSEIB, Universitat Politècnica de Catalunya, , Barcelona, Catalunya, Spain.
Dept. Physics, Biomolecular Sci, Manchester University, Manchester, UK.
H. Eugene Stanley
C. Mike Roland
Park, USA.
Naval Research Laboratory, Washington, USA. Kia L. Ngai
Eugene Yakub
Leonid Bulavin
Nikolay Malomuzh
Naval Research Laboratory, Washington, USA.
Computer Science Dept., State Economic University, Odessa, Ukraine.
Taras Shevchenko Kiev National University, Ukraine.
Odessa National University, Odessa, Ukraine.
PARTICIPANTSx
Marian Paluch
Stefan Jurga
Center for Polymer Studies, Dept. Phys., Boston University, Boston, USA.
Dept. Chem. Engn. & Inst. for Phys. Sci. & Tech. Univ. of Maryland College
Kirill Schmulovich
Akira Onuki Department of Physics, Graduate School of Science, Kyoto University, Kyoto,
Other Participants:
George Cordoyiannis National Centre for Scientific Research “Demokritos”, Aghia Paraskevi,
Micha Mierzwa
Wies aw Su kowski
Sebastian Pawlus
Institute of Experimental Mineralogy, Chernogolovka, Russia.
Japan.
Greece.
Institute of Physics, Silesian University Katowice, Poland.
Institute of Chemistry, Silesian University, Katowice, Poland.
Institute of Physics, Silesian University, Katowice, Poland. Ma gorzata Janik Institute of Physics, Silesian University, Katowice, Poland.
Aleksandr V. Chalyi Physics Dept., National Medical University, Kiev, Ukraine.
S awomir Ma lanka
Milan Svetec Regional Dev. Agency and Fac. of Educ., University of Maribor, Maribor,
Josef Bartos
Ricardo Casalini
Institute of Chemistry, Silesian University, Katowice, Poland.
Slovenia.
Polymer Inst., Slovak Academy of Sciences, Bratislava, Slovakia.
Naval Res. Lab., Washington DC and George Mason University, Fairfax, USA.
PARTICIPANTS xi
Vlad Popa-Nita
Dmitry Yu. Ivanov
H. Schvets
Vladimir Kulinski
Sergey Artemenko
St. Petersburg State Uni. of Refrig. and Food Engn, Saint Petersburg, Russia.
Faculty of Physics, University of Bucharest, Romania.
Odessa Natl. University, Odessa, Ukraine.
Odessa Natl. University, Odessa, Ukraine.
Odessa Natl. University, Odessa, Ukraine.
Odessa Natl. University, Odessa, Ukraine.
PARTICIPANTSxii
Vitaly Rogankov
the Black Sea in the background.
Participants of the ARW NATO “Soft Matter under Exogenic Impacts: Fundamentals and Emerging Technologies” Odessa, Ukraine, 2005 at the terrace of Hotel “Morskoy”. Arrows indicate directors of the workshop. Note
Strong sensitivity even to moderate external impacts is a canonical feature of soft matter systems, the novel category covering critical liquids, polymers and
dynamics are their subsequent common features, which can be strongly influenced by external impacts. This book presents the hardly available so far comprehensive presentation of high pressures, negative pressures, random
systems. Exogenic means derived or originating externally. It is used in social
far. Using this term we would like to point out strong and comprehensive influence of various external factors on soft matter system. The most classical example of exogenic actions is an asteroid impact, the problem from the discussion presented in this volume begins.
The book was prepared to the cooperation of the prominent specialist focusing on soft matter and exogenic impacts, the direction which joins unusual experimental and theoretical difficulties with the promise of milestone results. It can serve as a guide in the novel and still puzzling research area. However, it also contains new results, appearing just in this volume. Identification of new types of physical behavior, new technological materials, ultimate verification of condensed and soft matter physics models, new applications in geophysics,
brainstorming discussion in superior conditions.
Sylwester J. Rzoska (Poland) Victor A. Mazur (Ukraine)
PREFACE
The dominance of mesoscale structures, rich phase structure, and complex
constraints, and strong electric field exogenic impacts on various soft matter
sciences, geology, biology, or medicine but hardly, if at all used in physics so
biophysics, biotechnology – all these are topics of this book.
The research activity of some of polish participants was possible dueto the Polish Committee for Sci. Res. (KBN, grant no 2PO3B 025 34, for years 2003–2003, grant. resp. S. J. Rzoska).
to the Science NATO Programme which support made it possible the Directors of the ARW NATO and all participants are very grateful
blends, liquid crystals, glass forming liquids, bioliquids and biopolymers, . . .
This book was prepared due to the Advanced Research Workshop NATO
a brainstorming discussion which took place in Hotel Morskoy, Odessa, Ukraine, 8–12 October 2005. r.
“Soft Matter under Exogenic Impacts: Fundamental and Emerging Technologies”,
xiii
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