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Practical Aspects of

Supercritical Carbon Dioxide

Brayton System Testing

Bechtel Marine Propulsion CorporationBettis Atomic Power LaboratoryWest Mifflin, PA

Page 1Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Brayton System Testing

Eric Clementoni

Timothy Cox

Presentation Summary

• S-CO2 Brayton Cycle Integrated Systems Test (IST)

Overview and Operating Experience

• Best Practices for S-CO2 Power Cycle Operation

– Design Considerations

– Loop Cleanliness

– System Fill and Leakage

Page 2Supercritical CO2 Power Cycles Symposium September 9-10, 2014

– System Fill and Leakage

– Instrumentation

• Conclusions

• 100 kWe IST has been main S-CO2

development focus of BMPC

• Simple Brayton cycle

– Single variable speed turbine-compressor

– Single constant speed turbine-generator

IST Overview

Page 3Supercritical CO2 Power Cycles Symposium September 9-10, 2014

– Single constant speed turbine-generator

– Single recuperator

• Focus on system control

– Rapid startup

– Power changes

– Shutdown

CompressorTurbine

Heat

Source

Generator Turbine

Recuperator

Precooler

Sea WaterCooling

Water

IST Physical Layout

Turbo-Generator

Page 4Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Recuperator

Precooler

Turbo-Compressor (not

visible)

Operational Experience• Shakedown started in Fall 2011

• Brayton cycle operation started in Spring 2012

• Over 165 hours of Brayton system operation

• Achieved 40% of design power

Page 5Supercritical CO2 Power Cycles Symposium September 9-10, 2014

**40 kW on

power

analyzer

System Transient Modeling

• IST design supported by transient model

predictions

– Pipe size, valve resistance, valve stroke time,

support equipment operating requirements

Page 6Supercritical CO2 Power Cycles Symposium September 9-10, 2014

support equipment operating requirements

• Transient model valuable for startup and low

power operation

– Closed system more difficult to startup and get to

full power condition than open Brayton cycle

Mechanical Connections

• IST utilizes the following fittings in CO2 systems

– Grayloc fittings for main loop piping/component

connections

– ¼” Swagelok fittings welded to pipe for instrumentation

– ¼”-2” Swagelok fittings and 2” ANSI flanges for support

system connections

Page 7Supercritical CO2 Power Cycles Symposium September 9-10, 2014

system connections

• Fittings all leak tight when installed properly

• Bolt selection considerations– Thermal fatigue from heatup

and cooldown cycles

– Brittle fracture from low

temperature of leaking CO2

Thermal Stress Consideration• Small equipment allows for compact system arrangement

• Compact arrangements can make thermal stress more difficult

to accommodate

• IST design considered thermal stress from the beginning

– 4 thermal expansion loops included in Brayton loop piping to

accommodate thermal expansion

Page 8Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Material Quality / Cleanliness

• Supercritical CO2 is a strong solvent

• Materials testing and loop operating

experience has shown that some polymer

materials are incompatible with the

Page 9Supercritical CO2 Power Cycles Symposium September 9-10, 2014

materials are incompatible with the

supercritical CO2 environment

• BMPC test loops have implemented material

quality and cleanliness controls which have

shown effective at eliminating system

contamination

Turbine Nozzle Erosion

Page 10Supercritical CO2 Power Cycles Symposium September 9-10, 2014

System Fill and Leakage

• IST uses Coleman Instrument grade (99.99%)

CO2 for fill

• Three cycles of pulling vacuum and filling to

atmospheric pressure before full fill

Page 11Supercritical CO2 Power Cycles Symposium September 9-10, 2014

atmospheric pressure before full fill

• Low leakage levels from valve stem packing

and large shaft seals

Instrumentation• Temperature and pressure measurements give good

indication of loop conditions

• Coriolis flow meters used to determine both flow

rate and density of CO2

– Flow meters give good results for single phase or

supercritical flow

Page 12Supercritical CO2 Power Cycles Symposium September 9-10, 2014

supercritical flow

– Can give invalid readings during loop startup if installed

orientation allows for low point for liquid collection

Density Calculations using

REFPROP with T & P

Page 13Supercritical CO2 Power Cycles Symposium September 9-10, 2014

Summary

• No inherent issues with S-CO2 Brayton power

cycle operation identified in IST operation

• Off-design operations, thermal stress analysis,

instrumentation orientation, cleanliness, and

Page 14Supercritical CO2 Power Cycles Symposium September 9-10, 2014

instrumentation orientation, cleanliness, and

material compatability are important design

considerations

• Experience from small-scale testing will

minimize rework and operational issues for

larger systems

Acknowledgements

• This paper summarizes work that has been

performed a number of devoted engineers,

scientists, technicians, and support personnel

at the Bechtel Marine Propulsion Corporation

Page 15Supercritical CO2 Power Cycles Symposium September 9-10, 2014

at the Bechtel Marine Propulsion Corporation

and our subcontractors. This paper would not

be possible without the efforts of this team.

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