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FORM-I
for
PROPOSED EXPANSION OF PESTICIDES TECHINCAL (200
MT/MONTH), & SPECIALTY CHEMICALS (912
MT/MONTH) IN EXISTING UNIT
of
M/s. WANKSONS CHEMICAL INDUSTRIES PVT. LTD.
Plot No. 518, GIDC Industrial Estate, Panoli - 394 116,
Taluka: Ankleshwar, Dist. Bharuch, Gujarat, INDIA.
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.403, Centre Point, Nr. Kadiwala School, Ring Road, Surat - 395002
Prepared By:
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.403, Centre Point, Nr. Kadiwala School, Ring Road, Surat - 395002
NABL Accredited Testing Laboratory
ISO 9001:2008 Certified Company
Aqua-Air Environmental Engineers P. Ltd.403, Centre Point, Nr. Kadiwala School, Ring Road, Surat - 395002
Prepared By:
APPENDIX I
FORM 1
1. Basic Information
Sr. No.
Item Details
1. Name of the Project/s M/s. Wanksons Chemical Industries Pvt. Ltd.
2. S. No. in the Schedule 5 (b) & 5(f)
3. Proposed capacity / area / length / tonnage to be handled/command area/lease area/number of wells to be drilled
1. Existing Production Capacity: 1. Specialty Chemicals:
286 MT/Month
2. Total Production Capacity after Proposed Expansion:
Specialty Chemicals, Pesticides - 1192 MT/Month
- Reference: Annexure-1.
3. Total Plot Area: 10,290 m2
4. No bore well is and will be drilled within the premises.
4. New/Expansion/Modernization Expansion
5. Existing capacity/area etc. 5. Existing Production Capacity: 6. Specialty Chemicals:
286 MT/Month
7. Existing Plot Area: 10,290 m2
6. Category of project i.e. ‘A’ or ‘B’ ‘A’
7. Does it attract the general condition? If yes, please specify.
No.
8. Does it attract the specific condition? If yes, please specify.
No.
9. Location
Plot/Survey/Khasra No. Plot. No. 518
Village GIDC Industrial Estate, Panoli - 394 116
Tehsil Ankleshwar
District Bharuch
State Gujarat
10. Nearest railway station/airport along with By road distance:
distance in kms. Nearest Railway Station: Panoli = 2.5 km (approx.) Nearest Airport : Surat = 60 km (approx.)
11. Nearest Town, city, District Headquarters along with distance in kms.
By road distance: Nearest Town : Panoli = 2 km (approx.) Nearest District Head Quarter : Bharuch = 15 km (approx.)
12. Village Panchayats, Zilla Parishad, Municipal corporation, Local body (Complete postal addresses with telephone nos. to be given)
Notified Area Authority, Panoli
13. Name of the applicant M/s. Wanksons Chemical Industries Pvt. Ltd.
14. Registered address Plot. No. 518, GIDC Industrial Estate, Panoli -394 116, Tal: Ankleshwar, Dist: Bharuch, Gujarat.
15. Address for correspondence:
Name Mr. Indrasinh H. Parmar
Designation (Owner/Partner/CEO) GM (Production)
Address M/s. Wanksons Chemical Industries Pvt. Ltd. Plot. No. 518, GIDC Industrial Estate, Panoli -394 116, Tal: Ankleshwar, Dist: Bharuch, Gujarat.
Pin Code 394 116
E-Mail ihparmar@hotmail.com
Telephone No. Tel: +91-7490032431/9427178117 Mob.: +91 9724302128
Fax No. --
16. Details of Alternative Sites examined, if any location of these sites should be shown on a topo sheet.
No
17. Interlinked Projects No
18. Whether separate application of interlinked project has been submitted?
No interlinked project has been submitted.
19. If Yes, date of submission Not applicable
20. If no., reason Not applicable
21. Whether the proposal involves approval/clearance under: If yes, details of the same and their status to be given. 1. The Forest (Conservation) Act, 1980? 2. The Wildlife (Protection) Act, 1972? 3. The C.R.Z Notification, 1991?
Not applicable as proposed expansion activity will be within GIDC Industrial Estate, Panoli, Taluka Ankleshwar, Dist. Bharuch, Gujarat.
22. Whether there is any Government order/policy relevant/relating to the site?
No
23. Forest land involved (hectares) No
24. Whether there is any litigation pending against the project and/or land in which the project is propose to be set up? 1. Name of the Court 2. Case No.
No
3. Orders/directions of the Court, if any and its relevance with the proposed project.
(II) Activity
1. Construction, operation or decommissioning of the Project involving actions, which will cause
physical changes in the locality (topography, land use, changes in water bodies, etc.)
Sr. No.
Information/Checklist confirmation Yes /No?
Details thereof (with approximate quantities / rates, wherever possible) with source of information data
1.1 Permanent or temporary change in land use, land cover or topography including increase in intensity of land use (with respect to local land use plan)
No --
1.2 Clearance of existing land, vegetation and buildings?
No --
1.3 Creation of new land uses? No Land is for industrial purpose. Proposed expansion activity will be carried out within existing site which is located on level ground does not require any land filling for area grading work.
1.4 Pre-construction investigations e.g. bore houses, soil testing?
No As any kind of construction activity won’t require in proposed expansion activity, pre-construction investigations are not required.
1.5 Construction works? No No, any kind of construction works is not required. Existing infrastructures and ancillary facilities are adequate for proposed expansion activity. - Reference: Annexure - 2.
1.6 Demolition works? No --
1.7
Temporary sites used for construction workers or housing of construction workers?
No --
1.8 Above ground buildings, structures or earthworks including linear structures, cut and fill or excavations
Yes As existing infrastructures are adequate for proposed expansion activity, no kind of excavation work is required. - Reference: Annexure - 2.
1.9
Underground works including mining or tunneling?
No --
1.10 Reclamation works? No --
1.11 Dredging? No --
1.12 Offshore structures? No --
1.13 Production and manufacturing processes? Yes Reference: Anneure-3.
1.14 Facilities for storage of goods or materials?
Yes Existing storage facilities/area is available as an existing infrastructure for storage of
existing raw materials, finished products, hazardous/solid wastes, etc. Existing infrastructure for storage of raw materials, finished products, hazardous/solid wastes, etc. are adequate for storage of additional raw materials, finished products, hazardous/solid wastes, etc.
1.15
Facilities for treatment or disposal of solid waste or liquid effluents?
Yes 1. Water consumption & Waste water generation details
– Reference: Anneure-4. 2. Effluent Treatment Plant details
– Reference: Anneure-5. 3. Hazardous/Solid wastes generation and
disposal mode details – Reference: Anneure-6.
1.16
Facilities for long term housing of operational workers?
No --
1.17 New road, rail or sea traffic during construction or operation?
No --
1.18 New road, rail, air waterborne or other airports etc?
No The proposed expansion activity will be carried out within existing site located in well developed Industrial Estate having all infrastructural facilities. Existing transportation system is adequate too.
1.19 Closure or diversion of existing transport routes or infrastructure leading to changes in traffic movements?
No --
1.20 New or diverted transmission lines or pipelines?
No --
1.21
Impoundment, damming, converting, realignment or other changes to the hydrology of watercourses or aquifers?
No --
1.22 Stream crossings? No --
1.23
Abstraction or transfers or the water form ground or surface waters?
Yes 1. No ground water is and shall be used. 2. Raw water requirement is met through GIDC
water supply and will be met through same source after proposed expansion.
1.24
Changes in water bodies or the land surface affecting drainage or run-off?
No --
1.25
Transport of personnel or materials for construction, operation or decommissioning?
Yes Transportation of personnel or raw materials/finished products is primarily by road only & it will be done through the same way after proposed expansion.
1.26 Long-term dismantling or No --
decommissioning or restoration works?
1.27 Ongoing activity during decommissioning which could have an impact on the environment?
No --
1.28
Influx of people to an area in either temporarily or permanently?
No --
1.29 Introduction of alien species? No --
1.30 Loss of native species of genetic diversity? No --
1.31 Any other actions? No --
2. Use of Natural resources for construction or operation of the Project (such as land, water, materials
or energy, especially any resources which are non-renewable or in short supply):
Sr. No
Information/checklist confirmation Yes/ No?
Details there of (with approximate quantities/rates, wherever possible) with source of information data
2.1 Land especially undeveloped or agriculture land (ha)
No --
2.2 Water (expected source & competing users) unit: KLD
Yes 3. Raw water requirement is met through GIDC water supply and will be met through the same source after proposed expansion.
4. Water consumption & Waste water generation details – Reference: Anneure-4.
2.3 Minerals (MT) No --
2.4
Construction material - stone, aggregates, sand / soil (expected source MT)
No --
2.5 Forests and timber (source - MT) No --
2.6
Energy including electricity and fuels source, competing users Unit: fuel (MT), energy (MW)
Yes Reference: Anneure-7.
2.7 Any other natural resources (use appropriates standard units)
No --
3. Use, storage, transport, handling or production of substances or materials, which could be
harmful to human health or the environment or raise concerns about actual or perceived risks to
human health.
Sr. No.
Information / Checklist confirmation Yes/ No?
Details thereof (with approximate quantities / rates wherever possible) with source of information data
3.1 Use of substances or materials, which are hazardous (as per MSIHC rules) to human health or the environment (flora, fauna, and water supplies)
Yes
Reference: Annexure -8.
3.2 Changes in occurrence of disease or affect disease vectors (e.g. insect or water borne diseases)
No --
3.3 Affect the welfare of people e.g. by changing living conditions?
No --
3.4
Vulnerable groups of people who could be affected by the project e.g. hospital patients, children, the elderly etc.,
No
--
3.5 Any other causes No --
4. Production of solid wastes during construction or operation or decommissioning MT/month)
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate quantities
/ rates, wherever possible) with source of
information data
4.1 Spoil, overburden or mine wastes No --
4.2
Municipal waste (domestic and or
commercial wastes) No --
4.3
Hazardous wastes (as per Hazardous Waste
Management Rules)
Yes Reference: Anneure-6.
4.4 Other industrial process wastes Yes Reference: Anneure-6.
4.5 Surplus product No --
4.6
Sewage sludge or other sludge from effluent
treatment
Yes Reference: Anneure-6.
4.7 Construction or demolition wastes No --
4.8 Redundant machinery or equipment No --
4.9 Contaminated soils or other materials No --
4.10 Agricultural wastes No --
4.11 Other solid wastes Yes Reference: Anneure-6.
5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate
quantities/rates, wherever possible) with
source of information data
5.1 Emissions from combustion of fossil fuels
From stationary or mobile sources
Yes Reference: Annexure -9.
5.2 Emissions from production processes Yes Reference: Annexure -9.
5.3 Emissions from materials handling including
storage or transport.
Yes 1. Raw materials receive in
drums/carboys/bags/tankers and handled in
closed charging system with proper
ventilation and charged through close
pipeline in to reactors/treatment units. It will
be done through same way after proposed
expansion.
2. Thus there won't be any kind of emission
through storage and transport.
5.4 Emissions from construction activities
including plant and equipment
No --
5.5
Dust or odours from handling of materials
including construction materials, sewage
and waste
No --
5.6 Emissions from incineration of waste No --
5.7 Emissions from burning of waste in open air
(e.g. slash materials, construction debris)
No --
5.8 Emissions from any other sources No --
6. Generation of Noise and Vibration, and Emissions of Light and Heat:
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details there of (with approximate Quantities
/rates, wherever possible) With source of
source of information data
6.1
From operation of equipment e.g. engines,
ventilation plant, crushers
Yes 1. There are few activities due to which
noise generates. The equipments resulting in
noise generation are machineries of plant and
diesel generator. Adequate noise controls
measures are provided.
2. Proper and timely oiling, lubrication and
preventive maintenance is carried out for the
machineries & equipments to reduce noise
generation.
3. Use of PPEs like ear plugs and ear muffs
are made compulsory near the high noise
generating machines.
4. Noise monitoring is done regularly in
plant area.
5. D.G. Set is installed in a closed room and
provided with acoustic enclosure.
6. Above system will be followed after
proposed expansion to prevent/reduce noise to
be generated.
7. The unit has developed plantation within
the premises which helps to prevent the noise
pollution within site as well as surrounding
area.
6.2 From industrial or similar processes Yes 8. All machinery/equipment is well
maintained, have proper foundation with anti
vibrating pads wherever applicable and thus,
noise levels is within permissible limits.
9. An acoustic enclosure is provided for D.G.
set.
10. Above system will be followed after
proposed expansion to prevent/reduce noise to
be generated.
6.3 From construction or demolition No --
6.4 From blasting or piling No --
6.5 From construction or operational traffic No --
6.6 From lighting or cooling systems No --
6.7 From any other sources No --
7. Risks of contamination of land or water from releases of pollutants into the ground or into
sewers, surface waters, groundwater, coastal waters or the sea:
Sr.
No
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate quantities /
rates, wherever possible) with source of
information data
7.1
From handling, storage, use or spillage of
hazardous materials
Yes 11. All hazardous materials are stored safely &
separately in designated storage area.
12. Dyke walls are provided around
raw/hazardous materials storage tanks.
13. Materials stored in bags / drums keep on
pallets with concrete flooring and company
takes preventive action for no spillage likely to
occur.
14. Above system will be followed after
proposed expansion.
15. Reference: Annexure -8.
7.2
From discharge of sewage or other
effluents to water or the land (expected
mode and place of discharge)
Yes Sewage is disposed of through septic tank/soak
pit & to be done through same way after
proposed expansion.
7.3
By deposition of pollutants emitted to air
into the land or into water
No --
7.4 From any other sources No --
7.5 Is there a risk of long term build up of
pollution in the environment from these
sources?
Yes
16. Environmental Management System
(EMS) is installed i.e. ETP, Air Pollution Control
systems, Hazardous Waste Handling and
Management system as per rules, etc. which
eliminates the possibility of building up of
pollution.
17. In proposed expansion activity, additional
EMS will be implemented, if required.
8. Risks of accident during construction or operation of the Project, which could affect human
health or the environment:
Sr.
No
Information/Checklist confirmation
Yes/
No?
Details thereof (with approximate quantities /
rates, wherever possible) with source of
information data
8.1 From explosions, spillages, fires etc. from
storage, handling, use or production of
hazardous substances
Yes Reference: Annexure -8.
8.2 From any other causes No --
8.3 Could the project be affected by natural
disasters causing environmental damage
(e.g. floods, earthquakes, landslides,
cloudburst etc)?
No --
9. Factors which should be considered (such as consequential development) which could lead to
environmental effects or the potential for cumulative impacts with other existing or planned activities
in the locality
Sr.
No.
Information/Checklist confirmation Yes/
No?
Details thereof (with approximate quantities /
rates, wherever possible) with source of
information data
9.1 Lead to development of supporting. laities,
ancillary development or development
stimulated by the project which could have
impact on the environment e.g.:
* Supporting infrastructure (roads, power
supply, waste or waste water treatment,
etc.)
1. housing development
2. extractive industries
3. supply industries
4. other
Yes 1. Plot is located within GIDC, Panoli, Taluka:
Ankleshwar, having entire required
infrastructural facility i.e. road infrastructure,
water supply, power supply, etc.
2. Local people are employed and no housing is
required.
3. Reference: Annexure – 10.
9.2
Lead to after-use of the site, which could
have an impact on the environment
No --
9.3 Set a precedent for later developments No --
9.4 Have cumulative effects due to proximity
to Other existing or planned projects with
similar effects
No --
(III) Environmental Sensitivity
Sr.
No
Information/Checklist confirmation Name /
Identity
Aerial distance (within 25 km). Proposed
Project Location Boundary.
1 Areas protected under international
conventions national or local legislation for
their ecological, landscape, cultural or other
related value
No Plot is located in GIDC, Panoli, Taluka:
Ankleshwar, Dist. Bharuch, Gujarat.
2 Areas which are important or sensitive for
Ecological reasons - Wetlands,
watercourses or other water bodies, coastal
zone, biospheres, mountains, forests
No Plot is located in GIDC, Panoli, Taluka:
Ankleshwar, Dist. Bharuch, Gujarat.
3 Areas used by protected, important or
sensitive species of flora or fauna for
breeding, nesting, foraging, resting, over
wintering, migration
No Plot is located in GIDC, Panoli, Takula:
Ankleshwar, Dist. Bharuch, Gujarat.
4 Inland, coastal, marine or underground
waters
Yes 1. Sea Coast : 20 Km (approx.)
2. River Narmada : 14.6 Km (approx.)
3. Amla Khadi : 5.5 Km (approx.)
5 State, National boundaries No --
6 Routes or facilities used by the public for to
recreation or other tourist, pilgrim areas.
No --
7 Defense installations No --
8 Densely populated or built-up area Yes Ankleshwar city: 2 Lakh population
(approx.)
9 Areas occupied by sensitive man-made land
community facilities)
No
10 Areas containing important, high quality or
scarce resources (ground water resources,
surface resources, forestry, agriculture,
fisheries, tourism, tourism, minerals)
Yes
4. No ground water will be used.
5. Plot is located in industrial area & does not
affect agricultural land.
11 Areas already subjected to pollution or
environmental damage. (those where
existing legal environmental standards are
exceeded)
Yes Plot is located in GIDC, Panoli, Taluka:
Ankleshwar, Dist. Bharuch, Gujarat.
12 Are as susceptible to natural hazard which
could cause the project to present
environmental problems (earthquakes,
subsidence ,landslides, flooding erosion, or
extreme or adverse climatic conditions)
No --
28/07/2018
IV). Proposed Terms of Reference for EIA studies: Please refer Annexure – 11.
ANNEXURES
ANNEXURE NO. PARTICULARS
1 List of Products with their Production Capacity and Raw Materials Consumption
2 Plot layout
3 Brief Manufacturing Process Description
4 Details of water consumption & waste water generation
5 Description of Effluent Treatment Plant
6 Details of Hazardous/Solid Wastes Generation, Management and Disposal Mode
7 Power and Fuel Requirement
8 Hazardous Chemicals Storage and Handling Details
9 Details of Sources of Emissions and Air Pollution Control Equipments (APCM)
10 Socio - Economic Impacts
11 Proposed Terms of References
12 Copy of Land Possession/Plot Allotment Letter
13 Copy of CETP and Spray Dryer Membership Letter
14 Copy of Common TSDF & HWIF Membership Letter
15 Toposheet
16 Copy of GIDC Letter for Water Supply
ANNEXURE – 1
LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY
Sr.
No.
Products CAS No. Production Capacity
(MT/Month)
LD50
(mg/Kg)
Existing Proposed
Expansion
Total after
Proposed
Expansion
Pesticide Technical
1 Dichlorovos Technical (DDVP) 62-73-7 20
180
200
1100
2 Hexaconzole (T) 79983-71-4
--
2000
3 Tebuconzole (T) 107534-96-3 5000
4 Propioconzole (T) 60207-90-1 4000
5 1,2,4-Triazole 288-88-0 2300
6 Profenofos (T) 41198-08-7 2560
Specialty Chemicals
7 Chloral
(Trichloro Acetaldehyde)
75-87-6 213 400 400 168
8 Meta Chloro Propio Phenone (3-
CPP)
936-59-4 10 15 15 482
9
3-(Bromo ethyl)-2-chloro-4-
(methyl sulfonyl) Benzoic Acid
(PIA-4)
53250-83-2 25 Nil 25 1600
10
S-Benzyl O, O Diisopropyl
Phosphorothioate (PIZ)
26087-47-8 10 Nil 10 790
11 Dimethyl Amine Hydrochloride
(DMA - HCl)
506-59-2
10
25
25
1600
12
Iso Propyl Alcohol Hydrochloride
(IPA HCL)
7647-01-0 IPA - 12870
&
HCL - 5010
13 Methanolic Hydrochloride 9004-54-0 15800
14 Ethyl Acetate Hydrochloride 5407-04-5 - 5000
15 Ethyl Alcohol Hydrochloride 9004-54-0 - 5000
16 Propionyl chloride 79-03-8 - 24 24 823
17 Propiophenone 93-55-0 - 30 30 4500
LIST OF BY-PRODUCTS WITH THEIR PRODUCTION CAPACITY
Sr.
No.
By-Products CAS No. Production Capacity
(MT/Month)
Existing Total after Proposed
Expansion
1 Regenerated Sulfuric Acid (72%) 7664-93-9 373.75 653
2 Dilute Hydrochloric Acid (30-32%) 7647-01-0 656* 1200*
Dilute Hydrochloric Acid (20%) 0.723** 1.257**
3 Ethyl Chloride 75-00-3 95.83 180
4 Methyl Chloride 74-87-3 2.29 4.58
5 HBr 10035-10-6 6.45 42
6
Poly Aluminium Chloride (PAC) –
100%
1327-41-9 7.5 46
7 Sodium Hypochlorite (10%) 7681-52-9 90 120
* Existing: (656 - 11.5 = 644.5 MT). 11.5 MT converts to HCl gas & Consumes as raw material in
existing products i.e. DMA – Hydrochloride, IPA HCL and Methaonolic Hydrochloride.
* Total after Proposed Expansion: (1200 – 25 = 1175 MT). 25 MT will be converted to HCl gas &
Consumed as raw material in existing products i.e. 3-CPP, DMA – Hydrochloride, IPA HCL and
Methaonolic Hydrochloride and Propiophenone.
** HCl (20%) converts and to be converted to HCl (30-32%) and sell to actual user.
Note: No increase by-product due to adding new products.
18 2-Bromo 3-Chloro
Propiophenone
34911-51-8 - 4 4 2000
19 3-Methoxy Propiophenone 37951-49-8 - 4 4 1950
20 3-Hydroxy Propiophenone 13103-80-5 - 4 4 1310
21 Cyano Acetic Acid 372-09-8 - 10 10 1500
22 7-Ethyl Tryptophol (7-ETP) 41340-36-7 - 5 5 391
23 Closantel Amine 57808-65-8 - 5 5 5780
24 Diethyl Ketone 96-22-0 -- 10 10 2900
25 TBPO (Tributyl phosphate) 126-73-8 -- 60 60 2000
Total 286 826 1112
RAW MATERIAL CONSUMPTION:
Raw Material Consumption Quantity (MT/MT) CAS No.
Dichlorovos Technical (DDVP)
Chloral 0.668 75-87-6
Tri Methyl Phosphate 0.561 512-56-1
Hexaconzole (T)
Dimethyl sulfate 0.482 77-78-1
Sodium sulfide 0.026 1313-82-2
DCVP[2,4-dichloro valerophenone ] 0.760 61023-66-3
Pot. Hydroxide 0.310 1310-58-3
1,2,4-Triazole 0.245 288-88-0
Pot. carbonate 0.045 584-08-7
DMF 1.210 68-12-2
Tebuconazole
1-(4 – Chlorophenyl) 4-4- Dimethyl -
3- Pentanoate 675
66346-01-8
Sodium Methoxide 162 124-41-4
Di Methyl Sulfide 186 75-18-3
Solvent - Toluene 1400 108-88-3
1,2,4 - Triazole 206 288-88-0
Solvent - DMF 1100 68-12-2
Propiconzole (T)
DMSO 1.800 108-88-3
Pot. Hydroxide 0.237 1310-58-3
1,2,4-Triazole 0.265 288-88-0
Bromoketal 1.210 1670-47-9
1,2,4 H Trizole
Hydrazine Hydrate 0.473 7803-57-8
Formic Acid 1.360 64-18-6
Ammonia Gas 0.253 7664-41-7
Xylene 0.080 1330-20-7
Profenofos (T)
o-Chloro phenol 0.398 95-57-8
Liquid bromine 0.485 7726-95-6
DETCl 0.566 2524-04-1
TMA 0.709 75-24-1
Propyl bromide 0.363 106-94-5
Sodium hydroxide 0.215 1310-73-2
Chloral
Ethyl Alcohol 0.624 64-17-5
Chlorine 1.925 7782-50-5
Sulfuric Acid (98%) 1.223 7664-93-9
Meta Chloro Propio Phenone (3-cpp)
Benzoic Acid 1.078 71-43-2
Aluminium Chloride 1.05 7446-70-0
Propionyl Chloride 0.816 79-03-8
Ethylene Dichloride 0.5 107-06-2
Chlorine Gas 0.421 7782-50-5
HCl 0.025 7647-01-0
Hexane 0.1 110-54-3
3-(Bromo ethyl)-2-chloro-4-(methyl sulfonyl) Benzoic Acid (PIA-4)
2-Chloro-6-(methyl thio) Toluene
(PIO)
0.535 82961-52-2
Ethylene Dichloride 2.25 107-06-2
Aluminium Chloride 0.3 7446-70-0
Acetyl Chloride 0.25 75-36-5
Methanol 1.5 67-56-1
Hydrogen Peroxide 0.315 7722-84-1
IPA (Special grade) 0.054 67-63-0
HCl 0.05 7647-01-0
Bromine 0.49 7726-95-6
Ortho Dichloro Benzene 1.0 95-50-1
S-Benzyl O, O Diisopropyl Phosphorothioate (PIZ)
Sodium diiospropyl phosphorothlate 0.64 12125-02-9
Benzyl Chloride 0.35 100-44-7
Toluene 0.33 108-88-3
Dimethyl Amine Hydrochloride
Dimethyl Amine (40%) 1.11 124-40-3
Dry HCl gas 0.56 7647-01-0
Iso Propyl Alcohol Hydrochloride
Iso Propyl Alcohol 0.75 67-63-0
Dry HCl gas 0.25 7647-01-0
Methaonolic Hydrochloride
Methanol 0.75 67-56-1
Dry HCl gas 0.25 7647-01-0
Ethyl Acetate Hydrochloride
Ethyl Acetate 0.671 141-78-6
Hydrochloric Acid 0.329 7647-01-0
Ethyl Alcohol Hydrochloride
Ethyl Alcohol 0.411 64-17-5
Dry HCL gas 0.59 7647-01-0
Propionyl chloride
Propionic Acid 0.8 79-09-4
Thionyl Chloride 1.46 779-09-4
Propiophenone
Propionyl Chloride 0.76 79-03-8
Benzoic Acid / Benzene 0.91 / 0.734 65-85-0 / 71-43-2
AlCl3 1.18 7446-70-0
2-Bromo 3-Chloro Propiophenone
Bromin Soln. 1.05 7726-95-6
3-Chloropropiophenone 0.64 936-59-4
Sodium Thiosulphate 3.19 7772-98-7
Methylene chloride 2.78 75-09-2
3-Methxy Propiophenone
3- Chloropropiophenone 1.02 936-59-4
Methanol 0.2 67-56-1
3-Hydroxy Propiophenone
3- Chloropropiophenone 1.12 936-59-4
Sodium Hydroxide 0.27 1310-73-2
Cyano Acetic Acid
Mono Chloro Acetic Acid 1.11 79-11-8
NaCN 0.576 143-33-9
H2SO4 1.153 7664-93-9
Carbon 0.141 7440-44-0
Methyl isobutyl Ketone 1.178 108-10-1
7-Ethyl Tryptophol (7-ETP)
2-Ethyl phenyl hydrazine HCl 1.0 67843-74-7
2,3-dihydro furan 0.44 1191-99-7
Methanol 0.2 67-56-1
Toluene 7.0 108-88-3
Na2CO3 0.04 497-19-8
Closantel Amine
4-Chloro Benzyl Cyanide 0.52 104-83-6
4-Chloro 2 Nitro Toluene 0.59 89-59-8
Methanol 0.11 67-56-1
KOH 0.193 1310-58-3
Sodium Hydrosulfide 0.193 16721-80-5
Toluene 0.316 108-88-3
Activated Carbon 0.041 7440-44-0
Fanvalrate 20% EC
Fanvalrate Tech. 0.225 51638-58-1
Xylene 0.61 1330-20-7
Emulsifier 0.165 97593-29-8
Chloropyriphos 20% EC
Chloropyriphos (T) 0.215 2921-88-2
Aromax C-9 0.725 64742-95-6
Emulsifier 0.06 97593-29-8
Chloropyriphos 48% EC
Chloropyriphos (T) 0.511 2921-88-2
Aromax C-9 0.409 64742-95-6
Emulsifier 0.08 97593-29-8
Cypermetherin 25% EC
Cypermetherin (T) 0.27 52315-07-8
Xylene 0.253 1330-20-7
Emulsifier 0.478 97593-29-8
Monocrotophos 36% EC
Monocrotophos (T) 0.27 6923-22-4
Cyclohexanone 0.2525 108-94-1
Cypermetherin 10% EC
Cypermetherin 0.093 52315-07-8
Aromax C-9 0.384 64742-95-6
Emulsifier 0.524 97593-29-8
Dichlorovos Technical (DDVP) 76% EC
Dichlorvos 0.83 62-73-7
Xylene or Aromax C-9 0.099 1330-20-7 or
64742-95-6
Emulsifier 0.071 97593-29-8
2,4,D Ethyl Ester 38% EC
2,4,D Ethyl Ester 0.4 533-23-3
Sulphonate & polyoxy ethelene ether 0.55 67/548/EEC-
Emulsifier 0.05 97593-29-8
Imida Chlopride 17.8% SL
Imidachlorprid (T) 0.178 138261-41-3
Dimethyl sulpfoxide 0.752 67-68-5
Emulsifier 0.07 97593-29-8
Methyl Parathion 50 % EC
Methyl Parathion (T) 0.625 299-00-0
Xylene 0.205 1330-20-7
Emulsifier 0.17 97593-29-8
Mancozeb 75 % WP
Mancozeb (T) 0.882 8018-01-7
Suspensioning Agent (Gum) 0.06 --
China Clay 0.0577 1332-58-7
Acephate 75 % SP
Acephate 0.75 30560-19-1
Aerosol OTB 0.005 577-11-7
Fine Silica 0.245 112945-52-5
Diethyl Ketone
Benzoic acid 0.91 65-85-0
Propionic Acid 1.65 79-09-4
Alumina 0.03 1344-28-1
Calcium Acetate 0.75 62-54-4
TBPO
NBA 0.698 71-36-3
POCL3 2.685 10025-87-3
Caustic Lye 1.185 1310-73-2
ANNEXURE-2
PLOT LAYOUT
ANNEXURE-3
BRIEF MANUFACTURING PROCESS DESCRIPTION
1. Dichlorovos Technical (DDVP):
Process Description:
Charge chloral required quantity and addition of Trimethyl phosphate slowly at 50 0C. After addition of
TMP charge epichlorohydrine and maintain the reaction mass under vaccum for about 3 hrs. until
impurities are within specification. Then pack the material.
Chemical Reaction:
Mass Balance:
2) Hexaconzole (T)
Preparation of Trimethylsulfonium sulfate
Dimethyl sulfate is charged in dimethyl sulfide at 33 °C to form Trimethylsulfonium sulfate. 2, 4
Dichlorovalerophenone is reacted with Trimethylsulfonium sulfate in presence of potassium hydroxide
to form Oxirane. Solvent dimethyl sulfide is recovered by distillation and product (Oxirane) is separated
from potassium hydrogen sulfate. Water is added to dissolve salt and back extracted with methylene
dichloride and then, aqueous layer is transferred to ETP.1,2,4 1H-triazole and potassium hydroxide is
charged in DMF and previously prepared Oxirane is added at elevated temperature to form
Hexaconazole. After completion of reaction, organic phase is separated by filtration. Carbonate sludge is
washed with DMF and collected with organic filtrate. Sludge is transferred to solid waste DMF is distilled
out from reaction mass first at atmospheric distillation and then by vacuum distillation. Hexaconazole is
isolated from molten mass with help of water. Slurry is filtered, centrifuged and dried.
Chemical Reaction
Mass Balance
MATERIAL BALANCE-Hexaconazole Batch size (Final output): 1000 Kg
S.No Name of material Input Qty.
(Kg)
Product
Out put
Qty. (Kg)
Recovery Losses Total
Liquid Others
1 Dimethyl sulfate 482
1000
DMF loss
11488
2 Sodium sulfide 26 DMF Waste water 12
3 DCVP 760 1198.0 9278
4 Pot. Hydroxide 310
5 1,2,4-Triazole 245
6 Pot. carbonate 45
7 DMF 1210
8 Water 8410
1000.0 1198.0 9278.0 12.0
Total 11488 11488
3) Tebuconazole
Manufacturing Process:
Process Description:
Step -1
1-(4-Chlorophenyl)-4,4-Dimethyl-3-Pentanone reacted with Sodium Methoxide & Dimethyl
Sulfide in presence of Toluene to get 2- [ 2-( 4- Chlorophenyl)ethyl ]-2-(1,1 – Di methyl ethyl )
Oxirane.
Step -2
2- [ 2-( 4- Chlorophenyl)ethyl ]-2-(1,1 – Di methyl ethyl ) Oxirane. is reacted with 1,2,4-Triazole in
presence of DMF to give final product TEBUCONAZOLE
Chemical Reaction
Cl
1-(4-Chlorophenyl)-4,4-Dimethyl-3-
Pentanone224.5
+
Sodium Methoxide
54
+NaOH
40.0
STEP:1
Toluene
Intermediate-I
238.5
+
STEP:2
DMF
CH2 CH2 C CH3C
O CH3
CH3CH3ONa + CH3SCH3
Dimethyl Sulfide
62
Cl
CH2 CH2 C CH3C
OCH3
CH3
CH2
238.5
Cl
CH2 CH2 C CH3C
OCH3
CH3
CH2
1,2,4-Triazole
69
CH
N
N
CH
NH
Cl
CH2 CH2 C CH3C
OH CH3
CH3CH2
CH
N
N
CH
N
TEBUCONAZOLE
307.5
Material Balance / Mass Balance (All Quantities are in Kg)
IN- PUT OUT- PUT
Sr No Raw Materials / Items Kg/Batch Product / Bi Product Qty/Batch
1 1-(4 – Chlorophenyl) 4-4-
Dimethyl -3- Pentanoate 675 Tebuconazole 1000
2 Sodium Methoxide 162 Recovered Solvent - Toluene 1360
3 Di Methyl Sulfide 186 Solvent Loss - Toluene 40
4 Solvent - Toluene 1400 Methanol 95
5 1,2,4 - Triazole 206 20 % Sodium Methyl Sulfide 1048
6 Solvent - DMF 1100 Recovered Solvent - DMF 1070
7 Water 1690 Solvent loss - DMF 30
Aqueous Layer to ETP 768
Distillation Residue 14
Total 5419 5419
4) Propiconzole (T)
Manufacturing Process:
1, 2, 4-1H-Triazole and potassium hydroxide is charged in DMSO to form potassium salt of 1,2 4- 1H-
triazole. 2-Bromo-methyl-2-[(2, 4 dichlorophenyl)-4-propyl]-1, 3-dioxolan (Bromoketal) is gradually
added to DMSO containing potassium salt of Triazole. Temperature is raised and maintained for few
hours to complete the reaction. After completion of reaction solvent is removed by distillation. Residue
is washed with water and then crude Propiconazole is distilled to get technical grade Propiconazole.
Residue is transferred to ETP.
Chemical Reaction
Mass Balance
MATERIAL BALANCE-Propiconazole Batch size (Final output): 1000 Kg
S.No Name of material Input Qty.
(Kg)
Product
Output
Qty. (Kg)
Recovery Losses Total
Liquid Others
1 DMSO 1800
DMSO loss
2 Pot. Hydroxide 237 Bromoketal Waste water 20
3 1,2,4-Triazole 265 1000 1210 1480 Residue
5512 4 Bromoketal 1210 DMSO 22
5 Water 2000 1780
1000.0 2990.0 1480.0 42.0
Total 5512 5512
5). 1,2,4 H TRIZOLE
Manufacturing Process:
Charge Xylene and Hydrazine hydrate into the reactor. Start addition of Formic acid slowly below 60o
than purge Ammonia Gas slowly in 2 hrs than heat to reflux at 142- 145o b) Reaction Chemistry: C for 8
hrs, and continuously distilled out azeotrope of water and Xylene in receiver. Separate out water from
bottom and upper layer xylene is continuously transferred in to reactor for 8 hrs. Cool the reaction mass
at RT and filter it. Dry the wet cake in Dryer. Unload the product as 1, 2, 4 - Triazole.
Chemical Reaction:
Mass Balance:
6) Profenofos
Manufacturing Process:
Reaction of o-Chlorophenol with bromine gives Bromo Chlorophenol (BCP). Bromo Chlorophenol (BCP)
with diethyl thiophosphoryl chloride (DETCl) in presence of sodium hydroxide (NaOH) to yield
intermediate A. Intermediate A and Trimethylamine, to give Q‐Salt. Finally reaction of Q‐salt with
n‐propyl bromide gives Profenofos technical.
Chemical Reaction
Mass Balance
MATERIAL BALANCE-Profenofos Batch size (Final output): 1000 Kg
S.No Name of material Input Qty.
(Kg)
Product
Output
Qty.(Kg)
Recovery Losses Total
Liquid Others
1 o-Chloro phenol 398
1000
Hydro Bromic
acid
7397
2 Liquid bromine 485 206
3 DETCl 566 TMA Organic
Impurity
4 TMA 709 212.2 448.9
5 Propyl bromide 363 Aqueous waste Sodium
bromide
6 Water 4661 5268 261.9
7 Sodium hydroxide 215
1000 5686.2 710.8
Total 7397 7397
7) Chloral:
Process Description:
Ethyl alcohol charge in to glass line reactor and chlorine is pass under control temp. condition. HCl gas is
being produced as a by-product which further react with ethyl alcohol and ethyl chloride is being
produced. HCl gas is being scrub into series of scrubber and ten in to caustic scrubber to get ethyl
chloride. Ethyl Chloride then condenses in minus temp and cylinders are being filled to sale as by-
product HCl 30% is also being recovered and sale as a by-product. Chlorinated mass alcoholate is treated
with sulfuric acid 98% for getting pure chloral. Sulfuric Acid is being regenerated as 75% acid and sale as
by-product.
Chemical Reaction:
Mass Balance:
Meta Chloro Propio Phenone (3-cpp):
Process Description:
Stage-1:
Friedel Craft Reaction – Charge Benzoic Acid / Benzene and catalyst in GLR and cool at 10-12 0C. Add
propionyl chloride slowly keep temperature at <12 0C.
Distillation – Apply vaccum and distill propiophenone.
Stage-2:
Chlorination – Charge required quantity of solvent (EDC) cool to 10 0C then charged reactant
propiophenone and again chilled to 4 0C then start slow addition of catalyst AlCl3 with controlling
temperature after completion of catalyst charging purged chlorine with control rate and temperature
then quench the reaction in dilute HCl maintaining temperature belo 20 0C.
Solvent recovery & Fraction Distillation – Washed neutral organic layer to be taken for atmosphere
solvent recovery after completion of solvent recovery start & complete high vaccum, high temperature
fraction distillation to get dilute MCPP.
Centrifugation – Dilute MCPP is centrifuge to get wet cake of crude MCPP and after drying get pure
product.
Chemical Reaction:
Mass Balance:
Stage-1
Benzoic Acid /
3-(Bromo ethyl)-2-chloro-4-(methyl sulfonyl) Benzoic Acid (PIA-4)
Process Description:
Charge (EDC) in GLR. Check sample for m/c. Charge catalyst cool the mass with CHW up to 10-15 0C and
start addition of Acetyl Chloride. Maintain temp. under stirring and start feeding of PIA. Stir the mass for
3.0 hrs. at same temp. Send sample for QC. After confirming result quench the mass in other GLR.
Receive concentrate organic mass from SSR. Charge (catalyst) soln. Apply heating. Do the addition of
H2SO4 by maintaining temp. at 65-65 0C. Give sample after getting result start cooling transfer mass to
GLR. Flush reactor to GLR.
Receive organic mass from GLR in crystallizer. Cool the mass and maintain temp. to 32-35 0C. Start
addition of HCl. Do the sample for pH it should be < 1.0. Do the centrifuging lot. Collect aqueous in tank
for recovery. Give the wash of DM Water. Unload wet cake. Do the drying in RVD after drying fill up the
drums in 50 Kg.
Chemical Reaction:
Mass Balance:
S-Benzyl O, O Diisopropyl Phosphorothioate (PIZ):
Process Description:
Charge PIZ-001 (Ammonium Salt) in GLR maintain temp. 25 to 30 oC by chilling water to adjust pH by PIZ-
002 (HCl) to 6.5 to 6.8 – maintain for 1.3 hr.-charge PIZ-003 & 004 (Toluene and Benzyl Chloride) – heat
the mass upto 80-85 oC – maintain it for 2.3 to 3 hr – send sample for GC – settle the mass for 1.0 hr at
75 to 8 oC – separate the bottom aqueous – retain organic mass in GLR – Charge DM water under
agitation – settle mass for 1 hr – separate bottom organic mass in GLR – start vacuum and heating to
recovered PIZ-003 (Toluene) by maintain temp and vacuum – send sample to QC – fill up the drums for
final packing.
Chemical Reaction:
Mass Balance:
Dimethyl Amine Hydrochloride:
Process Description:
Take 40 % solution of DMA in GLR and start Dry HCL gas Purging at Room temperature and adjust
pH 5.5 keep 1 hour stirring then distilled Out water from Reaction mixture after water distillation
residual Reaction Mass to be Crystallized . Centrifuge and Dry the material till moisture level Comes
below 0.10 %. Final product will be packed in LDPE Bags having PVC auto sealed Liner inside.
Chemical Reaction:
(CH3)2.N + HCl(g) (CH3)2.NHCl
Mass Balance:
40 % DMA solution 500 kg Dry HCL gas 250 kg
Wet cake 475 kg
GLR
Crystaliser SSTD
Tray
Dryer
This water will be feed
to scrubber system
275 kg water
for HCl
Drying Loss 25 kg
Dry weight 450 kg DMA.HCl
Iso Propyl Alcohol Hydrochloride (IPA HCL):
Process Description:
Dry HCL gas is injected to IPA to get IPA HCl and monitoring the Assay by Keeping Law temperature of
Reaction mass. After achieving Desired Results material is packed in HDPE Drums and sealed with Plaster
of Paris.
Chemical Reaction:
(CH3)2.CHOH + HCl(g) CH3.CH2.CH2.OH .HCl
Mass Balance:
IPA Dry HCL gas of chloral
1200 kg plant 400 kg
Assay 18 % to 25 %
As per Demand
GLR
25% IPA.HCl
1600 kg
Methanolic Hydrochloride:
Process Description:
Dry HCL gas is injected to Methanol to get Methaonolic HCL and monitoring the Assay by Keeping Law
temperature of Reaction mass. After achieving Desired Results material is packed in HDPE Drums and
sealed with Plaster of Paris.
Chemical Reaction:
CH3OH + HCl(g) CH3OH .HCl
Mass Balance:
Methanol Dry HCL gas of chloral
1200 kg plant 400 kg
Assay 18 % to 25 %
As per Demand
GLR
25% MeOH.HCl
1600 kg
Ethyl Acetate Hydrochloride:
Process Description:
Dry HCL gas Is injected to Ethylacetate to get Ethylacetate Hydrochloride and monitoring the Assay by
Keeping low temperature of Reaction mass. After Achieving of desire results Material is packed in HDPE
Drums and sealed with Plaster of paris.
Chemical Reaction:
+ HCl (g) C4H8O2 .HCL
C4H8O2 Hydrogen chloride gas Ethylacetate Hydrochloride
Ethylacetate
Mass Balance:
Ethyl Acetate (671 kg)
Hydrochloric acid (329 kg)
REACTION
Ethylacetate Hydrochloride
(1000 kg)
Ethyl Alcohol Hydrochloride:
Process Description:
Dry HCL gas Is injected to Ethyl alcohol to get Ethyl alcohol Hydrochloride and monitoring the Assay by
Keeping low temperature of Reaction mass. After Achieving of desire results Material is packed in HDPE
Drums and sealed with Plaster of Paris.
Chemical Reaction:
C2H5OH + HCl (g) C2H5OH.HCl
Ethyl Alcohol Hydrogen chloride gas Ethyl Alcohol Hydrochloride
M.W. = 46 M.W. = 36.5 M.W = 82.5
Mass Balance:
Ethyl Alcohol (460 kg)
Hydrochloric acid (658 kg)
Ethyl Alcohol Hydrochloride
(1118 kg )
REACTION
Propionyl chloride:
Process Description:
Propionic acid reacted with thionyl chloride produce propionyl chloride and sulfuric acid.
Chemical Reaction:
O
OHCH3 +2
SO2Cl2
O
ClCH32 + H2SO4
Propionic AcidM.W. 74
Thionyl ChlorideM.W. 135
Propionyl Chloride M.W. 92.5
Sulfuric AcidM.W. 98
Mass Balance:
Propionic Acid (296 Kg) H2SO4 (392 Kg)
Thionyl Chloride (540 Kg)
Propionyl Chloride (370 Kg)
REACTION
Propionyl Chloride (900 Kg)
Addition of PC Hcl gas (322kg)
Benzoic acid / Benzene
(1078 kg / 875 kg)
Catalyst / Alcl3
(50 kg / 1400 kg) 30 to32% Hcl Soln Bi product(Qty 976 kg)
Chilled water (250kg) Co2 gas (388 kg)
Catalyst for Re use
Water (250 kg) - Reuse
Propiophenone (1184 kg)
GLR – 301
(3KL)
GLR – 211 (4 KL)
GLR-03 (10 KL)
Quenching
SSR-01 (5 KL)
Distillation (1434 kg)
Scrubber
(Water)
654 kg
C/F (for
Catalyst
Recovery &
Re use)
HDPE Tank-1.5 KL
(Product) - 1434 kg
Propiophenone:
Process Description:
Charge Propionyl chloride and Benzoic acid / Benzene in to GLR. In presence of aluminium chloride they
reaction occur. It generates HCl gas which scrubs in water scrubber. Reaction mass is quenched with
chilled water which further goes for catalyst recovery. Thereafter distillation is carried out to distilled
water and remaining is product.
Mass Balance:
2-Bromo 3-Chloro Propiophenone:
Process Description:
Dissolved 3’-Chloropropiophenone in Dichloromethane and stirring the Reaction mass for 10-15 min.at
25-35°C temperature. Then add prior prepared bromine solution to reaction mass within 3-4 hours with
temperature control.then maintain the reaction mass 45 min.with temperature control.
Then wash with process water and separate the bottam organic layer in RBF and discard the aq.layer.
then wash with sodium thiosulphate solution and agains separate the bottam organics layer in RBF and
discard the aq.layer. then wash the reaction mass with process water and separate the bottam organic
layer and discard the aq.layer.
Filter the reaction mass through celite bed and wash with Dichloromethane. Then distilled out
dichloromethane atmospherically completely.
Then apply the vacuum for removal of traces of solvent for 45 min. at 50°C and get the final product 2-
Bromo-3’-chloropropiophenone then packed in HDPE drums
Chemical Reaction:
+ Br2 Br + HBr
Cl Cl
Mass Balance:
Bromin soln. 190 kg Process Water 500 lit.
3-CPP 115 kg MDC 460 lit.
Recovery and recycle
Sodium Thiosulphate Aq.layer 550 lit.
Solution 575 lit.
ETP
Process water 500 lit. Aq.layer 575 lit.
Reactor
Separator
Reactor
Separator
Reactor
Separator
ETP
ETP
Aq.layer 575 lit.
MDC 510 lit.
Distilled MDC
510 lit.
180 kg 2-Bromo-3-chloropropiophenone
Organic layer
O
CH3
Cl
3'- ChloropropiophenoneM.W.168.62
C9H
9ClO
+ CH3OH
Metanol M.W.32.04
- HCl
3-Methoxy Propiophenone:
Process Description:
3- Chloropropiophenone reacts with methanol generates 3- Methoxy propiophenone and HCl.
Chemical Reaction:
Mass Balance:
3- Chloropropiophenone (674.48 Kg)
Methanol (128.16 Kg) HCl (18.04 Kg)
3’- Methoxy propiophenone (656.08 Kg)
REACTION
3-Hydroxy Propiophenone:
Process Description:
3- Chloropropiophenone reacts with NaOH generates 3- Hydroxy propiophenone and NaCl.
Chemical Reaction:
O
CH3
Cl
+ NaOH
O
CH3
OH
+ NaCl
3'- ChloropropiophenoneM.W.168.62
C9H
9ClO
Sodium hydroxideM.W. 40
3'- Hydroxy ChloropropiophenoneM.W.150.12
C9H
9O
2H
Sodium chlorideM.W. 58.5
Mass Balance:
3- Chloropropiophenone (674.48 Kg)
Sodium hydroxide (160 Kg) NaCl (234 Kg)
3’- Hydroxy Chloropropiophenone (600.48 Kg)
REACTION
Cyano Acetic Acid:
Process Description:
Monochloro acetic acid is taken into reactor. Add water to make liquid. Heat mass to 50 oC. Then add
sodium cyanide cake slowly. Keeping temp. below 70 oC. Check absence of sodium cyanide by TLC. Also
check cyanide content is nil through cyanide test. Once reaction is completed, cool the mass. The mass is
washed with sulfuric acid to remove impurities. Take organic layer for extraction using MIBK as solvent
to receive pure CAA in MIBK leaving sodium Chloride in aqueous soln. MIBK containing CAA is distilled to
remove MIBK. Cool and chill mass up to 10 oC. Centrifuge pure crystals. Recycle ML for next batch. Dry
crystals.
Chemical Reaction:
NaCN + + NaCl
O Cl
OH
O CN
OH
H2SO4
MIBK
Mass Balance:
Charging Vessels
Carbon Treatment
Extraction
ETP
1000 Kg
Solvent Recovery
Crystallizer
C/F
ETP
773 Kg
Mono Chloro Acetic Acid 1110 Kg
NaCN 576 Kg
H2SO4 1153 Kg
Carbon 141 Kg
MIBK 1178 Kg
Recycle
1175 Kg
CAA
1000 Kg
Dyer Loss
210 Kg
NHNH2HCl
O+ DMAC
NH
H2O
OH
+ HCl + NH 3
2-Ethyl phenyl hydrazine HCl 2,3-Dihydrofuran 7-Ethyl Tryptophol
7-Ethyl Tryptophol (7-ETP):
Process Description:
To stirred solution of 2-ethyl phenyl hydrazine HCl and DMAc-H2O. Dropwise add 2,3 dihydro furan at
25-30 oC. Heat the mass upto 50 oC and stirred for 30 min. Completion of reaction is monitored by TLC.
Add conc. H2SO4 at 50 oC and maintain reaction mass for 3-4 hrs. After completion of reaction mixure is
allowed to cool to RT. Adjust pH 4-5 by using dilute Na2CO3 soln. and then extract with MDC. Crude
distilled out and cool to get yellow colour product.
Chemical Reaction:
Mass Balance:
D. M. water 500 lit. EPH 250 kg
2,3-dihydro furan Toluene 1750 lit.
110 kg Methanol 50 kg Catalyst 10 kg
Layer separation
Recovery and recycle
Tar layer 2170 lit. Aq. layer 500 lit.
Toluene 600 lit.
Reactor
Reactor
Separator
Extracture
Organic layer Aq. layer 500 lit.
Toluene 2300 lit.
Recycle
Recycle
Inter Cut 140 kg
7-ETP 250 kg
Solvent recovery
Fractional distillation
Lower cut 80
kg.
Cl
N
+
ClN+
O + CH3OH + KOHCH3OH
+ NaHS
Cl Cl
CN
CH3
NH2
+ O2
4-Chloro Benzyl 4-Chloro-2-nitro- Closantel Amine Cyanide toluene
M.W. 151.59 171.58 291.14 32
C8H6ClN C 7H6ClNO2 C15H12N2Cl2
Closantel Amine
Process Description:
4-Chlorobenzyl Cyanide and 4-Chloro Nitro Toluene is added into reactor. Methanol is added and heat
upto 50 oC. Add solution of hydrosulfite powder as catalyst slowly. Keeping temp below 50 oC. Add
potassium hydroxide flakes into reactor and reflux mass for 12 hrs. Check completion of reaction. If
traces of PCBC seen, further reflux till it is absent. Cool product and add DM water into it. Stir the
product and then centrifuge product. Allow to settle layer. Remove organic layer and filter mass. Collect
filtrate in distillation vessel. Remove toluene by distillation. Centrifuge the mass. Collect wet cake and
dry it.
Chemical Reaction:
Mass Balance:
SS Reactor
4-Chloro Benzyl Cyanide 520 Kg
4-Chloro 2 Nitro Toluene 590 Kg
SS Reactor
Methanol 110 Kg
KOH 193 Kg
NaHS 193 Kg
Centrifuge DM Water 62 Kg
SS Reactor
Toluene 316 Kg
Activated Carbon 41 Kg
Filter
SS Crystallizer Toluene 311 Kg Recovered
Dryer
Closantel Amine
1000 Kg
Loss 100 Kg
Aq. Layer 573 Kg
Activated Carbon 41 Kg
Diethyl Ketone:
Manufacturing Process:
Propiophenone and diethyl ketone is produced by the reaction between Propionic acid and benzoic acid.
The reaction involves 1 mole of benzoic acid addition with 3 moles of Propionic acid. The reaction is
followed by addition of benzoic acid using alumina on calcium acetate (1-5%) as catalyst. The reaction
product is Propiophenone and diethyl ketone with some amount of water and carbon di oxide.
Chemical Reaction:
C6H5COOH + 3C2H5COOH (122 + 3*74) 344
Calcium acetate ↓ Al2O3 (Catalyst)
C6H6COC2H5 + C2H5COC2H5 + 2CO2↑ + 2H2O (134 + 86 + 88 + 36) 344
Benzoic acid
+
PA
→
Propiophenone
+
Diethyl Ketone
+
CO2
+
H2O
Mass Balance:
Sr. No. Input Quantity (Kg) Output Quantity (Kg)
1 Benzoic acid 122 Diethyl Ketone 134
2 Propionic acid 222 3-Pentanone 86
3 alumina 5 Water 143
4 calcium acetate 102 Loss 88
Total 451 Total 451
TBPO (Tri Butyl Phosphate):
Manufacturing Process:
STAGE 1:- REACTION OF POCL3 AND n-BUTANOL
1. Check reactor should be clean and dry. Bottom valve should be close. Open the vent of the
reactor and flush system with N2. Reflux line should be closed. Check sufficient quantity of
POCL3 available in Holding Tank.
2. Charge 2685 kg n-BUTANOL via mass flow meter. Note down initial and final reading of mass
flow meter.
3. After receiving n-BUTANOL start stirring and intercirculation in Reactor and submit sample for
moisture analysis.
4. Apply brine into the reactor jacket to achieve mass temp 5.C.
5. Start addition of POCL3 698kg at the dip of mass via MFM. By maintaining temp <20.C under N2.
Maintain the temp.
6. After POCL3 addition cook mass for 6hr. during cooking mass temp. Self-rise up to 25-30.C if
require apply cooling and maintain the temp.
7. After 6hr cooking start intercirculation by pump and submit sample for analysis. DBPO should be
<0.25% if more than further cooks and submits the sample.
8. After achieve result ok apply brine to cool the reaction mass and start transferring to
neutralization reactor By pump also start brine in reactor before transferring
.
STAGE 2:- NEUTRALIZATION AND WASHING
15% CAUSTIC WASH
1. After receiving all reaction mass from Pocl3 Addition Reactor cool the mass up to 10.C.
2. Then start addition of 3805 kg 15% caustic solution from Holding Tank
3. Complete the addition within 9-10hr below mass temp 27.C.
4. After addition of required quantity of 15%NAOH solution check PH should be 12-13. If not then add
more 15%NAOH solution to set PH
5. After set PH stirr mass for 1hr then stop stirring and allow mass for 1hr.
6. Carefully separate bottom aqueous layer and transfer it to Holding Tank
(At the end of acquis layer emulsion is found in glass pot. take emulsion in organic layer)
Bottom acquis layer = 3565 litre (12-13ph) (density 1.15)
WATER WASHING:-
1. After complete separation of bottom aq. layer close bottom valve of Reactor, charge 900 litre
water. In same reactor via mass flow meter.
2. After water addition stirr mass for 1hr.
3. Carefully separate bottom aq. layer and transfer it to Holding Tank Take emulsion in organic layer.
AQ. LAYER (BOTTOM) = 855 litre
(PH = 7-10.5) (DENSITY= 1) During settling submit sample for PH analysis should be <10.5. If PH
>10.5 than give further one water wash of 900litre.
1. After complete separation of aq. layer transfer organic layer to holding tank
Organic layer = 3770 litre
Organic Layer M/C : 9-11 %
(Density = 0.89-0.9)
STAGE - 3:- n-BUTANOL RECOVERY AND PRODUCT DISTILLATION
2. Reactor should be clean. Bottom valve should be closed. Open the vent of the reactor.
3. Take organic layer from Holding Tank in reactor after receiving organic layer start FFE pump and
circulation.
4. Then apply vacuum by 1st stage ejector.
5. After applying vacuum start hot oil circulation in FFE only and put hot oil set point 150 .c.
6. Start 100% collection in 1st cut as acquis n-butanol in holding tank in the temp. Range 35-120.c
mass temp. And vapour temp. 35-80.c. vacuum 615-635mmhg.
7. After achieve mass temp. 120. C and no collection of 1stcut then stop FFE and apply heating in R-
2510 only.
8. Then slowly increase vacuum by apply 2nd stage ejector. Also increase hot oil set point to 170 .c.
again collection starts and its collect in 1stcut.
9. Slowly recovery rate decrease and stops recovery then stop collection in 1stcut and start collection
in intercut tank. Vacuum 730-745mmhg. Collected aq. N-butanol in holding tank is used after
dry in distillation columns
10. Apply further 3rd and 4th stage ejector vacuum and increase hot oil set point 185.c.
11. Again recovery starts and collection continue in intercut up to vapour temp. 120. C (vacuum 755-
758mmhg).
12. After achieve vapour temp. 120. C start reflux and set reflux and collection as max. Reflux and
minimum reflux. (Set reflux and collection by only reflux valve and put collection min. as rota
meter flow movement below 50lit/hr rate).
13. Once vapour temp. Stable (approx. 125-130.c depends on vacuum) submit sample of online distilled
TBPO for n-butanol content by GC should be <3% and put under 100% reflux.
14. If result not ok then further collect in intercut for 15min and submit sample.
15. After getting result ok stop collection in intercut and start 100% collection in final cut tank Increase
oil set point up to 220.c and at the end of recovery
16. Once recovery stops apply cooling in to the reactor after achieve reactor temp. 100. C then charge
450lit aq. effluent from holding tank
17. Stirr to complete dissolve residue and after dissolve residue drain it to tank
18. Weight of distilled final cut TBPO is 1000kg.
19. Submit the sample for complete analysis.
20. After analysis ok transfer it to storage tank
Process Operation:
N-BUTANOL Caustic Lye (15%)
POCL3 Recycle DM water
TBPO TO STORAGE TANK
Drum Salt
Chemical Reaction:
Mass Balance:
Sr. No. Input Quantity (Kg) Output Quantity (Kg)
1 N-Butanol 698 TBPO 1000
2 POCL3 2685 N-Butanol Recovered 1500
3 Caustic Lye (15%) 3805 N-Butanol Loss 1185
4 DM Water 900 Water 4388
5 Dist. Residue 15
Total 8088 Total 8088
3C4H9OH + POCL3 (C4H9O) 3P=O + 3HCL(3*74=222) 153.5 266 (3*36.5=109.5)
3HCL + 3NAOH 3NACL + 3H2O
109.5 (3*40=120) (3*58.5=175.5) (3*18=54)
CHEMICAL REACTION
ANNEXURE-4
DETAILS OF WATER CONSUMPTION & WASTE WATER GENERATION
SR.
NO.
DESCRIPTION EXISTING (KL/Day) TOTAL AFTER PROPOSED EXPANSION
(KL/Day)
WATER
CONSUMPTION
WASTE WATER
GENERATION
WATER
CONSUMPTION
WASTE WATER
GENERATION
1 Process 0.01 0.008* 45.0 40.0
2 Boiler 15.0 3.5 15.0 3.5
3 Cooling & Chilling 5.0 1.274 25.0 6.5
4 Washing 1.6 1.6 5.0 5.0
5 Scrubber/APCM 23.09 -- 54.0 --
Total Industrial
44.7 6.382 – 0.008 =
6.374
144 55.00
7 Domestic 5.5 5 # 24.5 23.5 #
8 Gardening -- -- 10.5 --
Grand Total 50.2 11.374 179.0 78.5
* Water is reused in process (Product: Meta Chloro Propio Phenone).
# Domestic waste water is & will be disposed of through septic tank & soak pit.
WATER BALANCE DIAGRAM:
CETP, M/s. PETL for further treatment
Raw Water: 167 KL/Day from GIDC (Fresh – 144 KL/Day + Reuse-44 KL/Day)
Domestic:
24.5 KL/Day
Process: 45
KL/Day
Boiler: 15
KL/Day
Washing: 5
KL/Day Gardening:
10 KL/Day
Soak Pit &
Septic Tank:
23.5 KL/Day
40 KLD 3.5 KL/Day 6.5 KL/Day
ETP: 6.3 KL/Day
Cooling
Tower: 25
KL/Day
5 KL/Day
48.7 KL/Day Solvent
Stripper MEE
Condensate: 44.00 KL/Day
MEE Salt: 2.0 MT/Day
TSDF site Spent Solvent: 1.70
MT/Day Common
Incineration site
Scrubber-
54 KL/Day
ANNEXURE-5
EFFLUENT TREATMENT PLANT
In existing, M/s. Wanksons Chemical Industries Pvt. Ltd. has an Effluent Treatment Plant (ETP) of primary
treatment (neutralization) facility. Treated effluent sends to Common Effluent Treatment Plant (CETP) of
M/s. Panoli Enviro Technology Ltd. (PETL), Panoli for further treatment and disposal.
EXISTING ETP FLOW DIAGRAM:
5 KL
Equalization cum
Neutralization Tank
Raw Effluent
5 KL
Equalization cum
Neutralization Tank
5 KL
Equalization cum
Neutralization Tank
Caustic
Filter Press
30 KL
Raw Effluent Storage
Tank
Near 3-CPP Plant
10 KL
Treated Effluent
Storage Tank
10 KL
Treated Effluent
Storage Tank
10 KL
Treated Effluent
Storage Tank
PETL, Panoli
PROPOSED ETP FLOW DIAGRAM:
DESCRIPTION OF EFFLUENT TREATMENT PLANT
Capacity of ETP= 50 KL/Day
Wastewater shall be collected in Equalization cum Neutralization tank (ENT-01) where the continuous
addition and stirring of Caustic solution is done to maintain neutral pH of wastewater from Caustic
Dosing Tank (CDT-01) as per requirement by gravity. Mixer is provided in the ENT-01 to keep all
suspended solids in suspension and for proper mixing.
Then, neutralized wastewater shall be pump to Primary Settling Tank (PST-1). Alum and Polyelectrolyte
shall be dosed from Alum Dosing Tank (ADT-01) and Polyelectrolyte Dosing Tank (PEDT-01) respectively
by gravity into PST-01 to carry out coagulation by using a Mixer. Then Mixer is stopped and effluent is
allowed to settle in Primary Settling Tank (PST-01). After Primary treatment, Clear supernatant from
PST-01 shall be collected in Treated Effluent Sump (TES-01) before sent to In-house MEE for further
treatment.MEE condensate will reuse in plant premises.
Sludge settled in PST-01 shall be collected in Sludge Drying Beds (SDBs-01-A/B) where, dewatering shall
be carried out before storage in HWSA and ultimate disposal to TSDF.
The Domestic wastewater is disposed of through septic tank & soak pit.
Size of Tanks
S.N. Name of unit Size (m x m x m) No. MOC/ Remark
50 m3/Day
1 Collection cum Neutralization Tank
(CNT-01)
3.5 m x 3.5 m x
(2.5 m+0.5 FB) 1
RCC M30+A/A Bk.
Lining
2 Primary Settling Tank (PST-01) 2.0 m x 2.0 m x
(1.7 m + 0.5 HB+0.5 FB) 1
RCC M25+A/A Bk.
Lining
3 Treated Effluent Sump (TES-01) 3.5 m x 3.5 m x
(2.5 m+0.5 FB) 1 RCC M25
4 Sludge Drying Beds (SDBs-01-A/B) 3.0m x 2.0 m 2 RCC M25
5 Caustic Dosing Tank (CDT-01) 500 Lit 1 HDPE
6 Alum Dosing Tank (ADT-01) 500 Lit 1 HDPE
7 Poly Dosing Tank (PEDT-01) 250 Lit 1 HDPE
8 Multiple Effective Evaporator (MEE) 30 m3/D 1 SS
RCC M25 = REINFORCED CEMENT CONCRETE (M 25 GRADE) PCC = PLAIN CEMENT CONCRETE PP = POLYPROPELENE MSEP = MILD STEEL EPOXY PAINTED SS = STAINLESS STEEL
EXPECTED CHARACTERISTIC OF EFFLUENT (STREAM-I)
Sr. No. Category of Wastewater Before Treatment After Treatment
1 pH 3.5-6.5 6.5-8.0
2 COD (mg/L) 5000 3000
3 BOD3 (mg/L) 2000 1000
4 TDS (mg/L) 3500 3500
5 Ammonical Nitrogen (mg/L) 50 20
EXPECTED CHARACTERISTIC OF EFFLUENT (STREAM-II)
Sr. No. Category of Wastewater Before Treatment
1 pH 2-10
2 COD (mg/L) 45000
3 BOD3 (mg/L) 12000
4 TDS (mg/L) 40000
5 Ammonical Nitrogen (mg/L) 100
Flow Diagram:
ANNEXURE-6
DETAILS OF HAZARDOUS/SOLID WASTE GENERATION, MANAGEMENT AND DISPOSAL
SR.
NO.
TYPE OF WASTE CATEGORY
NO.
QUANTITY MODE OF
DISPOSAL EXISTING
(As per current
CC&A)
TOTAL AFTER
PROPOSED
EXPANSION
TOTAL AFTER
PROPOSED
EXPANSION
1 Used oil 5.1 0.008 MT/Month 0.092
MT/Month
0.092 MT/Month Collection,
Storage & sell to
MoEF/GPCB
approved vendor.
2 Discarded
Drums/Carboys/HD
PE Bags/liners
33.1 1.6 MT/Month
(30 #/Month)
92 Nos./Month 92 Nos./Month
1.6 MT/ Month
Collection,
Storage,
Decontamination
& sell to GPCB
authorized
vendor.
3 ETP sludge 35.3 0.41 MT/Month 2.91 MT/Month 4.0 MT/Month Collection,
Storage & send to
common TSDF site
of M/s. BEIL, or
M/s. SEPPL.
4 Distillation Residue 20.3 -- 9.16 MT/Month 15 MT/Month Collection,
Storage & send to
CHWIF of M/s.
BEIL or sell to
cement industries
for co-processing.
5 Spent Solvent from
Striper
-- -- -- 50 MT/Month Collection,
Storage & send to
CHWIF of M/s.
BEIL or sell to
cement industries
for co-processing.
6 MEE Salt 35.3 -- -- 60 MT/Month Collection,
Storage & send to
common TSDF site
of M/s. BEIL, or
M/s. SEPPL.
ANNEXURE-7
POWER AND FUEL REQUIREMENTS
1. Power Requirement
Sr.
No.
Requirement Source
Existing Total After
Proposed
Expansion
Existing After Proposed Expansion
1. 1000 KVA 1000 KVA 1. DGVCL (GEB)
2. D.G. Set - 1 no.
1. 350 KVA capacity
(emergency standby)
2. DGVCL (GEB)
3. D.G. Sets - 3 nos.
- 500 KVA capacity (1 Nos.)
- 380 KVA capacity (1 Nos.)
- 250 KVA capacity (1 Nos.)
(emergency standby)
2. Fuel Requirement
Sr. No.
Fuel Requirement (to be used in emergency only)
Existing Total After Proposed Expansion
1. Natural Gas 2290 SM3/day* (206 SM3/day)**
2890 SM3/day
2. Diesel 90 Liter/hr.* (20 Liter/hr.)**
235 Liter/hr.
* Actual quantity used
** Typographic error in current CC&A valid up to 4/4/2019.
ANNEXURE-8
HAZARDOUS CHEMICAL STORAGE AND HANDLING DETAILS
Sr. No.
Name of Hazardous chemical
Quantity Places of its Storage
(Storage tank /drums
/cylinders /barrels)
No. of Storages
Places of its Storage
State Type of Hazards
Control measures provided
Max. that Can be Stored
Actually stored
1. Toluene 10 KL 8 KL Tank 1 Tank Farm Area
Liquid Flammable/ Toxic
1. Closed handling and transferring systems for Hazardous chemicals.
2. Dyke walls and material collection systems are provided to all material storage tanks.
3. Fire Extinguishers and absorbents will be available near storage tanks and storage area.
4. Drums to be stored on pallet with the suitable trap.
2. Methanol 12 KL 12 KL Drums 60 # Storage Area Liquid Flammable
3. Chlorine 900 Kg (60 x 900 Kg) Tonner 60 # (54 MT)
Storage Area Liquid Flammable
4. Sodium Methoxide
4 MT 4 MT Bags 80 # Storage Area Liquid Flammable
5. Bromine 3 MT 3 MT Glass Bottle 1000 # Storage Area Liquid Toxic & Corrosive
6. HCl (30-32%)
125 KL 125 KL PP Storage Tank
5 Tank Farm Area
Liquid Corrosive
7. H2SO4 (98%) 40 KL 40 KL Storage Tank (20 KL)
2 Tank Farm Area
Liquid Corrosive
8. Ethyl Alcohol 330 KL 256 KL Storage Tank 5 Tank Farm Area
Liquid Flammable
9. Thionyl Chloride
5 MT 5 MT Drums 25 # Storage Area Liquid Toxic & Corrosive
10 Benzene 10 KL 10 KL Tank 1 Tank Farm Area
Liquid Flammable
11 IPA 10 MT 10 MT Drums 50 # Storage Area Liquid Flammable
12 o-Xylene 1 MT 1 MT Drums 5 # Storage Area Liquid Flammable
13 MDC 3 MT 3 MT Drums 15 # Storage Area Liquid Flammable
ANNEXURE-9
DETAILS OF SOURCE OF EMISSION
Sr. No.
Stack/Vent attached to Stack Height (meter)
Stack Diameter (meter)
Fuel name & Quantity
Type of Emission
APCM
Existing
1 Boiler (3 TPH)
30 # 0.406 Natural Gas 2290 SM3/day*
(206 SM3/day)**
PM SO2 NOx
--
2 Process Vent (Chlorinator & Distillation Reactor)
13 0.15
-- HCl Cl2
Existing Water Scrubbers (4 Nos.) + Caustic Scrubber (1 Nos.)
+ Additional (Proposed)
Water Scrubber (1 Nos.) + Caustic Scrubber (1 Nos.)
3 Dust Collector (Power – Formulation Unit)
20 0.15 -- PM SO2 NOx
--
4 D.G. Set (350 KVA) (Use in emergency only.)
-- -- Diesel 90 Liter/hr.*
(20 Liter/hr.)**
PM SO2 NOx
--
Proposed
5 Thermc Fluid Heater (4 Lac Kcal/hr)
30 # 0.406 Natural Gas (200 SM3/day)
--
6 D.G. Set (380 KVA) (To be use in emergency only.)
-- -- Diesel 90 Liter/hr.
PM SO2 NOx
--
7 D.G. Set (250 KVA) (To be use in emergency only.)
-- -- Diesel 55 Liter/hr.
PM SO2 NOx
--
* Actual quantity used.
** Typographic error in current CC&A valid up to 4/4/2019.
# Common stack between existing boiler and proposed thermic fluid heater.
ANNEXURE - 10
SOCIO - ECONOMIC IMPACTS
1) EMPLOYMENT OPPORTUNITIES
The manpower requirement is expected to generate some permanent jobs and secondary jobs for the
operation and maintenance of plant. This will increase direct/indirect employment opportunities and
ancillary business development to some extent for the local population. This phase is expected to create a
beneficial impact on the local socio-economic environment.
2) INDUSTRIES
Require raw materials and skilled & unskilled laborers will be utilized maximum from local area. The
increasing industrial activity will boost the commercial and economical status of the locality, to some
extent.
3) PUBLIC HEALTH
The company will regularly examine, inspects and tests its emission from sources to make sure that the
emission will keep below the permissible limit. Hence, there will not be any significant change in the
status of sanitation and the community health of the area, as sufficient measures will be taken under the
EMP.
4) TRANSPORTATION AND COMMUNICATION
Since the existing Panoli GIDC estate is having proper linkage for transport and communication, the
development of this project will not cause any additional impact.
In brief, as a result of the proposed project, there will be no adverse impact on sanitation, communication
and community health, as sufficient measures will be proposed to be taken under the EMP. Hence,
proposed project is not expected to make any significant change in the existing status of the socio -
economic environment of this region.
ANNEXURE – 11
PROPOSED DRAFT TERMS OF REFERENCE
1. Project Description
Justification of project.
Promoters and their back ground
Project site location along with site map of 10 km area and site details providing various industries,
surface water bodies, forests etc.
Project cost
Project location and Plant layout.
Infrastructure facilities
Water source and utilization including water balance.
List of Products & their production capacity
Details of manufacturing process of proposed products
List of hazardous chemicals
Storage and Transportation of raw materials and products.
2. Description of the Environment and Baseline Data Collection
Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km area.
Other industries in the impact area
Prevailing environment quality standards
Existing environmental status vis a vis air, water, noise, soil in 10 km area from the project site.
Ground water quality at 5-6 locations within 10 km.
Complete water balance
3. Socio Economic Data
Existing socio-economic status, land use pattern and infrastructure facilities available in the study
area were surveyed.
4. Impacts Identification and Mitigatory Measures
Identification of impacting activities from the proposed project during construction and operational
phase.
Impact on air and mitigation measures including green belt
Impact on water environment and mitigation measures
Soil pollution source and mitigation measures
Noise generation and control.
Hazardous/Solid waste quantification and disposal.
Control of fugitive emissions
5. Environmental Management Plan
Details of pollution control measures
Environment management team
Proposed schedule for environmental monitoring including
6. Risk Assessment
Objectives, Philosophy and methodology of risk assessment
Details on storage facilities
Process safety, transportation, fire fighting systems, safety features and emergency capabilities to be
adopted.
Identification of hazards
Consequence analysis
Recommendations on the basis of risk assessment done
Disaster Management Plan.
7. Information for Control of Fugitive Emissions
8. Information on Rain Water Harvesting
9. Green Belt Development plan
ANNEXURE – 12
COPY OF LAND POSSESSION / PLOT ALLOTMENT LETTER
ANNEXURE – 13
COPY OF CETP AND SPRAY DRYER MEMBERSHIP LETTER
ANNEXURE – 14
COPY OF COMMON TSDF & HWIF MEMBERSHIP LETTER
ANNEXURE – 15
TOPOSHEET
ANNEXURE – 16
COPY OF GIDC LETTER FOR WATER SUPPLY
Recommended