1.Name the following compounds a. KBr b.Na 3 (PO 5 ) c.Al(NO 2 ) 3 2. Give the Chemical Formula for...

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1.Name the following compounds a. KBrb. Na3(PO5)

c. Al(NO2)3

2. Give the Chemical Formula for the following compoundsa. Calcium Oxideb. Lithium Hydroxidec. Magnesium Manganate

BELL RINGER

POLYVALENT METALS – TRANSITION METALS

Unit 5: Chapter 6.3a

TRANSITION METALS

POLYVALENT METALS

• Many but not all transition metals have “multiple personalities”– # of valence electrons varies– they can form more than one ion (more

than one charge).• Also known as valence # or oxidation

#– Polyvalent

• Roman Numerals are used to signify the charge

POLYVALENT TRANSITION METALS

• Metals with more than one possible charge:• Specific charge is indicated in

parenthesis

POLYVALENT METALS & BONDING

• Fe(II) = – Iron (II) + oxygen =

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen =

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen =• Fe2+ & O2-

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = • Fe2+ & O2- Fe2O2 FeO

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = Iron (II) Oxide• Fe2+ & O2- Fe2O2 FeO

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = Iron (II) Oxide• Fe2+ & O2- Fe2O2 FeO

• Fe(III) = Fe3+

– Iron (III) + oxygen =

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = Iron (II) Oxide• Fe2+ & O2- Fe2O2 FeO

• Fe(III) = Fe3+

– Iron (III) + oxygen = Iron (III) Oxide

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = Iron (II) Oxide• Fe2+ & O2- Fe2O2 FeO

• Fe(III) = Fe3+

– Iron (III) + oxygen = Iron (III) Oxide• Fe3+ & O2-

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = Iron (II) Oxide• Fe2+ & O2- Fe2O2 FeO

• Fe(III) = Fe3+

– Iron (III) + oxygen = Iron (III) Oxide• Fe3+ & O2- Fe2O3

POLYVALENT METALS & BONDING

• Fe(II) = Fe2+

– Iron (II) + oxygen = Iron (II) Oxide• Fe2+ & O2- Fe2O2 FeO

• Fe(III) = Fe3+

– Iron (III) + oxygen = Iron (III) Oxide• Fe3+ & O2- Fe2O3

• Name these compounds just like other binary ionic compounds but include the metal’s oxidation # (charge) in parentheses

PRACTICE - POLYVALENT COMPOUNDS

• Names to Formulas– Silver (III) Nitride– Vanadium (III) Chloride– Lead (IV) Oxide– Silver (II) Nitride– Vanadium (II) Chloride– Lead (II) Oxide

PRACTICE - POLYVALENT COMPOUNDS

• Formulas to Names– Have to determine the oxidation

#/Charge of your metal.• Reverse the criss cross (doesn’t always work)

– Fe2O3 Fe3+ and O2-

• Make sure the compound is neutral (positive & negative charges cancel out)

–Fe3+ 2 x 3+ = 6+–O2- 3 x 2- = 6-

PRACTICE - POLYVALENT COMPOUNDS

• Formulas to Names– Have to determine the oxidation

#/Charge of your metal.• Reverse the criss cross (doesn’t always work)

– Fe2O3 Fe3+ and O2-

• Make sure the compound is neutral

• SnO3

PRACTICE - POLYVALENT COMPOUNDS

• Formulas to Names– Have to determine the oxidation

#/Charge of your metal.• Reverse the criss cross (doesn’t always work)

– Fe2O3 Fe3+ and O2-

• Make sure the compound is neutral

• SnO3 Sn3+ and O1-

PRACTICE - POLYVALENT COMPOUNDS

• Formulas to Names– Have to determine the oxidation

#/Charge of your metal.• Reverse the criss cross (doesn’t always work)

– Fe2O3 Fe3+ and O2-

• Make sure the compound is neutral • SnO3 Sn3+ and O1-

–O2- 3 x 2- = 6-–Sn? 1 x ? = 6+

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

Common Ions Hydrogen H+1 Aluminum Al+3 Nitrate (NO3)

-1

Calcium Ca+2 Iron (III) Fe+3 Sulfate (SO4)-2

Zinc Zn+2 Chlorine Cl-1 Carbonate (CO3)-2

Copper (II) Cu+2 Hydroxide OH-1 Phosphate (PO4)-3

Silver Ag+1 Phosphide P-3 Acetate (C2H3O2)-1

Which of these are: •Metals? •Nonmetals?

•Polyatomic ions?•Transition metals?

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