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COMMERCIAL NANOTECH PRODUCTS APPLICATIO N DEVELOPER GRAPHENE & M W C N T Commercialised Nano Materials & Technologies

NanoSmiths are here! Best Graphene and CNT supplier Globally!!

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Page 1: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

COMMERCIAL NANOTECH PRODUCTS

APPLICATIONDEVELOPER

GRAPHENE & M W C N T

Commercialised Nano Materials & Technologies

Page 2: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

PRODUCTS

MULTI-WALL CARBON NANO

TUBESGRAPHENE

Dispersion MWNT

Dispersion Graphene Solution

Functionalised Graphene

Functionalised MWNT

Base Nano materials produced in bulk

Page 3: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

STRENGTH

Page 4: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Graphene Enriched Ready to use Materials

UNIOILNano-Resin

Nano-CompositeIndustrial OilFor Tyre Industries

Nano- Resin/epoxy ForCoating/FRP

Reinforced & advancedconstruction materials

Page 5: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

N

od

GRAPHENE

20KG/DAY PRODUCTI

Proprietary CVD andmethod

CARBON NANOTUBEBulk production of Graphene

Chemical Exfoliation

1KG/DAY PRODUCTIONProprietary CVD method

All variants of Graphene:Graphene oxide Reduced Graphene Oxide

All variants of CNTs[no single wall]-Short MWCNT

Surface modified Graphene- Carboxylic,Hydroxyl,Amine

Surface modified MWCNT-Carboxylic, Hydroxyl,Amine

Dispersion of GRAPHENE in desired organic, inorganic solvent:1000litre/day

Dispersion MWCNT in desired organic, inorganic solvent:1000litre/day

Serving frequently to Aircraft, Paints,Automotive industries

Serving frequently to Aircraft, Paints,Automotive industries

GRAPHENE

Page 6: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

– Improvement of mechanical properties, especially strength– Enhancement of thermal stability– Enhancement of thermal conductivity– Improvement of fire retardancy– Electrical conductivity– Enhancement of oxidation stability– Antimicrobial environment

Benefits of Graphene in Polymer

Page 7: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

GRAPHENE : Has got widest spectrum of

Applications

e.g. strength, modulusand

•Mechanicalproperties dimensional

stability•Decreased permeability to gases,waterandhydrocarbons

•Thermal stability and heat distortion temperature•Flame retardancy and reduced smoke emissions•Chemical resistance•Surface appearance•Electrical conductivity

General Benefits of Graphene

Page 8: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Future Markets, reports 4K% increase of demand for graphene-based materials Graphene has moved swiftly from the research laboratory to the market

driven by demand from markets where advanced materials are required.

Graphene – Hype+ serious work= Commercial success

Page 9: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Game Changing

Innovative

Traditional NANOCOMPOSITEHigh strengthNot Brittle Lowest weightCONVENTION

AL COMPOSITEHigh strengthBrittleLower weight

METAL ALLOYSHigh strength High weight

11

Polyunate is a new fire proof PC for Aerospace

Page 10: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Properties Neat Resin Polyester resin[GP Resin] Graphene Enriched resin Polyester resin[GP Resin]

Tensile strength MPa 52 69

Flexural strength MPa 78 103

Compressive Strength 142 174MPaF.Modulus 3885 5082MPaBarcol Hardness 40 42

Specific gravity 1.1 1.21At 25 Degee C

H.D.T degree celsius

Elongation at break

63

2%

70

3%

Nano resin( GP Grade )

Page 11: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

ADVANCED RESIN PRODUCING HOGH MECHANICAL STRENGTH Fatigue Resistance and Micro-Cracking

■Superior mechanical properties (particularly strength and stiffness)■ Better adhesive properties (the ability to bond to the reinforcement or core)■ Improved resistance to fatigue and micro cracking■Reduced degradation from water ingress (diminution of properties due to water penetration)■ Increased resistance to osmosis (surface degradation due to waterpermeability)

GraphenePolyester Resin

Nano FRP is more advanced and superior

Page 12: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Gel time: 16 – 20 minutesLIQUID RESIN PROPERTIES (Typical values) Specific gravity at 25°C: 1.09Rotothinner viscosity at 25°C: 2.3 – 2.7 dPa.s Volatile content: 45%Gel time: 16 – 20 minutesQuantity to be applied: 1kg for 1 m2

REINFORCED Castings ResinHand Lay Up Resin

Filament Winding Resin Roofing Sheet Grade Resin Bullet Proof Helmet Grade Resin Synthetic Abrasive Grade Resin Anchoring Capsule Grade Resin Smc / Dmc Resin Pultrusion Resin Fire Retardants Resin

Nano FRP : Key applications

Page 13: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

•••••••••

Bullet Proof VestSmart actuatorsStructural materials for fight Jet CoatingSensorRFID InkIn navy ship Military gadgets Conductive plastics

Anti-thermal- camouflage screening

Other Defense Applications

Page 14: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

8/12/2015CNT in breast cancer cell 16

Few clips of our work

Page 15: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Few Nano Materials we produce

Page 16: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Bulk nano composites is our core competency

Page 17: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

GRAPHENE MIXING FOR TYRE COMPONENTTYRE RUBBER BASE

TYRE SAMPLE PREPARATION TWO ROLL MILLPREAPARED TEST AND CONTROL SAMPLES

Nano blend tyre Oil ensures superior mechanical properties & overall life

Page 18: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

CNT PASTE

Nano composite wear test

Pilot Plant CVD Set Up 20

Our various nano practices

Page 19: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Epoxy + CNT : a real phenomenon

Page 20: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

ased

Graphene blend nano coating

Page 21: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

FOULINGFouling is the term generally used to describe

the settlement and growth of marine plants and animals on submerged structures. These structures typically include ships’ hulls, piers, piling and oil rigs, but also includesthe internals of pipework used to carry water

as a coolant for industrial power plants

Macro-fouling – which includes plant (weed) and animal fouling

&Micro-fouling – which includes unicellular algae and bacteria (also referred to as 'slime').

4000 known species

colonise a submerged surfaceTrop

ical

/sub

trop

ical

zon

es: 2

0ºC+

,hi

gh fo

ulin

g ris

k. F

oulin

g co

ntin

ues

thro

ugho

ut th

e ye

ar w

ith a

mul

tiplic

ity

of s

peci

es.

Graphene blend Anti-Fouling Coating

Page 22: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

The use of Antifouling Paints can control this

Environmentally friendly antifouling coatings

New natural products, including biocide free coatings

Graphene blend Anti-Fouling Coating

Fouling Losses

Page 23: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Marine polymeric coatings, like most paint compositions, are made up from a binder and a series of pigments which include additives, colour and extenders. The antifouling additives are included in the top-coat or final coating layer of the multi-coat marine antifouling system. Thus, the binder and solvent selection need to be carefully tailored to the chemical properties of any new potential biocide molecule.

20,000 natural products

GRAPHENE enabled nano-paint is one of the promising entryinto the Anti Fouling domain

Graphene blend Anti-Fouling Coating

Page 24: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

❖Improvement of mechanical properties, especially strength

Enhancement of thermalconductivity

❖Improvement of fire retardancy

❖Electrical conductivity❖Enhancement of oxidation

stability❖Antimicrobial environment

Very unique mechanism than any other conventional fillers

Benefits of Graphene to polymers

Graphene is one of the only 2 D nanostructure material of Carbon which act very differently

Page 25: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmithsColony of bacteria

BIOFILM Adhesion

NANOCOATING prevents bacterial growth by causingoxidative stresses- [tested bacterial strains]

Graphene blend A

nti-Fouling C

oating

Page 26: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Bacterial colonisation is the first step in the formation of a biofilm, which leads to the colonisation of fouling organisms on the surface of the hulls of ships [Ref: Lejars M, Margaillan A, Bressy C. Fouling release coatings: a nontoxic alternative to biocidal antifouling coatings. Chem Rev 2012;112:4347–90

Graphene blend Anti-Fouling Coating

Page 27: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

•We have commercialised Graphene based antifouling coating exclusively for maritime industry.

•The innovative paint has the combination of properties : corrosion resistance in salt water, antibacterial resistance, antifouling properties, Reduced environmental impact & Improved mechanical properties.

•Graphene represents active surface & edges having compatibility with paint resin .The Nano-paint

acts by its dual feature, causes stress to microbes and repel the flora and fauna causing fouling!

Graphene blend Anti-Fouling Coating

Page 28: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Common Antifoulingpaint Before use

Common Antifouling paint After use

ACID IMMERSION TEST @ 24 HOURS IN 0.1M HCL COROSSION INHIBITION TEST

Weight loss1.69%-

Common antifouling

paint

1.06% Nano- antifouling

paint

Nano –Antifouling Nano Antifouling paint after usePaint Before use

Nano Anti Fouling demonstrates improved corrosion resistance

Page 29: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

>70% CORROSION EFFIECIENCY

EFFICIENT ANTIFOULING

PAINT

Economic advantages

Unique mechanism of

action

Nano Enrich antifouling coating

Page 30: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

SOLID CONTENT 50%

THEORETICAL SPREADING RATE 4M2/L

DRY FILM THICKNESS REQUIRED 50 MICRON

DRYING TIME 30 MIN

DRY HEAT RESISTANCE 150 DEGREE C

Method of Application: Brush / Roller / Airless sprayAirless spray recommended for uniformand high film build

Colour Brown

IMMEDIATE APPLICATIONS SHIP HULLS /VESSEL

Page 31: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Fungal growth after 24:No growth :No colony

Fungal growth after colony found :Growth continued

Nano antifouling paint Common paint

Tissue culture Lab report

More than dozens of bacterial cell line were studied under MTS assay in our lab[in-vitro] the nano antifouling paint growth media –these countable number of bacteria were stopped growing

Page 32: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Effective for longer periods Act by poisoning the organisms at the time

of attachment Repel the microbes because of chare

surface Resistance to the erosive effects of water

movement Smoothness Use of natural non-toxic materials Easy application Technologically advanced products

Nano Paint

Page 33: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

EpoxyNanocomposite

Nanocomposite Fibre

Nano material we produce

Page 34: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Few nano-equipment we designed

Page 35: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

INJECTION MOULDINGFOR PLASTIC SHEET FABRICATION

Extended facilities

Page 36: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Filter Unit TWIN SCREWEXTRUDER

Application equipment

Page 37: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

CVD Set Up –Running 250gm/batch CVD Set Up-Running

400gm/batch

MWCNT batch set ups

Page 38: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Nano comp osite wear test

28

CNT PASTEFresh CNT

Nano material we produce

Page 39: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Indian oil lubricant

Dabur-Nanoxel

Tata SwachXUV Car Dash board

http://www.nanotechproject.org/cpi/products

Common Nano Products in India

Page 40: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

Market demand 1.Very competitive price in market2.Enabling new entrepreneurs to manufacture in bulkquantity for commercial application3. World best quality4.Dozens of patentable technologies in hand on application front

1.Need low price 2.High quality3.Commercialisation of carbon nano material in high growth sectors4.Innovations on application point of view NanoSmiths

CONTRIBUTION

Page 41: NanoSmiths are here! Best Graphene and CNT supplier Globally!!

NanoSmiths

We aim to focus on the possibilities and avoid havocs! Andbelieve that together we can bring changes!!

THANKS!