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2012 AFPM Annual Meeting March 13 10:30 am – 12:00 pm Technology Pathways to Advanced Biofuels

CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

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Page 1: CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

2012 AFPM Annual MeetingMarch 1310:30 am – 12:00 pm

Technology Pathways to Advanced Biofuels

Page 2: CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

2012 Annual MeetingAM-12-32 Page 2

Describe:• Types of technology pathways under

development;• Biomass feedstock choices;• Development timeline for each technology

type; and• Interface with petroleum refining industry

Session Objective

Page 3: CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

Dr. Alan Del PaggioVice President – Upstream & RenewablesCRI Catalyst Company Houston, Texas

Biomass to Transportation Fuels via IH2 Technology

Page 4: CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

2012 Annual MeetingAM-12-32 Page 4

Key DifferentiatorsFeedstock Flexible

Stand Alone (or Synergistic) Operation

Attractive economics Low capex (low P, low TAN, simple)Low opex

Exothermic

Hydrocarbon productHigh energy density (i.e. 18 kBTU/lb)Yields 67-157 gal/ton MAF*Replaces ‘whole barrel’ gas/jet/dieselLow TANO below detection limitFungible

Self-sufficient internal “green” H2

>90% GHG reduction** Eases logistical constraints (H2)

Integrates existing technologies Rapid implementation

2) Bubbling Fluidized Bed Proprietary Catalyst

Renewable H2

340-470C<500psig

1) Feed ConditioningSizing , Drying & Feeding

1st Stage 2nd Stage

4) Fixed Bed Hydrotreater

Proprietary CatalystRenewable H2

<500psig

HDO’d Liquid

3) Renewable H2Light Gases

Distilled Hydrocarbon

Products

Hi Press Steam

Hot Water

N/S stream for Fertilizer

Char (burn)

Green CO2

Agri Residues

Wood/Forest Residue

Garbage (MSW)

Energy Crops

Algae

Gasoline, Jet and /or Diesel

Range Hydrocarbon Fuels / Blend

Stocks

IH2 Process Differentiators

* Moisture & Ash Free basis** IH2 technology LCA Analyses conducted by Prof. David Shonnard, et al Michigan Technical University; feed stock dependent

Page 5: CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

2012 Annual MeetingAM-12-32 Page 5

4.7

17.7

6.8

44.0

36.6

Feed

1st Stage HP/ 2nd Stage HC

Fractionation

HMU

Utilities & Con-tingency @ 35%

Installed Equipment Costs $112.6mln

112.6

5.7

11.7

102.7Installed Equipment Costs

Land/Develop

Permits & S/U

Standard Project Add-In's**

Total Capital Investment $232.8mln

91.31

7.8

2.14

17.3

5.9

29.6Wood $71.97/dry ton

Other Op Costs: Cata-lyst, Disposal, etc.

Fixed Cost

Depreciation

Avg Income Tax

Avg ROI

Operating Costs Total $1.60/gal*

*Includes $0.093/gal coproduct credit

** Prorated Expense (10%), H O & Construction (20%), Field Expense (10%), Working Capital (10%) , Project Contingency (30%)

• 2000mt/d wood (delivered to 1st stage at 10% moisture)

• Land acquisition & development costs included

• Equipment cost - HMU is largest @ $44mln ~40% TIC

• Total Capital ~Double Installed Equipment

• Feed Stock ~55% of Operating Cost

• Minimum Fuel Selling Price – 1.60$/gal (2007 USD)

• Refinery Synergy w/Refinery H2 Supply

• Reduces Capital Cost ~44.0MM$

• Estimated MSP $1.36/gal (2007 USD)

• NREL Economics validated by Global Engineering & Construction Company

Title: Techno-economic Analysis of the Integrated Hydropyrolysis and Hydroconversion Process for the Production of Gasoline and Diesel Fuels from BiomassAuthor: Eric C. D. Tan Platform: Analysis Report Date: May 23, 2011

IH2 Process Estimates

Page 6: CRI Excerpt from American Fuel and Petrochemical Manufacturer’s Panel Discussion

2012 Annual MeetingAM-12-32 Page 6

IH2 Technology Deployment

• Bench Scale­ Since 2009 @ 0.5-kg/hr

• Pilot Scale­ February S/U, continuous @ 50-kg/d

• Pre Commercial Scale­ Basic Engineering 5t/d demo(s)

• Commercial Scale­ Target availability 1/1/14 begin Engineering

• Significant interest from Asia

• US Refiners looking to partner