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Green Plastics: An Emerging Alternative for Petroleum Based Plastics Presented By ANTU BHATTACHARJEE BARASAT GOVT. COLLEGE WEST BENGAL STATE UNIVERSITY MSC. 3 rd SEM Reg no.-002559-2013 of 2013 ROLL : BGC/ZOOL NO: 14105 Year-2015

Green plastics :an emerging alternative of petroleum based plastics

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Green Plastics: An Emerging Alternative for Petroleum Based Plastics

Presented By ANTU BHATTACHARJEE

• BARASAT GOVT. COLLEGE

• WEST BENGAL STATE UNIVERSITY

• MSC. 3rd SEM • Reg no.-002559-2013 of

2013• ROLL : BGC/ZOOL NO:

14105• Year-2015

BACKGROUND

• ‘plastic’ is any organic synthetic or processed materials that are mostly thermoplastic or thermosetting polymers of high molecular mass.

• Littering or excessive use, has harmed the image of this useful Product.

problems of conventional plastics

HISTORY OF GREEN PLASTICS

• In 1868 John W. Hyatt invented Celluloid from plant fibers (cellulose).

• After 1907,with the invention of first petroleum based plastic sonly conventional plastic was steadily growing.

Fig: Henry Ford’s soy protein plastic based composites

INTRODUCTION

• Green plastics can be made from many different sources like – (A)Plant Oil, (F)Cellulose, (D)Corn, (B)Starch,(C) Potato Starch, (E)Sugarcane, Weeds etc.

• Examples: Polylactic acids (PLA), Polyhydroxybutyrate(PHB) etc.

PURPOSE OF GREEN PLASTICS

• Applications:Bottling, resins, packaging, etc

• Advantages over conventional plastics:

• 1.Reduces GHG in production

• 2.Requires no petrochemicals.

• 3.Biodegradable

• 4.Multiple end-of-life options

• 5.Reduced carbon footprint

CHARACTERS OF GREEN PLASTICS

• Biodegradable and compostable

• Renewability

• Environmentally friendly nature

FIG: shows Bio-Degradation of Green Plastic.

THE DIFFERENCES AMONG DEGRADABLE, BIODEGRADABLE,

AND COMPOSTABLE• Degradable Plastic:

means that something breaks down.

• Biodegradable Plastic: it can be broken down by the metabolism of micro-organisms.

• Compostable Plastic: means that it biodegrades within a certain amount of time, under certain conditions.

• This Figure shows typical data obtained when the per cent carbon released (as CO2) from a green plastic exposed in a composting environment is plotted as a function of time.

Green Plastics Classification

• Type I: Ex: polymers derived from cellulose.

• Type II: Ex:PHA, PHBV.

• Type III: Ex : PLA

SYNTHESIS OF PLA

PRODUCTION OF PHB

CARBON CYCLE OF GREEN-PLASTICS

SOME FACTS ABOUT GREEN PLASTICS

• Processing Green Plastics Products

• Recycling Issues

• Synthetic Blending

Standards and Certifications for COMPOSTABLE PLASTICS

• In the United States ASTM D-6400 international (ISO-14855).

• Certification from

other countries includes EcoLogo (Canada) and Vincotte (Belgium).

Cost Factor

• additional cost incurred due to increased processing steps.

• In India, the cost of biodegradable plastics is 2- 10 times more than conventional plastics.

DISCUSSIONS

• To promote green-plastics:

• educating the society• Standardizations and

certifications should be publicized.

• Infrastructure for collection and composting needs to be improved.

• Governmental incentives.

CONCLUSION

• society’s current views on environmental responsibility make this an ideal time for further growth of green plastics.

• If the trend continues and the motivation for innovation in this field persists, the results could be promising.

References

• Auras, R.A., Harte, B., Selke, S., & Hernandez, R. (2003). Mechanical, physical, and barrier properties of poly(lactide) films. Journal of Plastic Film & Sheeting, 19(2),123-135.

• Blackburn, R. S. (2005). Biodegradable and sustainable fibers (Ed.). Cambridge,UK: WoodheadPublishing Limited.

• Bregar, Bill (2010, October18). Greenwashing leads to consumer skepticism. Plastics News, pp. 12.• Dartee, M. (2010). It's time to get to know your way around bioplastics. Plastics Technology, 56(3),

18-22. Proceedings of The 2011 IAJC-ASEE International Conferenc ISBN 978-1-60643-379-9• Evans, J. (2010). Bioplastics get growing. Plastics Engineering, 66(2), 14-20 Municipal solid waste in

the United States:2007 Facts and figures(2008).• Greer, D. (2006). Plastic from plants, not petroleum. BioCycle, 47(6), 33-35• Hockensmith, D. (2010, October 4). P&G outlines broad sustainability plans. Plastics News, pp. 1,

20.• Inomata, I. (2009). The current status of bioplastics development in Japan.Bioplastics, 4(1), 42-44.• Khare, A., & Deshmukh, S. (2006). Studies toward producing eco-friendly plastics. Journal of Plastic

Film & Sheeting, 22(3), 193-211.• Knights, M. (2009). Injection molding biopolymers. Plastics Technology, 55(4), 39-48.• Kuruppalil, Z. (2010, November). Plastics packaging: The challenge of going green. Accepted to

publish in The First International Conference on Green and Sustainable Technology conference proceedings, University of North Carolina A & T.

• Patey, W. (2010). Thermoforming pla: how to do it right. Plastics Technology, 56(3),30-31.

References

• Phillips, A.L. (2008). Bioplastics boom. American Scientist, 96(2), 109-110.• Pitzi, T. J. (2010). Injection molding PHA bioplastics: validating moldability for paper mate pens.

Plastics Technology, 56(8), 27-28.• Queiroz, A.U.B., & Collares-Queiroz, F.P. (2009). Innovation and industrial trends in bioplastics.

Polymer Reviews, 49(2), 65-78.• Rustin, D. (2009). Being green can turn into green. PD&F , 30(1), 8-11• Schut, J. H. (2007). Foamed PLA Shows Promise In Biodegradable Meat Trays. Plastics

Technology,(53)12, 39-43.• Schut, J.H. (2007). Extruding biopolymers. Plastics Technology, 53(2), 60-75.• Schut, J.H. (2008). What's ahead for 'green' plastics. Plastics Technology 54(2), 64-89.• Sherman, L. M. (2008). Additives are needed for toughness, heat resistance & processability.

Plastics Technology, 64(7), 58-63.• Siracusa, V., Rocculi, P., Romani, S., & Rosa, M.D. (2008). Biodegradable polymers for food

packaging: a review. Trends in Food Science & Technology,19(12), 634-643.• Stevens, E.S. (2002). Green Plastics: An introduction to the new science of biodegradable plastics.

Princeton, NY: Princeton University Press.• Stevens, E.S. (2002). How green are green plastics?. BioCycle, 43(12), 42.• Stevens, E.S. (2003). What makes green plastics green?. BioCycle, 44(3), 24,4.• Tokiwa, Y., Calabia, B.P., Ugwu, C.U., & Aiba, S. (2009). Biodegradability of plastics. International

Journal of Molecular Sciences, 10(9), 3722-3742.

ACKNOWLEDGEMENT

• I am highly indebted to Dr. Tuhin Saha, Associate Professor of PG Department of Zoology, Barasat Govt. College for giving this review work and his guidance and encouragement throughout this study.

• Sincere thanks to all our respected sirs and madams of the PG Department of Zoology, Barasat Govt. College for giving me the opportunity to present this seminer.