Water-based paint formulations Vol. 4

WATER-BASED PA1 NT FORM U LATIONS

Volume 4

by

Ernest W. Flick

NOYES PUBLICATIONS I np I WesWood, New Jersey, U.S.A.

Copyright 8 1997 by Ernest W. Flick No patt of this book may be reproduced or utilized in any fonn or by any means, electronic or mechanical including photocopying, recording 01 by any information stonge and retrieval system, without permission in Writing from the Publisher.

Library of Congress Catalog Card Number: 75-2939

Printed in the United States ISBN 0-8155-1415-8

Published in the United States of America by Noyes Publications 369 Fairview Avenue Westwood, New Jersey 07675

10 9 8 7 6 5 4 3 2 1

Library of Congress Cataloging-in-Publications Data (Revised for vol. 4)

Flick, Ernest W. Water-based paint formulations.

Vol. 4 published by Noyes Publications. Includes index. 1. Paint--Patents. II. Title.

TP935.F62 1975 66T.63 75-2939 ISBN 0-8155-0571-X (v. 1) ISBN 0-8155-1345-3 (v. 3) ISBN 0-8155-1415-8 (v. 4)

In Memoryof

My Mother and Father

This collection of 232 up-to-date water-based trade and industrial formulations will be of value to technical and managerial personnel in paint manufacturing companies and firms which supply raw materials or services to these companies, and to those interested in less hazardous, environmentally safer formulations. The book will be useful to both those with extensive experience as well as those new to the field. This book includes new and different formulations than those included in the previously published Industrial Water - Based Paint Formulations and Water -Based Paint Formulations.

The data consist of selections of manufacturers' suggested formulations made at no cost to, nor influence from, the makers or distributors of these materials. The information given is presented as supplied; the manufacturer should be contacted if there are any questions. Only the most recent data supplied us has been included. Any solvent contained is minimal.

The table of contents is organized in such a way as to serve as a subject index. The formulations described are divided into sections which cover exterior, interior, and exterior and/or interior water-based paints, enamels, and coatings, as indicated below:

I. Coatings and Topcoats 11. Coil Coatings

111. Enamels IV. Enamels-Baking V. Exterior Paints and Related Products

VI. Interior Paints and Related Products VII. Lacquers VIII. Primers IX. Sealants and Related Compounds X. Stains

XI. Miscellaneous

Each formula has been placed in the chapter which is most applicable. The reader, if seeking a formula for a specific end use, should check each chapter which could possibly apply.

vii

... viii Preface

In addition to the above, there are two other sections which will be helpful to the reader:

XI. A chemical trade name section where trade-named raw materials are listed with a chemical description and the supplier's name. The specifications which the raw materials meet are included if applicable.

XIII. Main office addresses of the suppliers of trade-named raw materials and/or formulations.

Included in the descriptive information for each formulations, where available, the following properties may be listed: viscosity, solids, content, % nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag resistance, scrub stability, freeze-thaw stability, ease of application, gloss foaming, cratering, brightness, opacity, water spotting, adhesion to chalk, brush clean-up, reflectance, and sheen.

Ernest W. Flick

Notice

To the best of our knowledge the information in this publications is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequence arising from, such information. These formulations do not purport to contain detailed manufacturing nor user instruction, and by its range and scope could not possibly do so. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Author or Publisher.

Water-based paint raw materials could be toxic, and therefore, due caution should always be exercised in the use of these hazardous materials. Final determination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We strongly recommend that users seek and adhere to a manufacturer's or supplier's current instructions for handling each material they use.

The Author and Publisher have used their best efforts to include only the most recent data available. The reader is cautioned to consult the supplier in case of questions regarding current availability.

SECTION I: COATINGS AND TOPCOATS . . . . . . . . . . . . . . . . . . . . 1

Clearcoat Modification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

825/Rhoplex CL-104) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Ancamine 2410 High Solids Coating . . . . . . . . . . . . . . . . . . . . . . . . 4

2410/Ancamide 500 High Solids Coating . . . . . . . . . . . . . . . . . . 5

Cured with HMMM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Clear Wood Coating-A & B & C K-Flex UD-320W Modified . . . . 10 Direct to Metal Acrylic Latex Coating Starting Point

Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Low Gloss VinyVABS Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Clear Topcoat for Flexible Substrates . . . . . . . . . . . . . . . . . . . . . . . 12

. . . . . . . . . . 13

Lower Adhesion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Polyphobe Rheology Modifiers Formula C Good Leveling . . . . . 14 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

Acrylic EmulsiodUrea-Formaldehyde Wood

Aliphatic Wood Coating Formulation (Sancure

Exhibit 4 . Starting Formulation Ancamine

Black Single Coat K-Flex XM-4316 PU Dispersion

Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Strippable Coating Sample Formulation A Unmodified Strippable Coating Sample Formulation B

Strippable Coating Formulations Thickened with Ucar

Formula D High Build Strippable Coating for Plastic Substrates . . . . . . . . . . . . . . . . . . . . . 15 Strippable Coating Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Topcoat for Prefinished Hardboard Siding . . . . . . . . . . . . . . . . . . . . 17 Water-Borne Alkyd/Melamine Wood Clearcoat Modification . . . . . . 18 Waterborne Clear High Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . 20 White Gloss Maintenance Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . 21 White Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 Wood Topcoat Model Formulations . . . . . . . . . . . . . . . . . . . . . . . . 23

ix

x Contents and Subject Index

SECTION 11: COIL COATINGS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Chromate Coil-Coating Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Low-Sheen Coil-Coating Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . 26 Medium-Gloss Coil-Coating Topcoat . . . . . . . . . . . . . . . . . . . . . . 27 Strippable Coil Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

SECTION LII: ENAMELS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29 Acrylic Emulsion Enamel-B&C K-Flex UD-320W Modified . . . . . 30 Synergistic Effects of Combining Nacorr with Anti-

Corrosive Pigment in an Air Dry Water Reducible Alkyd Modified Acrylic Enamel . . . . . . . . . . . . . . . . . . . . . . . 31

Ancamide 2353 Fast Drying White Gloss Enamel . . . . . . . . . . . . . . 32 Ancamide 2353 Low VOC White Gloss Enamel . . . . . . . . . . . . . . . 33 Cary Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 Clear Enamel (For Maximum Solvent and Abrasion

Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Gloss Safety Red Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Gloss Safety Yellow Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Gloss White Enamel (Maximum Solvent and Abrasion

Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Green Air Dry Enamel for Flexible Substrates . . . . . . . . . . . . . . . . . 42 High-Hiding Eggshell Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43 MacGregor Gloss Black Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Pinehurst Gloss Green Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Self-Priming Interior Semi-Gloss Enamel . . . . . . . . . . . . . . . . . . . 46 Exterior Maintenance-Type Coating . . . . . . . . . . . . . . . . . . . . . . . . 46 Semigloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Southern Pines Gloss White Enamel . . . . . . . . . . . . . . . . . . . . . . . . 49 Spensol I54 Orange Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 Waterborne Black Enamel Based on Epotuf 37-143/37-680

(Formula No . 3019-28A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 Waterborne Blue Enamel Based on Epotuf 37-143/37-680

(Formula No . 3019-316) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Waterborne Dark Blue Enamel Based on Epotuf

37-143/37-680 (Formula No . 3019-31D) . . . . . . . . . . . . . . . . . 53 Waterborne Green Enamel Based on Epotuf 37-143/37-680

(Formula No . 3019-3lF) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Waterborne Orange Enamel Based on Epotuf 37-143/37-680

(Formula 3019-310 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 Waterborne Red Enamel Based on Epotuf 37-143/37-680

(Formula No . 3019-31B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Waterborne Red Orange Enamel Based on Epotuf

37-143/37-680 (Formula No . 3019-31E) . . . . . . . . . . . . . . . . . 57

Contents and Subject Index xi

Waterborne Yellow Epoxy Enamel Based on Epotuf 37-143/37-680 (Formula No . 3019-31C) . . . . . . . . . . . . . . . . . 58

Whispering Pines Semigloss White Enamel . . . . . . . . . . . . . . . . . . . 59 Anquamine 401 1:l White Gloss Enamel . . . . . . . . . . . . . . . . . . . . 60

Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 Anquamine 401/Solid Resin Dispersion 2:l White

SECTION IV: ENAMELS-BAKING . . . . . . . . . . . . . . . . . . . . . . . . 62 Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Phenolic Clear Bake Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 Clear High Gloss. Baking Finish . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Blue Metallic Urethane Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Experimental Water-Reducible Polyester Gloss White

Baking Enamel Using Halox SZP-391 . . . . . . . . . . . . . . . . . . . 65 Waterborne Acrylic Bake Enamel Water Reducible Polyester Baking Enamel Spensol L54 White Baking Enamel 2-Component Waterborne System . . . . . . . . . . . . . . . . . . . . . . . . . 69

. . . . . . . . . . . . . . . . . . . . . . . . . 66 . . . . . . . . . . . . . . . . . . . 67

. . . . . . . . . . . . . . . . . . . . . . . . 68

SECTION V: EXTERIOR PAINTS AND RELATED PRODUCTS . . . 70 Exterior Flat House Paint with ZnO . . . . . . . . . . . . . . . . . . . . . . . . 71 Exterior Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74 Exterior House Paint . Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . . 75

Exterior Semigloss Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 Exterior Tint Base Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 Exterior Trim Formulation Modified Vinyl Acrylic Paint . . . . . . . . . 79 Exterior Trim Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 Exterior White Flat House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Exterior White Trim house Paint . . . . . . . . . . . . . . . . . . . . . . . . . . 83 Good Quality White Exterior Flat Paint for Masonry . . . . . . . . . . . . 84 Good Quality White Exterior Flat Paint for Wood . . . . . . . . . . . . . . 85 Gregson Drive Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 High Quality Exterior Semi Gloss Paint . . . . . . . . . . . . . . . . . . . . . 87 High Sheen White House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Low VOC Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 Quality Exterior Flat Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 90 Quality Exterior Flat Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91 Quality White Exterior Trim Paint . . . . . . . . . . . . . . . . . . . . . . . . . 92 Quality White House Paint with ZnO . . . . . . . . . . . . . . . . . . . . . . . 94 Urethane Fortified Porch & Deck Enamel . . . . . . . . . . . . . . . . . . . . 95 Weather Barrier Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 White Exterior Flat House Paint with Zinc Oxide . . . . . . . . . . . . . . 97

Exterior Semigloss . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76

xii Contents and Subject Index

White Roof Coating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99

SECI'ION VI: INTERIOR PAINTS AND RELATED PRODUCTS . 100 Clear High Gloss Varnish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 Fast-Dry Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 Economy Flat Wall Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102 Good Quality Interior Flat with <50g/L VOC . . . . . . . . . . . . . . . . 104 High Quality Super Flat Interior Paint . . . . . . . . . . . . . . . . . . . . . 105 Interior Clear Wood Finish (Rhoplex CL-l04/Sancure 815) . . . . . . 106 Interior Sanding Sealer (Rhoplex CL-105) . . . . . . . . . . . . . . . . . . 106 Interior Contractor Flat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Interior Good Quality Flat for Roller and Brush

Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108 Interior Good Quality Flat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110 Interior Semigloss Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 111 Interior Vinyl Acrylic Eggshell for Roller and

Brush Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112 Interior Vinyl Acrylic Semigloss . . . . . . . . . . . . . . . . . . . . . . . . . 114 Intumescent Interior White Fire-Retardant Paint . . . . . . . . . . . . . . 115 Low VOC Interior Flat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 116 Solvent Free Interior Satin Paint . . . . . . . . . . . . . . . . . . . . . . . . . 117 White Interior Eggshell . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118

SECTION VII: LACQUERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 Green Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120

DIY Waterborne Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . 121 White Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122

Foam Control with Agitan Additives in a High Gloss

SECI'ION VIII: PRIMERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 Acrylic Latex Tannin Block Primer Using Halox BW-100 . . . . . . 125 Alkyd Modified Latex Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . 126 Ancamide 2353 Curing Agent Anti-Corrosive Primer . . . . . . . . . . 127 Anquamine 401/Semi-solid Epoxy Dispersion Lead

and Chromate Free Red Iron Oxide Primer 128 Anquamine 401/Solid Resin Dispersion Lead and

Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . 129 Corrosion Inhibitive Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Metal Wash Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130 Cost Effective 2K Water-Base Epoxy Primer Using

Halox SW-111 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131 Dipping Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132 Experimental General Purpose Tannin-Stain Resistant

Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . . 133

. . . . . . . . . . . . . . .

Contents and Subject Index xiii

Experimental High Performance Tannin-Stain Resistant Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . .

Experimental Waterbase Acrylic Red Iron Oxide Primer . . . . . . . . 135 Exterior House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 Exterior House Paint Primer Based on Ucar Latex 163 . . . . . . . . . 139 General Purpose Latex Maintenance Primer . . . . . . . . . . . . . . . . . 140 General Purpose/Low Cost Water-Base Primer . . . . . . . . . . . . . . . 141 High Performance Bare Metal Primer . . . . . . . . . . . . . . . . . . . . . . 142 High Performance Galvanized Metal Primer . . . . . . . . . . . . . . . . . 143 High Performance 2K Water-Base Epoxy Primer 144

Halox SZP-391 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 High Solids Red Iron Oxide Epoxy Primer . . . . . . . . . . . . . . . . . . 147 House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 Lead and Chromate Free Primer . . . . . . . . . . . . . . . . . . . . . . . . . . 149 Lead and Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . 150 Lead and Chromate Free Waterborne Epoxy Primer . . . . . . . . . . . 151 Lead Based Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 Lead Silico Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 Low Sheen Gray Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 Non-Lead/Non-Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . 155

134

. . . . . . . . . . . . . High Performance 2K Water-Base Epoxy Primer Using

Primer for Factory-Primer Hardboard Siding . . . . . . . . . . . . . . . . 156 Primer 20323D Based on Phosguard J-0853 and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 157 Primer 203236 Based on Phosguard J-0813 and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 158 Primer 20596F Based on Heucophos ZPZ and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 159 Primer 20596G Based on Heucophos ZMP and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 160 Primer 21102E Based on Molycoat 212 and 10 AS

Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 161 Primer 21105H Based on Phosguard J-0815 and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 162 Primer 211051 Based on Nalzin 2 and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 163 Primer 21109C Based on Strontium Chromate and 10 ES

Wollastocoat Henkel's Waterpoxy 1401:702 System . . . . . . . . 164 Rapid Dry Waterborne Epoxy Primer . . . . . . . . . . . . . . . . . . . . . . 165 Red Inhibitive Maintenance Primer . . . . . . . . . . . . . . . . . . . . . . . 167 Red Iron Oxide Corrosion Resistant Epoxy Primer (Two

Component System) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168 Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Red Iron Oxide Water Reducible Alkyd Primer . . . . . . . . . . . . . . . 171

xiv Contents and Subject Index

Rust Inhibitive Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . 172 Solvent Resistant. Water-Reducible Epoxy Primer . . . . . . . . . . . . 173 lT-P-1975 Federal Specification Metal Primer . . . . . . . . . . . . . . 174 Universal Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 Universal Primer Non-Lifting and High Salt Spray Resistance . . . . 176 Water-Base Acrylic Universal Primer Using Halox

Water-Base Acrylic Universal Primer Using Halox SZP-391 & Xtain A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178

Waterborne Black Iron Oxide Primer Based on Epotuf 37-143/37-680 (Formula No . 3019-38A) . . . . . . . . . . 179

Waterborne Red Iron Oxide Primer Based on Epotuf 37-143/37-680 (Formula No . 2954-76A) . . . . . . . . . . 180

Waterborne Red Oxide Epoxy Primer . . . . . . . . . . . . . . . . . . . . . . 181 Waterborne Yellow Iron Oxide Primer Based on

Epotuf 37-143/37-680 (Formula No . 3019-39B) . . . . . . . . . . 182 Water Reducible Alkyd Yellow Iron Oxide Primer

Using Halox SZP-391 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 183 Water Reducible Alkyd Yellow Iron Oxide Primer

Using Halox CW-491 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184 Water Reducible Epoxy-Ester Red Iron Oxide Primer . . . . . . . . . . 185 Water Reducible Epoxy-Ester Red Iron Oxide Primer

Using Halox CW-491 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 White. Corrosion Resistant Latex Primer . . . . . . . . . . . . . . . . . . . 188 White Inhibitive Maintenance Primer . . . . . . . . . . . . . . . . . . . . . . 189

SZP-391 & BW-100 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177

SECTION IX: SEALANTS AND RELATED COMPOUNDS . . . . . . 190 Ancamide 2353 Curing Agent Aluminum Mastic . . . . . . . . . . . . . . 191 Clear Sealant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192 High-Quality Exterior Latex Caulk . . . . . . . . . . . . . . . . . . . . . . . 193 Patching Compound (Brushing Grade) . . . . . . . . . . . . . . . . . . . . . 194 Patching Compound (Trowel Grade) . . . . . . . . . . . . . . . . . . . . . . . 195 Pigmented Caulk Formulation based on 2:l Vinyl

AcrylidAcrylic Blend . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 Premium.Performance. Medium-Flexibility Caulk . . . . . . . . . . . . 197 Sealant Application . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 198 Translucent Caulk Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 199 ASTM C-920 Pigmented Caulk Formulation . . . . . . . . . . . . . . . . 200 Translucent Sealant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 Vinyl Acrylic Sealant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 Weather-Barrier Mastic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203

SECTION X: STAINS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 Brown Wiping Stain . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206

Contents and Subject Index xv

Interior Wiping Stain (Emulsion E-2977) . . . . . . . . . . . . . . . . . . . 207

Light Redwood Wiping Stain . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 Stain Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 Tannin Stain Blocking Formulation . . . . . . . . . . . . . . . . . . . . . . . 210 Acrylic Tannin Stain-Blocking Primer . . . . . . . . . . . . . . . . . . . . . 210 Water Reducible Redwood Solid Color Stain . . . . . . . . . . . . . . . . 211

Stain . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207

SECI'ION XI: MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . 212 Anquamine 401 Clear Coat Semi-Solid Epoxy Dispersion . . . . . . . 213 Anquamine 401 Clear Coat Solid Epoxy Dispersion . . . . . . . . . . . 214 Anquamine 401 Liquid Epoxy Clear Coat . . . . . . . . . . . . . . . . . . . 214 Aqueous Polyester-Urethane Pigment Dispersion . . . . . . . . . . . . . 215 Black Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216 Clear Barriernie Coat for Vinyl . . . . . . . . . . . . . . . . . . . . . . . . . 216 Clear Tint Base . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217

Clear Waterborne Cement Sealer . . . . . . . . . . . . . . . . . . . . . . 218 Waterborne Black Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 218 Exterior/Interior Block Filler . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219 High Solids Self Priming Alkyd . . . . . . . . . . . . . . . . . . . . . . . . . . 220 Masonry Block Fill . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221 Masonry Blockfill . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222 Water Reducible Alkyd . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223 2-Component Waterborne System . . . . . . . . . . . . . . . . . . . . . . . . 224

FCA's for Waterborne Building Product Formulations

SECTION XII: TRADE NAMED RAW M A T E W S . . . . . . . . . . . 225

SECTION XIII: SUPPLIERS ADDRESSES . . . . . . . . . . . . . . . . . . 246

2 Water-Based Paint Formulations

A c r y l i c Eaulsion/Urea-Formaldehyde Wood C l e a r c o a t M o d i f i c a t i o n

K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e r e s i n m o d i f i e r . T h i s u re thane d i o l m o d i f y i n g r e s i n i m p a r t s improved s t a i n r e s i s t a n c e t o t h e f o r c e d d r y ( thermoset ) wood c l e a r c o a t fo rmul a t i on b e l ow.

What makes t h i s f o r m u l a t i o n unique, i s t h e absence o f n e u t r a l - i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used (Nacure 155) and lower tempera ture c u r e s may be ach ieved. A p o t l i f e of 24-48 hours i s p o s s i b l e .

WB Wood C l e a r c o a t Component: B e e t l e 65 Methanol S i l w e t t L-77 Rhopl ex AC-1024 Water Exxate 700 Chemcor AS-35-3 K-Flex UD-320W Nacure 155 Methanol

M o d i f i c a t i o n : 0%

24.5 2 .4 0 . 4

49.2 7.2 1 . 4 4.1 0.0 4.9 5 .9

%K-Flex UD-320W - 5% 10%

24.5 24.5 2 .4 2 . 4 0 . 4 0 . 4

44.2 39.3 9 . 4 11 .5 1 .4 1 . 4 4 . 1 4 .1 2 .8 5 .5 4 .9 4.9 5.9 5 .9

F o r m u l a t i on Procedure: 1 . The components were added i n t h e o r d e r as p resented , f o r

eas i e r i n c o r p o r a t i on. 2 . The Nacure 155 c a t a l y s t was p r e - d i l u t e d w i t h t h e methanol

be low i t i n t h e f o r m u l a t i o n b e f o r e i n c o r p o r a t i o n , w i t h a Nacure 155/Methanol r a t i o o f 45 .5 /54 .5 .

S u b s t r a t e : B i r c h Faced Plywood S e a l e r : S e l f Sealed ( 2 Coats, 2 bakes) Sealer /Topcoat , WFT: 20-25u (0 .8 -1 .0 m i l ) / C o a t Sealer /Topcoat Bake: 10 min./71C (160F)

4 Hour Spot T e s t S t a i n T e s t : 0% UD-320W 10% UD-320W Acrylic/UD-320W/B-65 50/0/50 40/10/50 C o f f e e Severe Haze L i g h t S t a i n M i l k Severe Haze No E f f e c t Mustard Water Lemon J u i c e

No E f f e c t L i g h t S t a i n Severe Haze No E f f e c t S l i g h t Haze No E f f e c t

No e f f e c t was seen i n t h e 4 hour s p o t t e s t i n any o f t h e f o r m u l a t i o n s w i t h ketchup, n a i l p o l i s h remover, i s o p r o p a n o l , l i q u i d c l e a n e r o r l i p s t i c k .

160F r e s u l t e d i n an H p e n c i l hardness and 100+ MEK doub le rubs .

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-26

Drawdowns made o v e r Aluminum p a n e l s and baked 10 minu tes a t

Coatings and Topcoats 3

A l i p h a t i c Wood Coat inn Formula t ion JSancure 825 /Rho~ lex CL-104)

61 end : Rhoplex CL-104 (38% S o l i d s ) Water

Add f o l l o w i n g w i t h good a g i t a t i o n :

Dowanol DPM Hexyl C a r b i t o l

Mix 10-15 minutes

Sancure 825 (34% S o l i d s ) Su r fac tan t Package (Premix t h e f o l l o w i n g ) :

Sur fyno l 104H Sur fyno l DF-l1OL

Minera l S p i r i t s Sur fyno l DF-70

DC-14

Add and mix 30 minutes

Pounds 134.2

33.8

12.75 2.55

100.0

2.6 1 . 3 1 .3 1 .3 0.7

Adjus t t o des i red v i s c o s i t y us ing Acrysol RM825 (Rohm & Haas Co.) I f requ i red , f l o w i s enhanced by a d d i t i o n o f very low l e v e l s o f

F luorad FC-129 (3M Corp.) as a 10% s o l u t i o n i n water. NOTE: Avoid excessive use o f f luorocarbons , as sharp sur face

tens ion drops can cause recoat problems and s t rong foaming tendencies.

Always a d j u s t t o des i red v i s c o s i t y range p r i o r t o eva lua t i ng f l o w / l e v e l and deaera t ion p r o p e r t i e s . Low v i s c o s i t y can y i e l d “Picture-Framing‘ ‘ and/or a “ F i sh-Eye“ e f f e c t . High v i s c o s i t y can y i e l d poor deaera t ion p r o p e r t i es.

Sur fyno l a d d i t i v e s have been shown t o p rov ide t h e f o l l o w i n g benef i t s :

*Color u n i f o r m i t y o f s t a i n s *Ear l y s t a i n 1 appi ng res i s tance *Consistent we t t i ng , f l o w and l e v e l i n g on va r ious woods *Foam c o n t r o l

Wi th no de t r imen ta l e f f e c t upon: *Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *Gloss r e t e n t i o n upon aging *Tannin b leed r e s i stance *Water s e n s i t i v i t y *Chemical res i s tance

SOURCE: A i r Products & Chemicals, I n c . : Sur fyno l Su r fac tan ts : Formula t ion A ( B . F . Goodrich)


Ancamine 2410 H i g h S o l i d s C o a t i n g

A S i d e : DER 331 TS 610 50% FC430 i n Xy lene

D ispe rse , t h e n reduce speed

S t a i n l e s s s t e e l f l a k e BYK 320 Aromat i c 100

B S i d e : Ancami ne 241 0 E t h y l A l c o h o l

D i s s o l v e , t h e n add:

C a b o s i l T S 720 W o l l a s t o c o a t 10ES

D i s p e r s e t o 6 n . s . u .

Me thy l E t h y l Ketone

T y p i c a l P r o p e r t i e s : Non V o l a t i l e by We igh t : 0 .75 Non V o l a t i l e by Volume: 0 . 6 0 PVC: 0 . 1 6 C P V C : 0 . 3 4 PVC/CPVC: 0 . 4 8 P i gment Con ten t : 0 .30 NVV on V e h i c l e : 0 . 6 4 VOC g /1 : 3 2 7 . 9 VOC l b s / g a l : 2 . 7 4

& 330.9

7 3 .5

176

79 7 . 1

1 5 0 . 5 37 .7

8 .8 133.3

152.3

Wei gh t /Ga l l o n Comp A : We igh t /Ga l l on Comp 0 : M i x i n q R a t i o : 1 : l

Gals 34 .1

0 . 4 0 . 4

3 . 2 1

1 0 . 9

1 5 . 5 5.8

0 . 5 5 . 5

22 .7

1 2 . 0 6 9 . 6 5

Weight p e r G a l l o n : 1 0 . 8 5 I n i t i a l V i s c o s i t y : 580 cP Pot L i f e : 4 . 5 h r Dry t o Touch: 0 .75 h r Dry Hard: 4 h r

Ancamine 2410 Chemical Res is tance : 7 Day Immers ion R e s u l t s :

Reagent : Acetone Cyclohexanone PM A c e t a t e E t h y l A c e t a t e E thano l I sodecano l A romat i c 100 To1 uene DMF TH F EP

R e s u l t : No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t

Reagent: NMP C1 o r o x S kyd r o 1 50% c a u s t i c 10% c a u s t i c 6% HC1 : S u l f u r i c : A c e t i c A c i d D i e t h y l ami ne 50% phenol i n x y l e n

R e s u l t : No E f f e c t N o E f f e c t No E f f e c t No E f f e c t No E f f e c t No E f f e c t 81 i s t e r e d 81 i s t e r e d B l i s t e r e d 0 1

i e D 0 4

SOURCE: A i r P roduc ts and Chemicals , I n c . : Ancamine 2410 C u r i n g Agent : E x h i b i t 3 F o r m u l a t i o n


E x h i b i t 4 - S t a r t i n g Formul-at ion Ancarni ne 241 O/Ancami de 500 High. Sol i d s C o a t i n g

A S i d e : DER 331 C a b o s i l TS-610

Lbs Ga ls 284.6 29.3

7.6 0.43

D i s p e r s e a t H i g h Speed Reduce Speed, t h e n add:

A1 umi num L243 106 8.59

When u n i f o r m l y mixed, add:

E p o d i l 759 S F 69

B S i d e : Ancami ne 241 0 B e e t l e 216-8 Ancamide 500 E t h y l A l c o h o l M e t h y l E t h y l Ketone n B u t y l A l c o h o l E t h y l A l c o h o l

T y p i c a l P r o p e r t i e s : Non V o l a t i l e by Weight : 0.72 Non V o l a t i l e by Volume: 0.64 PVC: 0.056 CPVC: 0.31 PVC/CPVC: 0.17 Pigment Con ten t : 0.09 NVV on V e h i c l e : 0.7 VOC g / l : 290.53 VOC l b s / g a l : 2.43

86.3 11.64 0.3 0.04

77.67 8.00 22.7 2.60 81.8 10.34 29.1 4.44 73.9 11.01 81.7 12.10 9.8 1.49

Weigh t /Ga l l on Comp A : 9.68 W e i g h t / G a l l o n Comp 0: 7.53 M i x i n g R a t i o : 1:l Weight p e r G a l l o n : 8.61 I n i t i a l V i s c o s i t y : 270 C P Pot L i f e : 3 h r Dry t o Touch: 1.5 h r Dry Hard: 4 h r

C o r r o s i o n Resi s tance : E x h i b i t 4 i s a p r e l i m i n a r y s t a r t i n g f o r m u l a t i o n combi n i ng

Ancamine 2410 c u r i n g agen t w i t h Ancamide 500 c u r i n g agen t as t h e B s i d e . C o r r o s i o n r e s i s t a n c e i s v e r y good. C l e v e l a n d h u m i d i t y t e s t i n g showed no a t t a c k a f t e r 700 h o u r s . S a l t s p r a y r e s u l t s on g r i t b l a s t e d s t e e l showed no a t t a c k i n t h e f i e l d and m ino r a t t a c k a t t h e s c r i b e (8 r a t i n g ) a f t e r 700 h o u r s .

SOURCE: A i r P r o d u c t s and Chemicals , I n c . : Ancamine 2410 C u r i n g Agent: E x h i b i t 4

6 Water-Eased Paint Formulations

B l a c k S i n g l e Coat K-Flex-XM-4316 P U - D ~ s p e r s l o n Cured w i t h HMMM

F o r m u l a t i o n WR-40 i s a h i g h pe r fo rmance h i g h g l o s s b l a c k f o r m u l a t i o n based on K-Flex XM-4316 p o l y e s t e r - u r e t h a n e d i s p e r s i o n c r o s s l i n k e d w i t h an amino r e s i n . The f o r m u l a t i o n o f f e r s a h i g h g l o s s c o a t i ng

Component: Pigment G r i n d Pas te , P a r t 1 : K-F1 ex XM-2311 Water , d e i o n i z e d D ime thy le thano lamine ( 1 ) Monarch 1300 K-Sperse 152 MS D ime thy le thano lamine ( 2 ) Pigment Paste, P a r t 2 : K-F lex XM-2311 K-F1 ex XM-4316 Water, d e i o n i z e d Pigment Paste K-F1 ex XM-4316 Water d e i o n i zed Resimene 747 Nacure 2547 S i l w e t L7604/L7605 ( 1 : l ) 25% i n H20 Water as r e q u i r e d f o r v i s c o s i t y ad jus tmen t F o r m u l a t i o n C h a r a c t e r i s t i c s :

Resi n/HMMM, r a t 1 0 : 75/25 N o n v o l a t i l e , c a l c u l a t e d , 'YO: 39.0 T h e o r e t i c a l VOC, g /L , ( l b / g a l l o n ) : 145, ( 1 .23 )

B r o o k f i e l d V i s c o s i t y , 25C, s p i n d l e #16, 60 rpm, c p . :

Cure Schedule, t empera tu re , t i m e : 150C, 15 m i n u t e s Dry F i l m Th ickness , m i l , ( m i c r o n ) : 1 . 0 ( 2 5 ) G loss , 60, 20, 90: 91, 81

pH: 7 . 8 - 8 . 3

F i l m P r o p e r t i e s : S u b s t r a t e , aluminum

% W t

2 . 4 0 2 .95 0 .15 1 . o o 0 .07 0 . 1 0

1 .20 1 . 2 0 1 . 1 0

10.17 63 .95

6 . 2 0 9 . 5 5 0 . 1 3 0 .40 9 . 6 0

300-500

F o r m u l a t i o n No tes : Pigment G r i n d Pas te P a r t 1 : B l e n d t h e K-Flex XM-2311 p o l y u r e t h a n e d i s p e r s a n t r e s i n w i t h wa te r and d i m e t h y l e t h a n o l a m i n e ( 1 ) and add t h e carbon b l a c k , p remix and add t h e b l e n d o f K-Sperse w i t h d i m e t h y l e t h a n o l a m i n e ( 2 ) , check t h e pH and add more d i m e t h y l e t h a - no lamine i f pH i s be low 9.2, d i s p e r s e i n a s t e e l b a l l m i l l t o Hegman NS 8 r a t i n g . Pigment Pas te P a r t 2 : A f t e r g r i n d i n g i n t h e s t e e l b a l l m i l l add t h e a d d i t i o n a l K-Flex XM-2311, XM-4316 and w a t e r t o t h e b a l l m i l l , r u n f o r an a d d i t i o n a l 30 m i n u t e s . The p igment c o n c e n t r a t e i s s t a b l e . A f t e r l o n g e r a g i n g a d d i t i o n o f s m a l l amounts o f amine f o r pH ad jus tmen t m i g h t be r e q u i r e d . Letdown Formula: L e t t h e p igment p a s t e down under a g i t a t i o n w i t h remainder o f K-Flex XM-4316, w a t e r , melamine c r o s s l i n k e r and c a t a l y s t . Add t h e s i l i c o n e s u r f a c t a n t and use t h e remainder o f t h e w a t e r f o r v i s c o s i t y a d j u s t m e n t s . F i n a l pH o f t h e f o r m u l a - t i o n s h o u l d be between 7 .8 t o 8 . 3 . SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-40


Clear Bake Coat ing

Ma te r i a1 : E p i -Re2 3522-W-60 Resin

~ _ _ _ Pounds Gal 1 ons 637.50 69.29

Thoroughly p re -n i x t h e f o l l o w i n g and add t o t h e above under g e n t l e a g i t a t i o n .

Cyme1 324 B u t y l O x i t o l G lyco l Ether 2-Propoxyethanol BYK-301 A n t i - c r a t e r i n g agent Syntex 3981 Acce le ra to r

53.10 5.71 22.50 3.00 40.20 5.00

2.00 0.25 2.75 0.37

Blend thorough ly . D isso lve f o l l o w i n g by warming t o 150F.

Add t o above under a g i t a t i o n be fo re a l l o w i n g t o coo l .

O i cyandi ami de Dei on i zed water

Typ ica l Coat i ng Proper t i es : % N o n - v o l a t i l e - we igh t : 48.5

- volume: 43.2 V i s c o s i t y : 57 K .U . pH: 7.0 Pounds/Gallon: 9.05

V o l a t i l e Composit ion:

Water Organics

V o l a t i l e Organic Compounds (VOC): Pounds/Gallon: 1.46 Grams/Li t e r : 175

13.50 0.41 133.00 15.97

_ _ _ _ _ _ Pounds Ga l lons 388.0 46.50

62.7 8.00

F i l m P roper t i es : * Bake Schedule: Penc i l Hardness Reverse Impact, i n . - l b s .

160 160 160 160

5 min. a t 450F 4H 30 min. a t 400F 5H 15 min. a t 400F 5H 30 min. a t 350F 4H

* F i lms cas t #42 Myra Bar (0.75 m f l a s h .

SOURCE: She1 1 Chemical Co. : S t a r t E p i -Rez 3522-W-60 Resin

1 . ) on bonder i t e 1000; 10 min.

ng Formula t ion No. 2500:


Clear Bake Coat inq Ma te r i a1 : Pounds Epi -Rez 3551 -WY-43 Resi n 756.0

Add under a g i t a t i o n : Ektapro EEP Bee t le 80 Water Typ ica l Coat ing P roper t i es :

To ta l Weight So l i ds , %: 47.5 To ta l Volume So l i ds , %: 41.8 Pounds/Gallon: 8.96 Epoxy/Urea, based on s o l i d s V o l a t i l e Organic Compounds

Pounds/Gal l o n : 1 .85 Grams/Li t e r : 222

V i s c o s i t y , B r o o k f i e l d #5 Sp

Dry F i l m Thickness: 1 .0 m i l Subs t ra te : Bonder i te 1000

Typ ica l F i l m Proper t i es :

21.2 86.8 31.5

%: 80/20 VOC) :

nd le , 20 rpm, cps: 1,400

Gal l ons 84.00

2.68 9.54 3.78

Bake Schedule a t 350F, minutes: 20 Penc i l Hardness: 3H Reverse Impact, i n . l b s . : 80

S t a r t i n g Formula t ion No. 2501: Epi-Rez 3551-WY-43 Resin

Pheno l ic C lear Bake Coat ing Pounds Ga l lons Mater i a1 :

Water 115.5 13.87

Methylon 75108 162.5 16.75 B u t y l O x i t o l G lyco l Ether 48.8 6.50 n-Buty l Alcohol 43.9 6.50 Syntex 3981 Acce le ra to r 58.1 7.90 Typ ica l Coat ing P roper t i es :

~~

Epi-Rez 3540-WY-55 Resin 442.9 48.48

Premix and add s low ly under a g i t a t i o n :

To ta l Weight So l i ds , %: 46.6 To ta l Volume So l i ds , %: 31.0 Pounds/Gallon: 8.72 Epoxy/Phenolic: 60:40 C a t a l y s t , a c t i v e on r e s i n s o l i d s , %: 3.3 V o l a t i l e Organic Compounds (VOC):

Pounds/Gallon: 2.68 Grams/Li t e r : 322

V i s c o s i t y , #4 Ford Cup, seconds: 40-60 pH: 6 .4 Reduction f o r Conventional Spray A p p l i c a t i o n : None

Dry F i l m Thickness: 0 . 4 m i l s Subs t ra te : Bonder i te 1000 Bake Schedule: 15 min. a t 450F Penc i l Hardness: 9H Reverse Impact, i n . l b s . : > I60 MEK Resistance, double rubs: 100

Typ ica l F i l m Proper t i es :


SOURCE: She l l Chemical Co.: S t a r t i n g Formulat ions


Clear Bake Coat ing

Ma te r i a1 : Epi -Rez 3540-WY-55 Resin Water Premix and add: Bee t le Urea Formaldehyde Resin n -Buty l A lcoho l Syntex 3981 Acce le ra to r

Pounds 579.6 113.7

8 0 . 7 43.2 55.9

Gal l o n s 63.42 13.65

8.92 6.40 7.61

Typ ica l Coat ing P roper t i es : To ta l Weight So l i ds , %: 45.7 To ta l Volume So l i ds , %: 42.6 Pounds/Gallon: 8.73 Epoxy/Urea: 80/20 C a t a l y s t , % ( A c t i v e on r e s i n s o l i d s ) : 2 V o l a t i l e Organic Compounds (VOC):

Pounds/Gal 1 on: 2.19 Grams/Li ter : 263

V i s c o s i t y , #4 Ford Cup, seconds: 60-80 pH: 7.1


Pheno l ic C lear Bake Coat ing

Ma te r i a1 : Par t A: Epi -Rez 3551 -WY-43 Resin Premix and add under a g i t a t i o n : Santol i nk EP560 Ektapro EEP Add under a g i t a t i o n : Water

_ _ _ _ _ _ Pounds Gal 1 ons

662.1 73.56

93.1 10.18 80.6 10.16

5 0 . 8 6.10

Typ ica l Coat i ng P r o p e r t i es : To ta l Weight So l i ds , %: 42.0 To ta l Volume So l i ds , %: 36.6 Pounds/Gallon: 8.87 Epoxy/Phenolic, based on s o l i d s , percent : 80/20 V o l a t i l e Organic Compounds (VOC):

Pounds/Gal 1 on: 2.90 Grams/Li ter : 348

V iscos i t y , #4 Ford Cup, seconds: 70-80

Dry F i l m Thickness: 0 . 5 m i l Subs t ra te : Bonder i te 1000 Bake Schedule a t 350F. minutes: 20 Penc i l Hardness: 5H Reverse Impact, i n . l b s . : s160 MEK Resistance, Double Rubs: 100

Typi c a l F i 1 m Proper t i es :

S t a r t i n g Formula t ion No. 2505: €pi-Rez 3551-WY-43 Resin

SOURCE: S h e l l Chemical Co. : S t a r t i n g Formulat ions


C l e a r Wood Coat inQ-A & B 8 C _- K-F1 ex UD-320W Modi f i e d

The f o l l o w i n g wood c o a t i n g f o r m u l a t i o n e v a l u a t e s K-Flex UD-320W a t 5 and 10% m o d i f i c a t i o n on s o l i d s . The system was c a t a l y z e d w i t h K-Cure 129W. Cure response was examined on c l e a n b a r e and 840 t r e a t e d Aluminum a t a r a p i d schedu le o f 60 sec./82C. Hardness improvements were found a t a l l l e v e l s o f m o d i f i c a t i o n (See f i l m p r o p e r t i e s ) . The t r e a t e d s u b s t r a t e gave s o f t e r f i l m s i n i t i a l l y compared t o b a r e m e t a l , but improved p r o p e r t i e s were observed a f t e r 24 h o u r s a g i n g . K-Flex UD-320W m o d i f i c a t i o n i n c r e a s e d f i l m hardness b u t d i d n o t improve w a t e r r e s i s t a n c e p r o p e r t i e s

Formul a t i on : Rhoplex AC-1024 B e e t l e 65 K-Flex UD-320W

K-Cure 129W

A c r y l i c / P o l y o l / U r e a % S o l i d s

F i l m P r o p e r t i e s :

FC-430

S u b s t r a t e : Aluminum (C lean Bare) Cure: 60 sec./82C F i l m Th ickness : 0 . 7 + - 0 . 1 m i l DFT

W* 66 .7 33.3

0 . 0 0 . 1 3 1 . 7

SO/-/50 6 6 . 7

A : 50,’-/50 I n i t i a l 24 Hours

0 : 45/5/50 I n i t i a l 24 Hours

C : 35/10/55 I n i t i a l 24 Hours

Penci 1 KHN25

HB-F 4.19 F-H 11.20

HB-F 6 . 2 5 H-2H 14 .20

HB-F 5.41 H-2H 15.50

W- Wt%C 61 .8 51 .4 34 .3 40 .4

3 . 9 8 . 2 0 . 1 3 0 .13 1 . 7 1 .8

45/5/50 35/10/55 6 7 . 5 72.2

Crossha tch Adhesion

MEK Rubs (%Loss)

200 0 200 0

200 0 200 0

180 0 200 0

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-10 A & B & C


I n g r e d i e n t s : Resin Phase: Water Maincote PR-71 Ammonia (28)

D i r e c t t o Meta l A c r y l i c La tex Coat ing S t a r t i n a P o i n t Formula t ion

Lbs Gals

45.9 5.510204

2.05 0.273333 481.2 55.31034

Set as ide f o r l a t e r a d d i t i o n , i n t o a separate vessel add:

Water Phase: Water Bentone AD Tamol 165 Drewpl us L-493 B u t y l Cel l o s o l v e D i b u t y l Ph tha la te Ammonia (28)

Premix:

Chrom. Grn. Oxide 5-5310 A c t i r o x 215 Nyad 1250

Disperse t o 5 n .s .u . Then homogenization, add, whi

E t h y l A lcohol 15% NaN02 i n Water 20% QR-708 i n Water

150 1.4

11.2 1

36.6 7.3 n

47.9 89.8

116.3

l e t down w i t h r e s i n phase e mix ing , t h e f o l l o w i n g :

18 3.06

12.75

18.00720 0.064641 1.222707 0.133155 4 .a73501 0.8371 55 0.4

1.078828 3.368847 4.805785

4 f t e r

2.748091 0.337375 1 .514251

General Performance Benef t s : E x c e l l e n t adhesion t o s t e e l , ga lvanized s t e e l and aluminum S u i t a b l e f o r s i n g l e coat s e r v i c e Excel 1 ent recoatab i 1 i t y w i t h s o l v e n t based f i n i s h e s High r e s i s t a n c e t o s a l t spray, 3000 hours f rom 2 d r y m i l s on

Appl i cab1 e under margi na l c o n d i t i o n s (40F) c o l d r o l l e d s t e e l

SOURCE: Nyco Minera ls , I n c . : Suggested Formulat ion


Low Gloss Vinvl/ABS Topcoat

Mater i a1 Spensol L53 D i sperse-Ayd Sur fyno l 104H Fl a t t i ng Agent TS100 Lodyne S107B

Lbs. Gals . 808.7 92.85

6 .6 0.75 6.0 0.75

25.0 1 .so 1 .4 0.15

Disperse a t h igh speed f o r 15-20 minutes, then premix and add:

M i cheml ube 737 Water

Anal y s i s: Percent Sol i d s , Weight : 31 .8 Percent So l i ds , Volume: 28.4 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25 Gloss (60/20): 7/4

VOC (exc lud ing water ) : Grams/Li t e r : 288 Pounds/Gal 1 on : 2.4

pH: 8.0-8.5

Formula t ion 2124-54C

16.4 2.0 16.7 2.0

C lear Topcoat for F l e x i b l e Subst ra tes

Ma te r i a1 : Spensol L53 Sur fyno l 104H C o l l o i d 679 Ucar SCT 100 M i cheml ube 737 Water

Lbs. Gals. 826.5 95.00

4 . 0 0.50 1.9 0.25 2.3 0.25

16.4 2.00 16.7 2.00

Add t h e above m a t e r i a l s i n o rder under good a g i t a t i o n . NOTE: An o p t i o n a l a z i r i d i n e c r o s s l i n k i n g agent can be added t o

t h e above formula a t a l e v e l o f 7-10 lbs . /100 ga l l ons .

Ana lys is : Percent Sol i ds , Wei gh t : 29.8 Percent So l i ds , Volume: 28.6 V i s c o s i t y @ 25C, #4 Ford, Secs.: 65+-5 Pounds/Gallon: 8.7

VOC (exc lud ing water ) : Grams/Li ter : 374 Pounds/Gallon: 3.1

PH: 8 .5 t -0 .3

Formula t ion 2307-248

SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulat ions


S t r i p p a b l e C o a t i n g Sample F o r m u l a t i o n A _____ Unmodi f i ed

I n n r e d i e n t s : Ucar La tex 447

Ucar F i l m e r IBT Foamaster VF Water

C o a t i n g P r o p e r t i e s :

AMP-95

V i s c o s i t y , cP: 1060 Stormer V i s c o s i t y , KU: 70 pH Value: 6 .6 T o t a l S o l i d s , % by w e i g h t : 59 .3

Pounds 797.3

2 . 1 47 .5

2.1 40 .9

S t r i p p a b l e C o a t i n q Sample F o r m u l a t i o n B - Lower - Adhesion

I n q r e d i e n t s : Ucar La tex 447 AMP-95 Ucar F i l m e r IBT Foamaster VF Soya L e c i t h i n Water

C o a t i n g P r o p e r t i e s : V i s c o s i t y , cP: 1820 Stormer V i s c o s i t y , KU: 83 pH Value: 6 . 7 T o t a l S o l i d s , % by w e i g h t : 60 .3

S u b s t r a t e S t r i p p a b i 1 i t y : S u b s t r a t e : Ga lvan ized S t e e l A1 -Bonderi t e A1 -A1 o d i ne Co ld R o l l e d S t e e l My1 a r G1 ass P o l y s t y r e n e Gloss A1 kyd P o l y e s t e r

X=peeled c l e a n and eas i l y

_ _ ~ Pounds 777.0

2 . 1 46.7

2.1 20 .0 41 .1

G a l l o n s 88 .54

0 .27 6 .01 0 .27 4 .91

G a l l o n s 86.33

0 .27 5.91 0.27 2 .29 4.93

Formula A X X X X X X X X X

Formula B X X X X X X X X X

SOURCE: Ucar Emuls ion Systems: Ucar La tex 447: F o r m u l a t i o n s A & B


S t r i p p a b l e Coat ina Formula t ions Thickened w i t h Ucar Polyphobe Rheology M o d i f i e r s

Formula C Good Leve l i ng

Pounds Gal l ons I n g r e d i e n t s : Ucar Latex 447 780.9 06.77 AMP-95 4.4 0.57 Ucar F i lmer IBT 46.8 5.95 Foamaster VF 2.1 0.28 Water 40.6 4.89 Ucar Polyphobe 107 13.4 1.54

~~

Coat ing P roper t i es : V i s c o s i t y , cP: 2500 Stormer V i s c o s i t y , KU: 104 pH Value: 8.1 To ta l So l i ds , % by we igh t : 60.1

Formula D H igh B u i l d

I n g r e d i e n t s : Ucar Latex 447

Ucar F i lmer IBT Foamaster VF Water Ucar Polyphobe 102

Coat ing P roper t i es :

AMP-95

V i s c o s i t y , cP: 3200 Stormer V iscos i t y , KU: 84 pH Value: 8.9 To ta l So l i ds , % by we igh t : 58.8

Subst ra te S t r i p p a b i 1 i t y : Subs t ra te : Galvanized Stee l A1 -Bonderi t e A1 -A lod i ne Cold Ro l l ed Stee l Mylar G1 ass Po lys ty rene Gloss A lkyd Po lyes ter

X=peeled c lean and e a s i l y NT=not

~~ Pounds Gal 1 ons 702.7 06.97

4 .8 0.62 46.9 5.94

2.1 0.27 40.6 4.07 11.6 1.33

Formula C Formula D X X X X NT NT X X X X X X NT NT X X NT NT

t e s t e d

SOURCE: Ucar Emulsion Systems: Ucar Latex 447: Formulat ions


S t r i p p a b l e C o a t i n q f o r P l a s t i c S u b s t r a t e s

I n q r e d i e n t s : Premix #1 :

Ucar V e h i c l e 441 Defoamer (1 ) Soya L e c i t h i n (2)

Premix #2: T r i o c t y l Phosphate S t r i p p i n g A i d (3) Water

Premix #3: T h i c k e n e r (4) Water

Premix #4: T r i e t h y l a m i n e I s o p r o p a n o l , 91% Water

Water

Pounds

603.8 9.1 10.1

40.2 13.9 39.2

27.1 27.2

7.2 8.6 14.3 48.3

Gal l o n s Wt%

69.80 71.12 1 .31 1.07 1.16 1.19

5.22 4.74 1.47 1.64 4.71 4.62

3.10 3.19 3.26 3.20

1.18 0.85 1.27 1.01 1.72 1 .68 5.80 5.69

i e r s : ) Defoamer - P a t c o t e 513 ( P a t t e r s o n Chemical ) o r e q u i v a l e n t . ) Soya L e c i t h i n - K e l e c i n 1081 (Spencer K e l l o g g ) o r e q u i v -

a1 e n t . e q u i v a l e n t .

(3) S t r i p p i n g A i d - S t rodex PK-90 ( D e x t e r Chemicals) o r

(4) T h i c k e n e r - A c r y s o l ASE-60 (Rohm and Haas) o r e q u i v a l e n t .

Procedure: B lend Premix #1 f i r s t , i n t h e o r d e r shown, and t h e n add t h e

r e m a i n i n g Premixes i n numer i ca l o r d e r . A l l o w f i v e t o 10 minu tes o f a g i t a t i o n between a d d i t i o n s o f Premixes. The l a s t i nc remen t o f w a t e r , shown below Premix #4, can b e added i n s tages t o a l l o w p r o p e r a g i t a t i o n .

C o a t i n g P r o p e r t i e s : T o t a l S o l i d s , % by w t : 40.1 p H : 8.6 V i s c o s i t y , B r o o k f i e l d , cP: 2410 V i s c o s i t y , S to rmer , KU: 84 Heat-Age S t a b i l i t y , 2 wk a t 12OF: Pass Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass

SOURCE: Ucar Emuls ion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n Sugges t ion LP-1924


S t r i p p a b l e C o a t i nq F o r m u l a t i o n s

I n q r e d i en t-s : Ucar V e h i c l e 441 Th ickener ( 1 ) (11% N . V ) B u t y l C a r b i t o 1 Sol v e n t Water C o a t i n g P r o p e r t i e s :

Weight p e r G a l l o n , l b : 8 . 6 p H 8 . 0 T o t a l S o l i d s , % by w t : 43 .8

Formul a t i on LP-3760 I n g r e d i entg: Ucar V e h i c l e 441 Th ickener ( 1 ) ( 1 1 % N.V.) B u t y l Carb i t o 1 S o l v e n t Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water C o a t i n g P r o p e r t i e s :

Weight p e r G a l l o n , l b : 8 .6 p H : 8 . 0 T o t a l S o l i d s , % by w t : 44.4

F o r m u l a t i o n LP-3761 I n g r e d i e n t s : i c a r V e h i c l e 441 Th ickener ( 1 ) (11% N.V . ) B u t y l C a r b i t o l S o l v e n t Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water C o a t i n g P r o p e r t i e s :

Weight p e r G a l l o n , l b : 8 . 6 pH: 8 . 0 T o t a l S o l i d s , % by w t : 44 .6

F o r m u l a t i o n LP-3762 I n g r e d i e n t s : Ucar V e h i c l e 441 Th ickener ( 1 ) (11% N.V . ) B u t y l C a r b i t o 1 S o l v e n t Soya L e c i t h i n W e t t i n g Agent ( 2 ) Water C o a t i n g P r o p e r t i e s :

Weight p e r G a l l o n , l b : 8 .6 pH: 8 . 0 T o t a l S o l i d s , % by w t : 45.0

F o r m u l a t i o n LP-3763

~- Pounds 840.0

5 . 4 8 . 4

10.0

-~ Gal 1 ons 9 7 . 1

0 .7 1 . o 1 . 2

Pounds Gal 1 ons 830.0 9 5 . 9

5 .4 0 . 7 8 . 4 1 . o 6 . 6 0 . 8 3.3 0 . 4

10 .0 1 . 2

Pounds G a l l o n s 827.0 9 5 . 6

5 .4 0 . 7 8 . 4 1 . o

10 .0 1 . I 3 . 3 0 . 4

1 0 . 0 I . 2

Pounds Gal 1 ons 820.0 94 .8

5 . 2 0 . 6 8 . 2 1 . o

16.4 1 . 9 3 .3 0 . 4

1 0 . 7 1 . 3

Suppl i e r s : ( 1 ) Th ickener - A c r y s o l G-110 (Rohm and Haas) o r e q u i v a l e n t . ( 2 ) W e t t i n g Agent - I n t e r w e t #33 ( I n t e r s t a b ) o r e q u i v a l e n t .

No te : I n c l u d e a s u i t a b l e p r e s e r v a t i v e i n each f o r m u l a s u g g e s t i o n .

SOURCE: Ucar Emuls ion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n s


Topcoat f o r Pre f i n i shed Hardboard S i d i n g

Inq red ien ts : PiQment O r 4 nd: Water T e r g i t o l Nonionic Sur fac tan t Tamol 731 Foamaster VF T i -Pure R-960 Nyta l 400 S i l c r o n G-601 Nuocide 960

Letdown : Ucar Veh ic le 462 Cyme1 325 Arcosol ve PP Sol vent Cycat 4040 Foamaster VF CAO-1 Ant i -Oxidant T inuv in 328 UV Absorber

NP-10

Pounds

134.8 4.7 9.3 1 .o

174.4 46.5 46.5

4.5

Gal l ons

16.2 0.6 1 .o 0.2 5.2 2.7 2.0 0 .6

535.4 60.8 45.2 4.4 36.1 4.9

2.8 0.3 1.1 0.1 3 .0 0.3 6 .5 0.7

Pa in t Proper t ies : Pigment Volume Concentrat ion, %: 28 Cross l inker , phr: 15 Cosolvent, phr : 15 Volume So l ids , %: 41 Weight per Gal lon, l b : 10.6

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 462: Formulat ion Suggestion


Water-Borne A1 kvd/Mel ami ne Kood C l e a r c o a t M o d i f i c a t i o n

K-Flex XM-2304 i s an e x p e r i m e n t a l p r i m a r y h y d r o x y l c o n t a i n i n g a l i p h a t i c , s a t u r a t e d u r e t h a n e r e s i n m o d i f i e r . T h i s wa te r -bo rne a l kyd /me lamine wood c l e a r c o a t f o r m u l a t i o n demons t ra tes improved s t a i n r e s i s t a n c e and f l o w / l e v e l i n g u s i n g t h i s p r o d u c t .

%K-Flex XM-2304 Component: 0% 5% 10% C a r g i l l 7412 Resimene 747 I s o p r o p a n o l Water K -F lex XM-2304 Nacure 155

K-F1 ex XM-2304: % S o l i d s ( C a l c u l a t e d )

W e t t i n g Alkyd/XM-Z304/HMMM

31 . 5 2 8 . 3 25 .1 31 . 5 31.5 31.5 14 .8 1 4 . 8 14 .8 1 5 . 7 15.6 1 5 . 6

0 . 0 3 . 5 6 . 5 6 . 5 6 .5 6 . 5

0% 5% 10% 66.6 6 6 . 5 66.4

5 0 / 0 / 5 0 45/5/50 40/10/50 Poor Good Bes t

S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood S e a l e r : Commerci a1 V i n y l Sander /Sea le r Topcoa t , WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) Topcoat Bake: 10 min. /71C (160F)

4 Hour Spot T e s t

S t a i n Tes t Mus ta rd Ketchup C o f f e e Homog. M i l k Lemon J u i c e L i q u i d C1 eaner N a i l P o l i s h Remover

0% XM-2304 M i l d A t t a c k S t a i n Severe S t a i n Severe A t t a c k M i l d A t t a c k Severe A t t a c k Severe A tack

5% XM-2304 10% XM-2304 M i l d A t t a c k No E f f e c t No E f f e c t No E f f e c t M i l d S t a i n M i l d S t a i n M i l d A t t a c k M i l d A t t a c k M i l d A t t a c k No E f f e c t Severe A t t a c k / M i l d A t t a c k No E f f e c t No E f f e c t

W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hou r s p o t t e s t by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d a m i l d a t t a c k by Peps1 Cola; s t a i n i n g f r o m wa te r ; and a seve re a t t a c k f r o m i s o p r o p a n o l .

W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H p e n c i l hardness and 100+ MEK d o u b l e r u b s a t 23 u ( 0 . 9 m i 1 ) on A1 umi num.



Water-Borne Alkyd/Melamine Wood Clearcoat Modif ication

K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , wa te r s o l u b l e r e s i n m o d i f i e r . T h i s u r e t h a n e d i o l m o d i f y i n g r e s i n i m p a r t s s t a i n r e s i s t a n c e t o t h e f o r c e d d r y ( t h e r m o s e t ) a lkyd/melamine wood c l e a r c o a t f o r m u l a t i o n be low.

What makes t h i s f o r m u l a t i o n un ique i s t h e absence o f n e u t r a l - i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used (Nacure 155) and lower t e m p e r a t u r e c u r e s may be ach ieved . The b i n d e r r e s i n ( a l k y d ) i s wa te r d i l u t a b l e w i t h t h e a d d i t i o n o f a c o s o l v e n t such as i s o p r o p a n o l . A p o t l i f e o f 8-10 hours i s p o s s i b l e .

WB Wood C 1 e a r c o a t -Modi f i c a t i o n Component: C a r g i l l 7412 Resimene 747 I s o p r o p a n o l Water K-F1 ex UD-320W Nacure 155

K-Flex UD-320W: % Sol i d s ( C a l c u l a t e d ) A1 kyd/K-F1 ex UD-32OW/HMMM

% K-Flex UD-320W 0% 5% 10%

31 . 5 28 .3 25.1 31 . 5 31 .5 3 1 . 5 14 .8 14 .8 14 .8 15.7 15.4 15 .0

0 . 0 3 . 5 7 . 1 6 .5 6.5 6 . 5

0% 5% 10% 6 6 . 6 66.5 66 .4

50/0/50 45/5/50 40/10/50

S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood S e a l e r : Commerci a1 V i n y l Sander/Seal e r Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l ) Topcoat , Bake: 10 min. /71C (160F)

S t a i n T e s t Mus ta rd Ketchup C o f f e e Homog. M i l k Lemon J u i c e Pepsi Co la N a i l P o l i s h Remover

4 Hour Spot Test 0% UD-320W 5% UD-320W

M i l d A t t a c k M i l d A t t a c k

Severe S t a i n Severe S t a i n S t a i n No E f f e c t

Severe A t t a c k No E f f e c t M i l d A t t a c k Severe A t t a c k M i l d A t t a c k M i l d A t t a c k

Severe A t t a c k No E f f e c t

10% UD-320W No E f f e c t No E f f e c t

M i l d S t a i n No E f f e c t

Severe A t t a c k No E f f e c t No E f f e c t

W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hou r s p o t t e s t by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d s t a i n i n g f rom wa te r and a seve re a t t a c k f r o m i s o p r o p a n o l and l i q u i d c l e a n e r

W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H p e n c i l hardness and 100+ MEK doub le r u b s a t 23u ( 0 . 9 m i l ) on A1 umi num.



Waterborne C lear Hiqh Gloss Topcoat

Edaplan LA-402 was used i n a Waterborne High Gloss Wood Topcoat t o improve w e t t i n g and l e v e l i n g . I n combinat ion w i t h Ag i tan 315 foam c o n t r o l agent, super io r f i l m p r o p e r t i e s a re ach i eved . Mater i a1 : & Rhoplex E-3188 (Rohm & Haas) 608.00 71 .77 Water 101.33 11.96

Ad jus t pH t o 8.5-9.0

Ammonia (28%) 5.27 0.62

Premix and add s low ly :

Water Dowanol PnB (DOW Chemical) Arcosolve DPM (Arco Chemical) Arcosolve DPt8 (Arco Chemical) T r i bu toxye thy l phosphate

Add f o l l o w i n g w h i l e mix ing :

FCA (Foam Cont ro l Agent) Wet t ing Agent Michem 392-25 (Michelman)

Ad jus t v i scosi t y

Acrysol RM-825 (Rohm & Haas) Water

P roper t i es : % N o n v o l a t i l e (by we igh t ) : 31.2 % N o n v o l a t i l e (by volume): 29.4 Weight per Ga l lon (pounds): 8.48 Theore t i ca l VOC ( g r a m s / l i t e r ) : 106 V i s c o s i t y (cPs): 150+-10%

14.79 1.75 14.79 1.75 14.79 1.75 9.93 1.17 9.93 1.17

0.49 0.06 2.47 0.29

14.11 1.67

0.51 0.06 50.67 5.98

SOURCE: King I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood Formulat ions


White Gloss Maintenance Topcoat

Inq red i en ts : Pigment G r i nd: Methyl C a r b i t o l Solvent Water Bentone LT Ammonium Hydroxide, 28% Aqueous So lu t i on Tamol 681 T r i t o n Nonionic Sur fac tan t CF-10 Nuosept 95 DeeFo HG-12 Acrysol RM-2020 Acrysol SCT-275 Tronox CR-828

Letdown : Methyl C a r b i t o l Solvent )Premix Acrysol SCT-275 1 Ucar Veh ic le 435 Ucar F i lmer IBT Troysan Polyphase AF-1 DeeFo HG-12 Sodium N i t r i t e , 15% Aqueous So lu t i on Ammonium Hydroxide, 28% Aqueous S o l u t i o n

Ad jus t t o minimum pH 8.7

Pounds

59.6 18.4 1 . o 1.8

18.2 2 .2 2 .3 1.9

17.2 8 .6

225.0

8.5 8 .6

626.9 15.8 4.9 1.9 9 .0 1.8

Pai n t P roper t i es : Pigment Volume Concentrat ion (PVC), %: 18.3 To ta l So l ids , %:

pH Value, i n i t i a l : 8.7 V i s c o s i t y :

Stormer, KU: 78 I C I , po ise : 1.1

by volume: 36.1

Weight per Gal lon, l b : 10.3 Freeze-Thaw S t a b i l i t y , 3 cyc les : Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass

F i l m Proper t ies : Cont ras t Rat io, 6-mil wet drawdown: 0.958 Gloss, 60: 70 Gloss, 20: 25

Gal 1 ons

7.00 2.21 0.06 0.25 2.00 0.25 0.25 0.25 2.00 1 .oo 6.59

1 .oo 1 .oo

72.06 2.00 0.50 0.25 1.08 0.25

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 435: Formulat ion Suggestion M-2453


Whi te Gloss Topcoat

____ M a t e r i a1 : A r o l o n 580-W-42 Tamol SG-1 T r i t o n CF-10 C o l l o i d 694 E t h y l e n e G l y c o l B u t y l Carb i t o 1 D o w i c i l 75 Water

Mix a t low speed:

T i t a n o x 2101

G r i n d under h i g h shear 15-20 m i n u t e s . Under low shear , add le tdown.

Water Col l o i d 694 A r o l o n 820-W-49 Propy lene G l y c o l B u t y l Carb i t o 1 A c e t a t e C o b a l t Hydrocure I1 Hydroxyethy l C e l l u l o s e QP-300 (10% S o l n ) Ammonia

*lo% QP-300 i n E t h y l e n e G l y c o l

A n a l y s i s : Pigment Volume Concent ra t ion , Percent : 20 .0 P igment /B inder R a t i o : 0.94/1 Percent S o l i d s , Weight: 57.4 Percent S o l i d s , Volume: 44.0 V i s c o s i t y @ 25C, KU: 72-76 Pounds/Gallon: 11.08

VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 144 Pounds/Gal lon: 1 .2

pH: 8.8-9.0

Lbs. Gals. 65.0 7.30

5.0 0 .52 3 .0 0.34 2.5 0.35

23.0 2.48 10.0 1 .26

1 . o 0 .08 18.0 2.16

300.0 8.57

20.0 2.40 2.5 0 .35

598.0 67.95 18.0 2.08

8 . 0 0.98 0 . 4 0.05 5 .0 0.53 1 . o 0.13

SOURCE: R e i c h h o l d Chrmica ls , I n c . : A r o l o n 820: Formula 194-2


Wood Topcoat Model Formula t ions

Rohm and Haas: Wt% Rhoplex WL-96 (42%) 73.9 Patco te 519 0 . 2 B u t y l Carbi t o 1 ) 6 .2 Dowanol PNB ) Premix 3 .1 Michem Lube 110 (25% S o l i d s ) 2.9 Ammonia (14%) Ad jus t t o pH 8 .0 0 .1 Water 13 .6 S.C. Johnson: Wt% Jonc ry l 554 90.9 Ek taso lve EB 3.6 Jonwax 26 4.5 Water 1 .o Goodyear : Wt% Ektaso lve EP 8 . 5 S a n t i c i z e r 160 2.7 D i e t h y l ami ne 1.1 Drew L-475 0 .2 Water 9 . 1 P l i o l i t e 7104 (44%) 58.5 W i tcobond 234 19.9 Sanncor : Wt% Water 16.1 Dowanol DPM 4.9 Rhoplex WL-96 (42%) 35.3 Sancure 815 42.3 Dehydran 1293 0.5 BYK 306 0.5 Acrysol RM-825 0.3 Ammon i a ( 1 4%) Approx. 0.1 Eva lua t i on i n C lear Topcoats:

Sur fyno l 104 s u r f a c t a n t was eva lua ted i n waterborne c l e a r topcoats t o c o n f i r m i t s m u l t i p l e b e n e f i t s i n ac tua l wood c o a t i n g formulas. Since t h e most s t r i n g e n t performance requ i re - ments a re r e l a t e d t o high-end wood coa t ings . Model topcoat fo rmu la t i ons o f t h i s t ype were se lec ted f o r study.

Sur fyno l 104 s u r f a c t a n t was added a t 1% t o t h e model topcoat fo rmu la t i ons .

I n o rder t o eva lua te a p p l i c a t i o n and f i l m p roper t y b e n e f i t s ,

Sur fyno l 104 s u r f a c t a n t ' s b e n e f i t s i nc lude : *Improved f 1 ow and 1 eve1 i ng *Super ior subs t ra te w e t t i n g *Low foam, and o f t e n defoaming performance *Rapid d i spl acement o f a i r bubbles *Mi n i mal r e s o l ub i 1 i za t i on i n water

SOURCE: A i r Products 8 Chemicals, I n c . : Sur fyno l Su r fac tan ts : Suggested Formulat ions

Coil Coatings 25

Chromate Coi 1 -Coati na Pr imer

I n g r e d i e n t s : Pigment Gr ind: Dei o n i zed Water Ethy lene G1 yco l N,N-Dimethylethanolamine Foamaster VF T e r g i t o l Nonionic S u r f a c t a n t NP-10 Polywet ND-2 L-203-D St ron t ium Chromate 233 Basic Z inc Chromate T i -Pure R-900

Letdown : N, N-D i methyl e thanol ami ne Ucar Veh ic le 462 Carbi t o 1 Solvent Arcosolve PP Solvent Cyme1 303 Foamaster VF Deionized Water

~ _ _ _ Pounds Ga l lons

46.0 5.54 3.8 0.41 0.6 0.09 0.3 0.03 3.8 0.45

15.3 1.63 25.6 0.83 25.6 0.81

204.5 5.96

5.9 0.79 629.5 71.85

16.1 1.88 16.1 2.15 35.5 3.55

1.8 0.22 31.7 3.81

Wei sh t%

4.33 0.35 0.06 0.03 0.35 1.44 2.41 2.41

19.25

0.56 59.26

1.52 1.52 3.42 0.17 2.92

Procedure:

o rder l i s t e d . Thoroughly mix l i q u i d components b e f o r e adding pigments. Add pigments s l o w l y and s t i r u n t i l un i form. Gr ind a t h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches about 50C.

For t h e letdown, add t h e i n g r e d i e n t s i n t h e order shown, making sure t h e mix i s un i fo rm a f t e r each a d d i t i o n . For a l e s s c r i t i c a l procedure, premix f i l m i n g a i d s w i t h c r o s s l i n k e r and water . Mix p a i n t a t l e a s t 10 minutes a f t e r t h e f i n a l a d d i t i o n .

P a i n t P r o p e r t i 8s:

Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer i n

Pigment:Binder Rat io : 0 . 8 : l . O T o t a l N o n v o l a t i l e s , % by weight : 54.3 Resin : Me1 ami ne: 89; 1 1 Organic i n E f f l u e n t , % by volume: 10 V i s c o s i t y , B r o o k f i e l d , cP: 300 pH Value: 9

SOURCE: Ucar Emulsion Systems: Ucar Veh Suggest ion LP-3821

9

c l e 462: Formulat ion


Low-Sheen Co i l -Coa t inq Topcoat

I n q r e d i e n t s : Pigment G r i nd: Ethy lene G lyco l Polywet ND-2 T e r g i t o l Nonionic S u r f a c t a n t NP-10 Foamaster VF N, N-Di methyl e thanol ami ne De i o n i zed Water S i l c r o n G-601 T i -Pure R-960 o r Zopaque RCL-6

Letdown : Foamaster VF Deionized Water N,N-Dimethylethanolamine Ucar V e h i c l e 462 Pigment G r i nd Arcosolve PP So lven t Cyme1 303

Procedure:

_ _ _ ~ Pounds Ga l l ons

2.42 0.26 9.69 1.03 2.39 0.27 1.17 0.15 0.30 0.04

95.87 11.53 48.46 2.77

193.80 5.82

2.11 0.27 22.10 2.65

3.26 0.44 585.18 66.80 354.10 21.87

30.20 4.02 39.50 3.95

Weight%

0.23 0.93 0.23 0.11 0 .03 9.25 4.68

18.70

0.20 2.13 0.32

56.47 34.16

2.91 3.81

Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank i n t h e o rde r l i s t e d . Mix a t low speed f o r 5 minutes. S lowly add t h e pigments and s t i r u n t i l un i fo rm. Gr ind a t h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches 50C.

b lend i n t o Ucar Veh ic le 462 w i t h s low a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t low speed f o r 10 minutes. Add t h e melamine r e s i n and s o l v e n t . S t i r a t moderate speed f o r 10 minutes.

P a i n t P r o p e r t i e s :

For t h e letdown, combine t h e ant i foam, water , and t h e amine;

Pigment:Binder R a t i o : 0 . 8 : l .O Pigment Volume Concentrat ion, %: 19.7 T o t a l N o n v o l a t i l e s , % by we igh t : 53.6 Organic i n E f f l u e n t , % by volume: 10.5 Resi n:Mel ami ne: 87: 13

SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 462: Fo rmu la t i on Suggest ion LP-3794

Coil Coatings 27

Medium-Gloss Co i l -Coat ing Topcoat

Ing red ien ts : Pigment Grind: Ethylene Glyco l T e r g i t o l Nonionic Sur fac tan t NP- Foamaster VF Polywet ND-2 N,N-Dimethylethanolamine Deionized Water Ti-Pure R-960 o r Zopaque RCL-6

Letdown : Foamaster VF Deionized Water N,N-Dimethylethanol ami ne Ucar Veh ic le 462 Pigment G r i nd Arcosolve PP Solvent Cyme1 303 Deionized Water

Pounds

2.48 10 2.53

0 .47 10.06 0.35

52.89 253.28

4.29 4.61 2.97

630.31 322.06

31.57 35.22 26.02

Gal 1 ons

0.27 0.29 0.06 1.07 0.05 6.36 7.61

Wei qht%

0.23 0.24 0.04 0.95 0.03 5.00

23.96

0.55 0.41 0.55 0.44 0.40 0.28

71.96 59.64 15.69 30.45 4.20 2.99 3.52 3.33 3.13 2.46

Procedure: Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank

i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add t h e t i t a n i u m d i o x i d e and s t i r u n t i l uni form. Grind a t h igh speed f o r 10 minutes o r u n t i l g r i n d reaches 50C.

For t h e letdown, combine t h e f i r s t increment o f water, t h e anti foam, and t h e amine; b lend i n t o t h e Ucar Veh ic le 462 w i t h slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h the n e u t r a l i z e d l a t e x and s t i r a t low speed f o r 10 minutes. Add t h e remaining water, melamine res in , and so l ven t . S t i r a t moderate speed f o r 10 minutes.

Pa in t P roper t i es : Pigment:Binder Ra t io : 0 .8 : l .O Pigment Volume Concentrat ion (PVC): 18.9 To ta l Nonvo la t i les , % by weight: 53.1 Organic i n E f f l u e n t , % by volume: 10.5 Resin:Melami ne: 89: 11 pH Value: 9

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 462: Formulat ion Suggestion LP-3793


I n g r e d i e n t s : Pigment G r i nd: D i spersant (1 ) Soya L e c i t h i n (2 ) Ethy lene G lyco l Water Defoamer (3) Calcium Carbonate (4) T i tan ium D i o x i d e (5 )

Le t Down: Ucar V e h i c l e 441 Dispersant ( 1 ) Soya L e c i t h i n Defoamer (3 ) Melamine ( 6 ) B u t y l C e l l o s o l v e So lven t Thickener (7) B lue T i n t Paste ( 8 )

S u o ~ l i e r s :

Pounds

3.3 3.1 4.7

74.3 0 .7

263.0 25.6

630.2 3 . 1 4 . 9 1.6 5 .6

14.4 6.3 2.6

Ga l l ons

0.33 0.33 0.50 8.93 0.09

11.69 0.73

72.86 0.31 0.53 0.20 0.56 1.92 0.73 0.29

Wei qht%

0.32 0.30 0.45 7.12 0.07

25.21 2.46

60.38 0.30 0.47 0.15 0.54 1.38 0.60 0.25

Dispersant - Strodex PK-90 (Dexter Chemical) o r e q u i v a l e n t Dispersant - Ross and Rowe 551 (Ross and Rowe Chemicals) o r e q u i v a l e n t . Defoamer - Foamaster VF (Diamond Shamrock) o r e q u i v a l e n t . Calc ium Carbonate - A tomi te (Thompson, Weinman) o r equ iv - a l e n t . T i t an ium D iox ide - Ti -Pure R-900 (duPont) o r e q u i v a l e n t . Me1 ami ne - Cyme1 350 (American Cyanamid) o r e q u i v a l e n t . Th ickener - Acrysol G-110, 22% (Rohm and Haas) o r equiv- a1 e n t . Aqueous D ispe rs ion - Thalo B lue (Tenneco) o r e q u i v a l e n t .

Procedure:

o rde r l i s t e d . Mix a t low speed f o r one minute. S lowly add p i g - ments and s t i r u n t i l un i form. Gr ind a t h i g h speed u n t i l d e s i r e d g r i n d f i neness has been accompl i shed.

For t h e letdown, pre-b lend Ucar V e h i c l e 441, Strodex PK-90, soya l e c i t h i n , and defoamer. W i th s low a g i t a t i o n , add t o t h e pigment g r i n d . S t i r a t low speed f o r 5 t o 10 minutes. Pre-blend B u t y l C e l l o s o l v e Solvent and melamine and add t o l e t down. S t i r f o r f i v e minutes. Add b l u e t i n t pas te and t h i c k e n e r and s t i r f o r 5 t o 10 minutes. If done s l o w l y and c a r e f u l l l y , l e t down

Charge t h e f i r s t f i v e components t o a Cowles m ixe r tank i n t h e

components may be added s e q u e n t i a l l y . Coat ing P r o p e r t i e s :

N o n v o l a t i l e s , %: 54 t o 55 pH: 8 . 0 Pigment/Binder R a t i o : 1 . O V i s c o s i t y a t 25C ( B r o o k f i e l d LVT, 60 r p m ) , cP: 200

SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: Formu Suggest ion LP-3024

o 300

a t i on


A c r y l i c Emu1 s i o n Enamel -B&C K-F1 ex UD-320W M o d i f i e d

K-F1 ex UD-320W modi f i c a t 1 on o f t h i s w h i t e a c r y l i c/melami ne emu ls ion f o r g e n e r a l i n d u s t r i a l a p p l i c a t i o n s demons t ra ted s e v e r a l advantages i n c l u d i ng: improved f l o w / l e v e l i ng, h i g h e r g l o s s , improved g l o s s r e t e n t i o n on QUV exposure -h ighe r s o l i d s ( l o w e r VOC) and lower c o s t p e r pound on a s o l i d s b a s i s .

G r i n d Compos i t i on : J o n c r y l 540

S u r f y n o l 104 T i - P u r e R-960 Water ( G r i n d t o 6+ Hegman on t h e B a l l M i l l )

Letdown Compos i t i on : G r i nd J o n c r y l 540 HMMM K-Flex UD-320W Nacor r 1552 Water

Enamel C h a r a c t e r i s t i c s :

AMP-95

V i s c o s i t y , cps (25C): 200-205

P igmen t /B inde r R a t i o : 0 . 7 6 : l . O pH: 8 .70 -8 .75

Q 41.8

1 . o 1 . o

4 8 . 6 7 . 6

Wt%-B Wt04-& 100.0 100.0

50 .9 39 .1 1 9 . 9 2 9 . 1

3 . 6 7.2 1 . 3 1 . 3

23.0 25 .0

A p p l i c a t i o n and Cure: S u b s t r a t e : B o n d e r i t e 1000 ( i r o n phosphated CRS) Cure Schedule: 15 ' /300F (150C) DFT ( m i l s ) : 0 .9+ -0 .01 ( 2 2 . 5 ~ )

F i l m P r o p e r t i e s : A c r y l ic/K-Flex/HMMM: Penci 1 Hardness Knoop Hardness (259) MEK R e s i s t a n c e (2X) Crossha tch Adhesion Impact R e s i s t a n c e :

D i r e c t ( i n l b s ) : Reverse ( i n l b s ) :

C1 eve1 and H u m i d i t y (55C)

0 C 65/5/30 57/16/33

4H-5H 4H-5H 17 .0 1 8 . 4

100 100 100% 100%

100-110 100-110 20- 30 20 -30

9/M 9/MD

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12 B & C

Enamels 31

S y n e r g i s t i c E f f e c t s o f Combinina Nacor r w i t h A n t i - C o r r o s i v e Pinment i n an A i r Dry Water R e d u c i b l e

A1 kyd M o d i f i e d A c r y l i c Enamel

Improvements i n t h e c o r r o s i o n r e s i s t a n c e o f a w a t e r r e d u c i b l e a i r d r y a c r y l i c enamel a r e p o s s i b l e u s i n g Nacor r r u s t and c o r r - o s i o n i n h i b i t o r s , When used i n c o m b i n a t i o n w i t h a c a l c i u m s t r o n t - ium p h o s p h o s i l i c a t e c o r r o s i o n i n h i b i t i n g p igment (Ha lox SW-1111, a d e f i n i t e improvement i n c o r r o s i o n r e s i s t a n c e was o b t a i ned. S a l t sp ray t e s t i n g was c a r r i e d o u t o v e r i r o n phosphated p a n e l s ( B o n d e r i t e 1000) .

G r i n d : Aquamac 1090 Nacor r 2 -Bu toxye thano l N y t a l 400 Ha lox SW-111 Raven B l a c k 16

Hal ox C o n t r o l SW-111

3 . 7 9 3 .79

2 .79 2 .79 11.61 9 . 2 9

2.38 0.71 0 .71

_ _ _ _ ----

_ _ _ _

Letdown: (Add g r a d u a l l y w h i l e on m i l l a t l ow rpm): C o b a l t Hydrocure 0.06 0.06 Manganese Hydrocu re 0 .08 0.08 Water 15.85 15.85 Ammonium Hydrox ide , 30% 0.28 0 .27

Aquamac 640 (pos t -add 8 shake) 64.83 64.80

Hal ox C h a r a c t e r i s t i c s : C o n t r o l SW-111 P i gment/Bi nde r R a t i o 0 .4 0 .4

T o t a l Res in S o l i d s , % by w e i g h t 32.0 32 .0

Ha lox , % based on t o t a l p a i n t w e i g h t -- 2 . 4


N o n - V o l a t i l e , % by w e i g h t 44 .3 4 4 . 4

Nacor r , % based on t o t a l p a i n t w e i g h t -- _ _

S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 7 days a t room tempera tu re (22-23C) A p p l i c a t i o n : Spray F i l m Th ickness : 20-25 m i c r o n s

Hal ox F o r m u l a t i o n T e s t Procedure: C o n t r o l SW-111 Penci 1 Hardness Tukon Hardness, KHN25

2B-B 28-8 1 .2 2 . 2

H a l o x t Nacor r

3 . 7 6 0.78 2 .77 9 . 2 1 2.36 0 . 7 0

0 . 0 6 0 . 0 8

15 .72 0 .27

64.29

H a l o x t Nacor r

0 .4 44 .0 31.8

0 . 8 2 . 4

Hal ox+ Nacor r 1151

28-8 2 . 2

Crossha tch Adhesion, % removed 0 0 0 S a l t Spray, 100 h o u r s L ight -med Very l i g h t No r u s t

S a l t Spray, 310 h o u r s Very Very Medi u m r u s t r u s t

dense r u s t dense r u s t r u s t The use o f N a c o r r s w i t h t h e a n t i - c o r r o s i v e p igment o f f e r e d t h e

b e s t c o r r o s i o n r e s u l t s i n t h i s s t u d y . They had l i t t l e o r no d e l e t e r i o u s e f f e c t on o t h e r p a i n t p r o p e r t i e s . SOURCE: K i n g I n d u s t r i e s : Nacor r WR-14


Ancamide 2353 Fast D rv ina White Gloss Enamel

Pa r t A: Gr ind Base: DER 660x80 (Dow) Nuosperse 657 ( H u l s America) Bee t le 216-8 (American Cyanamid) Dowanol PM (Dow) TiPure R-960 (DuPont)

Le t Down: High F lash Naphtha (Ashland) Methyl Propyl Ketone (Eastman)

Par t 8: Ancamide 2353 ( A i r Products) n-Butanol (Ashland)

Proper t i es : Par t A V i s c o s i t y : 86KU Par t B V i s c o s i t y : 64KU M i xed V i s c o s i t y : 80KU PVC: 15.2% Vo 1 ume

SOURCE

S o l i d s : 62.2%

- Lb

472.55 3.54 2.84

47.26 307.16

73.72 14.18

131.44 34.78

VOC, @ 80KU: 2.8 l b / g a l Mix Ra t io : 4:l by Volume I n d u c t i o n Time: 0 Pot L i f e , h r : 3 Dry Times: Set t o Touch, min: 50 Dust Free, min: 75 Hard Dry: Overnight

60 Gloss: 104

Gal

51.47 0.42 0.34 6.20 9.44

10.03 2.10

14.86 5.14

A i r Products and Chemicals, I n c . : Ancamide 2353 Cur ing Agent: Table 12 Formulat ion

Enamels 33

Ancamide 2353 Low VOC White Gloss Enamel

P a r t A: G r ind Base: L i q u i d DGEBA Epoxy Nuosperse 657 (Huls America) Sur fyno l 740 ( A i r Products) Dowanol PM (Dow) T iPure R-960 (DuPont)

Le t Down:

High Flash Naphtha (Ashland) Methyl Propyl Ketone (Eastman)

Par t 8 : Ancamide 2353 ( A i r Products) n-Butanol (Ashland)

Proper t i es : Par t A V i s c o s i t y : 73 KU Par t B V i s c o s i t y : 64 KU Mixed V i s c o s i t y : 70 KU PVC: 17% Volume S o l i d s : 70%

352.76 36.43 3.88 0.46 1.76 0.25

48.68 6.32 388.04 11.92

67.73 9.22 14.11 2.09

212.03 23.46 63.14 9.34

VOC, @ 70 KU: 2.2 l b / g a l Mix Ra t io : 2:l by Volume I n d u c t i o n Time: 0 Pot L i f e , h r : 2 Dry Times: Set t o Touch, h r : 5 Dust Free, h r : 7 Hard Dry: Overnight

60 Gloss: 102

SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Cur ing Agent: Tab1 e 11 Formulat ion


Carv Gloss White Enamel

I n a r e d i e n t s : Pigment Gr ind : B u t y l C e l l o s o l v e So lvent Water Tamol 731 T r i t o n Non ion ic S u r f a c t a n t CF-10 Byk 023 T i -Pure R-900 Na t roso l P lus 330 Water Nuosept 145

Letdown : Ucar La tex 481 Water B u t y l Carbi t o 1 Sol ven t So lven t 142HT LE-410 Emulsion Sur f yno l 104E

P a i n t P r o p e r t i e s : Pigment Volume Concent ra t ion , %: 17.8 Volume S o l i d s , %: 40.6 Weight S o l i d s , %: 51.9 Stormer, KU: 85 I C I , Po ise : 2 .0 pH Value: 9-9.6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0 .1 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 196

Pounds

39.0 20.0

9 . 6 2.4 2.5

240.0 1 .1 5.0 1 . 4

620.0 19.6 12.8 32.8 15.0 2 .0

Gal 1 ons

5.20 2.40 1.05 0.27 0.35 7.02 0.10 0.60 0.16

71.84 2.35 1.60 5.00 1.82 0.24

T y p i c a l T i t a n i u m D iox ide Pigment Performance

T i t a n i u m D i o i x d e Stormer I C 1 Gloss Values KU Poise 60 20

T i -Pure R-900 85 2.0 85 52 T i -Pure R-902 83 2 .1 79 41 T i -Pure R-960 86 2.0 79 41 T i -Pure R-706 82 1 .7 90 60

Tronox CR-828 Tiona RCL-535 Kronos 2310

T i o x i d e TR 90 T i o x i d e TR 93 T i o x i d e TR 80

86 2.0 87 59 83 1.7 87 59 84 1.8 84 53

83 86 85

1.7 88 54 1 . 8 86 57 2.0 90 68

SOURCE: Ucar Emulsion Systems: U l t ra -G loss Latexes: Fo rmu la t i on Suggest ion E-2218C

Enamek 35

C a w Gloss White Enamel

I n g r e d i e n t s : Pigment Gr ind : B u t y l C e l l os01 ve Sol vent Water Tamol 731 T r i t o n Nonionic Sur fac tan t CF-10 Byk 023 T i -Pure R-900 Water Nuosept 145 Ammonium Hydroxide, 28% Aqueous S o l u t i o n

Letdown : Ucar Latex 481 B u t y l C a r b i t o l So lvent Sol ven t 142HT LE-410 Emulsion Ucar Polyphobe 102 Rheo. Mod. Ucar Polyphobe 106HE Rheo. Mod. Water Sur fyno l 104E

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 17.8 Volume So l i ds , %: 40.7 Weight So l i ds , %: 52.1 Stormer, KU: 86 ICI, Poise: 2 .5 pH Value: 9-9.6 Freeze-Thaw S t a b i l i t y , cyc les passed: 0-1 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 196

F i 1 m P roper t i es : Gloss , 60: 88 Gloss, 20: 47 Flow and Leve l ing : Exce l l en t Dry-to-Touch, hour: 1 Recoat, hours: 2-4 Water/Bl i s t e r Resistance: Excel l e n t

Pounds

39.0 20.0

9.6 2.4 2 . 5

240.0 5.8 1 .4 2.0

620.0 12.8 32.8 15.0

5.0 2.7

10.0 2.0

Gal 1 ons

5.20 2.40 1.05 0.27 0.35 7.02 0.70 0.16 0.27

71.84 1.60 5.00 1 .82 0.57 0.31 1.20 0.24

SOURCE: Ucar Emulsion Systems: U l t ra -Gloss Latexes: Formula t ion Suggestion E-221 6G


C l e a r Enamel (For Maximum S o l v e n t and A b r a s i o n Res is tance)

_ _ _ _ _ _ Pounds Gal l o n s M a t e r i a1.L P a r t A: Epi-Rez 5522-WY-55 Resin 490.6 54.82 Michem Lube 743 Mar and S l i p Agent 41 . O 5.00 C y c l o Sol 63 32.3 4.37 E k t a s o l v e EP, 2-Propoxyethanol 33.2 4.37 Water 53.6 6.44

P a r t 0 : Epi-Cure 8290-Y-60 C u r i n g Agent DeeFo P I - 4 Concent ra te Defoamer Water

Composite Blend: V i s c o s i t y P a r t A 58 K.U. P a r t B 68 K.U. P a r t s A and 0 85 K.U.

145.8 16.51 4.0 0 .49

66.6 8.00

650.7 75.00 216.4 25.00

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 41.8 T o t a l Volume S o l i d s , %: 37.6 V o l a t i l e Organ ic Compounds ( V O C ) :

Pounds/Gallon: 2 .74 G r a m s / L i t e r : 329

I n d u c t i o n Time, minu tes : 30

Resi n Composi t i on : Epoxy Resin, %: 75.0 C u r i n g Agent, %: 25.0 T o t a l , %: 100.0

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1802: €p i -Rez 5522-WY-55 Resin/Epi -Cure 8290-Y-60 C u r i n g Agent

Enamels 37

Gloss Safe ty R e d Enamel

Ing red ien ts : P i gment G r i nd : Ucar Latex 481 T r i t o n Nonionic Sur fac tan t CF-10 T o l u i d i n e Red 10-6C-41-L100 Aquatrend I 1 Red I r o n Oxide D isp . 878-1046 Colanyl Carmine Disp. 13-3148 (Azo Red) Foamaster 333 Nat roso l P lus 330 Water Nuosept 145

Letdown : Ucar Latex 481 Bu ty l Ce l l oso l ve Solvent Bu ty l C a r b i t o l Solvent Solvent 140 LE-410 Emulsion Aquatrend I 1 Red I r o n Oxide Disp. 878-1046 Colanyl Carmine Disp. 13-3148 (Azo Red) Sur fyno l 104E

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 11 .O Volume So l i ds , %: 39.5 Weight So l ids , %: 43.4 Stormer, KU: 88 ICI, Poise: 1.5 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , cyc les passed: 5 Heat-Age S t a b i l i t y , 12OF, weeks passed: 4 VOC, grams per l i t e r : 210

F i l m Proper t i es : Gloss, 60: 81 Gloss, 20: 40 Flow and Leve l ing : Exce l l en t Dry-to-Touch, hour: I Recoat, hours: 2-4 Water/Bl i s t e r Resistance: Excel l e n t

Pounds

173.4 10.0

110.0 9 .4 7.8

15.0 1 . o 8.3 1.2

416.9 38.3 12.4 32.8 15.0 5.0 3.0 2 .0

Gal l o n s

20.09 1.14

11.58 0.59 0.76 2.00 0.09 1 .oo 0.13

48.31 5.10 1.55 5.00 1.82 0.31 0.29 0.24

SOURCE: Ucar Emulsion Systems: U l t ra -Gloss Latexes: Formulat ion Suggestion E-2222C


Gloss Safe ty Ye l low Enamel

I n p r e d i en t s : P i ament G r i nd:

Pounds

BuTyl Ce l l oso l ve Solvent Water Tamol 731 T r i t o n Nonionic Sur fac tan t CF-10 Foamaster 333 T i -Pure R-900 Nat roso l P lus 330 Water Nuosept 145 B u t y l Ce l l oso l ve Solvent

Letdown : Ucar Latex 481 Water Byk 026 B u t y l C a r b i t o l So lvent Sol ven t 142HT LE-410 Emulsion Aquis Dalamar Yel low Disp. YW-811D Aquatrend I 1 Yel low I r o n Oxide Disp. 878-0012 Aquatrend I1 Lamp Black Disp. 878-9908 Sur fyno l 104E

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 11.4 Volume So l i ds , %: 37.4 Weight So l i ds , %: 43.9 Stormer, KU: 89 ICI, Poise: 1 .7 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 218

F i 1 m P r o p e r t i es : Gloss, 60: 86 Gloss, 20: 46 F1 ow and Level i ng : Excel 1 e n t Dry-to-Touch, hour: 1 Recoat, hours: 2-4 Wate r /B l i s te r Resistance: E x c e l l e n t

12.8 10.0 5 . 0

10.0 15.0 66.3

2.8 5 .0 1.2

24.8

572.9 24.0

2.0 12.8 32.8 15.0 76.2 12.1 0.1 2.0

Ga l lons

1.70 1.20 0.54 1.14 2.00 1.94 0.25 0.60 0.13 3.30

66.39 2.88 0.25 1.60 5.00 1.82 8.28 0.73 0.01 0.24

SOURCE: Ucar Emulsion Systems: U l t ra -Gloss Latexes: Formula t ion Suggestion E-2225C

Enameh 39

Gloss White Enamel

M a t e r i a1 : P a r t A: Epi - rez 3520-WY-55 Resin Michemlube 182 Mar and S l i p Agent Water

P a r t 0: Epi-Cure 8537-WY-60 Cur ing Agent Ek taso lve DB Ace ta te T r i e t h y l a m i n e Pa tco te 519 Defoamer Kronos 2020 o r Tronox CR-800

Pounds

411.6 27.8 13.7

160.0 8 .2 3 . 7 4.0

250.0

Gal 1 ons

45.03 3.33 1.64

17.70 1 .oo 0.61 0.57 7.33

High Speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S . , t hen add:

Epi-Cure 8537-WY-60 Cur ing Agent Water

42.4 4.69 150.0 18.10

Composi t e 81 end : P a r t A P a r t B P a r t s A and B

V i scos i t y 85 KU 453.1 50.00

110 KU 619.1 50.00 99 KU

T y p i c a l Coa t ing P r o p e r t i e s : T o t a l Weight S o l i d s , %: 55.8 T o t a l Volume S o l i d s , %: 42.3 PVC, %: 17 .3 V o l a t i l e Organic Compounds (VOC):

Pounds/Gal 1 on : 1 .61 Grams/Li t e r : 187

Resin Composi t ion (based on s o l i d s ) : Epoxy Resin, %: 65.0 Cur ing Agent, %: 35.0 T o t a l , %: 100.0

Reduct ion f o r Convent ional Spray (by volume): P a r t s A and B: 17 P a r t s Water: 1 Par t

SOURCE: S h e l l Chemical Co.: S t a r t i n g Fo rmu la t i on No. 1606: Epi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Cur ing Agent


Gloss W h i t e ~ . . ~ Enamel

M a t cr i _a 1-1 P a r t A : Epi -Rez 3520-WY-55 Res in Michemlube 182 Mar and S l i p Agent Water

P a r t B : Epi -Cure 8536-MY-60 C u r i n g Agent Deefo P I - 4 Concen t ra te Defoamer R u t i l e T i t a n i u m D i o x i d e , Kronos 2020 o r

Tronox CR-800

H igh speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S

Epi -Cure 8536-MY-60 C u r i n g Agent Water

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , % : 5 1 . 5 T o t a l Volume S o l i d s , %: 3 7 . 6 PVC, % : 19 .5 V o l a t i l e Organ ic Compounds (VOC):

Pounds/Gal l o n s : 1 .89 Grams/Li t e r : 227

Res in Compos i t i on (based on s o l i d s ) : Epoxy Res in , %: 62 .2 C u r i n g Agent , %: 37 .8

~~ Pounds

329.4

8 8 . 6 27.8

160.0 4 . 0

250.0

G a l l o n s

36 .04 3 . 3 3

10.63

19 .28 0 . 4 9

7 .33

t h e n add:

2 2 . 5 2 .71 168 .2 20 .19

Reduc t ion f o r Conven t iona l Spray (by volume): None r e q u i r e d

SOURCE: S h e l l Chemical Co. : S t a r t i n g F o r m u l a t i o n No. 1805: Epi-Rez 3520-WY-55 Resin/Epi -Cure 8536-MY-60 C u r i n g Agent

Enamels 41

G l o s s W h i t e Enamel (Maximum S o l v e n t and A b r a s i o n Res is tance )

M a t e r i a1 : P a r t A : €p i -Rez 5522-WY-55 Res in C y c l o So l 63 E k t a s o l v e EP, 2-Propoxyethanol Water

P a r t 8: Epi -Cure 8290-Y-60 C u r i n g Agent Deefo P I - 4 C o n c e n t r a t e Defoamer T i - P u r e R-960 o r Kronos 2160 Water

H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C

Water G l a c i a l A c e t i c A c i d

Composite B lend : V i s c o s i t y P a r t A 61 K . U . P a r t B 103 K . U . P a r t s A and B 83 K . U .

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , O h : 54 .0 T o t a l Volume S o l i d s , % : 40 .4 PVC, %: 1 9 . 2 V o l a t i l e Organ ic Compounds (VOC):

Pounds/Gal lon: 2 . 3 4 G r a m s / L i t e r : 280

I n d u c t i o n Time, m i n u t e s : 30

Res in Compos i t i on (based on s o l i d s ) : Epoxy Res in , % : 74 .5 C u r i n g Agent , % : 2 5 . 5

~ _ _ _ Pounds Gal 1 ons

442.2 49.41 2 2 . 2 3 . 0 0 22.7 3.00 9 3 . 8 11 .26

135.1 15.30 4 .0 0.49

250.0 7 . 7 4 1 2 . 5 1 .so

6 6 . 1 7 .93 3 . 2 0 .37

580.9 66.67 470.9 33.33

Reduc t ion f o r Conven t iona l Spray (by vo lume) : P a r t s A and B: 25 p a r t s Water: 1 p a r t

SOURCE: S h e l l Chemical Co . : S t a r t i n g F o r m u l a t i o n No. 1803: Epi-Rez 5522-WY-55 Res in /Ep i -Cure 8290-Y-60 C u r i n g Agent


Green A i r Dry Enamel f o r Flexible Substrates

Materi a1 : Spensol L53 Amrnoni um Hydroxi de D i sperse-Ayd W28 C o l l o i d 679 Ucar SCT 100 Sunbr i te Yellow 272-0558 Sunbri t e Green 264-8142 Titanox 2101 Mapico 1075

Lbs. 261.6

1.9 4.4 1 .9 2.3

50.0 25.0 25.0 50.0

Gals. 30.00 0.25 0.50 0.25 0.25 4.69 1.43 0.75 1.48

Add the above i n order under good ag i ta t i on , then pebble o r sandmil l g r i n d t o 7 Hegman.

Letdown : Spensol L53 526.7 60.40

Analysis: Pigment Volume Concentration, Percent: 24.7 Pigrnent/Binder Rat io: 0.6/ l .O Percent Sol ids, Weight: 41.2 Percent Sol ids , Vol ume: 33.8 V iscos i t y @ 25C, #2 Zahn, Secs.: 50-60 Pounds/Gallon: 9.5

VOC (excluding water) : Grams/Liter: 289 Pounds/Gallon: 2.4

pH: 8.5+-0.3

SOURCE: Reichhold Chemicals, I nc . : Spensol L: Formula 2316-62A

Enamels 43

H i qh-Hidi nq Esashe11 Enamel

Pounds I n s r e d i e n t s : Pigment Gr ind : Water 226.7 Cel l o s i ze Hydroxyethy l C e l l u l ose ER-4400 2 . 0 Nuosept 145 2 . 3 Tamol 731 9 .2 T r i t o n Nonionic S u r f a c t a n t N-57 2.3 AMP-95 1 .o Propylene G lyco l 51.8 Col l o i d 643 1.9 Tronox CR-800 225.0 Opt iwhi t e 100.0 Burgess No. 98 25.0

Letdown : Ucar F i l m e r I B T B u t y l Carb i t o 1 Solvent Acrysol SCT-275 Ucar Latex 379G Col l o i d 643

Pai n t P r o p e r t i e s PVC, %: 35.6 Volume Sol i ds Weight Sol i d s Weight pe r Ga Stormer. KU: I C I . n o i s e : 1

%: 37.6 %: 53.4

l o n , l b : 04

. 4

11.9 11.9 17.2

418.2 2 . 8

1 . 0 9

G a l 1 ons

27.21 0.18 0.25 1 .oo 0.25 0.13 6.00 0.25 6.54 5.46 1.15

1.50 1.50 2.00

46.21 0.37

I .

pH, i n i t i a l : 8 .2 Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

F i 1 m P r o p e r t i e s : Ref 1 ectance, %: 91.9 Gloss, 60: 8 Sheen, 85: 22 Con t ras t R a t i o , 3-mi l f i l m * : 0.968 Flow and l e v e l i n g , brushed: Good

*Opaci ty i nc reased w i t h t o n i n g .

SOURCE: Ucar Emulsion Systems: Formulat ion Suggest ion I -1998A


MacGregor Gloss B1 ack Enamel

I n g r e d i e n t s : Pigment Gr ind : Ucar Latex 481 Byk 023 T r i t o n Nonionic Sur fac tan t CF-10 Aurasperse Carbon B1 ack W-7012 Water Nuosept 145 Ammoni urn Hydroxi de, 28% Aqueous Sol u t i on

Letdown : Ucar Latex 481 Dee Fo 102OF Bu ty l C e l l oso lve Sol vent B u t y l C a r b i t o l Solvent Sol vent 142HT LE-410 Emu1 s i on Water Ucar Polyphobe 102 Rheo. Mod. Ucar Polyphobe 106HE Rheo. Mod. Sur fyno l 104E

Pounds

88.0 2.5

10.0 45.0

8.3 1 . 2 2 . 4

556.0 5.0

39.0 12.4 32.8 15.0 15.0 8 .3 4.5 2 . 0

Ga l lons

10.20 0.35 1.14 4.69 1 .oo 0.13 0.29

64.43 0 .68 5.21 1.57 5.00 1.80 1.80 0.95 0.52 0.24

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 2.3 Volume So l i ds , %: 37.9 Weight So l i ds , %: 40.6 Stormer, KU: 90 I C I , Poise: 2 . 6 pH Value: 8.5-9 Freeze-Thaw S t a b i l i t y , cyc les passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 204

F i l m P roper t i es : Gloss, 60: 91 Gloss, 20: 65 Flow and Leve l ing : Excel l e n t Dry-to-Touch, hour: 1 Recoat, hours: 2 Water/Bl i s t e r Resistance: Excel l e n t

SOURCE: Ucar Emulsion Systems: U l t ra -G loss Latexes: Formula t ion Suggest i on E-2221 E

Enamels 45

Pinehurs t Gloss Green Enamel

I n g r e d i e n t s : Pigment Gr ind : B u t y l Ce l l oso l ve Solvent Water Tamol 731 T r i t o n Non ion ic Sur fac tan t CF-10 Byk 023 Chromium Oxide Green W-6017 Aurasperse Carbon B lack W-7012 Aurasperse Phtha lo Green W-6013 Yel low I r o n Oxide 878-1812 Nat roso l P lus 330 Water Nuosept 145

Letdown : Ucar Latex 481 Water B u t y l C a r b i t o l Solvent So lvent 142HT B u t y l Ce l l oso l ve Solvent Water LE-410 Emulsion Sur f yno l 104E

Pounds

7.5 5.8 5.0

10.0 2.5

53.3 3.2

25.4 7.0 2.0 4 .2 1 .2

640.0 8 .3

12.4 32.8 31 . 5

8 . 8 15.0 2.0

Gal 1 ons

1 . o o 0.70 0.54 1.14 0.31 3.08 0.34 2.54 0.42 0.18 0.59 0.13

74.16 1 .oo 1.55 5.00 4.20 1.06 1.82 0.24

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 4 .6 Volume So l i ds , %: 37.1 Weight So l i ds , %: 42.0 Stormer, KU: 88 I C I , Poise: 2.3 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 221

F i l m Proper t i es : Gloss, 60: 88 Gloss, 20: 64 Flow and Level i ng: Excel 1 en t Dry-to-Touch, hour: 1 Recoat. hours: 2-4 Wate r /B l i s te r Resistance: E x c e l l e n t

SOURCE: Ucar Emulsion Systems: U l t ra -Gloss Latexes: Formula t ion Suggestion E-22429


S e l f - P r i m i n a I n t e r i o r Semi-Gloss Enamel

Pigment G r i n d : Water Busperse 203 I g e p a l CTA-639 Bubreak 448 Water* C e l l o s i z e QP 15,000* Atomi t e T i - P u r e R-900

D isperse 10-15 minu tes on a h igh-speed m i l l Add t h e f o l l o w i n g w i t h s low a g i t a t i o n .

L e t Down: Rhopl ex R-AC-507 E t h y l e n e g l y c o l Texanol Water

*These i n g r e d i e n t s a r e premixed.

Lbs. 100.0

14.0 3 . 0 3 .0

25.0 2.0

73.0 200.0

550.0 40.0 25.0 32.0

E x t e r i o r Maintenance-Type C o a t i n g

Pigment G r i n d : Water Tam01 -681 8ubreak 448 I g e p a l CTA-639 E-845 T i -Pure R-900 Atomi t e Mica Kadox 911

D isperse 10-15 minu tes on a h igh-speed m i 11. Add t h e f o l l o w i n g w i t h s low a g i t a t i o n .

L e t Down: Rhopl ex MV-23 Texanol E t h y l e n e g l y c o l Water

Lbs. 100.0

14.0 3.0 3 .0

40.0 150.0 191 . o

25.0 12.0

527.0 5 .0

30.0 30.0

&& 9 . 3 7 1 .31 0 .28 0.28 2 . 3 4 0.19 6.84

18.74

51.55 3 .75 2.34 3.01

Wt% 8 .85 1 .24 0 .27 0.27 3 .54

13.27 16.90 2.21 1.06

46.64 0 .44 2.65 2.66

SOURCE: Buckman L a b o r a t o r i e s : B u t r o l 35: F o r m u l a t i o n Suggest ions

Enamels 47

Semi gloss Enamel

Inq red ien ts : Piament Grind: WaIer C e l l o s i z e Hydroxyethyl Ce l l u lose ER-15,000 Nuosept 145 Tamol 731 T r i t o n Nonionic Sur fac tan t N-57

Propylene G1 yco l Byk 035 Tronox CR-800

Letdown : Thickener; premix* Ucar Latex 3796 Ucar F i lmer IBT Byk 035 T r i t o n An ion ic Sur fac tan t GR-7M

AMP-95

Pounds

268.2 2.0 2.4 9.2 2.1 1 .o

43.2 1 .o

250.0

29.9 428.4

20.0 1.9 0.5

Gal 1 ons

32.20 0.18 0.25 1 .oo 0.25 0.13 5.00 0.13 7.27

3.48

2.52 0.25 0.06

47.28

Pa

*Premix cons is t s o f 1 : l : l b lend o f Propylene Glycol ; Rohm and Haas' Acrysol SCT-275 thickener:water, respec t i ve l y .

n t Proper t ies : PVC, %: 23.0 Volume So l i ds , %: 31.8 Weight So l i ds , %: 46.0 Weight per Gallon, l b : 10.60 Stormer, KU: 82 I C I , po ise : 0 . 4 pH, i n i t i a l : 8 .5 Freeze-thaw S t a b i l i t y , 3 cyc les : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

F i 1 m P roper t i es : Ref lectance, %: 89.5 Gloss, 60: 59 Cont ras t Rat io, 3-mi l f i l m : 0.967 Flow and Leve l ing :

brushed: Very Good drawdown, NYPC Blade: 8

SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion I-1989A


Semi q l oss Enamel

I ngred i en t s : Pigment Gr ind : Water Propylene Glyco l Tamol 1124 Proxel GXL Col 1 o i d 640 T i -Pure R-900 T r i t o n Nonionic Sur fac tan t N-101 ASP-1 70 Water

Letdown : Water C o l l o i d 640 NeoCar Latex 6040 Water Ucar F i lmer IBT Ammonium Hydroxide, 28% Aqueous S o l u t i o n Ucar Polyphobe 102 Rheology M o d i f i e r Water

Pa in t P roper t i es : PVC, %: 24.9 Volume So l i ds , %: 30.5 Weight So l ids , %: 44.5 Weight per Gal lon, l b : 10.47 Stormer, KU: 88-93 I C I , po ise : 1.1 pH Value: 8.75-9.25 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass

F i l m Proper t i es : Gloss, 20: 20 Gloss, 60: 65 Cont ras t Ra t io , 3 -mi l f i l m : 0.980 ASTM Scrub Cycles, w i t h shim: 1600 Block Resistance, 1 day: Exc Wet Adhesion, 4 hours: Exc Flow and Leve l ing : Exc S t a i n Removal : Exc

Pounds

15.0 55.0

5 . 0 1 . o 2 . 0

230.0 4 .0

15.0 50.0

39.9 1 .o

425.0 100.0 30.0 4 .0

20.0 50.0

Gal 1 ons

1.80 6.35 0.51 0.11 0.26 6.90 0.46 0.70 6.00

4.79 0.13

47.39 12.00 3.79 0.52 2.30 6.00

Source: Ucar Emulsion Systems: NeoCar Polymers: Formula t ion Suggestion E-2481

Enamels 49

Sou the rn P i n e s G loss W h i t e Enamel

I n g r e d i e n t s : Pigment G r i n d : P ropy lene G l y c o l Water Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Byk 023 T i -Pure R-900 Nuosept 145 Water Ammoni um Hydrox i de, 28% Aqueous Sol u t i on

Letdown : Ucar L a t e x 481 B u t y l C a r b i t o l S o l v e n t So l v e n t 142HT T r i t o n A n i o n i c S u r f a c t a n t GR-5M Byk 026 LE-410 Emu1 s i on Ucar Po lyphobe 102 Rheo. Mod. Water S u r f y n o l 104E

Pai n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 1 7 . 6 Volume S o l i d s , %: 41 .1 Weight S o l i d s , %: 53 .1 S to rmer , K U : 90 I C I , P o i s e : 1 . 9 pH Va lue : 8 . 5 - 9 . 5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 12OF, weeks passed: 4 VOC, grams p e r l i t e r : 174

F i l m P r o p e r t i e s : G loss , 60: 88 G loss , 20: 52 F1 ow and Leve l i ng : Exce l 1 e n t Dry - to -Touch, h o u r : 2 Recoat , h o u r s : 4 Wate r /B l i s t e r Res is tance : Exce l 1 e n t

___ Pounds

40 .0 2 0 . 0

9 . 6 2 . 4 2 .5

240.0 1 . 4

1 1 . 1 2 . 0

620.0 1 2 . 8 2 0 . 0

1 . o 1 . o

1 5 . 0 20.0 1 1 . 9 2 . 0

G a l l o n s

4 .62 2 .40 1 . 0 5 0 . 2 7 0 . 3 5 7 . 0 2 0 . 1 6 1 . 3 3 0 . 2 4

71 .84 1 . 6 2 3 . 0 5 0 . 1 2 0 .14 1 . 8 2 2 . 3 0 1 .43 0 . 2 4

SOURCE: Ucar Emuls ion Systems: U l t r a - G l o s s La texes : F o r m u l a t i o n Sugges t ion E-2251 C


Spensol L54 Oranqe Enamel

Materi a1 : Water Ammoni um Hydroxi de Bentone EW

Lbs. Gals. 30.0 3.60 1.1 0.15 3.0 0.14

Premix the above three materials and Cowles grind 15-20 minutes to fully disperse Bentone EW. Then add the following materials under good agitation:

Spensol L54 Surfynol GA Aerosol OT-75 Nalco 2300 Molybdate Orange Water

Pebble or sand mill grind to 7 N . S .

Letdown : _____ Materi a1 : Spensol L54 Surfynol 104H 15% Solution FC430 in Water Ucar SCT-100

Analysis: Pigment Volume Concentration, Pigment/Binder Ratio: 0.5/1 .O Percent Solids, Weight: 39.1 Percent Solids, Volume: 30.0 Viscosity, #4 Ford, Secs.: 80-

Pounds/Gallon: 9.7

VOC (excluding water): Grams/Li ter : 303 Pounds/Gallon: 2.5

Gloss (60): 50-60

pH: 8.5+-0.3

Percent: 9.0

.90

87.3 10.00 4.4 0.50 2.3 0.25 0.5 0.06

125.0 2.70 41.7 5.00

Lbs. 670.9

2.0 2.1 2.3

Gals. 76.85 0.25 0.25 0.25

SOURCE: Reichhold Chemicals, Inc.: Spensol L: Formula 2154-59A

Enamels 51

Waterborne Black Enamel Based on Eootuf 37-143/37-680

XFor ru la No. 3019-28A1

Component A:

Arcosolv PTB 2-Butoxy Ethanol Dowanol PPH

Add f o l l o w i n g i n o rder under a g i t a t i o n :

Wollastokup 10 ES Raven 410

High speed d isperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotuf 37-680 & Gals

78.91 8.91 24.41 3.34

3.68 0.49 7.37 0.04

48.40 20.02

2.00 1.38

Epotuf 37-680 2-Butoxy Ethanol

432.06 48.77 9.54 1.27

Component 0: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uni form: Epotuf 37-1 43 91.85 10.32 Epotuf 37-058 7.95 1.07 2-Butoxy Ethanol 73.09 9.84 Tap Water 98.04 11.77

Wei ght/Gal l o n (Lbs. ) : 8.96 Percent So l i ds (Wt.): 57.50 Percent So l i ds (Vo l . ) : 37.30 PVC (%): 46.30 VOC ( Lbs. /Gal 1 on) : 2.80

SOURCE: Reichhold Chemicals, I n c . : Formula 3019-28A


Waterborne Blue Enamel Based On Epotuf 37-143/37-600

LFormula No. 3019-31Gl

Component A : Epotuf 37-680 Arcosolv PTB 2-8utoxy Ethanol Oowanol PPH

Add following in order under agitation:

Wollastokup 10 ES Sunfast 81 ue 248-3750 Tioxide TR92

High speed disperse to 5 N . S . Add following under agitation:

j&S Gals 133.28 15.04 24.31 3.33 3.63 0.48 7.38 0 .84

64.54 34.37 22.02

Epotuf 37-600 368. 1

2.67 2.29 0.66

1.58

Component B: Mix following under high-speed agitation until uniform: EDotUf 37-143 88.91 Epotuf 37-058 2-Butoxy Ethanol Tap Water

Weight/Gallon (Lbs.): 9.29 Percent Sol ids (Wt . ) : 57.50 Percent Solids (Vol.): 37.30 PVC ( % ) : 46.30 VOC (Lbs./Gallon): 2.83

9.99 7.62 1.03 91 .15 12.14 82.89 9.95

SOURCE: Reichhold Chemicals, Inc.: Formula No. 3019-31G

Enamels 53

Waterborne Dark B lue Enamel Based on Epotu f 37-143/37-600

(Formula No. 3019-31Dl

Component A:


Add f o l l o w i n g i n o rder under a g i t a t i o n :

Wol lastokup 10 ES Sunfast B lue 248-3750

High speed d isperse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotuf 37-680 !& Gals

134.16 15.14 24.47 3.35 3.65 0.49 7.43 0.84

64.97 34.60

Epotuf 37-680 370.85

Component 0 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l un i fo rm:

Epotuf 37-1 43 Epotuf 37-050 2-Butoxy Ethanol Tap Water

89.50 7.67

91.75 83.44

Weight/Gallon ( L b s . ) : 9.12 Percent S o l i d s (Wt.) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC ( % ) : 46.30 VOC (Lbs/Gal lon): 2.83

SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31D

2.68 2.31

41 .86

10.06 1.04 12.22 10.02


Waterborne Green Enamel

XFormula No. 3019-31F) Based on E D O t U f 37-143/37-680

Component A:

Arcoso lv PTB 2-Butoxy Ethanol Dowanol PPH

Add f o l l o w i n g i n o rde r under a g i t a t i o n :

Epotu f 37-680

Wol las tokup 10 ES S u n b r i t e Y e l l o w 75 Sunfas t B lue 248-3750 T i o x i d e TR92

H igh speed d i spe rse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotu f 37-680 2-Butoxy Ethanol

~ Lbs 165.99 23.12

3.47 8.05

78.51 23.71

9.68 9.21

295.72 29.74

Component B: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l un i fo rm:

Epotu f 37-058 6.97

Tap Water 123.78

Epotu f 37-143 82.10

2-Butoxy Ethanol 59.85

Wei ght/Gal 1 on (Lbs . ) : 9.20 Percent Sol i d s (Wt . ) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC ( % ) : 46.30 VOC (Lbs . /Ga l l on ) : 2 .80

SOURCE: Re ichho ld Chemicals, I n c . : Formula No. 3019-31F

18.73 3.17 0.46 0.91

3.24 2.22 0.65 0.28

33.38 3.96

9.22 0.94 7.97

14.86

Enamels 55

Waterborne Oranqe Enamel Based on E p o t u f 37-143/37-600

(Formula 3019-3111

Component A :

A r c o s o l v PTB 2-Butoxy Ethano l Dowanol PPH

Add f o l l o w i n g i n o r d e r under a g i t a t i o n :

Wol las tokup 10 ES Sunbr i t e Ye1 low 74 Novoperm Red F3RK-70

H igh speed d i s p e r s e t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n :

Epotu f 37-680

EpOtuf 37-680

2-Butoxy Ethanol

Lbs 179.20 20.23

22.73 3.11 3.41 0 .45 8.36 0.95

78 * 45 26.52

8 .20

282.39 30.04

Component B: M i x f o l l o w i n g under h igh-speed a g i t a t i o n u n t i l u n i f o r m : EpOtuf 37-143 82.02 Epotu f 37-058 7.80 2-Butoxy Ethanol 60.60 Tap Water 122.11

Wei ght /Gal 1 on ( Lbs . ) : 9 . 1 2 Percent S o l i d s ( W t . ) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC ( % ) : 46.30 VOC ( L b s . / G a l l o n ) : 2 .80

SOURCE: Re ichho ld Chemicals, I n c . : Formula No. 3019-311

3.24 2.49 0 . 7 6

31.87 4 . 0 0

9 . 2 2 1 . o o 8 .07

14.66


Waterborne Red Enamel Based on Epo tu f 37-143/37-6%0

(Formula No. 3019-3181

Component A :



Wol lastokup 10 ES Novoperm Red F3RK-70

High speed d i spe rse t o 5 N . S . Add f o l l o w i n g under a g i t a t i o n :

2-Butoxy Ethanol Tap Water

Epotuf 37-680

Epotuf 37-680

!& 97.48 11 .oo 25.04 3.43

3.73 0.50 9.29 1 .06

60.09 2.48 20.69 1 .92

377.11 18.73 12.91

Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l un i fo rm: Epotuf 37-1 43 80.34 Epotuf 37-058 7.88 2-Butoxy Ethanol 65.27 Tap Water 118.45

Wei ght/Gal 1 on ( Lbs . ) : 8.97 Percent Sol i d s (Wt . ) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC ( % ) : 46.30 VOC (Lbs. /Gal lon) : 2.84

SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-318

42.56 2 .49 1.55

9.03 1.06

14.22 8.69

Enamels 57

Waterborne Red Orange Enamel Based on EDOtUf 37-143/37-600

I f o r m u l a No. 3019-31El

Component A:

A rcoso lv PTB 2-Butoxy Ethanol Dowanol PPH


Epotuf 37-680

Wol l a s t o k u p 10 ES S u n b r i t e Ye l l ow 74 Novoperm Red F3RK-70 T i o x i d e TR 92

H igh speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotuf 37-680 2-Butoxy Ethanol A rcoso lv PTB

Lbs Gals 157.10 17.73 23.40 3.21

3.49 0.46 8.57 0.97

73.31 19.47 8.20 7.56

307.00 25.51

5.40

Component 8: Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l un i fo rm: Epotuf 37-143 84.28 Epotuf 37-058 7.36 2-Butoxy Ethanol 57.28 Tap Water 124.03

Weight /Gal lon ( L b s . ) : 9 .12 Percent S o l i d s (Wt . ) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC ( % I : 46.30 VOC ( L b s . / G a l l o n ) : 2 .80

SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31E

3.03 1.83 0.76 0.23

34.65 3 .40 0.75

9.47 1.00 7.63

14.89


Waterborne Y e l l o w EDOXY Enamel Based on EDOtuf 37-143/37-680

(Formula No. 3019-31Cl

Component A:

A r c o s o l v PT8 2-Butoxy Ethano l Dowanol PPH


Wol las tokup 10 ES S u n b r i t e Y e l l o w 74 T i o x i d e TR-92

H igh speed d i s p e r s e t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

E p o t u f 37-680

E p o t u f 37-680

2-8utoxy Ethano l

Lbs Gal 198.55 22.41 22.56 3.09

3.36 0.45 8.21 0 .93

83.03 32.49 12.63

3 .43 3.05 0 .38

263.53 29.74 26.43 3.52

Component 8 : Mix f o l l o w i n g under h igh-speed a g i t a t i o n u n t i l u n i f o r m : E p o t u f 37-143 80.25 9.02 E p o t u f 37-058 6.91 0.93 2-Butoxy Ethano l 65.03 8 . 6 6 Tap Water 119.86 14.39

Wei g h t / G a l l on (Lbs. ) : 9.23 Percent S o l i d s ( W t . ) : 57.50 Percent S o l i d s ( V o l . ) : 37.30 PVC ( % ) : 46.30 VOC ( L b s . / G a l l o n ) : 2 .40

SOURCE: R e i c h h o l d Chemicals, I n c . : Formula 3019-31C

EnameLF 59

Whisoer ing Pines Semigloss White Enamel

Inq red ien ts : Pigment Gr ind : Propylene G lyco l Water 6yk 023 Tamol 731 T i -Pure R-902 Path 9 Nuosept 145 Water Ammoni um Hydroxi de,

Pounds

30.0 53.3

2.5 10.0

230.0 40.0

1.5 16.7

28% Aqueous Sol u t i on 2.0

Letdown : Ucar Latex 461 Ucar F i lmer I6T Sol vent 142HT LE-410 Emulsion Ucar Polyphobe 102 Rheo. Mod Water Su r f yno l 104E

556.0 12.4 31.5 15.0 16.9 19.7 2.0

Gal 1 ons

3.47 6.40 0.35 1.09 6.92 1.98 0.17 2.00 0.94

64.66 1.57 4.80 1 .BO 1.94 2.37 0.24

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 23.3 Volume So l i ds , %: 39.2 Weight So l i ds , %: 51.5 Stormer, KU: 93 I C I , Poise: 2.1 pH Value: 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F. weeks passed: 4 VOC, grams pe r l i t e r : 181

F i l m Proper t i es : Gloss, 60: 54 Gloss, 20: 14 Flow and Leve l ing : Exce l l en t Dry-to-Touch, hour: 2 Recoat, hours: 4 Water/61 i s t e r Resistance: Excel l e n t

SOURCE: Ucar Emulsion Systems: U l t ra -Gloss Latexes: Formula t ion Suggestion E-2245C


Anquamine 401 1 : l Wh i te Gloss Enamel

P a r t A : j& Gals Epi -Rez 3520-WY-55 Epoxy Res in (She1 1 ) 363.24 39.20 DER 331 Epoxy Res in (Dow) 40.36 4.17 Water S u r f y n o l DF-11OD ( A i r P r o d u c t s )

52.32 6 . 2 7 3 .00 0 .36

P a r t B: Anquami ne 401 C u r i n g Agent ( A i r P r o d u c t s ) 90.46 9 .90 Dowanol PM S o l v e n t (Dow) 40.87 5 . 3 7 Benzyl A l c o h o l 29.97 3.44 S u r f y n o l DF-l10D ( A i r P r o d u c t s ) 3 .00 0 . 3 6 T i P u r e 960 (DuPont) 272.48 8 .16 G l a c i a l A c e t i c A c i d ( A i r P r o d u c t s ) 5 . 3 1 0 . 6 1 Water 185.01 22 .16

T y p i c a l P r o p e r t i e s : W t S o l i d s ( % ) : 65.84 Res in S t o i c h i o m e t r y : 1 .3 :1 Volume S o l i d s ( 3 6 ) : 40.95 VOC ( l b / g a l ) : 1 .53 PVC ( % ) : 1 9 . 9 4 VOC ( g / l ) : 184

Wh i te G1 oss Enamel P r o p e r t i es : Pot L i f e , h r : >4 G loss , 60 spec, 1 day: >90 G loss , 60 spec, 4 week: >90 M i x R a t i o : 1 : l Mixed V i s c o s i t y , cP: 290 Tack F r e e Time, h r : 1 Hard Dry Time, h r : 6-8 P e n c i l Hardness, o v e r n i g h t : HB P e n c i l Hardness, 7 days: H Cross Hatch Adhesion: 5 1 /8 " Mandrel Bend: Pass D i r e c t Impact Res is tance , i n - l b s : 60 Reverse Impact Res is tance , i n - l b s : 20 VOC, l b / g a l : 1 . 6 Volume S o l i d s , % : 41 PVC, Yo: 19 .9

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Aquamine 401 C u r i n g Agen t : F o r m u l a t i o n 1

Enamels 61

Anquamixe-401/Sol i d R e s i n D i s p e r s i o n 2 : 1 W h i t e -Gloss Enamel

P a r t A: Lbs G-a 1 s Epi -Rez 3520-WY-55 Epoxy Res1 n (She1 1 ) 5 5 7 . 4 6 1 . 2 6 Water 4 5 . 1 5 . 4 1

P a r t B : Anquamine 401 C u r i n g Agent ( A i r P roduc ts ) 7 2 . 5 7 . 9 3 Dowanol PM S o l v e n t (00,) Dowanol EPh S o l v e n t (Dow) Defoamer T i Pure R960 (DuPont) G1 a c i a1 A c e t i c A c i d ( A i r P roduc ts ) Water

2 6 . 0 3 . 4 2 1 7 . 0 1 . 8 5

4 . 0 0 . 5 0 2 2 7 . 7 6 . 8 2

2 . 0 0 . 2 3 1 0 5 . 0 1 2 . 5 8

T y p i c a l P r o p e r t i e s : W t S o l i d s ( % ) : 7 4 . 2 6 Res in S t o i c h i o m e t r y : 1 . 5 8 : l Volume Sol i d s (%) : 4 3 . 0 3 VOC ( l b / g a l ) : 1 . 2 6 PVC ( % I : 1 5 . 8 5 VOC ( g / l ) : 151

Whi te G loss Enamel P r o p e r t i e s : Pot L i f e , h r : > 6 Gloss , 60 spec, 1 day: >90 Gloss, 60 spec, 4 w k : > 9 0 M i x R a t i o : 2 : l Mixed V i s c o s i t y , cP: 360 Tack F ree Time, h r : 1 Hard D r y Time, h r : 6-8 P e n c i l Hardness, o v e r n i g h t : HB P e n c i l Hardness, 7 days : H Cross Hatch Adhesion: 5 1/8" Mandrel Bend: Pass D i r e c t Impact Res is tance , i n-1 b s . : 60 Reverse Impact Res is tance , i n - l b s . : 20 Taber Abras ion , mg loss/lOOO c y c l e s : 9 0 VOC, l b / g a l : 1 . 8 Volume Sol i d s , '%: 4 3 PVC, % : 1 6 . 5

SOURCE: A i r P r o d u c t s and Chemicals , I n c . : Anquamine 401 C u r i n g Agent : Formul a t i on 2

Enamels-Baking 63

Clear Bake Coat ins Pounds Gal l ons Mater i a1 : _ _ _ ~

Epi -Rez 3551 -WY-43 Resi n 617.04 68.56

Ektapro EEP 16.14 2.04 Bee t le 80 188.87 20.87 Water 71 .OS 8.53 Typ ica l Coat ing P roper t i es :

Add under a g i t a t i o n :

To ta l Weight So l ids , %: 51.8 To ta l Volume So l i ds , %: 47.4 Pounds/Gallon: 8.93 Epoxy/Urea, based on s o l i d s , %: 60/40 V o l a t i l e Organic Compounds (VOC):


V iscos i t y , #4 Ford Cup, seconds: 60-70

Dry F i l m Thickness: 0.7 m i l Subs t ra te : Bonder i te 1000 Bake Schedule a t 350F, minutes: 20 Penc i l Hardness: 6H Reverse Impact, i n . l b s . : 160 M€K Double Rubs: 100

Typ ica l F i l m Proper t ies :

S t a r t i n g Formulat ion No. 2503: Epi-Rez 3551-WY-43 Resin

Phenol i c Clear Bake Coat ing Pounds Gal l ons Mater i a1 :

Epi -Rez 3540-WY-55 Resin 439.6 48.07 _ _ _ ~

Methyl I s o b u t y l Ketone 98.8 14.81 Dei oni zed Water 98.8 11.85 S i lwe t L-7604 Sur fac tan t 2.4 0.28 Santol i n k EP-560 193.3 21.15 Dimethylethanolamine 19.1 2.54 Syntex 3981 Acce le ra to r 9.1 1.30 Typ ica l Coat ing P roper t i es :

To ta l Weight So l i ds , %: 46.8 To ta l Volume So l i ds , %: 42.7 Pounds per Gal lon: 8.61 Epoxy/Phenol i c, sol i d s : 60/40 Percent Ca ta l ys t , Ac t ive , on Resins So l i ds : 0 . 5 V o l a t i l e Organic Compounds (VOC):


V iscos i t y , B rook f i e ld , #5 Spind le a t 50 RPM, cps: 1,200

Dry F i l m Thickness: 0.5 m i l s Substrate: Bonder i te 1000 Bake Schedule: 10 minutes a t 400F Penc i l Hardness: 6H Reverse Impact, i n . l b s . : 160 MEK Resistance, double rubs: 100

Typ ica l F i l m Proper t ies :

S t a r t i n g Formulat ion No. 2504: Epi-Rez 3540-WY-55 Resin

SOURCE: She l l Chemical Co.: S t a r t i n g Formulat ions


Clear H i q h Gloss, Bakina F i n i s h

Mater i a1 : Lbs. Cymel 303 premi x--combi ne i n t h e f o l l ow ing o rde r : Cymel 303 57 .6 Isopropanol 4.5 Nacure 2500-X 4 .5 T r ie thy lam ine 0.6 Water 28.8 Add i n f o l l o w i n g order w i t h a g i t a t i o n : Spensol L51 768.1 Cymel 303 Premix 96.0 Aerosol OTS 5 . 4 Lodyne S107B 5.4 Byk 301 3.1 Cure f o r 2 hours a t 250F o r 30 minutes a t 300F.

Ana lys i s : R a t i o o f Spensol L51 t o Cymel 303: 80:20 Percent So l i ds , Weight: 33.8 Percent So l i ds , Volume: 30.1 VOC (exc lud ing water ) :

Grams/Li t e r : 189 Pounds/Gallon: 1 .6

Formula t ion 2061-40D

B l u e Metal 1 ic Urethane Enamel

M a t e r i a l : Lbs. Component A--add i n f o l l o w i n g order w i t h a g i t a t i o n : Spensol L51 707.9 Premix t h e f o l l o w i n g two mate r ia l s , then add: A1 umi num Paste #E2255 30.0 Water 31 .2 Add : Aurasperse W4123 92.0 Sur fyno l 104H 4.0 Lodyne 51076 1 .5 Component B: XAMA-7 7.4

NOTE: Add t h e above Component B t o Component A p r i o r t o

Ana lys i s :

t i o n and mix w e l l f o r 5 t o 10 minutes.

Percent Sol i d s , Weight : 31 .8 Percent So l i ds , Volume: 28.4 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 25-30

VOC (exc lud ing wa te r ) : Grams/Li ter : 408 pH: 8.0-8.5

Pounds/Gallon: 3 . 4 Formula t ion 2099-19

Gals.

5.76 0.68 0.55 0 .10 3.46

87.88 10.55 0.63 0.56 0.38

Gals.

81 .oo

2.34 3.75

11.50 0.50 0.16

0.75

appl i ca-

SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulat ions

Enamels-Baking 65

Exper i ren ta l Water-Reducible Po lyes ter Gloss White Baking Enamel Usina Halox SZP-391

Grind: W/R Po lyes ter 72-7203 DMEA Cyme1 303

Lbs./lOO Gals. Gms/Liter 170.0 204.0

10.0 12.0 50.0 60.0

Premix t h e nex t two raw m a t e r i a l s be fore adding.

n-Butyl Alcohol Dow Corning 14 R-902 T i02 Halox SZP-391 Deionized Water

High Speed Disperse t o 7 Hegman g r i n d .

Letdown :

W/R Po lyes ter 72-7203 DMEA n-Octyl Alcohol Troysol LAC n-Butyl Alcohol Deionized Water

Mix u n t i l un i fo rm - Do not aera te !

Hold f o l l o w i n g f o r v i s c o s i t y adjustment.

8.0 9.6 0.8 I . o

225.0 275.0 15.0 18.0 50.0 60.0

100.0 120.0 15.0 18.0

1 .o 1.8 1.5 1.8

10.0 12.0 325.0 390.0

Deionized Water 55.0 66.0

Formula Constants: % P i gment/Wt . : 23.16 % Pigment/Vol . : 7.25 % Sol ids/Wt. : 48.24

Formula P roper t i es : Densi ty 1 bs. /ga l . : 10.36 Densi ty g/L: 1,249 Visc. #2 Zahn (sec.

% So l i ds /Vo l . : 33.12 pH @ R . T . : 8.5-9.0 % PVC: 21.85 VOC, l b s . / g a l . : 2.03 VOC, g/L: 304.5

SOURCE: Halox Pigments: Suggested Formulat ion PEG39

: 50-60


Waterborne A c r y l i c Bake Enamel

The WR-17 study was conducted t o demonstrate t h e improved co r ros ion res i s tance a f fo rded a waterborne system by choosing a more hydrophobic c a t a l y s t , Nacure 155 (DNNDSA), over a more h y d r o p h i l i c c a t a l y s t , K-Cure 1040 (p-TSA). Free a c i d c a t a l y s t , r a t h e r than t h e blocked vers ions , were used i n t h i s s tudy , s ince t h e formula a l ready conta ined a n e u t r a l i z i n g amine. A summary o f t he fo rmu la t i on , i t s phys i ca l p r o p e r t i e s and t e s t r e s u l t s a re l i s t e d below.

G r i nd Composit ion : T i tanox 2020 Acrysol WS-68 2-Butoxyethanol n-Butanol DMEA 0.1. Water

(Pebble M i l l Gr ind t o 7 t on Hegman)

Letdown Composi t i on : Acrysol WS-68 n-Butanol Hexamethoxymethylmelamine 2-Butoxyethanol *DMEA (10% i n water) * O . I . Water

*Used t o a d j u s t pH and v i s c o s i t y

C h a r a c t e r i s t i c s : P i gment/Bi nder : 40/60 Ac ry l i c/Mel ami ne: 80/20 To ta l S o l i d s , %: 37.7 To ta l Resin So l i ds , %: 22.6 Wt . /ga l . C 25C ( l b / g a l ) : 9.65 V . O . C . (Measured) l b . / g a l . : 1.84

A p p l i c a t i o n and Cure: Subs t ra te : Bonder i te 1000 ( i r o n phosphated CRS) Cure Schedule: 15' a t 149C (300F) F i 1 m Thickness : 0.7-0.8 m i 1

Wt% 15.07 3.97 0.67 0.63 0.90 4.69

43.63 0 .54 4.51 3.90 2.20

20.10

F i l m Proper t i es : Cont ro l K-Cure 1040 Nacure 155 p-TSA DNNDSA

Penc i l Hardness H-2H Tukon Hardness, KNH25 13.2 MEK Rubs (2X) 24 Impact Resistance, ( i n - l b s . ) Reverse 90-100 O i r e c t 40-50

Crosshatch Adhesion, % Loss 100 S a l t Spray, 150 h r s . (ASTM 8117)

mm Creep /B l i s te r : 6-7mm/10 6

H-2H H-2H 13.2 13.0

42 50

20-1 30 90-1 00 30-40 30-40

100 100

7mm/lO 3-4mm/ 0

SOURCE: K ing I n d u s t r i e s : Formula t ion WR-17

Enamels-Baking 67

Water Reduc ib le P o l v e s t e r Bak ing Enamel

I n t h i s s t u d y Nacor r c o r r o s i o n i n h i b i t o r s were i n c o r p o r a t e d i n t o a p igmented waterborne p o l y e s t e r system c r o s s l i n k e d w i t h a h i g h -NH t y p e melamine r e s i n . The Nacor rs were added a t a l e v e l o f 3%, based on t h e t o t a l f o r m u l a w e i g h t . S i n c e t h e Nacor rs a l s o f u n c t i o n as d i s p e r s i n g agents, t h e r e i s a d e f i n i t e advantage i n i n c o r p o r a t i ng them i n t o t h e d i s p e r s i ng s tage.

G r i n d (Pebble M i l l ) : T i -Pure R-960 Carg i 11 72-7203 2-Butoxyethanol Nacor r Water DMEA Letdown : Carg i 11 72-7203 DMEA Cyme1 327 S i l w e t 7605 (10% i n 2 -bu toxyethano l ) Water

C o n t r o l Nacor r 24.00 24.00 18.00 17.81

4.00 2.50 ---- 3.00 1.31 0.69

6.00 6.19 1 .oo 1 .69 6.67 6.67 1 .oo 1 .oo

37.33 37.14

---- ----

C h a r a c t e r i s t i c s : C o n t r o l Nacorr Pol yes ter /Me l ami ne R a t i o 75/25 75/25

Pigment, % 24 24 T o t a l Res in S o l i d s , % by we igh t 24 24 A d d i t i v e l e v e l , % based on t o t a l we igh t o f p a i n t -- 3.0 F i l m P r o p e r t i e s :

P igment /B i nder R a t i o 1 / I 1 / I

S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS Cure: 10 minutes/300F (149C) F i l m Th ickness : 16-21 mic rons

P e n c i l Hardness Tukon Hardness KHN25

C o n t r o l N-1151 N-1351 2H-3H 2H-3H H-2H

16.6 17.7 11 . o MEK Rubs (2X) 65 Impact ( i nch 1 bs . ) , Reverse 5-10

D i r e c t 70-80 Gloss, 60 9 1 . 4 S a l t Spray, 408 h r s . 13/D3 F i l m P r o p e r t i e s :

S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated Cure: 10 minutes/250F (121C) F i l m Th ickness : 16-21 mic rons

C o n t r o l Penci 1 Hardness H-2H Tukon Hardness KHN25 11.1 MEK Rubs (2x1 12 Impact ( i nch 1 bs . ) , Reverse (5

D i r e c t 60-70 Gloss, 60 93.3 S a l t Spray, 408 h r s . 13/MD4

SOURCE: K i n g I n d u s t r i e s : Nacor r WR-18

64 5-10

60-70 90.6 2/10

CRS

N-1151 H-2H 12.2

13 <5

60-70 94.7 2/10

24 5-10

60-70 92.2 2/F8

N-1351 HB-F

6 . 7 12

5-10 50-60

93.3 3F/2


Spensol L54 White Bakina Enamel

____ Mate r i a1 : Speneol L54 Water Ammonium Hydroxide Sur fyno l GA Aerosol OT-75 Foamki 11 639AA T i tanox 2101

Lbs. 87.3 75.0

1.9 4.4 2.3 1 .1

200.0

Pebble o r sandmil l g r i n d the above m a t e r i a l s t o 7+ N . S .

Letdown : Spensol L54 536.9

Gals. 10.00 9.00 0.25 0.50 0.25 0.15 5.85

61.50

Premix t h e nex t f o u r ma te r ia l s , then add under good a g i t a t i o n .

Cyme1 385 DMEA Isopropanol Water

Add t h e f o l l o w i n g under good a g i t a t i o n :

Sur fyno l 104H Versa-Flow 102

Bake schedule: 10 minutes a t 300F (150C).

Ana lys is : Pigment Volume Concentrat ion, Percent: 18 Pigment/Binder Ra t io : 0.8/1 .O Percent So l i ds , Weight: 44.7 Percent So l i ds , Volume: 32.6 V i s c o s i t y @ 25C, #4 Ford, Secs. : 30

Pounds/Gal l o n : 10.3

VOC ( e x c l ud i ng water) : Grams/Li ter : 240 Pounds/Gal 1 on : 2

Gloss (60): 60-70

pH: 8.3+-0.3

62.1 5.75 1.8 0.25 6.8 1 .oo

41.7 5.00

2 . 0 0.25 2.0 0.25

SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formula 2154-598

Enamels-Baking 69

?-Component Waterborne SysteE

Formu la t i on WR-41 demonstrates t h e improved performance o f a 2-component waterborne system when m o d i f i e d w i t h K-Flex XM-4316, a p o l y e s t e r - u r e t h a n e d i s p e r s i o n . A t b o t h NCO/OH r a t i o s , improvements were made i n g loss , M E K r e s i s t a n c e , and f l e x i b i l i t y .

NCO/OH R a t i o : 1 . 1 A c r y l i c / P U - D i s p e r s i o n : 80/20

Component A : Emulsion E-3275 K-F1 ex XM-4316 Sodium N i t r i t e (5% aq) Prog lyde DMM Edaplan LA 402 S i l w e t 7001 (5% aq) S i l w e t 7605 (25% aq) S i l w e t 7604 (25% aq) Dimethy lethanolamine

Component 0: Bayhydur XP-7063

Formu la t i on C h a r a c t e r i s t i c s : N o n v o l a t i l e , t h e o r e t i c a l , % : 46.3 T h e o r e t i c a l VOC, g /L, ( l b / g a l l o n ) : 60, ( 0 . 5 )

Formula t ion P roper t Gloss 60, %: 95

20, %: 69 Koenig Hardness Penc i l Hardness:

es, A i r - D r y 20-25C, 2 weeks:

s e c ) : 69 H-2H

Knoop Hardness: 2 . 4 MEK Double Rubs: 80 Impact, D i r e c t , i n c h . l b . : >160 Impact, Reverse, i n c h . l b . : >160

W t % 71 .38 17.40

0 . 0 0 0 . 8 9 0.07 0 . 0 0 0.25 0 .25 0.73

9 .03

Fo rmu la t i on P r o p e r t i e s , Bake 8OC 20 min . Pos t -cure 20-25C, 2 weeks : Subs t ra te : Bonder i t e 1000 c o l d r o l l e d s t e e l F i l m t h i ckness , mic ron (mi 1 . ) : 32+-2 (1.3+-0.1) NCO/OH R a t i o : 1 . 1 Knoop Hardness: 3 .7 Gloss 60, %: 96 MEK Double Rubs: 120

Koenig Hardness ( s e c ) : 89 Impact, Reverse, i n c h x l b . : 160 Penc i l Hardness: 2H

20, %: 66 Impact, Forward, i n c h x l b . : ,160

Fo rmu la t i on P repara t i on :

a g i t a t i o n f o r approx. 5 minu tes .

SOURCE: K ing I n d u s t r i e s : P r e l i m i n a r y Fo rmu la t i on WR-41

Add component B t o component A under low shear mechanical

Exterior Paints and Related Products 71

E x t e r i o r F l a t House P a i n t w i t h ZnO

I n q r e d i e n t s : P i gment G r i nd : Water Ucar Po l yphobe 9831 Rheology Modi f i e r Ammonium Hydrox ide , 28% Aqueous S o l u t i o n P r o x e l GXL C o l l o i d 226/35 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t X-100 Propy lene G1 y c o l Potass ium T r i p o l y p h o s p h a t e (KTPP) T i -Pure R-706 417-W Z i n c Ox ide Minex 4 N y t a l 300

___. Pounds

236.2 9 . 5 1 . 8 2 .0 8 . 5 1 . 9 3 . 3

25 .9 1 . 5

225.0 2 5 . 0

1 2 5 . 9 5 0 . 0

Letdown : Ucar L a t e x 625 426.4 B u t y l C a r b i t o l S o l v e n t 1 0 . 7 C o l l o i d 640 1 . 9 Skane M-8 2 . 2 Ammonium Hydrox ide , 28% Aqueous S o l u t i o n 0 . 9

P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 40.0 Volume S o l i d s , %: 38.0 Weight S o l i d s , % : 5 5 . 6 Weigh t p e r G a l l o n , l b : 11 .59 Stormer , KU: 95 I C I , P o i s e : 1 . 1 pH Va lue : 8 . 9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2

F i 1 m P r o p e r t i es : C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.969 R e f l e c t a n c e , %: 9 1 . 9 Sheen, 8 5 : 8 Wet Adhes ion , g l o s s a l k y d : E x c e l l e n t F low and L e v e l i n g : Good Sag R e s i s t a n c e , m i l s : >12

Gal l o n s

28 .30 1 . 1 0 0 . 2 0 0 .20 0 . 8 0 0 .30 0 . 4 0 3 .00 0 . 1 0 6 . 6 0 0 . 6 0 5 . 8 0 2 . 1 0

48 .40 1 . 4 0 0 .30 0 .30 0 .10

SOURCE: Ucar Emuls ion Systems: Ucar Po lyphobe 9831 Rheology M o d i f i e r : F o r m u l a t i o n Sugges t ion E-2483


E x t e r i o r F l a t House P a i n t w i t h ZnO

I n q r e d i e n t s : Pigment Gr ind : Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydroxide, 28% Aqueous S o l u t i o n Proxel GXL Col 1 o i d 226/35 C o l l o i d 640 T r i t o n Nonionic S u r f a c t a n t X-100 Propylene G1 y c o l Potassium Tr ipo lyphosphate (KTPP) T i -Pure R-706 417-W Z inc Oxide Minex 4 N y t a l 300

Pounds

227.2 18.5

1 .8 2 . 0 8.5 1 .9 3.3

25.9 1 .5

225.0 25.0

125.9 50.0

Letdown : Ucar Latex 625 426.4 Ucar F i l m e r I B T 10.7 C o l l o i d 640 1 .9 Skane ME 2.2 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9

Pai n t P roper t i es : P i gment Vol ume Concentrat ion, %: 40.0 Volume So l i ds , %: 38.0 Weight S o l i d s , %: 55.6 V i s c o s i t y , equi 1 i b r a t e d :

Stormer, KU: 98 I C I , Poise: 1 .5

Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Aged S t a b i l i t y , 120F, weeks passed: 2

F i l m P r o p e r t i e s : Con t ras t R a t i 0, 6 - m i 1 wet drawdown : 0.968 Ref lectance, %: 91.9 Sheen, 85: 7 Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass Wet Adhesion, g l o s s a l kyd : E x c e l l e n t

Gal l o n s

27.30 2.10 0.20 0.20 0.80 0.30 0.40 3.00 0.10 6.60 0.60 5.80 2.10

48.40 1.40 0.30 0.30 0.10

SOURCE: Ucar Emulsion Systems: Ucar La tex 625: Fo rmu la t i on Suggest ion E-2463


E x t e r i o r Gloss Whi te

I n q r e d i e n t s : Pigment Gr ind : Water Ammonium Hydrox ide, 28% Aqueous S o l u t i o n Sol ven t 142HT Tamol 165 Potassium Tr ipo lyphosphate (KTPP) T r i t o n Non ion ic S u r f a c t a n t CF-10 Proxe l GXL Byk 023 T i -Pure R-706

Letdown : Ucar La tex 481 Sol vent 142HT Byk 025 B u t y l C a r b i t o l So lven t Water Ammonium Hydrox ide, 28% Aqueous S o l u t i o n Ucar Pol yphobe 9831 Rheology Modi f i e r

P a i n t P r o p e r t i e s : Pigment Volume Concent ra t ion , %: 19.8 Volume S o l i d s , %: 33.9 Weight S o l i d s , %: 45.8 Weight pe r Ga l l on , l b : 10.28 Stormer, KU: 95 I C I , Po ise : 1.8 pH Value: 9-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0-1 Heat Age S t a b i l i t y , 120F, weeks passed: 4 V o l a t i l e Organ ic Content , g/L: 120

F i l m P r o p e r t i e s : Gloss, 60: 77 Gloss, 20: 34 F1 ow and Level i ng : Excel 1 e n t Dry-to-Touch, hours : 2 Recoat, hours : 4-6 Water /B l i s t e r Resi s tance: Good

Pounds

112.0 1 . o

10.0 13.7

0 .5 3 .0 2 .0 2.5

225.0

519.0 10.0 2.0

26.0 8 5 . 6

1 . o 14.8

G a l l o n s

13.40 0.10 1.50 1.50 0.03 0.40 0.20 0.30 6.80

58.60 1.50 0.30 3.30

10.10 0.10 1.70

SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology Modi f i e r : Formu la t i on Suggest ion E-2482


E x t e r i o r House P a i n t

Ma te r i a1 : Grind: Water Nuosept 95 (Nuodex) Tamol 731 (Rohm and Haas) Igepa l CO-630 (GAF) Ti-Pure R-902 (DuPont) Beaverwhite 325 Ta lc (Cyprus) 325 W.G. Mica (Unimin) FCA (Foam Cont ro l Agent)

Premix and add: Ethylene Glyco l Texanol (Eastman) Nat roso l P lus 330 PA (Aqualon)

Letdown : Water 248-5809 (McWhorter) FCA (Foam Cont ro l Agent) Water

P roper t i es : Pigment Volume Content, %: 31.2 % N o n v o l a t i l e (by we igh t ) : 54.6 % N o n v o l a t i l e (by volume): 39.3 VOC. g / l : 126 Stormer V iscos i t y . K . U . : 90+-5 I C 1 V i s c o s i t y , Poise: 1+-0.1 Gloss a t 60, %: 0-5

Recommended Products: Ag i tan 260, 315 o r 731

- Lbs

101.6 12.20 1.5 0.16 7.5 0.82 3.4 0.38

213.3 6.23 111.7 1.07 25.4 4.99 4.5 0.20

23.6 2.54 5.9 0.74 4.0 0.36

125.0 15.01 437.8 48.03 3.0 0.39

50.0 6.10

SOURCE: K ing I n d u s t r i e s : Formula t ion WR-39: F C A ' s f o r Trade Sales P a i n t


E x t e r i o r House P a i n t - T i n t Base

Ina red ien ts : Pigment Grind: Water Ucar Polyphobe 102 Rheo. Mod. Ammoni um Hydroxide, 28% Aqueous Sol u t i on Proxel GXL Tamol 1124 C o l l o i d 640 T r i t o n Non ion ic Sur fac tan t N-101 Propylene G lyco l Tronox CR-828 Minex 4 H y d r i t e F l a t D

Pounds

209.6 19.6

1.8 2.0 5 . 0 1 .9 3.2

25.9 150.0 125.0 75.0

Gal 1 ons

25.20 2.10 0.20 0.20 0.50 0.30 0.40 3.00 4.40 5.80 3.50

Letdown : Ucar Latex 625 455.9 51.80 Ucar F i lmer IBT 11.4 1.40 C o l l o i d 640 1.9 0.30 Troysan Polyphase AF-1 7.3 0.80 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0.9 0.10

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 35.8 Volume So l i ds , %: 38.0 Weight So l i ds , %: 53.2 V i s c o s i t y , e q u i l i b r a t e d :



F i l m P roper t i es : Cont ras t Ra t io , 6-mi l wet drawdown: 0.956 Ref lectance, %: 90.1 Sheen, 85: 7 Color Acceptance: E x c e l l e n t Color F l o a t : Good Wet Adhesion, 4-hr: E x c e l l e n t Flow and Leve l ing , ASTM D-4062: 8 F i l m B u i l d , s q . f t . / g a l . : 411 Low Temperature Coalescence:

sealed: 10 unsealed: 10

SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formulat ion Suggestion E-2460


E x t e r i o r Sen ia loss

~ _ _ _ Pounds Gal 1 ons I n q r e d i en t s : Pigment Gr ind : Water Nuosept 95 Propylene G1 yco l Tamol 1124 Ammonium Hydroxide (28% Aqueous So lu t i on ) T r i t o n Non ion ic Sur fac tan t N-57 C o l l o i d 653 T i -Pure R-700

Letdown : Water Ucar Pol yphobe 102 Rheology Modi f i e r Ucar Latex 2300 Ucar F i lmer IBT Col l o i d 653 Troysan Polyphase AF-1 T r i t o n An ion ic Sur fac tan t GR-7M

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 22.0 Volume So l ids , %: 32.6 Weight So l i ds , %: 47.2 Weight per Gal lon, l b : 10.43 Stormer, KU: 99 I C I , Poise: 1 .26 pH Value: 8.0 Freeze-Thaw S t a b i l i t y , cyc les passed: 7

F i l m Proper t i es : Gloss, 60: 78.3 Gloss, 20: 39.6 Cont ras t Ra t io , 6-mi l wet drawdown: 0.964 Reflectance, %: 91.8 Scrub Resistance, cyc les passed: 161

150.0 18.96 2.3 0.25 60.5 7.00 7.4 0.75 2.0 0.25 2.1 0.25 1.9 0.25

250.0 7.16

91.5 10.99 13.1 1 .so

447.7 50.88 11.2 1.41 2.8 0.37 7.3 0.75 1.1 0.13

SOURCE: Ucar Emulsion Systems: Formula t ion Suggestion E-2263


E x t e r i o r Semisloss Formulat ion

Inq red ien ts : P i gment G r i nd : Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammonium Hydroxide, 28% Aqueous So lu t i on Propylene Glycol Troysan 586 Tamol 1124 C o l l o i d 643 T r i t o n Nonionic Sur factant N-57 Tronox CR-828 Polygloss 90

Pounds

190.0 17.4

1.8 60.5

1.8 5.3 1.8 2.1

250.0 25.0

Letdown : Water 1 5.5 Ucar Polyphobe 102 Rheology M o d i f i e r ) Premix 4.4 NeoCar Latex 2300 474.4 C o l l o i d 643 1.8 Ucar F i lmer I B T 15.8 Troysan Polyphase AF-1 7.4 T r i t o n Anionic Sur factant GR-7M 1 . 1 Ammonium Hydroxide, 28% Aqueous So lu t i on 1.8

Gal 1 ons

22.80 2.00 0.23 6.99 0.19 0.54 0.23 0.25 7.50 1.15

0.66 0.51

53.61 0.23 1.99 0.74 0.13 0.23

Note: If wet adhesion i s desired, b lending w i t h an a c r y l i c res in , such as Ucar Latex 625, i s recommended.

Pai n t P roper t i es : PVC, %: 23.6 Volume Sol ids, %: 38.7 Weight Sol ids, %: 52.6 Weight per Gallon, l b : 10.68 Stormer, KU: 99 I C I , poise: 1 .5 pH Value: 8.7 Freeze-Thaw S t a b i l i t y , 3 cyc les: Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: pass

Fi 1 m Propert i es : Ref lectance, %: 92.3 Gloss, 20: 19 Gloss, 60: 59.5 Flow and Level ing: Exc Color Acceptance: Exc

SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulat ion Suggest i on E-2264

78 Water -Based Paint Formulations

E x t e r i o r T i n t Base Fo rmu la t i on

I nqred i en t s : Pigment Gr ind : Water Ucar Pol yphobe 102 Rheology Modi f i e r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Troysan 586 Tamol 1124 C o l l o i d 640 T r i t o n Non ion ic S u r f a c t a n t N-101 Propylene G1 yco l Tronox CR-828 Minex 4 H y d r i t e F l a t D

Pounds

197.4 15.2

1 .8 2.0 5.0 1 .9 3.2

25.9 150.0 125.0

75.0

Letdown : Water 3 .8 Ucar Latex 625 319.2 Ucar Latex 461 145.5 Ucar F i l m e r IBT 11.4 C o l l o i d 640 1 .9 Troysan Polyphase AF-1 7 . 3 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 0 .9

Pai n t P roper t i es : Pi gment Vol ume Concentrat i on, %: 35.8 Volume S o l i d s , %: 38.0 Weight pe r Ga l l on , l b : 10.9 Stormer, KU: 83 I C I , Po ise: 0.95 pH Value: 9 .6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2 R a t i o o f Ucar Latexes 625:461: 70:30

F i lrn P r o p e r t i e s : Sheen. 85: 9 . 2

Gal l o n s

23.7 1 .7 0 . 3 0.2 0 .5 0 .3 0 .4 3.0 4 .4 5.8 3 .5

0.5 36.3 16.9

1 .4 0 .3 0.8 0 .1

Con t ras t Rat io , 6-mi l wet drawdown: 0.952 Dry Adhesion ( u n t r e a t e d aluminum, ga lvan ized s t e e l , a1 kyd

Wet Adhesion ( u n t r e a t e d aluminum, ga lvan ized s t e e l , a l k y d

B1 i s t e r i ng ( u n t r e a t e d a1 umi num, g a l vani zed s t e e l , a1 kyd

and l a t e x c h a l k ) : Exc

and l a t e x cha lk , g l o s s a l k y d ) : Exc


SOURCE: Ucar Emulsion Systems: Ucar Latex 461: Fo rmu la t i on E-2474


E x t e r i o r T r i m F o r m u l a t i o n Modi f i ed V i nv l A c r v l i c P a i n t

I n q r e d i e n t s : P i ament G r i nd: WaTer Ucar Po l yphobe 102 Rheology Modi f i e r Ammonium Hydrox ide , 28% Aqueous S o l u t i o n Propy lene G l y c o l Nuosept 95 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90

Letdown : Water Ucar Po l yphobe 1 14 Rheology Modi f i e r B u t y l C a r b i t o l S o l v e n t Ucar F i l m e r I 8 T Ucar La tex 3796 Ucar La tex 633G C o l l o i d 643 Troysan Polyphase AF-1 Byk 346 Ammonium Hydrox ide, 28% Aqueous S o l u t i o n

Pai n t P r o p e r t i as : Pigment Volume C o n c e n t r a t i o n , %: 24.2 Volume S o l i d s , %: 35.0 Weight p e r G a l l o n , l b : 10 .7 Stormer, KU: 96 I C I , P o i s e : 1 .2 p H Value: 7 .6 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2 R a t i o o f Ucar La texes 379G:6336: 70:30

F i l m P r o p e r t i e s : Gloss, 60: 46 Gloss, 20: 10 C o n t r a s t R a t i o , 6 -mi l wet drawdown: 0.967 Ref lec tance, %: 91.8 B l o c k Res is tance: 8

Pounds

98.5 19.3

1 .8 59.6

2 .3 7.3 1 . 9 2 . 1

246.3 24.6

78.0 6 . 5

20.5 10.2

316.1 162.0

2 . 8 7 .2 1 . 1 1 . 8

Gal 1 ons

11.8 2.2 0 .3 6 . 9 0 .2 0 .7 0 . 3 0.2 7 .2 1 . 1

9 . 4 0 . 7 2 .6 1 . 3

34.9 18 .4

0 .4 0 .7 0 . 1 0 . 3

Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a1 kyd

Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d

B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d


and l a t e x c h a l k , g l o s s a l k y d ) ; Exc


SOURCE: Ucar Emuls ion Systems: Ucar L a t e x 0336: F o r m u l a t i o n E-2471


E x t e r i o r T r i m Formu la t i on

I n g r e d i e n t s : Pigment Gr ind : Water Ucar Pol yphobe 102 Rheology Modi f i e r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene G lyco l Troysan 586 Tamol 1124 C o l l o i d 643 T r i t o n Nonionic S u r f a c t a n t N-57 Tronox CR-828 Po lyg loss 90

Letdown : Water NeoCar Latex 2300 Ucar Latex 6336 C o l l o i d 643 Ucar F i lmer IBT Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 24.0 Volume S o l i d s , %: 35.5 Weight per Gal lon, l b : 1 0 . 7 Stormer, KU: 93 I C I , Poise: 1 . 4 pH Value: 8 .9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2

Pounds

190.6 21.8

1 . 8 60.5

1 . 8 5.3 1 . 8 2 . 1

250.0 25.0

7.2 365.4 107.8

1 .8 15.8 7 . 4 1 . 1 1 . 8

Gal 1 ons

22.9 2.5 0 . 3 7 . 0 0.2 0.5 0.3 0.2 7 . 3 1.1

0.9 41.3 12.3 0.3 2.0 0.8 0 . 1 0.3

F i l m P r o p e r t i e s : Gloss, 60: 77 Gloss, 20: 28 Con t ras t R a t i o , 6-mi l wet drawdown: 0.977 Ref lectance, %: 92.2 Block Resistance, 1-week d r y , RT: 8 Dry Adhesion ( u n t r e a t e d aluminum, ga lvan ized s t e e l ,

Wet Adhesion ( u n t r e a t e d aluminum, ga lvan ized s t e e l ,

61 i s t e r i ng ( u n t r e a t e d a1 umi num, ga l van ized s t e e l , a1 kyd

a l k y d c h a l k ) : Exc

a l k y d cha lk , g l o s s a l k y d ) : Good

c h a l k ) : Good

SOURCE: Ucar Emulsion Systems: Ucar Latex 6336: Formu la t i on E-2472


E x t e r i o r T r i m F o r m u l a t i o n

I n a r e d i e n t s : Pigment G r i n d : Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammoni um Hydrox i de, 28% Aqueous Sol u t i on P ropy lene G1 y c o l Nuosept 95 Tamol 1124 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Tronox CR-828 P o l y g l o s s 90

Pounds

98.5 1 9 . 3

1 . 8 5 9 . 6

2 . 3 7 . 3 1 . 9 2 . 1

2 4 6 . 3 2 4 . 6

Letdown : Water B u t y l C a r b i t o l S o l v e n t Ucar F i l m e r I 8 T Ucar L a t e x 626 Ucar L a t e x 471 C o l l o i d 643 Troysan Polyphase AF-1 Byk 346 Ammonium Hydrox ide , 28%

47.2 2 0 . 5 1 0 . 2

372.5 129 .4

2 . 8 7 . 2 1 . 1

Aqueous Sol u t i on 1 . 8

P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 2 4 . 2 Volume S o l i d s , %: 35.0 Weight p e r G a l l o n , l b : 10 .5 S to rmer , KU: 89 I C I , P o i s e : 1 . 5 p H Va lue : 8 . 8 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F, weeks passed: 2 R a t i o o f Ucar La texes 626:Ucar 471: 70:30

F i 1 m P r o p e r t i es : G loss , 60: 53 G loss , 20: 15 C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0 .97 R e f l e c t a n c e , %: 92 .2 B l o c k R e s i s t a n c e : 9

G a l l o n s

11 . 8 2 . 2 0 .3 6 . 9 0 . 2 0.7 0 . 3 0 . 3 7 . 2 1 . 1

5 .7 2 .6 1 . 3

42 .8 1 4 . 9

0 .4 0 . 8 0 . 1 0 . 3

Dry Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , a l k y d

B l i s t e r i n g ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e l , and l a t e x c h a l k ) : Exc

l a t e x c h a l k ) : Exc

l a t e x c h a l k , g l o s s a l k y d ) : Exc Wet Adhesion ( u n t r e a t e d aluminum, g a l v a n i z e d s t e e

SOURCE: Ucar Emuls ion Systems: Ucar L a t e x 471: Formu E-2475

a l k y d and

, a l k y d and

a t i o n


E x t e r i o r White F l a t House P a i n t

I n q r e d i en ts : P i gment G r i nd : Water Ucar Polyphobe 102 Rheo. Mod . Ammonium Hydroxide, 28% Aqueous S o l u t i o n Proxel GXL Tamol 1124 Col l o i d 640 T r i t o n Non ion ic Sur fac tan t N-101 Propylene G1 yco l T i -Pure R-706 Minex 4 Ny ta l 300

Pounds

234.5 19.6

1.8 2.0 5 . 0 1 .9 2.1

25.9 225.0 135.4

75.0

Letdown : Ucar Latex 625 408.6 Ucar F i lmer IBT 10.2 C o l l o i d 640 1 .9 Troysan Polyphase AF-1 7 .3 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 1 .8

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 42.5 Volume So l ids , %: 38.0 Weight So l i ds , %: 5 5 . 7 V i s c o s i t y , equi 1 i bra ted :

Stormer, KU: 90 I C I , Poise: 1 . 3


F i l m Proper t i es : Cont ras t Rat io , 6-mi l wet drawdown: 0.965 Ref lectance, %: 91.9 Wet Adhesion, g loss a lkyd : E x c e l l e n t Chalk Adhesion, ASTM #5: G o o d

Gal 1 ons

28.20 2.30 0.20 0.20 0 . 5 0 0.30 0.30 3.00 6.60 6.20 3.20

46.40 1.30 0.30 0.80 0.20

SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Formula t ion Suggestion E-2459

Exrenor Paints and Related Products 83

E x t e r i o r White T r i m House P a i n t

I n q r e d i e n t s : P i Qment G r i nd: Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydrox ide , 28% Aqueous Troy 586 Tamol 1124 C o l l o i d 640 T r i t o n N o n i o n i c S u r f a c t a n t N-57 Propy lene G1 y c o l T i -Pure R-902 P o l y g l o s s 90

Letdown : Ucar La tex 625 Ucar F i l m e r IBT

Pounds

208.1 19.6

S o l u t i o n 1 . 8 2 .0 7 .4 1 . 9 2.1

60.5 237.5

5 0 . 0

Gal 1 ons

24.90 2.30 0.20 0.20 0.70 0.30 0.20 7 . 0 0 7.10 2.30

459.3 52.20 11.5 1 .50

C o l l o i d 640 2 .8 0.40 Troysan Polyphase AF-1 7 .3 0.80 Ammonium Hydrox ide , 28% Aqueous S o l u t i o n 0 .9 0.10 Byk 346 1 . 1 0.10

P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n , %: 27.0 Volume S o l i d s , %: 34.0 Weight S o l i d s , %: 48.6 V i s c o s i t y , e q u i l i b r a t e d :

Stormer, KU: 91 I C I , Po ise : 1 . 3


F i l m P r o p e r t i e s : C o n t r a s t R a t i o , 6 - m i l wet drawdown: 0.968 R e f l e c t a n c e , %: 9 3 . 4 Gloss, 60: 40 Wet Adhesion, g l o s s a l k y d , 4 -hr : E x c e l l e n t Adhesion, 1 week, ASTM D3359 ( w e t ) :

a l k y d : 4A aluminum: 5A

Chalk Adhesion, ASTM #5: Good B l i s t e r i n g , 24 h r s . :

aluminum: 10 a l k y d c h a l k (ASTM # 5 ) : 8F

Flow and L e v e l i n g , brushed: 7

SOURCE: Ucar Emuls ion Systems: Ucar L a t e x 025: F o r m u l a t i o n Suggest ion E-2402


Good Q u a l i t y White E x t e r i o r F l a t P a i n t fo r Masonry

I n a r e d i e n t s : P i gment G r i nd : Water C e l l o s i z e Hydroxyethy l C e l l u l o s e QP-15,000 Potass ium T r i p o l y p h o s p h a t e (KTPP) Nuosept 95 C o l l o i d 643 T r i t o n N o n i o n i c S u r f a c t a n t N-101

Tamol 850 T i -Pure R-902 Eagle 417W Snowf 1 ake Minex 4

AMP-95

Pounds

199.9 2.5 2 .0 1 .5 2 .0 3 .0 1 .o 7.0

220.0 25.0

100.0 131.7

G a l l o n s

24.00 0 .22 0.09 0.16 0.26 0.34 0.13 0.71 6.60 0.53 4 .44 6.07

D isperse a t h i g h speed f o r 15 minu tes . Do n o t exceed 120F. D i s p e r s i o n s h o u l d be 3-4 on Hegman.

Letdown : Water 1 127.1 15.26 Propy lene G1 y c o l ) Premi x 40.0 4.62 C e l l o s i z e Hydroxyethy l C e l l u l o s e )

QP-15,000 ) 2 .3 0.20 C o l l o i d 643 2 .0 0.26 NeoCar La tex 2300 305.0 34.47 Ucar F i l m e r IBT 13.0 1.64

P a i n t P r o p e r t i e s : PVC, %: 50 .0 Volume S o l i d s , %: 35 .3 Weight S o l i d s , %: 54.6 Weight p e r G a l l o n , l b : 11.98 Stormer, KU: 88-93 I C I , p o i s e : 0 .8-1.0 pH Va lue : 8 .0 -8 .5 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass

F i l m P r o p e r t i e s : R e f l e c t a n c e , %: 89.4 Gloss, 60: 2 Sheen, 85: 3 C o n t r a s t R a t i o , 3 -mi l f i l m : 0.970 ASTM Scrub Cycles, w i t h sh im F a i l u r e : >3000

SOURCE: Ucar Emuls ion Systems: NeoCar Polymers: F o r m u l a t i o n Suggest i on E-2252


Good Q u a l i t y White E x t e r i o r F l a t P a i n t f o r Wood

I n g r e d i e n t s : Pigment G r i nd: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e QP- Potassium Tr ipo lyphosphate (KTPP) Nuosept 95 C o l l o i d 643 T r i t o n Nonionic Sur fac tan t N-101

Tamol 850 T i -Pure R-902 Eagle 417W Snowf 1 ake Minex 4

AMP-95

Pounds

195.8 15,000 2.5

2.0 1 .5 2.0 3.0 1 .o 7.0

245.0 50.0 70.0 85.0

Ga l lons

23.50 0.22 0.09 0.16 0.26 0.34 0.13 0.71 7.35 1.07 3.11 3.92

Disperse a t h i g h speed f o r 15 minutes. Do no t exceed 120F. D ispers ion should be 3-4 on Hegman.

Letdown : Water ) 51 .5 6.17 Propylene G1 yco l 1 40.0 4.62 C e l l o s i z e Hydroxethyl C e l l u l o s e ) Premix

QP-15,OOO 1 2.0 0.17 C o l l o i d 643 2.0 0.26 NeoCar Latex 2300 405.0 45.77 Ucar F i lmer I B T 17.0 2.15

Note: I f wet adhesion i s des i red , b lend ing w i t h an a c r y l i c r e s i n , such as Ucar Latex 625, i s recommended.

P a i n t P roper t i es : PVC, %: 39.8 Volume So l ids , %: 38.8 Weight So l i ds , %: 56.6 Weight per Ga l lon , l b : 11.82 Stormer, KU: 88-93 I C I , po ise : 0.8-1 .O pH value: 8.0-8.5 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass

Ref lectance, %: 90.8 Gloss, 60: 3 Sheen, 85: 6 Cont ras t Ra t io , 3-mi l f i l m : 0.976 ASTM Scrub Cycles, w i t h shim F a i l u r e : >3000

F i 1 m Proper t i es :

SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulat ion Suggestion E-2253


Ingrediernrs; Pigment G r i nd: Water Ucar Polyphobe Ammoni um Hydrox Sol v e n t 142HT Tamol 165 P o t a s s i um T r i po T r i t o n N o n i o n i c P roxe l G X L Byk 023 T i -Pu re R-706

Greqson D r i v e Gloss Whi te

Pounds

112.0 02 Rheo. Mod. 10 .0 de, 28% Aqueous S o l u t i o n 1 . o

1 0 . 0 1 3 . 7

yphosphate (KTPP) 0 . 5 S u r f a c t a n t CF-10 3 . 0

2 . 0 2 .5

2 2 5 . 0

Letdown : Ucar L a t e x 481 519.0 Sol v e n t 142HT 10.0 Byk 025 2 . 0 B u t y l C a r b i t o l S o l v e n t 26 .0 Water 76 .4 Ammonium H y d r o x i d e , 28% Aqueous S o l u t i o n 1 . o Ucar Polyphobe 106HE Rheo. Mod. 14.0

P a i n t P r o p e r t i e s : Pigment Volume C o n c e n r t a t i o n , % : 1 9 . 8 Volume S o l i d s , %: 33 .9 Weight S o l i d s , %: 45.8 Stormer, KU: 87 I C I , P o i s e : 1 . 0 pH Va lue : 9 -9 .5 Freeze-Thaw Stab Heat-Age S t a b i l i VOC, grams p e r 1

F i l m P r o p e r t i e s : G loss , 60: 90 G l o s s . 20: 70

l i t y , c y c l e s passed: 0-1 y. 12OF, weeks passed: 4 t e r : 120

Gal l o n s

13.40 1.20 0 .10 1 . 5 0 1 .50 0 . 0 3 0 . 4 0 0 . 2 0 0 . 3 0 6.80

____

58.60 1.50 0.30 3 .30 9 .17 0.10 1 .60

F1 ow and Leve l i ng : Excel 1 e n t Dry- to-Touch, h o u r s : 2 Recoat, h o u r s : 4-6 W a t e r / B l i s t e r R e s i s t a n c e : Good

SOURCE: Ucar Emuls ion Systems: U l t r a - G l o s s La texes : F o r m u l a t i o n Sugges t ion E-2256

Exterior Points and Related Products 87

H i g h Q u a l i t y E x t e r i o r Semi Gloss P a i n t

M a t e r i a1 : Gr ind: Water Na t roso l P lus (Aqualon) Acrysol RM 1020 (Rohm and Haas) Ac ryso l RM 825 (Rohm and Haas) Pigment D ispe rse r NL (BASF) TKPP (10% i n water) Proxel GXL ( I C 1 B i o c i d e s ) FCA (Foam Con t ro l Agent) Kronos 2310 (Kronos)

Letdown : Propylene g l y c o l Dowanol DPnB (Dow) Minera l S p i r i t s Acronal DS 6183 (BASF) FCA (Foam Con t ro l Agent) Water

Proper t i es : Pigment Volume Content, %: 25.5 % N o n v o l a t i l e (by we igh t ) : 45.2 % N o n v o l a t i l e (by volume): 32.1 VOC, g / l : 107.0 Stormer V i s c o s i t y , K . U . : 105t -5 I C 1 V i s c o s i t y , Poise: 1.5+-2 Gloss a t 60, %: 67.0

Weight p e r Ga l l on , l b s / g a l l o n : % foam on manufactur ing:

Recommended Product :

A l t e r n a t i v e Products:

SOURCE: K ing I n d u s t r i e s : Formulat

Ag i tan 731: High performance w

A g i t a n 260 o r A g i t a n 315

62.50 5.99 0.52 0.05

31.32 3.00 7.31 0.70 1.04 0.10 3.13 0.30 2.09 0.20 3.13 0.30

261 .02 25.02

41.76 4.00 10.44 1 .oo 10.44 1 .oo

417.63 40.00 3.13 0.30

188.46 18.04

Ag i tan 731 10.6 0.66

t h excel l e n t p e r s i s tency

on WR-39-2


High Sheen Whi te House P a i n t

I n q r e d i e n t s : Pounds Pigment Gr ind : Water 203.9 Ucar Polyphobe 102 Rheo. Mod. 15.2 Ammoni um Hydroxi de, 28% Aqueous Sol u t i on 1.8 Troy 586 2.0 Tamol 1124 4.9 C o l l o i d 643 1 . 9 T r i t o n Nonionic S u r f a c t a n t N-101 2.1 Propylene G lyco l 34.6 Kronos 2310 225.0 Minex 10 71 .O Burgess No. 98 75.0

Letdown : Ucar Latex 625 Ucar F i lmer IBT Col l o i d 643 Troysan Polyphase AF-1 Byk 346 Ammmonium Hydroxide, 28% Aqueous S o l u t

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 35 Volume S o l i d s , %: 38.1 Weight S o l i d s , %: 54.0 V i s c o s i t y , equi 1 i b r a t e d :

Stormer, KU: 88 I C I , Po ise: 1 .O

461.9 11.5

1.9 7 .3 1.1

on 0.9

2

Ga l l ons

24.48 1.75 0.25 0.20 0.48 0.25 0.25 4.00 6.75 3.27 3.42

52.19 1 .45 0.25 0.75 0.13 0.13


F i l m P r o p e r t i e s : Con t ras t Ra t io , 6 -m i l wet drwadown: 0.984 Ref lectance, %: 92.2 Sheen, 85: 64.0 Wet Adhesion, g l o s s a l kyd : E x c e l l e n t Chalk Adhesion, ASTM #5: Good

SOURCE: Ucar Emulsion Systems: Ucar Latex 625: Fo rmu la t i on Suggest ion E-2461


Low VOC E x t e r i o r House P a i n t

M a t e r i a1 : G r i n d : N a t r o s o l 250 MHR 2.5% (Aqualon) Water Tamol 731 (Rohm and Haas) KTPP T r i t o n CF-10 (Rohm and Haas) Kathon LX 1.5% (Rohm and Haas) FCA (Foam C o n t r o l Agent) T i -Pure R-902 ( DuPont ) Eag le Z i n c 417W (Eag le) Minex 4 ( Indusmin) A t t a g e l 50 (Eng lehard)

Letdown : Emuls ion E-3122 (Rohm and Haas) FCA (Foam C o n t r o l Agent) A c r y s o l RM-2020 (Rohm and Haas) N a t r o s o l 250 MHR 2.5% (Aqualon) Skane M-8 (Rohm and Haas) Water

Lbs

127.0 85.0 16.0

1 . o 1 . o 1 .7 2 .0

250.0 25 .0

144.0 5.0

301 .O 2.0

15 .0 29.0

2 . 0 149.0

%Wt

1 5 . 2 10.2

1.8 0.1 0 .1 0 . 2 0 .3 7.5 0 . 5 6 . 6 0 . 2

34.0 0.3 0 .2 1.7 3 . 5

17.9

P r o p e r t i e s : Pigment Volume Content , %: 43.5 % N o n v o l a t i l e (by w e i g h t ) : 52.4 % N o n v o l a t i l e (by vo lume): 34.3 Stormer V i s c o s i t y , K.U.: 9 2 t - 5 I C 1 V i s c o s i t y , Po ise : 1 .3+-2

Recommended Produc t : A g i t a n 731: S u p e r i o r per formance i n b o t h a p p l i c a t i o n and

p r o d u c t i o n o f p a i n t . F i n e t u n i n g w i l l o p t i m i z e per formance and may p r o v i d e a c o s t advantage.

A g i t a n 315: E x c e l l e n t foam c o n t r o l i n a l l aspec ts o f p a i n t manufac ture and a p p l i c a t i o n . Lower c o s t a l t e r - n a t i v e t o 731.

A l t e r n a t i v e Produc t : A g i t a n 260

SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-39-4


Q u a l i t y E x t e r i o r F l a t Formula t ion

I n g r e d i e n t s : Pigment G r i nd: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e QP-15,000 Potassium Tr ipolyphosphate (KTPP) Drewpl us L-475 T r i t o n Nonionic Sur fac tan t N-101 Tamol 850 AMP-95 T i -Pure R-902 Eagle 417W I m s i l A25 C e l i t e 499 Water

Letdown : Water 1 Nat roso l P lus 330 ) premix Propylene Glyco l Drewpl us L-475 Ucar Latex 6390 NeoCar Latex 2300 Ucar F i lmer I8T

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 48.7 Volume So l i ds , %: 30.0 Weight per Gal lon, l b : 11.5 Stormer, KU: 83-88 I C I , Poise: 0.9 pH Value: 8.9 Low Temperature Coalescence: Pass

F i l m Proper t i es : Gloss, 60: 2 Sheen, 85: 2 Cont ras t Ra t io , 6-mi l wet drawdown: 0.990 Ref lectance, %: 88.4 Scrub Resistance, cyc les passed: >1500 Dry Adhesion, crosshatch tape p u l l : Pass Wet Adhesion, c y c l e s passed: >2000 50-mil Mudcracking: Pass

Pounds

183.3 2.5 2.0 2.0 4.0 7.0 1 .5

220.0 50.0

130.0 20.0 16.7

188.2 4 . 0

30.0 2.0

65.0 208.0

14.0

Gal 1 ons

22.0 0 . 2 0.1 0 .3 0 .5 0 .7 0.2 6 .6 1 .1 5.9 1 .o 2.0

22.6 0.4 3.5 0.3 7 .4

23.5 1 .7

SOURCE: Ucar Emulsion Systems: Ucar Latex 8390: Formula t ion E-2477


Qual i ty Exterior Flat Paint

Inaredients; Pigment Grind: Water Cellosize Hydroxyethyl Cellulose ER-30,000 Nuosept 145 Tamol 960 Potassi um Tripolyphosphate (KTPP) Triton Nonionic Surfactant N-101

Propylene G1 ycol Colloid 640 Ti -Pure R-900 Eagle 417W Mica 325WG

~ ~ p - 9 5

IT-325

Letdown : Ucar Latex 379G Ucar Filmer IBT Skane M-8 Colloid 640

Paint Properti 8s: PVC, %: 40.1 Volume Solids, %: 39.3 Weight Solids, %: 57.7 Weight per Gallon, lb: 11.9 Stormer, KU: 100 ICI, poise: 0.9 pH, initial: 8.9 Freeze-thaw Stability, 3 cycles: Pass Heat-Aged Stability, 2 weeks at 120F: Pass

Film Properties: Ref 1 ectance, %: 90.5 Sheen, 85: 5.1 Contrast Ratio, 3-mil film: 0.966

Pounds

252.1 4.0 2.3 10.5 2.0 2.2 1 . o

34.5 1.9

225.0 25.0 25.0 175.0

408.3 17.8 2.2 1.9

Gal 1 ons

30.27 0.36 0.25 1 .oo 0.10 0.25 0.13 4.00 0.25 6.54 0.54 1.07 7.37

45.12 2.25 0.25 0.25

SOURCE: Ucar Emulsion Systems: Formulation Suggestion E-19928


Q u a l i t y Whi te E x t e r i o r T r im P a i n t

I n a r e d i e n t s : Pigment Gr ind : Water Ucar Pol yphobe 9831 Rheology Modi f i e r Ammonium Hydroxide, 28% Aqueous S o l u t i o n Propylene G lyco l Nuosept 95 Tamol 1124 Col l o i d 643 T r i t o n Nonionic S u r f a c t a n t N-57 Tronox CR-828 Po lyg loss 90

Pounds

98.5 5 .0 1.8

59.6 2.3 7.3 1 .9 2.1

246.3 24.6

Letdown : Water Ucar Polyphobe 9831 Rheology M o d i f i e r ) Water ) Premix B u t y l C a r b i t o l Solvent Ucar Latex 626 Col l o i d 643 Troysan Polyphase AF-1 T r i t o n A n i o n i c S u r f a c t a n t GR-7M Ammonium Hydroxide, 28% Aqueous S o l u t i o n

16.7 5.8

44.7 30.7

496.7 2.8 7.2 1 .1 0 . 9

Ga l l ons

11.79 0.60 0.20 6.90 0.30 0.69 0.30 0.30 7.39 1.18

1.99 0.69 5.38 3.04

57.08 0.39 0.79 0.10 0.10

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 24.2 Volume S o l i d s , %: 35.0 Weight S o l i d s , %: 49.7 Weight pe r Gal lon, l b : 10.56 Stormer, KU: 95 I C I , Po ise: 1 .4 pH Value: 8 .9 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 12OF. weeks passed: 2

F i l m P r o p e r t i e s : Gloss, 60: 71 Gloss, 20: 26 Color Acceptance: E x c e l l e n t Flow and Leve l i ng : E x c e l l e n t Wet Adhesion, 24-hr d r y : E x c e l l e n t

SOURCE: Ucar Emulsion Systems: Ucar Polyphobe Q83l Rheology M o d i f i e r : Fo rmu la t i on Suggest ion E-2484

I ng red ien ts : Pigment Gr ind : Water Ucar Polyphobe Ammoni um Hydrox Propylene G1 yco Nuosept 95 Tamol 1124 Col l o i d 643 T r i t o n Nonionic Tronox CR-828 Polygloss 90

Letdown : Water


Q u a l i t y White E x t e r i o r Tr im P a i n t

02 Rheology Modi f i e r de, 28% Aqueous So lu t

Su r fac tan t N-57

on

Ucar Pol yphobe 102 Rheology Modi f i e r ) Premi x Water 1 Bu ty l Carbi t o 1 Sol vent Ucar F i lmer IBT Ucar Latex 626 C o l l o i d 643 Troysan Polyphase AF-1 T r i t o n An ion ic Sur fac tan t GR-7M Ammonium Hydroxide, 28% Aqueous So lu t i on

Pa in t Proper t ies : Pigment Volume Concentrat ion, %: 24.2 Volume So l ids , %: 35.0 Weight So l ids , %: 49.7 Weight per Gal lon, l b : 10.56 Stormer, KU: 90-95 I C I , Poise: 1.4 pH Value: 8 .9 Freeze-Thaw S t a b i l i t y , cyc les passed: 3 Heat-Age S t a b i l i t y , 12OF, weeks passed: 2

F i l m Proper t i es : Gloss, 60: 62 Gloss, 20: 15 Color Acceptance: Exce l l en t Flow and Leve l ing : Excel l e n t Wet Adhesion, 24-hr d ry : Exce l l en t

Pounds Gal 1 ons

98.5 11.79 10.7 1.28

1 .8 0.20 59.6 6.90

2.3 0.30 7.3 0.69 1.9 0.30 2 .1 0.30

246.3 7.39 24.6 1.18

8 .2 0.98 8.6 1.02

44.7 5.38 20.5 2.56 10.2 1.28

496.7 57.08 2.8 0.39 7.2 0.79 1.1 0.10 0.9 0.10

SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion E-2458


Q u a l i t y White House P a i n t w i t h ZnO

I n q r e d i en ts : Pigment G r i nd: Water C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 Nuosept 95 Propylene Glyco l Col l o i d 226/35 Potassium Tr ipolyphosphate (KTPP) T r i t o n Nonionic Sur fac tan t N-101 Col l o i d 653 T i -Pure R-902 XX503R Nyta l 300 Minex 4

Pounds

295.6 4.0 2.3 25.9 10.3 1 . o 2.2 1.9

225.0 25.0 100.0 96.4

Letdown :

Ucar Latex 624 364.2 Ucar F i lmer I8T 9.1 Skane M8 2.2 C o l l o i d 653 2.8 Ammoni um Hydroxi de, 28% Aqueous Sol u t i on 2.0

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 45.0 Volume So l ids , %: 35.4 V i s c o s i t y , equi 1 i bra ted :


Weight per Ga l lon , l b : 11.70 Freeze-thaw S t a b i l i t y , 3 cyc les : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

F i 1 m Proper t i es : Cont ras t Rat io, 6-mi l wet drawdown: 0.951 Reflectance, %: 91 . 1 Sheen, 85: 4.0 Flow and Leve l ing , brushed: Good Wet Adhesion: E x c e l l e n t

Gal l o n s

35.49 0.36 0.25 3.00 1 .oo 0.05 0.25 0.25 6.75 0.54 4.21 4.44

41.39 1 .I5 0.25 0.37 0.25



Ure thane F o r t i f i e d Porch & Deck Enamel

M a t e r i a1 : A r o l o n 840-W-39 Water C o l l o i d 679 Cel l o s i ze QP4400 Ammonium Hydrox ide D i sperse-Ayd W28 Kroma Red RO 7097 T i t a n o x 2101 Durami t e

Lbs. 130.5

5 0 . 0 1 . 9 1 . o 1 . 9 4 . 4

5 0 . 0 5 . 0

1 5 0 . 0

Ga ls . 15 .00

6 . 0 0 0 . 2 5 0.09 0.25 0 . 5 0 1 .23 0 . 1 5 6 . 6 1

Add t h e above i n o r d e r under good a g i t a t i o n , t h e n pebb le o r sand m i l l g r i n d t o 7 Hegman.

Letdown : A r o l o n 840-W-39 Spensol L51 Ucar S C T I 00

u s I Gals_ 304.5 35.00 304.1 34.75

2 . 3 0 . 2 5

A n a l y s i s : Pigment Volume C o n c e n t r a t i o n , P e r c e n t : 22 .0 P igmen t /B inde r R a t i o : 0 . 8 / 1 . O Percen t S o l i d s , Weight : 46 .9 Percen t S o l i d s , Volume: 36 .4 V i s c o s i t y (a 25C, KU: 85-95 Pounds/Gal l o n : I O . 1

VOC ( e x c l u d i n g w a t e r ) : Grams/Li t e r : 150 Pounds/Gal lon: 1 . 3

pH: 8 . 5 + - 0 . 3

SOURCE: R e i c h h o l d Chemicals , I n c . : Spensol L: Formula 2262-80


Weather B a r r i e r Formulat-

I l r p d E n t s : Pigment G r i n d : Water C e l l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-52M D i s p e r s a n t ( 1 ) P o t a s s i um T r i p o l y p h o s p h a t e (KTPP) E t h y l e n e G l y c o l W e t t i n g Agent ( 2 ) A n t i f o a m ( 3 ) T i t a n i u m D i o x i d e ( 4 ) C a l c i um Carbonate ( 5 ) Z i n c Oxide ( 6 ) M i l d e w c i d e ( 7 )

Pounds

143.3 4.0 8 . 0 2 .0

20.0 1 . 2 1 . 5

1 0 3 . 0 385.0

40 .6 5 . 0

Letdown : Ucar L a t e x 123 496.6 Ucar F i lmer IBT 6 . 0 A n t i f o a m ( 3 ) 2 .0 Ammonium Hydrox ide , 28% Aqueous S o l u t i o n 2 . 5

Gal l o n s

17.3 0 . 3 0 . 8

2 .2 0 . 2 0 .2 3 . 2

1 7 . 1 0 .9 0 . 5

---

5 5 . 9 0 . 8 0 . 3 0 . 3

S , upp l i ( 1 )

e r s : D i s p e r s a n t - C o l l o i d 226/35 (Rhone-Poulenc) o r e q u i v a l e n t . W e t t i n g Agent - S u r f y n o l 104 ( A i r P r o d u c t s ) o r e q u i v a l e n t . A n t i f o a m - C o l l o i d 643 (Rhone-Poulenc) o r e q u i v a l e n t . T i t a n i u m D i o x i d e - T i - P u r e R-960 (DuPont) or e q u i v a l e n t . Ca lc ium Carbonate - A t o m i t e (ECC) o r e q u i v a l e n t .

( 6 ) Z i n c Oxide - Kadox 915 (Cookson) o r e q u i v a l e n t . ( 7 ) M i l d e w c i d e - Nopcocide N-96 (Henke l ) o r e q u i v a l e n t .

P a i n t P r o p e r t i e s : Pigment Volume C o n c e n t r a t i o n (PVC), %: 40 T o t a l S o l i d s , %:

by Volume: 53 .8 by We igh t : 6 8 . 5

Stormer V i s c o s i t y , KU: 110

F i 1 m P r o p e r t i es* : T e n s i l e :

S t r a i n Rate, i n / m i n : 2 .0 S t r e s s , p s i : 108 E l o n g a t i o n , % : 1070

S t r a i n Rate, i n / m i n : 2 . 0 S t r e s s , p s i : 52 E l o n g a t i o n , % : 1650

Water T ransmiss ion a t 24 Hours, mg: 90

180 Bend a t -2OC: No C r a c k i n g

T e n s i l e a f t e r 24-hour Water immers ion:

Water Pondi ng:

Low Temperature F l e x i b i l i t y :

* D r i e d and C o n d i t i o n e d 7 Days a t 72F (22C) and 50% RH

SOURCE: Ucar Emuls ion Systems: Ucar L a t e x 123: F o r m u l a t i o n WB-120


Whi te E x t e r i o r F l a t House P a i n t w i t h Z i n c Oxide

Pounds Ga l lons I n q r e d i en ts : _ _ _ ~ Pigment Grind: Water 249.1 29.90 C e l l o s i z e Hydroxyethyl C e l l u l o s e ER-30,000 4.0 0.40 Nuosept 95 2.3 0.25 Propylene G1 yco l 25.9 2.98

Tamol 850 4.0 0.40 T r i t o n Nonionic Sur fac tan t N-101 2.1 0.24 C o l l o i d 640 1.9 0.25 T i -Pure R-706 200.0 5.90

Minspar 4 100.0 4.63 Ny ta l 300 75.0 3.16

Letdown : Water 75.0 9.00 Ucar Latex 353 251 .O 27.50 Ucar Latex 6390 88.7 10.08 Ucar F i lmer IBT 23.8 3.01 Col l o i d 640 3.8 0.51 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 3.0 0.40

Potassium Tr ipolyphosphate (KTPP) 2.0 0.20

Eagle 417W 50 .0 1.11

P a i n t P roper t i es : PVC, %: 41 . 1 Volume So l i ds , %: 36.0 Weight So l i ds , %: 59.6 Weight per Ga l lon , l b : 11.61 Stormer, KU: 93 I C I , po ise : 0.9 pH, i n i t i a l : 9 .4 Freeze-thaw S t a b i l i t y , 5 cyc les : Pass Heat-Aged S t a b i l i t y :

1 week a t 140F: Pass 2 weeks a t 120F: Pass

R o l l e r S t a b i l i t y , 1 week*: Pass

F i 1 m P roper t i es : Ref lectance, %: 88.2 Cont ras t Rat io , 3 -mi l f i l m : 0.951 Wet Adhesion, 24-hr. , cyc les : >2000 Chalk Adhesion:

Dry: Exc Wet: Exc

Acceptance: Exc Development : Exc F l o a t : Exc

Co lor * :

*T in ted w i t h 2% by weight ph tha lo b l u e (Hu ls 888-7124)


98 Water-Bared Paint Formulations

White E x t e r i o r F l a t House P a i n t w i t h Z inc Oxide

I n g r e d i e n t s : P i grnent O r i nd : Cel l o s i ze Hydroxyethy l C e l l u l o s e QP-4400 Water Propylene G lyco l Tamol 960 Potass i urn Tr ipo lyphosphate (KTPP) T r i t o n Non ion ic S u r f a c t a n t CF-10 Col l o i d 643

T i -Pure R-902 Eagle 417W Minex 4 Opt iwhi t e A t t a g e l 50

AMP-95

Pounds

123.1 98.1 59.0

7.1 1 .5 2.5 1 . o 1 .o

225.0 25.0

145.0 50.0

5 .0

Letdown : NeoCar La tex 6035 378.0 Ucar F i l m e r IBT 20.0 Skane M-8 1 . o C o l l o i d 643 1 . 5 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 2.0 Cel l o s i z e Hydroxyethy l C e l l u l o s e QP-4400 43.0

Pai n t P roper t i es : PVC, %: 45.0 Volume S o l i d s , %: 37.0 Weight S o l i d s , %: 54.7 Weight per Gal lon, l b : 11.7 Stormer, KU: 97 ICI, po ise : 0 .8-1.0 pH Value: 8.5-9.0 Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass

F i l m P r o p e r t i e s : Ref lectance, %: 89.7 Gloss, 60: 3 Sheen, 85: 4 Con t ras t Ra t io , 3-mi l f i l m : 0.969 ASTM Scrub Cycles, w i t h shim F a i l u r e : > lo00 Chalk Adhesion: Exc

Gal 1 ons

14.78 11.78 6.86 0.72 0.15 0.28 0.14 0.13 6.76 0.54 6.68 2.73 0.25

41.77 2.53 0.12 0.21 0.24 5.16

SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulat ion Suggest ion E-2272


Whi te R o o f C o a t i n g

M a t e r i a1 : Water

Ammonia (28%) Potass ium T r i p o l y p h o s p h a t e AZO-33 Z i n c Oxide Durami t e T i t a n o x 2160 Bubble Breaker 3295 Bubble Breaker 776-P Methocel 31 2MS Texanol

D isperse under h i g h shear f o r 10-15 minu tes . Add le tdown:

A r o l o n 820-W-49

A n a l y s i s :

PMA-100

Pigment Volume C o n c e n t r a t i o n , Percent : 47.5 Pigment /B inder R a t i o : 2.26/1 Percent S o l i d s , Weight : 63.18 Percent S o l i d s , Volume: 47.33 V i s c o s i t y @ 25C, KU: 80-90 Gloss: F l a t Pounds/Gallon: 11.91

VOC ( e x c l u d i n g w a t e r ) : Grams/L i te r : 64.0 Pounds/Gallon: 0 .53

pH: 8.8-9.2

Lbs. Gals . 172.60 20.72

1 .80 0 . 0 9 0.90 0.12 1.92 0.09

22.83 0.49 466.65 20.74

24.31 0.73 3.30 0.44 3.30 0.44 4.14 0 .36

17.93 2.27

470.89 53.51

SOURCE: R e i c h h o l d Chemicals, I n c . : A r o l o n 820: Formula 2185-40A

Interior Paints and Related Products 101

Clear High Gloss Varnish

M a t e r i a l : Spensol L51 Ammonium Hydroxide Sur fynol 104H Byk 321 C o l l o i d 679 Arolon 840-W-39 M i cheml ube 02925 Lodyne S107B

Lbs. Gals. 651.9 74.50

1.9 0.25 4.0 0.50 1.9 0.25 I .9 0.25

167.5 19.25 31 .1 3.75

1 . o 0.10

Add t h e above ma te r ia l s i n order under good a g i t a t i o n , then add t h e f o l l o w i n g c u r i n g agent j u s t p r i o r t o use and m i x w e l l f o r a t l e a s t 10 minutes.

XAMA- 7 11.4 1.15

Analys is : Percent Sol i ds , Weight : 30.9 Percent So l ids , Volume: 28.0 V i s c o s i t y @ 25C #2 Zahn, Secs.: 20 Gloss (60): 100+ Pounds/Gallon: 8 .7

VOC (exc lud ing water ) : Grams/Liter: 290 pH: 8.5+-0.3

Pounds/Gallon: 2 . 4 Formulat ion 2307-22A

Fast-Dry Sealer

Mater i a1 : Spensol L51

Premix and add: Water Ammoni um Hydroxi de

Add i n f o l l o w i n g order w i t h a g i t a t i o n : Arolon 840-W-39 Sur fyno l 104H Lodyne SI07

Ana lys is : Ra t io of Spensol L51 t o Aro lon 840: 75:25 Percent So l ids , Weight: 32.1 Percent So l ids , Volume: 29.5 V i s c o s i t y @ 25C, #2 Zahn, Secs.: 23t-4 Pounds/Gallon: 8.73

VOC (exc lud ing water) : Grams/Liter: 286 pH: Bt -0.5

Pounds/Gallon: 2 .4 Forrnul a t i o n 2061 -91A

Lbs. Gal s . 687.2 78.63

1.4 0.17 0.4 0.06

176.2 20.25 5.2 0.66 2 . 2 0.23

S0URCE:Reichhold Chemicals, I n c . : Spensol L51: Formulations


Economv F l a t W a l l P a i n t

I n q r e d i e n t s : P i gment G r i nd : Water C e l l o s i z e Hydroxyethy l C e l l u l o s e ER-30,000 Nuosept 95 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40

Propy lene G1 y c o l Drewplus L-475 Tronox CR-813 ASP NC2 No. 1 Whi te C e l i t e 281

Letdown : Water Ucar La tex 353 Ucar F i l m e r IBT Drewpl us L-475

P a i n t P r o p e r t i e s : PVC, %: 70.0 Volume S o l i d s , %: 29 .8 Weight S o l i d s , %: 50.2 Weight p e r G a l l o n , l b : 11.32 Stormer, KU: 9 4 I C I , p o i s e : 0.9 pH, i n i t i a l : 8 . 3 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

AMP-95

Pounds

484.5 6 .0 2 .3 4 .6 2 .2 2 .2 1 .o

13.0 1 . o

75.0 200.0 150.0

25.0

Gal l o n s

58.16 0.55 0.25 0.50 0.25 0.25 0.13 I .50 0.13 2.34 9.30 6.65 1.30

30.2 3.63 125.4 13.78

8.1 1.03 1 . 9 0.25

F i l m P r o p e r t i e s : R e f l e c t a n c e , %: 91.2 Sheen, 85: 1 . 1 C o n t r a s t R a t i o , 3 -mi l f i l m : 0.959 ASTM Scrub Cycles, w i t h sh im f a i l u r e , 10%: 102 C o l o r * :

Acceptance: Exc Development: Exc

* T i n t e d w i t h 2% b y w e i g h t p h t h a l o b l u e ( H u l s 888-7214) o r r e d i r o n o x i d e ( H u l s 888-1045).

SOURCE: Ucar Emuls ion Systems: Ucar L a t e x 353: F o r m u l a t i o n Suggest ion 1-2469


Economy F l a t Wal l P a i n t

I n g r e d i e n t s : Pigment G r i n d : Water Cel l o s i z e H y d r o x y e t h y l C e l l u l o s e ER-30,000 Nuosept 95 Tamol 731 T r i t o n N o n i o n i c S u r f a c t a n t N-101 T e r g i t o l N o n i o n i c S u r f a c t a n t NP-40 AMP-95 Propy lene G l y c o l Drewplus L-475 Tronox CR-813 ASP NC2 No. 1 Whi te C e l i t e 281

Letdown : Water Ucar La tex 353 Ucar F i l m e r IBT Orewplus L-475

P a i n t P r o p e r t i e s : PVC, %: 70.0 Volume S o l i d s , %: 29.8 Weight S o l i d s , %: 50.2 Weight p e r G a l l o n , l b : 11.32 Stormer, KU: 94 I C I . o o i s e : 0 . 9

Pounds

484.5 6 .0 2 .3 4 .6 2 .2 2 . 2 1 .o

13.0 1 . o

75.0 200.0 150.0

25.0

30.2 125.4

8 . 1 1.9

Gal l o n s

58.16 0 . 5 5 0.25 0.50 0.25 0.25 0.13 1.50 0.13 2.34 9.30 6.65 1.30

3 .63 13.78

1.03 0.25

. . pH, i n i t i a l : 8 . 3 Freeze-thaw S t a b i l i t y , 5 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

F i 1 m P r o p e r t i es : R e f l e c t a n c e , %: 91.2 Sheen, 85: 1 . 1 C o n t r a s t R a t i o , 3 -mi l f i l m : 0.959 ASTM Scrub Cycles, w i t h sh im f a i l u r e , 10%: 102 C o l o r * :

Acceptance: Exc Development : Exc

* T i n t e d w i t h 2% b y we igh t p h t h a l o b l u e ( H u l s 888-7214) o r r e d i r o n o x i d e ( H u l s 888-1045).

SOURCE: Ucar Emuls ion Systems: Ucar La tex 353: F o r m u l a t i o n Suggest ion 1-2460


Good Q u a l i t y I n t e r i o r F l a t w i t h <50g/L VOC

I n q r e d i e n t s : P i gment G r i nd : Water Propylene G lyco l Proxel GXL Col l o i d 226/35 T r i t o n Nonionic S u r f a c t a n t N-101 Drewplus L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Sodium Hydrox ide (50% S o l u t i o n ) T i -Pure R-902 Snowf 1 ake Minex 4

Letdown : Ucar Latex 3796 Ucar F i l m e r IBT Drewplus L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Water

Pounds

358.0 10.0 0 .5 6.0 2.2 4.0

15.0 2.5

200.0 175.0 175.0

200.0 3.0 4.0

17.3 50.0

Gal 1 ons

43.00 1.16 0.05 0.59 0.25 0.52 1.72 0.19 6.00 7.75 8.05

22.10 0.38 0.52 1.98 6.01

P a i n t P r o p e r t i e s : PVC, %: 63.1 Volume So l i ds , %: 34.5 Weight S o l i d s , %: 55.1 Weight per Ga l l on , l b : 12.18 Stormer, KU: 87 I C I , p o i s e : 2 .1 pH, i n i t i a l : 9 .2 Freeze-Thaw S tab i 1 i t y , 1 c y c l e : Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass V o l a t i l e Organic Content, g/L: 45.6

F i 1 m P roper t i es : Ref 1 ectance, %: 90.0 Sheen, 85: 2 Con t ras t Ra t io , 3-mi l f i l m : * 0.961 ASTM Scrub Cycles, w i t h shim F a i l u r e : 330 C o l o r : *

Acceptance: Excel l e n t Development: E x c e l l e n t

Low Temperature Coalescence I O - m i l drawdown a t 40F: Pass Mudcracki ng, 3 0 - m i 1 on sheetrock: Pass

* T i n t e d w i t h 2% by weight p h t h a l o b l u e (Hu ls 888-7214) o r r e d i r o n o x i d e (Huls 888-1045).

SOURCE: Ucar Emulsion Systems: Fo rmu la t i on Suggest ion I-2230A


Hiah-Qua l i t y Super F l a t I n t e r i o r Pa in t

I ng red ien ts : P i Qment Grind: Water Propylene G1 yco l Proxel GXL Col 1 o i d 226/35 T r i t o n Nonionic Sur fac tan t N-10 C o l l o i d 640 Ucar Polyphobe 102 Rheology Mod

T i -Pure R-902 Snowf 1 ake 960 Minex 4

Letdown : Ucar Latex 3796 Ucar F i lmer IBT C o l l o i d 640

AMP-95 f i e r

Ucar Pol yphobe 102 Rheology Modi f i e r Water

Pounds

150.0 25.9

0 . 5 8.0 2.2 3.5

15.0 5.0

250.0 125.0 125.0

Gal l ons

18.02 3.00 0.05 0.78 0.25 0.47 1.72 0.63 7.51 5.54 5.76

419.8 46.64 16.8 2.11 3.5 0.50 7.5 0.86

51.3 6.16

Pai n t P roper t i es : PVC, %: 43.3 Volume So l i ds , %: 43.4 Weight So l i ds , %: 61.0 Weight per Gal lon, l b : 12.09 Stormer. KU: 90 I C I , po ise : 2.0 pH, i n i t i a l : 9.2 Freeze-Thaw S t a b i l i t y , 3 cyc les : Pass Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass

F i 1 m Proper t i es : Reflectance, %: 92.5 Sheen, 85: 7 Contrast Rat io, 3-mi l f i l m * : 0.962 ASTM Scrub Cycles, w i t h shim F a i l u r e : >2000 Color*:

Acceptance: Excel 1 ent Development : Excel 1 ent

*T in ted w i t h 2% by weight ph tha lo b l u e (Huls 888-7214) or red i r o n ox ide (Huls 888-1045).

SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion I-2227A


I n t e r i o r C lear Wood F i n i s h (RhoDlex CL-l04/Sancure 8151

B1 end : Rhopl ex CL-104 (38.5%) Sancure 815 (35.0%) Sur fyno l DF-62 Sur fyno l 104PG-50

Mix above f o r 10 minutes be fo re adding t h e f o l l o w i n g :

Hexyl Carbi t o1 Propylene Glyco l Acrysol RM-1020 Water Michem 39235 Aqueous Ammonia ( 14%)

Formulat ion B (Rohm and Haas)

I n t e r i o r Sandina Sealer (RhoDlex CL-1051

E l end : Rhopl ex CL-105 (37.0%) Sur fyno l DF-62 Water Aqueous Ammonia (14%)

Mix above f o r 10 minutes be fore adding t h e f o l l o w i n g :

Propasol B Hexyl Carbi t o1 Acrysol RM-2020 Water Aqueous Ammonia (7%) Sur fyno l 104DPM

Formulat ion C (Rohm & Haas)

Pounds 540.0 148.5

1.4 3.0

20.8 30.0 18.0 66.0 22.3

2.5

Pounds 709.3

1.3 32.9 8.0

45.2 22.3

4.1 30.8

2.6 3.0


*Color u n i f o r m i t y o f s t a i n s *Ear ly s t a i n 1 appi ng res i s tance *Consistent we t t i ng , f l o w and l e v e l i n g on var ious woods *Foam c o n t r o l

*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *Gloss r e t e n t i o n upon aging *Tannin b leed r e s i stance *Water s e n s i t i v i t y *Chemical res i s tance

Formulas

Wi th no de t r imenta l e f f e c t upon:

SOURCE: A i r Products 8, Chemicals, I nc . : Sur fyno l Sur fac tan ts :


I n t e r i o r Cont rac tor F l a t

I ng red ien ts : Pigment Gr ind Water Propylene G1 yco l Tamol 1124 T r i t o n Nonionic Sur fac tan t X-405 C o l l o i d 643 AMP-95 T i -Pure R-901 Opt iwh i te Durami t e C e l i t e 281

Letdown : Ucar Latex 379G Ucar F i lmer I B T C o l l o i d 643 Water Ucar Polyphobe 10 Water

Pa in t Proper t ies : PVC, %: 71.4 Volume Sol i d s , Wei ght Sol ids, Weight per Gal pti, i n i t i a l : 8

Pounds

184.0 26.0 10.0 2.0 1.5 2.0

100.0 150.0 190.0 20.0

148.0 8.0 2.5

50.0 Rheology Modi f i e r 21 .o -.

217.5

%: 40.3 %: 29.4 on, l b : 11.3 5-9.0

Gal 1 ons

22.09 3.02 1.01 0.23 0.21 0.25 3.33 8.20 8.41 1.04

16.35 1.01 0.34 6.00 2.41

26.11

Ucar Polyphobe 107: NVM lb /100 g a l : 5.3 Stormer, KU: 90/98 I C I , po ise : 0 .7 Scrub Cycles: 140

SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion I - 2 2 3 1 A


I n t e r i o r Good Quali ty F l a t f o r R o l l e r and Brush A p p l i c a t i o n

I n Q r e d i en ts : Pigment Gr ind : Water Propylene G1 yco l Tamol 1124 T r i t o n Nonionic Sur fac tan t X-405 Col l o i d 643 AMP-95 T i -Pure R-901 Opt i whi t e Durami t e Letdown : Ucar Latex 379 Ucar F i lmer IBT C o l l o i d 643 Water Ucar Polyphobe 103 Rheology M o d i f i e r Water Pa in t P roper t i es :

Pigment Volume Concentrat ion, %: 58.0 Volume So l i ds , %: 34.4 Weight So l i ds , %: 51.9 Weight per Gal lon, l b : 11.3 pH, i n i t i a l : 8.5-9.0

Thickener Comparison: Ucar Polyphobe 103:

NVM lb /100 g a l : 5 . 7 Stormer, KU: 91/98 I C I , P: 1 .5 Scrub Cycles: 1102 Flow/Level ing: Exce l l en t 50-mi 1 Mudcrack: Pass R o l l e r /Spa t te r : M i n i mal

NVM lb /110 g a l : 7 . 0 Stormer, KU: 86/96 I C I , P: 1.8 Scrub Cycles: 1200 Flow/Level ing: Excel l e n t 50-mi 1 Mudcrack: Pass R o l l e r /Spa t te r : M i n i mal

Ucar Polyphobe 102/104 blend: NVM lb/100 g a l : 3.7/2.3 Stormer. KU: 95/101

Ucar Polyphobe 102:

~I ~ ~I ~

I C I , P: 1.4 Scrub Cycles: 1200

Pounds

184.0 26.0

9.0 2.0 1.5 2.0

100.0 150.0 190.0

254.0 16.0 2.5

50.0 22.8

119.2

Flow/Level ing: Good 50-mi 1 Mudcrack: Pass R o l l e r /Spa t te r : M i n i mal

SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion

Gal 1 ons

22.09 3.02 0.91 0.23 0.21 0.25 3.33 8.20 8.41

28.07 2.03 0.34 6.00 2.62

14.31

1-2232


I n t e r i o r Good Q u a l i t y F l a t f o r R o l l e r and Brush A p p l i c a t i o n

I n g r e d i e n t s : Pigment Gr ind : Water Propylene G lyco l Tamol 1124 T r i t o n Non ion ic Sur fac tan t X-405 C o l l o i d 643

Ti-Pure R-901 Opt i whi t e Durami t e

Letdown : Ucar La tex 379 Ucar F i l m e r I B T C o l l o i d 643 Water Ucar Polyphobe 9831 Rheology M o d i f i e r Water

AMP-95

Pounds

184.0 26.0

9.0 2.0 1.5 2.0

100.0 150.0 190.0

254.0 16.0 2 . 5

60 .3 12.5

119.2

Gal 1 ons

22.09 3.02 0.91 0.23 0.21 0.25 3.33 8.20 8.41

20.07 2.03 0.34 7.20 1.40

14.31

P a i n t P r o p e r t i e s : Pigment Volume Concent ra t ion , %: 58.0 Volume S o l i d s , %: 34.4 Weight S o l i d s , %: 51.9 Weight per Ga l lon , l b : 11.3 Stormer, KU: 95 I C I , Poise: 1 .6 pH Value: 8.5-9.0 V o l a t i l e Organic Content, g/L: 139

Sheen, 85: 1.8 Flow and Leve l i ng : Good Sag Resistance, m i l s : 7


SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology M o d i f i e r : Formula t ion Suggest ion 1-2240

110 Water-Based Faint Formulations

I n t e r i o r Good Q u a l i t y F l a t

I n g r e d i e n t s : P i gment G r i nd : Water Propylene G1 yco l Proxel GXL Tamol 1124 T r i t o n Nonionic Sur fac tan t X-405 C o l l o i d 643

T i -Pure R-901 O p t i whi t e Ourami t e

Letdown : Ucar Latex 3796 Ucar F i lmer IBT Col l o i d 643 Water Ucar Pol yphobe 103 Rheology Modi f i er Water

Pa in t P roper t i es : PVC, %: 58.0 Volume So l i ds , %: 34.4 Weight So l i ds , %: 51.9 Weight per Ga l lon , l b : 11.3 pH, i n i t i a l : 8.5-9.0

AMP-95

Thickener Comparison: Ucar

NVM, lb /100 ga l Stormer, KU I C I , p o i s e Scrub Cycles Flow/Level i ng 50-mi 1 Mudcracki ng

Pounds

184.0 26.0

0.5 9.0 2.0 1.5 2.0

100.0 150.0 190.0

254.0 16.0 2.5

50.0 22.8

119.2

Polyphobe Ucar 02 7.0

Gal 1 ons

22.09 3.02 0.05 0.91 0.23 0.21 0.25 3.33 8.20 8.41

28.07 2.03 0.34 6.00 2.62

14.31

Pol yphobe 03 5.7

86/96 1.8

1200 Exc

Pass

91 /98 1.5

1102 Exc

Pass

SOURCE: Ucar Emulsion Systems: Formula t ion Suggestion I-2232A


I n t e r i o r Semi g loss Formula t ion

I n g r e d i e n t s : Pigment G r i nd: Water Ucar Polyphobe 102 Rheology M o d i f i e r Ammoni um Hydroxi de, 28% Aqueous Sol u t i on Propylene G1 yco l Proxel GXL Tamol 1124 Col l o i d 643 T r i t o n Nonionic Sur fac tan t N-57 Tronox CR-828 Burgess No. 98

Letdown : Water Ucar Polyphobe 102 Rheology M o d i f i e r B u t y l C a r b i t o l Solvent Ucar F i lmer IBT Ucar Latex 379G Ucar Latex 6030 C o l l o i d 643 Byk 346 Ammoni um Hydroxi de, 28% Aqueous Sol u t i on

Pounds

125.0 19.6

1.8 43.2

2.3 7 .3 1 .9 2.1

250.0 19.7

24.8 2.2

23.8 11.9

346.8 184.0

2.8 1.1 1.8

Gal 1 ons

15.0 2.3 0 .3 5.0 0.2 0.7 0.3 0.2 7 .3 0.9

3.0 0.3 3.0 1 .5

38.3 20.9

0.4 0.1 0 . 3

P a i n t P roper t i es : Pigment Volume Concentrat ion, %: 22.5 Volume So l i ds , 96: 36.4 Weight per Ga l lon , l b : 10.7 Stormer, KU: 83 I C I , Poise: 1 .9 pH Value: 8.7 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 3 Heat-Age S t a b i l i t y , 120F. weeks passed: 2 R a t i o o f Ucar Latexes 379:6030: 70:30

F i l m Proper t i es : Gloss, 60: 64 Gloss, 20: 18 Cont ras t Rat io , 6-mi l wet drawdown: 0.972 Ref lectance, %: 91.9 Block Resistance: 9 Flow and Leve l ing : Good Low Temperature Coalescence: 10 Washab i l i t y , s t a i n removal*: 10

(crayon, f e l t pen, l i p s t i c k , p e n c i l ) % g loss re ta ined : 92

*Washed w i t h Fan tas t i k ; lO=complete s t a i n removal Wet Adhesion, g loss a lkyd : Exc

SOURCE : Ucar Emulsion Systems: 1-2473

Ucar Latex 0030: Formulat ion

112 Water-Based Pain? Formidations

_ _ _ ~ I n t e r i o r V i n y l A c r y l i c Eggshel l f o r R o l l e r and Brush A p p l i c a t i o n

I n q r e d i e n t s : Pigment Gr ind: Water Propylene G1 yco l Tamol 1124 T r i t o n Nonionic S u r f a c t a n t X-100 C o l l o i d 643 Proxel GXL

T i -Pure R-900 Omyacarb UF

AMP-95

ASP-1 70

Letdown : Ucar Latex 379 Ucar F i l m e r IBT Col l o i d 643

Ucar Polyphobe 9831 Rheology M o d i f i e r Water

P a i n t P r o p e r t i e s :

AMP-95

Pigment Volume Concentrat ion, %: 36.4 Volume S o l i d s , %: 37.4 Weight S o l i d s , %: 54 .4 Weight pe r Gal lon, l b : 11.3 Stormer, KU: 95 I C I , Po ise: 1 . 2 pH Value: 8.5-9.0 V o l a t i l e Organic Content, g/L: 121

F i l m P r o p e r t i e s : Gloss, 60: 35 Flow and Leve l i ng : Good Sag Resistance, m i l s : 12

Pounds

100.0 26.0

8.0 2.0 1 .5 1 .5 2.0

230.0 100.0 50.0

420.0 12.0 2.5 2.0

11 .o 168.0

Ga l l ons

12.00 3.02 0.81 0.23 0.21 0.15 0.25 6.91 4.42 2.33

46.41 1.52 0.34 0.25 1.27

20.07

SOURCE: Ucar Emulsion Systems: Ucar Polyphobe 9831 Rheology Modi f i e r : Formulat ion Suggest ion 1-2241

I n t e r i o r V i n y l A c r y l i c Eqashel 1 f o r R o l l e r and Brush A p p l i c a t i o n

Ing red ien ts : Pigment G r i nd : Water Propyl ene G1 yco l Tamol 1124 T r i t o n Nonionic Sur fac tan t C o l l o i d 643 Proxel GXL

T i -Pure R-900 Omyacarb UF

AMP-95

ASP- 1 70

x-1 00

Pounds

100.0 26.0

8.0 2.0 1.5 1 .5 2.0

230.0 100.0 50.0

Letdown : Ucar Latex 379 420.0 Ucar F i lmer IBT 12.0 C o l l o i d 643 2.5 AMP-95 2.0 Ucar Pol yphobe 102 Rheology Modi f i e r 30.0 Water 149.0

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 36.4 Volume So l i ds , %: 37.4 Weight So l i ds , %: 54.4 Weight per Gal lon, l b : 11.3 pH, i n i t i a l : 8.5-9.0

Thickener Comparison: Ucar Polyphobe 114:

NVM lb/100 g a l : 5.0 Stormer, KU: 93 I C I , P: 0.5 Flow/Level ing: Poor Sag Resistance: 24+

Ucar Polyphobe 102: NVM l b / l 0 0 g a l : 7 .5 Stormer, KU: 92 I C I , P: 1.8 Flow/Level ing : Exce l l en t Sag Resistance: 12

Ucar Polyphobe 102/114 b lend ( 4 : l ) : NVM lb /100 aa l : 4.0 l b o f Ucar Po ly . 102 Storme;, KUT 97 I C I , P: 1.6 F1 ow/Level i ng : Very Good Sag Resistance: 14

Gal lons

12.00 3.02 0.81 0.23 0.21 0.15 0.25 6.91 4.42 2.33

46.41 1.52 0.34 0.25 3.45

17.89


SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion 1-2237


I n t e r i o r V i n y l A c r y l i c Semigloss

I nared i en t s : Pigment Gr ind : Water Polywet ND-35 T i -Pure R-902 Drewpl us L-475

Letdown : Ucar Latex 367 Water Ucar F i lmer I B T Nuosept 95 T r i t o n Nonionic Sur fac tan t GR-5M

Drewpl us L-475 Water (ad jus t according t o Polyphobe Ucar Polyphobe 114 Rheology M o d i f i e r

AMP-95

Pounds

104.9 4.0

205.0 2.0

423.0 33.3 23.8

2.0 1 .o 5.0 4.0

l e v e l ) 214.5 26.5

Gal l ons

12.59 0.39 6.16 0.28

47.00 4.00 3.01 0.21 0.12 0.64 0.56

25.75 3.05

Pa in t P roper t i es : Pigment Volume Concentrat ion, %: 20.4 Volume So l i ds , 96: 40.3 Weight So l ids , %: 54.2 Weight per Gal lon, l b : 10.5

Thickener Compari son : Ucar Polyphobe 114:

NVM lb/100 g a l : 6.6 B rook f i e ld , 0.3, P: 680 I C I , P: 0 . 5 60 Gloss: 79

Ucar Polyphobe 102: NVM lb /100 g a l : 10.7 Brook f ie ld , -0 .3 , P: 186 ICI, P: 2.2 60 Gloss: 74

Ucar Polyphobe 103: NVM lb/100 gal : 8.2 B rook f i e ld , 0.3, P: 336 I C I , P: 1.5 60 Gloss: 69

Ucar Polyphobe 107; NVM lb/100 g a l : 5.1 B rook f i e ld , 0.3, P: 226 I C I , P: 0.7 60 Gloss: 67

NVM lb /100 g a l : 5.6 B rook f i e ld , 0.3, P: 2,086 I C I , P: 0.7 60 Gloss: 70

Ucar Polyphobe 106HE:

SOURCE: Ucar Emulsion Systems: Formulat ion Suggestion 1-2239


Intumescent I n t e r i o r White F i re-Retardant Pa in t

I ngred i en t s : Pigment Grind: Water Potassium Tr ipolyphosphate (KTPP) Sur fac to l 365 Ucar Latex 367 C o l l o i d 677 Phos-Chek PI30 Aero Melamine (powdered grade) D i pen tae ry th r i t o 1 (powdered grade) Nuosept 6351 T i -Pure R-900 Chlorez 700

Pounds

290.0 3 .0 4.0

75.0 3.0

260.0 80.0 75.0 1 . o

60.0 40.0

Gal 1 ons

34.8 0 .3 0.4 8.2 0.3

17 .3 6.8 6.4 0.1 1 .8 2.9

Letdown : C e l l o s i z e Hydroxyethyl Ce l l u lose QP-15,OOOH

(1 .5% aqueous s o l u t i o n ) 45.0 5.2 Ucar Latex 367 145.0 16.0 C o l l o i d 677 1 .o 0.1

Procedure:

t h e order l i s t e d . Completely d isperse each ing red ien t be fo re adding t h e nex t . When t h e pigment g r i n d s l u r r y i s complete, a g i t a t e f o r an a d d i t i o n a l f i v e minutes; t r a n s f e r t o a pebble m i l l and g r i n d t o Hegman 3. Under a g i t a t i o n , prepare t h e f i n a l letdown i n t h e order l i s t e d . Under a g i t a t i o n , add t h e pigment g r i n d s low ly t o t h e letdown. Note: P ro tec t t h i ckener s o l u t i o n s w i t h p rese rva t i ve du r ing processing and storage.

Pa in t P roper t i es :

Under a g i t a t i o n , add a l l i ng red ien ts o f t h e pigment g r i n d i n

Pigment Volume Concentrat ion, %: 74 To ta l So l i ds , % by weight: 60 Weight per Gal lon, l b : 10.8 Stormer. KU: 75-80 Cont ras t Rat io : 0.87

SOURCE: Ucar Emulsion Systems: Ucar Latex 367: Formulat ion Suggestion 1-1338


Low VOC I n t e r i o r F l a t

_ _ _ _ _ _ _ Pounds Ga l l ons I n q r e d i e n t s : Pigment Gr ind : Water Kathon LX Tamol 1124 T r i t o n Nonionic S u r f a c t a n t N-101 Drewpl us L-475 Ucar Polyphobe 102 Rheology M o d i f i e r Sodi um Hydrox ide T i -Pure R-902 Durami t e I ceberg Water

Letdown : Ucar Latex 379 Water Drewpl us L-475 Ucar F i l m e r I B T Ucar Polyphobe 102 Rheology M o d i f i e r

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 64.9 Volume S o l i d s , %: 32.3 Weight S o l i d s , %: 53.1 Weight pe r Ga l l on , l b : 12.1 Stormer, KU: 92 VOC, grams per l i t e r : 26.09

F i l m P r o p e r t i e s : Gloss, 60: 2 Sheen, 85: 3 Con t ras t R a t i o , 6-mi l wet drawdown: 0.977 Ref lectance, %: 91 .8 Scrub Resistance, c y c l e s passed: 161

333.3 40.00 1.7 0.20 5.1 0.52 2 .0 0.23 2.0 0.26

15.0 1.73 3.0 0.15

190.0 5.70 185.0 8.21 155.0 7.07 50.0 6.00

200.7 22.18 39.4 4.73

2 . 5 0.33 7.7 0.96

15 .0 1.73

SOURCE: Ucar Emulsion Systems: Formulat ion Suggest ion 1-2238

Interior Paints and Related Products 11 7

- S o l v e n t Free I n t e r i o r S a t i n P a i n t

M a t e r i a l : G r i n d : Water KTPP (100%) Tamol 731 (Rohm and Haas) T r i t o n CF-10 (Rohm and Haas) Kathon LX 1.5% (Rohm and Haas) FCA (Foam C o n t r o l Agent) T i -Pure R-900 (DuPont) N y t a l 300 ( R . T . V a n d e r b i l t ) C a l c i um Carbonate

Letdown : Rovace SF-091 (Rohm and Haas) Rovaque OP-62 L O (Rohm and Haas) FCA (Foam C o n t r o l Agent) A c r y s o l RM-2020 (Rohm and Haas) A c r y s o l TT-935 (Rohm and Haas) Sodium Carbonate Water

P r o p e r t i e s : Pigment Volume Content , %: 37.0 % N o n v o l a t i l e (by volume): 34.0 Stormer V i s c o s i t y , K . U . : 95+-5 I C 1 V i s c o s i t y . Poise: 1.1+-2 Gloss a t 60 , -%: 13.0

Recommended P r o d u c t : A g i t a n 315: E f f i c i e n t . F i n e

A l t e r n a t i v e Produc ts : A g i t a n 260: E f f i c i e n t , c o s t A g i t a n 731: E f f i c i e n t , z e r o

SOURCE: K i n g I n d u s t r i e s : Formu

!&

260.0 1 .5 7.0 2.5 1 . 7 1 . o

170.0 40.0 70.0

372.2 45.0

2 .0 15.0 12.5 24.0 57.5

%wt

31.20 0 .07 0 . 7 6 0.28 0.20 0.13 5.10 1.68 3.11

41.50 5.22 0.26 1.65 1 .42 2.52 6.90

t u n i ng w i 11 p r o v i d e c o s t b e n e f i t s .

e f f e c t i v e . voc . a t i o n WR-39-3


White I n t e r i o r Eqsshe l l

I n q r e d i e n t s : ~~ Pounds Gal l o n s Pigment Gr ind : Water 226.7 27.21 Ucar Polyphobe 9831 Rheology M o d i f i e r 8.5 0.97 Nuosept 145 2.3 0.25 Tamol 731A T r i t o n Nonionic Sur fac tan t N-57 AMP-95 Propylene Glyco l Col l o i d 640 Tronox CR-800 Opt i wh i t e Burgess No. 98

Letdown : AMP-95 Ucar F i lmer IBT Water Ucar Latex 353 Col l o i d 640

P a i n t P roper t i es : PVC, %: 35.8 Volume So l i ds , %: 38.2 Weight So l i ds , %: 52.4 Weight per Ga l lon , l b : 11.04 Stormer, KU: 95 I C I , po ise : 1.4 pH, i n i t i a l : 9.0 Freeze-thaw S t a b i l i t y , 5 cyc Heat-Aged S t a b i l i t y , 2 weeks

F l m Proper t i es : Ref lectance, %: 91 .4 Gloss, 60: 6.3 Sheen, 85: 22.6 Cont ras t Ra t io , 3-mi l f i l m : .969 Co lor * :

Acceptance : Exc Development: Exc

*T in ted w i t h 2% by weight ph tha lo i r o n ox ide (Huls 888-1045).

11.5 1.25 2.3 0.25 2.0 0.26

51.8 6.00 1 .9 0.25

225.0 6.54 100.0 5.46 25.0 1.15

2.0 0.27 22.5 2.85 78.7 9.45

341 .O 37.47 2.8 0.37

es: Pass a t 120F: Pass

SOURCE: Ucar Emulsion Systems: Formu

b l u e (Hu ls 888-7124) o r red

a t i o n Suggest ion 1-1520


Green Lacquer

I n s r e d i e n t s : P i ament G r i nd : Water Ethy lene Glyco l Dispersant ( 1 ) T e r g i t o l Sur fac tan t NP-10 Ant i foam (2) Phthalo Green (3 ) Medium Chrome Yel low ( 4 )

Let Down: Ucar Veh ic le 443 B u t y l C a r b i t o l Solvent T r i bu toxyethy l Phosphate Phthalo Green (3) Deionized Water

Pounds

45.00 0.65 6.26 0.62 1 .oo

50.00 33.04

Gal l o n s

5.40 0.07 0.68 0.07 0.13 4.95 0.67

666.11 75.19 13.26 1.67 13.26 1.58 51.50 5.10 26.55 3.19

Suppl i e r s : ( 1 ) Dispersant - C o l l o i d 107 ( C o l l o i d s ) o r e q u i v a l e n t . ( 2 ) Ant i foam - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t . (3) Phthalo Green - T i nt-Ayd WD-2744 D i spers i on (Danie l

( 4 ) Medium Chrome Yel low - X-3356 C.P . Medium Y (Ciba-Geigy) Products) o r e q u i v a l e n t .

o r e q u i v a l e n t . Lacquer P r o p e r t i as :

by Weight: 37 by Volume: 31

P i gment/Bi nder Rat i o : 0.25/ 1 So l ids , %:

pH: 8 .5 V i s c o s i t y , No. 4 Ford Cup, sec: 25

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 443: Formulat ion Suggest ion LP-3812

Lacquers 121

Foam Con t ro l w i t h Ag i tan A d d i t i v e s i n a H iah Gloss DIY Waterborne Lacquer

The cho ice o f coa lesc ing agents can s i g n i f i c a n t l y i n f l u e n c e t h e genera t ion o f foam i n a waterborne fo rmu la t i on as w e l l as a f f e c t t h e performance o f t h e foam c o n t r o l agent (FCA).

Component: Rhoplex CL-104 (Rohm and Haas) DC-14 (Dow Corning A d d i t i v e s ) FCA (Foam Cont ro l Agent) Michem 39235 (Michelman)

Ad jus t pH t o 7-8

Aqueous Ammonia 28% Propylene Glyco l Coalescent Water

Ad jus t t o v i s c o s i t y

Water

j& %Wt 642.8 76.83

24.7 2.95 1 .3 0.16

21 . e 2.61

3 24.7 37.6 29.2

51.5

0.36 2.95 4.49 3.49

6.16

Proper t i es : % N o n v o l a t i l e (by we igh t ) : 30.7 % N o n v o l a t i l e (by volume): 29.1

V i s c o s i t y #2 Zahn, 25C (seconds): 20-26 Theore t i ca l VOC (pounds/gal lon): 2.07 Theore t i ca l VOC (grams/l i t e r ) : 249

Th is study has demonstrated t h a t d i f f e r e n t coalescents can

pH, 25C: 7.5-8.0

s i g n i f i c a n t l y a f f e c t foam genera t ion and hence t h e performance o f t h e foam c o n t r o l agent. However, Ag i tan 295 performed e q u a l l y w e l l i n bo th systems, regard less o f t h e coa lesc ing agent used.

For optimum foam p reven t ion and f i l m p r o p e r t i e s , Ag i tan 305 i s recommended w i t h t h e Texanol, w h i l e Ag i tan 731 i s recommended f o r t h e DPnB.

SOURCE: K ing I n d u s t r i e s : WR-32: FCA's f o r Waterborne Wood Formulat ions


White Lacauer

Ina red ien ts : Pigment G r i nd : Ucar Veh ic le 443 D i spersant (1 ) Su r fac tan t (2 ) T e r g i t o l Su r fac tan t NP-10 Ant i foam (3 ) T i tan ium Diox ide (4 )

Pebble M i l l ove rn igh t .

Le t Down: Ucar Veh ic le 443 Ant i foam ( 3 ) Proposol Solvent B T r i bu toxyethy l Phosphate Mar-Resi s t a n t A id ( 5 ) Ammonium Benzoate, 10% Aqueous So lu t i on Dei oni zed Water

Pounds

149.9 5.9 2.1 2.1 0.9

187.4

421.3 0.9

40.9 20.4

0.9 10.0

150.8

Gal l o n s

17.2 0.7 0.3 0 . 2 0.1 5.5

48.2 0.1 5 .6 2 . 4 0.1 1.1

18.1

Supp l ie rs : ( 1 ) Dispersant - Disperbyk (Byk-Mal l inckrod t ) o r equ iva len t . (2 ) Su r fac tan t - Sur fyno l 104 ( A i r Products) o r equ iva len t . (3 ) Ant i foam - Hodag PX-218 (Hodag) o r equ iva len t . ( 4 ) T i tan ium Diox ide - Zopaque RCL-9 (SCM) o r equ iva len t . (5) Mar-Resistant A id - Byk 301 (Byk -Ma l l l i nck rod t ) o r

equ iva len t .

Lacquer P roper t i es : Pigment/Binder Rat io : 0.8/1 To ta l So l i ds , %: 42.4 pH: 8 . 6 V i scos i t y , No. 4 Ford Cup, sec:

I n i t i a l : 20 A f t e r 10 days a t 140F: 20

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 443: Formulat ion Suggestion LP-3846

Lacquers 123

White Lacquer

I n a r e d i en ts : P i gment G r i nd : Ethy lene G lyco l D ispersant (1 ) T e r g i t o l S u r f a c t a n t NP-10 Ant i foam (2) Ammonium Hydroxide, 28% Aqueous Deionized Water T i t a n i um D iox ide (3)

Pounds

3.16 6.31 1.59 0.23

S o l u t i o n 0.44 28.20

156.52

Gal 1 ons

0.34 0.70 0.18 0.03 0.05 3.39 4.59

Gr ind f o r 15 minutes a t h i g h speed i n a high-shear mixer .

Let Down: Ucar Veh ic le 443 T r i bu toxye thy l Phosphate F i lmer (4) B u t y l C a r b i t o l So lvent Ammonium Benzoate Deionized Water

546.84 62.00 4.60 0.55

11.19 1.42 11.20 1.41 0.74 0.07

210.25 25.29

Suppl i ers : (1) D ispersant - Disperbyk (Byk -Mg l l i nck rod t ) o r equ iva len t (2) Ant i foam - C o l l o i d 675 ( C o l l o i d s ) o r e q u i v a l e n t . (3) T i tan ium D iox ide - T i tanox 2060 (NL I n d u s t r i e s ) o r

( 4 ) F i lmer - Texanol (Eastman) or e q u i v a l e n t . e q u i v a l e n t .

Lacquer P r o p e r t i e s : Pigment/Binder Ra t io : 0.67/1 S o l i d s , %:

by Weight: 38.5 by Volume: 28.1

pH: 8 . 5 V i s c o s i t y . No. 4 Ford Cup, sec: 35

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 443: Formula t ion Suggest ion LP-3813

Primers 125

fi Halox BW-100

Grind: Water Propylene G1 yco l Dow ic i l 75 C o l l o i d 111 S t rodex PK-95G Sur fyno l 104E Drewplus L-475 Texanol Pol yphobe 102 Aqua Ammonia (28%)

Lbs./100 Gals. Gms/Liter 250.0 300.0

15.0 18.0 1 .o 1.2 5 .0 6.0 3.5 4.2 4.0 4.8 2.0 2.4

10.0 12.0 16.0 19.2 4.0 4.8

Add t h e f o l l o w i n g a t h igh speed and d isperse t o 4+ Hegman g r i n d .

T i -Pure R-902 Halox BW-100 Beaverwhi t e 325 Snowf 1 ake

Letdown : CL 27NA Drewpl us L-475

175.0 210.0 100.0 120.0 50.0 60.0

185.0 222.0

340.0 408.0 2.0 2.4

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uni form. Premix t h e f o l l o w i n g 2 raw m a t e r i a l s and add under good a g i t a t i o n

DO NOT AERATE!

Water Pol yphobe 106E

Mix u n t i l un i fo rm.

Formula Constants: % P i gment/Wt . : 42.91 % P i gment/Vol . : 20.07 % Sol ids/Wt. : 57.79 % So l ids /Vo l . : 39.51 % PVC: 50.79 VOC, l b s . / g a l . : 1.01 VOC. g/L: 120.97

25.0 30.0 2 .0 2.4

Formula P roper t i 8s: Dens i ty l b s . / g a l . : 11.90 Densi ty g/L: 1,427.4 KU Visc. I3 R.T. : 85-90 pH I3 R.T . : 8.5-9.0

SOURCE: Halox Pigments: SugQested Formulat ion DOW/BW-100


A l k v d M o d i f i e d L a t e x Pr imer

I n g r e d i e n t : Pigment G r i n d : Water Busperse 39 /D ispersant Bubreak 448/Defoamer

(Premix n e x t 2 i t e m s )

Water QP-15000 C e l l o s i z e / H y d r o x y e t h y l

I g e p a l CTA 6 3 9 / S u r f a c t a n t Arop laz 1271/Long O i 1 A1 kyd B u t r o l 2 3 / M o d i f i e d Bar ium Meta-

b o r a t e T i - P u r e R-SOO/Titanium D i o x i d e -

R u t i l e M i ca-325 Atomi t e / C a l c i um Carbonate N y t a l 300/Talc-Magnesium S i l i c a t e

L e t Down: Rhoplex MV-23/Acry l ic Emuls ion Texano l /Es ter A l c o h o l E t h y l e n e G l y c o l Water

Pai n t P r o p e r t i es : T o t a l V e h i c l e 60.27 Pigment 39.73 V o l a t i l e 42.67 Organ ic S o l v e n t 7.59 Non-Vo la t i l e 57.33 Non-Vo la t i 1 e V e h i c l e 17.60

D e n s i t y ( lb /U.S. gal): 11.99 S p e c i f i c G r a v i t y : 1 .44 P . V . C . : 43.42% P/B R a t i o : 2.258 Spread @ 1 M i l : 624 F2 C o a t i n g VOC: 220 G/L M a t e r i a l VOC: 109 G/L

C e l l u l o s e

- Lb

100.10 8.01 3.00

25.02

1 .oo 6.01

42.04 100.10

200.19 25.02 75.07 75.07

483.46 5.00

30.03 20.02

w 83.10 16.90 61.07 10.58 38.93 22.02

Gal

12.02 0.74 0.44

3.00

0.09 0.68 5.01 3.25

6.01 1.06 3.32 3.17

54.94 0.63 3.23 2.40

Wt%

8 .35 0.67 0.25

2.09

0.08 0.50 3.51 8.35

16.69 2.09 6 .26 6 .26

40.32 0.42 2.50 1.67

SOURCE: Buckman L a b o r a t o r i e s : Formula t on Sugges ion: KR-01

Primers 127

Ancamide 2353 Curina Aaent Ant i -Cor ros ive Pr imer P re l im ina ry Formula t ion

P a r t A: L i q u i d DGEBA Epoxy MPA-1078 (Rheox)

Mix w e l l , then add a t h i g h speed:

T i Pure R-900 ( DuPont) 10 Wollastekup AS (Nyco)

Disperse t o 5 Hegman and 125F. Reduce speed and add:

!&J

233.7 4.0

25.0 370.0

Xylene (Ashland) 45.0

Par t B: Ancamide 2353 ( A i r Products) MPA-1078 (Rheox) Bee t le 216-8 (Cyanamid)

125.54 4.0 15.0

Mix w e l l a t h igh speed, then add:

Red I r o n Oxide 5-3100 (Minera l Pigments) 60.0 Beaverwhite 325 (Cyprus) 96.7 Phospl us 5-0866 ( M i ne ra l Pigments) 141.4

Disperse t o 5 Hegman and 125F. Reduce speed and add:

Diacetone A lcoho l (Union Carbide) Super High F1 ash Naphtha (Ash1 and)

31.3 106.8

Gal 24.093 0.541

0.751 15.289

6.207

15.212 0.541 1.724

1.441 4.204 5.065

3.997 14.691

Proper t i es : Volume Sol i d s : 71.8% VOC: <2.1 l b / g a l PVC: 39.7% Mix ing Ra t io : 1:l by Volume CPVC: 54.6% Pot L i f e , h r : 3 PVC/CVPC : 0.725 Dry t o Touch, h r : 1 Weight/gal lon. Pa r t A: 14.45 Dry Through, h r : 6 Weigh t /ga l lon , Pa r t B: 12.45 Weight/gal l on : 13.45

SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing Agent: Table 9 Formulat ion

I28 Water-Based Paint Formulations

Anquami ne 401 /Semi -sol i d Epox D i s p e r s i on ___ Lead and Chromate F r e e Red I ronYOx ide P r i m e r

P a r t A* Dow XUS19000.01 Epoxy Res in Benzy l A l c o h o l Water

P a r t B : Anquamine 401 C u r i n g Agent Water G l a c i a l A c e t i c A c i d ( A i r P r Red I r o n Ox ide** LVT 400 T a l c ( B a r r e t t ) W a l l a s t o k u p I O E S (Nyco) Zeospheres 400 ( 3 M ) Ha lox SZP 391 Dowanol PM S o l v e n t (Dow) Dowanol PnP S o l v e n t (Dow)

& @& 223.79 23 .11

1 1 . 1 7 1 .28 213.66 25 .60

( A i r P r o d u c t s ) 111.95 80.05

o d u c t s ) 2 . 1 0 62 .98

125.94 139.95

62 .98 76 .96 32 .18 33 .59

1 2 . 2 5 9 . 5 9 0 . 2 4 I . 5 7 5 .29 5 . 7 8 3 .43 3 .07 4.23 4.55

* A l t e r n a t e l y use Epi-Rez 3515-W-60 a t same l o a d i n g * * A l t e r n a t i v e l y use T i 0 2 f o r o f f - w h i t e p r i m e r

T y p i c a l P r o p e r t i e s : W t S o l i d s ( % ) : 6 5 . 9 6 Volume S o l i d s ( % ) : 51 .17 PVC ( % ) : 37 .4 Res in S t o i c h i o m e t r y : 1 . 6 : 1 VOC ( l b / g a l ) : 1 . 2 1 VOC ( g / l ) : 145

A n t i c o r r o s i v e P r imer P r o p e r t i e s : Pot L i f e , h r : 4 M i x R a t i o : 1 : l Tack F ree Time, h r : 1 . 0 Hard D r y Time, h r : 6 VOC, l b / g a l : 1 . 2 Volume S o l i d s , %: 51 PVC, % : 37 Cross Hatch Adhes ion : 5 1/4" Mandre l Bend: Fa i 1 D i r e c t Impac t Resi s tance , i n-1 bs: 20 D i r e c t Impact Resi s tance , i n-1 bs: (5

SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Anquamine 401 C u r i n g Agen t : F o r m u l a t i o n 3

Primers 129

Anquami ne 401 /Sol i d Resi n D i spe rs i on Lead and Chromate Free Red I r o n Oxide Pr imer

Par t A : Epi-Rez 3520-WY-55 Epoxy Resin ( S h e l l ) Benzyl Alcohol Sur fyno l DF-58 Defoamer ( A i r Products) Water Red I r o n Oxide Barium S u l f a t e lOES Wollastokup (Nyco) Halox SW-1116 Zeosphere 4007 (3M) Water Ground Mica

!=& 342.6

8.9 4.0

61.6 73.0 72.8

109.4 100.0 73.0 10.3

High speed d i spe rse t o a t e x t u r e of N . S . , then add:

Epi -Rez 3520-WY-55 Epoxy Resi n (She1 1 ) 129.3 Water 22.1

Par t 8 : Anquamine 401 Cur ing Agent ( A i r Products) 60.7 Water 111.8

Typ ica l P roper t i es : W t S o l i d s ( % I : 63.1 Volume S o l i d s ( % ) : 47.3 PVC (%) : 35.1 Resin S to ich iomet ry (on equ iva len ts ) : 1.6:1 VOC ( l b / g a l ) : 1.02 voc ( g / l ) : 122.5

Pot L i f e , h r : 4 Mix Rat io : 4 : l Tack Free Time, h r : 0.5 Hard Dry Time, h r : 6 VOC, l b / g a l : 1 . 0 Volume S o l i d s , %: 47 PVC, %: 35 Cross Hatch Adhesion: 4 Penc i l Hardness, ove rn igh t : HB Penc i l Hardness, 7 days: H 1/4” Mandrel Bend: F a i l D i r e c t Impact Resistance, i n - l b s : 35 Reverse Impact Resistance, i n - l b s : t5

A n t i c o r r o s i v e Primer P roper t i es :

SOURCE: A i r Products and Chemicals, I n c . : Anquamine 401 Agent: Formula t ion 4

37.65 1.03 0.48 7.39 1.79 1.99 4.52 4.20 3.65 0.44

14.21 2.65

6.58 13.42

Cur ing


Corrosion Inhibitive Primer

Material: j& Add to mixer with agitation: Water 98.6 Bubreak 448--Defoamer 2.0 Busperse 39--Dispersant 5 . 0 Igepal CTA-639 2.0 Premix and add the following: Natrosol 250HR 2.0 Water 6.0 Stir in the following pigments: Atomi te 135.0 Ti -Pure R-900 100.0 Busan 11-M1 5 0 . 0 High speed disperse to minimum 5 . 0 NS grind Let down with the following materials: Aquamac 700 570.0 Texanol 69.0 Butrol 35--Flash rust inhibitor 7.0 Parameters: Properties: Weight Solids: 52.9% Viscosity: 80-85 KU Volume Solids: 40.5% DH: 8.4-8.6

Gals

11.83 0.30 0.46 0.23

0.40 0.72

5.97 3.08 1.82

65.82 8.75 0.63

Pi gment Weight : 27.4% Gloss (a 60: 18-22 PVC: 27.9% P/B Ratio: 1.08 VOC Level: 174 g/L

Metal Wash Primer

With today‘s concern over coatings containing chromate pigments, there is a need for a chromate-free metal wash primer. Buckman Laboratories has developed a metal wash primer made with Busan 1 1 4 1 , which is a non-lead, non-chromate anticorrosive pigment. This formula is based on the military specification coating MIL-P-15328C entitled “Primer (Wash) Pretreatment Blue.” This specification is the same a s the U . S . Navy Formula 117-8 for metals. The Busan 11-M1 based primer has performed well in tests versus the traditional zinc chromate primer. The formula is as follows: Resin Component (80 gal lonsl : Lbs/100 Gals Polyvinyl -Butyral Resin (Ucar XYHL) 56 Busan ll-Ml 50 Ti-Pure R-900, Titanium Dioxide 50 Copper-Phthalocyanine Blue 17 Butyl Alcohol, Normal 125 Isopropyl Alcohol 341 Water 15 Acid Component (20 aallons): Phosphoric Acid, 85% 28 Water 25 Isopropyl Alcohol 99 Package separately: The mixed container must be used within

SOURCE: Buckman Laboratories: Suggested Formulations 8 hours after mixing.

Primers 131

Cost E f f e c t i v e 2K Water-Base Epoxv Pr imer Usina Halox SW-111

Component A: Lbs./100 G a l s . Grams/Li t e r Add t h e f o l l o w i n g i n o r d e r l i s t e d : €p i -Rez 5522-WY-55 450.0 540.0 D i ace tone A l c o h o l 7 .0 8.4 Water 100.0 120.0 Nopco NDW 2.0 2 . 4

Mix f o r 5 minu tes and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h speed :

R . I . O . R-4098 Halox SW-111 Wol 1 as tokup 1 OES Sparmi t e

100.0 50.0

150.0 100.0

120.0 60.0

180.0 120.0

H igh speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !

Epi r e z 5522-WY-55 Water

Component B: Mix a t l o w speed: € p i -Cure 8290-Y-60 Nacor r 1754

30.0 36.0 25.0 30.0

Lbs. / l o 0 Ga ls . Grams/L i t e r

60.0 72.0 3 . 0 3 .6

A d d t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t h i g h speed:

Zeeospheres 400 325 Mesh W.G. M ica

100.0 10.0

120.0 12.0

H igh speed d i s p e r s e t o 4+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !

Water M i x r a t i o : * Component A -

Component B - *TO o b t a i n optimum r e s u

p r i o r t o a p p l i c a t i o n . Formula Constan ts : % P i gment/Wt. : 41.65 % P igment /Vo l . : 18.78 % S o l i d s / W t . : 65.81 % Sol i d s / V o l . : 49.66 % PVC: 37.81 P/B R a t i o : 1.72 VOC, l b s . / g a l . : 1 .25 voc, g/L: 150.00

40.0 48 .0 80% by volume. 20% by volume. t s , a l l o w 20-30 minu tes i n d u c t i o n t me

Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 12.25 D e n s i t y g /L: 1,470.0 Set - to - touch: 30 minu tes Dry Hard: Overn igh t

SOURCE: Ha lox Pigments: Suggested F o r m u l a t i o n


D i pp i na Primer

Ing red ien ts : P i oment Grind: Oeioni zed Water Ammoni um Hydroxi de, 28% Aqueous Sol u t i on Dispersant ( 1 ) T e r g i t o l Sur factant NP-10 Anti foam (2) T i t a n i um Dioxide (3) Barytes (4 ) Stront ium Chromate ( 5 )

Let Down: Ucar Vehic le 443 Anti foam ( 2 ) Bu ty l Cel loso lve Solvent Bu ty l C a r b i t o l Solvent Hexamethoxymethylmelami ne (6) Ammonium Benzoate, 10% Aqueous So lu t i on Ammonium Hydroxide, 28% Aqueous So lu t i on Oeioni zed Water

Suppl iers :

Pounds

41.6 0.2 1.6 3.2 0 .7

50.0 53.1 57.7

500.0 0.8

51.5 20.6 54.7 8.5 6.5

127.1

Gal l ons

5.00 0.02 0.22 0.36 0.09 1 .so 1.45 1.87

57.52 0.11 6.86 2.60 5.47 0.93 0.74

15.26

o r equi va lent . (Oavis/MPC) o r equiva lent . Cyme1 303 (American Cyanamid)

(1) Dispersant - Bykumen WS (Byk-Mal l inckrodt) o r equiva lent . ( 2 ) Anti foam - Hodag PX-218 (Hodag) o r equiva lent . (3) Ti tanium Dioxide - Ti-Pure R-960 (Du Pont) o r equiva lent . (4) Barytes - Sparmite ( P f i z e r ) (5) Stront ium Chromate - 5-1365 (6) Hexamethoxymethylmelamine -

o r equiva lent .

Primer Proper t ies: Sol ids, % by w t : 37.4 pH: 9.5 V iscos i t y , B rook f i e ld , cP: 800

Add Water t o 18 sec (#3 Zahn Cup) f o r d ipp ing.

Primer Performance:* Bake Cycle, min: S a l t Spray:

Flash Time: 10 Hours Exposed: 565 Bake a t 200F: 2.5 Rust ing Rat ing: 9 F ina l Bake a t 300F: 10 B l i s t e r Rat ing: 9M

Penci l Hardness: 2H Creepage, i n : 1/8 Gloss, 60: 30 Impact Resistance, i n - l b :

D i r e c t : 45 Reverse: 5

*Substrate - Bonder i te 1000

SOURCE: Ucar Emulsion Systems: Ucar Vehic le 443: Formulat ion Suggestion C-2030

Primers 133

Experimental General Purpose Tann in-Sta in Res is tan t Water-Base Pr imer Usina Halox X t a i n A

Gr ind : Water Na t roso l 250 MR Aqua Ammonia (28%) Ethy lene G1 yco l Tamol 681 T r i t o n CF-10 Foamaster VL

Halox X t a i n A Snowf 1 ake

R-902

Lbs. / l o 0 Gals. Gms/Li t e r 100.00 120.00

0.75 0.90 1 .oo 1.20

30.00 36.00 15.00 18.00 3.00 3.60 2.00 2.40

150.00 180.00 15.00 18.00

220.00 264.00

High speed d i spe rse t o 4+ NS g r i n d .

Water 25.00 30.00

Letdown : Mor-Lok 1035 Skane M-8 Aqua Ammonia (28%) Texanol Foamaster VL

467.00 560.40 2.00 2 .40 1 .oo 1.20 5.00 6.00 1 .oo 1.20

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un i fo rm.

QR-708 Water

Add t h e f o l l o w i n g w h i l e m ix ing and mix u n t i l un i fo rm

5.50 79.00

P roper t i es : l b s . / g a l . : 1

Formula Constants: % P i gment/Wt . : 34.36 % Pigment/Vol . : 15.03 % Sol ids/Wt. : 55.81 % S o l i d s / V o l . : 40.73 % PVC: 36.89 VOC, l b s . / g a l . : 1.10 VOC, gms./ l . : 132.04

Formula Dens i t y Dens i ty PH @ R. KU Visc

SOURCE: Halox Pigments: Suggested Formu

.23 gms./ i . : 1,346.7 . : 9.0-9.5

@ R . T . : 95-100

a t i o n MOR-1035-A

6.60 94.80


ExDer i ren ta1 H i ph Performance Tanni n-Stai n Res is tan t Water-Base Pr imer Usina Halox X t a i n A

Gr ind : Lbs./100 Gals. Gms/Liter Water 125.00 150.00 Nat roso l 250 MR Aqua Ammonia (28%) E t h y l ene G1 yco l Tamol 681 T r i t o n CF-10 Foamaster VL

Halox X t a i n A Snowf 1 ake

High speed d i spe rse t o 4+ NS g r i n d

Water

Letdown : Mor-Lok 1043 Skane M-8 Aqua Ammonia (28%) Texanol Foamaster VL

R-902

0.75 1.00

30.00 18.00 3.00 2.00

150.00 5.00

277.00

25.00

434.00 2.00 1 .oo 4.75 1 .oo

0.90 1.20

36.00 21 - 6 0

3.60 2.40

180.00 6.00

332.40

30.00

520.80 2.40 1.20 5.70 1.20

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un i fo rm.

Add t h e f o l l o w i n g w h i l e m ix ing and mix u n t i l un i fo rm.

QR-708 Water

Formula Constants: % P i gment/Wt . : 37.60 % P i gment/Vol . : 17.11 % So l ids /Wt . : 57.21 % S o l i d s / V o l . : 41.18 % PVC: 41.55 VOC, l b s . / g a l . : 1.13 VOC, gms. / l . : 134.92

5.50 6.60 66.00 79.20

Formula P r o p e r t i e s : Dens i ty 1 bs. / g a l . : 11.51 Dens i t y gms. /l. : 1,381.2

KU V isc . @ R.T.: 90-95 pH @ R . T . : 9.0-9.5

SOURCE: Halox Pigments: Suggested Formula t ion MOR-1043-A

Primers 135

Exper imenta l Waterbase A c r y l i c Red I r o n Ox ide Pr imer

G r i n d : Water Methy l Carb i t o 1 Tamol 165 T r i t o n CF-10

Drew L-493

Snowf 1 ake

AMP-95

R . I . O . R0-4097

Lbs. /100 Gals . Gms/L i te r 63.0 75.6 52.0 62 .4 10.0 12.0 3.0 3 . 6 3 .0 3 . 6 1 .o 1 . 2

50.0 60.0 250.0 300.0

0 40.0 Ha lox SZP-391 3 3 .

High speed d i s p e r s e t o 4+ NS g r i n d .

Water 25.

Letdown : Mai n c o t e HG-54 Texanol D i b u t y l P h t h a l a t e Drew L-493 Aqua Ammonia (28%) Raybo 60

510. 4.

12 3 1 5

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un

A c r y s o l RM-1020 Water

M i x u n t i l u n i f o r m .

Formula Constants : % Pigment/Wt.: 31.58 % Pigment /Vol . : 13.81 % S o l i d s / W t . : 52.35 % S o l i d s / V o l . : 38.97 ?6 PVC: 35.41 VOC, l b s . / g a l . : 1.72 VOC. g/L: 206.40

0 30.0

0 612.0 0 9 5 5 0

form.

10.0 26.0

Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 10.63 D e n s i t y g /L: 1,275.9 KU V i s c . B R.T . : 90-95 pH @ R.T.: 8.0-9.0

4 .8 15.5 4.2 1 .8 6 .0

12.0 31.2

SOURCE: Ha lox Pigments: Suggested F o r m u l a t i o n HG54-391


Exper imen ta l Waterbase A c r y l i c

G r i n d : Water Me thy l Carb i t o 1 Tamol 165 T r i t o n CF-10 Drew L-493 Red I r o n Ox ide S n o w f 1 ake Ha lox BW-191

L e t Down: Mai n c o t e HG54 Texanol O i b u t y l P h t h a l a t e Drew L-493 Ammoni um Hydrox i de Sodium N i t r i t e Water Ucar Th ickener SCT

2 8%

200

Red Iron Ox ide P r i m e r

~__ Pounds _____ G a l l o n s 63 .00 7.56 52.00 6 .11 12 .30 1 .26

3 .00 0 .34 1 .oo 0 . 1 4

57.40 1 .34 192.60 8 . 5 6 100.00 4 .21

510.00 60.00 4 .00 0 . 5 0

12 .90 1 .48 3 . 6 0 0.50 1 . 7 0 0 .24 8 . 4 0 1 . 0 1

49 .00 5.90 7 .50 0 . 8 5

D e n s i t y l b s / g a l : 10.78 % W t . S o l i d s : 5 3 . 5 % V o l . S o l i d s : 40.0 % PVC: 3 5 . 0 V i s c o s i t y : 90-95 KU @ 77F

SOURCE: Ha lox P igments : Suggested F o r m u l a t i o n

Primers 137

ExDer imenta l Waterbase A c r y l i c Red I ron Ox ide P r i m e r

G r i n d : Water Me thy l C a r b i t o l Tamol 165 T r i t o n CF-10

Drew L-493

Snowf lake

AMP-95

R . I. 0 . R0-4097

Ha lox CW-491

L b.s Jl_O 0. G31-s .. Gm s / L 1 t_er 6 3 . 0 75 .6 5 2 . 0 6 2 . 4 10 .0 1 2 . 0

3 . 0 3 .6 3 . 0 3 . 6 1 . o 1 . 2

5 0 . 0 6 0 . 0 225.0 270.0

6 6 . 0 7 9 . 2

H i g h speed d i s p e r s e t o 4+ NS g r i n d

Water 2 5 . 0 30 t 0

Letdown : Mai n c o t e HG-54 Texanol D i b u t y l P h t h a l a t e Drew L-493 Aqua Ammonia (28%) Raybo 60

.310.0 6 1 2 . 0 4 . 0 4 . 0

12 9 1 5 . 5 3 . 5 4 . 2 1 . 5 1 . 8 5 . 0 6 .0

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un7 form.

A c r y s o l RM-1020 Water

M ix a n t i i u n i f o r m

Formula Cons tan ts : % Pigment/Wt. : 31 .99 % P igment /Vo l . : 13 .93 % S o l i d s / W t . : 52.62 % S o l i d s / V o l . : 39.05 % PVC: 35.66 VOC, l b s . / g a l : 1 . 7 0 VOC, g /L : 204.00

1 0 . 0 12 .0 26 .0 31 . 2

Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 10.71 D e n s i t y g /L: 1 ,285.1 KU V i s c . @ R .T . : 95-100 pH @ R . T . : 8 . 0 - 9 . 0

SOURCE: Ha lox Pigments: Suggested F o r m u l a t i o n HG54-491


E x t e r i o r House P a i n t Pr imer

I flared> entss: Pigment G r i n d : Water Ucar Polyphobe 102 Rheo. Mod. Ammonium Hydroxide, 28% Aqueous S o l u t i o n Nuosept 95 Col l o i d 226/35 Propylene G lyco l C o l l o i d 640 T r i t o n Nonionic S u r f a c t a n t N-101 Kronos 2310 Halox BW-100 N ic ron 400

Letdown : Water ) Ucar Polyphobe 102 )Premix Ucar Latex 625 C o l l o i d 640 B u t y l Carb i t o 1 Sol vent NuoCi de 404-D T r i t o n Nonionic S u r f a c t a n t CA Ammonium Hydroxide, 28% Aqueous S o l u t i o n

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 32.0 Volume S o l i d s , % : 40.0 Weight S o l i d s , %: 54.5 V i s c o s i t y , e q u i l i b r a t e d :

Stormer, KU: 90 I C I , Po ise: 1.45


F i l m P r o p e r t i e s : Con t ras t R a t i o , 6-mi l wet drawdown: 0.96 Ref 1 ectance, %: 88.3 Sheen, 85: 19.9 Tannin S t a i n Resis tance:

Cedar and Redwood: Very Good

Pounds

150.4 8 .7 1.9 2 . 3

10.2 25 .9

1 . 9 2.1

125.0 100.0 113.5

8 .3 8 . 7

508.6 1 . 9

12.7 10.3 2.1 1 . 9

Gal l o n s

18.05 1 .oo 0.25 0.25 1 . o o 3.00 0.25 0 .25 3.65 4.37 4.78

1 .oo 1 .oo

57.80 0 .25 1.60 1 .oo 0 . 2 5 0.25

SOURCE: U c a r Emulsion Systems: U c a r Latex 625: Fo rmu la t i on Suggest ion E-2456

Primers 139

E x t e r i o r House P a i n t Pr imer Based On Ucar Latex 163

I nqred i e n t s : Pigment Gr ind : Water C e l l o s i z e Hydroxyethy l C e l l u l o s e Nuosept 95 Col 1 o i d 226/35 C o l l o i d 640 T r i t o n Non ion ic S u r f a c t a n t N-101 Propylene G lyco l Tronox CR-828 N ic ron 400 Ta lc Halox EW-100

~~ Pounds Gal l o n s

244.7 29.37 ER-30,000 3.5 0.32

2 . 3 0.25 10.5 I .oo

1 . 9 0 .25 2.1 0.25

25.9 3.00 125.0 3.65 113.5 4.76 100.0 4.37

Letdown : Ucar Latex 163 437.5 49.16 Ucar F i l m e r IET 12.7 1 .60 C o l l o i d 640 1 .9 0.25 NuoCi de 404-D 10.3 1 .oo T r i t o n Nonionic S u r f a c t a n t CA 2 . 1 0.25 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 3.8 0.50

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 32.0 Volume S o l i d s , %: 40.0 Weight S o l i d s , %: 54.0 Weight per Ga l l on , l b : 11.0 Stormer, KU: 86 I C I . po i se : 1 .O pH, i n i t i a l : 8 . 5 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 120F: Pass

F i l m P r o p e r t i e s : Ref lectance, %: 88.3 Sheen, 85: 11.6 Con t ras t R a t i o , 6-mi l ba r : 0.96 Tannin S t a i n Resis tance cedar and redwood: Very Good

SOURCE: Ucar Emulsion Systems: Formulat ion Suggest ion E-2457


General Purpose Latex Maintenance Primer

- Ingredients: Pigment Grind: Water Busperse 39/Dispersant Bubreak 448/Defoamer

!&

105.91 8.47 3.18

(Premix next 2 items)

Water 26.48 QP-15000 Cellosize/Hydroxyethyl Cell ul ose 1.06 Igepal CTA 639/Surfactant 6.35 Aropl az 1271 /Long Oi 1 A1 kyd 40.47 Butrol 23/Modified Barium MetaboratelO5.91 Ti -Pure R-SOO/Ti tani um Dioxide- Rutile 211.83

Mi ca-325/Potassi um A1 umi num Si 1 i cate 26.48 Atomite/Calcium Carbonate 17.71 Nytal 3OO/Talc-Magnesium Silicate 17.71

Let Down: Rhoplex MV23/Acrylic Emulsion 511.57 Texanol/Ester Alcohol 5.30 Ethylene Glycol 31 .77 Water 21 .18

Paint Properties: %wt .__ %VOl Total Vehicle 66.65 87.45 Pi gment 33.35 12.55 Volatile 47.08 64.15 Organic Solvent 8.08 10.71 Non-Volati le 52.92 35.85 Non-Volatile Vehicle 19.56 23.20

Density (lb/U.S. gal): 11.41 Specific Gravity: 1 .37 P.V.C.: 35.00% P/B Ratio: 1.705 Spread I3 1 M i l : 575 F2 Coating VOC: 237 G/L Material VOC: 1 1 1 G/L

Gal

12.71 0.79 0.47

3.18

0.09 0.72 4.82 3.44

6.36 1.13 0.78 0.75

58.13 0.67 3.41 2.54

Wt%

9.28 0.74 0.28

2.32

0.09 0.56 3.55 9.28

18.56 2 . 3 2 1.55 1.55

44.82 0.46 2.78 1 .86

S O U R C E : Buckman Laboratories: Formulation Suggestion: KR-02

Primers 141

General PurposeJL0.w C o s t Water-Base P r i m e r

G r i n d : Water B u t y l C e l l o s o l v e Tamol 165 T r o y s o l LAC

Drew L-493 AMP-95

Lbs./100 G a l s . G m s i l i t e r 150.0 180.0 2 9 . 0 3 4 . 8 1 5 . 0 1 8 . 0

3 . 0 3 . 6 3 . 0 3 . 6 1 . o 1 .2

Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 5 Hegman g r i n d .

Y . I . O . YO-2087 Ha lox CW-491 N y t a l 400

Letdown : Water Mai n c o t e PR-71 D i b u t y l P h t h a l a t e Aqua Ammonia (28%)

Add g r i n d p o r t i o n under a g i t a t i o n and m ix u n t add t h e f o l l o w i n g i n o r d e r l i s t e d :

E thano l 95% Raybo 60

Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t

QR-700 A c r y s o l RM-1020

M ix u n t i l u n i f o r m .

5 0 . 0 60 .0 100.0 1 2 0 . 0 2 5 0 . 0 300 .0

9 3 . 0 111 . 6 380 .0 456.0

5 . 7 6 . 8 3 . 0 3 . 6

1 u n i f o r m . Then

14 .5 1 7 . 4 5 . 0 6 . 0

a e r a t e !

5 . 0 6 . 0 2 . 0 2 . 4

Formula C o n s t a n t s : % P i gment/Wt . : 36.05 % P i g m e n t / V o l . : 16.29 % S o l i d s / W t . : 54 .20 % S o l i d s / V o l . : 31 .35 % PVC: 42.63 VOC, l b s . / g a l . : 1 . 5 4 VOC, g /L: 184.68

Formula P r o p e r t i e s : D e n s i t y 1 b s . / g a l . : 11 .09 D e n s i t y g /L : 1 , 3 3 1 . 0 KU V i s c . @ R . T . : 90-95 p H @ R . T . : 9 . 0 - 9 . 5

SOURCE: Ha lox Pigments: Suggested F o r m u l a t i o n PR-71/491A


H i q h Per formance Bare M e t a l Pr imer

G r i nd : Water B u t y l C e l l o s o l v e Tamol 165 T r o y s o l LAC

Drew L-493 AMP-95

Lbs./100 Gals . Gms/L i te r 92.0 110.0 35.0 42.0 10 .0 1 2 . 0 2 .0 2 . 4 3 . 0 3 . 6 1 .o 1 .2

Add t h e f o l l o w i n g a t h i g h speed and d i s p e r s e t o 5 Hegman g r i n d .

Y . I . O . YO-209 Halox SZP-391 N y t a l 400

Letdown : Water Mai n c o t e PR-7 D i b u t y l Phtha Aqua Ammonia

a t e 28%)

50.0 60.0 50.0 60.0

125.0 150.0

112.0 134.5 470.0 564.0

7 .0 8 . 4 3 .0 3 . 6

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l u n i f o r m . Then add t h e f o l l o w i n g i n o r d e r l i s t e d .

E thano l 95% Raybo 60

18 .0 2 1 . 6 5.0 6 . 0

Add s l o w l y w h i l e m i x i n g a t h i g h speed. Do n o t a e r a t e !

QR-708 A c r y s o l RM-1020

Mix u n t i l u n i f o r m .

Formula Constan ts : % P i gment/Wt. : 22.51 % P i gment/Vol . : 8.76 % S o l i d s / W t . : 47.26 % Sol i ds/Vol . : 35.78 % PVC: 24.48 VOC, l b s . / g a l . : 1.85 VOC, g /L : 222.13

12.0 14 .4 5 . 0 6 .0

Formula P r o p e r t i e s : D e n s i t y Lbs . / g a l . : 10.00 D e n s i t y g /L: 1,199.7 KU V iSc . @ R.T.: 90-95 PH @ R.T.: 9 .0-9.5

SOURCE: Halox Pigments: Suggested F o r m u l a t i o n PR-71/391BM

Primers 143

Hitah Performance Galvanized Metal Primer

Grind: Water Butyl Cellosolve Tamol 165 Troysol LAC AMP-95 Drew L-493

Lbs. /100 Gals. Gms/Liter 9 2 . 0 1 1 0 . 0 35.0 4 2 . 0 1 0 . 0 1 2 . 0 2 . 0 2 . 4 3 . 0 3 . 6 1 . o 1 . 2

Add the following at high speed and disperse to 5 Hegman grind.

Y.I.O. YO-2087 Halox SZP-391 Shi eldex Nytal 400

Letdown : Water Mai ncote PR-71 Dibutyl Phthalate Aqua Ammonia (28%)

50.0 6 0 . 0 5 0 . 0 6 0 . 0 2 5 . 0 3 0 . 0

1 0 0 . 0 120 .0

1 0 6 . 5 1 2 8 . 0 470 .0 564 .0

7 . 0 8 . 4 3 . 0 3 . 6

Add grind portion under agitation and mix until uniform. Then add the following in order listed:

Ethanol 95% Raybo 60

18.0 21 . 6 5.0 6 . 0

Add slowly while mixing at high speed. Do not aerate!

OR-708 Acrysol RM-1020

Mix until uniform.

Formula Constants: % P i gment/Wt . : 2 2 . 6 3 % Pi gment/Vol . : 9 . 3 7 % Solids/Wt.: 47.50 % Solids/Vol.: 36.59 % PVC: 2 5 . 7 5 VOC, lbs./gal.: 1 . 8 3 VOC, g/L: 219.19

1 2 . 0 1 4 . 4 5 . 0 6 . 0

Formula Properties: Density lbs./gal.: 9 . 9 5 Density g/L: 1 , 1 9 3 . 2 KU Visc. @ R.T.: 90-95 pH @ R.T.: 9 . 0 - 9 . 5

SOURCE: Halox Pigments: Suggested Formulation PR-71/391GM


H i g h Per fo rmance 2 K Water-Base Epoxy P r i m e r

Component A : Add t h e f o l l o w i n g i n o r d e r l i s t e d

O i a c e t o n e A l c o h o l Water Nopco NDW

M i x f o r 5 m i n u t e s and add t h e f o l speed.

Eai -Rez 5522-WY-55

R . I . O . R-4098 H a l o x SZP-391 Wol 1 a s t o k u p 1 OES Sparmi t e

Lbs . / l o 0 G a l s . Gms(L1 t e r

450 .0 540 .0 7 .0 8 . 4

1 0 0 . 0 1 2 0 . 0 2 . 0 2 . 4

o w i n g w h i l e m i x i n g a t h i g h

1 0 0 . 0 120 .0 5 0 . 0 6 0 . 0

1 5 0 . 0 180.0 1 0 0 . 0 1 2 0 . 0

H i g h speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . DO NOT AERATE'

Ep i -Rez 5522-WY-55 Water

Component 8 : M i x a t l o w speed: Epi -Cure 8290-Y-60 N a c o r r 1754

3 0 . 0 3 6 . 0 2 5 . 0 30.0

Lbs . / l o 0 Gal s . G m s / L i t e r

6 0 . 0 7 2 . 0 3 . 0 3 . 6

Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m i x i n g a t h i g h speed:

Zeeospheres 400 1 0 0 . 0 120 .0 325 Mesh W.G. M i c a 1 0 . 0 1 2 . 0 H i g h speed d i s p e r s e t o a 4 t Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . DO NOT AERATE! Water 4 0 . 0 4 8 . 0

M i x R a t i o : * Component A : 80% b y vo lume. Component 8 : 20% b y vo lume.

*To o b t a i n opt imum r e s u l t s , a l l o w 20-30 m i n u t e s i n d u c t i o n t i m e p r i o r t o a p p l i c a t i o n .

Fo rmu la C o n s t a n t s : % Pigment /Wt. : 41 .63 % P i g m e n t / V o l . : 1 8 . 7 0 % S o l i d s / W t . : 6 5 . 7 7 % So l i d s / V o l . : 49 .5% % PVC: 3 7 . 7 1 P / B R a t i o : 1 . 7 2 VOC, l b s . / g a l . : 1 .32 VOC, g / L : 1 5 8 . 4 0

Formul a P r o p e r t i es : D e n s i t y l b s . / g a l . : 1 2 . 2 5 D e n s i t y g / L : 1 , 4 7 0 . 0 S e t - t o - t o u c h : 30 m i n u t e s D r y H a r d : O v e r n i g h t

SOURCE: H a l o x P igmen ts : Sugges ted F o r m u l a t i o n Epi -Rez/BBl

Primers 145

Hiah Performance 2K Water-Base EDOXV Pr imer Using Halox SZP-391

Component A: Lbs./lOO Gals . Grams/Li t e r Add t h e f o l l o w i n g i n o r d e r l i s t e d :

Waterpoxy 1401 E k t a s o l v e EP

375.0 450.0 30.0 36.0

M i x f o r 5 minu tes and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h speed.

R . I . O . R-4098 Halox SZP-391 Wol las tokup 10ES N y t a l 400

100.0 75.0

100.0 150.0

120.0 90.0

120.0 180.0

H igh speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e a r a t e !

De ion ized water 240.0 288 * 0

Component 0 : Mix a t low speed.

Waterpoxy 701 E k t a s o l v e EP

Lbs./100 Ga ls . Grams/Li t e r

80.0 5 .0

96.0 6 .0

Mix r a t i o : * Component A - 90% b y volume. Component B - 10% b y volume.

*To o b t a i n optimum r e s u l t s , a l l o w 20-30 minu tes i n d u c t i o n t i m e p r i o r t o a p p l i c a t i o n .

Formula Constan ts : % P i gment/Wt . : 36.75 % Pigment /Vol . : 15.80 % S o l i d s / W t . : 60.10 % Sol i ds/Vol . : 43.96 % PVC: 35.93 P/B R a t i o : 1 .57 VOC, l b s . / g a l . : 1 .57 voc, g/L: 188.40

Formula P r o p e r t i e s : D e n s i t y 1 bs . / g a l . : 11 .56 D e n s i t y g /L: 1,387.2 Set - to - touch: 30 minu tes Dry Hard: Overn igh t

SOURCE: Halox Pigments: Suggested F o r m u l a t i o n


H i g h Per formance 2K Water-Base Epoxy P r i m e r Usinq H a l o x SZP-391

Component A : Lbs./100 Ga ls . Grams/Li t e r A d d t h e f o l l o w i n g i n o r d e r l i s t e d : Epi-Rez 5522-WY-55 450.0 540.0 D i ace tone A l c o h o l 7 .0 8.4 Water 100.0 120 .0 Nopco NDW 2 .0 2.4

Mix f o r 5 m i n u t e s and add t h e f o l l o w i n g w h i l e m i x i n g a t h i g h speed :

R . 1 . O . R-4098 Halox SZP-391 W o l l a s t o k u p lOES Sparmi t e

100.0 50.0

150.0 100.0

120.0 60.0

180 .0 120.0

H i g h speed d i s p e r s e t o 5+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !

E p i -Rez 5522-WY-55 Water

Component 8 : Mix a t l o w speed: € p i -Cure 8290-Y-60

30.0 36.0 25.0 30.0

Lbs. /100 Ga ls . Grams/Li t e r

60.0 72.0 3.6 Nacor r 1754 3 . 0

Add t h e f o l l o w i n g raw m a t e r i a l s i n o r d e r l i s t e d w h i l e m ix h i g h speed:

Zeeospheres 400 100.0 325 Mesh W.G. M ica 10.0

ng a t

20.0 12.0

H i g h speed d i s p e r s e t o 4+ Hegman g r i n d . Then add t h e f o l l o w i n g s l o w l y w h i l e m i x i n g . Do n o t a e r a t e !

Water 40.0 48 .0

M i x R a t i o : * Component A - 80% b y volume. Component B - 20% b y volume.

*To o b t a i n optimum r e s u l t s , a l l o w 20-30 m i n u t e s i n d u c t i o n t i m e p r i o r t o a p p l i c a t i o n .

Formula C o n s t a n t s : Formula P r o p e r t i e s : 96 P i gment/Wt. : 41.63 D e n s i t y l b s . / g a l : 12.25 % Pigment /Vol . : 18.70 D e n s i t y g/L: 1,470.0 % S o l i d s / W t . : 65.77 S e t - t o - t o u c h : 30 m i n u t e s % So l i d s / V o l . 49.58 Dry Hard: Over n i gh t % PVC: 37.71 P/B R a t i o : 1 .72 VOC, l b s . / g a l . : 1 .32 voc, g/L: 158.40 SOURCE: Ha lox Pigments: Suggested F o r m u l a t i o n

Primers 147

H i q h S o l i d s Red I ron Oxide EDOXY Pr imer

M a t e r i a1 : P a r t A: Epon Res in 874-CX-90 B e e t l e 216-8 S h e l l Xy lene S h e l l MIBK PGME A c e t a t e Z i n c Phosphate 5-0852 10 ES Wol las tokup Sparmi t e M i c roMi ca C-3000 Copperas R-5098 H igh Speed D isperse t o a T e x t u r e o f 5-6 N . S Bentone SD-2 P a r t B: Epi-Cure C u r i n g Agent 3140 S h e l l Xy lene She1 1 n-Butanol

Composite B lend: P a r t A P a r t B P a r t s A and B: V i s c o s i t y : 85 K .U .

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l we igh t s o l i d s , p e r c e n t : 81.2 T o t a l v o l ume s o l i d s , p e r c e n t : 65.4 PVC, p e r c e n t : 35 .0 I n d u c t i o n t i m e , minu tes : 30 V o l a t i l e Organ ic Compounds (VOC):

Pounds p e r g a l l o n : 2.43 Grams p e r l i t e r : 292

F i 1 m ProDer t i es :

Pounds

263.0 12.0 75.5 60.4 15 .1

176.5 176.5 233.5

38.8 38.7

9 . 3

132.0 42.9 18.4

1099.3 193.3

Gal l o n s

28.85 1 .41

10.49 9.10 1 . 8 6 6 . 7 4 7 .29 6.35 1.36 0.90

0 . 6 5

16.32 5.95 2.73

75.00 25.00

(Drawdown on CRS. Cured f o r 7 days a t 77F, 55% R.H.) Pigment: b i n d e r r a t i o : 1.72 C u r i n g agent p h r , on s o l i d s : 56 Pot l i f e ( h r s ; f r o m 85-130 KU) : 6 Pounds/gal lon: 12.92 Dry f i l m t h i c k n e s s : 1 .5 m i l s S e t - t o - t o u c h d r y , h r s . : 1 . 0 C o t t o n - f r e e d r y , h r s . : 7 .5 Through-dry, h r s . : 1 8 . 0 P e n c i l hardness: H Impact r e s i s t a n c e , (D i r . /Rev. ) : 52/4 F l e x i b i l i t y : Pass 1 /4" Adhesion: SA S a l t spray t e s t i n g (500 h r s ) : 2F-2M Water r e s i s t a n c e (500 h r s a t 160F): 4M

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1819: Epon Res in 874-CX-Q0/Epi -Cure C u r i n g Agent 31 40


House P a i n t Pr imer

I n g r e d i e n t s : Pigment Gr ind : Water C e l l o s i z e Hydroxyethy l C e l l u l o s e ER-30,000 Nuosept 95 Propylene G lyco l Col 1 o i d 226/35 T r i t o n Non ion ic S u r f a c t a n t N-101 C o l l o i d 650 T i -Pure R-902 325 Mesh White Waterground Mica N y t a l 300

Letdown :

Ucar Latex 624 Ucar F i l m e r IBT NuoCide 404D C o l l o i d 650 Ammonium Hydroxide, 28% Aqueous S o l u t i o n

Pai n t P roper t i es : Pigment Volume Concentrat ion, %: 30.0 Volume So l i ds , %: 32.6 V i s c o s i t y , equi 1 i bra ted :

Stormer, KU: 80 I C I , po i se : 0 .7

Weight per Gal lon, l b : 10.54

Pounds

283.8 3.5 2.3

25.9 6 .4 2.2 1 . 9

150.0 25.0

100.0

426.7 10.7 10.3 2 .0 2.0

Gal 1 ons

34.07 0.32 0.25 3.00 0.62 0.25 0.25 4.50 1.07 4.21

48.49 1.35 1 .oo 0.37 0.25

Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass

F i l m P r o p e r t i e s : Con t ras t R a t i o , 6-mi l wet drawdown: 0.948 R e f 1 ectance, %: 88.7 Sheen, 85: 7 . 0 Flow and Leve l i ng , brushed: Good Wet Adhesion: E x c e l l e n t Chalk Adhesion: E x c e l l e n t

SOURCE: Ucar Emulsion Systems: Ucar Latex 824: Fo rmu la t i on Suggest ion E-2425

Primers 149

Lead

M a t e r i a l : P a r t A: Epi -Rez 5522-WY-55 Res D i acetone A lcoho l Col 1 o i d 640 Defoamer Water R0-4097 Kroma Red Sparmi t e l O E S Wol las tokup Halox SW-111

and Chromate Free Pr imer

n

H igh speed d i spe rse t o a t e x t u r e o f 6-7 N . S .

Epi -Rez 5522-WY-55 Resin 15% Sodium N i t r i t e S o l u t i o n (Water) Water

P a r t B: Epi-Cure 8290-Y-60 Cur ing Agent Water Zeeosphere 400 Water Ground Mica, 325 mesh

H igh speed d i s p e r s e t o a t e x t u r e o f 4-5 N.S.

Composite Blend: V i s c o s i t y P a r t A 114 K .U . P a r t B 101 K.U. P a r t s A and B 106 K.U.

&

330.0 7.0 3 . 5

80.0 100.0 23.1

150.0 100.0

147.0 8 . 0 8 . 7

60.0 11.0

100.0 10.0

957.3 234.7

Gals

37.21 0.89 0.41 9.60 2 .45 0.63 6.19 4.20

16.43 0.95 1 .04

6.80 1 .32 5.00 0.43

80.00 20.00

SOURCE: S h e l l Resins: S t a r t i n g Formula t ion No. 1818


Lead and Chromate Free Red I ron Oxide Pr imer

M a t e r i a l : P a r t A : Epi -Rez 5522-WY-55 Resin Oiacetone A lcoho l Col 1 o i d 640 Defoamer Water R0-4097 Kroma Red Sparmi t e 1 OES Wol 1 astokup Halox SW-111

High speed d i spe rse t o a t e x t u r e o f 5-6 P .C .S

Epi -Rez 5522-WY-55 Resin Water

P a r t 8 : Epi-Cure 8290-Y-60 Cur ing Agent Water Zeeosphere Type 400 Water Ground Mica, 325 mesh

High speed d i spe rse t o a t e x t u r e o f 4-5 P .C .S

Water

Composite B P a r t A P a r t B Pa r t s A and

SOURCE: She

end :

8

V i s c o s i t y 82 K.U.

101 K.U . 85 K . U .

!=,&

330.0 7.0 3 .5

80.0 100.0 100.0 150.0 50.0

147.0 16.6

60.0 11.0

100.0 10.0

53

984 234

1 Resins: S t a r t i n g Fo rmu la t i on No. 180

Gals

37.21 0.89 0.41 9.60 2.45 2.73 6.19 2.10

16.43 1.99

6.80 1.32 5.00 0.43

6.45

80.00 20.00

Primers 151

Lead and Chromate Free Waterborne EPOXY Pr imer

Mater i a1 : Par t A: Epi -Rez 5522-WY-55 Resin D i acetone A1 coho1 C o l l o i d 640 Defoamer Water R0-4097 Kroma Red, Red I r o n Oxide Sparmite Barium S u l f a t e lOES Wol lastokup Halox SW-111 Zeeosphere 400 Water Groumd Mica, 325 Mesh

High speed d isperse t o t e x t u r e o f 5-6 N.S.

€ p i -Rez 5522-WY-55 Resin 15% Aqueous Sodium N i t r i t e S o l u t i o n Water

P a r t 9: Epi-Cure 8292-Y-60 Cur ing Agent Water

Composi t e 81 end : V i scos i t y P a r t A 122 K.U. Par t B (#4 Ford cup,

P a r t s A and B 68 K . U .

Typ ica l Coat ing Proper t ies :

15.1 Seconds)

T o t a l Weight S o l i d s , %: 62.1 T o t a l Volume S o l i d s , %: 46.3 P . V . C . , %: 34.9 I n d u c t i o n Time, minutes: 30 V o l a t i l e Organic Compounds (VOC):

Pounds/Gallon: 1.23 Grams/L i ter : 148

Resin Composition (on s o l i d s ) : Epoxy Resin, %: 07.6 Cur ing Agent, %: 12.4

Pounds

330.0 7.0 3.5

60.0 71.1 71.1

106.7 100.0

71 .1 7.5

147.0 8.0 6.3

60.0 11c.o

989.3

170.0

Gal 1 ons

37.21 0 . 8 9 0.41 7.20 1.74 1 .94 4.40 4.20 3.55 0.32

16.43 0.95 0.76

6.80 13.20

80.00

20.00

SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulat ion No. 1818: Epi-Rez 5522-WY-55 Resin/Epi-Cure 8292-Y-60 Cur ing Agent


Lead Based .Pr imer

Mater1 a1 : P a r t A : 2-Propoxyethanol T r i t o n X - 1 0 0 S u r f a c t a n t Tamol 731 S u r f a c t a n t 9-148 Defoamer Bentone LT, 3% i n w a t e r

B lend w e l l and add: Red I r o n Oxide B a s i c Lead S i l i c o Chromate C e l l t e 499 Diatomaceous E a r t h Maonesi um S i 1 1 c a t e

Pounds

11.6 3 . 5 3.5 4.0

75.0

1 0 0 . 0 100 .0 25.0 25 .0

Gal 1 ons

1 .50 0 . 3 9 0.38 0 .48 8 .95

2 . 3 4 2.93 1 .30 1 .05 -

I n c r e a s e d i s p e r s e r speed t o 3,000 RPM. Achieve g r i n d f i n e n e s s o f 6-7 PCS. Add under reduced a g i t a t i o n : Epi -Rez 3520-WY-55 Res in 260.0 30.00 Tap Water 297.0 35.68

P a r t B: Epi -Cure 8536-MY-60 C u r i n g Agent

Composite B1 end : P a r t A P a r t 8

124.5 1 5 . 0 0

904.6 85.00 124.5 15.00

T y p i c a l C o a t i n g P r o p e r t i e s : V i s c o s i t y : P a r t A : 65 KU

P a r t 8 : 90 KU P a r t s A and 8: 94 KU

Wei g h t / G a l l l o n : I O . 29 A p p l i c a t i o n :

B rush : As i s Spray: Reduce 10 p a r t s p a i n t t o 1 p a r t wa te r t o a v i s c o s i t y

o f 80 Krebs U n i t s P . V . C . , %: 25 .2 V e h i c l e N o n - V o l a t i l e , %: 2 8 . 4 T o t a l Volume S o l i d s , %: 30.2 T o t a l Weight S o l i d s , %: 46.4 Res in Compos i t i on : Epoxy Res in , %: 67

V o l a t i 1 e Compos i t i on : Pounds Gal 1 ons Water 465.0 55.81

C u r i n g Agent, %: 33

O r g a n i c 85.2 11.20 Dry C h a r a c t e r i s t i c s (Room Temperature C u r e ) :

Set t o t o u c h : 30-60 m inu tes Dry t o hand le : 60 m inu tes Dry h a r d : 4 h o u r s Dry t o r e c o a t : 20 h o u r s

SOURCE: S h e l l Chemical Co. : S t a r t i n g F o r m u l a t i o n No. 1809: Epi-Rez 3520-WY-55 Res in /Ep i -Cure 8536-MY-60 C u r i n g Agent

Primers 153

Lead Silico Chromate Pr imer

M a t e r i a l : P a r t A: Epi -Rez 5522-WY-55 Res in D i ace tone A 1 coho1 T r i t o n X-100 S u r f a c t a n t Water C o l l o i d 640 Defoamer RO-4097 Kroma Red, Red I r o n Zeeospheres Type 400 B a s i c Lead S i l i c o Chromate

Oxide

Pebble m i l l a p p r o x i m a t e l y 18 hours

E p i -Rez 5522-WY-55 Res in Water

P a r t 8: Epi -Cure 8290-Y-60 C u r i n g Agent Water Zeeospheres Type 400

H igh speed d i s p e r s e t o a t e x t u r e o f 6 PC

Pounds

200.0 6 . 6 5 .0

84.8 3 .5

104.4 194.6 83.5

266.8 10.2

45.3 35.0

150.0

Water 26.4

Composi t e 81 end : V i s c o s i t y P a r t A 87 K . U . P a r t B 140 K .U . P a r t s A and B 90 K .U .

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 67 .1 T o t a l Volume Sol i d s , %: 5 1 . 4 P.V.C., %: 43.1 V o l a t i l e Organ ic Compounds (VOC):

Pounds/Gal 1 on : 1 .01 Grams/L i te r : 121


Res in Compos i t ion (based on s o l i d s ) : Epoxy Resin, %: 90.0 C u r i n g Agent, %: 1 0 . 0 T o t a l , %: 100.0

Reduct ion f o r Convent iona l Spray (by vo lume): P a r t s A and B: 20 p a r t s Water: 1 p a r t

959.4 256.7

Gal 1 ons

22.35 0 .84 0.56

10.18 0.41 2.45 9.73 2.45

29.81 1.22

5.13 4.20 7.50

3 .17

80.00 20.00

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1813: €pi-Rez 5522-WY-55 Resin/Epi -Cure 8290-Y-60 C u r i n g Agent


Low Sheen Gray Primer

Mater i a1 : Par t A : Epi -Rez 5522-WY-55 Resin Water

Pa r t 8: Epi -Cure 8290-Y-60 Curing Agent Kronos 2020 SP Black 4 Powder Patcote 847 Def

Pa r t A Par t B Par ts A

Typ ica l Tota Tota PVC , Vola

Water

High Speed D

Water

Composite Blend

and B

Coat i nQ

amer

sperse t o 7-8 N.S. Texture.

V i scosi t y 48 K . U . 76 K .U . 62 K .U .

Prooer t i es : Weigh: Sol;ds, %: 51.1 Weight So l ids , %: 39.5

%: 14.2 i l e Organic Compounds (VOC):

Pounds/Gallon: 1 .51 Grams/Li ter : 181

I n d u c t i o n Time, minutes: 30

Pounds

522.1 69.4

82.1 191 .o

0.3 2.0

25.0

126.2

592.5 426.6

Gal 1 ons

58.34 8.33

9.30 5.58 0.02 0.28 3.00

15.15

66.67 33.33

Resin Composition (based on s o l i d s ) : Epoxy Resin, %: 85.0 Cur ing Agent, %: 15.0

Reduction f o r Conventional Spray (by volume): ( V i s c o s i t y = 55 K.U.) Pa r t s A and B : 11 p a r t s Water: 1 p a r t

SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulat ion No. 1812: €pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60

Primers 155

M a t e r i a l : Water I g e p a l CO-630

Tamol 731 Foamaster VL S u r f y n o l 104H D i e t h y l e n e G l y c o l T i t a n o x 2101 Raven 1020 Ha lox BW-191

QP-4400

#on-Lead/Non-Chromate Primer

Monomethyl E t h e r

Lbs. 83.89

2 .54 0.87

10.70 1.10 1.66

35.32 58.50

0.65 148.69

H igh speed Cowles 15-20 minu tes t o a 3-4 Hegman g r i n d . Add le tdown: A r o l o n 820-W-49 540.36

Premix: Dalpad A Water

Premix: Arop laz 1271 C o b a l t Hydrocure I 1 C a l c i um Hydrocem Z i r c o n i um Hydrocem

Then add: S u r f y n o l 104H Skane M-8

Premi x : OR-708 Water

13.24 58.26

37.99 3.79 3.79 1.88

3.31 2.20

0.17 2.26

Gals . 10.06 0.29 0.07 1.23 0.14 0.21 4.14 1.75 0.03 6.27

61.40

1 .43 6 . 9 9

4.54 0.49 0.46 0.22

0.17 0.15

0.02 0 . 2 6

A n a l y s i s : Pigment Volume Concent ra t ion , Percent : 18.85 Pigment /B inder R a t i o : 0.69/1 Percent Sol i d s , Weight : 50.54 Percent S o l i d s , Volume: 34.52 V i s c o s i t y C 25C, KU: 85-89 Gloss (60): F l a t Pounds/Gallon: 10.08

VOC ( e x c l u d i n g w a t e r ) : pH: 8 .7-9.2

Grams/L i te r : 70.8 Pounds/Gallon: 0 .6

SOURCE: Re ichho ld Chemicals, I n c . : A r o l o n 820: Formula 2025-80-1


Primer f o r Factory-Pr i med Hardboard S i d i ng

I n g r e d i e n t s : Pigment Gr ind : Water T e r g i t o l Nonionic Sur fac tan t NP-10 Tamol 731 Foamaster VF T i -Pure R-960 ASP 400

Letdown : Ucar Veh ic le 462 Ucar A c r y l i c 515 Cyme1 325 Foamaster VF Nuocide 960 Arcosolve PP Solvent Propylene Glyco l

Pounds

164.3 6.0

17.6 2.6

96.5 289.4

325.0 118.2 31.3

0.9 5 . 1

31 . 3 35.3

Ga l lons

19.8 0.6 1.9 0 . 3 2.9

13.5

37.0 13.0 3.0 0.1 0 .6 3.0 4.3

P a i n t P r o p e r t i e s : Pigment Volume Concentrat ion, %: 42 C r o s s l i n k e r , p h r : 12 Cosolvent, phr : 15 Volume So l ids , %: 40 Weight per Gal lon, l b : 11.2

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 462: Suggested Formu 1 a t i on

Primers 157

Pr imer 20323D Based on Phosguard J - O m and 10 ES W o l l a s t o c o a t

Henkel ‘ s Waterpoxy 1401 :701 _Sysrem

Component A : Waterpoxy 1401 Ek taso lve EP 10 ES Wol l a s t o c o a t Red I r o n Oxide 5-3106 Phosguard 5-0853

D isperse t o 5 n . s . u . , reduce speed and add:

Methyl Amyl Ketone Water

Component 8 : Waterpoxy 701 Ek taso lve EP

Fo rmu la t i on Constants :

& 452.05

10.44 255.50 137.40 147.89

55 .00 74.60

100.00 10 .40

Non V o l a t i l e by Weight: 0 .70 VOC g r m s / l i t r e : Non V o l a t i l e by Volume: 0 .53 VOC l b s . / g a l . : PVC : 0 .36 Weight /Gal lon Comp A : CPVC : 0.46 Weight /Gal lon Comp 0 : PVC/CPVC : 0.79 M i x i n g R a t i o : Pigment Conten t : 0.44 Weight per Ga l l on : NVV by W t . o f Veh ic le : 0 .47

SOURCE: Nyco M ine ra l s , I n c . : Pr imer 20323D

Gals 49.95

1 .38 10 .56

3.30 5.22

8 .09 8.96

11.17 1.37

236.82 1.98

12.96 8 .80 6.97

12.43

1.58 Water-Based Paint Formulations

Pr imer 203236 Based on Phosguard 5-0813 and 10 ES W o l l a s t o c o a t

Henkel ‘s Waterpoxy 1401 :701 System

Component A : Waterpoxy 1401 E k t a s o l v e EP 10 ES W o l l a s t o c o a t Red I r o n Oxide 5-3106 Phosguard 5-0813


Methy l Amyl Ketone Water

Component B: Waterpoxy 701 E k t a s o l v e EP

F o r m u l a t i o n Constan ts

Lbs 452.05

10.44 255.50 137.40 130.49

55.00 74.60

100.00 10.40

PVC : 0.36 Wei gh t /Ga i CPVC : 0.46 Weight/Gal PVC/CPVC : 0.79 M i x i n g Rat Pigment Conten t ; 0.43 Weight p e r NVV by W t . o f V e h i c l e : 0 . 4 7

Non V o l a t i l e by Weight : 0 .70 VOC g r m s / l i t r e : Non V o l a t i l e by Volume: 0.53 VOC l b s . / g 1 . :

on Comp A : 12.76 on Comp 9: 8.80 0: 6 .97 G a l l o n : 12.26

Gals 49.95

1 . 3 8 10 .56 3 .30 5.22

8.09 8 .96

11.17 1.37

236.82 1.98

SOURCE: Nyco M i n e r a l s , I n c . : Pr imer 203230

Primers 159

Primer 20596F Based on Heucophos ZPZ ~~ and 10 ES Wollasto-

_ _ ~ _ Henkel's - Waterpoxy 1401:701 System

Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wol 1 astocoat Red Iron Oxide 5-3106 Heucophos ZPZ

Disperse to 5 n.s.u., reduce speed and add:


Component 0 : Waterpoxy 701 Ektasolve EP

Formulati on Constants

Lbs &lls 452.05 49 .95

1 0 . 4 4 1 . 3 8 255.50 1 0 . 5 6 137 .40 3 . 3 0 152 .48 5 . 2 2

5 5 . 0 0 8 . 0 9 74 .60 8 . 9 6

100 .00 1 1 . 1 7 10 .40 1 . 3 7

Non Volatile by Weight: 0 . 7 0 VOC grms/litre: 236 .82 Non Volatile by Volume: 0 . 5 3 VOC 1 bs. /gal . : 1 . 9 8 PVC : 0 . 3 6 Weight/Gallon Comp A : 13.01 cpvc: 0 . 5 5 Weight/Gallon Comp 6 : 8 . 8 0 PVC/CPVC : 0 .67 Mixing Ratio: 6 . 9 7 Pigment Content: 0 . 4 4 Weight per Gallon: 12 .48 NVV by Wt. o f Vehicle: 0 . 4 7

SOURCE: Nyco Minerals, Inc.: Primer 20596F


Primer 205966 Based On HeucoDhos ZMP and 10 ES Wol lastocoat

Henkel 's Waterpoxy 1401:701 System

Component A: Waterpoxy 1401 Ektaso lve EP 10 ES Wol lastocoat Red I r o n Oxide 5-3106 Heucophos ZMP

Disperse t o 5 n .s .u . , reduce speed and add:


Component B: Waterpoxy 701 Ektaso lve EP

Formula t ion Constants

& Gals 452.05 49.95 10.44 1 .38

255.50 10.56 137.40 3.30 152.48 5.22

55.00 8.09 74.60 8.96

100.00 11.17 10.40 1.37

Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : 236.82

PVC : 0.36 Weight/Gallon Comp A : 13.01 CPVC: 0.53 Weight/Gallon Comp 8 : 8.80 PVC/CPVC : 0.68 Mix ing Ra t io : 6.97 Pigment Content : 0.44 Weight per Ga l lon : 12.48 NVV by W t . o f Veh ic le : 0.47

SOURCE: Nyco Minera ls , I n c . : Primer 205966

Non V o l a t i l e by Volume: 0.53 VOC l b s . / g a l . : 1.98

Primers 161

Pr imer 21102E Based on Molycoat 212 and 10 AS W o l l a s t o c o a t

H e n k e l ' s Waterpoxy 1401:701 System

Component A: Waterpoxy 1401 E k t a s o l v e EP 10 AS W o l l a s t o c o a t Red I r o n Oxide 5-3106 M o l y w h i t e 212


Methy l Amyl Ketone Water

Component 9: Waterpoxy 701 E k t a s o l v e EP

& 452.05

10.44 255.50 137.40 130.39

55.00 74.60

100.00 10.40

F o r m u l a t i o n Constan ts Non V o l a t i l e b y Weight: 0 .70 VOC g r m s / l i t r e : Non V o l a t i l e bv Volume: 0.53 VOC l b s . / a a l . 3 :

&3& 49.95

1.38 10.56 3.30 5.22

8.09 8 . 9 6

11.17 1.37

236.82 1.98

PVC : 0.36 Weigh t /Ga i lon Comp A: 12.76 CPVC : 0.55 Weigh t /Ga l lon Comp 8: 8 .80 PVC/CPVC : 0.66 M i x i n g R a t i o : 6 .97 Pigment Content : 0 .43 Weight p e r G a l l o n : 12.26 NVV b y W t . of V e h i c l e : 0.47

SOURCE: Nyco M i n e r a l s , I n c . : Pr imer 21102E


Pr imer 21 105H Based on Phosauard 5-0815 and 10 ES W o l l a s t o c o a t

Henke l ' s Waterpoxy 1401:702 System

Component A : Waterpoxy 1401 Ek taso lve EP 10 ES Wol l a s t o c o a t Red I ron Oxide 5-3106 Phosguard 5-081 5

D isperse t o 5 n .s .u . , reduce speed and add:


Component 0: Waterpoxy 702 Ek taso lve EP

Fo rmu la t i on Constants

!& Gals 452.05 49.95

10.44 1.38 255.50 10.56 137.40 3.30 139.19 5.22

55.00 8.09 74.60 8 .96

45.28 5.27 23.41 3.08

Non V o l a t i l e by Weight: 0 .69 VOC g r m s / l i t r e : 237.36 Non V o l a t i l e by Volume: 0.51 VOC l b s . / g a l . : 1 . 9 8 PVC : 0.39 Weight /Gal lon Comp A: 12.86 CPVC : 0 . 5 0 Weight /Gal lon Comp B: 8.23 PVC/CPVC : 0.79 M i x i n g R a t i o : 10.47 Pigment Content : 0.45 Weight per Ga l l on : 12.45 NVV by W t . o f Veh ic le : 0 .44

SOURCE: Nyco M ine ra l s , I n c . : P r i m e r 21105H

Primers 163

Primer 211051 Based On N a l z i n 2 and 10 ES Wol las tocoat

Henkel 's Waterpoxy 1401 :702 System

Component A: Waterpoxy 1401 Ektasolve EP 10 ES Wol l a s t o c o a t Red I r o n Oxide 5-3106 N a l z i n 2

Disperse t o 5 n.s.u. , reduce speed and add:


Component 8 : Waterpoxy 702 Ektaso lve EP

Formula t ion Constants

& 452.05 10.44

255.50 137.40 172.32

55.00 74.60

45.28 23.41

Non V o l a t i l e by Weight: 0.70 VOC g r m s / l i t r e : Non V o l a t i l e by Volume: 0.51 VOC l b s . / g a l . : PVC : 0.39 Weight/Gallon Comp A: CPVC : 0.54 Weight/Gallon Comp 8: PVC/CPVC : 0.73 Mix ing Ra t io : Pigment Content : 0.46 Weight per Ga l lon : NVV by W t . o f Veh ic le : 0.43

SOURCE: Nyco Minera ls , I n c . : Primer 211051

Gals 49.95 1.38 10.56 3.30 5.22

8.09 8.96

5.27 3.08

237.36 1.98 13.23 8.23 10.47 12.80


Pr imer 21109C Based on S t r o n t i u m Chromate and 10 ES Wol las tocoat

Henke l ' s Waterpoxy 1401:702 System

Component A: Waterpoxy 1401 Ek taso lve EP 10 ES Wol las tocoat Red I r o n Oxide 5-3106 S t r o n t i u m Chromate



Component B : Waterpoxy 702 Ek taso lve EP


* L 453.17

10.47 256.20 137.75 166.40

55.10 74.79

68.04 35.18

Non V o l a t i l e bv Weiaht: 0 .69 VOC a r m s / l i t r e :

CPVC : 0 .54 Wei ght/Gal 1 on PVC/CPVC : 0 . 7 0 M i x i n g R a t i o : Pigment Conten t : 0.45 Weight per Ga NVV by W t . o f Veh ic le : 0 .44

50.07 1.38

10.59 3.31 5.27

8.10 8.98

7.91 4.64

250.17 2.09 Non V o l a t i l e b; V o l h e : 0.51 VOC i b s . / g a l . :

PVC : 0 .38 Weigh t /Ga l lon Comp A: 13.16 Comp B: 8.23

6.99 l o n : 12.54

SOURCE: Nyco M ine ra l s , I n c . : Pr imer 21109C

Primers 165

Rapid Dry Waterborne Epoxy Pr imer

M a t e r i a l : P a r t A: E p i -Rez 5522-WY-55 Resin D i acetone A1 coho1 C o l l o i d 640 Defoamer Water R0-4097 Kroma Red, Red I r o n Oxide lOES Wol lastokup Halox SW-111

High Speed Disperse t o a Tex tu re o f 5-6 N.S

Epi -Rez 5522-W-55 Resin E p i -Rez 3540-WY-55 Resin 15% Aqueous s o l u t i o n o f sodium n i t r i t e Water

P a r t B: Epi-Cure 8290-Y-60 Cur ing Agent Water Zeeosphere 400 t y p e Water Ground Mica, 325 Mesh

High Speed Disperse t o a t e x t u r e o f 4-5 N.S

Water G l a c i a l A c e t i c A c i d

Composite Blend: V i s c o s i t y P a r t A 64 K .U . P a r t 0 70 K.U. P a r t s A and B 62 K .U .

T y p i c a l Coa t ing P r o p e r t i e s : T o t a l Weight S o l i d s , %: 59.1 T o t a l Volume S o l i d s , %: 43.8 P.V.C., %: 36.2 I n d u c t i o n Time, minutes: 30 V o l a t i l e Organic Compounds (VOC):

Pounds/Gallon: 1.19 Grams/L i ter : 142.8

Res4 n ComDosi t i on : Epoxy Resin, %: 89.6 C u r i n g Agent, %: 10.4 Reduct ion t o Spray V i s c o s i t y : None r e q u i r e d

Pounds

258.7 5.4 2.7

59.4 77.6

116.6 116.6

114.3 74.1

6.2 79.7

46.7 8 .6

77.0 7.7

78.5 0 .4

911.4 219.7

Gal 1 ons

28.92 0.69 0.32 7.13 1.90 4.81 4.90

12.77 8.24 0.74 9.58

5.29 1.03 3.89 0.33

9 .42 0.04

80.00 20 * 00

SOURCE: S h e l l Chemical Co.: S t a r t i n g Fo rmu la t i on No. 1814: Epi-Rez 5522-WY-55 Resin/Epi-Rez 3540-WY-55 Resin/ Epi-Cure 8290-Y-60 Cur ing Agent


Rapid D r y Waterborne Epoxy Pr imer

M a t e r i a l P a r t A: Epi-Rez 5522-WY-55 Waterborne Resin Epi-Rez 3540-WY-55 Waterborne Resin C o l l o i d 640 Water Bentone LT

High Speed Mix f o r 15 minutes

Water D i acetone A lcoho l R0-4097 Kroma Red, Red I r o n Oxide Halox SW-111 Sparmi t e 325 Mesh Wet Ground Mica 399 Lo-Mi c r o n

High Speed Disperse t o a t e x t u r e of 5-6 N.S.

Pounds Gal 1 ons 205.0 22.78

_ _ _ ~

61.9 6.88 5.0 0.60

140.0 16.81 3.0 0.20

30.0 3.60 7.8 1 .oo

65.5 1.60 93.8 3.94 46.7 1.28 46.9 2.00 85.0 3.78

Epi-Rez 5522-WY-55 Resin 18.8 2.09 15% Aqueous s o l u t i o n o f potassium n i t r i t e 8 .0 0.95 Water 104.0 12.49

M a t e r i a l P a r t 8: Epi -Cure 8292-Y-60 Cur ing Agent Ek taso lve EP Water

27.0 3.08 37.9 5.00 99.3 11.92

Composite Blend: V i s c o s i t y P a r t A 102 K.U. 921.4 80.00 P a r t 8 10 .5 secs (Fo rd #4) 164.2 20.00 P a r t s A and 8 68 K.U.

T y p i c a l Coa t ing P r o p e r t i e s : Resin/Cur ing Agent R a t i o ( s o l i d s b a s i s ) :

Epoxy Resin: 88.1 Cur ing Agent: 11.9

T o t a l weight s o l i d s , %: 47.6 T o t a l volume s o l i d s , %: 33.2 P .V .C . , %: 40.8 I n d u c t i o n t ime, minutes: 30 V o l a t i l e Organic Compounds (VOC):

Pounds/gal 1 on : 1 .95 G r a m s / l i t e r : 234

SOURCE: S h e l l Chemical Co.: S t a r t i n g Fo rmu la t i on No. 1821: Epi-Rez 5522-WY-55 Waterborne Resin/Epi-Rez 3540-WY-55 Waterborne Resin/Epi-Cure 8292-Y-60 Cur ing Agent

Primers 167

Red I n h i b i t i v e Maintenance Pr imer

I n a r e d i en ts : Pigment Gr ind : Water Bentone LT Methyl C a r b i t o l So lvent Tamol 681 Nuosept 95 DeeFo HG-12 T r i t o n Non ion ic S u r f a c t a n t CF-10 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Acryso l RM-2020

Heucophos ZBZ Atomi te

Letdown : Methyl C a r b i t o l So lvent Acryso l SCT-275 Ucar Veh ic le 435 Ucar F i l m e r I B T Troysan Polyphase AF-1 Foamex 825 Sodium N i t r i t e , 15% Aqueous S o l u t i o n Ammonium Hydroxide, 28% Aqueous S o l u t i o n

5-3103

Ad jus t t o minimum pH 8 .7

Pounds

151.5 1 .o

25.5 18.2 2.3 2.1 2 . 2 1.8

17.2 50.0 75.0

145.8

8 . 5 8.6

505.1 11.4

4.9 2.1 9.0 1 .8

Ga l lons

18.19 0.06 3.00 2.00 0.25 0.25 0.25 0.25 2.00 1.20 2.51 6.46

1 .oo 1 .oo

58.06 1.44 0.50 0.25 1.08 0.25

P a i n t P roper t i es : Pigment Volume Concent ra t ion (PVC), %: 30.0 T o t a l So l i ds , %:

by volume: 34.0 pH Value, i n i t i a l : 8 .7 V i s c o s i t y :

Stormer. KU: 80 I C I , po i se : 0 .7

Weight per Ga l lon , l b : 10.4 Freeze-Thaw S t a b i l i t y , 3 cyc les : Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass

SOURCE: Ucar Emulsion Systems: Ucar Veh ic le 435: Formula t ion SugQest ion M-2452


Red I r o n Ox ide C o r r o s i o n R e s i s t a n t EPOXY Pr imer (Two Component System)

Ingredients: - Lb (Prepare P a r t # l & P a r t #2 s e p a r a t e l y )

P a r t #l E p o t u f 37-618/Epoxy Res in Hardener 147.91 X y l o l / X y l e n e 95.36 Ye1 k i ns-TS/Soya L e c i t h i n 3.89 B u t r o l 2 3 / M o d i f i e d Bar ium Meta-

b o r a t e 194.62 Red I r o n Oxide 194.62 N y t a l 300/Talc-Magnesium S i l i c a t e 18.49

P a r t #2: E p o t u f 38-501/Epoxy Res in Methy l I s o b u t y l Ketone X y l o l /Xy lene

272.91 70.06

105.10

M i x two components i n 1 : l r a t i o and w a i t f o r p a i n t a p p l i c a t i o n .

Pigment Vol a t i 1 e Organi c So lvent Non-Vol a t i 1 e N o n - V o l a t i l e Veh

D e n s i t y ( lb /U.S. S p e c i f i c G r a v i t y P.V.C.: 47.19% P/B R a t i o : 1.323

P a i n t P r o p e r t i es : %Wt %vel T o t a l V e h i c l e 63.03 87.92

36.97 12.08 35.09 74.41 35.09 74.41 64.91 25.59

c l e 27.94 13.52

g a l ) : 11.03 1.32

18.96 13.41 13.19 8 .65

0.46 0 .35

6.32 17.65 4.98 17.65 0.78 1.68

30.29 24.74 10.49 6 .35 14.54 9.53

30 minu tes b e f o r e

Spread @ 1 M i l : 411 F2 C o a t i n g VOC: 464 G/L M a t e r i a l VOC: 464 G/L

SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggest ion : KQ-23

Primers 169

Red I r o n Ox ide Pr imer

M a t e r i a l : P a r t A: 2-Propoxyethanol T r i t o n X-100 S u r f a c t a n t Tamol 731 S u r f a c t a n t 91 48 Defoamer Bentone LT, 3% i n water

B lend w e l l and add:

Red I r o n Oxide C e l i t e 499 Diatomaceous E a r t h Magnesi um S i 1 i c a t e

Pounds G a l l o n s

11.6 1.50 3 .5 0.39 3 . 5 0.38 4.0 0 .48

75.0 8.95

~ _ _ _

100.0 2.34 25.0 I .30

100.0 4.22

D i s p e r s e t o a g r i n d f i n e n e s s o f 6-7 P.C.S., t h e n add under a g i t a t i o n :

Epi -Rez 3520-WY-55 Res in Tap Water

P a r t B: Epi -Cure 8536-MY-60 C u r i ng Agent

Composite 81 end : P a r t A P a r t 8

276.0 30.00 295.0 35.44

124.5 15.00

893.6 85.00 124.5 15.00

T y p i c a l C o a t i n g P r o p e r t i e s : V i s c o s i t y : P a r t A: 68 Krebs U n i t s

P a r t B: 90 Krebs U n i t s P a r t s A and B: 98 Krebs u n i t s

Pounds/Gal l o n : 10 .18 A p p l i c a t i o n :

Brush: as i s Spray: Reduce 10 p a r t s p a i n t t o 1 p a r t water t o a v i s c o s i t y

o f 83 Krebs U n i t s P.V.C., %: 25.2 V e h i c l e N o n - V o l a t i l e , %: 29 .2 T o t a l Volume S o l i d s , %: 31 .3 T o t a l Weight S o l i d s , %: 45 .3 Res in Composi t ion: Epoxy Res in , %: 67

Vol a t i 1 e Composi t i on Pounds G a l l o n s Water 467.0 56.14

C u r i n g Agent, %: 33

Organ ics 85.2 11.20 V o l a t i l e Organ ic Compounds (VOC):

Pounds/Gallon: 2.05 G r a m s / L i t e r : 246

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1806: Epi -Rez 3520-WY-55 Resin/Epi -Cure 8536-MY-60 C u r i n g Agent


Red I ron Oxide P r i m e r

I n g r e d i e n t s : - Lb P i Oment O r i nd : Water 117.69 Busperse 39 /D ispersant 5.65 Bubreak 448/Defoamer 2.82 Z i n c S u l fa te -Heptahydra te 1.88 I g e p a l CTA 639/Sur fac tan t 2.82

(Mix 10 minu tes and add) B u t r o l 23/Modi f i ed B a r i um Meta-

b o r a t e 47.08 Red I r o n Oxide 94.15 N y t a l 300/Talc-Magnesi um S i 1 i c a t e 94.15

Le t Down: (Premix a l l t h e f o l l o w i n g i n g r e d i e n t s and t h Beckosol 13-402/Water Reduc ib le A1 kyd 282.46

B u t y l C e l l o s o l v e 84.74 Ammonium Hydroxide-28% 22.60 Water 233.50 Ac t i v - 8 / D r i e r 0 .94

Z i r c o n i urn 6%/Dri e r 5.65 C o b a l t Naphthenate-G%/Drier 1.88

A n t i s k i n n i n g Agent 1.88

P a i n t P r o p e r t i e s : %vel T o t a l V e h i c l e 76.27 91.98 Pigment 23.73 8.02 V o l a t i l e 54.56 68.54 Organ ic S o l v e n t 19.43 26.38 Non-Vo la t i l e 45.44 31.46 N o n - V o l a t i l e V e h i c l e 21.72 23.44

D e n s i t y ( lb /U.S. g a l ) : 10.00 Speci f i c G r a v i t y : 1 .20 P.V.C.: 25.50% P/B R a t i o : 1.093 Spread @ 1 M i l : 505 F2 C o a t i n g VOC: 403 G/L M a t e r i a l VOC: 233 G/L

en

__ Ga 1

14.13 0.53 0.42 0.11 0.32

1.53 2.41 3.97

add t o

32.84 11.28 3.01

28.03 0.12 0.26 0.79 0 .25

Wt%

11.77 0.56 0.28 0 .19 0.28

4.71 9.42 9 .42

t h e g r i n d )

28.25 0 .47 2.26

23.35 0.09 0.19 0 .56 0.19

SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggest ion : KP-10

Primers 171

Red I ron Ox ide Water R e d u c i b l e A l k v d Pr imer

I n q r e d i e n t s : - Lb Pigment G r i n d : Water 154.98 1 Busperse 39 /D ispersant 5.81 Bubreak 448/Oefoamer 2.91 I g e p a l CTA 6 3 9 / S u r f a c t a n t 2.91 Zinc S u l f a t e - H e p t a h y d r a t e 1.94 B u t r o l 2 3 / M o d i f i e d Bar ium Meta-

b o r a t e 48.43 Red I r o n Ox ide 98.86 N y t a l 300/Talc-Magnesium S i l i c a t e 193.72

Gal

18.60 0.54 0.43 0 .33 0.12

1.57 2.48 8.17

Wt%

14.64 0.55 0.27 0 .27 0.18

4.57 9.15

18.30

L e t Down: (Premix a l l t h e f o l l o w i n g i n g r e d i e n t s and t h e n add t o t h e g r i n d . ) C a r g i l l 7464/Water R e d u c i b l e A l k y d 248.93 28.78 23.51 Secondary B u t y l A l c o h o l 86.21 12.81 8.14 Ammonium Hydroxide-28% 9.69 1.29 0.91 Water 200.50 24.07 18.94 C o b a l t Naphthenate-6%/Or ier 1.94 0.26 0.18 Z i r c o n i um 6%/Dri e r 3.87 0.54 0.37

Pai n t P r o p e r t i as: T o t a l V e h i c l e 67. ao 87 .66 Pigment 32.20 12.34 V o l a t i 1 e 49.71 67.42 Organ ic S o l v e n t 16.14 24.74 Non-Vol a t i 1 e 50.29 32.58 N o n - V o l a t i l e V e h i c l e 18.08 20.24

D e n s i t y ( lb /U.S. g a l ) : 10.59 S p e c i f i c G r a v i t y : 1.27 P.V.C.: 37.88% P/B R a t i o : 1.781 Spread I3 1 M i l : 523 F2 C o a t i n g VOC: 357 G/L M a t e r i a l VOC: 205 G/L

SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggest ion: KP-09


Rust Inhibitive Chromate Primer

Material: Water Tamol 731 Triton CF-10 Nopco NDW Ethylene Glycol Dowicil 75 Kelecin 1081

Mix at low speed:

Titanox 2101 Zinc Chromate Y539D Oncor M50 Mica 325 Snowf 1 ake Lampblack #877 QP-4400

Lbs. Gals . 136.0 16.33 16.0 1.85 3.0 0.34 2.0 0.27

26.0 2.80 0.5 0.02 2.0 0.24

200.0 6.01 15.0 0.52 30.0 0.88 33.0 1.41 100.0 4.43 4.0 0.37 1.2 0 :1 1

Grind under high shear 15-20 minutes. NOTE: Do not allow temperature to exceed llOF during grind. Under low speed add letdown:

Nopco NDW 1.5 0.20 Arolon 820-W-49 500.0 57.08 Ammon i a 7.0 0.84 Diethylene Glycol Monobutyl Ether 6.0 0.76 Diethylene Glycol Monobutyl Ether Acetate 6.0 0.73

Prebl end : Aroplaz 1271 or 1272 Triton CF-10 Water

25.7 3.08 1.3 0.15 4.0 0.48

Analysis: Pigment/Binder Ratio: 1.37/1 Pounds/Gallon: 11.33 Percent Nonvolatile, Weight: 58.5 Percent Nonvolatile, Volume: 43.4 Pigment Volume Concentration, Percent: 31 .O pH: 8.8 Viscosity @ 25C, KU: 75-78 60/20 Gloss: Flat Grind Hegman: 4-5 VOC (excluding water):

Grams/Li ter : 1 1 3.0 Pounds/Gallon: 0.94

SOURCE: Reichhold Chemicals, Inc.: Arolon 820: Formula 5-3

Primers 173

S o l v e n t R e s i s t a n t , Water-Reducib le EPOXV Pr imer

M a t e r i a l :. P a r t A: Epi -Rez 5522-W-55 Resin D i acetone A1 coho1 T r i t o n X-100 S u r f a c t a n t Water C o l l o i d 640 Defoamer R0-4097 Kroma Red, Red I r o n Oxide Zeeospheres Type 600

Pebble m i l l a p p r o x i m a t e l y 18 hours

Epi -Rez 5522-WY-55 Resin Water

P a r t 6: Epi-Cure 8290-Y-60 C u r i n g Agent Water

Composite B lend: V i s c o s i t y P a r t A 64 K.U. P a r t 0 58 K . U . P a r t s A t B 85 K .U .

Pounds

200.0 6 . 6 5 .0

84.8 3 . 5

104.4 307.1

187.2 39.5

118.3 55.0

938.1 173.3

Gal 1 ons

22.35 0 .84 0 . 5 6

10.18 0.41 2 . 4 5

17.55

20.92 4 .74

13.40 6.60

80.00 20.00

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Weight S o l i d s , %: 6 2 . 6 T o t a l Volume S o l i d s , %: 49.2 P.V.C., %: 40.7 V o l a t i l e Organ ic Compounds (VOC):

Pounds/Gal 1 on : 1 .37 Grams/Li t e r : 164


Res in Composi t ion (based on s o l i d s ) : Epoxy Resin, %: 75.0 C u r i n g Agent, %: 25.0 T o t a l , %: 100.0

Reduct ion f o r Convent iona l Spray (by volume): P a r t s A and 6: 36 p a r t s Water: 1 p a r t

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1808: Epi-Rez 5522-W-55 Resin/Epi -Cure 8290-Y-60 C u r i n g Agent


TT-P-1975 Federal S D e c i f i c a t i o n Metal Pr imer

I n q r e d i e n t s : Pigment Gr ind : Water C e l l o s i ze Hydroxyethyl C e l l u l ose ER-15M Dispersant ( 1 ) Nonionic Sur fac tan t (2) Ethylene G lyco l B u f f e r (3) Anti foam (4) Preserva t i ve ( 5 ) T i tan ium D iox ide (6) I n h i b i t i v e Pigment (7) Mica (8) Calcium Carbonate (9)

Pounds

266.4 1 . o 15.2 2.7

26.8 2.0 2.4 2.7

133.9 89.2 35.7 46.5

Gal l o n s

32.0 0.1 1.7 0.3 2.9 0.3 0.3 0.3 3.9 2.7 1.5 2.1

Let Down: B u t y l C a r b i t o l Solvent--Premix w i t h : 7.2 0.9 Ucar Thickener SCT-275 8.2 1 .o Ucar Latex 163 423.6 47.6 Anti foam (4) 4.8 0.6 Mildewcide (IO) 5.8 0.6 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 9.0 1.2

Suppl i e r s : (1) Dispersant - C o l l o i d l l l M ( C o l l o i d s ) o r equ iva len t . (2) Nonionic Sur fac tan t - T r i t o n CF-10 (Rohm and Haas) o r

(3) B u f f e r - AMP 95 (Angus) o r equ iva len t . (4) Anti foam - C o l l o i d 770 ( C o l l o i d s ) o r equ iva len t . (5) Preserva t i ve - Nuosept 95 (Huls) o r equ iva len t . (6) Ti tan ium Diox ide - Ti-Pure R-900 (DuPont) o r equ iva len t . (7) I n h i b i t i v e Pigment - N a l z i n 2 (NL Chemicals) o r equ iva len t (8) Mica - 325 WG Mica (KMG Minera ls ) o r e q u i v a l e n t . (9) Calcium Carbonate - Snowflake (Thompson, Weinman) o r

equ iva len t .

equi Val en t . (IO) Mildewcide - Polyphase AF-1 (Troy) o r equ iva len t

Pa in t P roper t i es : Pigment Volume Concent ra t ion (PVC), %: 27.9 T o t a l So l i ds , % by Volume: 36.5

SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulat Suggestion LP-2085

on

Rimers 175

Un ive rsa l Pr imer

I n q r e d i e n t s : P i gment Gr ind : Water Methyl C a r b i t o l So lvent Ammonium Hydroxide, 28% Aqueous S o l u t i o n Tamol 165 Sur f yno l CT-111 Drewpl us L-475 Aerosi 1 R-972 T i -Pure R-900 M i c r o t a l c MP 12-50 Busan 11-MI Water

Letdown : B u t y l C a r b i t o l So lvent Ucar Latex 461

Ucar F i l m e r I B T ) Premix S a n t i c i z e r 160 ) Sodium N i t r i t e ) Premix Water 1 Water Ammoni um Hydroxide, 28% Aqueous Sol u t i on Ucar Polyphobe 102 Rheology M o d i f i e r

Pai n t P r o p e r t i es :

Arcoso lv PNB 1

Pigment Volume Concent ra t ion , %: 22.4 Volume So l i ds , %: 38.0 Weight S o l i d s , %: 49.5 Weight per Ga l lon , l b : 10.2 Stormer, KU: 85 I C I , Poise: 0 .9 pH va lue : 8.5-9.5 Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5 Heat-Age S t a b i l i t y , 120F, weeks passed: 4 VOC, grams per l i t e r : 225

Pounds

51 . 5 50.4

2.0 8.1 4.0 2.0 3.0

121 .o 61 .7 50.0 60.8

21.2 521.2

10.1 10.1 2.3 2.4

20.2 10.7

1.5 5.5

Ga l lons

6.18 5.93 0.26 0.92 0.48 0.27 0.19 3.57 2.74 2.08 7.30

2.66 59.91

1.37 1.27 0.24 0.14 2.42 1.28 0.20 0 .59

F i l m P r o p e r t i e s : Sheen, 85: 5 max Prohesion Cor ros ion Weathering Cycle, hours passed: 800 C leve land Humidi ty, hours passed: 800 Tanning/Stai n i ng Resistance: Good Tape Adhesion (ASTM 0-33): E x c e l l e n t S a l t Fog, hours: 48 max

SOURCE: Ucar Emulsion Systems: Formula t ion Suggestion E-18138


Un ive rsa l Pr imer Non-Li f t i ng and H i g h S a l t Spray Resis tance

I n s r e d i e n t s : Aroplaz 3859-2-80

Calcium Chem-All 8%

Premix:

Red I r o n Oxide 5-3106 Phosguard 5-0806 10 AS Wol lastocoat 399 Ta lc Methyl I s o b u t y l Ketone

Disperse t o 135F and 5 n.s .u.

MPA-1078

To1 uene VM & P Naphtha Aroplaz 3859-2-80 Cobal t Chem-A1 1 12% Z i r c o n i um Chem-All 12% nBu ty l A l coho l Skino #2 PM Acetate

& Gals 245.30 27.72

6.00 0.81 9.00 1.13

100.00 2.40 138.60 5.20 121 .oo 5.00 103.50 4.60 133.30 19.99

13.50 1 .86 68.80 11.24

123.20 13.92 1 .25 0.15 3.75 0.47

25.80 3.82 3.00 0.39

16.53 2.16


Non V o l a t i l e by Weight: 0.69 VOC g r a m s / l i t r e : 410.71 Non V o l a t i l e by Volume: 0.48 VOC l b s . / g a l . : 3.43 PVC : 0.35 Weight pe r Ga l l on : 11.03 CPVC: 0 .45 P i gment Content: 0.42 PVC/CPVC : 0.79

1 . Can be re-coated w i t h powerfu l s o l v e n t - c o n t a i n i n g topcoa ts .

2. Very h i g h s a l t spray r e s i s t a n c e - 3000 hours a t 3 m i l s . 3. Fast d r y i n g i n t h i n f i l m s . 4. Must be f u l l y cured be fo re t o p coated. 5. Ready t o spray w i t h o u t d i l u t i o n . 6. Touch d r y i n approx imate ly 8 minutes.

SOURCE: Nyco M ine ra l s , Inc . : Suggested Fo rmu la t i on

N o n - l i f t i n g epoxies, urethanes, and a l kyds .

Primers 177

Water-Base Acrylic Universa l Primer Us ing Halox SZP-391 & EJW-100

Grind: Lbs./100 Gals. Gms/Liter Add t h e f o l l o w i n g i n o rder l i s t e d w h i l e mix ing a t low speed: Water 125.0 150.0 Nopco NDW 1.5 1.8 Natrosol 250MBR 1 . o 1.2 Aqua Ammonia 28% 1 . o 1.2

Mix f o r 5 minutes then add t h e f o l l o w i n g raw mate r ia l i n o rder l i s t e d :

Ethylene G1 yco l Tamol 681 T r i t o n CF-10 T i -Pure R-902 Zinc Oxide Halox SZP-391 Halox BW-100 Snowf 1 ake

High speed d isperse t o 5+ Hegman g r i n d

Letdown : Rhopl ex MV-23 Texanol Skane M-8 Nopco NDW

30.0 36.0 18.5 27.8 3.0 3.6

150.0 180.0 10.0 12.0 50.0 60.0 50.0 60.0 130.0 156.0

490.0 588.0 8.0 9.6 2.0 2.4 1 . o 1.2

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l uni form. Then s low ly add t h e f o l l o w i n g raw mate r ia l w h i l e mix ing a t h igh speed. Do no t aera te !

OR-708 Thickener 5.5 6.6

Mix u n t i l un i fo rm and add t h e fo l l ow ing :

Water 58.0 70.0

Mix u n t i l uni form.

Formula Constants: % Pigment/Wt. : 34.55 % Pigment/Vol.: 14.76 % Sol ids/Wt. : 54.55 96 Sol i ds/Vol . : 38.71 46 PVC: 38.14 VOC. l b s . / g a l . : 1.14 VOC, g/L: 136.82

Formula Proper t ies : Dens i ty 1 bs. /ga l . : 1 1 .35 Dens i ty g/L: 1 ,367.4 KU V isc . @ R.T.: 90-95 pH @ R . T . : 9.0-9.5

SOURCE: Halox Pigments: Suggested Formulat ion MV-23/391-100


Water-Base A c r y l i c U n i v e r s a l Pr imer Us ing Halox SZP-391 (L X t a i n A

Q r i nd: Lbs./100 Gals Gms/Li ter Add t h e f o l l o w i n g i n o rde r l i s t e d w h i l e m ix ing a t low speed.

Water Nopco NDW Na t roso l 250MBR Aqua Ammonia 28%

125.0 150.0 1.5 1.8 1 .o 1.2 1 . o 1.2

Mix f o r 5 minutes then add t h e f o l l o w i n g raw m a t e r i a l i n o rde r l i s t e d :

Ethy lene G1 yco l Tamol 681 T r i t o n CF-10 T i -Pure R-902 Z inc Oxide Halox SZP-391 Halox X t a i n A Snowf 1 ake

High speed d i spe rse t o 5+ Hegman g r i n d

Letdown : Rhopl ex MV-23 Texanol Skane M-8 Nopco NDW

30.0 36.0 18.5 27.8 3.0 3 . 6

150.0 180.0 10.0 12.0 50.0 60.0

5.0 6 .0 175.0 210.0

490.0 588.0 8 .0 9 . 6 2 .0 2 .4 1 . o 1.2

Add g r i n d p o r t i o n under a g i t a t i o n and mix u n t i l un i fo rm. Then s l o w l y add t h e f o l l o w i n g raw m a t e r i a l w h i l e m i x i n g a t h i g h speed. Do n o t a e r a t e !

QR-708 Thickener 5.5 6 .6

Mix u n t i l u n i f o r m and add t h e f o l l o w i n g :

Water 58.0 70.0

Mix u n t i l un i fo rm.

Formula Constants: % P i gment/Wt . : 34.56 % Pigment/Vol . : 14.81 % So l i ds /Wt . : 54.57 % Soli ds/Vol . : 38.76 % PVC: 38.20 VOC, l b s . / g a l . : 1.14 VOC, g/L: 136.69

Formula P r o p e r t i e s : Dens i t y l b s . / g a l . : 11.35 Dens i t y g/L: 1,367.4 KU V i s c . @ R.T.: 90-95 pH @ R.T.: 9 .0-9.5

SOURCE: Halox Pigments: Fo rmu la t i on MV-23/3BlXA

Primers 179

Waterborne Black Iron Oxide Primer Based on EDotuf 37-143/37-680

(Formula No. 3019-38A)

Component A:

Arcoso lv PTB Dowanol PPH


Epotuf 37-680

BK-5099 Wol lastokup 10 ES

High speed d i spe rse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotuf 37-680 Arcoso lv PTB Tap Water

Lbs 183.82 38.54 10.79

85.85 285.60

214.59 25.73 92.72

Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i 1 un i fo rm: Epotuf 37-143 77.43 M ine ra l S p i r i t s 24.71 Aromat ic 150 24.71 Tap Water 33.32

Weight/Gal lon (Lbs.) : 10.98 Percent S o l i d s (Wt . ) : 55.56 Percent S o l i d s ( V o l . ) : 38.67 PVC ( % I : 35.88 VOC (Lbs . /Ga l l on ) : 2.50

SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-38A

Gals 20.75

5.28 1.23

2.07 11 .80

24.22 3.52

11.13

8.80 3.85 3.35 4.00


Waterborne Red I r o n Oxide Pr imer Based on EDotuf 37-143/37-680

I f o r m u l a No. 2954-76A)

Component A:

Arcosolv PTB Dowanol PPH


R5098 Red I r o n Oxide Wol lastokup 10 ES

High speed d i spe rse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotuf 37-680

Epotuf 37-680 Arcosolv PTB Tap Water

Lbs 172.36 34.47 10.34

87.04 290.42

209.42 24.99

112.88

Component 0 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l un i fo rm: Epotuf 37-143 72.91 M ine ra l S p i r i t s 24.13 Aromat ic 150 24.13 Tap Water 39.07

Weight/Gal lon (Lbs . ) : 11.02 Percent Sol i d s (Wt. ) : 54.89 Percent S o l i d s ( V o l . ) : 37.68 PVC ( % I : 37.25 VOC (Lbs . /Ga l l on ) : 2.46

SOURCE: Reichhold Chemicals, I n c . : Formula No. 2954-76A

Gals 19.45 4.72 1.18

2.03 12.00

23.64 3.42

13.55

8.28 3.76 3.28 4.69

Primers 181

Waterborne Red Oxide Epoxy Pr imer

Ma te r i a1 : P a r t A: Epi -Rez 5522-WY-55 Resin D i acetone A1 coho1 Col 1 o i d 640 Defoamer Water R0-4097 Kroma Red, Red I r o n Oxide Sparmi te Barium S u l f a t e 1OES Wol las tokup Halox SW-111 Zeeosphere 400 Water Ground Mica, 325 Mesh

H igh Speed D isperse t o a T e x t u r e o f 5-6 N .S

€ p i -Rez 5522-WY-55 Resin Water

P a r t 8 : €p i -Cure 8290-Y-60 Cur ing Agent Water

Composi t e 61 end: V i s c o s i t y P a r t A P a r t B P a r t s A and B 70 K.U .

T y p i c a l Coat ing P r o p e r t i e s : T o t a l Weight S o l i d s , %: 62.0 T o t a l Volume S o l i d s , %: 46.2 P . V . C . , %: 35.0 I n d u c t i o n Time, minutes: 30 V o l a t i l e Organic Compounds (VOC):


Resi n Composi t i on : Epoxy Resin, %: 87.6 Cur ing Agent, %: 12.4 T o t a l , %: 100.0

Pounds

330.0 7 .0 3.5

60 .0 71.1 71 . I

106.7 100.0 71 . 1

7.5

147.0 14.2

60.0 110.0

989.2 170 .0

Gal l o n s

37.21 0 . 8 9 0.41 7.20 1 .74 1 . 9 4 4.40 4.20 3 .55 0.32

16.43 1 .71

6 .80 13.20

80.00 20.00

Source: S h e l l Chemical Co.: S t a r t i n g Fo rmu la t i on No. 1810: Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 Cur ing Agent


Waterborne Y e l l o w I r o n Oxide Pr imer Based on EDotuf 37-143/37-680

(Formula No. 3019-396)

Component A :

A r c o s o l v PTB Dowanol PPH


Epotu f 37-680

YD-2288 Wol las tokup 10 ES

H igh speed d i spe rse t o 5 N.S. Add f o l l o w i n g under a g i t a t i o n :

Epotu f 37-680 A r c o s o l v PTB Tap Water

& 183.41 38.45 10.77

69.43 284.95

214.11 25.88 93.71

Component 8 : Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l un i fo rm: Epotu f 37-143 77.25 M ine ra l S p i r i t s 24.55 Aromat ic 150 24.55 Tap Water 33.90

Weight /Gal lon ( L b s . ) : 10.81 Percent Sol i d s (Wt. ) : 54.80 Percent S o l i d s ( V o l . ) : 38.50 PVC ( % ) : 35.89 VOC ( Lbs . /Gal 1 on) : 2.50

SOURCE: Re ichho ld Chemicals. I n c . : Formula No. 3019-398

Gals 20.70

5.72 1.22

2.07 11.77

24.17 3.55

11.25

8 .78 3.82 3.33 4.07

Primers 183

Water Reducible Alkyd Yellow I r o n Oxide Primer Using Halox SZP-391

Grind: Chempol 10-0091 Buty l Cel loso lve DMEA Aqua Ammonia (28%) Y . I .O . YO-2087 Halox SZP-391 Beaverwhi t e 325 Snowf 1 ake Bentone SD-1

Disperse a t h igh speed t o 4+ NS gr ind.

Letdown : Chempol 10-0091 DMEA Aqua Ammonia (28%) Cobalt Hydro-Cure 5% Cal c i um Hydro-Cure 5% Zirconium Hydro-Cure 12% Act ive 8 Byk 301 n-Butanol

Add slowly whi le mixing.

Water

Lbs. /100 Gals. Gms/Liter 200.0 240.0

55.0 66.0 4 . 0 4 . 8 4 . 0 4 . 8

75.0 90.0 33 .0 40 .0 75.0 90 .0 75.0 90 .0

1 .o 1.2

50.0 4 . 0 4 . 0 2 . 0 3 . 5 2 . 0 1 . o 1 . o

25 .0

60 .0 4 . 8 4 . 8 2 . 4 4 . 2 2 . 4 1 . 2 1 . 2

30.0

400.0 480.0

Formula Constants: % P i gment/Wt . : 25.67 % Pigment/Vol . : 10.24 % Solids/Wt.: 44.75 % So l i ds/Vol . : 31.35 % PVC: 32 .65 VOC, lbs . /ga l . : 2 .93 VOC, g/L: 351.68

Formula Propert ies: Density lbs. /ga l . : 10.15 Density g/L: 1,217.8 KU V i sc. @ R.T. : 80-85 pH @ R.T.: 9 .0-9.5

SOURCE: Halox Pigments: Suggested Formulation WRA-301


Water R e d u c i b l e A l k y d Y e l l o w I ron Oxide Pr imer U s i n s Ha lox CW-491

G r i n d : Chempol 10-0091 B u t y l C e l l o s o l v e DMEA Aqua Ammonia (28%)

Halox CW-491 Y.I.O. YO-2087

Beaverwhi t e 325 Snowf 1 ake Bentone SD-1

D i s p e r s e a t h i g h speed t o 4+ NS g r i n d .

Letdown : Chempol 10-0091 DMEA Aqua Ammonia (28%) C o b a l t Hydro-cure 5% Calc ium Hydro-cure 5% Z i r c o n i u m Hydro-cure 12% A c t i v e 8 Byk 301 n-Butanol

Add s l o w l y w h i l e m i x i n g . Water

M i x u n t i l u n i f o r m .

Formula Constan ts : % Pigment/Wt.: 25.67 % P i gment/Vol . : 10.24 % S o l i d s / W t . : 44.75 % Sol i d s / V o l . : 31 .35 % PVC: 32.65 VOC, l b s . / g a l . : 2.93 VOC, g /L: 351.68

Lbs./lOO Gals . Gms/L i ter 200.0 240.0

55.0 66.0 4.0 4.8 4 .0 4 .8

75.0 90.0 33.0 40.0 75.0 90.0 75.0 90.0

1 .0 1.2

50.0 4.0 4 .0 2 .0 3.5 2.0 1 .o 1 . o

25.0

60.0 4.8 4 .8 2.4 4 .2 2 . 4 1 . 2 1 .2

30.0

400.0 480.0

Formula P r o p e r t i e s : D e n s i t y l b s . / g a l . : 10.15 D e n s i t y g /L: 1,217.8 KU V i s c . @ R . T . : 80-85 pH C R.T. : 9 .0-9.5

SOURCE: Ha lox Pigments: Suggested F o r m u l a t i o n WRA-491

Primers I85

Water Reducib le EDoxv-Ester Red I r o n Oxide Pr imer

Gr ind: W/R Epoxy Es te r Resin B u t y l C e l l os01 ve Aqua Ammonia (28%)

Red I r o n Oxide Halox SZP-391 Ta lc

AMP-95

Lbs/100 Gals. Gms/Li ter 340.0 408.0

25.0 30.0 3.0 3 . 6 3.0 3.6

100.0 120.0 42.0 50.4

791 .O 229.2

High speed d i s p e r s e t o 4+ NS G r i n d

Letdown : W/R Epoxy Es te r Resin B u t y l Cel l o s o l ve Aqua Ammonia (28%) Coba l t Hydrocure (13%) Manganese Hydrocure (12%) A c t i v 8 N-Butanol Byk 301

A d d s l o w l y w h i l e m ix ing and mix u n t i l un i fo rm.

125.0 25.0

3.0 2.5 2.5 1 .o

25.0 2.0

150.0 30.0 3 . 6 3.0 3.0 1.2

30.0 2.4

Water 175.0 210.0

Formula Constants: % P i gment/Wt. : 31 .24 % Pigment/Vol . : 12.15 % Sol ids/Wt. : 52.28 % S o l i d s / V o l . : 34.70 % PVC: 34.70 VOC, l b s . / g a l . : 4.13 voc, g/L: 494.87

Formula P r o p e r t i e s : Dens i t y l b s . / g a l . : 10.65 Oensi ty g / l . : 1,278.4 KU V isc . @ R.T.: 80-85 pH @ R . T . : 9.0-9.5

SOURCE: Halox Pigments: Suggested Fo rmu la t i on WREE39lH


Water Reducible Eooxv-Ester Red I r o n Oxide Primer

Grind: W/R Epoxy Es ter Resin Bu ty l Ce l l oso l ve Aqua Ammonia (28%)

Red I r o n Oxide Halox CW-191 Ta lc

AMP-95

Lbs./100 Gals. Gms/Liter 340.0 408.0

25.0 30.0 3.0 3 .6 3.0 3.6

100.0 120.0 42.0 50.0

190.0 228.0

High speed d isperse t o 4+ NS g r ind .

Letdown : W/R Epoxy Es ter Resin Bu ty l Ce l l oso l ve Aqua Ammonia (28%) Cobalt Hydrocure (12%) Manganese Hydrocure (12%) A c t i v e 8 N-Butanol BYK 301

Add s low ly w h i l e mix ing and mix u n t i l uni form.

125.0 150.0 25.0 30.0

3.0 3 .6 2.5 3.0 2.5 3.0 1 . o 1.2

25.0 30.0 2.0 2.4

Water 175.0 210.0

Formula Constants: % P i gment/Wt . : 31 ,55 % P i gment/Vol . : 12.35 % Sol ids/Wt. : 52.54 % So l i ds /Vo l . : 34.90 % PVC: 35.39 VOC, l b s . / g a l . : 4.12 VOC, g/L: 493.60

Formul a P roper t i 8s : Densi ty l b s . / g a l . : 10.64 Densi ty g/L: 1,276.4 KU V isc . @ R.T.: 80-85 p H @ R . T . : 9.0-9.5

SOURCE: Halox Pigments: Suggested Formulat ion WREE491

Primers 187

Water Reduc ib le Epoxy-Ester R e d I ron Oxide Pr imer

Us ing Halox CW-491

Gr ind : W/R Epoxy Es te r Resin B u t y l C e l l o s o l v e Aqua Ammonia (28%)

Red I r o n Oxide Halox CW-491 Ta lc

AMP-95

Lbs. / l o 0 Gals. Gms/Li t e r 340.0 408.0

25.0 30.0 3.0 3 .6 3.0 3 .6

100.0 120.0 42.0 50.0

190.0 228.0

High speed d i spe rse t o 4+ NS g r i n d .

Letdown : W/R Epoxy Es te r Resin B u t y l C e l l o s o l v e Aqua Ammonia (28%) Coba l t Hydrocure (12%) Manganese Hydrocure (12%) A c t i v e 8 N- But ano 1 Byk 301

Add s low ly w h i l e m ix ing and mix u n t i l un i fo rm.

125.0 25.0

3.0 2.5 2.5 1 .o

25.0 2.0

150.0 30.0

3.6 3.0 3 .0 1.2

30.0 2.4

Water 175.0 210.0

Formula Constants: % P i gment/Wt . : 31 .55 % P i gment/Vol . : 12.35 % So l ids /Wt . : 52.54 % S o l i d s / V o l . : 34.90 % PVC: 35.39 VOC, l b s . / g a l . : 4.12 VOC, g/L: 493.60

Formula P r o p e r t i e s : Dens i ty l b s . / g a l . : 10.64 Dens i ty g /L : 1,276.4 KU V isc . @ R . T . : 80-85 pH @ R . T . : 9.0-9.5

SOURCE: Halox Pigments: Suggested Formula t ion WREE491


White. Cor ros ion Res is tan t La tex Pr imer

I nnred i en t s : Pigment G r i nd: Water Busperse 39/Dispersant Bubreak 448/Defoamer Igepa l CTA 639/Surfactant C e l l o s i z e QP-l500O/Hydroxyethyl

Water B u t r o l 23/Modif ied Barium Meta-

T i -Pure R-SOO/Titanium Diox ide-

Atomite/Calcium Carbonate Mica-325 Mesh/Water Ground

Le t Down: Rhopl ex MV-23/Acryl i c Emu1 si on Texanol/Ester Alcohol Ethylene Glyco l Water

Pai n t Proper t i es : To ta l Veh ic le 63.19 Pigment 36.81 V o l a t i l e 44.32 Organic Solvent 4.23 Non-Vo la t i le 55.68 Non-Vo la t i le Veh ic le 18.87

Dens i ty ( lb/U.S g a l ) : 11.61 S p e c i f i c G r a v i t y : 1.39 P . V . C . : 40.65% P/B Rat io : 1.951 Spread @ 1 M i l : 617 F2 Coat ing VOC: 134 G/L M a t e r i a l VOC: 59 G/L

C e l l u l ose

bo ra te

R u t i l e

!& Gal

100.12 12.02 10.01 0.93 3.00 0.44 3.00 0.34

2.00 0.17 25.03 3.00

100.12 3.25

150.19 4.51 150.19 6.65 25.03 1.07

500.62 56.89 7.01 0.89

30.04 3.23 55.07 6.61

%vel 84.36 15.64 61 .52

5.63 38.48 22.84

a 8.62 0.86 0.26 0.26

0.17 2.16

8.62

12.93 12.93 2.16

43.10 0.60 2.59 4.74

SOURCE: Buckman Labora tor ies : Formula t ion Suggestion: KP-08

Primers 189

Whi te I n h i b i t i v e Maintenance Pr imer

I n a r e d i e n t s : Pigment G r i n d : Water Eentone LT Methy l C a r b i t o l S o l v e n t Tamol 681 Nuosept 95 DeeFo HG-12 T r i t o n N o n i o n i c S u r f a c t a n t CF-10 Ammonium Hydrox ide, 28% Aqueous S o l u t i o n A c r y s o l RM-2020 Tronox CR-828 Heucophos ZBZ Atomi t e

Letdown : Methy l C a r b i t o l S o l v e n t A c r y s o l SCT-275 Ucar V e h i c l e 435 Ucar F i l m e r IET Troysan Polyphase AF-1 Foamex 825 Sodium N i t r i t e , 15% Aqueous S o l u t i o n Ammonium Hydrox ide , 28% Aqueous S o l u t i o n

Pounds

151.5 1 . o

25.5 18.2

2 . 3 2.1 2 . 2 1.8

17.2 100.0

50 .0 125.7

8 . 5 8 . 6

505.1 1 1 . 4

4.9 2 . 1 9 . 0 1.8

loris

8.19 0 . 0 6 3.00 2.00 0.25 0 .25 0.25 0 .25 2 .00 2 .93 1 .67 5 .57

1 . o o 1 . o o

58.06 1 . 4 4 0 .50 0 .25 1 .08 0.25

A d j u s t t o minimum p H 8 . 7

Pai n t P r o p e r t i es : Pigment Volume C o n c e n t r a t i o n (PVC) , %: 30 .0 T o t a l S o l i d s , %:

by volume: 34.0 pH Value, i n i t i a l : 8 . 7 V i s c o s i t y :

Stormer, KU: 80 I C I , p o i s e : 0 .8

Weight p e r G a l l o n , l b : 10.5 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass Heat S t a b i l i t y , 2 weeks a t 140F: Pass

SOURCE: Ucar Emuls ion Systems: Ucar V e h i c l e 435: F o r m u l a t i o n Suggest ion M-2451

Sealants and Related Compounds 191

Ancamide 2353 Curina Aaent Aluminum Mas t i c P r e l i m i na ry Formula t ion

Par t A: L i q u i d DGEBA Epoxy MPA-1078 (Rheox) 10 Wollastekup AS (Nyco)

Disperse t o 6 Hegman and 130F:

Epod i l L ( A i r Products) High Flash Naphtha Bee t le 216-8 (Cyanamid) Lansford L243 ( S i 1 b e r l i n e ) Diacetone Alcohol (Union Carbide) Cabosi l TS 720 (Cabot)

Pa r t 8 : Ancamide 2553 ( A i r Products)

- Lb Gal

307 31.7 8 1.0

250 10.3

35 4.0 120 16.5 25 2.8 125 10.2 24 3.0 10 0.4

169 20

Proper t i es : Volume S o l i d s : 71 .9% VOC: t2.5 l b ga l PVC: 20.0% M ix ing Ra t io 4:l by Volume CPVC: 47.1% Pot L i f e , h r 5 PVC/CPVC: 0.426 Dry t o Touch, h r : 3 Weight/gal lon, Pa r t A: 11.29 Dry Through, h r : 7 Weight/gal lon, Pa r t B: 8.45 Wei gh t /ga l l on : 10.73

SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Cur ing Agent: Table 10 Formula


Clear Sealant

I na red i en ts : Ucar Latex 100 T e r g i t o l Nonionic Sur fac tan t NP-4 Nopco NXZ Proxel GXL Ucar F i lmer I B T Cosan 158 Propylene Glyco l Ucar Thickener 146 Ammonium Hydroxide, 28% Aqueous S o l u t i o n Acrysol SCT-275

Weight% 95.15

0.16 0.36 0.24 0.85 0.42 0.85 0.48 0.64 0.85

M i x i ng Procedure: A high-shear, low-speed vacuum mixer o f t h e double-bladed

p lane ta ry t ype o r t h e double-bladed sigma t ype i s recommended. Charge t h e l a t e x t o t h e mixer. Add t h e remaining i n g r e d i e n t s s low ly i n t h e order l i s t e d t o t h e mixer w i t h a g i t a t i o n . The mix w i l l t h i cken when t h e NH40H i s added. S t i r f o r f i v e minutes and then add assoc ia t i ve th i ckener . M ix ing t ime should be >30 m i nutes.

Sealant P roper t i es : Nonvo la t i l es , % by weight: 61.9 pH Value: 8.8 V iscos i t y , B rook f i e ld , P: 24,000 Semco Gunnab i l i t y , g/sec: 28 ASTM C731: Pass Too l i ng Time, min: >5 Boeing Slump, i n : 0 . 0 E longat ion a t Break, %: 1000 Tens i l e Strength, max, p s i : 230 Time f o r 180-mil Bead t o D r y Clear, days: 7 Shore "A" Hardness, 7 days a t 50% R.H.: 48

SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulat ion Suggestion CC-1010


High-Qual i t y E x t e r i o r Latex Caulk

Ing red ien ts : C o l l o i d 677 Propyl ene G1 yco T e r g i t o l Nonion Composi t i on T Potassium Tr ipo Tamol 983 T i -Pure R-900 Ucar Latex 100

San t i c i ze r 160 Organofuntional Camel Carb Snowf 1 ake Camel Cal Minera l Spi r i ts Nuosept 95 Skane M8

Acrysol SCT-275

c Sur fac tan t NP-40

yphosphate (KTPP)

S i lane A-187

Ammoni um Hydroxi de, 14% Aqueous Sol u t i on

Caulk Proper t ies : To ta l So l ids , %:

bv weiaht: 84.7

Pounds 1.8

13.6 5 .5 3.0 0 . 5 0 .9

12.7 418.0

0 .5 109.0

0.6 521.6 172.7 58.2 22.7

1 . 8 2.3

5.5

Gal lons 0.3 1.6 0.6 0.1 0.0 0.1 0.4

46.9 0.1

11.8 0.1

23.0 7 . 7 2.6 3.5 0.2 0.3

0 . 7

Wt% 0.13 1.01 0.40 0.22 0 .04 0.07 0.94

30.94 0.03 8.07 0.05

38.63 12.78 4.31 1.68 0.13 0.17

0.40

- by volume: 74.4

Weight per Gallon, t h e o r e t i c a l , l b : 13.5 V iscos i t y , B rook f i e ld , P:

I n i t i a1 : 2800 A f t e r 5 freeze-thaw cyc les : 2150

Pigment Volume Concentrat ion, %: 45 Boeing Slump: None O F Bend: Pass Shore "A" Hardness, 72F a t 50% R.H. :

1-day: 10 3-day: 33 7-day: 50

i n i t i a l : 9.5 a f t e r 5 freeze-thaw cyc les : 9.0

S t ress-St ra in Proper t ies : 32F - OF t e n s i l e s t rength , max, p s i 54 67 330 e longat ion a t break, % 230 155 87

Semco Gunnab i l i t y , g/sec:

Adhesion P roper t i es : 180 Peel Adhesion*, p l i Subst rate Drv 24-hr. Water Soak G1 ass 20.7 (COH) 15.1 (COH) A1 umi num 21.9 (COH) 13.2 (COH) Concrete 20.5 (COH) 12.7 (AO/COH) Hypal on Sheet 13.8 (COH) 12.9 (COH) * COH=cohesi ve f a i 1 u re

A 0 =adhesive f a i 1 u re

SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulation Suggestion CP-1001

194 Water-Based Paint Formulatiom

Patch ina C o l w u n d (Brushina Grader

I n q r e d i e n t s : P i gment G r i nd : Ucar Latex 163 Wet t ing Agent (1 ) S l u r r y o f :

Water Ammonium Hydroxide, 28% Aqueous S o l u t i o n Ant i foam (2) D ispersant (3 )

P rese rva t i ve ( 4 ) Calcium Carbonate ( 5 ) Mica ( 6 ) T i tan ium Diox ide ( 7 ) M i 1 dewci de (9 )

Le t Down: Coarse S i l i c a (10) Minera l Spi r i t s Ammonium Hydroxide, 28% Aqueous S o l u t i o n Ethylene Glyco l

Suppl i e r s :

*Post Added

Pounds

667.5 1.7 8.3 1 . 5 3.9 3.1 0 . 8

90.0 25.8 65.6

4.5

286.7* 3.4 3.4

17.6

Ga l lons

75.0 0.2 1 .o 0.2 0 . 5 0.3 0 .1 4.0 1.1 2.1 0.3

12.2 0.6 0.5 1.9

Wet t ing Agent - Sur fyno l 104 ( A i r Products) o r equ iva len t . Ant i foam - C o l l o i d 770 ( C o l l o i d s ) o r equ iva len t . Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equ iva len t . P rese rva t i ve - Cosan 101 (Cosan) o r equ iva len t . Calcium Carbonate - Duramite (Thompson, Weinman) o r equ iva len t . Mica - 325 WG Mica (KMG M ine ra l s ) o r equ iva len t . T i tan ium Diox ide - Ti-Pure R-901 (DuPont) o r equ iva len t . S i l i c a - C e l i t e 281 (Johns-Manvi l le) o r equ iva len t . Mi ldewcide - Nopcocide N-96 (Diamond Shamrock) o r equ iva len t . Coarse S i l i c a - Ru f f B u f f (Tammsco) o r equ iva len t .

Pa tch ing Compound P r o p e r t i 8s: Pigment Volume Concent ra t ion (PVC) , %: 31 .7 To ta l So l ids , %:

by Volume: 60.4 by Weight: 71.6

SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulat ion Suggestion V-2084


Patch ins Compound (T rowe l Grade l

I n a r e d i e n t s : Pigment Grind: Ucar Latex 163 Wet t ing Agent (1) S l u r r y o f :

Water Ammonium Hydroxide, 28% Aqueous S o l u t i o n T e r g i t o l Nonionic Sur fac tan t NP-40 Ant i foam (2) Dispersant (3)

Preserva t i ve ( 4 ) Calcium Carbonate (5) Mica (6) Ti tan ium Diox S i l i c a (8) Mildewcide (9

Le t Down: Coarse S i 1 i c a

Pounds

685.3

8.6 1.7 1 .l 1.7 3.5 0.8

219.3

-----

Gal lons

77.0

1 . o 0.2 0.1 0.2 0.3 0.1 9.7

----

25.8 1.1 64.4 2.1 64.6 3.4 5.1 0.3

34.5 1.6 3.4 0.5 Minera l S p i r i ~

A m m o n i t i m Hvdrnxida. 3R% A a t i e n u s S n l u t i n n 3 . 4 0 . 5 . ....... - . . . - ... . . , -. -. . . - - , - - . - . . - - - - - - - - . - - . -. . - . .

Ethylene Glyco l 17.2 1.9

Supp l i e rs : ( 1 ) Wet t ing Agent - Sur fyno l 104 ( A i r Products) o r equ iva len t (2) Anti foam - C o l l o i d 770 ( C o l l o i d s ) o r equ iva len t . (3) Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equ iva len t . (4 ) P rese rva t i ve - Cosan 101 (Cosan) o r equ iva len t . ( 5 ) Calcium Carbonate - Duramite (Thompson, Weinman) o r

(6) Mica - 325 WG Mica (KMG Minera l s ) o r equ iva len t . (7) Ti tan ium D iox ide - Ti-Pure R-901 (DuPont) o r equ iva len t . (8) S i l i c a - C e l i t e 281 (Johns-Manvi l le) o r equ iva len t . (9) Mildewcide - Nopcocide N-96 (Diamond Shamrock) o r

(10) Coarse S i l i c a - Ru f f B u f f (Tammsco) o r equ iva len t .

equ iva len t .

equ iva len t .

Pa tch ing Compound Proper t i es : Pigment Volume Concent ra t ion (PVC), %: 29.7 To ta l So l i ds , %:


SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulat ion Suggestion V-2083

1% Water-Based Paint Formulations

Pi Qlented Caulk Formulat ion based on 2:l V i n y l A c r v l i c / A c r v l i c Blend

Ina red i en ts : Ucar Latex 161 Ucar Latex 163 T r i t o n Nonionic Sur fac tan t X-405 Nopco NXZ Propylene G1 yco l Ammonium Hydroxide, 14% Aqueous So lu t i on Cosan 234 Acrysol SCT-200 S a n t i c i z e r 160 Si lane A-187 Minera l Spi r i t s

Pounds 269.5 127.7 5.0 1.6 12.5 0.4 6.0 0.5 99.8 0.6 20.8

Blend 10 minutes, then add t h e f o l l o w i n g :

Tamol 850 1.2 Composi t i on T 3.3 T i -Pure CR-800 14.0 W i ngdal e White 576.2 Potassium Tr ipolyphosphate (KTPP) 0.5 Microwhi te 25 254.0 Ammonium Hydroxide, 28% Aqueous So lu t i on 0.8

Gal lons 30.12 14.40 0.60 0.20 1.50 0.05 0.70 0.06 10.70 0.07 3.20

0.15 0.40 0.81 25.50 0.02 11.40 0.12

Disperse a t h igh speed u n t i l un i fo rm i n consistency ( t y p i c a l l y

Typ ica l Proper t ies : To ta l So l ids , %:

10-30 minutes) .

by weight: 83.9 by volume: 73.6

Pigment : B i nder Rat io : 3.2: 1 P l a s t i c i z e r on Latex So l i ds , 96: 44.9

SOURCE: Ucar Emulsion Systems: Ucar Latex 161: Formulat ion JDD-995

Sealants and Related CompoundF 197

Premi um-Performance. Medium-F1 e x i b i 1 i t y Caul k

Ina red ien ts : Ucar Latex 163 Sur fac tan t (1) Su r fac tan t (2 ) P l a s t i c i z e r (3 ) Too l i ng Agent (4 ) Ethylene Glyco l Water Cal c i um Carbonate (5 ) T i t a n i u m D iox ide (6 ) Ammonium Hydroxide, 28%

Sol u t i on

Pounds 485.0

6 . 5 8 . 5

93.5 19.0 12.5 32.5

583.0 10.0

0 . 5 Aqueous

Gal lons 54.5

0.7 0 .4

10.1 2.9 1.4 3.9

25.8 0.3

---

K% 38.8

0.5 0 . 7 7.5 1.5 1 .o 2.6

46.6 0.8

---

Suppl i ers : (1) Su r fac tan t - T r i t o n X-405 (Rohm and Haas) o r equ iva len t . (2 ) Su r fac tan t - Composition R (Merck) o r equ iva len t . (3) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r equ iva len t . (4) Too l i ng Agent - Varsol No. 1 (Exxon) o r equ iva len t . ( 5 ) Calcium Carbonate - Atomite (Thompson, Weinman) o r

(6 ) T i tan ium Diox ide - Ti-Pure R-901 (DuPont) o r equ iva len t . equ iva len t .

Seal an t Proper t i es : To ta l So l ids , % by w t : 79.0 Weight per Ga l lon ( t h e o r e t i c a l ) , l b : 12.5 F i l l e r / L a t e x So l i ds Rat io : 2.1/1.0 P l a s t i c i z e r (on t o t a l b inde r s o l i d s ) , % by w t : 26.0 Shore "A" Hardness ( 4 wks a t 73F, 50% RH) : 27 Tens i l e S t rength ( 2 w k s a t 73F, 50% RH), p s i : 13 E longat ion ( 2 wks a t 73F, 50% RH), %: 460 180 Peel Adhesion (per i n ) :

Pinewood: 9 (adhesive) Aluminum: 11 (cohesive) Glass: 12 (cohesive)

Ex t rus ion : Good g u n n a b i l i t y ASTM Shrinkage (28 days a t 73F, 50% RH) Slump a t Room Temperature: None Recovery (25% Extension RT f o r 1/2 h r ) ,

SOURCE: Ucar Emulsion Systems: Ucar Latex Suggestion K-2080

%: <25

%: >80

63: Formulat ion


Sealant A ~ p l i c a t i o n

Inq red ien ts : Ucar Latex 163 Sur fac tan t (1) P l a s t i c i z e r (2 Tool i ng Agent Water Ethvlene Glvco

3)

Calcium carbonate ( 4 ) Extender (5) Sur fac tan t (6 ) T i tan ium Diox ide ( 7 )

Weiqht% 33.00

0 .70 9.00 2.00 1.50 1 .oo

48.00 3.00 1 .oo 0.80

Suppl i e r s : ( 1 ) Sur fac tan t - T r i t o n X-405 (Rohm and Haas) o r equ iva len t . (2) P l a s t i c i z e r - Benzof lex 9-88 ( V e l s i c o l ) o r equ iva len t . (3) Too l i ng Agent - Varsol No. 1 (Exxon) o r equ iva len t . (4) Calcium Carbonate - Atomite (Thompson, Weinman) o r

(5) Extender - Barytes No. 1 (Wi l l iams) o r equ iva len t . (6) Su r fac tan t - Composition T (Merck) o r equ iva len t . ( 7 ) T i tan ium Diox ide - Ti-Pure R-901 (OuPont) o r equ iva len t .

equ iva len t .

Sealant P roper t i es : Nonvo la t i l es , %: 83.3 F i l l e r / L a t e x So l i ds Ra t io : 2.6/1.0 P l a s t i c i z e r t o Latex So l ids , %: 31.2 Weight per Gal lon, l b : 12.5 24-hr Ex t rus ion Rate, g/sec: 3 Shore "A" Hardness, 1 month: 22 Tens i l e Strength, p s i : 8 Elongat ion, %: 158 Accelerated Weathering, XW, Wooden Channel, 1000 h r :

Very good

SOURCE: Ucar Emulsion Systems: Ucar Latex 163: Formulat ion Suggestion K-2079

Sealants and Related Compouna!s 199

Trans lucent Caulk Formula t ion

Ina red ien ts : Lb/100 Gal Ga l lons Ucar Latex 105 758.16 89.09 Ant i foam (1) 0.59 0.08 Ucar F i lmer IBT 6.18 0.87 Ammonium Hydroxide, 28% Aqueous S o l u t i o n 5.88 0.78 Ethylene Glyco l 9.81 1.06 Nonionic Sur fac tan t ( 2 ) 1.96 0.26 Dispersant (3 ) 1.96 0.22 S i l i c a (4 ) 24.52 1.34 P l a s t i c i z e r (5 ) 53.94 5.83 Union Carbide Organofunct ional S i l ane A-187 3.92 0.44 P rese rva t i ve (6 ) 2.94 0.39 T e r g i t o l Nonionic Sur fac tan t NP-10 2.94 0.35

Suppl i e r s : (1 ) Antifoam-Nopco NXZ (Henkel) o r equ iva len t . (2) Nonionic Sur fac tan t - Sur fyno l 104E ( A i r Products) o r

(3 ) Dispersant - Disperse-Ayd W-22 (Dan ie l ) o r equ iva len t . (4 ) S i l i c a - Cab-0-Si1 L-90 (Cabot) o r equ iva len t . ( 5 ) P l a s t i c i z e r - S a n t i c i z e r 160 (Monsanto) o r equ iva len t . (6 ) P rese rva t i ve - Nuosept 95 (Hu ls ) o r equ iva len t .

equi Val en t .

Typ ica l P r o p e r t i 8s: pH Value: 7.2 T o t a l So l i ds , %:

by Weight: 60.2 by Volume: 55.1

B r o o k f i e l d V i s c o s i t y , P: 31,000

Typ ica l Performance Proper t i es : Boei ng S1 ump: Passed Semco Gunnab i l i t y , g/sec: 32

A f t e r 5 Freeze-Thaw Cycles: 11 A f t e r 14-day Heat Aging: 34

7-day d r y : 30 14-day d r y : 30

Shore A:

ASTM C679 Tack: Passed ASTM C794 180 Peel Adhesion, p l i :

Dry Glass: 33.8 Dry Aluminum: 31.3 Wet Glass (7-day immersion): 15.0 Wet Aluminum: 14.0

ASTM C793: Passed

SOURCE: Ucar Emulsion Systems: Ucar Latex Suggestion CT-2002

05: Formu a t i o n


Translucent Caulk Formulation

Ingredients : Ucar Latex 169 Nopco NXZ Ammonium Hydroxide, 28% Aqueous Ethylene G1 ycol Surfynol 104E Daniels WO-22 Cab-0-Si 1 L-90 Sant ic izer 160 Organof unc t i onal S i 1 ane A-1 87 Nuosept 95 T e r g i t o l Nonionic Surfactant NP-

Pounds 758.5 0.6

Sol u t i on 6.3 14.4 2.1 2.1 26.4 58.2 4.2 3.2

,lo 3.2

Typical Proper t i 8s : Total Sol ids, % by weight: 63.5 pH: 7.2 Viscos i ty , Poise: 31,000 Tensi le, ps i , maximum: 64 Elongat ion a t break, %: 990 Water Absorption, %, 7 days: 31.6

Formulation CT-2012

ASTM C-920 Pigmented Caulk Formulation

Ingredients : Sant ic izer 160 Potassi um Tripolyphosphate (KTPP) T r i t o n Nonionic Surfactant X-405 Oaxad 30-30

Pounds 106.1 1.8

13.5

Proxel GXL Cosan 101 Ucar Latex 169 Snowf 1 ake T i -Pure R-902 Mineral S p i r i t s Organofunctional S Ammoni um Hydroxide Methocel 856 Propylene G1 ycol Acrysol ASE-60

1.8 1 . o 1.5

481.1 532.7 12.9 25.1

lane A-187 1.2 28% Aqueous Solut ion 1.3

2.1 14.6 9.3

Gal 1 ons 87.90 0.09 0.84 1.56 0.28 0.24 1.44 6.28 0.47 0.42 0.38

Gallons 11.46 0.08 1.53 0.19 0.13 0.19 55.48 23.65 0.39 3.97 0.14 0.17 0.18 1.68 1.06

Typical Proper t i 8s Total Sol ids, %: Tensile, ps i , maximum: 90

Pigment:Binder: 1.8:l Shore A Hardness: 30

SOURCE: Ucar Emulsion Systems: Ucar Latex 169: Suggested

by weight: 79.5 Elongation a t Break, %: 270 by volume: 70.7 Water Absorption, %, 7 days: 11.3

Formu 1 a t i ono


Trans1 ucent Seal an t

I nq red i en ts : Ucar Latex 100 Nopco NXZ Ucar F i lmer IBT Ammoni um Hydroxi de, 14% Aqueous

Propyl ene G1 yco l Sur fyno l 104 D i sperse-ayd W-22 Cab-0-Si1 LM-130 Organofunctional S i l ane A-187

So 1 u t i on

Pounds 815.50

0.68 7.13

13.53 11.32 2.22 2.29

28.04 3.36

42 28

Nuisept 95 3. T e r g i t o l Nonionic Sur fac tan t NP-10 3

Caulk Proper t ies : To ta l So l ids , % by weight: 61.2 pH Value: 9 .4 Weight per Gallon, t h e o r e t i c a l , l b : V i scos i t y , B rook f i e ld , P: 27,800 Boeing Slump: None Semco Gunnab i l i t y , g/sec:

i n i t i a l : 24 a f t e r 5 freeze-thaw cyc les : 24

g lass: >50 a1 umi num: >50

Hunter Lab Co lor : L: +93.24 a: -0.59

180 Peel Adhesion, Dry, p l i :

b: -0.78

3.5

Gal lons 92.67 0.09 1 .oo

1.71 1.31 0.30 0.26 1.53 0.39 0.36 0.39

Wei qht% 91.47 0.08 0.80

1.52 1.27 0.25 0.25 3.16 0.40 0.40 0.40

Y I E : -0.93 ASTM C732 Weathering-500 Hours: no c rack ing

no d i s c o l o r a t i o n no adhesion loss

SOURCE: Ucar Emulsion Systems: Ucar Latex 100: Formulat ion Suggestion CT-2008

202 Water-Bared Paint Formulatwns

V i n y l Ac rv l i c Seal an t

I n g r ed i en t s :. Ucar Latex 161 Kathon LX (1.5%) ( 1 ) Tamol 850 Ethylene Glyco l S a n t i c i z e r 160 Minera l S p i r i t s Nat roso l 250 MXR Potassi um Tr ipolyphosphate (KTPP) Camel F i l T i -Pure R-902 T r i t o n Nonionic Sur fac tan t X-405 Ammonium Hydroxide, 28% Aqueous S o l u t i o n

Typ ica l P roper t i es : To ta l So l i ds , %:

by we igh t : 82.2 by volume: 78.2

Pigment Volume Concent ra t ion (PVC): 46.9 Pigment:Binder Ra t io : 3:l P l a s t i c i z e r on Latex So l i ds , %: 40.0 Elongat ion a t Break, %: 722.0 Boeing Slump: Pass ASTM C-731: Pass ASTM C-732 Weathering: No bond l o s s ASTM C-734 OF Bend: Pass ASTM C-736 Extension-Recovery: Pass Water Absorpt ion, 7 days, %: 41.9

Pounds 450.0

1.3 1.3

12.4 99.0 20.0 3.0 1 . o

729.4 15.0 9.1 0.5

Gal 1 ons 50.34 0.15 0.14 1.34 10.69 3.07

0.05 32.42 0.45 1 .oo 0.07

0.28

SOURCE: Ucar Emulsion Systems: Ucar Latex 161 : Formulat ion CM-294

Sealants and Related Compowrds 203

Weather-Barrier Mast ic

I na red i en ts : P i gment G r i nd : Water C e l l o s i z e Hydroxyethyl Ce l l u lose D i spersant ( 1 ) Potassium Tr ipolyphosphate E thy l ene G1 yco l Ant i foam (2) T i tan ium Diox ide (3 ) Calcium Carbonate (4) Z inc Oxide (5) M i ldewcide (6 )

Le t Down: Ucar Latex 163 Ucar F i lmer I B T Ant i foam (2)

Pounds

150.0 QP-4400H 4.0

4.0 1 .o

20.0 1.5

62.0 407.0

40.0 5.0

Gal lons

18.0 0.3 0.4

2.2 0.2 1.9

18.1 0.9 0 .5

---

502.0 56.4 6.0 0 . 8 2 . 0 0.3

Suppl i e r s : ( 1 ) Dispersant - C o l l o i d 226/35 ( C o l l o i d s ) o r equ iva len t . (2) Ant i foam - Nopco NXZ (Diamond Shamrock) o r equ iva len t . (3 ) T i tan ium Diox ide - "Ti-Pure" R-960 (DuPont) o r equ iva len t (4) Calcium Carbonate - "Atomite" (Thompson, Weinman) o r

(5) Zinc Oxide - AZO-55 (ASARCO) o r equ iva len t . (6 ) Mi ldewcide - Nopcocide N-96 (Diamond Shamrock) o r equiv-

equi Val en t .

a1 en t . Mast ic P roper t i es :

Pigment Volume Concentrat ion (PVC), %: 40.0 To ta l So l ids , %:


F i l m Proper t ies* : Tensi 1 e Propert i es :

S t r a i n Rate, %: 20 100 200 Stress, p s i : 120 120 200 Elongat ion, %: 420 300 260

200 S t r a i n Rate, in/min: --- --- 70 Stress, p s i : --- ---

800 Elongat ion, %: --- ---

Tens i l e P roper t i es a f t e r 7 days water immersion:

Water Ponding: Water Transmission a t 24 h r : 210 mg water Low-Temperature F l e x i b i l i t y : 180 Bend a t -4F: No c rack ing Water Vapor Transmission Rate f o r 336 h r , perms: 5.7 Adhesion t o Urethane Foam, 180 Peel, l b / i n :

Dry: 7.8 (Foam Cohesion F a i l u r e ) Wet-7 days immersion i n water: 2.2 (Foam Cohesion F a i l u r e ) *Dr ied and cond i t ioned 7 days a t 72F and 50% RH

SOURCE: Ucar Emulsion Systems: Ucar Latex 183: Formulat ion Suggestion WB-2081


Weather-Barrier Mast ic

The f o l l o w i n g fo rmu la t i on has undergone ex tens ive e x t e r i o r exposure and provides improved res i s tance t o d i r t and d a r l y cha l k i ng :

Inq red ien ts : Pi ament O r i nd : Wa:er Dispersant ( 1 ) Potassi um Tr ipolyphosphate Wett ing Agent (2) Ethylene Glyco l Ant i foam (3) T i tan ium Diox ide (4 ) Calcium Carbonate (5) Zinc Oxide (6) M i 1 dewci de (7 ) Water Cel l o s i ze Hydroxyethyl Ce l l u lose QP-15000

Let Down: Ucar Latex 163 Ucar F i lmer I 8 1 Ant i foam (3) Water

Pounds

95.8 8.9 1 .o 1.2

19.3 1.5

112.5 420.3

44.3 2.5

33.3 3.9

496.9 5.8 1.9 2.5

Gal 1 ons

11.5 0.9

0 . 2 2.1 0.2 3.5

18.7 I . o 0.3 4.0 0.3

---

55.8 0 . 8 0.3 0.3

Suppl i ers : (1) Dispersant - C o l l o i d 226/35 (Co l lods) o r equ iva len t . (2 ) Wet t ing Agent - Sur fyno l 104 ( A i r Products) o r equ iva len t . (3 ) Ant i foam - C o l l o i d 643 ( C o l l o i d s ) o r equ iva len t . ( 4 ) T i tan ium Diox ide - Ti-Pure R-960 (DuPont) o r equ iva len t . (5) Calcium Carbonate - Atomite (Thompson, Weinman) o r equiv-

(6 ) Zinc Oxide - XX-503 (NJ Z inc) o r equ iva len t . (7 ) Mi ldewcide - Skane M-8 (Rohm and Haas) o r equ iva len t .

a l e n t .

Mast ic Proper t i 8s : Pigment Volume Concentrat ion (PVC) %: 43.0 To ta l So l i ds , % by Volume: 55.0

SOURCE: Ucar Emulsion Systems: Ucar Latex 183: Formulat ion Suggestion WB-2002


Brown Wiping Stain

Materi a1 : Kelsol 3931-WG4-45 2-Butoxy Ethanol Patcote 531 Red Iron Oxide R-4098 Yellow Iron Oxide 1075A Brown Iron Oxide 444 Syloid 234

Lbs. 261.00 18.00 7.50 7.30 4.50 14.90 25.00

Grind to a 5+ Hegman grind

Kel sol 3931 -WG4-45 402.00

Premix the following, then add under agitation.

2-Butoxy Ethanol Acti v-8 Cobalt Hydrocure I 1 Manganese Hydrocure I 1

Pregel the following, then add under agitation:

4.00 2.40 3.80 6.00

Ammoni um Hydroxi de

Carbopol 941 Water

Pol OX WSR-301 2.20 1.10 1.10

100.00

Analysis: Figment Volume Concentration, Percent: 2.17 Pigment/Binder Concentration, Percent: 0.164 Percent Sol ids, Weight : 42.55 Percent Solids, Volume: 39.29 Pounds/Gallon: 8.59

VOC (excl udi ng water) : Grams/Liter: 229 Pounds/Gallon: 1.91

pH: 8.2-8.6

Gals. 31.45 2.39 1.09 0.17 0.13 0.38 1.50

48.43

0.53 0.30 0.50 0.71

0.29 0.11 0.11 12.00

SOURCE: Reichhold Chemicals, Inc.: Kelsol 3931: Formula 2581-81-A

Stains 207

I n t e r i o r Wiping S t a i n I E n u l s i o n E-2977)

Blend: Water Aurasperse W-1021 Y I O Aurasperse W-3041 R I O Aurasperse W-7012 LB Emu1 s i on E-2977 Sur fyno l DF-37* Propylene Glyco l Ammoni um Hydroxi de (28%) Acrysol ASE-60\1:1 Water/premi x Water Sur fyno l 104DPM

*Surfynol DF-58, 70 and 75

Formulat ion E (Rohm & Haas)

Pounds 150.0 22.5

7.6 3.3

372.0 1.3

39.0 6 .3

64.0 64.0

133.8 4.4

defoamers are v i a b l e a l t e r n a t i v e s .

S t a i n

81 end : Joncry l 95 Ektasolve DB Sur fyno l DF-37 Super Seatone Burn t Umber Nuosept 95

Mix a t 1000 rpm f o r 10-15 minutes. Premix t h e f o l l o w i n g and add w i t h a g i t a t i o n : Letdown : Water Propylene Glyco l Nat roso l 250 HBR Ammon i a Sur fyno l 104DPM

Formulat ion F (S.C.Johnson)

Pounds 293.19

9.00 1.32

100.00 1.50

441 .32 30.24

3.00 1 .oo 8 . 8 0


*Color u n i f o r m i t y o f s t a i n s *Ear ly s t a i n l app ing res i s tance *Consistent wet t ing , f l o w and l e v e l i n g on var ious woods *Foam c o n t r o l

*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion *G1 oss r e t e n t i on upon aging *Tannin b leed res i s tance *Water s e n s i t i v i t y *Chemical res i s tance

Wi th no de t r iman ta l e f f e c t upon:

SOURCE: A i r Products & Chemicals, I n c . : Sur fyno l Sur fac tan ts : Suggested Formulat ions


M a t e r i a1 : Spensol L54 Water D i sperse-Ayd W22 Foamki 11 639AA Mapico 297 BK 5000

L i a h t Redwood Wipina S t a i n

Pebble m i l l g r i n d 16-24 h r s . Then add i n f o l l o w i n g order w i t h a g i t a t i o n :

Letdown : 3% Bentone LT Pregel* Spensol L54 Aro lon 820-W-49 Lodyne S107 QR708B Ammoni um Hydroxi de

*3% Bentone LT Pregel: Water (de ion ized p re fe r red ) Bentone LT High speed d i sperser 15-20 m i nutes.

Analys is : Rat io o f Spensol L54 t o Aro lon 820: 50:50 Pigment Volume Concentrat ion, Percent: 2.6 Pigment/Binder Rat io : 0.15/1 .0 Percent So l ids , Weight: 26.5 Percent So l ids , Volume: 24.3 Percent Vehic le Sol i ds . Weight : 20.8 Percent Vehic le So l ids , Volume: 19.6 Pounds/Gallon: 8.44

VOC (exc lud ing water) : Grams/Li t e r : 72 Pounds/Gallon: 0.60

pH: 8.Ot-0.5

Lbs. Gals. 51.9 5.94 51.8 6.22

0.5 0.06 0 . 8 0.10

24.5 0.60 1.7 0.04

288.0 34.12 254.2 29.12 187.4 21.29

1.7 0.18 17.5 2.10 1.7 0.23

818.9 98.31 25.4 1.69

SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulat ion 2099-81 D

Stains 209

S t a i n Concentrate

Component A: Ma te r i a1 : Kel s o l 3931 -WG4-45 2-Butoxy Ethanol Water Ammoni um Hydroxi de Patco te 531 Mapico 567 Mapico 1075 Atomi t e S y l o i d 234

Pebble o r sand m i l l t o 6+ Hegman g r i n d .

Letdown : Kel s o l 3931-WG4-45 Cobalt Hydrocure I 1 Manganese Hydrocure I1 Ac t i v -8 2-Butoxy Ethanol

Premix t h e nex t t h r e e m a t e r i a l s be fo re adding:

Polyphase AF-1 2-Butoxy Ethanol Aerosol OT-75 M i cheml ube 51 1 Water

Lbs. 207.5

7.5 34.7

1 .9 1 .8

50.0 25.0 50.0 10.0

166.0 1 .9 2.1 0.2 3.8

9 . 8 3.8 2.3

32.0 37.5

Gal s. 25.00

1 .oo 4.17 0.25 0.25 1.16 0 .74 2.22 0.60

20.00 0.25 0.25 0.03 0.50

1 .oo 0.50 0.25 4.00 4.50

Add t h e f o l l o w i n g amount o f water j u s t p r i o r t o use and mix w e l l .

Component 0: Water

Ana lys is : Pigment Volume Concentrat ion, Percent Pigment/Binder R a t i o Percent Sol i ds , Weight Percent So l ids , Volume V i s c o s i t y @ 25C. #4 Ford, Secs. Pounds/Gal 1 on VOC (exc l ud i ng water) :

Grams/Li t e r Pounds/Gal 1 on :

277.6 33.33

Comp. A 18

2.8/1 .O 49.0 39.3

110 9.72

169 1 .4

Comp. A+B 18

0.0/1 .O 34.45 26.2

19 9.26

169 1 .4

NOTE: T h i s t ype o f f o rmu la t i on might be b e n e f i c i a l t o p a i n t manufacturers who s e l l d i r e c t l y t o b u i l d i n g o r p a i n t i n g c o n t r a c t o r s . These s t a i n concent ra tes can be mixed w i t h water a t t h e j o b s i t e .

SOURCE: Reichhold Chemicals, Inc.: Ke lso l 3931: Formula 2210-44


Tannin S t a i n B lock ina Formula t ion

Pigment Grind: Water Bubond 357 Busperse 39 Bubreak 4400 Igepa l CTA 639 Water Cel l o s i ze QP-15000 TiPure R-900 Ny ta l 300

Le t Down: Ucar 376 Texanol Ethylene Glyco l C e l l o s i ze QP-15000 Water

T i n t t o des i red c o l o r

% by Weisht 9.2 1 . 0 0 . 6 0.3 0.3 2.3 0 . 2

18.3 9 .9

39.2 2.0 2.7 0.2

13.8

A c r y l i c Tannin S ta in -B lock inq Pr imer

Mater i a1 : Water Busperse 39 T r i t o n X-100 Bubreak 448 Premix f o l l o w i n g , then add t o above: Water C e l l o s i ze QP-15000 S i f t i n f o l l o w i n g pigments: T i -Pure R-900 Nyta l 300 Busan 11-M1 High speed d isperse t o Hegman 5.0. Reduce speed as shown below: Rhopl ex MV-23 Ac ry l i c Emu1 s i o n Water Texanol Ethylene G1 yco l

% bv Weisaht 8 .6 0 .6 0.3 0 .2

2.2 0 .2

17.4 6.6 2.5

and l e t down

48.1 8 .8 2.0 2.5

SOURCE: Buckman Labora tor ies , I n c . : Suggested Pa in t Formulat ions

Stains 211

Water Reducible Redwood S o l i d Co lor S t a i n

I n c o r p o r a t i o n o f Ag i tan 701 i n t o a water r e d u c i b l e wood s t a i n g r i n d y i e l d s improved g r i n d v i s c o s i t y as w e l l as foam c o n t r o l i n t h e letdown. A d d i t i o n o f t h i s s i l i c o n e t ype FCA has no e f f e c t on r e c o a t a b i l i t y o f t h e topcoat .

Gr ind: McWhorter 73-7358 Red I r o n Oxide Aeros i l R972 (Degussa) FCA (Foam Cont ro l Agent)

& %Wt 70 8.13 50 5.80

2.5 0.29 2.5 0.29

High speed 15 Minutes t o 6 Hegman

Data on Imoroved V i s c o s i t v and Foam Cont ro l w i t h Ao i tan : Test No Ag i tan Gr ind V i s c o s i t y , 25C, Poise 69 Gr ind Weight per Ga l l on (pounds) 10.06

Letdown : Add w h i l e mix ing : McWhorter 73-7358 OK 412 (Degussa Corp.) B u t y l C e l l os01 ve Premix and add: Manganese Hydro Cure I 1 (Mooney) Bu ty l Ce l l oso l ve Polyphase AF-1 (Troy Chemical ) Add f o l l o w i n g w h i l e mix ing : Aqueous Ammonia 28% Deionized Water Aquabead 519 (Mic ro Powders)

P roper t i es : % N o n v o l a t i l e (by we igh t ) : 29.54

(by volume): 25.41 Pigment t o Binder Ra t io : 0.44 Pigment Volume Concentrat ion: 11.92 Weight per Ga l lon (pounds): 8.61 Theore t i ca l VOC (pounds/gal lon): 2.84

Water-Cosolvent Weight Ra t io : 80.68:19.32 pH, 25C: 8.8 V i s c o s i t y , #2 Zahn Cup, 25C (seconds): 33

( g r a m s / l i t e r ) : 341

- Ag i tan 701

58.5 11.11

&

90.0 10.45 25.0 2.90 8 0 . 0 9.29

9.5 1 . l o 24.0 2.79

8 . 0 0.93

11.5 1.33 468.4 54.38

20.2 2.32

SOURCE: K ing I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood Formulat ions

Miscellaneous 213

Anquamine 401 C lea r Coat Semi-Solid EDOXY D ispe rs ion

Par t A: Dow XUS19000.01 Epoxy Resin* Benzyl Alcohol Water

& Gals 346.93 38.70

17.35 1.99 216.83 25.98

Par t 8 : Anquami ne 401 Curing Agent (A i r Products) 177.00 19.37 Water 35.40 4.24 Dowanol PM Solvent (Dow) 35.40 4.66 Benzyl A lcoho l 44.25 5.07

* A l t e r n a t e l y use Epi-Rez 3515 a t same load ing

Typ ica l P roper t i es : W t s o l i d s (%) : 57.45 VOC s o l i d s ( % I : 52.43 VOC ( l b / g a l ) : 1.05 VOC ( g / l ) : 126

Anauamine 401 C lear Coat ProDer t ies : Pot L i f e , h r : >4 Gloss, 60 spec, 1 day: 100 Gloss, 60 spec, 8 wk: >90 Mix Ra t io : 2 : l Mixed V i s c o s i t y , cP: 320 Tack Free Time, h r : 1.0 Hard Dry Time, h r : 6-8 Penci 1 Hardness, ove rn igh t VOC, l b / g a l : 1 .1 Volume So l ids , %: 56

SOURCE: A i r Products and Chem Agent: Formula t ion 5

F

ca l s , I n c . : Anquamine 401 Cur ing


Anquamine 401 Clear Coat S o l i d EDOXV Dispers ion

Par t A: €pi-Rez 3520 Water

Par t 8: Anquami ne 401 Water Defoamer PnP Solvent Typ ica l Proper t i es :

W t S o l i d s ( % ) : 70.0 Volume S o l i d s ( % ) : 41.35 VOC ( l b / g a l ) : 1.13 VOC ( g / l ) : 136

Pot L i f e , h r : >5 Gloss, 60 spec, 1 day: 100 Gloss, 60 spec, 8 wk: >SO Mix Ra t io : 4:l Mixed V i s c o s i t y , CP: 390 Tack Free Time, h r : 0.5 Hard Dry Time: 6-8 Penc i l Hardness, ove rn igh t : F VOC, l b / g a l : 1 . 1 Volume So l i ds , %: 42

Anquami ne 401 C1 ear Coat Proper t i es :

Anquami ne 401 L i q u i d EDOXV Clear Coat

Pa r t A : DER 331 Epoxy Resin (Dow) Benzyl Alcohol

& 621.68 89.20

79.06 61.59 4.25

24.85

Lbs 411 .SO 65.04

Par t B: Anquami ne 401 Curing Agent (A i r Products) 270.98 Water 169.91

Letdown : Water 416.50 Typ ica l P roper t i es :

W t S o l i d s (%): 47.5 VOC ( l b / g a l ) : 0.47 Volume S o l i d s ( % I : 44.2 VOC ( g / l ) : 56 Resin S to ich iomet ry : 1.6:l

Gloss, 60 specu lar : >90 Hard Dry: Overnight Pot l i f e , h r : 1 VOC l b / g a l : 0.47 Set t o Touch, h r : 3

L i q u i d Epoxy C1 ear Coat Proper t i 8s :

69.30 10.69

8.74 7.38 0.53 3.36

Gals 42.54 7.46

29.65 20.36

50.00

SOURCE: A i r Products and Chemicals, I n c . : Anquamine 401 Cur ing Agent: Formulat ions 8 & 7

Miscellaneous 215

Aaueous Pol yester-Urethane P i qment D i spe rs i on

K-Flex XM-2311 and K-Flex XM-4310 a re bo th exper imental a l i p h a t i c po lyes ter -u re thane aqueous d i spe rs ions recommended fo r thermoset water-borne coa t ings . K-Flex XM-2311 prov ides excel 1 en t p i gment w e t t i ng p r o p e r t i e s . K-F1 ex XM-4310 has a 1 ower a c i d number, h igher hydroxyl number and i s recommended as a mod i fy ing r e s i n f o r thermoset water-borne a c r y l i c s , po l yes te rs , a lkyds o r urethanes o r p r imary r e s i n f o r c r o s s l i n k i n g w i t h ami nopl a s t r e s i ns. Gr ind : (Cowles) Gr ind t o 8 N .S . Hegman Gauge: Component: % by Weight K-F1 ex XM-2311 10.00 Water 0.70 T i -Pure R-900 23.85 Letdown : K-F1 ex XM-4310 43.89 HMMM 7 .45 S i l i c o n e A (25%)* 0.18 S i l i c o n e B (25%)** 0.18 Water 9.45 Nacure 2547 0.30 Dimethylethanolamine 1.43 Water 2.57 Charac ter i s t i cs :

XM-2311/XM-4310/HMMM: 14/61/25 To ta l So l ids , %: 54.54 Theore t i ca l VOC, g / l : 32.2 Pigment/Binder Ra t io : 0.8/1 .O pH Value ( A s i s ) : 8.45 V i s c o s i t y , cps***: 200 * * *Brook f ie ld , Sp ind le #16, 60 RPM

Subst ra te : I r o n Phosphated Cold Ro l l ed S tee l Cure: 15 Minutes/ l49C (300F) Dry F i l m Thickness: 20-25 microns (0 .8 -1 .0 m i l s )

Penc i l Hardness: 2H Knoop Hardness, 259: 4 .4 MEK Double Rubs: 200+ Impact Resistance ( i n . l b s . ) : D i r e c t : 160+

60 Gloss, %: 94.10 Cleveland Humidi ty Resistance (325 Hours): 60 Gloss,%: 90.54 Taber Abrasion Index (CS 17, 5009): 274

F i l m P roper t i es :

Proper t i es :

Reverse: 160+

Formula t ion Notes: 1. S lowly add n e u t r a l i z i n g amine (10% i n H20) under good a g i t a -

t i o n t o g r i n d and/or f i n a l f o rmu la t i ons f o r pH and v i s c o s i t y adjustment.

2. Cosolvent i s no t recommended f o r v i s c o s i t y adjustment. 3 . C a t a l y s t l e v e l recommendation range: 0.1-0.25% a c t i v e p-TSA

5 . Immediate letdown o f g r i n d i s recommended.


on t o t a l r e s i n s o l i d s . 4. Recommended pH i s 7.5-8.0.

* S i l w e t L-7604 * * S i l w e t L-7605


Black Gloss Enanel

Mater i a1 : Spensol L52 Aerosol OT-75 Sur fyno l 104H Ammoni um Hydroxi de Regal 330 Carbon Black

Lbs. Gals. 175.4 20.00

2.3 0.25 2.0 0.25 1.9 0.25

15.0 1 .oo

Add t h e above ma te r ia l s i n t h e order l i s t e d under good a g i t a t i o n , then pebble m i l l g r i n d t o 7 N.S.

Letdown : Spensol L52

Add t h e f o l use and mix

XAMA- 7

Anal y s i s :

owing c ross w e l l .

i n k i n g agent op t i ona

679.7 77.50

) j u s t p r i o r t o

7.4

P;gment Volume Concentrat ion, Percent: 3.5 Pigment/Binder Rat io : 0.6/1 . O Percent So l ids , Weight: 31.9 Percent So l ids , Volume: 28.4 V i s c o s i t y @ 25C, #4 Ford, Secs.: 25-30 Pounds/Gal 1 on : 8.82

VOC (exc lud ing water ) : Grams/Liter: 275 Pounds/Gallon: 2.3

pH: 8.5t-0.3

Formulat ion 21 54-1 0

Clear B a r r i e r / T i e Coat f o r V i n y l

Ma te r ia l : Arolon 840-W-39 Water Carbi t o 1 Ammoni um Hydroxi de Spensol L54 Aerosol OT-75 Add t h e above m a t e r i a l s i n

Lbs. 599.2 33.3 35.0

1.9 194.8

2.9 o rder under good a g i t a t i o n .

0.75

Gal s. 68.87

4.00 4.25 0.25

22.31 0.32

Ana lys is : Percent So l ids , Weight: 33.9 Percent So l ids , Volume: 31.2 V i s c o s i t y I3 25C, #2 Zahn. Secs.: 20-25

VOC (exc lud ing water) : Grams/Liter: 209 Pounds/Gallon: 8.7 PH: 8.5-9.0

Pounds/Gallon: 1.7 Formulat ion 2262-831)

SOURCE: Reichhold Chemicals, I n c . : Sponsol L: Formulat ions

Miscellaneous 21 7

Clear T i n t Base

M a t e r i a l : Kel s o l 3931 -WG4-45 Strodex P-1 00 I n t e r c i de T-0

Lbs. Gals. 370.0 44.52

1.6 0.19 4 .2 0.43

Premix t h e nex t t h r e e m a t e r i a l s i n o rder , then add under good a g i t a t i o n :

Act i v-8 Cobalt Hydrocure I1 Manganese Hydrocure

Add t h e f o l l o w i n g i n o rde r :

Pol ymekon SPP-W Polyphase AFl Water Ammoni um Hydroxi de

Ana lys is : Percent So l i ds , Weight: 23.3

2.1 0.36 1.3 0.17 5 . 0 0.66

33.3 4.16 8.4 0 . 8 1

405.9 48.73 0 . 5 0.07

Percent S o l i d s ] Volume: 21.6 (approx)

V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25 VOC (exc lud ing water ) :

Grams/Li t e r : 185 Pounds/Gal 1 on : 1 .54

pH: 8.2-8.6

SOURCE: Reichhold Chemicals, I n c . : Ke lso l 3931: Formula 2099-32


FCA’s f o r Waterborne B u i l d i n g Product Formula t ions C lear Waterborne Cement Sealer

Mater i a1 : Rhoplex AC-3001 (Rohm and Haas) FCA (Foam Cont ro l Agent) B u t y l Ce l l oso l ve Sur fyno l 104E ( A i r Products)

Proper t i es : % N o n v o l a t i l e (by we igh t ) : 45.78 V i s c o s i t y , CPS: 150+-10% pH: 7.7-8.7

Waterborne B lack Topcoat

Gr ind : Water Nat roso l 250MR (Hercules) Ammoni a (28%) Tamol 731-25 (Rohm and Haas) FCA (Foam Cont ro l Agent) Bay fer rox 318M ( M i l e s ) WG-325 Mica (KMG Mine ra l s ) Gr ind a t h i g h speed f o r 15 minutes

Letdown : Rhoplex AC-3001 (Rohm and Haas) Bu ty l Ce l l oso l ve Sur fyno l 104H ( A i r Products) Water

P roper t i es : % N o n v o l a t i l e (by we igh t ) : 50.0

(by volume): 37.9 pH, 25C: approx. 9.0 V i s c o s i t y , #4 Ford cup, 25C, seconds: 18 Coalescent, % on polymer s o l i d s : 15 T h e r e t i c a l VOC ( g r a m s / l i t e r ) : 119.8

(pounds/gal lon): 1.0

& 761.68 0.88

36.40 1.04

& 121.8

1 .1 0 . 5

12.1 3.8

174.5 48.3

605.1 43.6

3.2 13.7

95.21 0.11 4.55 0.13

11.85 0.11 0.05 1.18 0.37

16.98 4.70

58.88 4.24 0.31 1.33

Resu l ts demonstrate the v e r s a t i l i t y o f Ag i tan 260 as a p e r s i s t e n t foam c o n t r o l agent and i t s a b i l i t y t o improve c o l o r ( represented by t h e L Value and ye l l ow index) and prevent pigment f l o a t .


Miscellaneous 219

E x t e r i o r / I n t e r i s r B l o c k F i l l e r

I n q r e d i e n t s : Pigment G r i nd: Water Potass i um Tr ipo l yphospha te (KTPP) Drewplus L-475 Tamol 731 Propylene G1 y c o l T r i t o n Nonionic S u r f a c t a n t N-101 Kathon LX T i -Pure R-900 ASP 400 325 Mesh White Waterground Mica Minex 4 Snowf 1 ake Ammonium Hydroxide, 28% Aqueous S o l u t i o n Water NeoCar Latex 2300 Ucar F i l m e r IBT Water 1 C e l l o s i z e Hydroxyethy l C e l l u l o s e )Premix

ER-15,000 1

Pounds

240.0 2.0 3.0

10.0 20.0 3.0 1 .5

40.0 150.0 50.0

100.0 400.0

2.0 25.0

230.0 15.0 22.0

4 . 0

Gal 1 ons

28.80 0.09 0.39 1.09 2.31 0.34 0.18 1.20 6.97 2.12 4.61

17.76 0.26 3.00

25.99 1 .89 2.63

0.35

P a i n t P r o p e r t i e s : PVC. %: 70.6 Volume S o l i d s , %: 47.2 Weight S o l i d s , %: 67.0 Weight pe r Gal on, l b : 13.17 Stormer, KU: 115 I C I , p o i s e : 1.55 pH Value: 9.2 Freeze-Thaw S t a b i l i t y , 3 c y c l e s : F a i l Heat-Aged S t a b i l i t y , 4 weeks a t 140F: Pass

Ref lectance, %: 83.5 Gloss, 60: 2 .3 Mudcracking, 50 m i l : Pass Sag Resistance, m i l s : 16 F i l l e d Appearance on Block: Exc


SOURCE: Ucar Emulsion Systems: NeoCar Polymers: Formulat ion Suggest ion K-2216


High S o l i d s Self Pr iming A l k y d

I n a r e d i e n t s : Pigment Gr ind : C a r g i l l 57-5766/High S o l i d s A lkyd Ye1 k i ns-TS/Soya L e c i t h i n Bentone 38 Methyl Alcohol Ti-Pure R-SOO/Titanium Diox ide-

B u t r o l 23/Modi f i e d Bar i um Meta-

Atomite/Calcium Carbonate Ny ta l 300/Talc-Magnesium S i l i c a t e Minera l S p i r i t s (Rule 66)

Le t Down: C a r g i l l 57-5766/High S o l i d s Resin Z i rconium 6% Cobalt Naphthenate-6%/Drier A n t i s k i n n i ng Agent Minera l S p i r i t s (Rule 66)

Pa in t P r o p e r t i es: To ta l Veh ic le 49.94 Pigment 50.06 Vol a t i 1 e 15.95 Organic Solvent 15.95 Non-Volat i l e 84.05 Non-Vo la t i le Veh ic le 33.98

Densi ty ( lb/U.S. g a l ) : 11.99 S p e c i f i c G r a v i t y : 1.44 P . V . C . : 31 .55% P/B Ra t io : 1.473 Spread @ 1 M i 1 : 1133 F2 Coat ing VOC: 229 G/L M a t e r i a l VOC: 229 G / L

R u t i l e

bo ra te

j& Gal

224.26 27.35 2.99 0.35 1.99 0.14 1.50 0.23

199.35 5.99

99.68 3.24 149.51 6.62 149.51 6.31 37 * 88 5.89

224.26 27.35 6.98 0.98 1.99 0.27 1.99 0.26

96.68 15.04

77.71 22.29 29.35 29.35 70.65 48.36

18.71 0.25 0.17 0.12

16.63

8.32 12.47 12.47 3.16

18.71 0.58 0.17 0.17 8.07

SOURCE: Buckman Labora tor ies : Formula t ion Suggestion: KQ-20

Miscellaneous 221

Masonry B l o c k

M a t e r i a1 : P a r t A : 2-Propoxyet hanol T r i t o n X-100 S u r f a c t a n t Tamol 731 (25% N . V . ) S u r f a c t a n t C o l l o i d 640 Defoamer R u t i l e T i t a n i u m D i o x i d e Atomi t e C a l c i um Carbonate Water

Pounds

11.6 3 . 5 3.5 4 . 0

50.0 100 .0

50.0

Gal l o n s

1 .50 0 .39 0.38 0.50 1 .46 4 . 4 4 6.00

M ix a t h i g h speed 10 m inu tes ; t h e n add and m ix 3 m i n u t e s :

S h o r t S t u f f P o l y e t h y l e n e F i b e r s 7 . 0 0 . 9 3

Add under reduced speed:

Water E p i -Rez 3520-WY-55 Res in

P a r t B: €p i -Cure 8536-MY-60 C u r i n g Agent ASP 170 Aluminum S i l i c a t e 325 Mesh Water Ground M ica Water

48.6 5.83 260.0 28.57

124.5 15.00 5 0 . 0 2 . 3 8

100.0 4 .24 166.0 20.00

M ix a t h i g h speed 10 m inu tes ; t h e n add and m ix 3 m i n u t e s :

S h o r t S t u f f P o l y e t h y l e n e F i b e r s Water

T y p i c a l C o a t i n g P r o p e r t i e s : T o t a l Volume S o l i d s , %: 41 .7 T o t a l Weight S o l i d s , %: 57.7 PVC, 94: 45.6 V o l a t i l e O r g a n i c Compounds (VOC):

Pounds/Gal lon: 1 .60 Grams/Li t e r : 192

A p p l i c a t i o n : Brush and R o l l e r

Res in Compos i t i on ( s o l i d s ) : Epoxy Resin, %: 65.7 C u r i n g Agent, %: 34.3 T o t a l , %: 100.0

Composite B lend : V i s c o s i t y P a r t A 97 KU P a r t 0 >141 KU P a r t s A and B 131 KU

1 . o 0 .13 22.4 2.69

Pounds Gal 1 ons 538.2 50.00 588.9 50.00

SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1615: Masonry B l o c k F i l l : Epi-Rez 3520-WY-55 Resin/Epi -Cure 8536-MY-60 C u r i n g Agent


Masonry B l o c k f i 11

M a t e r i a1 : P a r t A: 2-Propoxyethanol T r i t o n X-100 S u r f a c t a n t Tamol 731 S u r f a c t a n t C o l l o i d 640 Defoamer Tap Water Mix and add: R u t i l e T i tan ium D iox ide Atomi te Calc ium Carbonate ASP 170 Alumi num S i 1 i c a t e H i speed d i spe rse 10 minutes; t hen add: Shor t S t u f f Po lye thy lene F i b e r s Tap Water Add a t reduced speed: Epi -Rez 3520-W-55 Resin

P a r t 8 : Epi -Cure 8537-W-60 Cur ing Agent Tap Water Mix we1 1 and add: ASP 170 Aluminum S i 1 i c a t e 325 Mesh Water Ground Mica Atomi te Calc ium Carbonate H i speed d i spe rse 10 minutes; t hen add: Shor t S t u f f Po lye thy lene F i b e r s Tap Water

Composi t e 81 end : P a r t A Pa r t B

T y p i c a l Coat V i s c o s i t y

P . V . C . . %

Pounds

11.6 3.5 3 .5 4.0

71 .O

50.0 75.0 35.0

7.0 11.4

260.0

129.0 166.0

50.0 100.0 125.0

1 .o 28.7

532.0 599.7

ng P r o p e r t i es : P a r t A: 128 Krebs U n i t s P a r t B: 108 Krebs U n i t s P a r t s A and B: Fresh: 108 Krebs U n i t s 42.2

T o t a l Weight S o l i d s , %: 67.4 T o t a l Volume S o l i d s , %: 46.2 Resin Composi t ion: Epoxy Resin, %: 65

V o l a t i l e s Composi t ion: Water. l b s . : 393.6

V o l a t i l e Organic Compounds (VOC):

Cur ing Agent, %: 35

Organic, l b s . : 63.6

Pounds/Gal 1 on : 1 .21 Grams/L i ter : 145

A p p l i c a t i o n : Brush and R o l l e r

Gal 1 ons

1.50 0.39 0.38 0.50 8.50

1.46 3.30 1.67

0.93 1.37

30.00

14.25 20.00

2.38 4.24 5.56

0.13 3.44

50.00 50.00

SOURCE: S h e l l Chemical Co.: S t a r t i n g Fo rmu la t i on No. 1616: €pi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Cur ing Agent

Miscellaneous 223

Water Reducible A1 kyd

I n g r e d i e n t s : - Lb Pigment G r i n d : Water 132.72 Busperse 39 /D ispersant 5.90 Bubreak 448/Defoamer 2.95 Z i n c S u l f a t e - H e p t a h y d r a t e 1.97 I g e p a l CTA 6 3 9 / S u r f a c t a n t 1 .97 B u t r o l 2 3 / M o d i f i e d Bar ium Metabora te 49.16 Red I r o n Oxide 98.31 N y t a l 300/Talc-Magnesi um S i 1 i c a t @ 196.63

L e t Down: C a r g i l l 74-7450/Water Reduc ib le

A1 kyd 252.67 n-Buty l A l c o h o l 84.55 Ammoni urn Hydrox i de-28% 9.83 Water 216.29 C o b a l t Napthenate-6%/Dr ier 1 .97 Z i r c o n i u m 6% 3.93

P a i n t P r o p e r t i e s : %Wt T o t a l V e h i c l e 67.32 87.47 P i grnent 32.68 12.53 Vol a t i 1 e 50.16 68.37 Organ ic S o l v e n t 17.20 26.47 N o n - V o l a t i l e 49.84 31.63 N o n - V o l a t i l e V e h i c l e 17.16 19.11

D e n s i t y ( lb . /U .S. g a l ) : 10.59 S p e c i f i c G r a v i t y : 1.27 P.V.C.: 39.60% P/B R a t i o : 1.905 Spread F 1 M i l : 507 F2 C o a t i n g VOC: 376 G/L M a t e r i a l VOC: 218 G/L

Gal 5

15.93 12.53 0 .55 0.56 0.44 0.28 0.12 0 .19 0.22 0.19 1.60 4.64 2.51 9.29 8.30 18.57

29.71 23.86 12.53 7.99

1.31 0.93 25.97 20.43

0.27 0.19 0.55 0.37

SOURCE: Buckman L a b o r a t o r i e s : F o r m u l a t i o n Suggest ion : KQ-22


2-Component Waterborne System

Formula t ion WR-41 demonstrates the improved performance o f a 2-component waterborne system when mod i f i ed w i t h K-Flex XM-4316, a po lyes ter -u re thane d i spe rs ion . A t bo th NCO/OH r a t i o s , improvements were made i n g loss , MEK res is tance, and f l e x i b i l i t y .

NCO/OH Ra t io : 1 .6 Ac ry l ic/PU-Di spers i on: 80/20

Component A : Emulsion E-3275 K-Flex XM-4316 Sodium N i t r i t e (5% aq) Proglyde DMM Edaplan LA 402 S i l w e t 7001 (5% aq) S i l w e t 7605 (25% aq) S i l w e t 7604 (25% aq) Dimethyl ethanol ami ne

Component B: Bayhydur XP-7063

Formula t ion C h a r a c t e r i s t i c s : Nonvo la t i l e , t h e o r e t i c a l , %: 48.7 Theore t i ca l VOC, g/L, ( l b . / g a l l o n ) : 48, (0 .4 )

Wt% 69.31 16.89

0.00 1 .23 0.07 0 .00 0.00 0.00 0.00

12.50

Formulat ion Proper t ies , A i r -Dry 20-25C, 2 weeks: Subs t ra te : Bonder i te 1000 c o l d r o l l e d s t e e l F i l m th ickness , micron ( m i l . ) : 32+-2 (1.3+-0.1) Dry Time (minu tes) : Set t o touch: 4.5

Surface d r y : 12 Through d ry : 18

20, %: 74 MEK Double Rubs: 120 Gloss 60, %: 96 Knoop Hardness: 5 . 5

Koenig Hardness ( sec ) : 108 Impact, D i r e c t , i n c h . l b . : >160 Penc i l Hardness: 2H-3H Impact, Reverse, i n c h . l b . : >160

Formula t ion P roper t i es , Bake 80C 20 min. Post-cure 20-25C, 2 weeks: Subs t ra te : Bonder i te 1000 c o l d r o l l e d s t e e l F i l m th ickness , micron ( m i l . ) : 32+-2 (1.3+-0.1) NCO/OH R a t i o : 1.6 Gloss 60, %: 100 Knoop Hardness: 7

Koenig Hardness ( sec ) : 134 Impact, Forward, i n c h x lb . :>160 Penc i l Hardness: 3H Impact, Reverse, i n c h x lb. :>160

20, %: 80 MEK Double Rubs: 135

Formula t ion Prepara t ion :

a g i t a t i o n f o r approx. 5 minutes.

SOURCE: K ing I n d u s t r i e s : P re l im ina ry Formula t ion WR-41

Add component B t o component A under low shear mechanical


RAW MATERIAL CHEMICAL DESCRIPTION SOURCE

AC 1024 Ac ry l i c r e s i n Rohm&

Acronal DS 6183 Copolymer a c r y l i c es te r d i spe rs ion BASF

Acrysol ASE-60/G-110/ Water-soluble a c r y l i c r e s i n s Rohm& RM-S25/RM-l02O/RM-2020/

TT-935/WS-68 SCT-200/SCT-275/

Act i v-8 D r i et-, acce le ra to r , s t a b i 1 i zer RTVan

Aero Me1 ami ne Powdered grade

Aerosi 1 R-972 Fumed s i l i c a

Aerosol OT-75/OTS Surface a c t i v e agent

A1 umi num L243

A1 umi num Paste #82255

AMP-95 Dispersant

Ancamide 500/2353/ 2410

Anquami ne 401

Aquabead 519

Aquacat

Aquamac 640/700

Aquamac 1085/1090

Aqua-sperse 877-9907

Arcoso lv DPM

Arcosolv DPNP

Arcoso lv D P t B

Arcosolv PNB

Arcosolv PNP

AmCyan

Degussa

AmCyan

S i 1 ber

A1 coa

2-amino-2-methyl-1-propanol Angus

Curing agents f o r epoxy r e s i n s Paci f i c

L i q u i d polyamide c u r i n g agent Paci f i c

M ic ro

D r i e r c a t a l y s t U l t r a

A c r y l i c l a t e x

e a l k y d Water-sol ub

.ampblack Co

D i propylene

Sol vent

Coalescent

Solvent

Solvent

McWhort

McWhort

o r Dispersant Hul s

g l y c o l monomethyl e the r Arc0

Arco

Arc0

Arc0

Arc0

Trade Named Raw Materials 227

RAW MATERIAL

Arcoso lv PP

Arcosolv PTB

Aro lon 500-W-42

Aro l on 020-W-49

Aro lon 840-W-39

Aromatic 100

Aromatic 150

Atomi t e

Aroplaz 1271

Aroplaz 1272

Aroplaz 3859-2-80

ASA 35.3

ASP-NCP/ASP-l70/ ASP-400

Atomi t e

A t tage l 50

CHEMICAL DESCRIPTION

Solvent

Sol vent

O x i d i z i n g a lkyd . % s o l i d s : 42

A c r y l i c polymer. % s o l i d s : 49

A c r y l i c polymer. % s o l i d s : 39

Hydrocarbon so l ven t

Hydrocarbon so l ven t

Cal c i um carbonate

Long-o i l l i n s e e d a l kyd r e s i n

100% s o l i d s ve rs ion o f Aroplaz 1271

A lkyd r e s i n

Wax emulsion

A1 uminum s i 1 i c a extender pigments

SOURCE

Arc0

Arc0

Rei chh

Reichh

Rei chh

Exxon

Exxon

ECC

Rei ch

Reich

Reich

CCA

Engel

Calcium carbonate, n a t u r a l ECC

C o l l o i d a l a t t a p u l g i t e th i ckener Engel

Aurasperse W-1021 Y I O Yel low i r o n ox ide Har s haw

Aurasperse W-3041 R I O Red i r o n ox ide Harshaw

Aurasperse W-4123 Harshaw

Aurasperse W-7012 LB Carbon b l a c k Harshaw

AZO-33 Z inc ox ide Asarco

AZO-55 Z i nc o x i de. American process Asarco

228 Water-Based Paint Formulatiom

R A W MATERIAL CHEMICAL DESCRIPTION

B a r y t e s No. 1 Bar ium s u l f a t e ex tender p igment

Bas ic Lead S i l i c o Chromate

Bayhydur XP-7063 W a t e r - d i s p e r s i b l e i s o c y a n a t e

B a y f e r r o x 318M S y n t h e t i c i r o n o x i d e p igment

Beaverwhi t e 325 T a l c ex tender p igment

Beckosol 13-402 Water r e d u c i b l e a1 kyd

B e e t l e 65/80/216-8 Urea- formaldehyde compound

Bentone AD/EW/LT/ R h e o l o g i c a l a d d i t i v e SD-1/38

Benzof 1 ex 9-88 P l a s t i c i z e r

BK5000 Pigment

BK5099 Pigment

B l a s t i t e #220 Aluminum o x i d e

Brown I r o n Oxide 444 Pigment

Bubble Breaker 776-P/ Defoamers 3295

Bubond 357 C a t i o n i c po lymer

Bubreak 448/4400 Defoamer

Burgess N o . 98/No. 128 Hydrous c l a y

Busan 11-M1 Bar ium metaborate m i c r o b i o c i d e

Busperse-39/203 D i s p e r s i n g agent

B u t r o l 23/35 C o r r o s i o n and s c a l e i n h i b i t o r

B u t y l Carb i t o 1 D i e t h y l e n e g l y c o l monobutyl e t h e r

B u t y l C a r b i t o l A c e t a t e D i e t h y l e n e g l y c o l monobutyl e t h e r a c e t a t e

SOURCE

WC&D

Rheox

Bayer

M i l e s

Cyprus

Rei c h

AmCyan

Rheox

Vel s i c

P f i z e r

Harcros

SOH IO

Col umb

W i t c o

Buckman

Buckman

Burgess

Buckman

Buckman

Buckman

Union

Union


R A W MATERIAL CHEMICAL DESCRIPTION SOURCE

B u t y l Cel l o s o l v e Ethylene g l y c o l monobutyl e the r UnCarb

Bu ty l O x i t o l G lyco l e the r She1 1

Byk 020/023/025 Defoamers Bykchem

ace ta te

0yk 155/156/301/306/ A d d i t i v e s 320/321/346

BykChem

Bykumen WS Wet t i ng/di spers i ng agent BykChem

Cab-0-Si 1 L-SO/LM-130 Fumed s i 1 i cas TS-61 O/TS-720

Calcium Hydrocem D r i e r c a t a l y s t f o r water systems

Calcium Hydro-Cure Ca ta l ys t f o r water systems

Camel Cal Ex t ra f i n e ground l imestone s l u r r y

Camel Carb Calcium carbonate extender

Camel F i l

CAO- 1

Carbi t o 1

Ca lc i um carbonate

An t iox idan t

D ie thy lene g l y c o l monoethyl e the r and e t h y l ene g l y c o l m ix tu re

Carbopol 941 Thickening agent

Cargi 11 57-5766 WR High s o l i d s a l k y d

Cargi 11 72-7203 WR O i l f r e e po lyes te r

Cargi 11 74-7450 WR Short soya a l k y d

Cargi 11 74-7474 WR chain-stopped a l k y d

C a r g i l l 7412 Non-oxi d i z i ng a1 kyd

Cabot

Mooney

Mooney

Genst a r

Genstar

Genst a r

PMCSpec

UnCarb

BFGood

Cargi 11

Cargi 11

Cargi 11

Cargi 11

Cargi 11


RAW MATERIAL CHEMICAL DESCRIPTION

Cargill 7464 Water reducible a1 kyd

Cel i te 281 /499 Di atomaceous si 1 i cas

Cellosize ER-52M Hydroxyethyl cellulose thickeners ER-15,000/ER-30,000/ QP-44OO/QP-44OOH/QP-l5,OOO/ QP-15, OOOH Chemcor AS-35-3 Wax emulsion

Chempol 10-0091 WR short oxidizing oil alkyd

Chlorez 700 Chlorinated paraffin resin

Chromi um Green Oxide 5-5310 Pigment

CL 27NA

Cobalt Chem-All 12%

Cobalt Hydrocure 12%/ Catalysts for water systems I1

Cobalt Naphthenate-6% Drier

Colloid 107/111/111M/ Dispersants 226/35

Colloid 640/643/650/ Defoamer/Antifoams 653/675/677/679/ 694/770

Composi ti on R/T Surfactants

Cosan 101/158/234 Preservat i ves

Cycat 4040 Acid catalyst

Cyclo Sol 63 Aromatic solvent

Cyme1 303/324/325/ Melamine-formaldehyde resins 327/350/385

SOURCE

Cargi 11

Manvi 1 1

UNCarb

CCA

Freeman

Dover

Mi nPi g

Dow

Mooney

Mooney

Interst

Rhone-

Rhone-

Cal gon

Cosan

AmCyan

She1 1

AmCyan


R A W MATERIAL

Dalpad A

Daxad 30-30

DC F l u i d 593

DC-14

DeeFo HG-12/PI-4/ 806-1 15

Dehydran 1293

DER 331/660X80

D i cyandi ami de

D i sperbyk

Disperse-Ayd/W22/W28

DMEA

Dowanol DPM/DPnB/ EPh/ PM/ PnB/Pn P/PPH

Dow Corning 14/57

Dow ic i l 75

Dow XUS19000.01

Drewpl us L-475/ L-493/Y-281

D r i k a l i t e

Durami t e

CHEMICAL DESCIPTION

Coal esc i ng agent

Dispersant

Phenyl t r ime th i cone

S i 1 i cone

Antifoam/defoamers

Defoamer

Epoxy r e s i n s

Dispersant

D ispersants

N e u t r a l i z i n g amine

Glyco l e the r p roduc ts

S i 1 i cone a d d i t i v e s

A n t i m i c r o b i a l agent

Epoxy r e s i n

Foam c o n t r o l agents

Calcium carbonate extender pigment

Calcium carbonate extender pigment

E-845 Thickener

Eagle Z inc 417W Z inc ox ide

Edaplan LA 402 Flow and l e v e l i n g agent

SOURCE

Dow

Grace

DowCorn

DowCorn

U l t r a

Henkel

Dow

AmCyan

BykChem

Daniel

UnCarb

DowChem

DowCorn

DowChem

DowChem

Drew

ECC

ECC

Rohm&

Eagle

K ing


RAW MATERIAL

E k t a p r o EEP

E k t a s o l v e DB

E k t a s o l v e DB A c e t a t e

E k t a s o l v e DE

E k t a s o l v e EB

E k t a s o l v e EP

Emul s i o n E-2977

Emuls ion E-3122

Emul s i on E-3275

€ p i -Cure 8290-Y-60

Epi -Cure 8292-Y-60

Epi -Cure 8536-MY-60

Epi -Cure 8537-WY-60

Epi -Rez 351 5-W-60

Epi-Rez 3520-WY-55

Epi -Rez 3522-W-60

E p i -Rez 3540-WY-55

Epi -Rez 3551 -WY-43

Epi-Rez 5522-WY-55

E p o d i l L

E p o d i l 759

E p o t u f 37-058

E p o t u f 37-143

E p o t u f 37-618


E t h e r e s t e r

Sol ven t

S o l v e n t

Sol v e n t

Sol ven t

2-propoxyethanol s o l v e n t

A c r y l i c emuls ion

A c r y l i c d i s p e r s i on

Epoxy c u r i n g agent




Epoxy r e s i n

SOURCE

Eastman

Eastman

Eastman

Eastman

Eastman

Eastman

Rohm&

Rohm&

Rohm&

Shel 1

Shel 1

Shel 1

Shel 1

Shel 1

Epoxy r e s i n Shel





Hydrocarbon d i l u e n t f o r epoxy r e s i n s

R e a c t i v e d i 1 uent

Epoxy r e s i n

Epoxy r e s i n

Epoxy r e s i n hardener

Rei ch

Rei ch

Rei ch


RAW MATERIAL

EpotUf 37-680

E p o t u f 38-501

Exxa te 700


Epoxy r e s i n

Epoxy r e s i n

Oxo-acetate c o s o l v e n t

FC-430 F1 u o r o s u r f a c t a n t

F1 a t t i ng Agent TS-100

F l u o r a d FC-129 F1 uorochemi c a l

Foamaster R/VF/VL/ Ant i foam/defoamers 333

Foamex 825 A n t i foam

Foamki 11 639AA Foam c o n t r o l agen t

F u n g i t r o l 234 Fungi c i de

Go ld Bond R M i c r o c r y s t a l l i n e s i l i c a

H a l o f l e x 202 Polymer emu1 s i on

Ha lox 8W-100 C a l c i u m b a r i u m phospho-si 1 i c a t e

Ha lox BW-191/CW-191/ W h i t e non - lead p igmen ts CW-49l/SW-ll l/SW-1116/ sz P-39 1

Halox X t a i n A

HEC QP-4400 H y d r o x y e t h y l c e l l u l o s e

Heucophos ZMP/ZPZ Z i n c y e l l o w s

Hexyl C a r b i t o 1 S o l v e n t

SOURCE

Rei c h

Rei ch

Exxon

3M

Degussa

3M

Henkel

TegoChe

C r u c i b

Cosan

Tamms

ICIRes

Ha l ox

Hal ox

Hal ox

UnCarb

Heubach

UnCarb


R A W MATERIAL

Hodag PX-218

H y d r i t e F l a t D

I ceberg

Igepa l GO-630/ CTA-639

I m s i l A25

I n t e r c i d e T-0

I n t e r w e t #33

5-1365

5-31 03

Jonc ry l SCX-1520/ 56/95/540/554

Jonwax 26

Kadox-515/911/915

Kathon LX

K-Cure 129W

Ke lec in 1081

Kel s o l 3931 -WG4-45

K-F1 ex UD-320W/ XM-2304

K-F1 ex XM-2311

K-Flex XM-4310


Anti foam

Kao l i n extender pigment

Anhydrous aluminum s i l i c a t e

Sur fac tan ts

M i c r o c r y s t a l l i n e s i l i c a

M i c r o b i o s t a t

Wet t ing agent

S t ron t ium chromate

A c r y l i c polymers

Wax emulsion

Z inc ox ide

Fung ic ide

Ca ta l ys t

Soybean o i l

O i l copolymer. % s o l i d s : 45

Poly01 s

Pigment d i s p e r s i n g r e s i n

Polyester-urethane d i spe rs ion

SOURCE

Hodag

Georgia

Burgess

Rhone-

Unimin

Akzo

Davis

M i nPi g

Johnson

Johnson

N J Z i nc

Rohm&

K ing

Rei ch

Rei ch

K ing

K ing

K ing

Tra& Named Raw Materials 235

R A W MATERIAL

K-Flex XM-4316

K-Flex 188

Kodaf lex DBP

KP-140

Kroma Red R0-7097

Kronos 2020

Kronos 2160

Kronos 2310

K-Sperse 152MS

L-203-D

Lampblack #E77

Lansford L243

Lodyne S107/S107B

LVT 400

Magnacat

Mai nco te HG-54

Mai nco te PR-71

Manganese Hydrocure


Polyester-urethane d i spe rs ion

Pol yo1

P l a s t i c i z e r

P1 a s t i c i zer

I r o n ox ide pigment

Rut i 1 e t i t a n i um d i o x i de

T i t a n i um d i o x i d e

T i tan ium d i o x i d e

Dispersant

S t ron t i um chromate

Ta lc

D r i e r - c a t a l y s t

Ac ry l i c 1 atex


Ca ta l ys t

Manganese Hydrocure I 1 Ca ta l ys t

Mapico Red 297 I r o n ox ide

Mapico Red 347A I r o n ox ide

Mapico 567 I r o n ox ide

Mapico 1075 I r o n ox ide

SOURCE

King

King

Eastman

Eastman

P f i zer

Kronos

Kronos

Kronos

K ing

Cookson

Hul s

S i 1 ber

C i ba-

B a r r e t t

U l t r a

Rohm&

Rohm&

OMGroup

OMGrou p

Col umb

Col umb

Col umb

Col umb


RAW MATERIAL

McWhorter 73-7358

McWhorter 248-5409

Merbac 35

Methocel J-12-MS/856

Methyl Carbi t o 1

Methyl on 751 08

Mica

M i chem 392-25

M i chem Lube 11 0/182/ 511/737/743/02925

M i c r o t a l c MP12-50

Microwhi t e 25

Minex 4/10

Min-U-Si1 40

Moly-White 212

Monarch 1300

Mor-Lok 1035/1043

MPA- 1078

Nacor r

Nacorr 1552/1754

CHEMICAL DESCRIPTION SOURCE

Modi f i ed p o l yo1 e f i n

A c r y l i c emulsion

McWhort

McWhort

B a c t e r i c i d e Cal gon

Hydroxypropyl m e t h y l c e l l u l o s e s Dow

D ie thy lene g l y c o l monomethyl e t h e r UnCarb

Occi den

325 mesh, water ground Engl i s h KMG/ Uni m i n

Wax emulsion Michel

M i chel Wax a d d i t i v e s

P f i zer

GeoMarb

Low micron t a l c

Sodium potassium aluminum s i l i c a t e s Unimin

S i l i c a p a i n t f i l l e r

Cor ros ion i n h i b i t i v e pigment

F l u f f y carbon b l a c k

A n t i - s e t t l i n g agent

Cor ros ion i n h i b i t o r

Cor ros ion i n h i b i t o r s

Nacure X49-11O/XP-l81/Catalysts f o r po l ymer i c c o a t i n g s XP-188/155/25OO-X/ 2547

Uni m i n

Sherwi n

Cabot

Morton

Rheox

K ing

K ing

K i ng


RAW MATERIAL

Na lco 2300

Nal z i n SC- l /2

N a t r o s o l P l us/P1 us 330/P1 us 330PA

N a t r o s o l 250 HBR/ 1 on

250HR/250MHR/250MR/ 250MXR

NeoCar L a t e x 2300



Neoc ry l XA-6085

N i c r o n 400 T a l c

Nopco NDW/NXZ

Nopcoci de N-96

No. 1 Wh i te

Novoperm Red F3RK-70

NuoCide 404-D/960

Nuocure C o b a l t 10%

Nuocure Manganese 6%

Nuosept 95/951/145/ 6 3 5 1

Nuosperse 657

Nyad 1250

N y t a l 300/400

CHEMICAL DESCRIPTION SOURCE

A n t i foam Nal c o

C o r r o s i o n i n h i b i t i v e p igmen ts Rheox

H y d r o x y e t h y l c e l l u l oses-modi f i ed Aqua1 on

H y d r o x y e t h y l c e l l u l o s e s Aqua-

NeoCar po l ymer . 55% s o l i d s

E x t e r i o r po l ymer . 53.5% s o l i d s

For i n t e r i o r semig loss app l i c a t i ons

A c r y l i c copolymer

Defoamers

M i 1 dewci des

Ca lc ium c a r b o n a t e

M i 1 dewci de

P o l y u r e t h a n e c a t a l y s t

P o l y u r e t h a n e c a t a l y s t

P r e s e r v a t i v e s

D i s p e r s i n g agent

W o l l a s t o n i t e

T a l c s

UnCarb

UnCarb

UnCarb

I C I Res-

Luzenec

Hen k e l

Henkel

ECC

Hoec h s t

H u l s

Hul s

Hul s

Hu l s

Hu l s

Nyco

Vander



OK 412 F l a t t i n g agent

Omyacarb UF Natura l ca lc ium carbonate

Oncor M50 A n t i - co r ros i ve pigment

Opt iwhi t e Anhydrous aluminum s i l i c a t e

Organofunct ional S i lane A-187

Patco te 513/519/531/ Defoamers 047

Phos-Chek P/30 Flame re ta rdan t

Phosguard 5-0806/ 5-0013/5-0015/5-0053

Pigment D isperser NL Dispersant

P1 i 01 i t e 7104 Styrene-butadiene copolymer

PMA-100 Fungic ide

PM Aceta te

Po lyg loss 90 C1 ay

Polymekon SPP-W

POlyOX WSR-301 Water s o l u b l e r e s i n

Polyphase AF-1 B a c t e r i c i d e f u n g i c i d e

Pol y-Tex 61 1 -Q

Polywet ND-Z/ND-35 D ispe rsan t / su r fac tan ts

Proglyde DMM Dipropylene g l y c o l d imethyl e the r

Propasol Solvent B I n d u s t r i a l so l ven t

Proxel GXL Chemical b i o c i d e

SOURCE

Degussa

Omya

NLChem

Burgess

OSISpec

P a t t e r

Monsant

M i nPi g

BASF

Goodyea

Dow

Arco

Huber

Mooney

UnCarb

Troy

I n t e r e z

Uni r o y

DowChem

UnCarb

I C 1



91 48 Defoamer

QR-708/OR-7088/ Rheology mod i f i e rs QR-1374

R-2899 I r o n Oxide Red i ron ox ide

Raven 16/410/1020 Carbon b lacks

Raybo 60 F1 ash r u s t i n h i b i t o r

Red I r o n Oxide 5-3100 Pigment

Red I r o n Oxide 5-3106 Pigment

Red I r o n Oxide R-2899/R-4098/R-5098 Pigments

Red I r o n Oxide R0-4097 Pigment

Regal 330 Carbon b lack

Resi mene 747/797 Me1 ami ne r e s i ns

Rhoplex AC-1024/ A c r y l i c emulsions AC-3001/CL-lO4/CL-l05/ E-3188/MV-23/R-AC-507/WL-96

Ropaque OP-62 LO Opaque polymer

Ross & Rowe 551 Modi f i ed 1 ec i t h i n

Rovace SF-091 V i n y l a c r y l i c copolymer

R u f f B u f f Coarse s i l i c a

SOURCE

Troy

Rohm&

P f i zer

Col umb

Raybo

M i nPi g

M i nPi g

P f i zer

Harcros

Cabot

Monsan

Rohm&

Rohm&

Ross&

Rohm&

Tammsco

Sancure 81 5/825

S a n t i c i z e r 160

San to l i nk EP-560

SF-69

Shi e ldex

Shor t S t u f f

Waterborne urethane r e s i n Sanncor

P l a s t i c i z e r Mon san t o

Cross1 i nker Monsanto

S i 1 i cone GE

An t i - co r ros ion pigment, nontox ic Davison

Po lye thy lene f i b e r s Min i F i b



S i c o r ZNP-S A n t i - c o r r o s i o n p igment

S i 1 ane A-187

S i l c r o n G-601 F i n e p a r t i c l e s i l i c a g e l

S i 1 wet L-77/7001/ S i l i c o n e w e t t i n g agen ts L-7604/L-7605

Skane M-8 M i l d e w c i d e f o r p a i n t

S k i n o #2 A n t i s k i n n i ng agen t

Snowf 1 ake Ca lc ium c a r b o n a t e

S o l v e n t 142HT

Sparmi t e B a r i um s u l f a t e

S p e c i a l B l a c k 4 Carbon b l a c k

Spensol L44/L51/L52/ Urethane p o l y o l s L53/L54

S t rodex MO-lOO/P-100/ S u r f a c t a n t s PK-90/PK-95G

S u n b r i t e Green 264-8142/ Pigments Sunbr i t e Ye1 1 ow 74/ S u n b r i t e Y e l l o w 272-0558/ S u n f a s t B l u e 248-3750

Super Seatone B u r n t Umber Pigment

S u r f a c t o l 365 D i s p e r s a n t

S u r f y n o l C T - l l l / S u r f a c t a n t s CT-131/CT-151/DF-37/ DF-62

S u r f y n o l DF-58/ Defoamers DF-70/DF-75

S u r f y n o l DF-llOD/ S u r f a c t a n t s DF-11 OL/DF-21 O/GA/ TG/104/104DPM/104€/ 104H/104PG-50/420/ 485

SOURCE

BAS F

OSISpec

SCM

UnCarb

Rohm&

OMGr ou p

ECC

She1 1

H a r c r o s

Degussa

Re ich

D e x t e r

Sun

H i 1 t o n

CasChem

A i r P r o d

A i r P r o d

A i r P r o d



sws 211 A n t i foam

S y l o i d 234 S i 1 i c a f 1 a t t i ng agen t

Syntex 3981 A c c e l e r a t o r

T a l c 399 Ex tender p igment

Tamol 165/681/731/ D i s p e r s a n t s 731A/050/960/983/ 11 24/SG-1

Tan 10A

T e r g i t o l NP-4/NP-10/ N o n i o n i c s u r f a c t a n t s NP-40

Texanol Coal e s c i ng agent

T h a l o B l u e Aqueous d i s p e r s i on

T h i x a t r o l ST T h i x o t r o p e

T i n t - A y d WD-2744 P h t h a l o g reen d i s p e r s i o n

T i n u v i n 328 UV abso rbe r

T i o n a RCL-9 T i t a n i u m d i o x i d e

T i o x i de TR-92 T i t a n i um d i o x i d e

T i -Pure CR-800/ T i t a n i u m d i o x i d e s R-700/R-702/R-706/ R-900/R-901/R-902/ R-960

T i t a n o x 2020/2060/ T i t a n i um d i o x i d e s 21 01 /2160

T r i t o n GR-7M A n i o n i c s u r f a c t a n t

T r i t o n CF-10 W e t t i n g agent

T r i t o n CA/GR-SM/ N o n i o n i c s u r f a c t a n t s N-57/N-lOl/X-100/ X-405

SOURCE

Wacker

Davi son

Rhone-

WC&D

Rohm&

Col umb

UnCarb

Eastman

Tenneco

Rheox

D a n i e l

C i ba-

S CM

T i o x i d e

duPont

Kronos

UnCarb

UnCarb

UnCarb

242 Water-Based Point Formulations


Tronox CR-800/CR-813/ R u t i l e t i t a n i u m d iox ides CR-828

Troysan Polyphase Fungic ides AF-1/174/586

Troysol LAC Detergent /sur fac tan t

TS 610

Ucar 515

Ucar F i 1 mer I B T

Ucar Latex 100

Ucar Latex 105

Ucar Latex 144

Ucar Latex 146

Ucar Latex 161

Ucar Latex 163

Ucar Latex 169

Ucar Latex 353

Ucar Latex 367

Ucar Latex 379

Ucar Latex 3796

Ucar Latex 421

Ucar Latex 422

Ucar Latex 446

Ucar Latex 447

Ucar Latex 461

Ucar Latex 471


High s o l i d s a c r y l i c b inde r

S e l f - c r o s s l i n k i n g a c r y l i c l a t e x

S ty rene-acry l i c emu1 s i on polymer

V i n y l a c r y l i c copolymer

A1 1 - a c r y l i c b i nder

Ac ry l i c polymer b i nder

V i n y l ace ta te copolymer

Ac ry l i c 1 a tex polymer

A c r y l i c l a t e x polymer

V i n y l a c r y l i c polymer

S ty rene /ac ry l i c l a t e x - s o f t

S ty rene /ac ry l i c l a tex -ha rd

SOURCE

Kerr-Mc

Troy

Troy

Cabot

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb



Ucar Latex 481 U l t r a - g l o s s l a t e x . Polymer: Hard

Ucar Latex 624 100% a c r y l i c l a t e x

Ucar Latex 625 Acry l i c 1 a tex

Ucar l a t e x 626 A1 1 - a c r y l i c b i nder

Ucar Latex 651 A c r y l i c l a t e x

Ucar Latex 2300

Ucar Latex 6030 F i ne p a r t i c l e s ze "booster" 1 a tex

Ucar Latex 6336 Hard, a l l - a c r y l c l a t e x

Ucar Latex 6390 A c r y l i c b i nder . "Booster" 1 a tex

Ucar Pol yphobe 102/103 Rheology modi f i e r s

Ucar Polyphobe 106HE/ High e f f i c i e n c y th i ckeners 107/114-

Ucar Polyphobe 9831

Ucar SCT100/SCT200/ 146

Ucar Veh ic le 435

Ucar Veh ic le 441

Ucar Veh ic le 443

Ucar Veh ic le 455

Ucar Veh ic le 462

Ucar XYHL

Ucar 376

Rheology modi f i e r

Thickeners

SOURCE

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

UnCarb

A c r y l i c polymer (45% s o l i d s ) UnCarb

Ac ry l i c emu1 s i on Uncarb

A c r y l i c l a t e x (41% s o l i d s ) UnCarb

S e l f -cross1 i n k i ng a c r y l i c 1 a tex UnCarb

Thermosett ing s t y rene a c r y l i c l a t e x UnCarb

P o l y v i n y l - b u t y r a l r e s i n UnCarb

UnCarb



V a r s o l No. 1 M i n e r a l s p i r i t s

Versa-F1 ow 102

Waterpoxy 701 /702/1401 Epox ies

Wingdale Wh i te N a t u r a l ground c a l c i u m c a r b o n a t e

W i t cobond 234 P o l y u r e t h a n e d i s p e r s i o n

W o l l a s t o c o a t 10AS

W o l l a s t o k u p IOES

W/R Epoxy E s t e r Res in

W/R P o l y e s t e r 72-7203

SOURCE

Exxon

Shamroc

Henkel

GeorMar

W i t c o

Nyco

NyCQ

Rei ch

C a r g i 11

X-3356 C.P. Medium Medium chrome y e l l o w p igment C i ba-

XX-503/XX-503R Z i n c o x i d e s NJZ inc

XAMA- 7 Rohm&

YD-2288

Ye1 k i ns-TS Soya l e c i t h i n

Y e l l o w I r o n Oxide YO-2087 Pigment

Y e l l o w I r o n Oxide 1075A Pigment

Zeeospheres 400

Zeeospheres 600

Z i n c Chromate Y539D

Z i n c Hydro-Nap

Z i n c Ox ide 417-W

H a r c r o s

Ross&

H a r c r o s

Col umb

Zeel and

Zeel and

Heubach

Mooney

Eag1 e



Z i r c o 6% D r i e r

Z i r con i um Chem-All 12%

Z i r con i um Hydro-Cem Z i r con i um d r i e r , 12%

Zirconium Hydro-Cure 12% Ca ta l ys t f o r water systems

Zopaque RCL-6 T i tan ium d i o x i d e . R u t i l e

Zopaque RCL-9 T i t a n i um d i o x i d e

1 OES Wol 1 as tocoat

233 Basic Z inc Chromate

399 Lo-Micron Ta lc Extender pigment

895-9901 Water-dispersed b lack pigment

SOURCE

I n t e r s t

Mooney

Mooney

Mooney

SCM

SCM

Nyco

Wayne

WC&D

Tenneco

Suppliers' Addresses 247

A i r Products and Chemicals 7201 Hami 1 t o n B lvd . Al lentown, PA 18195 (215)-481-4911/(800)-345-3148

Akzo Chemical s , I n c . 300 S. R ive rs ide Plaza Chicago, I L 60175 (312)-906-7500/(800)-257-8292

Alcoa I n d u s t r i a l Chemicals P.O. Box 67 Bauxi te, AR 72011 (501)-776-4981/(800)-643-8771

American Cyanamid Co. Chemicals Group One Cyanamid Plaza Wayne, NJ 07470 (201)-831-2000/(800)-443-0443

Angus Chemical Co. 1500 E. Lake Cook Rd. B u f f a l o Grove, I L 60089 (708)-215-8600/(800)-362-2580

Aqua1 on P .O. Box 15417 2711 C e n t r e v i l l e Rd. W i 1 m i ngton, DE 19850 (302)-996-2000/(800)-345-8104

ARC0 Chemical Co. 3801 West Chester P ike Newtown Square, PA 19073 (215)-359-2000

Asarco, I n c . 180 Maiden Lane New York, NY 10038 (212)-510-2000

BASF Corp. 100 Cherry H i l l Rd. Parsippany, NJ 07054

Buckman Labora to r ies I n t ' l I n c . 1256 N. McLean 8 l vd . Memphis, TN 38018

(201)-316-3000/(800)-526-1072

(901)-278-0330/(800)-BUCKMAN

Burgess Pigment Co. P.O. Box 349 Sandersv i l l e , GA 31082 (912)-5552-2544/(800)-641-8999

Byk-Chemi e USA 524 S. Cherry S t . Wall i ngford , CT 06492

Cabot Corp. R t . 36 West Tuscola, I L 61953

(203)-265-2086

(217)-253-3370/(800)-222-6745

Calgon Corp. P.O. Box 1346 Pi tsburgh, PA 15230

C a r g i l l , I n c . P.O. Box 5630 M i nneapol i s , MN 55440 (612)-475-6478/(800)-535-1443

(412)-777-8000/(800)-4-CARBON

CasChem, I n c . 40 Avenue A. Bayonne, NJ 07002

Chemical Corp. o f America 2 Car l ton Ave. E . Ruther fo rd , NJ 07073

(201)-858-7900/(8OO)-CAS-CHEM

(201)-438-5600

C i ba-Gei gy Corp. 7 S k y l i n e D r . Hawthorne, NY 10532 (914)-347-4700/(800)-431-1900

Columbian Chemicals Co. 1600 Parkwood C i r c l e A t l a n t a , GA 30339 (404)-951-5700/(800)-235-4003

Cosan Chemical Corp. 400 14th S t . C a r l s t a d t , N J 27072 (201)-460-9300


C r u c i b l e Chemical Co., I n c . P.O. Box 6786 G r e e n v i l l e , SC 29606 (803)-277-1284/(800)-845-8873

Cyprus I n d u s t r i a l M i n e r a l s P.O. Box 3419 Englewood, CO 80155 (800)-325-0299

Dan ie l Produc ts 400 Claremont Ave. Jersey C i t y , NJ 07304 (201)-432-0800

Frank D. Dav is Co. 7011 M u i r k i r k Rd. Bel t s v i 1 l e , MD 20705 (301)-776-2400/(800)-638-4444

Davi son Chemical D i v . W . R . Grace & Co. P .O. Box 2117 B a l t i m o r e , MD 21203

Degussa Corp. 65 Cha l lenger Rd. R i d g e f i e l d Park, N J 07305 (201)-641-6100

Dexter Chemical Corp. 845 Edgewater Rd. Bronx, NY 10474

Dover Chemical Corp W15 & D a v i s P.O. Box 40 Dover, OH 44622 (800)-321-8805

Dow Chemical USA 2020 Dow Center Mid land, M I 48674 ( 800 ) - 258-CH EM

Dow C o r n i n g Corp. Box 0994 Mid land, M I 48686 (5171-496-4000

Drew I n d u s t r i a l D i v . Ashland Chemical I n c . One Drew P laza Boonton, NJ 07005 (201)-263-7800/(800)-526-1015

DuPont Co. 1007 Market S t . W i 1 m i ng ton , DE 19898 (800) -441 -751 5

Eagle-P icher I n d u s t r i e s , I n c . P.O. Box 550 C & P o r t e r S t r e e t s J o p l i n , MO 64802 (417)-623-8000

Eastman Chemical Co. P.O. Box 431 K i n g s p o r t , TN 37662 (615)-229-4006/(8OO)-EASTMAN

ECC I n t e r n a t i o n a l 5775 Peachtree-Dunwoody Rd. A t l a n t a , GA 30342 (404)-843-1551/(800)-843-3222

Engelhard Corp. 101 Wood Ave. I s e l i n , N J 08830 (908)-205-5000

E n g l i s h Mica Co. R i dgeway Center B1 dg . Stamford, CT 06905 (203)-324-9531

Exxon Chemical Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6633

Freeman I n d u s t r i e s , I n c . 100 M a r b l e d a l e Rd. Tuckahoe, NY 10707 (914)-961-2100


GE S i 1 i cones 260 Hudson R ive r Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886

Genstar Stone Products Co. Exec Plaza I V 11350 McCormick Rd. Hunt Va l l ey , MD 21031 (410)-527-4000

Georgia Marble Co. 1201 Roberts B lvd . , 8 ldg . 100 Kennesaw, GA 30144 (404) -421 -6500

B.F. Goodrich Co. 991 1 Brecksvi 11 e Rd. Brecksvi 11 e, OH 441 41 (216)-447-5000/(800)-331~1144

Goodyear T i r e & Rubber Co. 1144 E . Market S t . Akron, OH 44316 (216)-796-3010

W.R. Grace & Co.-Conn. 55 Hayden Ave. Lexington, MA 02173 (61 7)-861 -6600

Harcros Chemical s I n c 5200 Speaker Rd. Kansas C i t y , KS 66106 (913)-321-3131

Harshaw/F i l t ro l Pa r tne rsh ip 30100 Chagrin B lvd . Cleveland, OH 44124

Henkel Corp. 11501 Nor th lake D r . C i n c i n n a t i , OH 45299 (513)-530-7300/(800)-543-7370

Heucotech, L t d . 99 Newbold Rd. F a i r l e s s H i l l s , PA 19030 (215)-736-9533/(800)-HEUEACH

H i 1 ton-Davi s Co. 2235 Langdon Farm Rd. C i n c i n n a t i , OH 45237 (513)-841-4000/(800)-477-1022

Hoechst Celanese Corp. 5200 77 Center D r i v e Char lo t te , NC 28217 (704)-559-6000/(800)-365-2436

J.M. Huber Corp. Clay D iv . One Huber Rd. Macon, GA 31298 (912)-745-4751/(800)-637-8176

Huls America I n c . 80 Centennial Ave. P i scataway, N J 08855 (908)-980-6800/(800)-631-5275

I C 1 Resins US 730 Main S t . Wi lmington, MA 01887 (508)-658-6600/(800)-225-0947

I n t e r s t a b Chemicals, I n c . 500 Jersey Ave. P . O . Box 638 New Brunswick, NJ 08903

S.C. Johnson Polymer 1525 Howe S t . Raci ne, W I 53403 (414)-631-4875/(800)-231-7868

Kerr-McGee Chemical Corp. Kerr-McGee C t r . P . O . Box 25861 Oklahoma C i t y , OK 73125 (405)-270-1313/(800)-654-3911

King I n d u s t r i e s , I n c . Science Rd. Norwalk, CT 06852 (203)-866-5551/(800)-431-7900


KMG M i n e r a l s , I n c . P.O. Box 729 1433 Grover Rd. K i ngs Mounta in, NC 28086 (704)-739-3616/(800)-443-MICA

Kronos, I n c . P.O. Box 60087 3000 N . Sam Houston Pkwy Houston, TX 77205 (713)-987-6300

M a n v i l l e F i l t r a t i o n 8, M i n e r a l s P.O. Box 519 Lompoc, CA 93438 (303)-978-4900/(800)-6

McWhorter 400 East Cot tage P lace C a r p e n t e r s v i l l e , I L 60

4-31 03

10

Michelman, I n c . 9089 S h e l l Road C i n c i n n a t i , OH 45236 (5131-793-7766

M i c r o Powders, I n c . 580 Whi te P l a i n s Rd. Tar ry town, NY 10591 (914)-793-4058

M i l e s I n c . Mobay Road P i t t s b u r g h , PA 15205 (412)-777-2000/(800)-662-2927

M i n e r a l P i gments Corp. Dav is C o l o r s 7011 M u i r k i r k Rd. B e l t s v i l l e , MD 20705

Monsanto Chemi c a l Co. 800 N . L indbergh B l v d . S t . Loui s, MO 63167 (314)-694-1000/(800)-325-4330

Mooney Chemicals I n c . 2301 Scranton Rd. C leve land, OH 44113

Mor ton I n t e r n a t i o n a l 333 W. Wacker D r i v e . Chicago, I L 60606

Na lco Chemical Co. One N a l c o C t r . N a p e r v i l l e , I L 60563

(312)-807-2000

(708)-305-1000

New Jersey Z i n c Co. F o u r t h S t . 8 F r a n k l i n Ave. Palmerton, PA 18071

NL Chemicals, I n c . P.O. Box 700 H igh ts town N J 08520

Nyco M i n e r a l s , I n c . , P.O. Box 368 W i l l s b o r o , NY 12996 (5181-963-4262

O c c i d e n t a l Chemical Corp. 300 Berwyn Park Berwyn, PA 19312 (215)-251-1000

OM Group I n c . 2301 Scranton Rd. C leve land, OH 44113 (216)-781-8383/(800)-321-9696

Omya I n c . 61 Main S t . P r o c t o r , VT 05765 (802)-459-3311/(800)-451-4468

Paci f i c Anchor Chemical Corp. 1224 Mendon R d . Cumberland, R I 02864 (401)-333-4100/(800)-874-66668

P f i z e r , I n c . 235 E. 42 S t . New York, NY 10017 (212)-573-7217


PMC S p e c i a l t i e s Group 20525 Center Ridge Rd. Rocky R i v e r , OH 44116 (216)-356-0700

Raybo Chemical Co. P.O. Box 2155K H u n t i n g t o n , WV 25722

R e i c h h o l d Chemicals, I n c . P.O. Box 13582 Research T r i a n g l e Park, NC27709 (919)-990-7500/(800)-448-3482

Rheox, I n c . P.O. Box 700 H igh ts town, N J 08520 (609)-443-2500

Rhone-Poulenc I n c . Prospec t P l a i n s Rd. Cranbury, NJ 08512 (609)-860-4000

Rohm & Haas Co. Independence M a l l West P h i l a d e l p h i a , PA 19105 (215)-592-3000

Sanncor I n d u s t r i e s , I n c . 300 Whi tney S t . P.O. Box 703 Leomi n s t e r , MA 01 453 (508)-537-4748

SCM Chemical s 2701 Broen ing Hwy B a l t i m o r e , MD 21222 (301)-288-8884/(800)-638-3234

Shamrock Techno log ies , I n c . Foot o f P a c i f i c S t . Newark, NJ 07114

S h e l l Chemical Co. Two She1 1 P laza P . 0 . 8 0 ~ 1422 Houston, TX 77251

(201 )-242-2999

(EOO)-TEC-EPON

Sherwin W i 11 i ams Co. Chemi c a l s D i v . P.O. Box 6520 C leve land, OH 44101 (216)-566-2344

S i l b e r l i n e Mfg . Co. P.O. Box A Lans ford , PA 18232 (71 7) -668-6050

Sun Chemical Corp. 4526 C h i c k e r i n g Ave. C i n c i n n a t i , OH 45242 (513)-68l-5950/(800)-543-2323

3M Corp. 3M Center S t . Pau l , MN 55144 (61 2) -733-1 11 0

Tammsco, I n c . P . O . Box J Tamms, I L 62988

Tenneco M i n e r a l s Co. P.O. Box 281300 Lakewood, CO 80228 (303)-987-6200

Troy Corp. 72 Eag le Rock Ave. East Hanover, N J 07936 (201)-884-4300

U l t r a A d d i t i v e s , I n c . 460 S t r a i g h t S t . Paterson, NJ 07501 (201)-279-1306/(800)-524-0055

Unimin Corp. 258 E l m S t . New Canaan, CT 06840 (203)-966-8880/(800)-243-9004

UCAR Emu1 s i o n Systems 410 Gregson D r i v e Cary, NC 27511 (919)-469-6700


R.T . V a n d e r b i l t C o . . I n c . 30 W i n f i e l d S t . P . O . Box 5150 Norwalk, CT 06856 (203)-853-1400

V e l s i c o l Chemical Corp. 5600 N . R i v e r Rd. Rosemont, I L 60018 (708)-698-7000

Wacker S i l i c o n e s Corp. 3301 Sutton Rd. Adr ian , MI 49221 (517)-264-8500/(800)-248-0063

Whi t taker , C l a r k & D a n i e l s , I n c . 1000 Cool idge St. South P l a i n f i e l d , NJ 07080 (908)-561-6100/(800-732-0562

Witco Corp. 520 Madison Ave. New York , NY 10022 (212)-605-394l/(800)-238-9150

Education

Water-based paint formulations Vol. 4