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Engineering 112 Foundations of Engineering

02 chapter 11 thermodynamics

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Page 1: 02 chapter 11 thermodynamics

Engineering 112Foundations of Engineering

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Student Information Sheet

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Engineering Disciplines

Electrical Engineering Civil Engineering Mechanical Engineering Industrial Engineering Aerospace Engineering Chemical Engineering

Biomedical Engineering Materials Engineering Agricultural Engineering Nuclear Engineering Architectural Engineering Petroleum Engineering Engineering Technology

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Course Syllabus PurposeMaterialExamsGradingCourse Policies

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Objectives of ENGR 112

Develop a better understanding of enginesBecome a better problem solver Develop a mastery of unit analysisImprove your mathematics skills Prepare you for statics and dynamicsDevelop teaming skills

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Course Calendar

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A Brief History of EGR111/112

These courses were added to the curriculum at TAMU in the early 1990’s.

12 disciplines require these courses.The courses were first taught at SFA

starting in the Fall of 2002.They are part of an articulation agreement

with TAMU.They also transfer to other universities.

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Course Description

PHY108 Introduction to PHY/EGR

EGR111 Foundations I

EGR112 Foundations II

EGR215 Electrical Engineering

EGR343 Digital Systems

EGR250 Engineering Statics

EGR321 Engineering Dynamics

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CoursePre-EGR

DUAL Minor

PHY108

EGR111

EGR112

EGR215 ~ ~

EGR342 ~ ~

PHY250 ~

PHY321 ~

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Teaming Expectations

Many of the activities in ENGR 112 require collaboration with other class members

Each student will be assigned to a teamAll students will receive team training

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Before Wednesday…

Get a Note Book and Text BookDouble Check you Schedule

4th Class Day12th Class DayMid-Semester

Complete Problems 1 – 5 on HW1

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Can you boil water at room temperature?

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How can you design a room that is completely silent?

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Thermodynamics

Chapter 11

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Thermodynamics

Developed during the 1800’s to explain how steam engines converted heat into work.

Thought Questions:Is heat just like light and sound?Is there a “speed of heat”?

Answer: Not really.

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11.1 Forces of Nature

Gravity ForceElectromagnetic ForceStrong ForceWeak Force

Nuclear Forces

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Chapter 11 - Thermodynamics

11.1 - Forces of Nature

11.2 - Structure of Matter

11.3 - Temperature

11.4 - Pressure

11.5 - Density

11.6 - States of Matter

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11.2 Structure of Matter

ProtonsAtomic Number - number of protons

Neutronsnuclear glue

ElectronsValence Electrons - those far from the nucleus

Atoms, Molecules, and a LatticeAmorphous - random arrangement of atomsCrystal - atoms are ordered in a lattice

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Which is colder?

Metal or Wood?

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11.3 Temperature

Measured in Fahrenheit, Celsius, and Kelvin

Rapidly moving molecules have a high temperature

Slowly moving molecules have a low temperature

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Cool Hot

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What is “absolute zero”?

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Temperature Scales

Fahrenheit Celsius Kelvin

Boiling Pointof Water

Freezing Pointof Water

Absolute Zero

212F

32F

-459F

100C

0C

-273C

373 K

273 K

0 K

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11.4 Pressure

Pressure - force per unit area It has units of N/m2 or Pascals (Pa)

A

FP

F

A

Impact Weight

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Pressure

What are the possible units for pressure?N/m2

Pascal 1 Pa = 1 N/m2

atm 1 atm = 1 × 105 Papsi 1 psi = 1 lb/inch2

mm Hg 1 atm = 760 mm Hg

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11.5 Density

Density - mass per unit volumeIt has units of g/cm3

V

M

High densityLow density

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11.6 States of Matter

Solid Liquid

Gas Plasma

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State of Matter Definitions

Phase DiagramPlot of Pressure versus Temperature

Triple PointA point on the phase diagram at which all

three phases exist (solid, liquid and gas)

Critical PointA point on the phase diagram at which the

density of the liquid a vapor phases are the same

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Figure 11.8 - Phase Diagram

Plasma

Gas

Vapor

Liquid

Solid

Ttriple Tcritical

Ptriple

Pcritical

Pressure

Temperature

Critical Point

TriplePoint

Boiling

Condensation

Sublimation

Melting

Freezing

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Questions

Is it possible to boil water at room temperature? Answer: Yes. How?

Is it possible to freeze water at room temperature? Answer: Maybe. How?

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Gas Laws

Perfect (ideal) GasesBoyle’s LawCharles’ LawGay-Lussac’s LawMole Proportionality Law

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Boyle’s Law

2

12

1 V

V

P

P

T = const n = const

P1

V1

P2

V2

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Charles’ Law

1

2

1

2

T

T

V

VT1

V1

T2

V2

P = const n = const

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Gay-Lussac’s Law

1

2

1

2

T

T

P

PT1

P1

T2

P2

V = const n = const

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Mole Proportionality Law

1

2

1

2

n

n

V

V

T = const P = const

n1

V1

n2

V2

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Thermodynamics

Chapter 11Homework 1

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Boyle’s Law

2

12

1 V

V

P

P

T = const n = const

P1

V1

P2

V2

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Charles’ Law

1

2

1

2

T

T

V

VT1

V1

T2

V2

P = const n = const

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Gay-Lussac’s Law

1

2

1

2

T

T

P

PT1

P1

T2

P2

V = const n = const

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Mole Proportionality Law

1

2

1

2

n

n

V

V

T = const P = const

n1

V1

n2

V2

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Perfect Gas Law

The physical observations described by the gas laws are summarized by the perfect gas law (a.k.a. ideal gas law)

PV = nRTP = absolute pressureV = volumen = number of molesR = universal gas constantT = absolute temperature

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Table 11.3: Values for R

mol·Katm·L

mol·KPa·m3

08205.0

314.8

mol·K

cal

mol·K

J

1.987

314.8

Work Problem 11.8

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Thermodynamics

Chapter 11Movie R.A.T.

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RAT Movies

For the movies that follow, identify the gas law as a team.

Only the recorder should do the writing.

Turn in the team’s work with the team name at the top of the page.

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Balloon Example (Handout)

A balloon is filled with air to a pressure of 1.1 atm.

The filled balloon has a diameter of 0.3 m. A diver takes the balloon underwater to a

depth where the pressure in the balloon is 2.3 atm.

If the temperature of the balloon does not change, what is the new diameter of the balloon? Use three significant figures.

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Volumes?

CubeV=a3

SphereV=4/3 r3

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33

2

112

2

131

32

31

3

11

32

3

22

2

112

2

1

1

2

atm 3.2

atm 1.1 m 3.0

23

4

23

4

P

PDD

P

PkDkD

kDD

V

kDD

V

P

PVV

P

P

V

V

= 0.235 m

Solution

P1 = 1.1 atmD1 = 0.3 m

P2 = 2.3 atmD2 = ?

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Work

Work = Force Distance W = F x

The unit for work is the Newton-meter which is also called a Joule.

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Joule’s ExperimentJoule showed that mechanical energy could beconverted into heat energy.

F

M

xH2O

T

W = Fx

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Heat Capacity Defined

Q - heat in Joules or caloriesm - mass in kilogramsT - change the temperature in KelvinC has units of J/kg K or kcal/kg K1 calorie = 4.184 Joules

Tm

QC

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F

m

xH2O

T

Tm

QC

W = Fx 1 kcal= 4184 J

Problem 11.9

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Heat Capacity

An increase in internal energy causes a rise in the temperature of the medium.

Different mediums require different amounts of energy to produce a given temperature change.

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Myth Busters - Cold Coke

Do you burn more calories drinking a warm or cool drink?

How many calories do you burn drinking a cold Coke?Assume that a coke is 335ml and is chilled to

35F and is about the same density and heat capacity as water. The density of water is 1g/cm3.

1 kcal=4184 J 1ml=1cm3

The heat capacity of water is 1 calorie per gram per degree Celsius (1 cal/g-°C).

TC = (5/9)*(TF-32)

Tm

QC

http://en.wikipedia.org/wiki/Calorie

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Thermodynamics

Chapter 11

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11.11 Energy

Energy is the ability to do work.It has units of Joules.It is a “Unit of Exchange”.Example

1 car = $20k1 house = $100k5 cars = 1 house =

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11.11 Energy Equivalents

What is the case for nuclear power?1 kg coal » 42,000,000 joules1 kg uranium » 82,000,000,000,000

joules1 kg uranium » 2,000,000 kg coal!!

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11.11.3 Energy Flow

Heat is the energy flow resulting from a temperature difference.

Note: Heat and temperature are not the same.

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Heat Flow

T = 100oC

T = 0oC

Temperature Profile in Rod

HeatVibrating copper atom

Copper rod

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11.12 Reversibility

Reversibility is the ability to run a process back and forth infinitely without losses.

Reversible Process Example: Perfect Pendulum

Irreversible Process Example: Dropping a ball of clay

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Reversibility Movies of reversible phenomena

appear the same when played forward and backward.

IrreversibilitiesThe opposite is true.

“Movie Making”

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Reversible Process

Examples: Perfect PendulumMass on a SpringDropping a perfectly elastic ballPerpetual motion machinesMore?

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Irreversible Processes

Examples:Dropping a ball of clayHammering a nailApplying the brakes to your carBreaking a glassMore?

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Example: Popping a Balloon

Not reversible unless energy is expended

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Sources of Irreversibilities

Friction (force drops)Voltage dropsPressure dropsTemperature dropsConcentration drops

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First Law of Thermodynamicsenergy can neither be created

nor destroyed

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Second Law of Thermodynamicsnaturally occurring processes are

directionalthese processes are naturally

irreversible

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Third Law of Thermodynamicsa temperature of absolute zero is

not possible

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Heat into Work

Thot TcoldHeat

Engine

W

QhotQcold

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Carnot Equation: Efficiency

The maximum work that can be done by a heat engine is governed by:

hot

cold

hot

max

T

T

Q

WEfficiency 1

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What is the maximum efficiency that a heat engine can have using steam and an ice bath?

Team Exercise (3 minutes)

Thot TcoldHeat

Engine

W

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Work into Heat

Although there are limits on the amount of heat converted to work, work may be converted to heat with 100% efficiency.

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Chapter 12

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Heat Capacity for Constant Volume Processes (Cv)

Heat is added to a substance of mass m in a fixed volume enclosure, which causes a change in internal energy, U. Thus,

Q = U2 - U1 = U = m Cv TThe v subscript implies constant volume

Heat, Qaddedm m

Tinsulation

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Heat Capacity for Constant Pressure Processes (Cp)

Heat is added to a substance of mass m held at a fixed pressure, which causes a change in internal energy, U, AND some PV work.

Heat, Qadded

T

m m

x

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Cp Defined

Thus,Q = U + PV = H = m Cp T

The p subscript implies constant pressure

H, enthalpy. is defined as U + PV, so H = (U+PV) = U + VP + PV = U + PV

Experimentally, it is easier to add heat at constant pressure than constant volume, thus you will typically see tables reporting Cp for various materials (Table 21.1 in your text).

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Individual Exercises (5 min.)

1. Calculate the change in enthalpy per unit lbm of nitrogen gas as its temperature decreases from 1000 oR to 700 oR.

2. Two kg of water (Cv=4.2 kJ/kg K) is heated by 200 BTU of energy. What is the change in temperature in K? In oF?

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Solution

1. From table 21.2, Cp for N2 = 0.249 BTU/lbmoF.

Note that since oR = oF + 459.67, then T oR = T oF, so

2.

F2.45))K)( 1.52((

K 1.25

)2.4( kg 2

)055.1(BTU 200

Kin change 1Fin change 1.8

K kgkJ

BTUkJ

vmC

QT

Recall, we are referring to a temperature CHANGE

m

mp

lb

BTU 49.74

)F 300(Flb

BTU249.0TC

m

H

Page 80: 02 chapter 11 thermodynamics

Homework

Page 81: 02 chapter 11 thermodynamics

http://demoroom.physics.ncsu.edu/html/demos/88.html

Exercise

A stick man is covered with marshmallows and placed in a sealed jar.

What will happen to the marshmallow man when the jar is evacuated? Why?

Page 82: 02 chapter 11 thermodynamics

Solution

Click to activate, then click play Suggestion: view at 200%

marshmallow.mov

Page 83: 02 chapter 11 thermodynamics

Other Homework Questions

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What’s next?

Page 85: 02 chapter 11 thermodynamics

Example Problem

A cube of aluminum measures 20 cm on a side sits on a table.

Calculate the pressure (N/m2) at the interface.

Note: Densities may be found in your text.

A

FP

V

M

Page 86: 02 chapter 11 thermodynamics

L = 0.2 m

L = 0.2 m

L = 0.2 mA

FP

mgF 3LVm

2LA

Solution

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Heat/Work Conversions

Heat can be converted to work using heat enginesJet engines (planes)steam engines (trains)internal combustion engines

(automobiles)

Page 88: 02 chapter 11 thermodynamics

Team Exercise (2 minutes)

On the front of the page write down 2 benefits of working in a team.

On the back write down 1 obstacle that we must overcome to work in engineering teams.

You have two minutes…

Page 89: 02 chapter 11 thermodynamics

Why Teamwork

Working in groups enhances activities in active/collaborative learning

Generate more ideas for solutionsDivision of laborBecause that’s the way the real world

works!!Industry values teaming skills

Page 90: 02 chapter 11 thermodynamics

Why Active/Collaborative Learning

Activecountless studies have shown

improvement in:short-term retention of material,long-term retention of material,ability to apply material to new situations

Collaborativeby not wasting time on things you already

know we can make the best use of class time

Page 91: 02 chapter 11 thermodynamics

Teamwork Obstacles

What are some potential problems with teamwork? “I’m doing all of the work.”

Solution: It is part of your team duties to include everyone in a team project.

“I feel like I’m teaching my teammates.” Exactly. By explaining difficult concepts to your team members

your grasp of difficult concepts can improve.

“What if I don’t get along with my teammates.” Solution: This is a problem that all workers have at some point. The team may visit with the instructor during office hours to iron out

differences.

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Project One

The Rubber Band Heat Engine

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Example Problemsfrom Homework

Page 94: 02 chapter 11 thermodynamics

Let’s take notes…

Page 95: 02 chapter 11 thermodynamics

Boyle’s Law

2

12

1 V

V

P

P

T = const n = const

P1

V1

P2

V2

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Charles’ Law

1

2

1

2

T

T

V

V

T1

V1

T2

V2

P = const n = const

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Gay-Lussac’s Law

1

2

1

2

T

T

P

P

T1

P1

T2

P2

V = const n = const

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Mole Proportionality Law

1

2

1

2

n

n

V

V

T = const P = const

n1

V1

n2

V2

Page 99: 02 chapter 11 thermodynamics

Problems

Homework 1111213

In-class AssignmentProblem 1

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Problems

Homework 114

In-class AssignmentProblem 2