Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex 11- United Kingdom (UK)
SAFETY DATA SHEET HARDENER HW 2934
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier
Product name Product code Product description
HARDENER HW 2934 00048074 Not available.
1.2 Relevant identified uses of the substance or mixture and uses advised against Product use : Hardener for adhesive systems
1.3 Details of the supplier of the safety data sheet Supplier Huntsman Advanced Materials (Europe)BVBA
Everslaan 45
e-mail address of person responsible for this SDS
3078 Everberg I Belgium Tel. : +41 61 299 20 41 Fax: +41 61 299 20 40 Global_ Product_ EHS [email protected]
1.4 Emergency telephone number Supplier Telephone number EUROPE: +32 35 75 1234
France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300
I SECTION 2: Hazards identification 2.1 Classification of the substance or mixture
Product definition : Mixture Classification according to Directive 1999/45/EC [DPDJ
HUNTSMAN
The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification R43
R52/53 Human health hazards May cause sensitisation by skin contact.
Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements Hazard symbol or symbols
Indication of danger Irritant
Date of issue I Date of revision : 8 September 2011 1113
Conforms to Regu lation (EC) No. 1907/2006 (REACH), Annex II United Kingdom (UK) HARDENER HW 2934 Date of printing Date of issue
: 8 September 2011 : 8 September 2011
MSDS no. Version
SECTION 2: Hazards ident ification Risk phrases R43- May cause sensitisation by skin contact.
00048074 1.02
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases S2- Keep out of the reach of children. S24- Avoid contact with skin . S37- Wear suitable gloves. S46- If swallowed, seek medical advice immediately and show this container or label.
Hazardous ingredients Supplemental label elements
N(3-dimethylaminopropyl)-1,3-propylenediamine Not applicable.
Special packaging reguirements Containers to be fitted : Not applicable. with child-resistant fastenings Tactile warning of danger Not applicabte.
2.3 Other hazards Other hazards which do : Not available. not result in classification
I SECTION 3: Composition/information on ingredients Substance/mixture : Mixture
Classification Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No.
name 1272/2008 [CLP] triethylene glycol CAS: 14970-87-7 1 - 3 Xn; R20/22 Acute Tox. 4, H302 dimercaptan N, R51/53 N; R51/53 Acute Tox. 4, H332
Aquatic Chronic 2, H411
N(3- CAS: 1 0563-29-8 1 - 3 Xn; R21 /22 Acute Tox. 4, H302 dimethylaminopropyl)- C; R34 Acute Tox. 4, H312 1 ,3-propylenediamine R43 Skin Corr. 18, H314
Eye Dam. 1, H318 Skin Sens. 1, H31 7
2,4,6- CAS: 90-72-2 1 - 3 Xn;R22 Acute Tox. 4, H302 tris(dimethy1aminomethy1)phenol Xi; R36/38 Skin lrrit. 2, H315
Eye lrrit. 2, H319 4-dimethylaminoethyl- CAS: 1 04-19-8 1 3 T; R24 Acute Tox. 4, H302 1-methyl-4-piperazine Xn ; R22 Acute Tox. 3, H311
C; R34 Skin Corr. 16, H314 Eye Dam. 1, H318
n-butyl acetate CAS: 123-86-4 1 - 3 R10 Flam. Liq . 3, H226 Index: 607-025-00-1 R66,R67 STOT SE 3, H336
See section 16 for See Section 11 for the the full text of the R- full text of the H phrases declared statements declared above above.
Type
[1]
[1]
[1)
[1]
(1] (2]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
~
I Date of Issue I Date of revision 8 September 2011 2113]
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II- United Kingdom (UK) 3/13
]H.IJ.RDENER HW 2934 Date of printing 8 September 2011 MSDS no. 00048074
1.02 Date of issue 8 September 2011 Version
SECTION 3: Composition/information on ingredients [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XII I Occupational exposure limits, if available, are listed in Section 8.
I SECTION 4: First aid measures 4.1 Description of first aid measures
Eye contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 1 0 minutes. Get medical attention if irritation occurs .
Inhalation
Skin contact
Ingestion
Protection of first-aiders
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie , belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects
Eye contact No known significant effects or critical hazards. Inhalation Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure. Skin contact Ingestion
May cause sensitisation by skin contact. No known significant effects or critical hazards.
Over-exposure signs/symptoms Eye contact No specific data. Inhalation Skin contact
Ingestion
No specific data. Adverse symptoms may include the following: irritation redness No specific data.
Date of issue I Date of revision : 8 September 2011 3113