i
Mendeleev Communications
CONTENTS
VOLUME 17 NUMBER 1 2007 MENCEX (1) 1–56 (2007)
1 Structural and optical properties of titania photonic crystal films prepared by a sol–gel method
Alexander S. Sinitskii, Vera V. Abramova, Yuri D. Tretyakov
1 µm
4 Optical study of photonic crystal films made of polystyrene microspheres
Alexander S. Sinitskii, Pavel E. Khokhlov, Vera V. Abramova, Tatyana V. Laptinskaya, Yuri D. Tretyakov
7 Kinetic models of the prebiological evolution of macromolecules. Thermocycle as the motive force of the process
Sergei D.Varfolomeev
Autocatalyticexplosion
1
21
10 Synthesis of two lipopentasaccharides related to the nodulation factors of the nitrogen-fixing bacterium Rhizobium sp. NGR 234
Sergey L. Sedinkin, Alexander I. Zinin, Nelli N. Malysheva, Alexander S. Shashkov, Vladimir I. Torgov, Vladimir N. Shibaev
X = OH, β-OMe
O
O OMe
OAcOH
Me
O
NHAcX
OH
O
NHAc
OHO
OH
O
NH
OHO
O
HOHO
2
14 Synthesis of a cycloimide bacteriochlorin p conjugate with the closo-dodecaborate anion
Mikhail A. Grin, Andrey A. Semioshkin, Rustam A. Titeev, Evgeniya A. Nizhnik, Julia N. Grebenyuk, Andrey F. Mironov, Vladimir I. Bregadze
NH N
N HN
O
N OO
HN
Me HH
Et
HMe
H
CO2Me
O
O
O
2–
2Bu4N+
ii
16 Nanostructured Ba6Mn24O48 whiskers
Ekaterina A. Pomerantseva, Marina G. Kozlova, Kirill V. Didenko, Alexander G. Veresov, Eugene A. Goodilin, Yuri D. Tretyakov
1 µm
18 Mass-spectrometric study of the solid-phase reaction of Na4XeO6·8H2O with U(SO4)2·4H2O
Larisa N. Khazimullina, Evgenii G. Galkin, Alexander V. Mamykin, Ivan G. Tananaev, Valerii P. Kazakov, Boris F. Myasoedov
100
80
60
40
20
0 2 4 6 8 10t/min
Inte
nsity
(ar
bitr
ary
units
)
20 Asymmetric hydrogenation of the C=O bond with the recycling of an organometal catalyst deposited on a solid organic polyelectrolyte
Eugenia V. Starodubtseva, Olga V. Turova, Maxim G. Vinogradov, Vladimir A. Ferapontov, Ilya V. Razmanov, Sergei G. Zlotin, Alexander S. Kucherenko
COOMe
O
H2 /RuII–BINAP–HCl
O O*
98–99% ee
N
H2C CH2
X
X = Cl, BF4, PF6
n
22 Polyether-functionalised uridine as an ion receptor
Jan Milecki, Grzegorz Schroeder
OOH
HO OH
N
N
O
O
O
O
OH...
M+
OOH
HO OH
N
N
O
O
M+
O
O
OH
...
OOH
HO OH
N
N
O
O
M+
H O
O
O
...
25 The first application of the Friedländer reaction for the synthesis of [1,8]naphthyridine derivatives containing phosphorus
Georgy V. Bodrin, Pavel S. Lemport, Sergey V. Matveev, Pavel V. Petrovskii, Edward E. Nifant’ev
PPh2XRO N N
PPh2
RXN
CHO
NH2
+Catalyst
Solvent
27 Semi-synthesis of deoxyartemisinin
Asish K. Bhattacharya, Ashish K. Pathak, Ram P. Sharma
O
O
H
OO
O
O
O
H
O
O
Al–NiCl2·6H2O/THFor Ni2B/MeOH
iii
29 Hydrogen bonding- and stacking-induced stereospecific [2 + 2]-photocycloaddition within a pseudodimeric complex of two styryl dyes
Artem I. Vedernikov, Sergey K. Sazonov, Pavel S. Loginov, Natalia A. Lobova, Mikhail V. Alfimov, Sergei P. Gromov
NEtO O
O
O
O
O
N
MeO
MeO
NH
HH
N
N
MeO
MeO
Et
OO
O
O
O
O
HN
H
H
hv
32 Enhanced photo and thermal oxidative stability of the charge-transfer complexes of a conjugated polymer
Sergei A. Arnautov, Elena M. Nechvolodova, Sergei M. Lomakin, Alexander N. Shchegolikhin
MEHPPV-51MEHPPV
Mas
s lo
ss (
wt%
)
T/°C
60
50
40
30
20
10
050 60 70 80 90 100 110 120 130 140 150
34 Synthesis and optical properties of linear and branched bithienylsilanes
Elena A. Shumilkina, Oleg V. Borshchev, Sergey A. Ponomarenko, Nikolay M. Surin, Alexandra P. Pleshkova, Aziz M. Muzafarov
SS
Me4 – xSix
x = 1–4
37 Porphyrin dimers and their interaction with DNA
Kai Wang, Shi-tao Fu, Lei Wu, Zao-ying Li
R
R
N C
OHN
R
R
R
NC
OHN
I–
I–
R
40 Unexpected formation of 4-methyl-1-vinyl- -carboline in the reaction of 3-acetylindole oxime with acetylene
Boris A. Trofimov, Elena Yu. Schmidt, Albina I. Mikhaleva, Nadezhda V. Zorina, Igor A. Ushakov, Andrey V. Afonin, Alexander M. Vasil’tsov
δδ
N
Me
NOH
H
N
HC CH
KOH/DMSO, 120 °C,
20–25 atm, 1 h
NMe
40%
N
6%
N
+
43 Microwave-induced protection and deprotection of 4-oxo-(4H)-1-benzopyran-3-carbaldehydes catalysed by Envirocat EPZ10R
Santosh S. Shindalkar, Balaji R. Madje, Murlidhar S. Shingare
O
R1
R2
R3
O
O
O
R1
R2
R3
O
OAc
OAc
EPZ10, Ac2OMW, 300 W
EPZ10 MW, 800 W
iv
45 Vapour-phase extraction for the isolation of organic compounds from aqueous solutions
Victor N. Bekhterev, Elena A. Kabina
6420
–2–4–6–8
–10
ln K
eq
acid
7
LE (n-C5H11OH)
VPE (EtOH)
GE (N2)
C2C3 C4
C5
C6
C2
C3
C3
C4C5
C5
C6
y = 1.2383x – 2.6283R2 = 0.9999
y = 0.7202x – 2.2959R2 = 0.9576
y = 0.3004x – 8.0034R2 = 0.9771
48 Coupling of 1,2-bis(alkoxyamino)cyclohexanes with 1,3-dicarbonyl compounds: first synthesis of 1,4-dialkoxy-2,3-dihydro-1,4-diazepinium salts
Evgenii A. Mostovich, Dmitrii G. Mazhukin, Yurii V. Gatilov, Tatyana V. Rybalova
NHOR
NHOR
OH
R1R3
O
R2
N
N
RO
RO
R1
R2
R3
XOH
HH
O
R2
N
N
OR
OR
CHPh
2EtOH, HX
(X = Cl, ClO4)room temperature24–96 h, 63–93%
EtOH, room temperature
24–96 h, 42–61%
51 Synthesis of substituted 2-hydroxyaryl aldehydes by the microwave-induced Reimer–Tiemann reaction
Yeshwant B. Vibhute, Subhash M. Lonkar, Mudassar A. Sayyed, Mohammad A. Baseer
R
OHR1
R2
+ CHCl3NaOH, [H2O:EtOH]
MWI
R
OHR1
R2 CHO
52 Stereoselective synthesis of N-unsubstituted pyrazolidines from 3-nitro-2-trichloromethyl-2H-chromenes and hydrazine hydrate
Vladislav Yu. Korotaev, Igor B. Kutyashev, Vyacheslav Ya. Sosnovskikh, Mikhail I. Kodess
R
O
NO2
CCl3
OH HN NH
NO2
CCl3
R
N2H4
R = H, MeO, Br
AUTHOR INDEXAbramova, Vera V., 1, 4Afonin, Andrey V., 40Alfimov, Mikhail V., 29Arnautov, Sergei A., 32Baseer, Mohammad A., 51Bekhterev, Victor N., 45Bhattacharya, Asish K., 27Bodrin, Georgy V., 25Borshchev, Oleg V., 34Bregadze, Vladimir I., 14Didenko, Kirill V., 16Ferapontov, Vladimir A., 20Fu, Shi-tao, 37Galkin, Evgenii G., 18Gatilov, Yurii V., 48Goodilin, Eugene A., 16Grebenyuk, Julia N., 14Grin, Mikhail A., 14Gromov, Sergei P., 29Kabina, Elena A., 45Kazakov, Valerii P., 18Khazimullina, Larisa N., 18Khokhlov, Pavel E., 4
Kodess, Mikhail I., 52Korotaev, Vladislav Yu., 52Kozlova, Marina G., 16Kucherenko, Alexander S., 20Kutyashev, Igor B., 52Laptinskaya, Tatyana V., 4Lemport, Pavel S., 25Li, Zao-ying, 37Lobova, Natalia A., 29Loginov, Pavel S., 29Lomakin, Sergei M., 32Lonkar, Subhash M., 51Madje, Balaji R., 43Malysheva, Nelli N., 10Mamykin, Alexander V., 18Matveev, Sergey V., 25Mazhukin, Dmitrii G., 48Mikhaleva, Albina I., 40Milecki, Jan, 22Mironov, Andrey F., 14Mostovich, Evgenii A., 48Muzafarov, Aziz M., 34Myasoedov, Boris F., 18
Nechvolodova, Elena M., 32Nifant’ev, Edward E., 25Nizhnik, Evgeniya A., 14Pathak, Ashish K., 27Petrovskii, Pavel V., 25Pleshkova, Alexandra P., 34Pomerantseva, Ekaterina A., 16Ponomarenko, Sergey A., 34Razmanov, Ilya V., 20Rybalova, Tatyana V., 48Sayyed, Mudassar A., 51Sazonov, Sergey K., 29Schmidt, Elena Yu., 40Schroeder, Grzegorz, 22Sedinkin, Sergey L., 10Semioshkin, Andrey A., 14Sharma, Ram P., 27Shashkov, Alexander S., 10Shchegolikhin, Alexander N., 32Shibaev, Vladimir N., 10Shindalkar, Santosh S., 43Shingare, Murlidhar S., 43Shumilkina, Elena A., 34
Sinitskii, Alexander S., 1, 4Sosnovskikh, Vyacheslav Ya., 52Starodubtseva, Eugenia V., 20Surin, Nikolay M., 34Tananaev, Ivan G., 18Titeev, Rustam A., 14Torgov, Vladimir I., 10Tretyakov, Yuri D., 1, 4, 16Trofimov, Boris A., 40Turova, Olga V., 20Ushakov, Igor A., 40Varfolomeev, Sergei D., 7Vasil’tsov, Alexander M., 40Vedernikov, Artem I., 29Veresov, Alexander G., 16Vibhute, Yeshwant B., 51Vinogradov, Maxim G., 20Wang, Kai, 37Wu, Lei, 37Zinin, Alexander I., 10Zlotin, Sergei G., 20Zorina, Nadezhda V., 40
54 Conference Calendar
55 Notice to Authors