Mater ia l Sa fe ty Data Shee t
Product Name
Product Code{s}
UN-No
Recommended Use
Company
Company Emergency Phone Number Emergency Telephone Number
•"O-^ Urt* l o ' i n n r t | , - y ! - = - n . J - p - h —
1. PRODUCT AND COMPANY IDENTIFICATION
CAUTION!
Appearance Black
AC-<S251 Black Class B Base
AC-251 Black Class B Base
Not regulatKi
Sealant.
Advanced Chemistry 8> Technology, Inc. 7341 Anaconda Avenue Garden Grove, CA 92841
714-373-2837 (8 AM to 5 PM Pacific)
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION
Emergency Overview May cause skin, eye, and respiratory tract irritation
Physical State Paste/Gel Odor Sulphurous
OSHA Regulatory Status
Potential Health Effects Principle Routes of Exposure
Acute Toxicity Eyes Skin inhalation Ingestion
Chronic Effects
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin contact. Inhalation, Eye contact
Contact with eyes may cause irritation. May cause irritation. May cause irritation of respiratory tract. Ingestion may cause imtation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
Repeated or prolonged skin cxintact may cause skin irritation and/or dermatitis and sensitization of susceptible pereons.
A§gra¥ated Medical Condltlorss Skin disorders. Lr er disoi^^s. Kidney disordsm. Altergies.
3. COMPOSITION.INFORMATION ON INGREDIENTS
AC-^51 Black Class B Base Revision Date December 23, 2009
Caldum carbonate Phenol
Formaldehyde Carbon black
471-34-1 108-95-2 50-00-0
~~~'""~~"~~^"^'ni^S;8&4 ~"^~—^-1
30-40 .001-.004
.0001-0.004 0.1-0,5
Eye Contact
Skin Contact
inhalation
ingestion
Notes to Physician
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Get medical attention immediately if symptoms occur.
Wash skin with soap and water.
Administer oxygen if breathing is difficult and you are trained. Apply artificial respiration If victim is not breatiiing.
Do not induce vomiting without medical advice. Consult a physician.
Treat symptomaticaNy.
S. FIRE-FIGHTING MEASURES
Flash Point Method
Suitable Extinguishing Media
Hazardous Combustion Products
Explosion Data Sensitivify to Mechanical Impact Sensitivity to Static Discharge
Protective Equipment and Precautions for Firefighters
> 93 °C / > 200 T Ctos^ cup
Use:. Water spray. Cafton dioxide (CO2). Dry chemical.
Carbon monoxide, Cart)on dioxide (COE). Sulfur oxides. Nitrogen oxides (NOx), Aldehyde
Not impact sensitive. Not sensitive.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NiOSH (approved or equivalent) and full protective gear.
NFPA Health Hazard 1 Flammabillty 1 Stability 0 Physical and Chemical Hazards N/A
Personal Precautions
Methods for Containment
6. ACCIDENTAL RELEASE MEASURES
Avoid contact with the skin and the eyes. Use personal protective equipment. Ensure adequate ventilation. Refer to Sections.
Contain and col!s:t spillage with non-combustible absorbent materia!, (e.g. sand, earth, diatoma<^ous earth, vemiiculite) and place in container for disposal aaxirding to local /
7. HANDLING AND STORAGE
wash contaminated clothing before re-use, Do not smoke,
sp at temperatures below 28''C.. Keep out of ttie reac^ of chj;
AC-^SI Black Class B Base Revision Date December 23, 2009
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Chemical Name Catcium carbonate
471-34-1 Phenol 108-95-2
Fomialdehyde 50-00-0
Carton btack 1333-86-4
ACGfH TLV
TWA: 5 ppm
TWA: 3.5 mg/m^
OSHA PEL TWA; 5 mg/m^ TWA-ISmg/m*
TWA: 5 ppm TWA: 19 mg/m^
TWA: 0.75 ppm
TWA: 3.5 mg/m'* (vacated) TWA: 3.5 mg/m^
L NIOSH iDLH TWA: 5 mg/m^ TWA: lOmq/m^ IDLH: 250 ppm
Ceiling: 60 mg/m^ Ceiling: 15.6 ppm
TWA: 5 ppm TWA: 19 mq/m^ IDLH: 20 ppm
Ceiling: 0.1 ppm TWA: 0.016 ppm
IDLH: 1750mg/m= TWA: 0.1 mg/m-' TWA: 3.5rmlm^
Engineering Measures
Personal Protectiye Eguiprnent Eyeff^ace Protection Skin and Body Protection Respiratory Protection
Hygiene Measures
Showers, eyewash stations, and ventilation systems.
Safety glasses with side-shields. Wear protective gloves/clothing. Maintain adequate ventilation.
Do not eat, drink or smoke when using this product. Remove and wash (X)ntaminated clothing before re-use. General industrial hygiene practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical State Flasii Point Autoignltion Temperature
Explosion Limits
Specific Gravit/
Evaporation Rate Vapor Density Actual VOC (Ib/ga!) EPA VOC (g/l)
Btack Paste/Get > 93 "C / > 200 T No data available
No information available
1.61 glee
No information available No infonnatlon available. 0,07
Odor pH Method Boiling Point/Range Flammabiiity Limi^ in Air
Solubility
Vapor Pressure Weight per Gallon (lbs) EPA VOC (lb/gat) Viscosity
Sulphurous No data available Closed cup Not applicable No infotmation available
Soluble in aromatic hydrocarbons and ketones No information available 13.41 0.07 Thixotropic paste
10. STABILITY AND REACTIVITY
Stability Stable under norma! conditions.
j m
1 1 . TOXICOLOGICAL INFORMATION
AC-€a51 Black Class B Base Revision Date December 23, 2009
Acute Toxicity
Product Information
Irritation
The product ifeelf has not been t e s t ^ . May be harmful if swallowed.
Moderately irritating to eyes, skin and respiratory system.
Chemicaf Name Calcium carbonate
Phenol
Formaldehyde
Carbon blade
LD50 Oral 6450 mg/kg ( Rat)
31?mg/kg (Rat)
100mgfl<g (Rat)
15400 mgjkg { Rat)
UJSO Dermal
525 mg/kg ( Ral) 630 mq/kq { Rabbit) 270mg/kg (Rabbit)
3 g/kg { Rabbit)
LC50 inhalation
0,578mg/L (Ra t )4h 250 ppm (Rat )4h
Chronic Toxicity
Chronic T o x i c i ^
Carcinogenicity
Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Cliemlcal Name \ ACGIH Fomialdehyde 1 A2
i Carbon black j
lARC Group 1
Group 2B
NTP Reasonably Anticipated
OSHA X
X
Target Organ Effects Liver, Kidney, Skin
12. ECOLOGICAL INFORMATION
Ecotoxicity This product contains an ingredient that is classified, acxx)rding to European regulations, as "harmful to aquatic organisms, may cause long-term adverse effects In the aquatic environment".
Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea)
Phenol EC50=150mg/L96h LC50 5 -12 mg/L Oncorhynchus mykiss 96 h LC50= 23-88 mg/L Lepomis
macroctiirus 96 h LC50= 24 mg/L Pimephales
promelas % h LC50- 27.8 mg^
Brachydanlo rerio 96 h LCK3= 40 mg/L Pc^dlia
reticulata 96 h LC50= S.g mg/L
lus mylcfss 96 h
EC50 21-36 mg/L 30 min EC50 = 23.28 mg/L 5 min EC50 = 25.61 mg/L 15 min EC50 = 2a.8mg/L5min
EC5Q = 31.6 mg/L 15 min
LC50 = 13mg/L48h EC50 = 23.0 mg/L 48 h
Chemicai Name
AC-€S!51 Black Class B Base Revision Date December 23, 2009
= 1,47 ^onnafdehyde = 0,35 25 X
Waste Disposal Method Dispose of contents/container in accordance with local regulation.
Chemical Name
Calcium carijonate! - 471-34-1
Phenol - 108-95-2 Formaldehyde - 50-00-0
Carbon black-1333-86-4
RCRA • Haiogenated Organic Compounds
RCRA - P Series Wastes RCRA-F Series Wastes RCRA - K Series Wastes
Chemicat Name PhencJ
Fomialdehyde
CaltfcH-nia Hazardous Waste Stetus Toxic; Corrosive Toxic; iqnitable
DOT UN-No
lATA
IMDG/IMO
Not regulated Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA DSL EINECS/ELINCS ENCS lECSC KECL PICCS AlCS
U.S. Federal Regulations
Complin Complies Complies Complin Complies Complies Complies Complies
SARA 313 Section 313of Title ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations,
Acute Health Hazard Chronic Health Hazard Fire Hazard
Yes
AC-®251 Black Class B Base Revision Date December 23, 2009
Sudden Release of Pressure Hazard Reactive Hazard
No
Clean Water Act Component
Phenol 108-95-2 ( .001-004)
Formaldehyde 50-00-0 ( .0001-0,004 )
CWA - Reportable Quantities
10001b
1001b
CWA - Toxic Pollutents CWA-Priority Pollutants: CWA - Hazardous 1 Substances
X X X
X
Chemical Name
Pheni^
Formaldehyde
CAS-No
108-95-2
50-00-0
Weight %
.001-004
.0001-0.004
HAPS data
Present
Present
VOC Chemicals
Group III
Group!
Class 1 Ozone ! Class 2 Ozone Deptetors ; Depletors
CERCLA
Chenric^ Name Phenc^
Formaldehyde
Hazardous Substences RQs 10001b
1001b
Extremely Hazardous Substances RQs 10001b
1001b
U.S. State Regulations
California Proposition 65 This product contains the following Proposition 65 chemicals:
Chemical Name i CAS-No Fomialdehyde
CartKjn black
50-00-0
1333-86-4
California Prop. 65 Carcinogen
Carcinogen
Chemical Name Caldum cartjonate
Phenol
Formaldehyde
Carbon blade
Massachusetts X
X
X
X
New Jersey Pennsvlvania
! ^
X
X
X
X
X
X
illlnots
X
X
X
Rhode Island X
X
X
X
International Regulations
Mexico - Grade Slight risk, Grade 1
Carcinogen Stattis Exposure Limits Mexico. TV-JA---- 10
Mexico: TWA" 5 ppm Mexfcp: TWA= 18 rf^m^
Mexico. TWA= 3.5 mg/m^ . Mexico; STEL= T mg/m^
Canada
AC^251 Biack Class B Base Revision Date December 23. 2009
This product has been classified tn acconjance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class D2A Very toxic materials D2B Toxic materials
© Ch^TiIca) Name
Phend Formaldetiyde
NPRi X X
OTHER INFORMATION
NFPA HMiS PPE Transpor t Symbo l
K 'Rd l l l Hrtxj^-;-
1 --mi R^AcUvity
1
1
0
Not regulated
Prepared By David Jordan Director of R&D
Issuing Date
Revision Date
Revision Note
December 24, 2009
December 23, 2009
(M)SDS sections updated. 1. 16.
Disclaimer The information provided on tiiis SOS is correct to the best of our Itnowtedge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless speci^ed in tiie text
Material Safety Data Sheet
U.n., T A I r t T l f t
Product Name
Product Code{s}
UN-No
Recommended Use
Company
Company Emergency Phone Number Emergency Telephone Number
F*i---!-si-— p-i*<- n « « « ~ . u ^ , -Ti n n n n P^.^.!-.!-,^ I J - . ^ t ^^^
1. PRODUCT AND COMPANY IDENTIFICATION
AC-®251 Catalyst
AC-251 Blacl< and Gray Catalyst
Not r^utated
Hardener.
Advanced Chemistry & Technology, Inc. 7341 Anaconda Avenue Garden Grove, CA 92841
714-373-2839 (8 AM to 5 PM Pacific)
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION CAUTION!
Emergency Overview May be hannfui if inhaled
May cause skin, eye, and respiratory tract irritation May be harmftjl if swallowed
Appearance Viscous liquid, Blacic Physical State Viscous liquid Odor Sligtit
OSHA Regulatory Stetus
Potential Health Effects Principle Routes of Exposure
Acute Toxicity Eyes Skin inhalation ingestion
Chronic Effecte
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Eye contact, Skin contact. Ingestion
May cause slight imtation. Substance may cause slight skin irritation. May cause irritation of respiratory tract. May be harmful if swrallowed.
Repeated or prolonged si in cont^jt may cause skin irritation and/or dermatitis and
Environmental Hmax4 May cause long-temi adveree etf^ts in the aquatic environment.
3. COMPOSITION INFORMATION ON INGREDIENTS
AC-msi Catal^t Revision Date December 23. 2009
Chemical Name Hydrcigenated tetphenyis
Terphenyis Manganese dioxide
Cartx)n black
CAS-No 61788-32-7 26140-60-3 1313-13-9 1333-86-4
^"^"^"""^w^iiiszizir^ 35-40 1 -5
45-50 1 -5
Eye Contect
Skin Contect
Inhalation
Ingestion
Notes to Physician
Protection of First-aiders
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye invitation persists, consult a specialist.
Wash off immediately with soap and plenty of water, (f skin irritation persists, call a physician. Remove and wash cxjntaminated clothing before re-use.
Move to fresh air. If symptoms peralst. rail a physician, if breathing is irregular or stopped, administer artificiaf respiration.
Do not induce vomiting wittiout medical advice. Consult a physician. Never give anytfting by mouth to an unconscious person.
Treat symptomatically.
Avoid contact with skin, eyes and clothing.
Flash Point Method
Suitebte Extinguishing Media
Hazardous Combustion Producte
Explosion Data Sensitivity to Mechanical Impact Sensitivity to Stetic Discharge
> 1 1 0 X />230°F Closed ojp
Dry chemical, CO2. water spray or aicohol-resistant foam.
Carbon oxides. Cartoon monoxide. Carbon dioxide (CO2)
Not sensitive. Not sensitive.
Specific Hazards Arising from the Chemicat in the event of fire and/or explosion do not breathe fumes. Do not allow run-off from fire fighting to enter drains or water courees.
Protective Equipment and Precautions for Firetightets As in any fire, wear s€^-a)ntained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fui! protective gear.
NFPA Health Hazard 1 Flammabili^ 1 Stability 0 Physical and Cfiemlcal
6. ACCIDENTAL RELEASE MEASURES
diatomaceous earth, vemiicuiite) and place in container for dispcsa! according to ICK^I / national regulations (see Section 13).
AC-®251 Catai^t Revision Date Etecemiber 23, 2009
Methods for Cleaning Up Prevent product from entering drains. Take up medianicalty and collect in suitable container for disposal. Use personal prot^tive equipment.
Handling
Storage
Wear personal protective equipment. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminate clothing before re-use.
Keep tightly closed in a dry and cool place. K^p away from heat and sources of ignition. Keep at temperatures below 28°C..
Chemical Name Hydrogenated terphenyis
6178&-32-7 Terphenyis 26140-60-3
Manganese dioxide 1313-13-9
Carixjn black 1333-86-4
ACGIH TLV TWA: 0.5 ppm
TWAr 0.2 mg/m^
TWA: 3.5 mg/m^
OSHA PEL (vacated) TWA: 0,5 ppm {vacated) TWA: 5 mq/m^
(vacated) Ceifing: 0.5 ppm (vacated) Ceiling: 5 mglnr
Ceiling: 1 ppm Ceiling: Qmq/m^
(vacated) Ceiling; 5 mg/m^ Ceiling: 5 mg/m^
TWA: 3.5 mginf (vacated) TWA: 3.5 mg/m^
NIOSH IDLH TWA; 0.5 ppm TWA; 5 mq/m^
IDLH; 500 mg/m^
IDLH; 500 mg/m^ TWA: 1 mg/m^ STEL: 3 mq/m^
IDLH: 1750 mg/m' TWA; 0,1 mg/m^ TWA: 3.5 mq/m^
Engineering Measures
Pereonal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection
Hygiene Measures
Showera Eyewash stations Ventilation systems.
Safety glasses with side-shiefds. Wear protective gloves/ctothing. Wear latex or Nitrite gloves. If exposure limits are exceeded or in-itation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratoiy protection must be provided in accordance with current local regulations.
Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and glov^, including the inside, before re-use. Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical State Flash Point Autoignltion Temperatum
VisoDus liquid Black ViSOTus liquid >110°C / > 2 3 0 T No information avai
Odor pH Method Boiling Point/Range Flammabilft/ Limite in Air
Slight Not applicable Closed cup Not applicable No information
10. STABILITY AND REACTIVITY
AC-(§a51 Catalyst Revision Date December 23,2009
Stebility
Incompatible Products
Conditions to Avoid
Stable.
Adds. Strong reducing agents.
Excessive heat.
Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Thermal decomposition can lead to release of irritating gases and vapors.
Hazardous Reactions
Hazardous Polymerization
Acute Toxicity
Product Information
None under normal processing.
Hazardous polymeri^ion does not occur.
1 1 . TOXICOLOGICAL INFORMATION
Product does not present an acute toxicity hazard based on known or supplied information.
Chemical Name JHydrogenated terphenyis_
Terphenyis
LD50 Oral J02.0P mg/kg_ lRatJ_
__ LD50 Dermal _ 6800 mg/kg ( Rabbit} 12500mgftg (Rabbit)
LC5Q Inliaiation^ 4.3mq/L7"Rat"}4h
Manganese dioxide 9000 mg/kg { Rat) Carbon black 15400 mgfl g (Rat) 3g/kg (Rabbit)
Chronic Toxicity
Chronic Toxicity
Carcinogenicity
Repeated or prolonged skin contact may cause sidn irritation and/or dermatitis and sensitization of susceptible persons.
The table below indicates whether each agency has listed any ingredient as a carcinc^en.
Cheirricai Name Carbon biack
ACGIH lARC Group 2 B ^ ^ |
NTP OSHA X
Legend: lARC: {International Agency for Research on Cancer) GnDup 2B - Possibly Carcinogenic to Humans
Target Organ Effects Liver, Kidney, Skin, Central nervous s retem (CNS)
Ecotoxicity The environmental Impact of this
12. ECOLOGICAL INFORMATION
LC^> 0.53 mgA-Onajrti^fffihus mykiss 96 h
LC50> 0.53 mg/L Prmephates promejas 96 h
AC-®251 Catalyst Revision Date December 23. 2009
Terphenyis
CartMn t^ack
EC50 = 0,02 mg/L 96 h LC50> 0.11 mg/L Lepomis maaochirus 96 h LC5O0-11 mqH.
OncoftiyncSius mykiss 96 h LC50>0.11 mg^
Pimeti^aies promelas 96 h 1
EC50> 0.11 mg/L 48 h
EC50 > 5600 mg/L 24 h
Persistence and Degradability No data is available on the product itself.
_Chemicai Name Manganese dioxide
LoflPow <0 20 "C
.13. DISPOSAL CONSIDERATIONS
Waste Disposal Method Dispose of in accordance with local regulations.
Contaminated Packaging Dispose of in accordance with local regulations.
Chemical Name
Hydrogenated terphenyis -61788-32-7
Terphenyis - 26140-60-3 Manganese diOJdde -1313-
13-9 Carbon black -1333-86-4
RCRA • Halogenated | RCRA - P Series Wastes Organic Compounds
i
RCRA - F Series Wastes RCRA - K Series Wastes
1
14. TRANSPORT INFORMATION
DOT UN-No
lATA
IMDG/IMO
Not regulated Not regulated
Not regulated
Not regulated
International Inventories
TSCA DSL EINECS/ELINCS ENCS lECSC KECL
Complies Complies Complies Does not Comply Complies
U.S. Federal Regyiations
SARA 313 Section 313 of Title ill of frie Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
AC-®251 Catalyst Revision Date Decemt>er23. 2009
Chemical Name
Manganese dksxide
CAS-No
1313-13-9
Weight %
45-50
SARA 313-Threshold 1 Values %
1.0
SARA 311/312 Hazard Categories Acute htealth Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
No Yes No No No
Clean Water Act This product does not contain any sulastances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) {see 40 CFR 61) This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act:.
Chemical Name
Manganese dioxide
CAS-No
1313-13-9
Weight %
^ 45-50
HAPS data ! VOC Chemicals
Present (includes any unique
chemKaf substance that contains
Manganese as part of its infrastructure)
Class 1 Ozone Depletors
Class 2 Ozone Depletors
CERCLA
U.S. State Regu la t ions
California Proposition 65 This product contains the foltow/ing Proposition 65 chemicals:
Chemical Name Carbon btack
CAS-No 1333-86-4
California Prop. 65 Carcinogen
Chemical Name Hydrogenated terphenyis
Terphenyis Manganese dioxide
Hiflassachusetts
Carbon black
New Jersey Pennsylvania (lilnois Rhode Island
In ternat iona l Regu la t ions
l^exlco - Grade Slight risk. Grade 1
Chen^cai Hams Hydrogenated terphenyis
Terphenyla Manganese diOKKJe
Gatbon biack
Carcinoiien Status Exposure Urr^te Mejdcs: T^A= G-5 ppm Mexico: TWA= 5 rssq/m^
Msjtico: Ceiling- 0.5 ppm Mexfco: TWA- 0.2 mg/m^ Mexico: TWA= 3,5 mg/rrfl Mexico: STEL= 7 mq/m^
Canada
Page 6 (7
AC-^51 Catalyst Revision Date December 23, 2009
This product has been classified in accordance with ttie hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class D2A Very toxic materials D28 Toxic materials
Chemical Name Manganese dioxide
NPRI X
16, OTHER INFORMATIOI
NFPA HMIS PPE Transport Symbol Not regulated
^ M 1
K j t t l ^ ^H .1 R«4Ctf^ty 0
Prepared By
Issuing Date
Revision Date
Revision Note
David Jordan Director of R&D
December 24, 2009
December 23, 2009
3.9.12. 16.
Disclaimer The infomiation provided on ttiis MSDS is correct to the best of our knoviHedge, information and belief at the date of its publication. The infomiation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warrant or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text
AC-TECH. Material Safety Data Sheet
Issuing Date June 9, 2010 Revision Date June 8, 2010 Revision Number 06
1 . PRODUCT AND COMPANY IDENTIFICATION
Product Name
Product Code(s)
UN-No
Recommended Use
Company
Company Emergency Phone Number Emergency Telephone Number
AC-®137Red
AC-137 Red Adhesion Promoter
1170
Metal adhesion promoter.
Advanced Chemistry & Technology, Inc. 7341 Anaconda Avenue Garden Grove, CA 92841
714-373-2837 (8 AM to 5 PM Pacific)
Chemtrec 1-800-424-9300
2. HAZARDS IDENTIFICATION DANGER!
Appearance Red
Emergency Overview FLAMMABLE LIQUID AND VAPOR
Harmful by inhalation Harmful if swallowed
Physical State Liquid Odor Alcohol
OSHA Regulatory Status
Potential Health Effects Principle Routes of Exposure
Acute Toxicity Eyes Skin Inhalation
Ingestion
Chronic Effects
Main Symptoms
Aggravated Medical Conditions
Environmental Hazard
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin contact, Inhalation, Eye contact.
Irritating to eyes. Vapor may cause irritation. Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Harmful by inhalation. Avoid breathing vapors or mists. Inhalation of vapors in high
concentration may cause irritation of respiratory system. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Harmful if swallowed.
Repeated or prolonged skin contact with the unexposed coating may cause skin irritation and/or dermatitis and sensitization of susceptible persons. See Section 11 for additional Toxicological Information.
Redness. Inhalation of high vapor concentrations may cause symptoms like headache,
dizziness, tiredness, nausea and vomiting.
Skin disorders. Liver disorders. Kidney disorders. Allergies.
See Section 12 for additional Ecological Information.
Page 1 / 9
AC-®137Red Revision Date June 8, 2010
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name Ethanol
Isopropyl alcohol Methyl alcohol
CAS-No 64-17-5 67-63-0 67-56-1
Weight % 70-80 2.5-10 2.5-10
4. FIRST AID MEASURES
Eye Contact
Skin Contact
Inhalation
Ingestion
Notes to Physician
Protection of First-aiders
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Wash skin with soap and water.
Move to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult and you are trained. Call a physician immediately.
Immediate medical attention is required. Induce vomiting, but only if victim is fully conscious.
Treat symptomatically.
Remove all sources of ignition.
5. FIRE-FIGHTING MEASURES
Flammable Properties
Flash Point Method
Suitable Extinguishing Media
Uniform Fire Code
Hazardous Combustion Products
Explosion Data Sensitivity to Mechanical Impact
Specific Hazards Arising from the Chemical In the event of fire, cool tanks with water spray.
Protective Equipment and Precautions for Firefighters
Flammable.
13 "C I 55 T Closed cup
Use:. Water spray. Carbon dioxide {CO2). Dry chemical.
• Flammable Liquid: l-B
Carbon monoxide. Carbon dioxide (CO2), Aldehydes.
Not impact sensitive.
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA Health Hazard 2 Flammabiiity 3 Stability 0 Physical and Chemical Hazards N/A
Page 2 / 9
AC-®137Red Revision Date June 8, 2010
6. ACCIDENTAL RELEASE MEASURE!
Personal Precautions
Methods for Containment
Methods for Cleaning Up
Avoid contact with the skin and the eyes. Use personal protective equipment. Ensure adequate ventilation. Refer to Section 8.
Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).
Pick up and transfer to properly labeled containers. Ground and bond containers when transferring material. Clean contaminated surface thoroughly. Prevent product from entering drains.
7. HANDLING AND STORAGE
Handling
Storage
Wear personal protective equipment. Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes and clothing. Do not smoke. Remove and wash contaminated clothing before re-use.
Keep at temperatures below 28°C. Keep away from open flames, hot surfaces and sources of ignition. Keep out of the reach of children.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Chemical Name Ethanol 64-17-5
Isopropyl alcohol 67-63-0
Methyl alcohol 67-56-1
ACGIH TLV
= 400 ppm STEL TWA: 200 ppm
= 250 ppm STEL TWA: 200 ppm
OSHA PEL TWA: 1000 ppm
TWA: 1900 mg/m^ (vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mq/m^ TWA: 400 ppm
TWA: 980 mg/m^ (vacated) TWA: 400 ppm
(vacated) TWA: 980 mg/m^ (vacated) STEL: 1225 mg/m^
(vacated) STEL: 500 ppm TWA: 200 ppm
TWA: 260 mg/m^ (vacated) TWA: 200 ppm
(vacated) TWA: 260 mg/m^ (vacated) STEL: 250 ppm
(vacated) STEL: 325 mg/m^ Skin
NIOSH IDLH IDLH: 3300 ppm 10% LEL
TWA: 1000 ppm TWA: 1900 mg/m^
IDLH: 2000 ppm 10% LEL TWA: 400 ppm
TWA: 980 mg/m^ STEL: 1225 mg/m^
STEL: 500 ppm
IDLH: 6000 ppm TWA: 200 ppm
TWA: 260 mg/m^ STEL: 325 mg/m^ STEL: 250 ppm
Engineering Measures
Personal Protective Equipment Eye/Face Protection SIdn and Body Protection Respiratory Protection
Hygiene Measures
Showers, eyewash stations, and ventilation systems.
Safety glasses with side-shields. If splashes are likely to occur, wear:. Face-shield. Wear protective gloves/clothing. Maintain adequate ventilation. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators.
Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. General industrial hygiene practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Red Odor Alcohol
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AC-®137Red Revision Date June 8, 2010
Physical State
Flash Point Autoignltion Temperature
Explosion Limits Specific Gravity
Evaporation Rate Vapor Density Actual VOC (lb/gal) EPA VOC (g/l)
Liquid
13 "C / 55 "F No data available
No information available 0.82 g/cc
No information available No information available. 6.07 723
pH
Method
Boiling Point/Range
Flammabiiity Limits in Air
Solubility
Vapor Pressure Weight per Gallon (lbs) EPA VOC (lb/gal) Viscosity
No data available
Closed cup Not applicable
No information available
Soluble in aromatic hydrocarbons and ketones No information available 6.83 6.07 (Water)
Stability
Incompatible Products
Conditions to Avoid
10- STABILITY AND REACTIVITY
Stable under normal conditions.
Incompatible with strong acids and bases. Strong oxidizing agents.
Keep away from open flames, hot surfaces and sources of ignition. Keep away from children.
Hazardous Decomposition Products Carbon oxides. Aldehydes.
Hazardous Polymerization Hazardous polymerization does not occur.
1 1 . TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
Irritation
The product itself has not been tested. Harmful by inhalation. Product is harmful by ingestion.
Moderately irritating to eyes, skin and respiratory system.
Chemical Name Ethanol
Isopropyl alcohol
Methyl alcohol
LD50 Oral 7060 mg/kg ( Rat)
4396 mg/kg ( Rat)
5628 mg/kg ( Rat)
LD50 Dermal
12800 mg/kg (Rat) 12870 mg/kg (Rabbit) 15800 mg/kg (Rabbit)
LC50 Inhalation
72.6 mg/L ( Rat) 4 h
64000 ppm ( Rat) 4 h 83.2 mq/L ( Rat) 4 h
Chronic Toxicity
Chronic Toxicity
Carcinogenicity
Repeated or prolonged skin contact with the unexposed coating may cause skin irritation and/or dermatitis and sensitization of susceptible persons. See Section 11 for additional Toxicological Information.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name Ethanol
ACGIH lARC Group 1
NTP Known
OSHA X
lARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans
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AC-®137Red Revision Date June 8, 2010
Target Organ Effects Liver, Kidney, Skin, Central nervous system (CNS), Lungs.
12. ECOLOGICAL INFORMATION
Ecotoxicity Chemical Name
Ethanol
Isopropyl alcohol
Methyl alcohol
Toxicity to Algae
EC50> 1000 mg/L 72 h EC50> 1000 mg/L 96 h
Toxicity to Fish
LC50= 12900 mg/L Oncorhynchus mykiss 96 h
LC50= 14.2 mg/L Pimephales promelas 96 h
LC50= 61200 mg/L Pimephales promelas 96 h
LC50= 94900 mg/L Pimephales promelas 96 h
LC50= 9640 mg/L Pimephales promelas 96 h
LC50= 13200 mg/L Oncorhynchus mykiss 96 h
LC50= 28100 mg/L Pimephales promelas 96 h
Microtox
EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min
EC50 = 35390 mg/L 5 min
EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min
Daphnia Magna {Water Flea)
EC50= 10800 mg/L 24 h EC50 = 9268 mg/L 48 h
EC50 = 13299 mg/L 48 h
Chemical Name Ethanol
Isopropyl alcohol Methyl alcohol
Loq Pow -0.32
= 0.05 25 °C = -0.77
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method Dispose of contents/container in accordance with local regulation. Can be incinerated, when in compliance with local regulations. This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).
Contaminated Packaging Dispose of in accordance with local regulations.
Chemical Name Ethanol
Isopropyl alcohol Methyl alcohol
California Hazardous Waste Status Toxic; Ignitable Toxic, Ignitable Toxic; Ignitable
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AC-®137Red Revision Date June 8, 2010
I l 4 . TRANSPORT INFORMATION
DOT Proper Shipping Hazard Class UN-No Packing Group
lATA UN-No Proper Shipping Hazard Class Packing Group ERG Code
IMDG/IMO Proper Shipping Hazard Class UN-No Packing Group EmS No.
Name
Name
Name
Ethanol Solution 3 1170 II
1170 Ethanol Solution 3 II 127
Ethanol Solution 3.2 1170 II F-E, S-D
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AC-®137Red Revision Date June 8, 2010
1 5 . R E G U L A T O R Y I N F O R M A T I O N
International Inventories
TSCA DSL EINECS/ELINCS ENCS lECSC KECL PICCS AlCS
Listed Listed Listed Not Listed Listed Listed Listed Listed
U.S. Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name
Isopropyl alcohol Methyl alcohol
CAS-No
67-63-0 67-56-1
Weight %
2.5-10 2.5-10
SARA 313-Threshold Values %
1.0 1.0
SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
Yes Yes Yes No No
Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42). Component
Isopropyl alcohol 67-63-0(2.5-10)
CWA - Reportable Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants
CWA - Hazardous Substances
X
Chemical Name
Methyl alcohol
CAS-No
67-56-1
Weight %
2.5-10
HAPS data
Present
VOC Chemicals
Group IV
Class 1 Ozone Depletors
Class 2 Ozone Depletors
CERCLA
Chemical Name Methyl alcohol
•Hazardous Substances RQs 5000 lb
Extremely IHazardous Substances RQs
U.S. state Regulat ions
California Proposition 65 This product does not contain any Proposition 65 chemicals.
Chemical Name Ethanol
CAS-No 64-17-5
California Prop. 65 Developmental
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AC-®137Red Revision Date June 8, 2010
Chemical Name Ethanol
Isopropyl alcohol
Methyl alcohol
IVIassachu setts X
X
X
New Jersey X
X
X
Pennsylvania X
X
X
Illinois
X
Rhode Island X
X
X
International Regulat ions
Mexico -Grade Moderate risl<, Grade 2
Chemical Name Ethanol
Isopropyl alcohol
Methyl alcohol
Carcinoqen Status Exposure Limits Mexico: TWA= 1900 mg/m^ Mexico: TWA= 1000 ppm Mexico: TWA= 400 ppm
Mexico: TWA= 980 mg/m^ Mexico: STEL= 1225 mg/m^
Mexico: STEL= 500 ppm Mexico: TWA= 200 ppm
Mexico: TWA= 260 mg/m^ Mexico: STEL= 250 ppm
Mexico: STEL= 310 mq/m^
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS Hazard Class B2 Flammable liquid
D2A Very toxic materials D2B Toxic materials
Chemical Name Isopropyl alcohol Methyl alcohol
NPRI X X
1 6 . O T H E R I N F O R M A T I O N
N F P A HMIS PPE T r a n s p o r t S y m b o l
Prepared By David Jordan Director of R&D
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AC-®137 Red Revision Date June 8, 2010
Issuing Date June 9, 2010
Revision Date June 8, 2010
Revision Note (M)SDS sections updated. 9. 16.
Disclaimer The information provided on this SDS is correct to the best of our l<nowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
End of MSDS
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