ESHID-600127 From: Haagenstad, Mark P Sent: Tuesday, January 06, 2015 3:43 PM To: [email protected]; [email protected]; John Kieling; [email protected]; Kliphuis, Trais, NMENV; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; [email protected]; Cobrain, Dave, NMENV; [email protected] Cc: Pete Maggiore; Silas DeRoma; Cummings, Lisa K; Nickless, David J; Bishop, M. Lee; Turner, Gene E; Armijo, Karen (CONTR); Wallace, Terry C; Torres, Enrique; Woitte, Deborah Kay; Clemmons, Steve; Allen, Don; Brandt, Michael Thomas; Sharp-Geiger, Raeanna Racine; Dorries, Alison Marie; Grieggs, Tony; Bacigalupa, Gian A; Vigil-Holterman, Luciana R; Alexander, Rick A; Baumer, Andy; Martinez, Saundra; Sauer, Selena Z; Wood, Yvonne Barbara; Schreiber, Arleen Thorn; Maestas, Pamela Therese; Hargis, Kenneth Marshall; Diaz, Tammy; Juarez, Catherine L; Cabbil, Cheryl Denise; Young, Steven L; Erickson, Randy; Funk, David John; Alexander, Rick A; Frederici, Dave; Diaz, Tammy; Juarez, Catherine L; Robinson, Bruce Alan; Lansing, Michael Alan; Haagenstad, Mark P Subject: Daily Technical Submission - January 6, 2015
Attached is the written daily technical submission for today. The Permittees are submitting the attached
information pursuant to: Section 19 of the May 19, 2014, Administrative Order; the July 10, 2014 letter from
NMED regarding Modification to May 19, 2014, Administrative Order; and Section IX of the September 19, 2014, LANL Nitrate Salt-Bearing Waste Container Isolation Plan, Revision 2.
Please contact me if additional information would be helpful.
Mark Haagenstad
Environmental Protection Division
Compliance and Permitting Group
Los Alamos National Laboratory
Office: (505) 665-2014 Mobile: (505) 699-1733
36877
111111111111111111111111111 Ill\ Ill\
NMED I LANL Technical Summary
January 6, 2015
Participants:
• New Mexico Environment Department: Tim Hall, Siona Briley and Greg Lauer. • LANL - Los Alamos Field Office: • LANL - Los Alamos National Security: Randy Erickson, Alison Dorries, Don Allen,
Tony Grieggs, Mark Haagenstad, Luciana Vigil-Holterman and Cathy Juarez.
LANL Technical Update:
• Location of Nitrate Salt-Bearing Wastes
o Remediated nitrate salt-bearing waste containers. • All containers remain in the 375 Permacon.
o Unremediated nitrate salt-bearing waste containers. • All containers remain in the 231 Permacon.
• Monitoring - Daily Temperature
o Temperatures remain below 90°F. • Previous day's temperature data attached.
• Monitoring - Visual Inspections
o No abnormal conditions were observed.
• Monitoring - headspace gas (HSG) o Containers (SWBs) 68685 and SB50522.
• Continue daily head space gas (HSG) sample collection. • January 6, 2015 HSG data attached.
o H2, CO, C02 and N20
o Other containers • A minimum of once per month HSG sampling will be conducted.
• To date in January, LANL has conducted HSG sampling on 15 SWBs.
• January 6, 2015 HSG data attached.
• Additional measures currently underway
o As a conservative measure, LANL is currently conducting additional monitoring. This additional monitoring includes:
• Containers (SWB) 68685 and SB50522. • LANL continuing solid phase micro-extraction. • Hourly temperature measurements are currently being performed
on SWB 68685 and SB50522.
1
• Five (5) other SWB overpacks (containing 55-gallon drums of remediated nitrate salt-bearing waste).
• Continue twice-weekly HSG sample collection.
• Anticipated Changes to Nitrate Salt-Bearing Waste Containers (e.g. movement, repackaging)
o Currently, no further movements or re-packaging are planned.
Other:
• Verbal and written notifications were provided to NMED-HWB's Steve Pullen on December 29, 2014 regarding the Fire Watch that was established within Dome 231 at 2:30 am on December 29, 2014 after a nitrogen leak was discovered in the dry pipe suppression system located within the Permacon in Dome 231. The Fire Watch will be in effect until the system can be repaired.
o Upon inspection on January 5, 2015, one sprinkler head inside the Dome 231 Permacon was discovered to need replacement. No container movements are anticpated at this time. The Permitees will notify NMED if this changes.
• As noted in previous daily submissions, notes for two Daily Technical Call Submissions were entered into the Electronic Public Reading Room (EPRR) outside of the 5 business day requirement in the Administrative Order and the LANL Isolation Plan.
Next Call: Thursday, January 8, 2015
2
Summary Chart - Requested Information I Pending Issues:
· Requested Information
I . NMED contact I process for LANL to notify NMED under the Revised Isolation Plan (e.g., 24 hour notices}: . .. . ...
: Actionee
2. 1 Keep NMED informed on the status of on- 1 LANL going chemistry I analytical work.
3. 1 On upcoming daily call, provide additional . LANL
4.
5.
6.
7.
8.
9.
IO.
11.
• discussion on the potential for liquids in the ' 350 post-1991 cemented containers (including
a discussion of the review ofRTR tapes).
On upcoming call, provide additional discussion on why 231 and 375 Permacon fire suppression systems are not part of the LANL RCRA Hazardous Waste Facility Permit
; Contingency Plan. Send copy of June 4, 2014 written daily submission to Trais Kliphuis. Also, include
; her on future daily submissions. ' Provide LANL procedures and example
records associated with post-1991 TA-55 cementation process discussed on June 6. Provide information on numbers of containers
, in the post-1991 cemented waste streams from ' the T A-55 process discussed on June 6. This
should include numbers regarding RTR status (R TR' d, meet WIPP criteria, requiring remediation): Provide RTR video and pre-screening information associated with those containers
· requiring remediation from the post-1991 cemented waste streams from the T A-55 process discussed on June 6. Provide copy of CCP/LANL Interface
·Document.
Provide a list of the analytes for which LANL is sampling HSG (C02 and LFL analytes).
Discuss potential sampling ofHSG for NOx.
LANL
LANL
LANL
.LANL
LANL
LANL
:LANL
LANL
Status
Ju11~ 9, 2014 . Complete
' July 6, 2014 (Discussion on call)
July 18, 2014 (Meeti11~ ~eld) ... Complete
June 5, 2014
Complete
June 5, 2014 Complete
; July 3, 2014 · Complete
June 17, 2014
(Supplemental Info provided July 3)
Complete
July 3, 2014
Complete
June 9, ~014 Complete
June 11, 2014 Complete
June 16, 2014
3
Requested Information
12. Follow-up with Tim Hall regarding LANL Hazardous Waste Facility Permit and procedures that LANL is developing for possible future sampling of empty parent containers and unremediated nitrate salt-
. bearing containers at LANL.
Actionee Status
LANL
Completion Date
" ~- '
Complete
. Empty Parent June 16, 2014
Unremediated August 14, 2014 (Supplemental
: information discussed on sampling of parent containers)
August 26, 2014 (Letter on applicability of LANL HWFP for
· opening waste containers)
4
Requested Information Actionee
Respond to NMED email request for LANL information associated with the nitrate salt-bearing parent and daughter waste containers.
WIPP Recovery Daily Meeting Action List item #84 - NMED requested a copy of the LANL remediation records for waste stored in Panel 6 (Trais Kliphuis)- is a subset of the information in item 5 of this action.
Status
Complete July 9, 2014 (Letter sent addressing items 1-4 and 6-9 of the email request)
July 17, 2014 (Letter sent with updated spreadsheet)
August 7, 2014 (First submittal in response to item 5)
August 14, 2014 (Letter addressing items 2&8 - Second submittal in
response to item 5)
August 18, 2014 (Third submittal in response to item 5)
August 21, 2014 (Fourth submittal in response to item 5)
August 27, 2014 (Fifth submittal in response to item 5)
September 4, 2014 (Sixth submittal in response to item 5)
September 9, 2014 (Seventh submittal in response to item 5)
September 11, 2014 (Eighth submittal in response to item 5)
September 22, 2014 (Ninth submittal in response to item 5)
September 23, 2014 (Tenth submittal in response to item 5)
October I, 2014
(Eleventh submittal in response to item 5)
October 8, 2014
(Twelfth submittal in response to i tern 5)
October 16, 2014
(Thirteenth submittal in response to i tern 5)
October 23, 2014
(Fourteenth submittal in response to item 5)
October 27, 2014
(Fifteenth submittal in response to i tern 5)
October 28, 2014 (Sixteenth submittal in response to item 5)
November 3, 2014 (Seventeenth submittal in response to item 5)
5
Requested Information TA.ctionee Status Completion Date
' ~' '~
14. · NMED will review the Round Sheets 'NMED NMED has reviewed Complete 1 (provided in June 11 summary) and inform Round Sheets - no
LANL if these should be attachments to the comments I direction at June 23, 2014 Revised Plan, or if they fall under the this time. NMED will
provision in Section I of the Revised Isolation address any comments in their formal response to
' Plan and their identification during this Revised Container technical call is sufficient. Isolation Plan.
" ~,"
15. NMED has requested 'copies of any waste LANL Complete processing, treatment, characterization stop
June 13, 2014 orders issued since Feb 14, 2014.' (Included w/ daily summary)
June 16, 2014 (Discussed current TA-54 & WCRRF operations)
16. . NMED requested information on the location LANL Complete of drums 68327 and 68328. Request made June 14. June 14, 2014
""'""' '"""'""
17. • Update on LANL efforts - including LANL LANL/ Complete teams. (On June 20 call, LANL offered to NMED schedule an update.meeti11g): July 2, 2014
18. . Neutralizer use in association with container :LANL Complete S855793 (parent of 68660 and 68685).
June25., 2014 19. List of nitrate salt-bearing waste containers ·LANL Complete
that LANL records indicate contain absorbed liquids with the same neutralizer, as discussed September 30, during June 25 technical call. 2014
(with August 26, 2014 response)
20. Schedule follow-on update on LANL efforts - LANL/ Complete · including teams. NMED
August 14, 2014 (Meeting held)
21. NMED requested information on document LANL Complete . approval I review (as discussed on July 3
call). . July 29, 2014 22. : What ~nalyses will be conducted on samples LANL Complete
taken from empty drums that previously contained nitrate salt-bearing waste. July 7, 2014
23. 1
NMED ~equested the followi~g information LANL Complete on cemented waste containers generated from
• T A-55, that are currently stored above-ground July 17,2014 I
at Area G: container id number; location; (Letter sent w/ form (cans or monoliths); and type of information)
concrete. Additionally, NMED requested July 18, 2014 information on pH adjustment during waste
generation process, and information on (Meeting held)
anticipated pH of free liquids (and rationale).
6
Requested Information 'Actionee
36. NMED request regarding LANL Causal LANL Analysis associated with processing of nitrate
: salt-bearing waste at WCRRF - when document is Final.
37. NMED requested a diagram illustrating the , LANL current locations within the 375 Permacon of , the 55 SWBs that contain the 57 remediated
· nitrate salt-bearing waste containers. NMED . also requested a list of these 55 SWBs and the : waste drums within each SWB (including the
container numbers and waste stream type).
Status
Document is currently Draft.
Completion Date
Complete October 27, 2014 (Diagram submitted)
November 3, 2014 (Table submitted)
. November 20, ' 2014
(Revised table · submitted)
8
..
Requested Information Actionee Status Completion Date
'"'~~"""""'''~'
38. NMED requested documentation regarding LANL In Progress Submitted 100 out CINOI.001 waste containers that are not part LANL will submit this of586 RTRs and
' of the September 19, 2014 Nitrate Salts- documentation in documentation on
' Bearing Waste Container Isolation Plan, batches as it is becomes October 3, 2014.
Revision 2. available. Submitted documentation for 101-200 containers on October 10, 2014. Submitted documentation for
' 201-300 containers on October 16, 2014. Submitted documentation for 301-400 containers on October 23, 2014. Submitted documentation for 401-500 containers on October 27, 2014. Submitted documentation for 501-586 containers
, on November 12, 2014. Submitted RTR Videos 101-150 on November 12,
' 2014. Submitted RTR Videos 151-200 on November 20, 2014. Submitted RTR Videos 201-250 on December 1, 2014. Submitted RTR Videos 251-300 on December 19?.2014.
39. NMED requested a diagram of the location of ;LANL Complete the thermocouples on 68685 and SB50522.
"•'" ,,,, c' October 27, 20.14 .. :
40. , NMED requested a copy of the safety basis 'LANL Document is currently . document for remediation planning when it is in Draft.
finalized.
41. , Trending and correlation of temperature and LANL In progress . HSG m()nitoring data.
""""'"''¥""' ''""""
42. Schedule a fourth update on LANL efforts - LANL/ Complete including teams. NMED November 3,
2014
9
Requested Information Status Completion Date
43. Schedule a fifth update on LANL efforts - · LANL/ Complete including teams. NMED November 20,
2014 44. Schedule a sixth update on LANL efforts - LANL/ Complete
incl udin,g teams. ,NMED December 9, 2014 45. NMED requested documentation regarding LANL In Progress
CINOI drums. Additions to original questions added during
technical phone call
t" D(!~e!ll.ber 9, 2914.
46. NMED requested documentation regarding •LANL In Progress . duplicate dru!ll 11um]:)er.
47. NMED requested the ESS plan for • LANL Document is currently temperature control and sampling once in Draft. finalized.
48. Schedule a seventh update on LANL efforts - , LANL/ In Progress. including teams. NMED
10
~emea1atea r.11uate ;:,a1t \..Ontamer neaaspace uas Ana1ys1s
68685 5850522 70503(68540/68553)
Date H2 ppm CO ppm C02 ppm N20 ppm H2 ppm CO ppm C02 ppm N20 ppm H2 ppm CO ppm C02 ppm N20ppm
01/06/15 142 434 10642 2798 1700 459 38470 966 23 0 1127 63
Page 1of4
Remediated Nitrate Salt Container Headspace Gas Analysis
69013 69417 69445
Date H2 ppm CO ppm C02 ppm N20 ppm H2 ppm CO ppm C02 ppm N20 ppm H2 ppm CO ppm C02 ppm N20 ppm
01/06/15 30 0 1222 98 6 0 3 0 244 325 4783 318
l'\emea1atea nnuate :>alt \..Ontamer neaaspace uas Ana1ys1s
69520 69618 69620
Date H2 ppm CO ppm C02 ppm N20 ppm H2 ppm CO ppm C02 ppm N20 ppm H2 ppm CO ppm C02 ppm N20 ppm
01/06/15 94 112 1618 447 116 138 1320 216 334 422 4067 856
Page 3 of 4
Remediated Nitrate Salt Container Headspace Gas Analysis
69641
Date H2 ppm CO ppm C02 ppm N20 ppm
I I 01/06/15 425 615 5638 1417
UET
Nitrate Salt-Bearing TRU Waste Container Monitoring
ATTACHMENT 2 Page 1 of3
Document No.: EWMO-AREAG-FO-[ Revision: Effective Date:
_______ !1_~ge:
5 11/03114 25 of 38
·l246
TA-54 AREA G TA-54-231 NITRATE SALT TRU WASTE CONTAINER DAILY TEMPERATURE DATA SHEET
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ATTACHMENT 2 Page 3 of3
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Document No.: EWMO-AREAG-FO-[ · 1246 Revision: Effective Date: Page:
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5 ! 1/03/14 27 of 38
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ATTACHMENT 3 Page 1 of3
Document No.: EWMO-AREAG-FO-. Revision: Effective Date:
5 11/03!!4 28 of38
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TA-54 AREA G TA-54-375 CELL l NITRATE SALT TRU WASTE CONTAINER DAILY TEMPERATURE DATA SHEET
Date: From
T A-54-375 Cell 1
Calibrated Infrared rhermomeler
(4.2.i
Ambient Temperature
'"" 11 LA000000705li3 u 0..
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69636
69616
69417
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6952()
6964!
69298
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29 of38
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ATTACHMENT 4 Pagel of3
Document No.: EWMO-AREAG-FO-L, ... •'-1246 Revision: Effective Date:
5 l li03/l4 3 l of 38
TA-54 AREA G TA-54-375 CELL 2 NITRATE SALT TRU WASTE CONTAINER DAILY TEMPERATURE DATA SHEET
6.(6] Date: From to~-'·--: ... ~ ..... .
T A-54-375 Cell 2
Calibrated infrared Thermometer
(4.2.l !I
Ambient T"mperature
(6-!7Ji
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LASB02198
68638
6%15
69635 1-----
69642
6%30
69633 o-----
68430
6863!
6%34
68567
94227
LA
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68507
69568
69553
69639
69637
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(6.[l2jJ
End Time (6.[JJD
Comments:
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<:
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32 of38
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Document No.: EWMO-AREAG-FO-L -!246 Nitrate n ... , .. ;,.,., TRU VVastc Container L¥1umun Revision: 5
Effective Date: 1 l/03il4 UET Page: 33 of 38
ATTACHMENT 4 3 of 3
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5 l li03/14 34 of38
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ell3
Cal for:ned ll:1 fr a red Them;omda
(4.2. l fl JIB])
Monday
C.f6J SurtTime:
fnesday
6.f6] St:m: Time:
Brnnd· ....................... ,.··-··-·-····
Mo<ld: ······-····-···-·· ..... . Cai. [)u,, Date·
Number 1-------~------J.....:..~..::..::.:..~~:::;:;;;;;:;:..._+ . .:...:.:: . .:..:::.:.::..:.:..--·----
Ambient "kmp..:ratur"
(6.PJJ
Contniner lD # I
695l'l
6%45
94%8
93605
69548
69604
End Time (6.fDll
____ op
Temp (°F)
<>f ----
Opcratm: ··-································ ()pcrut0~ ,_~ ,~-"··~
Wed:1esdJy
6.(6] Stan rirnt:o
BrJrJ
\fodd: -Due D<lte·
File Ndmh"!
, .... ~:
Clperntor: _____ _
Oper1ror:
I q_ "'7 rJ (A l..p
Thursday
6.f6]
S1Jn Time:
Brand
MoJd Cal. Due D3te:
Fde Number
·----"F
Operator ___ _
Opt'ntor __ .....
Friday
6.[6]
Start Time:
Brnnd
J'.fodel·
Cal. Due Date:
Fik Nt:'nt·er
~~--~--
oF
Opaatm: ____ _
Op.crator:
Saturday
6.[61 Start Time:
Brund·
SvfoJei: Cal Due Date
F1k Number
Operntor ____ _
Sunday
6.[fr! ! Start Time:
Brand:
Model: ................. --···--·· Cai Due Date
File Number
___ cf
Temp (°F) {6.f!!!i6.191l
____ "F
Opcrnwr: ___ _
0µ.::rawr: ____ _
UET
Nitrate Salt-Bearing Tfn; \Vastc Container ,..., .... v
Date: From -'-----'-- to
ATTACHMENT 5 2 of2
Document No.: EWMO-AREAG-FO-C Revision: 5 Effective Date: ! J/03/14
35 of JS
·1246
-······-··-··-··-··- ···--··-··-·····-··-··-.. -- ···---------··----··---·---
OperJtor (print)
Operator (print)
Operator
j
Operator (print}
8, 1 !21 Revie\ved
SUM or des1gnee (prim;
Signature
Signature
Signature
Signature
l#
l" ,~
Z#
z.;; ~r?·
.,., E_..ff
Operator (print)
(print}
Initials Dntc Operntm (print)
lnitbb Date Operator (print)
!
Initials Dale Operator (print)
Initials Date
!nifriis Date: Opcrawr (print)
hlitinls Date
' Sig:utme Z# lnitials Date
l# lnitials Dnte I
7.li Initials Date
I
Z# Initials Date
j
Signature Z# Initials Date
Z# lnitiuls Date
I I j
Signature Z# Initials Date
Nitrate Salt-l:learing TIW Waste Container Monitoring
ATTACHMENTfi Pagel ofl
Doc11mcnt Nu.. EWMO-AREAO-FO-DOP.-1246 Revision. Effective Dut.: l l/03!l4
36 of 38
TA-54 AREA C NITRATE SALT TRG WASTE CONTAINER llOtRLY TEMPERHCRE DATA SHEET
6 [6] Date From ... j#t to ____ ····---···~~- Location:
Cal1br;11:::-J 1U1;;r<:d Th~rmcmcttr
{4~~i!IHBlJ
Srnrt Time (; [6]
S1ort Time
Brand
! Model
C'Jl DU!.' DM"
h;;~ 'utWx·r
UFT
6.16) Date
CJ!iLratc-J lntrnn:d fiK~·nnr.1nun
-~, Jil]fb!J
" 3 ~L:.JA:.t:L.".L;£.,. ___ to .k.!'1:£. ..... 10.:.-..~ ... .t:.
Nilrnle TIW \VaSie Container Mn11itorlug
ATTAClliVIENT 6 P;igc I ofl
Document No.Revision: Efkctivc Dat<::
TA-54 AHE:A G NITRATE SALT T!HJ WASTE CONTAINER 1-mnu_y TEMPERA TlJRE DATA SHEET
LocaLnn: -0f"~&?;l-x: , r'-' ..... -
t•G COPY
rq,,.ELde-_ _,,_ !.II": ·-··.~--~---
EWMO-AREAG-FO-DOP-1246 5 ] l/03/14 36 of1R
StnrtT1me 6 [6l
<)?
Nitrate Salt-Bearing TIHJ Wash' Container Monitoring
Lnc~aior:
~-i'-
9i:
Document No : R~vismn
Effewve Date
EWM0-1\REAG·I 0-DOP-1241! 5 11103/14 J7 of38 .... .-.................................... .