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EA om. SAFETY DATA SHEET |ECOLAB 7052HD-325
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |
Product name
Other means of identification
Recommended use
Restrictions on use
Product dilution information
Company
Emergency healthinformation
Issuing date
HD-325
Not applicable
Cleaning product
Reserved for industrial and professional use.
0.26 %
Ecolab lnc.
1 Ecolab Place
SL Paul, Minnesota USA 551021-300-352-5326
1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)
04/01/2019
| SECTION 2. HAZARDS IDENTIFICATION
GHSClassification
Product AS SOLDSkin corrosion
Serious eye damage
Product AT USE DILUTIONSkin corrosionSerious eye damage
GHSlabel elements
Product AS SOLDHazard pictograms
Signal Word
Hazard Statements
Precautionary Statements
Category 14Category 1
Category 1ACategory 1
Danger
Causes severe skin burns and eye damage.
Prevention:
Do not breathe dusts or mists. Wash skin theroughly after handling.
Wear protective gloves/ protective clothing! eye protection! faceprotection.
Response:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN(or hair); Take off immediately all contaminated clothing. Rinse skinwith water/shower. IF INHALED: Remove persanlo fresh air and keepcomfortable for breathing. Immediately call a POISONCENTER/doctor. IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue
finsing. Immediately call a POISON CENTER/doctor. Wash
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contaminated clothing before reuse.Storage:Slore locked up.Disposal:
Dispose of contents/ container to an approved waste disposal plant.
Product AT USE DILUTIONHazard pictograms
Signal Word : Danger
Hazard Statements : Causes severe skin burns and eye damage.
Precautionary Statements : Prevention:Wash skin thoroughly after handling. Wear protective gloves!protective clothing/ eye protection/ face protection.Response:IF SWALLOWED:Rinse mouth. Do NOT induce vomiting. IF ON SKIN(or hair): Take off immediately all contaminated clothing. Rinse skinwith water/shower, IF INHALED: Remove person to fresh air and keepcomfortable for breathing. immediately call a POISONCENTER/doctor, IF IN EYES: Rinse cautiously with water for severalminutes, Remove contactlenses, if present and easy to do. Continuerinsing. Immediately call a POISON CENTER/doctor. Washcontaminated clothing before reuse.Storage:
Stare locked up.Disposal:Dispose of contents/ container to an approved waste disposal plant.
Product AS SOLDOther hazards | Mixing this product with acid or ammonia releases chlorine gas,
Product AT USE DILUTIONOther hazards : Mixing this product with acid or ammonia releases chlorine gas.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Product AS SOLDPure substance/mixture > Mixture
Chemical name CAS-No. Concentration (%)Sodium Carbonate 497-19-8 30 - 60Sodium hydroxide 1310-73-2 10-30
sodium chloride 7647-14-5 5-10disodium metasilicate 6834-92-06 5-10Sadium dichlare-s-triazinetrione dihydrate 51580-86-0 1-5oxirane, methyl-, polymer with oxirane 9003-11-56 Feb ce
Product AT USE DILUTION
No hazardous ingredients
| SECTION 4. FIRST AID MEASURES
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Product AS SOLDIn case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention immediately.
ALSO
In case of skin contact Wash off immediately with plenty of water for at least 15 minutes. Use
a mild soap if available. Wash clothing before reuse. Thoroughly cleanshoes before reuse, Get medical attention immediately.
2130000,
Es
E If swallowed > Rinse mouth with water. Do NOT induce vomiting. Never givea anything by mauth to an unconscious person. Get medical attention
immediately.
If inhaled : Removeto fresh air, Treat symptomatically. Get medical attention ifsymptoms occur.
Protection offirst-aiders : If potential for exposure exists refer to Section 8 for specific personalprotective equipment.
Notes to physician | Treat symptomatically.
Most important symptoms | See Section 11 for more detailed information on health effects andand effects, both acute and symptoms,delayed
Product AT USE DILUTIONIn case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present and easy to do.Continue rinsing. Get medical attention immediately.
In case of skin contact . Wash off immediately with plenty of water for at least 15 minutes. Usea mild soapif available. Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never giveanything by mouth to an unconscious person. Get medical attentionimmediately,
If inhaled : Removeto fresh air. Treat symptomatically. Get medical attention ifsymptoms occur.
| SECTION 5. FIRE-FIGHTING MEASURES
Product AS SOLD
Suitable extinguishing media : Use extinguishing measures that are appropriate to localcircumslances and the surrounding environment.
Unsuitable extinguishing : None known.media
Specific hazards during fire : Not flammable or combustible, -fighting
Hazardous combustion : Decomposition products may include the following materials:products Carbon oxides
Nitrogen oxides (NOx)
Oxides of phosphorus
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Special protective equipment : Use personal protective equipment.forfire-fighters
Specific extinguishing | Fire residues and contaminatedfire extinguishing water must bemethods disposed of inawith local regulations. In the event offire
and/or explosión do not breathe fumes,
| SECTION 6. ACCIDENTAL RELEASE MEASURES !
Product AS SOLDPersonal precautions, >» Ensure adequate ventilation. Keep people away fram and upwind ofprotective equipment and spillleak. Avoid inhalation, ingestion and contact with skin and ayes.emergency procedures When workers are facing concentrations above the exposurelimit they
must use appropriate certified respirators. Ensure clean-up is
conducted by trained personnel only. Refer to protective measureslisted in sections 7 and 8.
"= ‘ronmental precautions > Do not allow contact with soil, surface or ground water,
ads and materials for > Sweep up and shovel into suitable containers for disposal.containment and cleaning up
Product AT USE DILUTION
Personal precautions, : Ensure adequate Ventilation. Keep people away from and upwind ofprotective equipment and spillleak. Avoid inhalation, Ingestion and contact with skin and eyes.emergency procedures When workers are facing concentrations above the exposure limit they
Must use appropriate certified respirators. Ensure clean-up isconducted by trained personnel only. Refer to protective measureslisted in sections 7 and 8.
Envircamental precautions : De not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal according tolocal / national regulations (see section 13). For large spills, dikespilled material or otherwise contain material to ensure runoff does notreach a waterway.
[SECTION 7. HANDLING AND STORAGE
Product AS SOLD
Advice on safe handling : Do not ingest. Do not get in eyes. on skin, or on clothing. Do notbreathe dust! fume/ gas/ mist! vapors/ spray. Use only with adequateventilation. Wash hands thoroughly after handling, Mixing this productwith acid or ammonia releases chlorine gas.
Conditions for safe storage : Do not store near acids. Keep out of reach of children. Store insuitable labeled containers.
Storage temperature : -30 °C to 40°C
Product AT USE DILUTION
Advice on safe handling : De not ingest. Do not get |n eyes, on skin, or on clothing. Do notbreathe dust fume! gas! mist/ vapors/ spray. Use only with adequateventilation. Wash hands thoroughly after handling. Mixing this productwith acid or ammonia releases chlorine gas.
Conditions for safe storage . Do not store near acids. Keep out of reach of children, Store in
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suitable labeled containers.
[SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Product AS SOLDIngredients with workplace control parameters
Components CAS-No. Form of Permissible Basisexposure concentration
sodium hydroxide 1310-73-2 Ceiling 2 mgim3 ACGIHCeiling 2 mgim3 NIOSH REL
TWA 2 mama OSHA Z1 Engineering measures
Personal protective equipment
Eye protection
Hand protection
Skin protection
Respiratory protection
Hygiene measures
Product AT USE DILUTIONEngineering measures
Personal protective equipment
Eye protection
Hand protection
Skin protection
Respiratory protection
Effective exhaust ventilation system. Maintain air concentrationsbelow occupational exposure standards.
: Wear eye protection! face protection.
Wearthe following personal protective equipment:Standard glove type.
Gloves should be discarded and replacedif there is any indication ofdegradation or chemical breakthrough.
Personal protective equipment comprising: suitable protective glaves,: safety goggles and protective clothing
: When workers are facing concentrations above the éxposure limit theymust use appropriate certified respirators.
Handle in accordance with good industrial hygiene and safetypractice, Remove and wash contaminated clothing before re-use.
Wash face, hands and any expased skin thoroughly after handling,Provide sultable facilities for quick drenching or flushing of the eyesand body in case of contact or splash hazard.
Effective exhaust ventilation system. Maintain air concentrationsbelow occupational exposure standards,
Wear eye protection! face protection.
: Wearthe following personal protective equipment:Standard glove type.Gloves should be discarded and replacedif there is anyindication ofdegradation or chemical breakthrough.
Personal protective equipment comprising: suitable protective gloves,
safety goggles and protective clothing
When workers are facing concentrations above the exposurelimit theymust Use appropriate certified respirators.
SECTION 9, PHYSICAL AND CHEMICAL PROPERTIES
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Appearance
Color
Odor
pH
Flash point
Odor Threshold
Melting pointreezing paint
Initial boiling point andboiling range
Evaporation rate
Flammability (solid, gas)
Upper explosion limit
Lower explosion limit
Wapor pressure
Reiative vapor densily
Relative density
Water solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Thermal decomposition
Viscosity, kinematic
Explosive properties
Oxidizing properties
Molecular weight
Yoo
Product AS SOLD Product AT USE DILUTION
powder liquid
tan tan
Chlorine slight
13,0, (1%) 12.5 - 13.4
Not applicable
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data. available Swen SE
No data available
No data available
No data available
No data available
No data available
Ho data available
[SECTION 10. STABILITY AND REACTIVITY
Product AS SOLD
Chemical stability
Passibility of hazardousreactions
Conditions to avoid
Incompatible materials
Hazardous decompositionproducts
Stable under normal candjtions.
Mixing this product with acid or ammonia releases chlorine gas.
None known.
> Acids
Metals
In case offire hazardous decomposition products may be producedsuch as:Carbon oxidesNitrogen oxides (NOx)
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Oxides of phosphorus
BED20000L0SO
0-00
5E
[ SECTION 11, TOXICOLOGICAL INFORMATION
Information on likely roules ofexposure
Potential Health Effects
Product AS SOLDEyes
Skin
Ingestion
Inhalation
Chronic Exposure
Product AT USE DILUTIONEyes
Skin
Ingestion
Inhalation
Chronic Exposure
Inhalation, Eye contact, Skin contact
: Causes serious eye damage.
Causes severe skin burns.
Causes digestive tract bums.
May cause nose, throat, and lund irritation.
Health injuries are not known or expected under notmal use.
: Causes serious eye damage.
: Causes severe skin burns.
Causes digestive tract burns.
May cause nose, throat, and lungirritation,
Health injuries are not known or expected under normal use:
Experience with human exposure
Product AS SOLDEye contact
Skin contact
Ingestion
Inhalation
Product AT USE DILUTIONEye contact
Skin contact
Ingestion
Inhalation
Toxicity
Product AS SOLDProduct
Acute oral toxicity
Acute inhalalion toxicity
Redness, Pain, Corrosion
Redness, Pain, Corrosion
Corrosion, Abdominal pain
Respiratoryirritation, Cough
Redness, Pain, Corrosion
Redness, Pain, Corrasion
Corrosion, Abdominal pain
Respiratory irritation, Gough
| Acute toxicity estimate : 2,754 mg/kg
. 4h Acute toxicity estimate : 144.23 mg/lTest atmosphere: dust/mist
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Acute dermal toxieity
Skin corrosion/irrilation
Serious eye damageleyeirritation
Respiratory or skinsensitization
Carcinogenicity
Reproductive effects
Germ cell mutagenicity
Teratogenicity
STOT-single exposure
STOT-repeated exposure
Aspiration toxicity
Components
Acute dermal toxicity
No data available
No data available +
Na data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
No data available
sodium chloride
LDS0 Rabbit: > 10,000 mg/kg
Sodium dichloro-s+triazinetrione dihydrateLD50 Rat: > 5,000 mg/kg
| SECTION 12. ECOLOGICAL INFORMATION
Product AS SOLDEcotoxicity
Environmental Effects
Product
Toxicity to fish
Toxicity to daphnia and otheraquatic invertebrates
Toxicity to algae
Components
Toxicity to fish
Components
Toxicity ta daphnia and other
aquatic invertebrates
Toxic to aquatic life.
No data available
No data available
No data available
Sodium Carbonate
96 h LCS0 Lepomis macrochirus (Bluegill sunfish): 300 mg/l
sodium chloride
86 h LCSG Fish: 5,840 mgd
disodium metasilicate .96 h LC50 Fish: 210 mall
oxirane, methyl-, polymer with oxirane96 h LC50 Fish: > 100 img!
Sodium Carbonate |" 48h EC5O Geriodaphnia (water flea): 213.5 mg/l
Sodium hydroxide
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48 h EC50: 40 mgll
Sodium dichloro-s-triazinetrione dihydrate48 h EC50 Daphnia: 0.196 mail
Persistence and degradability
Product AS SOLD
Readily biodegradable,
Preduct AT USE DILUTIONReadily biodegradable.
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
| SECTION 13. DISPOSAL CONSIDERATIONS
Product AS SOLDDisposal methods : Do not contaminate ponds, waterways or ditches with chemical or
used container. Where possible recycling is preferred to dispasal orincineration. If recycling is not practicable, dispase of in compliancewith local regulations. Dispose of wastes in an approved waste
disposal facility.
Disposal considerations > Dispose of as unused product, Empty containers should be taken toan approved waste handling site for recycling or disposal. Do not re-use empty conlainers. Dispose of in accordance with local, state, andfederal requlations.
Product AT USE DILUTIONDisposal methods : Do not contaminate ponds, waterways or ditches with chemical or
used container. Where possible recycling is preferred to disposal orincineration, If recycling is not practicable, dispose of in compliancewith local regulations. Dispose of wastes in an approved wastedisposalfacility.
Disposal considerations : Dispose of as unused product, Empty containers should be taken toan approved waste handling site for recycling or disposal, Do not re-use emply containers. Dispose of in accordance with local, state, andfederal regulations.
[SECTION 14. TRANSPORT INFORMATION
Product AS SOLD
The shipper/consignor/senderis responsible to ensure that the packaging, labeling, and markings arein compliance with the selected mode of transport.
Land transport (DOT)
UN number : 3262
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Description of the goods
Glass
Packing group
Environmentally hazardous
Sea transport (IMDG/IMO)
UN numberDescription of the goods
ClassPacking groupMarine pollutant
Corrosive solid, basic, inorganic, n.o.s.
(sodium hydroxide}
8
il
no
3262CORROSIVE SOLID, BASIC, INORGANIC, N.O.S;
{sodium hydroxide): 6
Ulho
| SECTION 15. REGULATORY INFORMATION
Product AS SOLD
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
Camponents CAS-Na, Compenent RQ (lbs) Calculated product RQ(lbs)
Sodium hydroxide 1310-73-2 1000 5000
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards
SARA 302
SARA 313
California Prop. 65
> Skin corrosion orirritation
Serious eye damage or ayeinvitation
This material does not contain any components with a section 302EHS TFQ.
: This material does not contain any chemical components with knownCAS numbers that exceed the threshold (De Minimis) reporting levelsestablished by SARATitle |||, Section 313.
This product does not contain any chemicals known to the State of California to cause cancer, birth, orany other reproductive defects.
The ingredients of this product are reported in the following Inventories:
United States TSCA Inventory :
On the inventory, or in compliance with the inventory
Canadian Domestic Substances List (DSL):All components of this product are on (he Canadian DSL
Australia Inventory of Chemical Substances (AICS):
Onthe inventory, or in compliance with the inventory
New Zealand. Inventory of Chemical Substances :On the inventory, or in compliance with the inventory
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Japan. ENCS - Existing and New Chemical Substances Inventory |On the inventory, or in compliance with the inventory
Korea. Korean Existing Chemicals Inventory (KECI) :On the inventory, or in compliance with the inventory
Philippines Inventory of Chemicals and Chemical Substances (FICCS) :Onthe inventory, or in compliance with the inventory
China. Inventory of Existing Chemical Substances in China (IECSC}:On the inventory, or in compliance with the inventory
Taiwan Chemical Substance Inventory (TCSI):not determined
[SECTION 16. OTHER INFORMATION
Product AS SOLD
NFPA: HMIS Ill:Flammability
HEALTH
5 = FLAMMABILITY= =
| PHYSICAL HAZARD 0
o 0 = not significant. 1 =Slight.
Special hazard. 2 = Moderate, 3 = High4 Exireme, *= Chronic
Product AT USE DILUTION
NFPA: HMISIll:Flammability .
HEALTH
E 3 ; := E FLAMMABILITY=z =
=PHYSICAL HAZARD 0
D <= not significant, 4 =Slighl,Special harard, 2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Issuing date : 04/01/2019Version 1 1.2Prepared by : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health informationfor this revision isindicated by a barin the left-hand margin of the SDS.
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of ts publication, The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and is
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not to be considered a warranty or qualily specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, Unless specified in the text,
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