Coal Gasification Renewed –technology options to exploit Europe‘scoal reserves
Brussels, November 13, 2013
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 2Copyright TK Uhde 2013
ThyssenKrupp
Why coal gasification (gasification of solids) ?
TK Uhde‘s experience and expertise in gasification
Presentation Outline
Summary and Outlook
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 3Copyright TK Uhde 2013
Climate change
Urbanization
Globalization
Leading engineering
expertise
in
MaterialMechanical
Plant
More consumer and capital goods
More resource and energy use
More infrastructure and buildings
ReducedCO2 emissions,
renewable energies
Efficient resource and
energy use,alternative
energies
Efficient infrastructure
and processes
Demand (“more”)Drivers
Demography
Finite resources
Political framework
Business opportunities RestrictionsDemand (“better”)
Leading engineering expertise supports global sustainable progress
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 4Copyright TK Uhde 2013
Diversified industrial group: Our business areasKey indicators – fiscal 2011/2012*
Elevator Technology
Industrial Solutions**
Components Technology
Materials Services
Steel Europe
7,011 453
28,011
5,705587
47,561
5,257689
18,111
13,165311
27,595
10,992 247
27,761
Sales (€ million)
EBIT*** (€ million)
Employees
Sales (€ million)
EBIT*** (€ million)
Employees
Sales (€ million)
EBIT*** (€ million)
Employees
Sales (€ million)
EBIT*** (€ million)
Employees
Sales (€ million)
EBIT*** (€ million)
Employees
* **
***
Continuing operations (excluding Inoxum and Steel Americas)Created effective January 01, 2013 through the combination of the Plant Technology and Marine Systems business areas; Figures on a pro forma basisAdjusted
TK Uhde (Business Unit Process Technology)
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 5Copyright TK Uhde 2013
Site-SeeingMore than 2.000 plants built by TK Uhde on all continents
130 plants
115 plants375 plants120 plants
105 plants500 plants150 plants
Fertilisers RefineriesNitric acid Aromatics185 plants 380 plants 75 plants
Org. Chemicals/petrochemicalsHydrogen, ammonia, methanol Plastics, synthetic fibres Polyester / polyamides400 plants
Electrolysis Coke Plant Technologies Tank storage facilities Industrial plants150 plants
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 6Copyright TK Uhde 2013
ThyssenKrupp
Why coal gasification (gasification of solids) ?
TK Uhde‘s experience and expertise in gasification
Presentation Outline
Summary and Outlook
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 7Copyright TK Uhde 2013
Why Coal Gasification (gasification of solids) ?TK Uhde’s Solid-Gasification Reference Plants & Projects
builtselected
builtselected
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 8Copyright TK Uhde 2013
Why Coal Gasification (gasification of solids) ?From Feedstock to Products
Gas, Naphtha
Oil/Residues
SteamReformer/ ATR
SteamReformer/ ATR
HTW *GasificationHTW *Gasification
Synthesis Gas
CO +H2
Synthesis Gas
CO +H2
Methanol
Ammonia
Power Plant(IGCC)
FischerTropschSynthesis
CO-Conversion
Methanation
DieselDiesel
Petrol + LPGPetrol + LPG
Urea
Diesel, NaphthaDiesel, Naphtha
PetroleumCoke
Hard Coal
Biomass
PRENFLO *GasificationPRENFLO *Gasification
Biomass
Brown Coal
Waste
LubricantsLubricants
MTO
MTG
Feedstock Gasification Syngas ProductFurther processing
HydrogenHydrogen
SyntheticNaturalGasSyntheticNaturalGas
ElectricityElectricity
FertilizerFertilizer
Oil GasificationOil Gasification
*) TK Uhde proprietary gasification technology
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 9Copyright TK Uhde 2013
fossil fuel prices
fossil fuel availability
proven technology
clean technology
polygeneration
CCS
sellable by-productsfossil fuel flexibility ideal for low rank fuel
Feedstock Technology Product
Why Coal Gasification (gasification of solids) ?Market Drivers
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 10Copyright TK Uhde 2013
550 °C 1350 – 1600 °C800 – 1100 °C
Why Coal Gasification (gasification of solids) ?Proven Gasification Processes
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 11Copyright TK Uhde 2013
ThyssenKrupp
Why coal gasification (gasification of solids) ?
TK Uhde‘s experience and expertise in gasification
Presentation Outline
Summary and Outlook
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 12Copyright TK Uhde 2013
Various Materials require various Gasification Technologies TK Uhde‘s Gasification Portfolio
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 13Copyright TK Uhde 2013
PSG PDQ HTWEntrained-flow gasification Fluidized bed gasification
Various Materials require various Gasification Technologies TK Uhde‘s Gasifiers
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 14Copyright TK Uhde 2013
PRENFLO burner test rig6 t/d (450 m³n/h syngas)
PRENFLO Fürstenhausen48 t/d (3,500 m³n/h syngas)
PRENFLO Puertollano 2,400 t/d (180,000 m³n/h syngas)
Start Up: 1984
Start Up: 1985
Start Up: 1998
Scale Up Factor:8
Scale Up Factor:50
Koppers-TotzekStart of development 1941
57 yearsShell-Koppers pilot plant Hamburg150 t/d coal
Start Up: 1978
DevelopmentsFrom Koppers-Totzek to PRENFLO
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 15Copyright TK Uhde 2013
Koppers-Totzek gasification plant in Modderfontein, S. Africa(Design capacity: 1,000 t/d of ammonia)
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 16Copyright TK Uhde 2013
Koppers-Totzek gasification plant in India(Capacity: 900 t/d of ammonia)
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 17Copyright TK Uhde 2013
PRENFLO Plant in Fürstenhausen, Germany
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 18Copyright TK Uhde 2013
Dry-fed, single train IGCC with CCS Pilot Plant at Elcogas, Spain300 MW net based on petcoke / coal feedstock
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 19Copyright TK Uhde 2013
Start Up: 1988
HTW-Peat Gasification, Kemira
HTW- Pilot PlantRheinbraun Wachtberg40 t/d Lignite, 10 bar
HTW- Demonstration PlantRheinbraun Berrenrath720 t/d Lignite, 10 bar
KoBra IGCC RWE, Hürth3700 t/d Lignite 27 bar
Start Up: 1978
Start Up: 1986
Engineering: 1994
Scale Up Factor:18
Scale Up Factor:5
Atmospheric Winkler generators1956 – 1964 260 t/d Lignite
>20 Years
HTW Laboratory PlantRWTH-Aachen12 t/d Coal, Atm.
Start Up: 1974
HTW-Pilot Plant (WVW)Rheinbraun Wesseling185 t/d Lignite, 25 bar
Start Up: 1989
DevelopmentsThe HTW Process
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 20Copyright TK Uhde 2013
HTW Pilot PlantRWE-Plant-WachtbergFrechen / Germany1,6 t/h1978 - 1985
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 21Copyright TK Uhde 2013
HTW PlantWVW- UK-WesselingWesseling / Germany7,7 t/h Lignite10 – 25 bar1988 - 1990
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 22Copyright TK Uhde 2013
HTW Syngas PlantKemira OyOulu / Finnland30 t/h Peat≈ 300 t/d NH3
1988 - 1991
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 23Copyright TK Uhde 2013
25 t/h dried lignite – 140 MWth34,000 m³/h of syngas≈ 300 t/d Methanol67,000 total operating hours84 % availability (last 10 years) 1986 - 1997
HTW Commercial Scale Demo PlantBerrenrath/Germany
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 24Copyright TK Uhde 2013
HTW-Precon-GasificationNiihama / Japan48 t/d Municipal Waste1999 - 2002
Sumitomo Heavy Industries Ltd.
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 25Copyright TK Uhde 2013
ICM‘s 18,000 bbl/d CTL Plant in MongoliaCoal-to-Gasoline (CTG) plant *
*) Photo Courtesy TransgasDevelopment#1 coal preparation
#2 coal gasification
#3 CO-shift reactor
#4 acid gas removal
#5 methanol synthesis #6 methanol-to-gasoline #7 gasoline storage
PRENFLO PDQ gasifiers
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 26Copyright TK Uhde 2013
ICM‘s 18,000 bbl/d CTL Plant in MongoliaPresentation of Feasibility Study
Ulaanbaatar, Mongolia, June, 2008
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 27Copyright TK Uhde 2013
ICM‘s 18,000 bbl/d CTL Plant in MongoliaMinister Battulga at ThyssenKrupp’s Reference Plant
Elcogas, Puertollano, Spain, April 08, 2013
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 28Copyright TK Uhde 2013
JAM Project in China – Commissioning in 2009Converting Coal into Gasoline
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 29Copyright TK Uhde 2013
Coal
Petcoke
Wood
Strawetc.
Feedstock Pretreatment Gasification Gas Treatment
Milling
Torrefaction CO-Shift
Synthesis
GaselTM
Fischer-Tropsch
Synthesis and
ProductUpgrading
Biodiesel; Bio-
kerosene
AGR
Liquid Residues
BioTfueL – integrated process chainPRENFLO with FT based on solid and liquid feedstock
UhdeTotal
CEAIFP
Sofi-proteol
Axens
TargetDevelopment and commercialisation of integrated process chain for productionof 2nd generation biofuels
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 30Copyright TK Uhde 2013
Biomass-to-Methanol Plant, Hagfors / Värmland / SwedenArtist View
Photo courtesy VärmlandsMetanol AB
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 31Copyright TK Uhde 2013
ThyssenKrupp
Why coal gasification (gasification of solids) ?
TK Uhde‘s experience and expertise in gasification
Presentation Outline
Summary and Outlook
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 32Copyright TK Uhde 2013
Gasification is a proven process, a vast number of gasifiersare operating since decades successfully on commercialbasis
Gasification allows flexibility in feedstock (coal, petcoke, biomass, waste, meaningful combinations)
Gasification allows conversion of carbonaceous feedstocksinto high valuable products (chemicals, hydrogen, SNG, synthetic fuels, polygeneration)
Summary
Gasification produces sellable by-products (sulfur, fly-ash, slag)
Gasification allows CO2 capture based on existingtechnologies
Gasification decreases dependency from oil and/or gas imports
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 33Copyright TK Uhde 2013
Opportunities for gasification of solids in Europe:
Northern Europe:Biomass (e.g. forest residues, peat)
Southern Europe / Mediterranean Area:Biomass (agricultural waste)Coal (high ash/low rank coal)
Outlook
Central/Eastern Europe:Lignite / low rank coal
Europe in general:imported coal and/or waste
TK Uhde acts as technology provider.Demand and regulatory environment are driver of its utilisation
Coal Gasification RenewedNovember 13, 2013 – Brussels – Page 34Copyright TK Uhde 2013
PRENFLO IGCC, Puertollano, SpainAutumn 2013
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