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Page 1: Asymmetric Oxidation Catalysis by a Chiral Al(salalen) Complex: Highly Enantioselective Oxidation of Sulfides with Aqueous Hydrogen Peroxide

2007

SulfoxidesQ 0600 Asymmetric Oxidation Catalysis by a Chiral Al(salalen) Complex: Highly Enan-

tioselective Oxidation of Sulfides with Aqueous Hydrogen Peroxide. — The chiral water-compatible aluminum complex ALC efficiently catalyzes the oxidation of sul-fides by aqueous H2O2 to give the corresponding sulfoxides with good to excellent enantioselectivities. — (YAMAGUCHI, T.; MATSUMOTO, K.; SAITO, B.; KATSUKI*, T.; Angew. Chem., Int. Ed. 46 (2007) 25, 4729-4731; Dep. Chem., Fac. Sci., Kyushu Univ., Higashi, Fukuoka 812, Japan; Eng.) — Klein

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