Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 566029-W
Project name DOD TINDAL
Project ID 754-MELEN199420 TASK 140.01
Received Date Oct 03, 2017
Client Sample ID 0990_PB059_170929
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03107
Date Sampled Sep 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 118
13C5-PFPeA (surr.) 1 % 137
13C5-PFHxA (surr.) 1 % 150
13C4-PFHpA (surr.) 1 % 115
13C8-PFOA (surr.) 1 % 101
13C5-PFNA (surr.) 1 % 129
13C6-PFDA (surr.) 1 % 64
13C2-PFUnDA (surr.) 1 % 45
13C2-PFDoDA (surr.) 1 % 30
13C2-PFTeDA (surr.) 1 % INT
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 77
D3-N-MeFOSA (surr.) 1 % 17
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 566029-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB059_170929
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03107
Date Sampled Sep 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 30
D9-N-EtFOSE (surr.) 1 % 19
D5-N-EtFOSAA (surr.) 1 % 43
D3-N-MeFOSAA (surr.) 1 % 47
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 171
18O2-PFHxS (surr.) 1 % 132
13C8-PFOS (surr.) 1 % 95
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 129
13C2-6:2 FTS (surr.) 1 % 95
13C2-8:2 FTS (surr.) 1 % INT
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 45
Nitrate (as N) 0.02 mg/L 0.63
Sulphate (as SO4) 5 mg/L 13
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 460
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 83
Magnesium 0.5 mg/L 48
Potassium 0.5 mg/L 4.5
Sodium 0.5 mg/L 34
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 566029-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Oct 06, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Oct 06, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Oct 11, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Oct 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Oct 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 566029-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 3, 2017 8:33 AMAddress: Level 1, 436 Johnston Street Report #: 566029 Due: Oct 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDELProject ID: 754-MELEN199420 TASK 140.01
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Major A
nions
Major C
ations
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB059_170929
Sep 29, 2017 Water M17-Oc03107 X X X
Test Counts 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 566029-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 566029-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 566029-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 78 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 95 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 90 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) % 110 50-150 Pass
Perfluorononanoic acid (PFNA) % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) % 86 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 105 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 101 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 121 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 107 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 85 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 118 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 111 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 135 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 111 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 64 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 93 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 84 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 84 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 87 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 114 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 83 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 51 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 115 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 95 70-130 Pass
Chloride % 125 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 124 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 88 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 98 70-130 Pass
Magnesium % 104 70-130 Pass
Potassium % 96 70-130 Pass
Sodium % 115 70-130 Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 566029-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Oc03152 NCP % 91 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Oc03152 NCP % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Oc03152 NCP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc03152 NCP % 115 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Oc03152 NCP % 133 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Oc03152 NCP % 108 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Oc03152 NCP % 104 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc03152 NCP % 121 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Oc03152 NCP % 110 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc03152 NCP % 106 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc03152 NCP % 120 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Oc03152 NCP % 96 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc03152 NCP % 116 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc03152 NCP % 110 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc03152 NCP % 121 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc03152 NCP % 113 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc03152 NCP % 130 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc03152 NCP % 121 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Oc03152 NCP % 78 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc03152 NCP % 95 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc03152 NCP % 104 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc03152 NCP % 97 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc03152 NCP % 106 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc03152 NCP % 112 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc03152 NCP % 99 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc03152 NCP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc03152 NCP % 52 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc03152 NCP % 110 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 566029-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) P17-Oc04002 NCP % 90 70-130 Pass
Chloride S17-Oc01852 NCP % 116 70-130 Pass
Nitrate (as N) M17-Oc01935 NCP % 92 70-130 Pass
Sulphate (as SO4) P17-Oc02333 NCP % 115 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium S17-Oc01851 NCP % 70 70-130 Pass
Magnesium S17-Oc01851 NCP % 101 70-130 Pass
Potassium M17-Se32574 NCP % 116 70-130 Pass
Sodium M17-Se32574 NCP % 120 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 566029-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) P17-Oc04012 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Oc03107 CP mg/L 45 47 4.7 30% Pass
Nitrate (as N) P17-Oc04002 NCP mg/L 35 36 4.0 30% Pass
Sulphate (as SO4) M17-Oc03107 CP mg/L 13 13 2.8 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Oc03107 CP mg/L 460 470 3.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Oc03107 CP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Oc03147 NCP mg/L 90 92 2.0 30% Pass
Magnesium M17-Oc03147 NCP mg/L 39 40 1.0 30% Pass
Potassium M17-Oc03147 NCP mg/L 1.5 1.6 2.0 30% Pass
Sodium M17-Oc03147 NCP mg/L 3.5 3.5 <1 30% Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 566029-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 566029-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 566032-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 03, 2017
Client Sample ID 0990_PP063_171002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03141
Date Sampled Oct 02, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.02
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N09< 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 73
13C5-PFPeA (surr.) 1 % 98
13C5-PFHxA (surr.) 1 % 96
13C4-PFHpA (surr.) 1 % 113
13C8-PFOA (surr.) 1 % 100
13C5-PFNA (surr.) 1 % 84
13C6-PFDA (surr.) 1 % 64
13C2-PFUnDA (surr.) 1 % 49
13C2-PFDoDA (surr.) 1 % 40
13C2-PFTeDA (surr.) 1 % 13
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 67
D3-N-MeFOSA (surr.) 1 % 15
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 566032-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PP063_171002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03141
Date Sampled Oct 02, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 19
D9-N-EtFOSE (surr.) 1 % 15
D5-N-EtFOSAA (surr.) 1 % 57
D3-N-MeFOSAA (surr.) 1 % 54
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.03
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.03
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.15
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.25
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 98
18O2-PFHxS (surr.) 1 % 86
13C8-PFOS (surr.) 1 % 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 56
13C2-6:2 FTS (surr.) 1 % 54
13C2-8:2 FTS (surr.) 1 % INT
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.4
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.25
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.4
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.45
Sum of PFASs (n=28) 0.1 ug/L 0.49
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 19
Nitrate (as N) 0.02 mg/L 0.74
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 390
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 83
Magnesium 0.5 mg/L 35
Potassium 0.5 mg/L 1.3
Sodium 0.5 mg/L 5.2
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 566032-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Oct 06, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Oct 06, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Oct 11, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Oct 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Oct 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 566032-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 3, 2017 8:21 AMAddress: Level 1, 436 Johnston Street Report #: 566032 Due: Oct 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDELProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Major A
nions
Major C
ations
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PP063_171002
Oct 02, 2017 Water M17-Oc03141 X X X
Test Counts 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 566032-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 566032-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 566032-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 103 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 102 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 104 50-150 Pass
Perfluorooctanoic acid (PFOA) % 105 50-150 Pass
Perfluorononanoic acid (PFNA) % 101 50-150 Pass
Perfluorodecanoic acid (PFDA) % 108 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 103 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 117 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 69 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 105 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 98 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 98 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 68 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 88 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 100 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 101 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 99 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 102 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 107 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 103 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 103 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 100 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 80 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 71 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 69 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 80 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 52 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 95 70-130 Pass
Chloride % 121 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 120 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 88 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 98 70-130 Pass
Magnesium % 104 70-130 Pass
Potassium % 96 70-130 Pass
Sodium % 115 70-130 Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 566032-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Se35410 NCP % 116 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Se35410 NCP % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Se35410 NCP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Se35410 NCP % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Se35410 NCP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Se35410 NCP % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Se35410 NCP % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Se35410 NCP % 103 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Se35410 NCP % 117 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se35410 NCP % 65 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se35410 NCP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Se35410 NCP % 97 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se35410 NCP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se35410 NCP % 54 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se35410 NCP % 70 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se35410 NCP % 90 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se35410 NCP % 104 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se35410 NCP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Se35410 NCP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se35410 NCP % 120 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se35410 NCP % 109 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se35410 NCP % 130 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se35410 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se35410 NCP % 82 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se35410 NCP % 76 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se35410 NCP % 75 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se35410 NCP % 78 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se35410 NCP % 57 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 566032-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) P17-Oc04012 NCP % 90 70-130 Pass
Chloride M17-Oc07407 NCP % 113 70-130 Pass
Nitrate (as N) M17-Oc01935 NCP % 92 70-130 Pass
Sulphate (as SO4) M17-Oc04090 NCP % 129 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium S17-Oc01851 NCP % 70 70-130 Pass
Magnesium S17-Oc01851 NCP % 101 70-130 Pass
Potassium M17-Se32574 NCP % 116 70-130 Pass
Sodium M17-Se32574 NCP % 120 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 566032-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se35409 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se35409 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) P17-Oc04012 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Oc04156 NCP mg/L 100 92 12 30% Pass
Nitrate (as N) P17-Oc04002 NCP mg/L 35 36 4.0 30% Pass
Sulphate (as SO4) M17-Oc04156 NCP mg/L 31 29 6.7 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Oc03099 NCP mg/L 42 49 15 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Oc03099 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Oc03147 NCP mg/L 90 92 2.0 30% Pass
Magnesium M17-Oc03147 NCP mg/L 39 40 1.0 30% Pass
Potassium M17-Oc03147 NCP mg/L 1.5 1.6 2.0 30% Pass
Sodium M17-Oc03147 NCP mg/L 3.5 3.5 <1 30% Pass
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 566032-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 566032-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 566035-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 03, 2017
Client Sample ID 0990_PB062_171002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03142
Date Sampled Oct 02, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 99
13C5-PFPeA (surr.) 1 % 82
13C5-PFHxA (surr.) 1 % 89
13C4-PFHpA (surr.) 1 % 125
13C8-PFOA (surr.) 1 % 124
13C5-PFNA (surr.) 1 % 106
13C6-PFDA (surr.) 1 % 76
13C2-PFUnDA (surr.) 1 % 58
13C2-PFDoDA (surr.) 1 % 45
13C2-PFTeDA (surr.) 1 % 19
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 78
D3-N-MeFOSA (surr.) 1 % 33
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 566035-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB062_171002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03142
Date Sampled Oct 02, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 23
D7-N-MeFOSE (surr.) 1 % 37
D9-N-EtFOSE (surr.) 1 % 33
D5-N-EtFOSAA (surr.) 1 % 50
D3-N-MeFOSAA (surr.) 1 % 52
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.07
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.05
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 98
18O2-PFHxS (surr.) 1 % 120
13C8-PFOS (surr.) 1 % 80
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 110
13C2-6:2 FTS (surr.) 1 % 84
13C2-8:2 FTS (surr.) 1 % 42
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.12
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.05
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.12
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.13
Sum of PFASs (n=28) 0.1 ug/L 0.14
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 22
Nitrate (as N) 0.02 mg/L 0.35
Sulphate (as S) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 370
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 85
Magnesium 0.5 mg/L 37
Potassium 0.5 mg/L 1.0
Sodium 0.5 mg/L 8.6
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 566035-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Major Cations
Ammonia (as N) Melbourne Oct 06, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Alkali Metals Melbourne Oct 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Major Anions
Chloride Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Oct 06, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as S) Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Oct 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 566035-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 3, 2017 8:30 PMAddress: Level 1, 436 Johnston Street Report #: 566035 Due: Oct 11, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Major A
nions
Major C
ations
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB062_171002
Oct 02, 2017 Water M17-Oc03142 X X X
Test Counts 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 566035-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 566035-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as S) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 566035-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 121 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 114 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 106 50-150 Pass
Perfluorooctanoic acid (PFOA) % 110 50-150 Pass
Perfluorononanoic acid (PFNA) % 118 50-150 Pass
Perfluorodecanoic acid (PFDA) % 106 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 111 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 119 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 101 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 111 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 111 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 101 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 104 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 94 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 99 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 109 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 108 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 107 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 107 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 68 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 102 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 95 70-130 Pass
Chloride % 125 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as S) % 124 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 97 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 98 70-130 Pass
Magnesium % 104 70-130 Pass
Potassium % 96 70-130 Pass
Sodium % 115 70-130 Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 566035-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Oc03147 NCP % 120 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Oc03147 NCP % 104 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Oc03147 NCP % 120 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc03147 NCP % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Oc03147 NCP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Oc03147 NCP % 118 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Oc03147 NCP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc03147 NCP % 112 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Oc03147 NCP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc03147 NCP % 116 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc03147 NCP % 118 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Oc03147 NCP % 114 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc03147 NCP % 107 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc03147 NCP % 111 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc03147 NCP % 102 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc03147 NCP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc03147 NCP % 101 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc03147 NCP % 116 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Oc03147 NCP % 95 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc03147 NCP % 96 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc03147 NCP % 118 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc03147 NCP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc03147 NCP % 99 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc03147 NCP % 114 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc03147 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc03147 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc03147 NCP % 73 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc03147 NCP % 85 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 566035-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) P17-Oc04012 NCP % 90 70-130 Pass
Chloride M17-Oc07407 NCP % 113 70-130 Pass
Nitrate (as N) M17-Oc01935 NCP % 92 70-130 Pass
Sulphate (as S) M17-Oc03142 CP % 96 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium S17-Oc01851 NCP % 70 70-130 Pass
Magnesium S17-Oc01851 NCP % 101 70-130 Pass
Potassium M17-Se32574 NCP % 116 70-130 Pass
Sodium M17-Se32574 NCP % 120 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Oc03142 CP ug/L 0.01 0.01 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc03142 CP ug/L 0.01 < 0.01 4.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc03142 CP ug/L 0.07 0.08 11 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc03142 CP ug/L 0.05 0.05 1.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 566035-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc03142 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc03142 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) P17-Oc04012 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Oc03107 NCP mg/L 45 47 4.7 30% Pass
Nitrate (as N) P17-Oc04002 NCP mg/L 35 36 4.0 30% Pass
Sulphate (as S) M17-Oc03107 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) S17-Oc01854 NCP mg/L < 20 < 20 <1 30% Pass
Carbonate Alkalinity (as CaCO3) S17-Oc01854 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Oc03147 NCP mg/L 90 92 2.0 30% Pass
Magnesium M17-Oc03147 NCP mg/L 39 40 1.0 30% Pass
Potassium M17-Oc03147 NCP mg/L 1.5 1.6 2.0 30% Pass
Sodium M17-Oc03147 NCP mg/L 3.5 3.5 <1 30% Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 566035-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 566035-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 566036-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 03, 2017
Client Sample ID 0990_PB061_170930
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03147
Date Sampled Sep 30, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 91
13C5-PFPeA (surr.) 1 % 79
13C5-PFHxA (surr.) 1 % 89
13C4-PFHpA (surr.) 1 % 117
13C8-PFOA (surr.) 1 % 115
13C5-PFNA (surr.) 1 % 91
13C6-PFDA (surr.) 1 % 63
13C2-PFUnDA (surr.) 1 % 50
13C2-PFDoDA (surr.) 1 % 38
13C2-PFTeDA (surr.) 1 % 30
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 46
D3-N-MeFOSA (surr.) 1 % 28
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 566036-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB061_170930
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc03147
Date Sampled Sep 30, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 20
D7-N-MeFOSE (surr.) 1 % 29
D9-N-EtFOSE (surr.) 1 % 20
D5-N-EtFOSAA (surr.) 1 % 41
D3-N-MeFOSAA (surr.) 1 % 43
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.04
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.07
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 100
18O2-PFHxS (surr.) 1 % 114
13C8-PFOS (surr.) 1 % 63
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 82
13C2-6:2 FTS (surr.) 1 % 71
13C2-8:2 FTS (surr.) 1 % 40
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.11
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.07
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.11
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.11
Sum of PFASs (n=28) 0.1 ug/L 0.11
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 11
Nitrate (as N) 0.02 mg/L 0.16
Sulphate (as S) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 390
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 90
Magnesium 0.5 mg/L 39
Potassium 0.5 mg/L 1.5
Sodium 0.5 mg/L 3.5
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 566036-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Major Cations
Ammonia (as N) Melbourne Oct 06, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Alkali Metals Melbourne Oct 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Major Anions
Chloride Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Oct 06, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as S) Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Oct 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 566036-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 3, 2017 8:33 PMAddress: Level 1, 436 Johnston Street Report #: 566036 Due: Oct 11, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: TOT TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Major A
nions
Major C
ations
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB061_170930
Sep 30, 2017 Water M17-Oc03147 X X X
Test Counts 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 566036-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 566036-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as S) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 566036-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 121 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 114 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 106 50-150 Pass
Perfluorooctanoic acid (PFOA) % 110 50-150 Pass
Perfluorononanoic acid (PFNA) % 118 50-150 Pass
Perfluorodecanoic acid (PFDA) % 106 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 111 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 119 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 101 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 111 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 111 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 101 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 104 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 94 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 99 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 109 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 108 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 107 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 107 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 68 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 102 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 95 70-130 Pass
Chloride % 125 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as S) % 124 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 97 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 98 70-130 Pass
Magnesium % 104 70-130 Pass
Potassium % 96 70-130 Pass
Sodium % 115 70-130 Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 566036-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Oc03147 CP % 120 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Oc03147 CP % 104 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Oc03147 CP % 120 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc03147 CP % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Oc03147 CP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Oc03147 CP % 118 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Oc03147 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc03147 CP % 112 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Oc03147 CP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc03147 CP % 116 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc03147 CP % 118 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Oc03147 CP % 114 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc03147 CP % 107 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc03147 CP % 111 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc03147 CP % 102 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc03147 CP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc03147 CP % 101 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc03147 CP % 116 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Oc03147 CP % 95 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc03147 CP % 96 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc03147 CP % 118 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc03147 CP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc03147 CP % 99 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc03147 CP % 114 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc03147 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc03147 CP % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc03147 CP % 73 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc03147 CP % 85 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 566036-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) P17-Oc04012 NCP % 90 70-130 Pass
Chloride M17-Oc07407 NCP % 113 70-130 Pass
Nitrate (as N) M17-Oc01935 NCP % 92 70-130 Pass
Sulphate (as S) P17-Oc02333 NCP % 115 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Oc03147 CP % 136 70-130 Fail Q08
Magnesium M17-Oc03147 CP % 131 70-130 Fail Q08
Potassium M17-Oc03147 CP % 128 70-130 Pass
Sodium M17-Oc03147 CP % 127 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Oc03142 NCP ug/L 0.01 0.01 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc03142 NCP ug/L 0.01 < 0.01 4.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc03142 NCP ug/L 0.07 0.08 11 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc03142 NCP ug/L 0.05 0.05 1.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 566036-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc03142 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc03142 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) P17-Oc04012 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Oc03107 NCP mg/L 45 47 4.7 30% Pass
Nitrate (as N) P17-Oc04002 NCP mg/L 35 36 4.0 30% Pass
Sulphate (as S) M17-Oc03107 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) S17-Oc01854 NCP mg/L < 20 < 20 <1 30% Pass
Carbonate Alkalinity (as CaCO3) S17-Oc01854 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Oc03147 CP mg/L 90 92 2.0 30% Pass
Magnesium M17-Oc03147 CP mg/L 39 40 1.0 30% Pass
Potassium M17-Oc03147 CP mg/L 1.5 1.6 2.0 30% Pass
Sodium M17-Oc03147 CP mg/L 3.5 3.5 <1 30% Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 566036-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 566036-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 566039-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 02, 2017
Client Sample ID 0990_PB060_170930
0990_QCPB309_170930
0990_QCPB308_170930
Sample Matrix Water Water Water
Eurofins | mgt Sample No. M17-Oc03152 M17-Oc03153 M17-Oc03154
Date Sampled Sep 30, 2017 Sep 30, 2017 Sep 30, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 103 107 102
13C5-PFPeA (surr.) 1 % 157 141 141
13C5-PFHxA (surr.) 1 % 172 153 149
13C4-PFHpA (surr.) 1 % 117 118 115
13C8-PFOA (surr.) 1 % 95 101 101
13C5-PFNA (surr.) 1 % 109 115 130
13C6-PFDA (surr.) 1 % 51 64 64
13C2-PFUnDA (surr.) 1 % 26 41 38
13C2-PFDoDA (surr.) 1 % 17 26 27
13C2-PFTeDA (surr.) 1 % INT INT INT
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 67 80 80
D3-N-MeFOSA (surr.) 1 % 11 17 14
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 566039-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB060_170930
0990_QCPB309_170930
0990_QCPB308_170930
Sample Matrix Water Water Water
Eurofins | mgt Sample No. M17-Oc03152 M17-Oc03153 M17-Oc03154
Date Sampled Sep 30, 2017 Sep 30, 2017 Sep 30, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT INT INT
D7-N-MeFOSE (surr.) 1 % 15 25 23
D9-N-EtFOSE (surr.) 1 % INT 15 14
D5-N-EtFOSAA (surr.) 1 % 28 40 38
D3-N-MeFOSAA (surr.) 1 % 38 43 45
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 185 174 167
18O2-PFHxS (surr.) 1 % 131 131 132
13C8-PFOS (surr.) 1 % 74 93 91
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % INT 134 134
13C2-6:2 FTS (surr.) 1 % 95 88 93
13C2-8:2 FTS (surr.) 1 % INT INT INT
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1 < 0.1
Chloride 1 mg/L 22 - 20
Sulphate (as SO4) 5 mg/L < 5 - < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 360 - 350
Alkali Metals
Calcium 0.5 mg/L 62 - 68
Magnesium 0.5 mg/L 40 - 40
Potassium 0.5 mg/L 2.4 - 2.4
Sodium 0.5 mg/L 6.3 - 6.4
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 566039-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 09, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Oct 06, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Oct 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Oct 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 566039-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 2, 2017 8:21 AMAddress: Level 1, 436 Johnston Street Report #: 566039 Due: Oct 9, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB060_170930
Sep 30, 2017 Water M17-Oc03152 X X X X X
2 0990_QCPB309_170930
Sep 30, 2017 Water M17-Oc03153 X
3 0990_QCPB308_170930
Sep 30, 2017 Water M17-Oc03154 X X X X X
Test Counts 2 2 2 2 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 566039-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 566039-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 78 50-150 Pass
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 566039-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 95 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 90 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) % 110 50-150 Pass
Perfluorononanoic acid (PFNA) % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) % 86 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 105 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 101 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 121 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 107 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 85 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 118 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 111 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 135 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 111 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 64 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 93 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 84 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 84 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 87 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 114 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 83 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 51 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 115 50-150 Pass
LCS - % Recovery
Chloride % 123 70-130 Pass
Sulphate (as SO4) % 121 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 91 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 104 70-130 Pass
Magnesium % 111 70-130 Pass
Potassium % 103 70-130 Pass
Sodium % 105 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Oc03152 CP % 91 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Oc03152 CP % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Oc03152 CP % 96 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc03152 CP % 115 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Oc03152 CP % 133 50-150 Pass
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 566039-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) M17-Oc03152 CP % 108 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Oc03152 CP % 104 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc03152 CP % 121 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Oc03152 CP % 110 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc03152 CP % 106 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc03152 CP % 120 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Oc03152 CP % 96 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc03152 CP % 116 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc03152 CP % 110 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc03152 CP % 121 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc03152 CP % 113 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc03152 CP % 130 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc03152 CP % 121 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Oc03152 CP % 78 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc03152 CP % 95 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc03152 CP % 104 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc03152 CP % 97 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc03152 CP % 106 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc03152 CP % 112 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc03152 CP % 99 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc03152 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc03152 CP % 52 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc03152 CP % 110 50-150 Pass
Spike - % Recovery
Result 1
Chloride S17-Oc01852 NCP % 116 70-130 Pass
Sulphate (as SO4) M17-Oc07859 NCP % 89 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Oc03147 NCP % 136 70-130 Fail Q08
Magnesium M17-Oc03147 NCP % 131 70-130 Fail Q08
Potassium M17-Oc03147 NCP % 128 70-130 Pass
Sodium M17-Oc03147 NCP % 127 70-130 Pass
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 566039-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc02460 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc02460 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 566039-W
Duplicate
Result 1 Result 2 RPD
Chloride B17-Se32562 NCP mg/L 3500 3400 <1 30% Pass
Sulphate (as SO4) M17-Oc04726 NCP mg/L 390 370 5.3 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) M17-Oc03152 CP mg/L 360 340 5.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Oc02305 NCP mg/L 120 110 2.0 30% Pass
Magnesium M17-Oc02305 NCP mg/L 38 38 1.0 30% Pass
Potassium M17-Oc02305 NCP mg/L 1.4 1.5 7.0 30% Pass
Sodium M17-Oc02305 NCP mg/L 6.0 6.0 <1 30% Pass
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 566039-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 566039-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 566224-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Oct 04, 2017
Client Sample ID 0990_PB064_171002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc04329
Date Sampled Oct 02, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 110
13C5-PFPeA (surr.) 1 % 181
13C5-PFHxA (surr.) 1 % 139
13C4-PFHpA (surr.) 1 % 151
13C8-PFOA (surr.) 1 % 153
13C5-PFNA (surr.) 1 % 124
13C6-PFDA (surr.) 1 % 85
13C2-PFUnDA (surr.) 1 % 68
13C2-PFDoDA (surr.) 1 % 67
13C2-PFTeDA (surr.) 1 % 48
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 88
D3-N-MeFOSA (surr.) 1 % 100
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 566224-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB064_171002
Sample Matrix Water
Eurofins | mgt Sample No. M17-Oc04329
Date Sampled Oct 02, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 99
D7-N-MeFOSE (surr.) 1 % 85
D9-N-EtFOSE (surr.) 1 % 73
D5-N-EtFOSAA (surr.) 1 % 90
D3-N-MeFOSAA (surr.) 1 % 97
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 114
18O2-PFHxS (surr.) 1 % 145
13C8-PFOS (surr.) 1 % 74
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L 0.31
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.2
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.2
13C2-4:2 FTS (surr.) 1 % INT
13C2-6:2 FTS (surr.) 1 % 147
13C2-8:2 FTS (surr.) 1 % INT
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.31
Sum of PFASs (n=28) 0.1 ug/L 0.31
Chloride 1 mg/L 72
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 670
Alkali Metals
Calcium 0.5 mg/L 58
Magnesium 0.5 mg/L 100
Potassium 0.5 mg/L 10
Sodium 0.5 mg/L 28
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 566224-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Oct 07, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Oct 07, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Oct 07, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Oct 07, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 566224-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Oct 4, 2017 9:37 AMAddress: Level 1, 436 Johnston Street Report #: 566224 Due: Oct 11, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB064_171002
Oct 02, 2017 Water M17-Oc04329 X X X X X
Test Counts 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 566224-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 566224-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 94 50-150 Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 566224-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 84 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 92 50-150 Pass
Perfluorooctanoic acid (PFOA) % 92 50-150 Pass
Perfluorononanoic acid (PFNA) % 108 50-150 Pass
Perfluorodecanoic acid (PFDA) % 92 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 102 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 135 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 96 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 91 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 94 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 93 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 97 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 93 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 90 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 86 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 96 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 78 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 94 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 86 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 95 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 65 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 94 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 122 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 66 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 100 50-150 Pass
LCS - % Recovery
Chloride % 100 70-130 Pass
Sulphate (as SO4) % 106 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 100 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 107 70-130 Pass
Magnesium % 109 70-130 Pass
Potassium % 103 70-130 Pass
Sodium % 117 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Oc11112 NCP % 100 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Oc11112 NCP % 90 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Oc11112 NCP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc11112 NCP % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Oc11112 NCP % 97 50-150 Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 566224-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) B17-Oc11112 NCP % 117 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Oc11112 NCP % 108 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc11112 NCP % 97 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Oc11112 NCP % 87 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc11112 NCP % 99 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc11112 NCP % 76 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Oc11112 NCP % 94 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc11112 NCP % 91 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc11112 NCP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc11112 NCP % 72 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc11112 NCP % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc11112 NCP % 83 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc11112 NCP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Oc11112 NCP % 103 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc11112 NCP % 83 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc11112 NCP % 93 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc11112 NCP % 92 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc11112 NCP % 100 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc11112 NCP % 56 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc11112 NCP % 100 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc11112 NCP % 129 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc11112 NCP % 61 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc11112 NCP % 98 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Oc07392 NCP % 102 70-130 Pass
Sulphate (as SO4) M17-Oc05319 NCP % 106 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Total Alkalinity (as CaCO3) P17-Oc05212 NCP % 112 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 566224-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Calcium M17-Oc05322 NCP % 115 70-130 Pass
Magnesium M17-Oc05322 NCP % 113 70-130 Pass
Potassium M17-Oc05322 NCP % 108 70-130 Pass
Sodium M17-Oc05322 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 566224-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Oc06728 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Oc06728 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Oc04329 CP mg/L 72 71 <1 30% Pass
Sulphate (as SO4) M17-Oc04329 CP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) M17-Oc04329 CP mg/L 670 650 2.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Oc05322 NCP mg/L 140 140 4.0 30% Pass
Magnesium M17-Oc05322 NCP mg/L 340 350 4.0 30% Pass
Potassium M17-Oc05322 NCP mg/L 230 230 3.0 30% Pass
Sodium M17-Oc05322 NCP mg/L 1500 1600 4.0 30% Pass
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 566224-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Oct 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 566224-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 567120-W-V2
Project name 754-MELEN199420
Received Date Oct 11, 2017
Client Sample ID 0990_PB037_170831
Sample Matrix Water
Eurofins | mgt Sample No. B17-Oc11817
Date Sampled Aug 31, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 119
13C5-PFPeA (surr.) 1 % 160
13C5-PFHxA (surr.) 1 % 167
13C4-PFHpA (surr.) 1 % 138
13C8-PFOA (surr.) 1 % 119
13C5-PFNA (surr.) 1 % 120
13C6-PFDA (surr.) 1 % 73
13C2-PFUnDA (surr.) 1 % 71
13C2-PFDoDA (surr.) 1 % 73
13C2-PFTeDA (surr.) 1 % 48
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 63
D3-N-MeFOSA (surr.) 1 % 93
D5-N-EtFOSA (surr.) 1 % 117
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 11
Report Number: 567120-W-V2
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB037_170831
Sample Matrix Water
Eurofins | mgt Sample No. B17-Oc11817
Date Sampled Aug 31, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D7-N-MeFOSE (surr.) 1 % 31
D9-N-EtFOSE (surr.) 1 % 55
D5-N-EtFOSAA (surr.) 1 % 61
D3-N-MeFOSAA (surr.) 1 % 56
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 143
18O2-PFHxS (surr.) 1 % 126
13C8-PFOS (surr.) 1 % 84
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % INT
13C2-6:2 FTS (surr.) 1 % 123
13C2-8:2 FTS (surr.) 1 % 67
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 11
Report Number: 567120-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Oct 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 11
Report Number: 567120-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 11
Report Number: 567120-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 86 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 103 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 89 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) % 110 50-150 Pass
Perfluorononanoic acid (PFNA) % 118 50-150 Pass
Perfluorodecanoic acid (PFDA) % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 90 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 93 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 131 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 119 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 11
Report Number: 567120-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 92 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 105 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 147 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 97 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 99 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 79 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 93 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 86 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 100 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 99 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 116 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 96 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Oc12761 NCP % 94 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Oc12761 NCP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Oc12761 NCP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc12761 NCP % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Oc12761 NCP % 108 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Oc12761 NCP % 107 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Oc12761 NCP % 93 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc12761 NCP % 87 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Oc12761 NCP % 91 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc12761 NCP % 113 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc12761 NCP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Oc12761 NCP % 90 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc12761 NCP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc12761 NCP % 127 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc12761 NCP % 112 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc12761 NCP % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc12761 NCP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc12761 NCP % 90 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 11
Report Number: 567120-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) B17-Oc12761 NCP % 83 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc12761 NCP % 105 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc12761 NCP % 95 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc12761 NCP % 75 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc12761 NCP % 91 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc12761 NCP % 101 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc12761 NCP % 101 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc12761 NCP % 99 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc12761 NCP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc12761 NCP % 86 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Oc11819 CP % 94 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Oc11819 CP % 127 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Oc11819 CP % 82 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc11819 CP % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Oc11819 CP % 118 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Oc11819 CP % 104 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Oc11819 CP % 89 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc11819 CP % 71 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Oc11819 CP % 66 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc11819 CP % 117 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc11819 CP % 94 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Oc11819 CP % 72 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc11819 CP % 90 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc11819 CP % 107 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc11819 CP % 85 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc11819 CP % 75 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc11819 CP % 83 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc11819 CP % 76 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Oc11819 CP % 79 50-150 Pass
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 11
Report Number: 567120-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) B17-Oc11819 CP % 90 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc11819 CP % 89 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc11819 CP % 77 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc11819 CP % 85 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc11819 CP % 80 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc11819 CP % 97 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc11819 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc11819 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc11819 CP % 62 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 11
Report Number: 567120-W-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc12760 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc12760 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 11
Report Number: 567120-W-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Oc11818 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Oc11818 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 11
Report Number: 567120-W-V2
Comments
Split Report
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Oct 16, 2017
Date Reported: Oct 16, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 11
Report Number: 567120-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 542977-W
Project name DOD TINDAl
Project ID 754_MELEN199420
Received Date Apr 20, 2017
Client Sample ID TDL_2145URALLA
Sample Matrix Water
Eurofins | mgt Sample No. B17-Ap15804
Date Sampled Apr 13, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
13C4-PFBA (surr.) 1 % 58
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01
13C5-PFPeA (surr.) 1 % 53
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01
13C5-PFHxA (surr.) 1 % 63
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01
13C4-PFHpA (surr.) 1 % 65
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01
13C8-PFOA (surr.) 1 % 63
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
13C5-PFNA (surr.) 1 % 58
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
13C6-PFDA (surr.) 1 % 41
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
13C2-PFUnDA (surr.) 1 % 34
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
13C2-PFDoDA (surr.) 1 % 32
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01
13C2-PFTeDA (surr.) 1 % 25
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 40
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
D3-N-MeFOSA (surr.) 1 % 39
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
D5-N-EtFOSA (surr.) 1 % 47
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
D7-N-MeFOSE (surr.) 1 % 32
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
D9-N-EtFOSE (surr.) 1 % 33
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 10
Report Number: 542977-W
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID TDL_2145URALLA
Sample Matrix Water
Eurofins | mgt Sample No. B17-Ap15804
Date Sampled Apr 13, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSAA (surr.) 1 % 33
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
D3-N-MeFOSAA (surr.) 1 % 32
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 56
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01
18O2-PFHxS (surr.) 1 % 58
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
13C8-PFOS (surr.) 1 % 39
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 108
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
13C2-6:2 FTS (surr.) 1 % 84
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
13C2-8:2 FTS (surr.) 1 % 45
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 10
Report Number: 542977-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 10
Report Number: 542977-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Apr 20, 2017 9:00 AMAddress: 3G Marine Pde Report #: 542977 Due: Apr 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDAlProject ID: 754_MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 TDL_2145URALLA
Apr 13, 2017 Water B17-Ap15804 X
Test Counts 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 10
Report Number: 542977-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
4. Results are uncorrected for matrix spikes or surrogate recoveries.
5. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
6. Samples were analysed on an 'as received' basis. 7. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per Kilogram mg/l: milligrams per litre
ug/l: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100ml: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery
CRM Certified Reference Material - reported as percent recovery
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 10
Report Number: 542977-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 120 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 117 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 118 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 115 50-150 Pass
Perfluorooctanoic acid (PFOA) % 115 50-150 Pass
Perfluorononanoic acid (PFNA) % 112 50-150 Pass
Perfluorodecanoic acid (PFDA) % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 110 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 112 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 93 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 10
Report Number: 542977-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 116 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 119 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 111 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 114 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 107 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 124 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 106 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 115 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 103 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 105 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 115 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 116 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 112 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 56 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Ap19703 NCP % 118 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Ap19703 NCP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Ap19703 NCP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Ap19703 NCP % 114 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Ap19703 NCP % 112 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Ap19703 NCP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Ap19703 NCP % 113 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Ap19703 NCP % 115 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Ap19703 NCP % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Ap19703 NCP % 91 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Ap19703 NCP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Ap19703 NCP % 115 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Ap19703 NCP % 118 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Ap19703 NCP % 120 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Ap19703 NCP % 122 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Ap19703 NCP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Ap19703 NCP % 110 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Ap19703 NCP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 10
Report Number: 542977-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) B17-Ap19703 NCP % 115 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Ap19703 NCP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Ap19703 NCP % 109 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Ap19703 NCP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Ap19703 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Ap19703 NCP % 110 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Ap19703 NCP % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Ap19703 NCP % 108 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Ap19703 NCP % 90 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Ap19703 NCP % 58 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 10
Report Number: 542977-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 10
Report Number: 542977-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: May 04, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 10
Report Number: 542977-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 542977-W-V2
Project name DOD TINDAl
Project ID 754_MELEN199420
Received Date Apr 20, 2017
Client Sample ID TDL_2145URALLA_BORE
Sample Matrix Water
Eurofins | mgt Sample No. B17-Ap15804
Date Sampled Apr 13, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 58
13C5-PFPeA (surr.) 1 % 53
13C5-PFHxA (surr.) 1 % 63
13C4-PFHpA (surr.) 1 % 65
13C8-PFOA (surr.) 1 % 63
13C5-PFNA (surr.) 1 % 58
13C6-PFDA (surr.) 1 % 41
13C2-PFUnDA (surr.) 1 % 34
13C2-PFDoDA (surr.) 1 % 32
13C2-PFTeDA (surr.) 1 % 25
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 40
D3-N-MeFOSA (surr.) 1 % 39
D5-N-EtFOSA (surr.) 1 % 47
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 10
Report Number: 542977-W-V2
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID TDL_2145URALLA_BORE
Sample Matrix Water
Eurofins | mgt Sample No. B17-Ap15804
Date Sampled Apr 13, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D7-N-MeFOSE (surr.) 1 % 32
D9-N-EtFOSE (surr.) 1 % 33
D5-N-EtFOSAA (surr.) 1 % 33
D3-N-MeFOSAA (surr.) 1 % 32
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 56
18O2-PFHxS (surr.) 1 % 58
13C8-PFOS (surr.) 1 % 39
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 108
13C2-6:2 FTS (surr.) 1 % 84
13C2-8:2 FTS (surr.) 1 % 45
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 10
Report Number: 542977-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 10
Report Number: 542977-W-V2
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Apr 20, 2017 9:00 AMAddress: 3G Marine Pde Report #: 542977 Due: Apr 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDAlProject ID: 754_MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 TDL_2145URALLA
Apr 13, 2017 Water B17-Ap15804 X
Test Counts 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
First Reported:May 04, 2017
Date Reported:May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 10
Report Number: 542977-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 10
Report Number: 542977-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 120 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 117 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 118 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 115 50-150 Pass
Perfluorooctanoic acid (PFOA) % 115 50-150 Pass
Perfluorononanoic acid (PFNA) % 112 50-150 Pass
Perfluorodecanoic acid (PFDA) % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 110 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 112 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 93 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 10
Report Number: 542977-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 116 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 119 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 111 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 114 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 107 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 124 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 106 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 115 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 103 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 105 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 115 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 116 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 112 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 56 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Ap19703 NCP % 118 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Ap19703 NCP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Ap19703 NCP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Ap19703 NCP % 114 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Ap19703 NCP % 112 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Ap19703 NCP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Ap19703 NCP % 113 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Ap19703 NCP % 115 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Ap19703 NCP % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Ap19703 NCP % 91 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Ap19703 NCP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Ap19703 NCP % 115 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Ap19703 NCP % 118 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Ap19703 NCP % 120 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Ap19703 NCP % 122 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Ap19703 NCP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Ap19703 NCP % 110 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Ap19703 NCP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 10
Report Number: 542977-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) B17-Ap19703 NCP % 115 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Ap19703 NCP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Ap19703 NCP % 109 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Ap19703 NCP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Ap19703 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Ap19703 NCP % 110 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Ap19703 NCP % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Ap19703 NCP % 108 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Ap19703 NCP % 90 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Ap19703 NCP % 58 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 10
Report Number: 542977-W-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Ap19702 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Ap19702 NCP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 10
Report Number: 542977-W-V2
Comments
Report amended to correct sample ID
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: May 04, 2017
Date Reported: May 12, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 10
Report Number: 542977-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Chris Molloy
Report 544592-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date May 03, 2017
Client Sample ID 0990_053MW01_170427
0990_053MW06_170428
0990_070MW01_170428
0990_BCPMW01_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03446 M17-My03448 M17-My03449 M17-My03450
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 0.09 < 0.05 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 99 83 85 110
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.11 N090.01 N090.02 N090.02
13C5-PFPeA (surr.) 1 % 103 102 105 112
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.17 N090.04 N090.09 N090.02
13C5-PFHxA (surr.) 1 % 96 105 105 110
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.03 < 0.01 < 0.01 < 0.01
13C4-PFHpA (surr.) 1 % 98 105 106 111
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.03 < 0.01 N090.01 < 0.01
13C8-PFOA (surr.) 1 % 95 129 111 124
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 88 79 86 100
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 92 120 63 104
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 80 103 57 93
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 60 94 49 85
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 52 42 27 44
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 64 79 52 57
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 58 51 42 62
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 41 31 26 57
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 36 44 35 48
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 42 43 34 47
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 70
Report Number: 544592-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_053MW01_170427
0990_053MW06_170428
0990_070MW01_170428
0990_BCPMW01_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03446 M17-My03448 M17-My03449 M17-My03450
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSAA (surr.) 1 % 62 86 54 61
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 76 107 62 90
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.08 N090.03 N090.08 N090.01
13C3-PFBS (surr.) 1 % 96 103 103 104
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.07 N090.02 N090.05 N090.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.50 N090.12 N090.18 N090.06
18O2-PFHxS (surr.) 1 % 86 104 98 104
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.13 N090.14 N090.07 N090.03
13C8-PFOS (surr.) 1 % 89 107 73 108
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 83 100 82 97
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 93 85 91 98
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 87 102 55 86
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 1000 980 - 850
pH 0.1 pH Units 6.9 7.2 - 6.9
Client Sample ID 0990_BCRUMW01_170428
0990_BORE06_170428
0990_BORE05_170428
0990_NT0073MW02_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03451 M17-My03452 M17-My03453 M17-My03454
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 0.08 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 109 105 124 129
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.02 N090.02 < 0.01 < 0.01
13C5-PFPeA (surr.) 1 % 107 106 119 123
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.05 N090.03 N090.01 < 0.01
13C5-PFHxA (surr.) 1 % 110 101 117 119
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFHpA (surr.) 1 % 109 99 119 119
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.02 N090.01 < 0.01 < 0.01
13C8-PFOA (surr.) 1 % 115 101 138 132
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 102 54 33 90
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 113 56 127 113
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 70
Report Number: 544592-W
Client Sample ID 0990_BCRUMW01_170428
0990_BORE06_170428
0990_BORE05_170428
0990_NT0073MW02_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03451 M17-My03452 M17-My03453 M17-My03454
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 101 38 99 123
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 75 45 86 93
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 69 38 76 104
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 71 38 70 63
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 55 38 67 65
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 45 33 38 45
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 43 30 44 39
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 56 31 45 49
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 62 34 70 61
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 83 43 98 83
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.03 N090.03 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 110 104 111 113
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.02 N090.02 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.19 N090.11 N090.03 < 0.01
18O2-PFHxS (surr.) 1 % 95 92 112 107
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.18 N090.20 N090.34 N090.03
13C8-PFOS (surr.) 1 % 92 58 101 104
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 94 80 115 160
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 96 76 115 155
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 109 32 95 132
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 780 - 770 650
pH 0.1 pH Units 7.1 - 7.2 7.3
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 70
Report Number: 544592-W
Client Sample ID 0990_NT0050MW02_170429
R160990_NT0065MW02_170428
R160990_NT0065MW04_170428
R160990_NT0269MW01_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03455 M17-My03456 M17-My03457 M17-My03458
Date Sampled Apr 29, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 2.7 0.84 < 0.3
13C4-PFBA (surr.) 1 % 121 103 110 111
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01 N096.3 N091.7 N090.65
13C5-PFPeA (surr.) 1 % 113 82 87 91
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01 N0919 N096.8 N091.2
13C5-PFHxA (surr.) 1 % 111 78 85 91
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 N093.5 N090.93 < 0.3
13C4-PFHpA (surr.) 1 % 114 103 111 114
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 N098.2 N092.3 N090.66
13C8-PFOA (surr.) 1 % 124 92 110 116
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 0.41 < 0.3 < 0.3
13C5-PFNA (surr.) 1 % 102 110 107 118
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.3 < 0.3 < 0.3
13C6-PFDA (surr.) 1 % 96 77 101 117
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.3 < 0.3 < 0.3
13C2-PFUnDA (surr.) 1 % 66 100 124 115
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.3 < 0.3 < 0.3
13C2-PFDoDA (surr.) 1 % 57 66 80 80
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.3 < 0.3 < 0.3
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.3 < 0.3 < 0.3
13C2-PFTeDA (surr.) 1 % 47 14 22 20
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
13C8-FOSA (surr.) 1 % 56 85 95 106
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
D3-N-MeFOSA (surr.) 1 % 43 48 55 57
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
D5-N-EtFOSA (surr.) 1 % 39 30 30 31
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
D7-N-MeFOSE (surr.) 1 % 56 40 49 39
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
D9-N-EtFOSE (surr.) 1 % 57 51 52 48
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
D5-N-EtFOSAA (surr.) 1 % 35 72 87 78
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
D3-N-MeFOSAA (surr.) 1 % 42 73 95 98
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01 N096.6 N091.8 0.38
13C3-PFBS (surr.) 1 % 111 98 104 108
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 N096.7 N091.8 N090.43
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01 N0950 N0911 N093.3
18O2-PFHxS (surr.) 1 % 106 90 103 109
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 N093.6 N090.84 N090.25
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.02 N09170 N0935 N099.5
13C8-PFOS (surr.) 1 % 78 74 99 104
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.3 < 0.3 < 0.3
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 70
Report Number: 544592-W
Client Sample ID 0990_NT0050MW02_170429
R160990_NT0065MW02_170428
R160990_NT0065MW04_170428
R160990_NT0269MW01_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03455 M17-My03456 M17-My03457 M17-My03458
Date Sampled Apr 29, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 1.5 < 1.5 < 1.5
13C2-4:2 FTS (surr.) 1 % 118 84 88 91
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 1.5 < 1.5 < 1.5
13C2-6:2 FTS (surr.) 1 % 129 87 90 92
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 1.5 < 1.5 < 1.5
13C2-8:2 FTS (surr.) 1 % 90 79 97 96
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 1.5 < 1.5 < 1.5
Conductivity (at 25°C) 1 uS/cm 700 - 730 670
pH 0.1 pH Units 7.1 - 7.0 7.0
Client Sample ID 0990_NT0269MW02_170428
0990_BORE24_170428
0990_NT0048MW1_170428
0990_NT0064MW11_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03459 M17-My03460 M17-My03461 M17-My03462
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 28, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 0.23 < 0.05 < 0.05 0.22
13C4-PFBA (surr.) 1 % 106 107 123 116
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.17 N090.10 N090.03 N090.31
13C5-PFPeA (surr.) 1 % 100 102 116 106
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.52 N090.17 N090.11 N091.5
13C5-PFHxA (surr.) 1 % 94 95 113 90
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.04 N090.04 N090.01 N090.19
13C4-PFHpA (surr.) 1 % 99 91 114 98
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.10 N090.06 N090.04 N090.52
13C8-PFOA (surr.) 1 % 79 91 98 66
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 0.02 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 68 73 56 70
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 64 78 93 37
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 50 60 103 59
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 53 56 84 52
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 48 57 120 45
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 42 50 70 37
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 37 50 46 36
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 34 38 28 37
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 70
Report Number: 544592-W
Client Sample ID 0990_NT0269MW02_170428
0990_BORE24_170428
0990_NT0048MW1_170428
0990_NT0064MW11_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03459 M17-My03460 M17-My03461 M17-My03462
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 28, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 33 40 32 31
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 37 53 46 32
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 36 43 73 34
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 49 56 75 42
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.22 N090.06 N090.13 N090.78
13C3-PFBS (surr.) 1 % 98 101 107 94
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.12 N090.06 N090.10 N090.62
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N091.1 N090.40 N090.88 N094.4
18O2-PFHxS (surr.) 1 % 79 86 89 103
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.04 N090.03 N090.04 N090.32
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.18 N090.99 N091.1 N0912
13C8-PFOS (surr.) 1 % 57 69 85 53
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 86 85 167 116
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 0.09 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 74 80 145 116
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 0.02
13C2-8:2 FTS (surr.) 1 % 56 59 110 52
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 290 - 330 1100
pH 0.1 pH Units 7.0 - 8.0 7.0
Client Sample IDR160990_NT0064MW12_170429
R160990_NT0064MW13_170429
R160990_NT0064MW14_170429
0990_BORE10_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03463 M17-My03464 M17-My03465 M17-My03466
Date Sampled Apr 29, 2017 Apr 29, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 30 12 0.44 < 0.05
13C4-PFBA (surr.) 1 % 103 106 109 120
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N0965 N0926 N090.85 < 0.01
13C5-PFPeA (surr.) 1 % 81 89 94 109
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N09280 N0964 N092.8 N090.01
13C5-PFHxA (surr.) 1 % 64 85 95 107
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N0947 N0912 N090.45 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 70
Report Number: 544592-W
Client Sample IDR160990_NT0064MW12_170429
R160990_NT0064MW13_170429
R160990_NT0064MW14_170429
0990_BORE10_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03463 M17-My03464 M17-My03465 M17-My03466
Date Sampled Apr 29, 2017 Apr 29, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C4-PFHpA (surr.) 1 % 90 105 112 104
Perfluorooctanoic acid (PFOA) 0.01 ug/L N0987 N0945 N091.6 < 0.01
13C8-PFOA (surr.) 1 % 68 77 110 102
Perfluorononanoic acid (PFNA) 0.01 ug/L N091.1 N092.0 < 0.3 < 0.01
13C5-PFNA (surr.) 1 % 99 107 116 65
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.3 < 0.3 < 0.3 < 0.01
13C6-PFDA (surr.) 1 % 76 66 110 53
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.3 < 0.3 < 0.3 < 0.01
13C2-PFUnDA (surr.) 1 % 119 109 118 57
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.3 < 0.3 < 0.3 < 0.01
13C2-PFDoDA (surr.) 1 % 109 45 110 47
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.3 < 0.3 < 0.3 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.3 < 0.3 < 0.3 < 0.01
13C2-PFTeDA (surr.) 1 % 46 30 35 46
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
13C8-FOSA (surr.) 1 % 86 92 98 39
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
D3-N-MeFOSA (surr.) 1 % 38 59 35 36
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
D5-N-EtFOSA (surr.) 1 % 31 39 23 29
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
D7-N-MeFOSE (surr.) 1 % 46 55 45 26
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
D9-N-EtFOSE (surr.) 1 % 58 58 59 28
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
D5-N-EtFOSAA (surr.) 1 % 83 94 91 34
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 1.5 < 1.5 < 1.5 < 0.05
D3-N-MeFOSAA (surr.) 1 % 92 73 95 45
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N0961 N0915 N092.0 < 0.01
13C3-PFBS (surr.) 1 % 90 104 106 105
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N0957 N0916 N091.8 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N09240 N09170 N0916 N090.03
18O2-PFHxS (surr.) 1 % 103 79 102 91
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N0924 N098.2 N090.62 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N09270 N091200 N093.7 N090.12
13C8-PFOS (surr.) 1 % 102 80 100 59
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.3 < 0.3 < 0.3 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 1.5 < 1.5 < 1.5 < 0.01
13C2-4:2 FTS (surr.) 1 % 89 89 94 118
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L 7.8 < 1.5 < 1.5 < 0.05
13C2-6:2 FTS (surr.) 1 % 87 91 94 105
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 1.5 < 1.5 < 1.5 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 70
Report Number: 544592-W
Client Sample IDR160990_NT0064MW12_170429
R160990_NT0064MW13_170429
R160990_NT0064MW14_170429
0990_BORE10_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03463 M17-My03464 M17-My03465 M17-My03466
Date Sampled Apr 29, 2017 Apr 29, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
13C2-8:2 FTS (surr.) 1 % 84 78 92 59
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 1.5 < 1.5 < 1.5 < 0.01
Conductivity (at 25°C) 1 uS/cm - 360 - 830
pH 0.1 pH Units - 7.1 - 7.1
Client Sample ID 0990_BORE11_170429
0990_QC1GW_170428
0990_QC2GW_170428
0990_QCSGW_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03467 M17-My03468 M17-My03469 M17-My03473
Date Sampled Apr 29, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
PFOS/PFOA/6:2FTS
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L - - - < 0.01
Perfluorooctanoic acid (PFOA) 0.01 ug/L - - - < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L - - - < 0.05
13C8-PFOS (surr.) 1 % - - - 95
13C8-PFOA (surr.) 1 % - - - 109
13C2-6:2 FTS (surr.) 1 % - - - 95
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
13C4-PFBA (surr.) 1 % 123 116 113 -
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01 N090.10 N090.02 -
13C5-PFPeA (surr.) 1 % 107 104 105 -
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01 N090.17 N090.06 -
13C5-PFHxA (surr.) 1 % 108 98 101 -
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 N090.04 < 0.01 -
13C4-PFHpA (surr.) 1 % 106 99 100 -
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 N090.06 N090.01 -
13C8-PFOA (surr.) 1 % 112 86 102 -
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 0.02 < 0.01 -
13C5-PFNA (surr.) 1 % 71 72 102 -
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
13C6-PFDA (surr.) 1 % 59 55 98 -
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
13C2-PFUnDA (surr.) 1 % 52 54 96 -
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
13C2-PFDoDA (surr.) 1 % 46 49 69 -
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
13C2-PFTeDA (surr.) 1 % 40 42 46 -
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
13C8-FOSA (surr.) 1 % 52 38 86 -
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
D3-N-MeFOSA (surr.) 1 % 40 27 72 -
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 70
Report Number: 544592-W
Client Sample ID 0990_BORE11_170429
0990_QC1GW_170428
0990_QC2GW_170428
0990_QCSGW_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03467 M17-My03468 M17-My03469 M17-My03473
Date Sampled Apr 29, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
D5-N-EtFOSA (surr.) 1 % 31 23 64 -
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
D7-N-MeFOSE (surr.) 1 % 35 27 68 -
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
D9-N-EtFOSE (surr.) 1 % 41 29 58 -
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
D5-N-EtFOSAA (surr.) 1 % 35 31 81 -
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
D3-N-MeFOSAA (surr.) 1 % 42 41 92 -
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01 N090.06 N090.04 -
13C3-PFBS (surr.) 1 % 105 104 109 -
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 N090.06 N090.04 -
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.02 N090.39 N090.42 -
18O2-PFHxS (surr.) 1 % 93 84 98 -
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 0.03 N090.01 -
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.10 N091.0 N090.25 -
13C8-PFOS (surr.) 1 % 62 51 95 -
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
13C2-4:2 FTS (surr.) 1 % 136 116 127 -
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 0.10 < 0.05 -
13C2-6:2 FTS (surr.) 1 % 121 99 98 -
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
13C2-8:2 FTS (surr.) 1 % 55 55 121 -
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
Conductivity (at 25°C) 1 uS/cm 510 - - -
pH 0.1 pH Units 7.8 - - -
Client Sample ID 0990_QC9GW_170429
0990_QC13GW_170430
0990_QC18GW_170501
0990_75COLLINS-BORE_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03474 M17-My03475 M17-My03476 M17-My03477
Date Sampled Apr 29, 2017 Apr 30, 2017 May 01, 2017 Apr 28, 2017
Test/Reference LOR Unit
PFOS/PFOA/6:2FTS
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 -
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 -
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 -
13C8-PFOS (surr.) 1 % 93 104 104 -
13C8-PFOA (surr.) 1 % 103 106 101 -
13C2-6:2 FTS (surr.) 1 % 78 98 66 -
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 70
Report Number: 544592-W
Client Sample ID 0990_QC9GW_170429
0990_QC13GW_170430
0990_QC18GW_170501
0990_75COLLINS-BORE_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03474 M17-My03475 M17-My03476 M17-My03477
Date Sampled Apr 29, 2017 Apr 30, 2017 May 01, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L - - - < 0.05
13C4-PFBA (surr.) 1 % - - - 120
Perfluoropentanoic acid (PFPeA) 0.01 ug/L - - - N090.02
13C5-PFPeA (surr.) 1 % - - - 117
Perfluorohexanoic acid (PFHxA) 0.01 ug/L - - - N090.12
13C5-PFHxA (surr.) 1 % - - - 109
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L - - - N090.02
13C4-PFHpA (surr.) 1 % - - - 108
Perfluorooctanoic acid (PFOA) 0.01 ug/L - - - N090.04
13C8-PFOA (surr.) 1 % - - - 108
Perfluorononanoic acid (PFNA) 0.01 ug/L - - - < 0.01
13C5-PFNA (surr.) 1 % - - - 109
Perfluorodecanoic acid (PFDA) 0.01 ug/L - - - < 0.01
13C6-PFDA (surr.) 1 % - - - 80
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L - - - < 0.01
13C2-PFUnDA (surr.) 1 % - - - 55
Perfluorododecanoic acid (PFDoA) 0.01 ug/L - - - < 0.01
13C2-PFDoDA (surr.) 1 % - - - 40
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L - - - < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L - - - < 0.01
13C2-PFTeDA (surr.) 1 % - - - 18
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L - - - < 0.05
13C8-FOSA (surr.) 1 % - - - 79
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L - - - < 0.05
D3-N-MeFOSA (surr.) 1 % - - - 56
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L - - - < 0.05
D5-N-EtFOSA (surr.) 1 % - - - 56
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L - - - < 0.05
D7-N-MeFOSE (surr.) 1 % - - - 57
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L - - - < 0.05
D9-N-EtFOSE (surr.) 1 % - - - 50
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L - - - < 0.05
D5-N-EtFOSAA (surr.) 1 % - - - 65
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L - - - < 0.05
D3-N-MeFOSAA (surr.) 1 % - - - 69
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L - - - N090.11
13C3-PFBS (surr.) 1 % - - - 113
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L - - - N090.11
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L - - - N090.74
18O2-PFHxS (surr.) 1 % - - - 101
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L - - - N090.05
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L - - - N091.5
13C8-PFOS (surr.) 1 % - - - 86
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L - - - < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 70
Report Number: 544592-W
Client Sample ID 0990_QC9GW_170429
0990_QC13GW_170430
0990_QC18GW_170501
0990_75COLLINS-BORE_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03474 M17-My03475 M17-My03476 M17-My03477
Date Sampled Apr 29, 2017 Apr 30, 2017 May 01, 2017 Apr 28, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L - - - < 0.01
13C2-4:2 FTS (surr.) 1 % - - - 120
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L - - - < 0.05
13C2-6:2 FTS (surr.) 1 % - - - 88
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L - - - < 0.01
13C2-8:2 FTS (surr.) 1 % - - - 80
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L - - - < 0.01
Client Sample ID0990_PRIVATEBORE001_170428
0990_QC6_17/04/28
0990_QC14_17/04/30
0990_SW04_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03478 M17-My03479 M17-My03480 M17-My03481
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
PFOS/PFOA/6:2FTS
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L - < 0.01 < 0.01 -
Perfluorooctanoic acid (PFOA) 0.01 ug/L - < 0.01 < 0.01 -
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L - < 0.05 < 0.05 -
13C8-PFOS (surr.) 1 % - 81 82 -
13C8-PFOA (surr.) 1 % - 101 112 -
13C2-6:2 FTS (surr.) 1 % - 81 76 -
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 - - < 0.05
13C4-PFBA (surr.) 1 % 128 - - 118
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.03 - - < 0.01
13C5-PFPeA (surr.) 1 % 135 - - 107
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.15 - - < 0.01
13C5-PFHxA (surr.) 1 % 128 - - 106
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02 - - < 0.01
13C4-PFHpA (surr.) 1 % 126 - - 102
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.05 - - < 0.01
13C8-PFOA (surr.) 1 % 126 - - 98
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 - - < 0.01
13C5-PFNA (surr.) 1 % 109 - - 92
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 - - < 0.01
13C6-PFDA (surr.) 1 % 89 - - 78
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 - - < 0.01
13C2-PFUnDA (surr.) 1 % 89 - - 68
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 - - < 0.01
13C2-PFDoDA (surr.) 1 % 95 - - 60
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 - - < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 - - < 0.01
13C2-PFTeDA (surr.) 1 % 88 - - 43
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 70
Report Number: 544592-W
Client Sample ID0990_PRIVATEBORE001_170428
0990_QC6_17/04/28
0990_QC14_17/04/30
0990_SW04_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03478 M17-My03479 M17-My03480 M17-My03481
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 - - < 0.05
13C8-FOSA (surr.) 1 % 93 - - 73
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 - - < 0.05
D3-N-MeFOSA (surr.) 1 % 96 - - 54
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 - - < 0.05
D5-N-EtFOSA (surr.) 1 % 91 - - 52
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 - - < 0.05
D7-N-MeFOSE (surr.) 1 % 83 - - 48
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 - - < 0.05
D9-N-EtFOSE (surr.) 1 % 79 - - 48
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 - - < 0.05
D5-N-EtFOSAA (surr.) 1 % 71 - - 65
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 - - < 0.05
D3-N-MeFOSAA (surr.) 1 % 73 - - 70
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.14 - - < 0.01
13C3-PFBS (surr.) 1 % 140 - - 110
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.15 - - < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.95 - - N090.01
18O2-PFHxS (surr.) 1 % 121 - - 99
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.07 - - < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.9 - - 0.02
13C8-PFOS (surr.) 1 % 91 - - 78
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 - - < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 - - < 0.01
13C2-4:2 FTS (surr.) 1 % 165 - - 131
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 - - < 0.05
13C2-6:2 FTS (surr.) 1 % 114 - - 95
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 - - < 0.01
13C2-8:2 FTS (surr.) 1 % 102 - - 92
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 - - < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 70
Report Number: 544592-W
Client Sample ID 0990_SW05_17/04/30
0990_SW06_17/04/30
0990_SW07_17/05/01
0990_SW09_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03482 M17-My03483 M17-My03484 M17-My03485
Date Sampled Apr 30, 2017 Apr 30, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 118 116 122 114
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.05
13C5-PFPeA (surr.) 1 % 108 105 110 104
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.21
13C5-PFHxA (surr.) 1 % 104 103 107 103
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.03
13C4-PFHpA (surr.) 1 % 104 103 106 95
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.07
13C8-PFOA (surr.) 1 % 102 101 103 81
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 95 89 94 65
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 77 72 78 47
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 64 61 64 39
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 63 56 58 36
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 44 33 40 25
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 75 70 73 40
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 78 62 51 35
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 80 55 40 30
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 54 48 45 28
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 57 46 46 29
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 63 58 62 30
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 66 61 68 32
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.14
13C3-PFBS (surr.) 1 % 111 111 113 111
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.12
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.01 N090.02 N090.01 N090.70
18O2-PFHxS (surr.) 1 % 99 98 101 86
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.08
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.02 N090.03 N090.02 N092.0
13C8-PFOS (surr.) 1 % 79 73 78 47
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 70
Report Number: 544592-W
Client Sample ID 0990_SW05_17/04/30
0990_SW06_17/04/30
0990_SW07_17/05/01
0990_SW09_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03482 M17-My03483 M17-My03484 M17-My03485
Date Sampled Apr 30, 2017 Apr 30, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 131 126 127 126
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 97 94 92 77
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 85 83 85 53
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - 700 - 820
pH 0.1 pH Units - 7.9 - 7.5
Client Sample ID 0990_SW14_17/05/01
0990_SW16_17/05/01
0990_SW23_17/05/01
0990_SW27_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03486 M17-My03487 M17-My03488 M17-My03489
Date Sampled May 01, 2017 May 01, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 121 123 122 112
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.03 N090.03 0.02 0.04
13C5-PFPeA (surr.) 1 % 113 111 131 123
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.11 N090.11 N090.10 N090.15
13C5-PFHxA (surr.) 1 % 108 108 121 119
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02 N090.02 N090.02 N090.02
13C4-PFHpA (surr.) 1 % 107 107 115 113
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.03 N090.03 N090.03 N090.05
13C8-PFOA (surr.) 1 % 110 105 104 103
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 98 100 93 99
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 80 78 77 82
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 69 67 68 72
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 63 59 68 67
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 41 40 78 68
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 72 76 59 62
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 55 66 59 53
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 44 54 59 61
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 70
Report Number: 544592-W
Client Sample ID 0990_SW14_17/05/01
0990_SW16_17/05/01
0990_SW23_17/05/01
0990_SW27_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03486 M17-My03487 M17-My03488 M17-My03489
Date Sampled May 01, 2017 May 01, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 51 53 47 45
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 51 53 49 46
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 66 68 72 72
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 73 68 74 75
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.07 N090.07 N090.06 N090.08
13C3-PFBS (surr.) 1 % 115 116 128 125
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.06 N090.06 N090.05 N090.07
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.45 N090.44 N090.40 N090.49
18O2-PFHxS (surr.) 1 % 99 99 99 98
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.04 N090.04 N090.03 N090.03
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.98 N090.92 N090.81 N090.69
13C8-PFOS (surr.) 1 % 75 80 67 72
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 125 137 178 181
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 87 102 122 128
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 84 93 112 130
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - - - 620
pH 0.1 pH Units - - - 8.3
Client Sample ID 0990_SW28_17/05/01
0990_SW29_17/05/01
0990_SW31_17/05/01
0990_SW32_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03490 M17-My03491 M17-My03492 M17-My03493
Date Sampled May 01, 2017 May 01, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 113 118 120 118
Perfluoropentanoic acid (PFPeA) 0.01 ug/L 0.03 < 0.01 < 0.01 < 0.01
13C5-PFPeA (surr.) 1 % 113 133 132 126
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.11 < 0.01 < 0.01 < 0.01
13C5-PFHxA (surr.) 1 % 111 127 129 127
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 70
Report Number: 544592-W
Client Sample ID 0990_SW28_17/05/01
0990_SW29_17/05/01
0990_SW31_17/05/01
0990_SW32_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03490 M17-My03491 M17-My03492 M17-My03493
Date Sampled May 01, 2017 May 01, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C4-PFHpA (surr.) 1 % 113 119 119 117
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.03 < 0.01 < 0.01 < 0.01
13C8-PFOA (surr.) 1 % 105 113 109 109
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 105 97 98 98
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 82 83 75 75
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 71 72 63 67
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 66 70 66 69
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 66 81 84 81
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 78 61 65 61
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 70 60 75 59
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 80 59 83 65
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 53 46 66 47
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 57 48 62 47
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 68 76 69 69
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 76 82 70 74
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.07 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 115 133 132 130
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.06 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.41 < 0.01 < 0.01 < 0.01
18O2-PFHxS (surr.) 1 % 101 108 108 109
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.38 < 0.01 < 0.01 < 0.01
13C8-PFOS (surr.) 1 % 78 76 70 73
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 153 197 198 191
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 118 139 137 135
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 70
Report Number: 544592-W
Client Sample ID 0990_SW28_17/05/01
0990_SW29_17/05/01
0990_SW31_17/05/01
0990_SW32_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03490 M17-My03491 M17-My03492 M17-My03493
Date Sampled May 01, 2017 May 01, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
13C2-8:2 FTS (surr.) 1 % 113 131 118 120
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - - 660 690
pH 0.1 pH Units - - 8.4 8.4
Client Sample ID 0990_SW37_17/04/30
0990_SW38_17/04/30
0990_SW39_17/04/30
0990_SW44_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03494 M17-My03495 M17-My03496 M17-My03497
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 120 119 120 107
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01 < 0.01 < 0.01 0.02
13C5-PFPeA (surr.) 1 % 139 135 129 127
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01 < 0.01 < 0.01 N090.01
13C5-PFHxA (surr.) 1 % 129 129 132 118
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFHpA (surr.) 1 % 121 121 125 112
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C8-PFOA (surr.) 1 % 105 111 116 103
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 93 99 108 97
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 78 80 85 83
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 74 70 75 76
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 75 70 75 72
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 71 71 80 63
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 59 64 70 61
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 57 66 69 60
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 74 67 65 65
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 49 53 61 44
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 51 53 63 51
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 70
Report Number: 544592-W
Client Sample ID 0990_SW37_17/04/30
0990_SW38_17/04/30
0990_SW39_17/04/30
0990_SW44_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03494 M17-My03495 M17-My03496 M17-My03497
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 75 76 77 86
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 77 76 83 91
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 132 133 135 122
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.01 N090.01 N090.03 N090.01
18O2-PFHxS (surr.) 1 % 103 108 112 103
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.03 N090.04 N090.06 N090.10
13C8-PFOS (surr.) 1 % 72 73 78 78
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 197 194 199 178
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 131 132 139 127
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 125 122 130 128
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 710 740 - 240
pH 0.1 pH Units 7.9 7.7 - 8.1
Client Sample ID 0990_SW46_17/04/30
0990_SW49_17/04/30
0990_SW50_17/05/01
0990_SW51_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03498 M17-My03499 M17-My03500 M17-My03501
Date Sampled Apr 30, 2017 Apr 30, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 0.06 0.09 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 93 124 119 119
Perfluoropentanoic acid (PFPeA) 0.01 ug/L 0.07 0.14 0.04 0.04
13C5-PFPeA (surr.) 1 % 97 126 133 129
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.36 N090.45 N090.11 N090.12
13C5-PFHxA (surr.) 1 % 88 118 123 127
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.04 N090.07 N090.02 N090.02
13C4-PFHpA (surr.) 1 % 85 121 119 125
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.09 N090.16 N090.04 N090.05
13C8-PFOA (surr.) 1 % 77 113 109 114
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 68 108 100 105
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 70
Report Number: 544592-W
Client Sample ID 0990_SW46_17/04/30
0990_SW49_17/04/30
0990_SW50_17/05/01
0990_SW51_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03498 M17-My03499 M17-My03500 M17-My03501
Date Sampled Apr 30, 2017 Apr 30, 2017 May 01, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C6-PFDA (surr.) 1 % 53 90 81 83
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 45 73 75 73
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 40 67 76 72
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 49 89 90 84
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 39 60 62 62
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 42 67 72 68
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 53 67 77 72
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 29 44 49 47
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 32 47 55 50
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 45 75 78 72
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 49 84 83 76
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.48 N090.19 N090.07 N090.07
13C3-PFBS (surr.) 1 % 92 122 129 132
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.37 N090.16 N090.06 N090.06
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N091.9 N091.4 N090.47 N090.51
18O2-PFHxS (surr.) 1 % 72 100 103 107
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.07 N090.09 N090.03 N090.04
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.5 N093.3 N091.0 N091.5
13C8-PFOS (surr.) 1 % 48 76 72 69
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 129 161 190 191
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 84 118 132 139
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 73 119 125 124
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - - 650 -
pH 0.1 pH Units - - 7.8 -
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 70
Report Number: 544592-W
Client Sample ID 0990_SW52_17/04/30
0990_SW54_17/04/29
0990_SW56_17/0430
0990_SW57_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03502 M17-My03503 M17-My03504 M17-My03505
Date Sampled Apr 30, 2017 Apr 29, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 121 128 95 118
Perfluoropentanoic acid (PFPeA) 0.01 ug/L 0.04 0.02 0.02 0.02
13C5-PFPeA (surr.) 1 % 133 128 86 134
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.12 N090.04 N090.04 N090.04
13C5-PFHxA (surr.) 1 % 126 126 89 125
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
13C4-PFHpA (surr.) 1 % 122 121 84 123
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.04 0.01 N090.01 N090.01
13C8-PFOA (surr.) 1 % 113 109 73 113
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 106 94 63 105
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 78 77 52 79
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 69 68 44 66
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 69 69 42 67
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 86 83 53 103
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 66 60 41 62
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 76 62 37 79
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 92 55 44 96
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 57 44 27 54
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 64 51 30 58
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 70 65 44 73
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 75 64 46 77
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.07 N090.03 N090.03 N090.03
13C3-PFBS (surr.) 1 % 131 129 90 131
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.06 N090.02 N090.02 N090.03
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.46 N090.15 N090.19 N090.18
18O2-PFHxS (surr.) 1 % 104 104 69 108
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.03 N090.01 N090.01 N090.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.90 N090.23 N090.27 N090.23
13C8-PFOS (surr.) 1 % 71 69 47 77
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 70
Report Number: 544592-W
Client Sample ID 0990_SW52_17/04/30
0990_SW54_17/04/29
0990_SW56_17/0430
0990_SW57_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03502 M17-My03503 M17-My03504 M17-My03505
Date Sampled Apr 30, 2017 Apr 29, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 189 173 112 189
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 135 115 69 135
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 117 102 62 117
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - - 670 -
pH 0.1 pH Units - - 8.0 -
Client Sample ID 0990_SW58_17/04/30
0990_SW59_17/04/30
0990_SW60_17/04/30
0990_SW61_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03506 M17-My03507 M17-My03508 M17-My03509
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 0.08
13C4-PFBA (surr.) 1 % 127 126 108 110
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.02 N090.02 N090.03 N090.16
13C5-PFPeA (surr.) 1 % 115 117 110 102
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.04 N090.05 N090.05 N090.49
13C5-PFHxA (surr.) 1 % 127 125 117 106
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 < 0.01 0.01 N090.07
13C4-PFHpA (surr.) 1 % 127 132 122 107
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.01 N090.01 N090.01 N090.14
13C8-PFOA (surr.) 1 % 116 125 112 95
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 103 105 102 77
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 75 69 73 57
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 64 55 61 46
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 62 53 62 45
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 63 54 64 61
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 74 66 62 40
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 85 87 79 43
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 100 97 83 55
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 70
Report Number: 544592-W
Client Sample ID 0990_SW58_17/04/30
0990_SW59_17/04/30
0990_SW60_17/04/30
0990_SW61_17/04/30
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03506 M17-My03507 M17-My03508 M17-My03509
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 30, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 61 52 58 29
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 69 57 62 34
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 65 54 60 43
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 64 58 63 49
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.03 N090.03 N090.03 N090.21
13C3-PFBS (surr.) 1 % 128 128 116 106
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.03 N090.03 N090.03 N090.17
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.19 N090.18 N090.20 N091.3
18O2-PFHxS (surr.) 1 % 111 113 101 87
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.01 N090.01 N090.01 N090.08
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.25 N090.29 N090.27 N092.6
13C8-PFOS (surr.) 1 % 69 65 66 50
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 174 179 168 137
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 125 137 126 92
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 99 91 99 64
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 680 700 - 720
pH 0.1 pH Units 7.9 7.8 - 7.6
Client Sample ID 0990_SW62_17/04/30
0990_SW64_17/04/30
0990_SW68_17/04/30
0990_SW74_17/04/29
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03510 M17-My03511 M17-My03512 M17-My03513
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 0.12 0.11 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 93 112 114 104
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.19 N090.18 < 0.01 N090.02
13C5-PFPeA (surr.) 1 % 90 108 113 115
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.65 N090.68 N090.01 N090.04
13C5-PFHxA (surr.) 1 % 97 108 120 123
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.09 N090.08 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 70
Report Number: 544592-W
Client Sample ID 0990_SW62_17/04/30
0990_SW64_17/04/30
0990_SW68_17/04/30
0990_SW74_17/04/29
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03510 M17-My03511 M17-My03512 M17-My03513
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C4-PFHpA (surr.) 1 % 100 111 116 116
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.19 N090.22 < 0.01 N090.01
13C8-PFOA (surr.) 1 % 84 97 97 96
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 74 86 65 75
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 58 67 50 57
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 45 58 43 46
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 42 57 47 50
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 38 72 51 60
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 37 45 36 43
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 40 44 40 44
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 39 45 50 58
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 28 35 29 31
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 32 38 34 35
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 51 63 46 45
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 56 64 51 51
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.34 N090.39 N090.02 N090.03
13C3-PFBS (surr.) 1 % 102 114 123 121
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.28 N090.31 N090.02 N090.02
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N092.1 N092.4 N090.14 N090.17
18O2-PFHxS (surr.) 1 % 82 88 91 95
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.10 N090.17 < 0.01 N090.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N092.5 N094.9 N090.09 N090.28
13C8-PFOS (surr.) 1 % 49 63 43 50
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 142 160 175 173
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 92 107 105 107
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 23 of 70
Report Number: 544592-W
Client Sample ID 0990_SW62_17/04/30
0990_SW64_17/04/30
0990_SW68_17/04/30
0990_SW74_17/04/29
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03510 M17-My03511 M17-My03512 M17-My03513
Date Sampled Apr 30, 2017 Apr 30, 2017 Apr 30, 2017 Apr 29, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
13C2-8:2 FTS (surr.) 1 % 75 94 72 75
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - 520 - -
pH 0.1 pH Units - 8.2 - -
Client Sample ID 0990_SW81_17/05/01
0990_QC10SW_17/04/30
0990_QC11SW_17/04/30
0990_QC15SW_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03514 M17-My03515 M17-My03517 M17-My03519
Date Sampled May 01, 2017 Apr 30, 2017 Apr 30, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 0.09 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 88 103 114 107
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01 N090.16 N090.02 N090.04
13C5-PFPeA (surr.) 1 % 91 112 117 105
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01 N090.44 N090.04 N090.11
13C5-PFHxA (surr.) 1 % 100 119 126 114
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 N090.07 < 0.01 N090.02
13C4-PFHpA (surr.) 1 % 97 121 115 109
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 N090.16 N090.01 N090.04
13C8-PFOA (surr.) 1 % 80 115 101 97
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 68 109 91 85
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 56 73 63 53
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 45 59 50 43
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 41 59 52 46
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 34 62 64 55
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 43 66 58 55
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 42 82 68 64
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 42 80 86 67
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 34 66 53 54
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 36 64 54 54
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 24 of 70
Report Number: 544592-W
Client Sample ID 0990_SW81_17/05/01
0990_QC10SW_17/04/30
0990_QC11SW_17/04/30
0990_QC15SW_17/05/01
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03514 M17-My03515 M17-My03517 M17-My03519
Date Sampled May 01, 2017 Apr 30, 2017 Apr 30, 2017 May 01, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 48 57 51 45
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 54 60 52 50
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01 N090.19 N090.03 N090.06
13C3-PFBS (surr.) 1 % 105 119 126 114
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 N090.16 N090.03 N090.06
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01 N091.4 N090.20 N090.45
18O2-PFHxS (surr.) 1 % 82 94 95 89
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 N090.08 N090.01 N090.03
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.02 N093.0 N090.28 N091.1
13C8-PFOS (surr.) 1 % 52 75 59 51
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 143 169 172 149
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 89 131 110 101
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 73 100 79 70
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm - - 680 690
pH 0.1 pH Units - - 8.0 7.8
Client Sample ID 0990_SW21_17/05/01
0990_NT0049MW02_170428
0990_NT0367MW01_170428
0990_NT0077MW01_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03522 M17-My03523 M17-My03524 M17-My03525
Date Sampled May 01, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 0.07 < 0.05 < 0.05
13C4-PFBA (surr.) 1 % 112 121 108 110
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.03 0.06 < 0.01 N090.02
13C5-PFPeA (surr.) 1 % 119 126 122 118
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.10 N090.06 < 0.01 N090.03
13C5-PFHxA (surr.) 1 % 120 127 128 123
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02 N090.03 < 0.01 N090.01
13C4-PFHpA (surr.) 1 % 114 126 125 125
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.03 N090.02 < 0.01 N090.02
13C8-PFOA (surr.) 1 % 102 119 111 117
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 91 119 99 114
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 25 of 70
Report Number: 544592-W
Client Sample ID 0990_SW21_17/05/01
0990_NT0049MW02_170428
0990_NT0367MW01_170428
0990_NT0077MW01_170428
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03522 M17-My03523 M17-My03524 M17-My03525
Date Sampled May 01, 2017 Apr 28, 2017 Apr 28, 2017 Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C6-PFDA (surr.) 1 % 66 110 82 107
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 57 93 82 107
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 56 65 60 65
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 61 72 69 117
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 59 75 52 63
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 66 86 59 80
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 73 104 68 111
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 57 71 36 50
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 53 70 38 61
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 60 78 65 92
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 62 124 105 133
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.06 N090.01 < 0.01 N090.03
13C3-PFBS (surr.) 1 % 121 126 123 124
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.05 N090.01 < 0.01 N090.03
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.40 N090.10 N090.05 N090.26
18O2-PFHxS (surr.) 1 % 92 111 105 108
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.03 < 0.01 < 0.01 N090.02
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.91 N090.21 N090.12 N090.77
13C8-PFOS (surr.) 1 % 63 94 73 88
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 171 179 172 181
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 115 131 120 130
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 92 151 112 156
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 640 - 820 600
pH 0.1 pH Units 8.2 - 7.0 7.1
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 26 of 70
Report Number: 544592-W
Client Sample ID 0990_077MW01_170428
0990_077MW03_170428
0990_NT0046MW01_170429
0990_NT0046MW03_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03526 M17-My03527 M17-My03528 M17-My03529
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 0.11 < 0.05
13C4-PFBA (surr.) 1 % 117 107 104 105
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.02 N090.02 N090.23 < 0.01
13C5-PFPeA (surr.) 1 % 120 109 98 92
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.05 N090.03 N090.65 < 0.01
13C5-PFHxA (surr.) 1 % 126 124 98 103
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 < 0.01 N090.04 < 0.01
13C4-PFHpA (surr.) 1 % 127 125 103 102
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.01 N090.01 N090.05 < 0.01
13C8-PFOA (surr.) 1 % 113 117 94 98
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 109 119 88 98
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 105 108 78 90
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 97 102 67 61
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 64 73 55 50
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 95 72 56 65
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 64 70 49 61
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 77 84 46 68
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 87 100 51 73
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 53 56 34 56
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 63 66 40 58
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 79 89 72 57
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 123 136 73 66
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.04 N090.03 N090.48 < 0.01
13C3-PFBS (surr.) 1 % 126 122 105 105
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L 0.03 N090.02 N090.25 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.37 N090.21 N090.95 < 0.01
18O2-PFHxS (surr.) 1 % 106 108 89 99
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.01 N090.01 N090.04 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.22 N090.32 N090.93 N090.01
13C8-PFOS (surr.) 1 % 85 95 69 81
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 27 of 70
Report Number: 544592-W
Client Sample ID 0990_077MW01_170428
0990_077MW03_170428
0990_NT0046MW01_170429
0990_NT0046MW03_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03526 M17-My03527 M17-My03528 M17-My03529
Date Sampled Apr 28, 2017 Apr 28, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 176 171 152 139
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 126 134 108 113
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-8:2 FTS (surr.) 1 % 144 157 107 121
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 540 790 - 450
pH 0.1 pH Units 7.1 7.0 - 7.5
Client Sample ID 0990_NT0065MW03_170428
0990_NT0050MW01_170429
0990_054MW02_170428
R160990_064MW01_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03530 M17-My03531 M17-My03532 M17-My03533
Date Sampled Apr 28, 2017 Apr 29, 2017 Apr 28, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 2.5 < 0.05 < 0.05 12
13C4-PFBA (surr.) 1 % 75 98 106 131
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N093.9 < 0.01 < 0.01 N0915
13C5-PFPeA (surr.) 1 % 66 104 111 112
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N0917 < 0.01 < 0.01 N0926
13C5-PFHxA (surr.) 1 % 99 111 120 121
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N092.3 < 0.01 < 0.01 N0911
13C4-PFHpA (surr.) 1 % 69 111 117 123
Perfluorooctanoic acid (PFOA) 0.01 ug/L N095.4 < 0.01 < 0.01 N0923
13C8-PFOA (surr.) 1 % 95 101 113 120
Perfluorononanoic acid (PFNA) 0.01 ug/L N090.09 < 0.01 < 0.01 3.1
13C5-PFNA (surr.) 1 % 68 97 101 121
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 0.71
13C6-PFDA (surr.) 1 % 43 90 93 110
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
13C2-PFUnDA (surr.) 1 % 50 90 84 115
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
13C2-PFDoDA (surr.) 1 % 45 67 68 109
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
13C2-PFTeDA (surr.) 1 % 48 127 97 66
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
13C8-FOSA (surr.) 1 % 38 53 55 113
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
D3-N-MeFOSA (surr.) 1 % 43 58 55 93
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
D5-N-EtFOSA (surr.) 1 % 48 74 80 100
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 28 of 70
Report Number: 544592-W
Client Sample ID 0990_NT0065MW03_170428
0990_NT0050MW01_170429
0990_054MW02_170428
R160990_064MW01_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03530 M17-My03531 M17-My03532 M17-My03533
Date Sampled Apr 28, 2017 Apr 29, 2017 Apr 28, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
D7-N-MeFOSE (surr.) 1 % 31 44 43 95
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
D9-N-EtFOSE (surr.) 1 % 30 51 46 92
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
D5-N-EtFOSAA (surr.) 1 % 50 95 74 113
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.3
D3-N-MeFOSAA (surr.) 1 % 52 121 92 107
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N096.1 < 0.01 N090.02 13
13C3-PFBS (surr.) 1 % 109 113 125 136
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N095.6 < 0.01 N090.01 N098.5
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N0934 < 0.01 N090.05 N0970
18O2-PFHxS (surr.) 1 % 97 101 109 121
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N093.0 < 0.01 < 0.01 N0912
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N09110 N090.08 N090.05 N09660
13C8-PFOS (surr.) 1 % 91 76 77 85
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
13C2-4:2 FTS (surr.) 1 % 95 158 170 129
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L 0.17 < 0.05 < 0.05 0.41
13C2-6:2 FTS (surr.) 1 % 78 127 126 117
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L 0.08 < 0.01 < 0.01 25
13C2-8:2 FTS (surr.) 1 % 67 142 130 127
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.3
Conductivity (at 25°C) 1 uS/cm 610 - 810 630
pH 0.1 pH Units 7.5 - 7.0 7.2
Client Sample IDR160990_064MW02_170429
0990_064MW04_170429
0990_064MW05_170429
0990_064MW06_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03534 M17-My03535 M17-My03536 M17-My03537
Date Sampled Apr 29, 2017 Apr 29, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 48 < 0.05 < 0.05 0.05
13C4-PFBA (surr.) 1 % 115 100 90 137
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N09120 < 0.01 N090.01 N090.06
13C5-PFPeA (surr.) 1 % 93 111 91 140
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N09370 N090.01 N090.02 N090.29
13C5-PFHxA (surr.) 1 % 114 117 90 155
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N0963 < 0.01 < 0.01 N090.04
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 29 of 70
Report Number: 544592-W
Client Sample IDR160990_064MW02_170429
0990_064MW04_170429
0990_064MW05_170429
0990_064MW06_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03534 M17-My03535 M17-My03536 M17-My03537
Date Sampled Apr 29, 2017 Apr 29, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C4-PFHpA (surr.) 1 % 101 113 92 155
Perfluorooctanoic acid (PFOA) 0.01 ug/L N09160 < 0.01 < 0.01 N090.09
13C8-PFOA (surr.) 1 % 95 101 86 143
Perfluorononanoic acid (PFNA) 0.01 ug/L N095.4 < 0.01 < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 111 96 87 145
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 65 87 78 136
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 103 76 75 124
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 90 66 69 100
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 56 114 44 65
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 103 54 47 100
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 73 68 48 99
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 67 79 51 123
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 73 45 34 76
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 68 51 35 66
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 103 76 96 96
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.3 < 0.05 < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 98 77 97 100
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L 130 N090.41 N090.17 0.20
13C3-PFBS (surr.) 1 % 102 120 93 152
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N09100 N090.26 N090.07 N090.17
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N09650 N090.82 N090.75 N090.96
18O2-PFHxS (surr.) 1 % 110 99 80 140
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N0938 N090.01 < 0.01 N090.05
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N093600 N090.28 N090.06 N090.22
13C8-PFOS (surr.) 1 % 124 78 66 133
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 72 167 129 174
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L 3.9 < 0.05 < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 86 120 107 127
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L 0.74 < 0.01 < 0.01 < 0.01
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 30 of 70
Report Number: 544592-W
Client Sample IDR160990_064MW02_170429
0990_064MW04_170429
0990_064MW05_170429
0990_064MW06_170429
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My03534 M17-My03535 M17-My03536 M17-My03537
Date Sampled Apr 29, 2017 Apr 29, 2017 Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
13C2-8:2 FTS (surr.) 1 % 95 128 116 123
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.3 < 0.01 < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 480 - - -
pH 0.1 pH Units 7.2 - - -
Client Sample ID 0990_NT0064MW10_170429
0990_SW53_170429
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-My03538 M17-My03539
Date Sampled Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L 0.18 < 0.05
13C4-PFBA (surr.) 1 % 104 113
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.25 < 0.01
13C5-PFPeA (surr.) 1 % 114 105
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N091.1 N090.01
13C5-PFHxA (surr.) 1 % 102 119
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.09 < 0.01
13C4-PFHpA (surr.) 1 % 108 105
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.15 < 0.01
13C8-PFOA (surr.) 1 % 88 84
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01
13C5-PFNA (surr.) 1 % 82 68
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01
13C6-PFDA (surr.) 1 % 76 55
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01
13C2-PFUnDA (surr.) 1 % 77 49
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01
13C2-PFDoDA (surr.) 1 % 54 50
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01
13C2-PFTeDA (surr.) 1 % 104 67
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 47 38
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05
D3-N-MeFOSA (surr.) 1 % 66 43
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05
D5-N-EtFOSA (surr.) 1 % 70 72
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05
D7-N-MeFOSE (surr.) 1 % 47 34
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05
D9-N-EtFOSE (surr.) 1 % 49 33
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 31 of 70
Report Number: 544592-W
Client Sample ID 0990_NT0064MW10_170429
0990_SW53_170429
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-My03538 M17-My03539
Date Sampled Apr 29, 2017 Apr 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05
D5-N-EtFOSAA (surr.) 1 % 78 51
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05
D3-N-MeFOSAA (surr.) 1 % 108 49
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.65 N090.01
13C3-PFBS (surr.) 1 % 112 123
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.45 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N094.3 N090.06
18O2-PFHxS (surr.) 1 % 107 87
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.14 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N093.8 N090.07
13C8-PFOS (surr.) 1 % 69 48
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 172 157
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05
13C2-6:2 FTS (surr.) 1 % 119 94
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L 0.02 < 0.01
13C2-8:2 FTS (surr.) 1 % 124 73
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
Conductivity (at 25°C) 1 uS/cm 200 790
pH 0.1 pH Units 7.5 7.3
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 32 of 70
Report Number: 544592-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
PFOS/PFOA/6:2FTS Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Analysis of PFCs in environmental samples by LC-MS/MS
Conductivity (at 25°C) Brisbane May 08, 2017 28 Day
- Method: LTM-INO-4030
pH Brisbane May 08, 2017 0 Day
- Method: LTM-GEN-7090 pH in water by ISE
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 33 of 70
Report Number: 544592-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_053MW01_170427
Apr 28, 2017 Water M17-My03446 X X X
2 0990_053MW06_170428
Apr 28, 2017 Water M17-My03448 X X X
3 0990_070MW01_170428
Apr 28, 2017 Water M17-My03449 X
4 0990_BCPMW01_170428
Apr 28, 2017 Water M17-My03450 X X X
5 0990_BCRUMW01_170428
Apr 28, 2017 Water M17-My03451 X X X
6 0990_BORE06 Apr 28, 2017 Water M17-My03452 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 34 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
_170428
7 0990_BORE05_170428
Apr 28, 2017 Water M17-My03453 X X X
8 0990_NT0073MW02_170428
Apr 28, 2017 Water M17-My03454X X X
9 0990_NT0050MW02_170429
Apr 29, 2017 Water M17-My03455X X X
10 0990_NT0065MW02_170428
Apr 28, 2017 Water M17-My03456X
11 0990_NT0065MW04_170428
Apr 28, 2017 Water M17-My03457X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 35 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
12 0990_NT0269MW01_170428
Apr 28, 2017 Water M17-My03458X X X
13 0990_NT0269MW02_170428
Apr 28, 2017 Water M17-My03459X X X
14 0990_BORE24_170428
Apr 28, 2017 Water M17-My03460 X
15 0990_NT0048MW1_170428
Apr 28, 2017 Water M17-My03461 X X X
16 0990_NT0064MW11_170429
Apr 29, 2017 Water M17-My03462X X X
17 0990_NT0064MW12_17042
Apr 29, 2017 Water M17-My03463X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 36 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
9
18 0990_NT0064MW13_170429
Apr 29, 2017 Water M17-My03464X X X
19 0990_NT0064MW14_170429
Apr 29, 2017 Water M17-My03465X
20 0990_BORE10_170429
Apr 29, 2017 Water M17-My03466 X X X
21 0990_BORE11_170429
Apr 29, 2017 Water M17-My03467 X X X
22 0990_QC1GW_170428
Apr 28, 2017 Water M17-My03468 X
23 0990_QC2GW_170428
Apr 28, 2017 Water M17-My03469 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 37 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
24 0990_QCSGW_170428
Apr 28, 2017 Water M17-My03473 X
25 0990_QC9GW_170429
Apr 29, 2017 Water M17-My03474 X
26 0990_QC13GW_170430
Apr 30, 2017 Water M17-My03475 X
27 0990_QC18GW_170501
May 01, 2017 Water M17-My03476 X
28 0990_75COLLINS-BORE_170428
Apr 28, 2017 Water M17-My03477X
29 0990_PRIVATE BORE001_170428
Apr 28, 2017 Water M17-My03478X
30 0990_QC6_17 Apr 28, 2017 Water M17-My03479 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 38 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
/04/28
31 0990_QC14_17/04/30
Apr 30, 2017 Water M17-My03480 X
32 0990_SW04_17/04/30
Apr 30, 2017 Water M17-My03481 X
33 0990_SW05_17/04/30
Apr 30, 2017 Water M17-My03482 X
34 0990_SW06_17/04/30
Apr 30, 2017 Water M17-My03483 X X X
35 0990_SW07_17/05/01
May 01, 2017 Water M17-My03484 X
36 0990_SW09_17/05/01
May 01, 2017 Water M17-My03485 X X X
37 0990_SW14_1 May 01, 2017 Water M17-My03486 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 39 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
7/05/01
38 0990_SW16_17/05/01
May 01, 2017 Water M17-My03487 X
39 0990_SW23_17/05/01
May 01, 2017 Water M17-My03488 X
40 0990_SW27_17/05/01
May 01, 2017 Water M17-My03489 X X X
41 0990_SW28_17/05/01
May 01, 2017 Water M17-My03490 X
42 0990_SW29_17/05/01
May 01, 2017 Water M17-My03491 X
43 0990_SW31_17/05/01
May 01, 2017 Water M17-My03492 X X X
44 0990_SW32_1 May 01, 2017 Water M17-My03493 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 40 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
7/05/01
45 0990_SW37_17/04/30
Apr 30, 2017 Water M17-My03494 X X X
46 0990_SW38_17/04/30
Apr 30, 2017 Water M17-My03495 X X X
47 0990_SW39_17/04/30
Apr 30, 2017 Water M17-My03496 X
48 0990_SW44_17/04/30
Apr 30, 2017 Water M17-My03497 X X X
49 0990_SW46_17/04/30
Apr 30, 2017 Water M17-My03498 X
50 0990_SW49_17/04/30
Apr 30, 2017 Water M17-My03499 X
51 0990_SW50_1 May 01, 2017 Water M17-My03500 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 41 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
7/05/01
52 0990_SW51_17/05/01
May 01, 2017 Water M17-My03501 X
53 0990_SW52_17/04/30
Apr 30, 2017 Water M17-My03502 X
54 0990_SW54_17/04/29
Apr 29, 2017 Water M17-My03503 X
55 0990_SW56_17/0430
Apr 30, 2017 Water M17-My03504 X X X
56 0990_SW57_17/04/30
Apr 30, 2017 Water M17-My03505 X
57 0990_SW58_17/04/30
Apr 30, 2017 Water M17-My03506 X X X
58 0990_SW59_1 Apr 30, 2017 Water M17-My03507 X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 42 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
7/04/30
59 0990_SW60_17/04/30
Apr 30, 2017 Water M17-My03508 X
60 0990_SW61_17/04/30
Apr 30, 2017 Water M17-My03509 X X X
61 0990_SW62_17/04/30
Apr 30, 2017 Water M17-My03510 X
62 0990_SW64_17/04/30
Apr 30, 2017 Water M17-My03511 X X X
63 0990_SW68_17/04/30
Apr 30, 2017 Water M17-My03512 X
64 0990_SW74_17/04/29
Apr 29, 2017 Water M17-My03513 X
65 0990_SW81_1 May 01, 2017 Water M17-My03514 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 43 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
7/05/01
66 0990_QC10SW_17/04/30
Apr 30, 2017 Water M17-My03515 X
67 0990_QC11SW_17/04/30
Apr 30, 2017 Water M17-My03517 X X X
68 0990_QC15SW_17/05/01
May 01, 2017 Water M17-My03519 X X X
69 0990_SW21_17/05/01
May 01, 2017 Water M17-My03522 X X X
70 0990_NT0049MW02_170428
Apr 28, 2017 Water M17-My03523X
71 0990_NT0367MW01_170428
Apr 28, 2017 Water M17-My03524X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 44 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
72 0990_NT0077MW01_170428
Apr 28, 2017 Water M17-My03525X X X
73 0990_077MW01_170428
Apr 28, 2017 Water M17-My03526 X X X
74 0990_077MW03_170428
Apr 28, 2017 Water M17-My03527 X X X
75 0990_NT0046MW01_170429
Apr 29, 2017 Water M17-My03528X
76 0990_NT0046MW03_170429
Apr 29, 2017 Water M17-My03529X X X
77 0990_NT0065MW03_17042
Apr 28, 2017 Water M17-My03530X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 45 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
8
78 0990_NT0050MW01_170429
Apr 29, 2017 Water M17-My03531X
79 0990_054MW02_170428
Apr 28, 2017 Water M17-My03532 X X X
80 0990_064MW01_170429
Apr 29, 2017 Water M17-My03533 X X X
81 0990_064MW02_170429
Apr 29, 2017 Water M17-My03534 X X X
82 0990_064MW04_170429
Apr 29, 2017 Water M17-My03535 X
83 0990_064MW05_170429
Apr 29, 2017 Water M17-My03536 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 46 of 70
Report Number: 544592-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 3, 2017 10:00 AMAddress: 3G Marine Pde Report #: 544592 Due: May 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Chris Molloy
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Conductivity (at 25°C
)
HO
LD
pH PF
OS
/PF
OA
/6:2FT
S
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X X X X X
Perth Laboratory - NATA Site # 18217
84 0990_064MW06_170429
Apr 29, 2017 Water M17-My03537 X
85 0990_NT0064MW10_170429
Apr 29, 2017 Water M17-My03538X X X
86 0990_SW53_170429
Apr 29, 2017 Water M17-My03539 X X X
87 0990_053MWA_170428
Apr 29, 2017 Water M17-My03698 X
Test Counts 43 1 43 6 80
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 47 of 70
Report Number: 544592-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
4. Results are uncorrected for matrix spikes or surrogate recoveries.
5. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
6. Samples were analysed on an 'as received' basis. 7. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per Kilogram mg/l: milligrams per litre
ug/l: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100ml: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery
CRM Certified Reference Material - reported as percent recovery
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 48 of 70
Report Number: 544592-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
PFOS/PFOA/6:2FTS
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
PFOS/PFOA/6:2FTS
Perfluorooctanesulfonic acid (PFOS) % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 92 50-150 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 108 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 110 50-150 Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 49 of 70
Report Number: 544592-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 109 50-150 Pass
Perfluorononanoic acid (PFNA) % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) % 113 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 94 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 137 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 103 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 103 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 96 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 102 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 125 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 96 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 99 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 99 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 101 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 99 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 93 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 91 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 88 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03451 CP % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03451 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03451 CP % 87 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03451 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03451 CP % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03451 CP % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03451 CP % 102 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03451 CP % 105 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03451 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03451 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03451 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03451 CP % 103 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03451 CP % 107 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 50 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03451 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03451 CP % 123 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03451 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03451 CP % 89 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03451 CP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03451 CP % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03451 CP % 91 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03451 CP % 92 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03451 CP % 102 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03451 CP % 101 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03451 CP % 109 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03451 CP % 86 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03451 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03451 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03451 CP % 82 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03455 CP % 92 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03455 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03455 CP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03455 CP % 107 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03455 CP % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03455 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03455 CP % 97 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03455 CP % 101 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03455 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03455 CP % 102 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03455 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03455 CP % 103 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03455 CP % 105 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 51 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03455 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03455 CP % 112 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03455 CP % 113 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03455 CP % 82 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03455 CP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03455 CP % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03455 CP % 93 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03455 CP % 94 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03455 CP % 102 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03455 CP % 94 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03455 CP % 94 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03455 CP % 88 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03455 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03455 CP % 101 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03455 CP % 99 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03473 CP % 109 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03473 CP % 123 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03473 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03473 CP % 110 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03473 CP % 108 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03473 CP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03473 CP % 114 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03473 CP % 116 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03473 CP % 111 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03473 CP % 116 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03473 CP % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03473 CP % 81 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03473 CP % 110 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 52 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03473 CP % 107 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03473 CP % 113 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03473 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03473 CP % 96 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03473 CP % 119 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03473 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03473 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03473 CP % 111 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03473 CP % 116 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03473 CP % 112 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03473 CP % 114 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03473 CP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03473 CP % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03473 CP % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03473 CP % 54 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03481 CP % 106 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03481 CP % 113 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03481 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03481 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03481 CP % 104 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03481 CP % 109 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03481 CP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03481 CP % 113 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03481 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03481 CP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03481 CP % 121 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03481 CP % 85 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03481 CP % 110 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 53 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03481 CP % 110 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03481 CP % 117 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03481 CP % 120 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03481 CP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03481 CP % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03481 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03481 CP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03481 CP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03481 CP % 111 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03481 CP % 107 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03481 CP % 116 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03481 CP % 119 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03481 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03481 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03481 CP % 59 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03489 CP % 79 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03489 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03489 CP % 102 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03489 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03489 CP % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03489 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03489 CP % 108 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03489 CP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03489 CP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03489 CP % 93 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03489 CP % 96 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03489 CP % 90 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03489 CP % 101 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 54 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03489 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03489 CP % 95 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03489 CP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03489 CP % 86 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03489 CP % 84 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03489 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03489 CP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03489 CP % 105 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03489 CP % 110 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03489 CP % 87 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03489 CP % 106 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03489 CP % 80 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03489 CP % 106 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03489 CP % 82 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03489 CP % 51 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03504 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03504 CP % 117 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03504 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03504 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03504 CP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03504 CP % 114 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03504 CP % 113 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03504 CP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03504 CP % 96 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03504 CP % 85 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03504 CP % 90 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03504 CP % 89 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03504 CP % 88 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 55 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03504 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03504 CP % 95 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03504 CP % 86 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03504 CP % 97 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03504 CP % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03504 CP % 88 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03504 CP % 87 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03504 CP % 110 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03504 CP % 110 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03504 CP % 105 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03504 CP % 106 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03504 CP % 75 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03504 CP % 112 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03504 CP % 82 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03504 CP % 58 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03507 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03507 CP % 115 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03507 CP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03507 CP % 111 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03507 CP % 126 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03507 CP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03507 CP % 109 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03507 CP % 115 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03507 CP % 118 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03507 CP % 115 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03507 CP % 116 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03507 CP % 124 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03507 CP % 111 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 56 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03507 CP % 119 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03507 CP % 118 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03507 CP % 119 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03507 CP % 121 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03507 CP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03507 CP % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03507 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03507 CP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03507 CP % 103 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03507 CP % 107 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03507 CP % 112 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03507 CP % 96 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03507 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03507 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03507 CP % 71 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03523 CP % 109 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03523 CP % 119 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03523 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03523 CP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03523 CP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03523 CP % 117 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03523 CP % 113 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03523 CP % 117 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03523 CP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03523 CP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03523 CP % 114 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03523 CP % 116 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03523 CP % 111 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 57 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03523 CP % 117 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03523 CP % 115 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03523 CP % 106 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03523 CP % 106 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03523 CP % 103 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03523 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03523 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03523 CP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03523 CP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03523 CP % 110 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03523 CP % 102 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03523 CP % 96 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03523 CP % 115 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03523 CP % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03523 CP % 56 50-150 Pass
Spike - % Recovery
PFOS/PFOA/6:2FTS Result 1
Perfluorooctanesulfonic acid(PFOS) M17-My03528 CP % 95 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03528 CP % 114 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03528 CP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03528 CP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03528 CP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03528 CP % 118 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03528 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03528 CP % 111 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03528 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03528 CP % 103 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03528 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03528 CP % 100 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03528 CP % 105 50-150 Pass
Spike - % Recovery
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 58 of 70
Report Number: 544592-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03528 CP % 113 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03528 CP % 111 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03528 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03528 CP % 118 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03528 CP % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03528 CP % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03528 CP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03528 CP % 112 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03528 CP % 104 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03528 CP % 115 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03528 CP % 98 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03528 CP % 91 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03528 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03528 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03528 CP % 65 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Conductivity (at 25°C) M17-My03446 CP uS/cm 1000 970 6.4 30% Pass
pH M17-My03446 CP pH Units 6.9 6.9 pass 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03449 CP ug/L 0.07 0.09 15 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03449 CP ug/L 0.01 0.01 2.0 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03449 CP ug/L 0.02 0.02 3.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03449 CP ug/L 0.09 0.09 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 59 of 70
Report Number: 544592-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluoroundecanoic acid (PFUnA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03449 CP ug/L 0.08 0.08 3.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03449 CP ug/L 0.05 0.05 3.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03449 CP ug/L 0.18 0.17 3.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03454 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 60 of 70
Report Number: 544592-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorododecanoic acid (PFDoA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Conductivity (at 25°C) M17-My03461 CP uS/cm 330 340 3.6 30% Pass
pH M17-My03461 CP pH Units 8.0 8.0 pass 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03469 CP ug/L 0.25 0.26 4.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03469 CP ug/L 0.01 0.01 3.0 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 61 of 70
Report Number: 544592-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03469 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03469 CP ug/L 0.06 0.06 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03469 CP ug/L 0.04 0.04 3.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03469 CP ug/L 0.04 0.04 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03469 CP ug/L 0.42 0.42 1.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03469 CP ug/L 0.01 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 62 of 70
Report Number: 544592-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03488 CP ug/L 0.81 0.63 25 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03488 CP ug/L 0.03 0.03 2.0 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 63 of 70
Report Number: 544592-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03488 CP ug/L 0.02 0.02 8.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03488 CP ug/L 0.10 0.10 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03488 CP ug/L 0.02 0.02 1.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03488 CP ug/L 0.06 0.06 2.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03488 CP ug/L 0.05 0.05 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03488 CP ug/L 0.40 0.38 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03488 CP ug/L 0.03 0.03 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Conductivity (at 25°C) M17-My03494 CP uS/cm 710 710 <1 30% Pass
pH M17-My03494 CP pH Units 7.9 8.0 pass 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 64 of 70
Report Number: 544592-W
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03503 CP ug/L 0.23 0.17 27 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03503 CP ug/L 0.01 < 0.01 5.0 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03503 CP ug/L 0.02 0.02 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03503 CP ug/L 0.04 0.04 5.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03503 CP ug/L 0.03 0.02 7.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03503 CP ug/L 0.02 0.02 5.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03503 CP ug/L 0.15 0.14 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03503 CP ug/L 0.01 0.01 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 65 of 70
Report Number: 544592-W
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03506 CP ug/L 0.25 0.23 9.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03506 CP ug/L 0.01 0.01 5.0 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03506 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03506 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03506 CP ug/L 0.03 0.03 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03506 CP ug/L 0.03 0.03 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03506 CP ug/L 0.19 0.19 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03506 CP ug/L 0.01 0.01 7.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 66 of 70
Report Number: 544592-W
Duplicate
Result 1 Result 2 RPD
Conductivity (at 25°C) M17-My03519 CP uS/cm 690 690 <1 30% Pass
pH M17-My03519 CP pH Units 7.8 7.8 pass 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03522 CP ug/L 0.91 1.0 9.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03522 CP ug/L 0.03 0.03 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03522 CP ug/L 0.03 0.03 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03522 CP ug/L 0.10 0.10 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03522 CP ug/L 0.02 0.01 3.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03522 CP ug/L 0.06 0.06 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03522 CP ug/L 0.05 0.05 4.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03522 CP ug/L 0.40 0.37 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03522 CP ug/L 0.03 0.03 13 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 67 of 70
Report Number: 544592-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
PFOS/PFOA/6:2FTS Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-My03529 CP ug/L 0.01 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 68 of 70
Report Number: 544592-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Conductivity (at 25°C) M17-My03534 CP uS/cm 480 480 <1 30% Pass
pH M17-My03534 CP pH Units 7.2 7.2 pass 30% Pass
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 69 of 70
Report Number: 544592-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
R16 The LORs have been raised due to the high concentration of one or more analytes
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: May 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 70 of 70
Report Number: 544592-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 544592-W-V2
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date May 03, 2017
Client Sample ID0990_75COLLINS-BORE_170428
Sample Matrix Water
Eurofins | mgt Sample No. M17-My03477
Date Sampled Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.02
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.12
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.04
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 120
13C5-PFPeA (surr.) 1 % 117
13C5-PFHxA (surr.) 1 % 109
13C4-PFHpA (surr.) 1 % 108
13C8-PFOA (surr.) 1 % 108
13C5-PFNA (surr.) 1 % 109
13C6-PFDA (surr.) 1 % 80
13C2-PFUnDA (surr.) 1 % 55
13C2-PFDoDA (surr.) 1 % 40
13C2-PFTeDA (surr.) 1 % 18
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 79
D3-N-MeFOSA (surr.) 1 % 56
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 27
Report Number: 544592-W-V2
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_75COLLINS-BORE_170428
Sample Matrix Water
Eurofins | mgt Sample No. M17-My03477
Date Sampled Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 56
D7-N-MeFOSE (surr.) 1 % 57
D9-N-EtFOSE (surr.) 1 % 50
D5-N-EtFOSAA (surr.) 1 % 65
D3-N-MeFOSAA (surr.) 1 % 69
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.11
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.11
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.74
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.05
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.5
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 113
18O2-PFHxS (surr.) 1 % 101
13C8-PFOS (surr.) 1 % 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 120
13C2-6:2 FTS (surr.) 1 % 88
13C2-8:2 FTS (surr.) 1 % 80
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 27
Report Number: 544592-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 27
Report Number: 544592-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 27
Report Number: 544592-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 108 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 110 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 109 50-150 Pass
Perfluorononanoic acid (PFNA) % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) % 113 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 94 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 137 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 27
Report Number: 544592-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 103 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 103 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 96 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 102 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 125 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 96 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 99 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 99 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 101 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 99 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 93 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 91 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 88 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03451 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03451 CP % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03451 CP % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03451 CP % 102 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03451 CP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03451 CP % 105 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03451 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03451 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03451 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03451 CP % 103 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03451 CP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03451 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03451 CP % 123 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03451 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03451 CP % 89 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03451 CP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03451 CP % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03451 CP % 91 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-My03451 CP % 92 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03451 CP % 102 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03451 CP % 101 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03451 CP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03451 CP % 100 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03451 CP % 86 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03451 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03451 CP % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03451 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03451 CP % 82 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03455 CP % 107 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03455 CP % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03455 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03455 CP % 97 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03455 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03455 CP % 101 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03455 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03455 CP % 102 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03455 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03455 CP % 103 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03455 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03455 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03455 CP % 112 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03455 CP % 113 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03455 CP % 82 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03455 CP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03455 CP % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03455 CP % 93 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03455 CP % 94 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) M17-My03455 CP % 102 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03455 CP % 94 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03455 CP % 94 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03455 CP % 92 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03455 CP % 88 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03455 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03455 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03455 CP % 101 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03455 CP % 99 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03473 CP % 110 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03473 CP % 108 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03473 CP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03473 CP % 114 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03473 CP % 123 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03473 CP % 116 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03473 CP % 111 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03473 CP % 116 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03473 CP % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03473 CP % 81 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03473 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03473 CP % 107 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03473 CP % 113 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03473 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03473 CP % 96 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03473 CP % 119 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03473 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03473 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03473 CP % 111 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03473 CP % 116 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorohexanesulfonic acid(PFHxS) M17-My03473 CP % 112 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03473 CP % 114 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03473 CP % 109 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03473 CP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03473 CP % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03473 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03473 CP % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03473 CP % 54 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S17-My04377 NCP % 110 50-150 Pass
Perfluoropentanoic acid (PFPeA) S17-My04377 NCP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) S17-My04377 NCP % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S17-My04377 NCP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) S17-My04377 NCP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) S17-My04377 NCP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) S17-My04377 NCP % 108 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S17-My04377 NCP % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) S17-My04377 NCP % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S17-My04377 NCP % 135 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S17-My04377 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S17-My04377 NCP % 116 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S17-My04377 NCP % 111 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S17-My04377 NCP % 100 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S17-My04377 NCP % 117 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S17-My04377 NCP % 96 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S17-My04377 NCP % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S17-My04377 NCP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S17-My04377 NCP % 111 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S17-My04377 NCP % 118 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S17-My04377 NCP % 108 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroheptanesulfonic acid(PFHpS) S17-My04377 NCP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S17-My04377 NCP % 110 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S17-My04377 NCP % 89 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S17-My04377 NCP % 111 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S17-My04377 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S17-My04377 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S17-My04377 NCP % 71 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03481 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03481 CP % 104 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03481 CP % 109 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03481 CP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03481 CP % 113 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03481 CP % 113 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03481 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03481 CP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03481 CP % 121 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03481 CP % 85 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03481 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03481 CP % 110 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03481 CP % 117 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03481 CP % 120 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03481 CP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03481 CP % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03481 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03481 CP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03481 CP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03481 CP % 111 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03481 CP % 107 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03481 CP % 116 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorooctanesulfonic acid(PFOS) M17-My03481 CP % 106 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03481 CP % 119 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03481 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03481 CP % 105 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03481 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03481 CP % 59 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03489 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03489 CP % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03489 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03489 CP % 108 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03489 CP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03489 CP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03489 CP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03489 CP % 93 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03489 CP % 96 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03489 CP % 90 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03489 CP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03489 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03489 CP % 95 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03489 CP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03489 CP % 86 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03489 CP % 84 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03489 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03489 CP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03489 CP % 105 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03489 CP % 110 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03489 CP % 87 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03489 CP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03489 CP % 79 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorodecanesulfonic acid(PFDS) M17-My03489 CP % 80 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03489 CP % 106 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03489 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03489 CP % 82 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03489 CP % 51 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03504 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03504 CP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03504 CP % 114 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03504 CP % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03504 CP % 117 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03504 CP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03504 CP % 96 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03504 CP % 85 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03504 CP % 90 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03504 CP % 89 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03504 CP % 88 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03504 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03504 CP % 95 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03504 CP % 86 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03504 CP % 97 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03504 CP % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03504 CP % 88 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03504 CP % 87 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03504 CP % 110 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03504 CP % 110 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03504 CP % 105 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03504 CP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03504 CP % 95 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03504 CP % 75 50-150 Pass
Spike - % Recovery
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03504 CP % 112 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03504 CP % 105 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03504 CP % 82 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03504 CP % 58 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03507 CP % 111 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03507 CP % 126 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03507 CP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03507 CP % 109 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03507 CP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03507 CP % 115 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03507 CP % 118 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03507 CP % 115 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03507 CP % 116 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03507 CP % 124 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03507 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03507 CP % 119 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03507 CP % 118 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03507 CP % 119 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03507 CP % 121 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03507 CP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03507 CP % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03507 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03507 CP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03507 CP % 103 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03507 CP % 107 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03507 CP % 112 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03507 CP % 99 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03507 CP % 96 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03507 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03507 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03507 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03507 CP % 71 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03523 CP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03523 CP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03523 CP % 117 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03523 CP % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03523 CP % 119 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03523 CP % 117 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03523 CP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03523 CP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03523 CP % 114 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03523 CP % 116 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03523 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03523 CP % 117 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03523 CP % 115 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03523 CP % 106 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03523 CP % 106 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03523 CP % 103 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03523 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03523 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03523 CP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03523 CP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03523 CP % 110 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03523 CP % 102 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03523 CP % 109 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03523 CP % 96 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03523 CP % 115 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03523 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03523 CP % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03523 CP % 56 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03528 CP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03528 CP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03528 CP % 118 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03528 CP % 104 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03528 CP % 114 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03528 CP % 111 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03528 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03528 CP % 103 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03528 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03528 CP % 100 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03528 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03528 CP % 113 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03528 CP % 111 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03528 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03528 CP % 118 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03528 CP % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03528 CP % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03528 CP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03528 CP % 112 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03528 CP % 104 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03528 CP % 115 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03528 CP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03528 CP % 95 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03528 CP % 91 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 27
Report Number: 544592-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03528 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03528 CP % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03528 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03528 CP % 65 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03449 CP ug/L 0.02 0.02 3.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03449 CP ug/L 0.09 0.09 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03449 CP ug/L 0.01 0.01 2.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03449 CP ug/L 0.08 0.08 3.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03449 CP ug/L 0.05 0.05 3.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03449 CP ug/L 0.18 0.17 3.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03449 CP ug/L 0.07 0.09 15 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03454 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03469 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03469 CP ug/L 0.06 0.06 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03469 CP ug/L 0.01 0.01 3.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03469 CP ug/L 0.04 0.04 3.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03469 CP ug/L 0.04 0.04 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03469 CP ug/L 0.42 0.42 1.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03469 CP ug/L 0.01 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03469 CP ug/L 0.25 0.26 4.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03488 CP ug/L 0.02 0.02 8.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03488 CP ug/L 0.10 0.10 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03488 CP ug/L 0.02 0.02 1.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03488 CP ug/L 0.03 0.03 2.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03488 CP ug/L 0.06 0.06 2.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03488 CP ug/L 0.05 0.05 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03488 CP ug/L 0.40 0.38 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03488 CP ug/L 0.03 0.03 9.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03488 CP ug/L 0.81 0.63 25 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03503 CP ug/L 0.02 0.02 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03503 CP ug/L 0.04 0.04 5.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03503 CP ug/L 0.01 < 0.01 5.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03503 CP ug/L 0.03 0.02 7.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03503 CP ug/L 0.02 0.02 5.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03503 CP ug/L 0.15 0.14 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03503 CP ug/L 0.01 0.01 5.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03503 CP ug/L 0.23 0.17 27 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03506 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03506 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03506 CP ug/L 0.01 0.01 5.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03506 CP ug/L 0.03 0.03 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03506 CP ug/L 0.03 0.03 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03506 CP ug/L 0.19 0.19 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03506 CP ug/L 0.01 0.01 7.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03506 CP ug/L 0.25 0.23 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 23 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03522 CP ug/L 0.03 0.03 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03522 CP ug/L 0.10 0.10 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03522 CP ug/L 0.02 0.01 3.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03522 CP ug/L 0.03 0.03 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03522 CP ug/L 0.06 0.06 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03522 CP ug/L 0.05 0.05 4.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03522 CP ug/L 0.40 0.37 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03522 CP ug/L 0.03 0.03 13 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03522 CP ug/L 0.91 1.0 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 24 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03529 CP ug/L 0.01 0.01 2.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 25 of 27
Report Number: 544592-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 26 of 27
Report Number: 544592-W-V2
Comments
V2- Split report
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
R16 The LORs have been raised due to the high concentration of one or more analytes
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 27 of 27
Report Number: 544592-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 544592-W-V3
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date May 03, 2017
Client Sample ID0990_PRIVATEBORE001_170428
Sample Matrix Water
Eurofins | mgt Sample No. M17-My03478
Date Sampled Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.03
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.15
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.02
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.05
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 128
13C5-PFPeA (surr.) 1 % 135
13C5-PFHxA (surr.) 1 % 128
13C4-PFHpA (surr.) 1 % 126
13C8-PFOA (surr.) 1 % 126
13C5-PFNA (surr.) 1 % 109
13C6-PFDA (surr.) 1 % 89
13C2-PFUnDA (surr.) 1 % 89
13C2-PFDoDA (surr.) 1 % 95
13C2-PFTeDA (surr.) 1 % 88
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 93
D3-N-MeFOSA (surr.) 1 % 96
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 29
Report Number: 544592-W-V3
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_PRIVATEBORE001_170428
Sample Matrix Water
Eurofins | mgt Sample No. M17-My03478
Date Sampled Apr 28, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 91
D7-N-MeFOSE (surr.) 1 % 83
D9-N-EtFOSE (surr.) 1 % 79
D5-N-EtFOSAA (surr.) 1 % 71
D3-N-MeFOSAA (surr.) 1 % 73
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L N090.14
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.15
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N090.95
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.07
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.9
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 140
18O2-PFHxS (surr.) 1 % 121
13C8-PFOS (surr.) 1 % 91
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 165
13C2-6:2 FTS (surr.) 1 % 114
13C2-8:2 FTS (surr.) 1 % 102
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 29
Report Number: 544592-W-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 03, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 29
Report Number: 544592-W-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 29
Report Number: 544592-W-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 108 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 110 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 109 50-150 Pass
Perfluorononanoic acid (PFNA) % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) % 113 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 94 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 137 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 29
Report Number: 544592-W-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 103 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 103 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 96 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 102 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 125 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 96 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 99 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 99 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 101 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 99 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 93 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 91 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 88 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03451 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03451 CP % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03451 CP % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03451 CP % 102 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03451 CP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03451 CP % 105 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03451 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03451 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03451 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03451 CP % 103 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03451 CP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03451 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03451 CP % 123 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03451 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03451 CP % 89 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03451 CP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03451 CP % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03451 CP % 91 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-My03451 CP % 92 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03451 CP % 102 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03451 CP % 101 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03451 CP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03451 CP % 100 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03451 CP % 86 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03451 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03451 CP % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03451 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03451 CP % 82 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03455 CP % 107 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03455 CP % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03455 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03455 CP % 97 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03455 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03455 CP % 101 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03455 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03455 CP % 102 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03455 CP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03455 CP % 103 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03455 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03455 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03455 CP % 112 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03455 CP % 113 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03455 CP % 82 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03455 CP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03455 CP % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03455 CP % 93 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03455 CP % 94 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) M17-My03455 CP % 102 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03455 CP % 94 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03455 CP % 94 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03455 CP % 92 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03455 CP % 88 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03455 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03455 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03455 CP % 101 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03455 CP % 99 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03473 CP % 110 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03473 CP % 108 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03473 CP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03473 CP % 114 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03473 CP % 123 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03473 CP % 116 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03473 CP % 111 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03473 CP % 116 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03473 CP % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03473 CP % 81 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03473 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03473 CP % 107 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03473 CP % 113 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03473 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03473 CP % 96 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03473 CP % 119 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03473 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03473 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03473 CP % 111 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03473 CP % 116 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorohexanesulfonic acid(PFHxS) M17-My03473 CP % 112 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03473 CP % 114 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03473 CP % 109 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03473 CP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03473 CP % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03473 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03473 CP % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03473 CP % 54 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S17-My04377 NCP % 110 50-150 Pass
Perfluoropentanoic acid (PFPeA) S17-My04377 NCP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) S17-My04377 NCP % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S17-My04377 NCP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) S17-My04377 NCP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) S17-My04377 NCP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) S17-My04377 NCP % 108 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S17-My04377 NCP % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) S17-My04377 NCP % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S17-My04377 NCP % 135 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S17-My04377 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S17-My04377 NCP % 116 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S17-My04377 NCP % 111 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S17-My04377 NCP % 100 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S17-My04377 NCP % 117 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S17-My04377 NCP % 96 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S17-My04377 NCP % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S17-My04377 NCP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S17-My04377 NCP % 111 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S17-My04377 NCP % 118 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S17-My04377 NCP % 108 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroheptanesulfonic acid(PFHpS) S17-My04377 NCP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) S17-My04377 NCP % 110 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S17-My04377 NCP % 89 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S17-My04377 NCP % 111 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S17-My04377 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S17-My04377 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S17-My04377 NCP % 71 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) S17-My04377 NCP % 110 50-150 Pass
Perfluoropentanoic acid (PFPeA) S17-My04377 NCP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) S17-My04377 NCP % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) S17-My04377 NCP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) S17-My04377 NCP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) S17-My04377 NCP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) S17-My04377 NCP % 108 50-150 Pass
Perfluoroundecanoic acid (PFUnA) S17-My04377 NCP % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) S17-My04377 NCP % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) S17-My04377 NCP % 135 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) S17-My04377 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) S17-My04377 NCP % 116 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S17-My04377 NCP % 111 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S17-My04377 NCP % 100 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S17-My04377 NCP % 117 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S17-My04377 NCP % 96 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S17-My04377 NCP % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S17-My04377 NCP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) S17-My04377 NCP % 111 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) S17-My04377 NCP % 118 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) S17-My04377 NCP % 108 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) S17-My04377 NCP % 109 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorooctanesulfonic acid(PFOS) S17-My04377 NCP % 110 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) S17-My04377 NCP % 89 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S17-My04377 NCP % 111 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S17-My04377 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S17-My04377 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S17-My04377 NCP % 71 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03481 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03481 CP % 104 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03481 CP % 109 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03481 CP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03481 CP % 113 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03481 CP % 113 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03481 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03481 CP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03481 CP % 121 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03481 CP % 85 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03481 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03481 CP % 110 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03481 CP % 117 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03481 CP % 120 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03481 CP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03481 CP % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03481 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03481 CP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03481 CP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03481 CP % 111 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03481 CP % 107 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03481 CP % 116 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03481 CP % 106 50-150 Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorodecanesulfonic acid(PFDS) M17-My03481 CP % 119 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03481 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03481 CP % 105 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03481 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03481 CP % 59 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03489 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03489 CP % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03489 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03489 CP % 108 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03489 CP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03489 CP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03489 CP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03489 CP % 93 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03489 CP % 96 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03489 CP % 90 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03489 CP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03489 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03489 CP % 95 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03489 CP % 87 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03489 CP % 86 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03489 CP % 84 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03489 CP % 93 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03489 CP % 96 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03489 CP % 105 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03489 CP % 110 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03489 CP % 87 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03489 CP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03489 CP % 79 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03489 CP % 80 50-150 Pass
Spike - % Recovery
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03489 CP % 106 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03489 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03489 CP % 82 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03489 CP % 51 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03504 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03504 CP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03504 CP % 114 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03504 CP % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03504 CP % 117 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03504 CP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03504 CP % 96 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03504 CP % 85 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03504 CP % 90 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03504 CP % 89 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03504 CP % 88 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03504 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03504 CP % 95 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03504 CP % 86 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03504 CP % 97 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03504 CP % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03504 CP % 88 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03504 CP % 87 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03504 CP % 110 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03504 CP % 110 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03504 CP % 105 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03504 CP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03504 CP % 95 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03504 CP % 75 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03504 CP % 112 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03504 CP % 105 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03504 CP % 82 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03504 CP % 58 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03507 CP % 111 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03507 CP % 126 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03507 CP % 113 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03507 CP % 109 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03507 CP % 115 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03507 CP % 115 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03507 CP % 118 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03507 CP % 115 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03507 CP % 116 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03507 CP % 124 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03507 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03507 CP % 119 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03507 CP % 118 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03507 CP % 119 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03507 CP % 121 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03507 CP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03507 CP % 121 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03507 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03507 CP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03507 CP % 103 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03507 CP % 107 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03507 CP % 112 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03507 CP % 99 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03507 CP % 96 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03507 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03507 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03507 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03507 CP % 71 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03523 CP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03523 CP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03523 CP % 117 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03523 CP % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03523 CP % 119 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03523 CP % 117 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03523 CP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03523 CP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03523 CP % 114 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03523 CP % 116 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03523 CP % 111 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03523 CP % 117 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03523 CP % 115 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03523 CP % 106 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03523 CP % 106 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03523 CP % 103 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03523 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03523 CP % 110 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03523 CP % 113 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03523 CP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03523 CP % 110 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03523 CP % 102 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03523 CP % 109 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03523 CP % 96 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03523 CP % 115 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03523 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03523 CP % 100 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03523 CP % 56 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My03528 CP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My03528 CP % 124 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My03528 CP % 118 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My03528 CP % 104 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My03528 CP % 114 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My03528 CP % 111 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My03528 CP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My03528 CP % 103 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My03528 CP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03528 CP % 100 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03528 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My03528 CP % 113 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03528 CP % 111 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03528 CP % 99 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03528 CP % 118 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03528 CP % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03528 CP % 109 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03528 CP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My03528 CP % 112 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03528 CP % 104 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03528 CP % 115 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03528 CP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03528 CP % 95 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03528 CP % 91 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 29
Report Number: 544592-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03528 CP % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03528 CP % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03528 CP % 94 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03528 CP % 65 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03449 CP ug/L 0.02 0.02 3.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03449 CP ug/L 0.09 0.09 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03449 CP ug/L 0.01 0.01 2.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03449 CP ug/L 0.08 0.08 3.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03449 CP ug/L 0.05 0.05 3.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03449 CP ug/L 0.18 0.17 3.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03449 CP ug/L 0.07 0.09 15 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03449 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03449 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03454 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03454 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03454 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03469 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03469 CP ug/L 0.06 0.06 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03469 CP ug/L 0.01 0.01 3.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03469 CP ug/L 0.04 0.04 3.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03469 CP ug/L 0.04 0.04 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03469 CP ug/L 0.42 0.42 1.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03469 CP ug/L 0.01 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03469 CP ug/L 0.25 0.26 4.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03469 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03469 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S17-My04378 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S17-My04378 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) S17-My04378 NCP ug/L < 0.05 ** 5.0 30% Pass
Perfluoropentanoic acid (PFPeA) S17-My04378 NCP ug/L < 0.01 ** 1.0 30% Pass
Perfluorohexanoic acid (PFHxA) S17-My04378 NCP ug/L < 0.01 ** 14 30% Pass
Perfluoroheptanoic acid (PFHpA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorooctanoic acid (PFOA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorononanoic acid (PFNA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorodecanoic acid (PFDA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoroundecanoic acid (PFUnA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorododecanoic acid (PFDoA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) S17-My04378 NCP ug/L < 0.05 ** <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) S17-My04378 NCP ug/L < 0.01 ** 22 30% Pass
Perfluorodecanesulfonic acid(PFDS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) S17-My04378 NCP ug/L < 0.05 ** 21 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) S17-My04378 NCP ug/L < 0.01 ** <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03479 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03479 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03488 CP ug/L 0.02 0.02 8.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03488 CP ug/L 0.10 0.10 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03488 CP ug/L 0.02 0.02 1.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03488 CP ug/L 0.03 0.03 2.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03488 CP ug/L 0.06 0.06 2.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03488 CP ug/L 0.05 0.05 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03488 CP ug/L 0.40 0.38 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03488 CP ug/L 0.03 0.03 9.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03488 CP ug/L 0.81 0.63 25 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 23 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03488 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03503 CP ug/L 0.02 0.02 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03503 CP ug/L 0.04 0.04 5.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03503 CP ug/L 0.01 < 0.01 5.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03503 CP ug/L 0.03 0.02 7.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03503 CP ug/L 0.02 0.02 5.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03503 CP ug/L 0.15 0.14 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03503 CP ug/L 0.01 0.01 5.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03503 CP ug/L 0.23 0.17 27 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 24 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03503 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03503 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03506 CP ug/L 0.02 0.02 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03506 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03506 CP ug/L 0.01 0.01 5.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03506 CP ug/L 0.03 0.03 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03506 CP ug/L 0.03 0.03 1.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03506 CP ug/L 0.19 0.19 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03506 CP ug/L 0.01 0.01 7.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03506 CP ug/L 0.25 0.23 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 25 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03506 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03506 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03522 CP ug/L 0.03 0.03 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03522 CP ug/L 0.10 0.10 2.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03522 CP ug/L 0.02 0.01 3.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03522 CP ug/L 0.03 0.03 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03522 CP ug/L 0.06 0.06 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03522 CP ug/L 0.05 0.05 4.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03522 CP ug/L 0.40 0.37 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03522 CP ug/L 0.03 0.03 13 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03522 CP ug/L 0.91 1.0 9.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 26 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03522 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03522 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My03529 CP ug/L 0.01 0.01 2.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 27 of 29
Report Number: 544592-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My03529 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My03529 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 28 of 29
Report Number: 544592-W-V3
Comments
V3- Split report
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
R16 The LORs have been raised due to the high concentration of one or more analytes
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Inorganic (QLD)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: May 10, 2017
Date Reported: May 12, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 29 of 29
Report Number: 544592-W-V3
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 546502-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date May 16, 2017
Client Sample ID0990_TDL220COLLINRD -BORE
0990_TDL220COLLINRD -TANK1
0990_TDL220COLLINRD -TAP1
0990_TDL1661STUART BORE
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My16593 M17-My16594 M17-My16595 M17-My16596
Date Sampled May 12, 2017 May 12, 2017 May 12, 2017 May 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.04 N090.04 N090.03 < 0.01
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.21 N090.22 N090.16 < 0.01
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.03 N090.03 N090.02 < 0.01
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.07 N090.07 N090.05 < 0.01
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 91 100 96 83
13C5-PFPeA (surr.) 1 % 114 122 115 103
13C5-PFHxA (surr.) 1 % 117 118 120 113
13C4-PFHpA (surr.) 1 % 136 137 141 123
13C8-PFOA (surr.) 1 % 118 124 125 110
13C5-PFNA (surr.) 1 % 109 124 138 102
13C6-PFDA (surr.) 1 % 53 61 69 65
13C2-PFUnDA (surr.) 1 % 52 63 60 45
13C2-PFDoDA (surr.) 1 % 47 53 64 49
13C2-PFTeDA (surr.) 1 % 22 20 23 26
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 73 87 86 59
D3-N-MeFOSA (surr.) 1 % 40 53 63 26
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 546502-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_TDL220COLLINRD -BORE
0990_TDL220COLLINRD -TANK1
0990_TDL220COLLINRD -TAP1
0990_TDL1661STUART BORE
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-My16593 M17-My16594 M17-My16595 M17-My16596
Date Sampled May 12, 2017 May 12, 2017 May 12, 2017 May 12, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 30 42 52 22
D7-N-MeFOSE (surr.) 1 % 37 39 48 20
D9-N-EtFOSE (surr.) 1 % 35 40 46 25
D5-N-EtFOSAA (surr.) 1 % 55 58 63 44
D3-N-MeFOSAA (surr.) 1 % 56 59 69 47
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L 0.14 0.14 0.10 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.14 0.13 N090.11 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N091.4 N091.5 N091.1 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.08 N090.08 N090.05 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N092.8 N093.1 N092.0 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 115 115 119 130
18O2-PFHxS (surr.) 1 % 80 84 86 123
13C8-PFOS (surr.) 1 % 64 65 78 97
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 241 235 243 177
13C2-6:2 FTS (surr.) 1 % 163 171 176 133
13C2-8:2 FTS (surr.) 1 % 85 93 98 78
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 546502-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 546502-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 16, 2017 12:32 PMAddress: 3G Marine Pde Report #: 546502 Due: May 23, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_TDL220COLLINRD -BORE
May 12, 2017 Water M17-My16593X
2 0990_TDL220COLLINRD -TANK1
May 12, 2017 Water M17-My16594X
3 0990_TDL220COLLINRD -TAP1
May 12, 2017 Water M17-My16595X
4 0990_TDL1661STUARTBORE
May 12, 2017 Water M17-My16596X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 546502-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: May 16, 2017 12:32 PMAddress: 3G Marine Pde Report #: 546502 Due: May 23, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
Test Counts 4
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 546502-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 546502-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 101 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) % 103 50-150 Pass
Perfluorononanoic acid (PFNA) % 103 50-150 Pass
Perfluorodecanoic acid (PFDA) % 111 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 98 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 144 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 546502-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 93 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 117 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 112 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 109 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 110 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 90 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 91 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 103 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 93 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 97 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 97 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 112 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 130 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My16594 CP % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My16594 CP % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My16594 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My16594 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My16594 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My16594 CP % 104 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My16594 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My16594 CP % 105 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My16594 CP % 100 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16594 CP % 146 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16594 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My16594 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16594 CP % 97 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16594 CP % 115 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16594 CP % 106 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16594 CP % 108 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16594 CP % 111 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16594 CP % 106 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 546502-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-My16594 CP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16594 CP % 87 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16594 CP % 95 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16594 CP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16594 CP % 86 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16594 CP % 100 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16594 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16594 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16594 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16594 CP % 138 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My16593 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My16593 CP ug/L 0.21 0.21 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My16593 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My16593 CP ug/L 0.07 0.06 7.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 546502-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My16593 CP ug/L 0.14 0.13 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16593 CP ug/L 0.14 0.14 6.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16593 CP ug/L 1.4 1.4 5.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16593 CP ug/L 0.08 0.07 12 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16593 CP ug/L 2.8 2.6 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 546502-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 546502-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 546502-W-V2
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date May 16, 2017
Client Sample ID0990_TDL220COLLINSRD -BORE
0990_TDL220COLLINSRD -TANK1
0990_TDL220COLLINSRD -TAP1
Sample Matrix Water Water Water
Eurofins | mgt Sample No. M17-My16593 M17-My16594 M17-My16595
Date Sampled May 12, 2017 May 12, 2017 May 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L N090.04 N090.04 N090.03
Perfluorohexanoic acid (PFHxA) 0.01 ug/L N090.21 N090.22 N090.16
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L N090.03 N090.03 N090.02
Perfluorooctanoic acid (PFOA) 0.01 ug/L N090.07 N090.07 N090.05
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 91 100 96
13C5-PFPeA (surr.) 1 % 114 122 115
13C5-PFHxA (surr.) 1 % 117 118 120
13C4-PFHpA (surr.) 1 % 136 137 141
13C8-PFOA (surr.) 1 % 118 124 125
13C5-PFNA (surr.) 1 % 109 124 138
13C6-PFDA (surr.) 1 % 53 61 69
13C2-PFUnDA (surr.) 1 % 52 63 60
13C2-PFDoDA (surr.) 1 % 47 53 64
13C2-PFTeDA (surr.) 1 % 22 20 23
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 73 87 86
D3-N-MeFOSA (surr.) 1 % 40 53 63
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 9
Report Number: 546502-W-V2
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_TDL220COLLINSRD -BORE
0990_TDL220COLLINSRD -TANK1
0990_TDL220COLLINSRD -TAP1
Sample Matrix Water Water Water
Eurofins | mgt Sample No. M17-My16593 M17-My16594 M17-My16595
Date Sampled May 12, 2017 May 12, 2017 May 12, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 30 42 52
D7-N-MeFOSE (surr.) 1 % 37 39 48
D9-N-EtFOSE (surr.) 1 % 35 40 46
D5-N-EtFOSAA (surr.) 1 % 55 58 63
D3-N-MeFOSAA (surr.) 1 % 56 59 69
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L 0.14 0.14 0.10
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.14 0.13 N090.11
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L N091.4 N091.5 N091.1
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.08 N090.08 N090.05
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N092.8 N093.1 N092.0
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 115 115 119
18O2-PFHxS (surr.) 1 % 80 84 86
13C8-PFOS (surr.) 1 % 64 65 78
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 241 235 243
13C2-6:2 FTS (surr.) 1 % 163 171 176
13C2-8:2 FTS (surr.) 1 % 85 93 98
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 9
Report Number: 546502-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 9
Report Number: 546502-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 9
Report Number: 546502-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 101 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) % 103 50-150 Pass
Perfluorononanoic acid (PFNA) % 103 50-150 Pass
Perfluorodecanoic acid (PFDA) % 111 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 98 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 144 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 9
Report Number: 546502-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 93 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 117 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 112 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 109 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 110 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 90 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 91 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 103 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 93 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 97 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 97 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 112 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 130 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My16594 CP % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My16594 CP % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My16594 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My16594 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My16594 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My16594 CP % 104 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My16594 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My16594 CP % 105 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My16594 CP % 100 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16594 CP % 146 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16594 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My16594 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16594 CP % 97 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16594 CP % 115 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16594 CP % 106 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16594 CP % 108 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16594 CP % 111 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16594 CP % 106 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 9
Report Number: 546502-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-My16594 CP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16594 CP % 87 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16594 CP % 95 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16594 CP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16594 CP % 86 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16594 CP % 100 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16594 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16594 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16594 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16594 CP % 138 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My16593 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My16593 CP ug/L 0.21 0.21 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My16593 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My16593 CP ug/L 0.07 0.06 7.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 9
Report Number: 546502-W-V2
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My16593 CP ug/L 0.14 0.13 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16593 CP ug/L 0.14 0.14 6.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16593 CP ug/L 1.4 1.4 5.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16593 CP ug/L 0.08 0.07 12 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16593 CP ug/L 2.8 2.6 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 9
Report Number: 546502-W-V2
Comments
Split Report
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 9
Report Number: 546502-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 546502-W-V3
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date May 16, 2017
Client Sample ID 0990_TDL1661STUART BORE
Sample Matrix Water
Eurofins | mgt Sample No. M17-My16596
Date Sampled May 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 83
13C5-PFPeA (surr.) 1 % 103
13C5-PFHxA (surr.) 1 % 113
13C4-PFHpA (surr.) 1 % 123
13C8-PFOA (surr.) 1 % 110
13C5-PFNA (surr.) 1 % 102
13C6-PFDA (surr.) 1 % 65
13C2-PFUnDA (surr.) 1 % 45
13C2-PFDoDA (surr.) 1 % 49
13C2-PFTeDA (surr.) 1 % 26
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 59
D3-N-MeFOSA (surr.) 1 % 26
D5-N-EtFOSA (surr.) 1 % 22
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 546502-W-V3
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_TDL1661STUART BORE
Sample Matrix Water
Eurofins | mgt Sample No. M17-My16596
Date Sampled May 12, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D7-N-MeFOSE (surr.) 1 % 20
D9-N-EtFOSE (surr.) 1 % 25
D5-N-EtFOSAA (surr.) 1 % 44
D3-N-MeFOSAA (surr.) 1 % 47
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 130
18O2-PFHxS (surr.) 1 % 123
13C8-PFOS (surr.) 1 % 97
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 177
13C2-6:2 FTS (surr.) 1 % 133
13C2-8:2 FTS (surr.) 1 % 78
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 546502-W-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane May 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 546502-W-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands.
In the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
Batch Duplicate A second piece of analysis from a sample outside of the clients batch of samples but run within the laboratory batch of analysis.
Batch SPIKE Spike recovery reported on a sample from outside of the clients batch of samples but run within the laboratory batch of analysis.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs 20-130%
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 546502-W-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 101 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 101 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) % 103 50-150 Pass
Perfluorononanoic acid (PFNA) % 103 50-150 Pass
Perfluorodecanoic acid (PFDA) % 111 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 98 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 144 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 546502-W-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 93 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 117 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 112 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 109 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 110 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 90 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 91 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 103 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 93 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 97 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 97 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 112 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 130 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My16594 CP % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-My16594 CP % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My16594 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My16594 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My16594 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My16594 CP % 104 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My16594 CP % 110 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My16594 CP % 105 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My16594 CP % 100 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16594 CP % 146 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16594 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My16594 CP % 102 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16594 CP % 97 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16594 CP % 115 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16594 CP % 106 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16594 CP % 108 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16594 CP % 111 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16594 CP % 106 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 546502-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-My16594 CP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16594 CP % 87 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16594 CP % 95 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16594 CP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16594 CP % 86 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16594 CP % 100 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16594 CP % 108 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16594 CP % 111 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16594 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16594 CP % 138 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-My16662 NCP % 106 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-My17853 NCP % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-My16662 NCP % 108 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-My16662 NCP % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-My16662 NCP % 109 50-150 Pass
Perfluorononanoic acid (PFNA) M17-My16662 NCP % 112 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-My16662 NCP % 118 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-My16662 NCP % 100 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-My16662 NCP % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16662 NCP % 149 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16662 NCP % 121 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-My16662 NCP % 105 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16662 NCP % 107 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16662 NCP % 128 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16662 NCP % 109 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16662 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16662 NCP % 104 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16662 NCP % 112 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-My16662 NCP % 97 50-150 Pass
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 546502-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoropentanesulfonic acid(PFPeS) M17-My16662 NCP % 100 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16662 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16662 NCP % 103 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16662 NCP % 110 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16662 NCP % 91 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16662 NCP % 118 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16662 NCP % 116 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16662 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16662 NCP % 148 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-My16593 CP ug/L 0.04 0.04 2.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My16593 CP ug/L 0.21 0.21 3.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My16593 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-My16593 CP ug/L 0.07 0.06 7.0 30% Pass
Perfluorononanoic acid (PFNA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 546502-W-V3
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My16593 CP ug/L 0.14 0.13 4.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16593 CP ug/L 0.14 0.14 6.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16593 CP ug/L 1.4 1.4 5.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16593 CP ug/L 0.08 0.07 12 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16593 CP ug/L 2.8 2.6 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16593 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16593 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-My17855 NCP ug/L 0.58 0.77 28 30% Pass
Perfluorohexanoic acid (PFHxA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 546502-W-V3
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-My16661 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-My16661 NCP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 546502-W-V3
Comments
Split Report
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: May 23, 2017
Date Reported: May 23, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 546502-W-V3
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 552653-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Jul 03, 2017
Client Sample ID
0990_5694STUARTHWY_BORE_170629
0990_5694STUARTHWY_TANK_170629
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Jl01774 M17-Jl01775
Date Sampled Jun 29, 2017 Jun 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01 < 0.01
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 95 96
13C5-PFPeA (surr.) 1 % 80 81
13C5-PFHxA (surr.) 1 % 93 93
13C4-PFHpA (surr.) 1 % 104 106
13C8-PFOA (surr.) 1 % 108 109
13C5-PFNA (surr.) 1 % 103 104
13C6-PFDA (surr.) 1 % 90 92
13C2-PFUnDA (surr.) 1 % 70 93
13C2-PFDoDA (surr.) 1 % 60 81
13C2-PFTeDA (surr.) 1 % 21 31
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 130 116
D3-N-MeFOSA (surr.) 1 % 52 56
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 10
Report Number: 552653-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID
0990_5694STUARTHWY_BORE_170629
0990_5694STUARTHWY_TANK_170629
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Jl01774 M17-Jl01775
Date Sampled Jun 29, 2017 Jun 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 36 35
D7-N-MeFOSE (surr.) 1 % 54 48
D9-N-EtFOSE (surr.) 1 % 57 53
D5-N-EtFOSAA (surr.) 1 % 86 95
D3-N-MeFOSAA (surr.) 1 % 89 97
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 104 103
18O2-PFHxS (surr.) 1 % 109 112
13C8-PFOS (surr.) 1 % 83 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 118 113
13C2-6:2 FTS (surr.) 1 % 129 141
13C2-8:2 FTS (surr.) 1 % 86 96
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 10
Report Number: 552653-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 10
Report Number: 552653-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Jul 3, 2017 8:56 AMAddress: 3G Marine Pde Report #: 552653 Due: Jul 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_5694STUARTHWY_BORE_170629
Jun 29, 2017 Water M17-Jl01774X
2 0990_5694STUARTHWY_TANK_170629
Jun 29, 2017 Water M17-Jl01775X
Test Counts 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 10
Report Number: 552653-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 10
Report Number: 552653-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 102 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 111 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 110 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) % 116 50-150 Pass
Perfluorononanoic acid (PFNA) % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) % 116 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 112 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 114 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 72 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 10
Report Number: 552653-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 106 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 111 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 114 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 108 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 117 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 102 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 104 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 98 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 108 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 103 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 94 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 55 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Jl01776 NCP % 99 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Jl01776 NCP % 105 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Jl01776 NCP % 116 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Jl01776 NCP % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Jl01776 NCP % 109 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Jl01776 NCP % 110 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Jl01776 NCP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Jl01776 NCP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Jl01776 NCP % 134 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Jl01776 NCP % 54 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Jl01776 NCP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Jl01776 NCP % 103 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Jl01776 NCP % 113 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Jl01776 NCP % 110 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Jl01776 NCP % 110 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Jl01776 NCP % 101 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Jl01776 NCP % 101 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Jl01776 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 10
Report Number: 552653-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-Jl01776 NCP % 97 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Jl01776 NCP % 94 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Jl01776 NCP % 88 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Jl01776 NCP % 97 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Jl01776 NCP % 94 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Jl01776 NCP % 82 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Jl01776 NCP % 97 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Jl01776 NCP % 100 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Jl01776 NCP % 109 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Jl01776 NCP % 52 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 10
Report Number: 552653-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Jl01774 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Jl01774 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 10
Report Number: 552653-W
Comments
Some surrogate recoveries were recorded in excess of the QC limit designated in QSM 5.1 of 50-150%. Since no positive results were reportedfor any PFAS compounds for any of the Samples in this case no data was affected.
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 10
Report Number: 552653-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 552657-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Jul 03, 2017
Client Sample ID0990_MANBULLOO_BORE_170627
Sample Matrix Water
Eurofins | mgt Sample No. M17-Jl01784
Date Sampled Jun 27, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA) 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA) 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA) 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA) 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA) 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA) 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA) 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA) 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA) 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 99
13C5-PFPeA (surr.) 1 % 98
13C5-PFHxA (surr.) 1 % 114
13C4-PFHpA (surr.) 1 % 121
13C8-PFOA (surr.) 1 % 120
13C5-PFNA (surr.) 1 % 109
13C6-PFDA (surr.) 1 % 87
13C2-PFUnDA (surr.) 1 % 63
13C2-PFDoDA (surr.) 1 % 43
13C2-PFTeDA (surr.) 1 % INT
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE) 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 128
D3-N-MeFOSA (surr.) 1 % 33
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 10
Report Number: 552657-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID0990_MANBULLOO_BORE_170627
Sample Matrix Water
Eurofins | mgt Sample No. M17-Jl01784
Date Sampled Jun 27, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 13
D7-N-MeFOSE (surr.) 1 % 23
D9-N-EtFOSE (surr.) 1 % 21
D5-N-EtFOSAA (surr.) 1 % 83
D3-N-MeFOSAA (surr.) 1 % 95
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS) 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 118
18O2-PFHxS (surr.) 1 % 128
13C8-PFOS (surr.) 1 % 83
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 162
13C2-6:2 FTS (surr.) 1 % 145
13C2-8:2 FTS (surr.) 1 % 92
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 10
Report Number: 552657-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Jul 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 10
Report Number: 552657-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Jul 3, 2017 8:56 AMAddress: 3G Marine Pde Report #: 552657 Due: Jul 10, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 18217
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_MANBULLOO_BORE_170627
Jun 27, 2017 Water M17-Jl01784X
Test Counts 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 18217
Date Reported:Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 10
Report Number: 552657-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 10
Report Number: 552657-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 102 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 111 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 110 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) % 116 50-150 Pass
Perfluorononanoic acid (PFNA) % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) % 116 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 112 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 114 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 72 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 117 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 10
Report Number: 552657-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluorooctane sulfonamide (FOSA) % 106 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 111 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 114 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 108 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 117 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 112 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 102 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 104 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 98 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 108 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 103 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 94 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 55 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Jl01781 NCP % 92 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Jl01781 NCP % 100 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Jl01781 NCP % 104 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Jl01781 NCP % 94 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Jl01781 NCP % 100 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Jl01781 NCP % 102 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Jl01781 NCP % 101 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Jl01781 NCP % 98 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Jl01781 NCP % 108 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Jl01781 NCP % 64 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Jl01781 NCP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Jl01781 NCP % 94 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Jl01781 NCP % 106 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Jl01781 NCP % 96 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Jl01781 NCP % 112 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Jl01781 NCP % 98 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Jl01781 NCP % 100 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Jl01781 NCP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 10
Report Number: 552657-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorobutanesulfonic acid(PFBS) M17-Jl01781 NCP % 91 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Jl01781 NCP % 89 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Jl01781 NCP % 88 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Jl01781 NCP % 88 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Jl01781 NCP % 87 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Jl01781 NCP % 83 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Jl01781 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Jl01781 NCP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Jl01781 NCP % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Jl01781 NCP % 56 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 10
Report Number: 552657-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Jl01779 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Jl01779 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 10
Report Number: 552657-W
Comments
Some surrogate recoveries were recorded in excess of the QC limit designated in QSM 5.1 of 50-150%. Since no positive results were reportedfor any PFAS compounds for any of the Samples in this case no data was affected.
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Jul 10, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 10
Report Number: 552657-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 558274-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 10, 2017
Client Sample ID 0090_PB008_170804
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au14518
Date Sampled Aug 04, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.05
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.16
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.03
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.05
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L 0.01
13C4-PFBA (surr.) 1 % 64
13C5-PFPeA (surr.) 1 % 80
13C5-PFHxA (surr.) 1 % 84
13C4-PFHpA (surr.) 1 % 86
13C8-PFOA (surr.) 1 % 93
13C5-PFNA (surr.) 1 % 85
13C6-PFDA (surr.) 1 % 67
13C2-PFUnDA (surr.) 1 % 67
13C2-PFDoDA (surr.) 1 % 68
13C2-PFTeDA (surr.) 1 % 67
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 80
D3-N-MeFOSA (surr.) 1 % 84
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 558274-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0090_PB008_170804
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au14518
Date Sampled Aug 04, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 57
D7-N-MeFOSE (surr.) 1 % 51
D9-N-EtFOSE (surr.) 1 % 47
D5-N-EtFOSAA (surr.) 1 % 94
D3-N-MeFOSAA (surr.) 1 % 81
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.17
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.19
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.92
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.06
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.4
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 106
18O2-PFHxS (surr.) 1 % 102
13C8-PFOS (surr.) 1 % 79
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L 0.06
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 86
13C2-6:2 FTS (surr.) 1 % 105
13C2-8:2 FTS (surr.) 1 % 82
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 2.32
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 1.45
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 2.37
Sum of WA DER PFAS (n=10) 0.05 ug/L 2.84
Sum of PFASs (n=28) 0.1 ug/L 3.12
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 17
Nitrate (as N) 0.02 mg/L 0.13
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 590
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 82
Magnesium 0.5 mg/L 36
Potassium 0.5 mg/L 1.9
Sodium 0.5 mg/L 4.3
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 558274-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 17, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 12, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 12, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 12, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 12, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 12, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 12, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 558274-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 1:42 PMAddress: 3G Marine Pde Report #: 558274 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0090_PB008_170804
Aug 04, 2017 Water M17-Au14518 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 558274-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 558274-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 558274-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 106 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 90 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 103 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 107 50-150 Pass
Perfluorooctanoic acid (PFOA) % 105 50-150 Pass
Perfluorononanoic acid (PFNA) % 109 50-150 Pass
Perfluorodecanoic acid (PFDA) % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 109 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 105 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 115 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 101 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 109 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 60 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 97 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 104 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 100 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 105 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 102 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 110 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 104 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 121 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 96 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 97 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 81 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 102 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 74 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 96 70-130 Pass
Chloride % 115 70-130 Pass
Nitrate (as N) % 99 70-130 Pass
Sulphate (as SO4) % 73 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 96 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 111 70-130 Pass
Magnesium % 109 70-130 Pass
Potassium % 108 70-130 Pass
Sodium % 89 70-130 Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 558274-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Au17420 NCP % 107 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Au17420 NCP % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Au17420 NCP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Au17420 NCP % 108 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Au17420 NCP % 106 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Au17420 NCP % 107 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Au17420 NCP % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Au17420 NCP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Au17420 NCP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au17420 NCP % 109 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au17420 NCP % 106 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Au17420 NCP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au17420 NCP % 106 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au17420 NCP % 97 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au17420 NCP % 102 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au17420 NCP % 105 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au17420 NCP % 106 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au17420 NCP % 102 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Au17420 NCP % 106 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au17420 NCP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au17420 NCP % 108 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au17420 NCP % 111 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au17420 NCP % 105 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au17420 NCP % 109 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au17420 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au17420 NCP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au17420 NCP % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au17420 NCP % 92 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 558274-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au14069 NCP % 98 70-130 Pass
Chloride M17-Au13603 NCP % 111 70-130 Pass
Nitrate (as N) M17-Au14069 NCP % 97 70-130 Pass
Sulphate (as SO4) M17-Au13068 NCP % 89 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Carbonate Alkalinity (as CaCO3) M17-Au14373 NCP % 96 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au15549 NCP % 109 70-130 Pass
Magnesium M17-Au16383 NCP % 127 70-130 Pass
Potassium M17-Au15549 NCP % 95 70-130 Pass
Sodium M17-Au16383 NCP % 126 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au14798 NCP ug/L 0.01 0.01 1.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au14798 NCP ug/L 0.03 0.02 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 558274-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au14798 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au14798 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au16344 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Au13227 NCP mg/L 220 220 1.9 30% Pass
Nitrate (as N) M17-Au16344 NCP mg/L 0.03 0.03 10 30% Pass
Sulphate (as SO4) M17-Au14976 NCP mg/L 18 18 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au14329 NCP mg/L 65 65 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au14329 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au14518 CP mg/L 82 78 5.0 30% Pass
Magnesium M17-Au14518 CP mg/L 36 35 1.0 30% Pass
Potassium M17-Au14518 CP mg/L 1.9 1.9 1.0 30% Pass
Sodium M17-Au14518 CP mg/L 4.3 4.2 3.0 30% Pass
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 558274-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 21, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 558274-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Jeni Young
Report 559645-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB026_170816
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25650
Date Sampled Aug 16, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 92
13C5-PFPeA (surr.) 1 % 66
13C5-PFHxA (surr.) 1 % 98
13C4-PFHpA (surr.) 1 % 102
13C8-PFOA (surr.) 1 % 105
13C5-PFNA (surr.) 1 % 86
13C6-PFDA (surr.) 1 % 62
13C2-PFUnDA (surr.) 1 % 67
13C2-PFDoDA (surr.) 1 % 62
13C2-PFTeDA (surr.) 1 % 62
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 21
D3-N-MeFOSA (surr.) 1 % INT
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559645-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB026_170816
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25650
Date Sampled Aug 16, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % INT
D9-N-EtFOSE (surr.) 1 % INT
D5-N-EtFOSAA (surr.) 1 % INT
D3-N-MeFOSAA (surr.) 1 % 10
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.02
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.03
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 106
18O2-PFHxS (surr.) 1 % 123
13C8-PFOS (surr.) 1 % 104
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 114
13C2-6:2 FTS (surr.) 1 % 89
13C2-8:2 FTS (surr.) 1 % 48
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.05
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.03
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.05
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Ammonia (as N) 0.01 mg/L 0.01
Chloride 1 mg/L 14
Nitrate (as N) 0.02 mg/L 0.15
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 450
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 100
Magnesium 0.5 mg/L 42
Potassium 0.5 mg/L 2.1
Sodium 0.5 mg/L 4.8
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559645-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 23, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 23, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 23, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559645-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559645 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Jeni Young
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB026_170816
Aug 16, 2017 Water M17-Au25650 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559645-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559645-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559645-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 120 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559645-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559645-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au24012 NCP % 92 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au24012 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25112 NCP % 90 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559645-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25254 NCP mg/L 180 180 <1 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559645-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559645-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 559646-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB025_170815
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25651
Date Sampled Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.08
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.03
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 95
13C5-PFPeA (surr.) 1 % 72
13C5-PFHxA (surr.) 1 % 103
13C4-PFHpA (surr.) 1 % 116
13C8-PFOA (surr.) 1 % 116
13C5-PFNA (surr.) 1 % 100
13C6-PFDA (surr.) 1 % 58
13C2-PFUnDA (surr.) 1 % 68
13C2-PFDoDA (surr.) 1 % 61
13C2-PFTeDA (surr.) 1 % 61
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 30
D3-N-MeFOSA (surr.) 1 % INT
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559646-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB025_170815
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25651
Date Sampled Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % INT
D9-N-EtFOSE (surr.) 1 % INT
D5-N-EtFOSAA (surr.) 1 % 12
D3-N-MeFOSAA (surr.) 1 % 13
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.09
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.10
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.64
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.07
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.75
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 98
18O2-PFHxS (surr.) 1 % 89
13C8-PFOS (surr.) 1 % 82
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 107
13C2-6:2 FTS (surr.) 1 % 85
13C2-8:2 FTS (surr.) 1 % 48
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.39
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.78
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.42
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.63
Sum of PFASs (n=28) 0.1 ug/L 1.8
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 16
Nitrate (as N) 0.02 mg/L 0.33
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 460
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 110
Magnesium 0.5 mg/L 41
Potassium 0.5 mg/L 1.8
Sodium 0.5 mg/L 6.7
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559646-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 23, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 23, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 23, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559646-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559646 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB025_170815
Aug 15, 2017 Water M17-Au25651 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559646-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559646-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559646-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 119 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559646-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559646-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au25819 NCP % 90 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au25819 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25112 NCP % 90 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559646-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25652 NCP mg/L 17 18 8.3 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559646-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559646-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 559647-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB024_170815
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25652
Date Sampled Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.08
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 105
13C5-PFPeA (surr.) 1 % 78
13C5-PFHxA (surr.) 1 % 116
13C4-PFHpA (surr.) 1 % 125
13C8-PFOA (surr.) 1 % 135
13C5-PFNA (surr.) 1 % 119
13C6-PFDA (surr.) 1 % 76
13C2-PFUnDA (surr.) 1 % 82
13C2-PFDoDA (surr.) 1 % 75
13C2-PFTeDA (surr.) 1 % 82
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 54
D3-N-MeFOSA (surr.) 1 % 15
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559647-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB024_170815
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25652
Date Sampled Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 25
D9-N-EtFOSE (surr.) 1 % 26
D5-N-EtFOSAA (surr.) 1 % 16
D3-N-MeFOSAA (surr.) 1 % 18
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.08
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.08
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.48
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.04
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.56
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 100
18O2-PFHxS (surr.) 1 % 105
13C8-PFOS (surr.) 1 % 94
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 123
13C2-6:2 FTS (surr.) 1 % 88
13C2-8:2 FTS (surr.) 1 % 55
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.04
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.58
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.06
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.26
Sum of PFASs (n=28) 0.1 ug/L 1.38
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 17
Nitrate (as N) 0.02 mg/L 0.21
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 510
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 110
Magnesium 0.5 mg/L 40
Potassium 0.5 mg/L 1.9
Sodium 0.5 mg/L 4.8
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559647-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 23, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 23, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 23, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559647-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559647 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Jeni Young
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB024_170815
Aug 15, 2017 Water M17-Au25652 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559647-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559647-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559647-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 119 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559647-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559647-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au25819 NCP % 90 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au25819 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25112 NCP % 90 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559647-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25652 CP mg/L 17 18 8.3 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 CP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559647-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559647-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Jeni Young
Report 559648-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB021_170814-1
0990_PB021_170814-2
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au25653 M17-Au32402
Date Sampled Aug 14, 2017 Aug 14, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 95 123
13C5-PFPeA (surr.) 1 % 70 131
13C5-PFHxA (surr.) 1 % 109 139
13C4-PFHpA (surr.) 1 % 121 124
13C8-PFOA (surr.) 1 % 120 120
13C5-PFNA (surr.) 1 % 104 105
13C6-PFDA (surr.) 1 % 69 83
13C2-PFUnDA (surr.) 1 % 67 69
13C2-PFDoDA (surr.) 1 % 61 71
13C2-PFTeDA (surr.) 1 % 58 64
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 43 85
D3-N-MeFOSA (surr.) 1 % 11 97
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559648-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB021_170814-1
0990_PB021_170814-2
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au25653 M17-Au32402
Date Sampled Aug 14, 2017 Aug 14, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT 55
D7-N-MeFOSE (surr.) 1 % 17 77
D9-N-EtFOSE (surr.) 1 % 17 63
D5-N-EtFOSAA (surr.) 1 % 13 65
D3-N-MeFOSAA (surr.) 1 % 14 63
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 105 109
18O2-PFHxS (surr.) 1 % 121 103
13C8-PFOS (surr.) 1 % 104 96
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 112 130
13C2-6:2 FTS (surr.) 1 % 84 101
13C2-8:2 FTS (surr.) 1 % 51 80
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1
Ammonia (as N) 0.01 mg/L 0.02 0.02
Chloride 1 mg/L 12 16
Nitrate (as N) 0.02 mg/L 0.25 0.29
Sulphate (as SO4) 5 mg/L < 5 < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 530 430
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10 < 10
Alkali Metals
Calcium 0.5 mg/L 68 < 0.5
Magnesium 0.5 mg/L 41 < 0.5
Potassium 0.5 mg/L 2.1 < 0.5
Sodium 0.5 mg/L 24 170
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559648-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 29, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 29, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559648-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559648 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Jeni Young
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB021_170814-1
Aug 14, 2017 Water M17-Au25653 X X
2 0990_PB021_170814-2
Aug 14, 2017 Water M17-Au32402 X X
Test Counts 2 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559648-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559648-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559648-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 119 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 116 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559648-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559648-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au25819 NCP % 90 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au25819 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25112 NCP % 90 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au24741 NCP % 118 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Potassium M17-Au28001 NCP % 100 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559648-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25652 NCP mg/L 17 18 8.3 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25108 NCP mg/L 1400 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559648-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 04, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559648-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 559650-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB023_170815
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25657
Date Sampled Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.08
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.03
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 85
13C5-PFPeA (surr.) 1 % 64
13C5-PFHxA (surr.) 1 % 88
13C4-PFHpA (surr.) 1 % 95
13C8-PFOA (surr.) 1 % 97
13C5-PFNA (surr.) 1 % 87
13C6-PFDA (surr.) 1 % 56
13C2-PFUnDA (surr.) 1 % 69
13C2-PFDoDA (surr.) 1 % 64
13C2-PFTeDA (surr.) 1 % 69
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 31
D3-N-MeFOSA (surr.) 1 % INT
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559650-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB023_170815
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25657
Date Sampled Aug 15, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 12
D9-N-EtFOSE (surr.) 1 % 13
D5-N-EtFOSAA (surr.) 1 % INT
D3-N-MeFOSAA (surr.) 1 % 12
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.10
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.11
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.67
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.07
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.78
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 97
18O2-PFHxS (surr.) 1 % 88
13C8-PFOS (surr.) 1 % 79
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 107
13C2-6:2 FTS (surr.) 1 % 78
13C2-8:2 FTS (surr.) 1 % 45
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.45
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.81
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.48
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.7
Sum of PFASs (n=28) 0.1 ug/L 1.88
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 13
Nitrate (as N) 0.02 mg/L 0.52
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 480
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 110
Magnesium 0.5 mg/L 41
Potassium 0.5 mg/L 1.9
Sodium 0.5 mg/L 5.5
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559650-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 23, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 23, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 23, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559650-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559650 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB023_170815
Aug 15, 2017 Water M17-Au25657 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559650-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559650-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559650-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 119 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559650-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559650-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au25819 NCP % 90 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au25819 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25112 NCP % 90 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559650-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25652 NCP mg/L 17 18 8.3 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559650-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559650-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Jeni Young
Report 559652-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB022_170814
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25658
Date Sampled Aug 14, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 96
13C5-PFPeA (surr.) 1 % 72
13C5-PFHxA (surr.) 1 % 116
13C4-PFHpA (surr.) 1 % 127
13C8-PFOA (surr.) 1 % 125
13C5-PFNA (surr.) 1 % 97
13C6-PFDA (surr.) 1 % 64
13C2-PFUnDA (surr.) 1 % 62
13C2-PFDoDA (surr.) 1 % 54
13C2-PFTeDA (surr.) 1 % 56
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 85
D3-N-MeFOSA (surr.) 1 % 35
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559652-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB022_170814
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25658
Date Sampled Aug 14, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 18
D7-N-MeFOSE (surr.) 1 % 35
D9-N-EtFOSE (surr.) 1 % 46
D5-N-EtFOSAA (surr.) 1 % INT
D3-N-MeFOSAA (surr.) 1 % INT
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 104
18O2-PFHxS (surr.) 1 % 119
13C8-PFOS (surr.) 1 % 90
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 108
13C2-6:2 FTS (surr.) 1 % 86
13C2-8:2 FTS (surr.) 1 % 40
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 15
Nitrate (as N) 0.02 mg/L 0.04
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 500
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 92
Magnesium 0.5 mg/L 48
Potassium 0.5 mg/L 1.9
Sodium 0.5 mg/L 21
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559652-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 23, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 23, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 23, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559652-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559652 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Jeni Young
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB022_170814
Aug 14, 2017 Water M17-Au25658 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559652-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559652-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559652-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 120 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559652-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559652-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au25819 NCP % 90 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au25819 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25715 NCP % 102 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26590 NCP ug/L 0.03 0.03 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26590 NCP ug/L 0.08 0.09 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26590 NCP ug/L 0.02 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26590 NCP ug/L 0.03 0.03 6.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26590 NCP ug/L 0.08 0.08 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26590 NCP ug/L 0.07 0.07 2.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26590 NCP ug/L 0.63 0.64 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26590 NCP ug/L 0.08 0.08 4.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26590 NCP ug/L 0.81 0.76 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559652-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25254 NCP mg/L 180 180 <1 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559652-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559652-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 559662-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB020_170814
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25698
Date Sampled Aug 14, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 102
13C5-PFPeA (surr.) 1 % 79
13C5-PFHxA (surr.) 1 % 117
13C4-PFHpA (surr.) 1 % 133
13C8-PFOA (surr.) 1 % 125
13C5-PFNA (surr.) 1 % 114
13C6-PFDA (surr.) 1 % 73
13C2-PFUnDA (surr.) 1 % 74
13C2-PFDoDA (surr.) 1 % 70
13C2-PFTeDA (surr.) 1 % 77
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 36
D3-N-MeFOSA (surr.) 1 % INT
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 559662-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB020_170814
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au25698
Date Sampled Aug 14, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % INT
D9-N-EtFOSE (surr.) 1 % 10
D5-N-EtFOSAA (surr.) 1 % 12
D3-N-MeFOSAA (surr.) 1 % 15
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 104
18O2-PFHxS (surr.) 1 % 119
13C8-PFOS (surr.) 1 % 113
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 110
13C2-6:2 FTS (surr.) 1 % 80
13C2-8:2 FTS (surr.) 1 % 47
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 15
Nitrate (as N) 0.02 mg/L 0.86
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 440
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 89
Magnesium 0.5 mg/L 37
Potassium 0.5 mg/L 2.8
Sodium 0.5 mg/L 6.7
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 559662-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 23, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 23, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 23, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 559662-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 12:00 AMAddress: 3G Marine Pde Report #: 559662 Due: Aug 29, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB020_170814
Aug 14, 2017 Water M17-Au25698 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 559662-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 559662-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 559662-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 94 70-130 Pass
Chloride % 119 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 90 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 559662-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 559662-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au25819 NCP % 90 70-130 Pass
Chloride P17-Au25697 NCP % 122 70-130 Pass
Nitrate (as N) M17-Au25819 NCP % 94 70-130 Pass
Sulphate (as SO4) M17-Au25819 NCP % 80 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) M17-Au25112 NCP % 90 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium P17-Au25694 NCP % 122 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium P17-Au25694 NCP % 113 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26590 NCP ug/L 0.03 0.03 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26590 NCP ug/L 0.08 0.09 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26590 NCP ug/L 0.02 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26590 NCP ug/L 0.03 0.03 6.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26590 NCP ug/L 0.08 0.08 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26590 NCP ug/L 0.07 0.07 2.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26590 NCP ug/L 0.63 0.64 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26590 NCP ug/L 0.08 0.08 4.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26590 NCP ug/L 0.81 0.76 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 559662-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26590 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26590 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au25819 NCP mg/L 58 55 5.0 30% Pass
Chloride M17-Au25652 NCP mg/L 17 18 8.3 30% Pass
Nitrate (as N) M17-Au25819 NCP mg/L < 0.4 < 0.4 <1 30% Pass
Sulphate (as SO4) M17-Au25652 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L 410 410 1.0 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au25111 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Magnesium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Sodium M17-Au25118 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 559662-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 559662-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559770-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 10, 2017
Client Sample ID 0990_PB007_1_170802-1
0990_PB007_2_170802
Sample Matrix Water Water
Eurofins | mgt Sample No. B17-Au26301 B17-Au26302
Date Sampled Aug 02, 2017 Aug 02, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.02 N090.02
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.09 N090.09
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.01 N090.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.03 N090.03
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 147 145
13C5-PFPeA (surr.) 1 % 121 128
13C5-PFHxA (surr.) 1 % 134 129
13C4-PFHpA (surr.) 1 % 154 146
13C8-PFOA (surr.) 1 % 185 147
13C5-PFNA (surr.) 1 % 153 145
13C6-PFDA (surr.) 1 % 87 82
13C2-PFUnDA (surr.) 1 % 72 76
13C2-PFDoDA (surr.) 1 % 64 64
13C2-PFTeDA (surr.) 1 % 32 28
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 96 93
D3-N-MeFOSA (surr.) 1 % 59 55
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 11
Report Number: 559770-W
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB007_1_170802-1
0990_PB007_2_170802
Sample Matrix Water Water
Eurofins | mgt Sample No. B17-Au26301 B17-Au26302
Date Sampled Aug 02, 2017 Aug 02, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 43 39
D7-N-MeFOSE (surr.) 1 % 45 43
D9-N-EtFOSE (surr.) 1 % 51 48
D5-N-EtFOSAA (surr.) 1 % 55 42
D3-N-MeFOSAA (surr.) 1 % 62 58
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.07 N090.07
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.08 N090.09
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.56 N090.69
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.04 N090.04
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.1 N091.1
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 136 134
18O2-PFHxS (surr.) 1 % 113 105
13C8-PFOS (surr.) 1 % 82 119
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 164 131
13C2-6:2 FTS (surr.) 1 % 127 115
13C2-8:2 FTS (surr.) 1 % 86 86
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.66 1.79
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 1.13 1.13
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.69 1.82
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.88 2.01
Sum of PFASs (n=28) 0.1 ug/L 2 2.14
Ammonia (as N) 0.01 mg/L < 0.01 -
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 510 -
Chloride 1 mg/L 15 -
Nitrate (as N) 0.02 mg/L 0.22 -
Sulphate (as SO4) 5 mg/L < 5 -
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10 -
Alkali Metals
Calcium 0.5 mg/L 110 -
Magnesium 0.5 mg/L 39 -
Potassium 0.5 mg/L 1.8 -
Sodium 0.5 mg/L 4.7 -
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 11
Report Number: 559770-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 24, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Bicarbonate Alkalinity (as CaCO3) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 24, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 11
Report Number: 559770-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 559770 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB007_1_170802-1
Aug 02, 2017 Water B17-Au26301 X X
2 0990_PB007_2_170802
Aug 02, 2017 Water B17-Au26302 X
Test Counts 1 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 11
Report Number: 559770-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 11
Report Number: 559770-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 11
Report Number: 559770-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 88 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 87 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 74 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 79 50-150 Pass
Perfluorooctanoic acid (PFOA) % 84 50-150 Pass
Perfluorononanoic acid (PFNA) % 86 50-150 Pass
Perfluorodecanoic acid (PFDA) % 77 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 88 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 86 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 61 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 83 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 79 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 69 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 90 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 80 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 91 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 66 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 85 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 82 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 79 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 85 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 73 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 89 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 80 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 81 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 91 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 93 70-130 Pass
Chloride % 114 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 112 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 97 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 11
Report Number: 559770-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Au26322 NCP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Au26322 NCP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Au26322 NCP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Au26322 NCP % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Au26322 NCP % 113 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Au26322 NCP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Au26322 NCP % 96 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Au26322 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Au26322 NCP % 110 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au26322 NCP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au26322 NCP % 129 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Au26322 NCP % 111 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au26322 NCP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au26322 NCP % 96 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au26322 NCP % 109 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au26322 NCP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au26322 NCP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au26322 NCP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Au26322 NCP % 89 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au26322 NCP % 115 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au26322 NCP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au26322 NCP % 99 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au26322 NCP % 103 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au26322 NCP % 123 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au26322 NCP % 113 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au26322 NCP % 114 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au26322 NCP % 92 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au26322 NCP % 127 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 11
Report Number: 559770-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au26893 NCP % 89 70-130 Pass
Chloride M17-Au27402 NCP % 114 70-130 Pass
Nitrate (as N) M17-Au26893 NCP % 92 70-130 Pass
Sulphate (as SO4) B17-Au26301 CP % 115 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Carbonate Alkalinity (as CaCO3) M17-Au26275 NCP % 96 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au26270 NCP % 124 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium M17-Au26270 NCP % 121 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Au26315 NCP ug/L 0.03 0.03 2.0 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Au26315 NCP ug/L 0.12 0.12 1.0 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Au26315 NCP ug/L 0.02 0.02 4.0 30% Pass
Perfluorooctanoic acid (PFOA) B17-Au26315 NCP ug/L 0.04 0.04 1.0 30% Pass
Perfluorononanoic acid (PFNA) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Au26315 NCP ug/L 0.09 0.09 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au26315 NCP ug/L 0.11 0.11 5.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au26315 NCP ug/L 0.85 0.84 1.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au26315 NCP ug/L 0.05 0.05 1.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au26321 NCP ug/L 0.05 0.05 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 11
Report Number: 559770-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au26315 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au26315 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au26893 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Bicarbonate Alkalinity (as CaCO3) B17-Au26301 CP mg/L 510 470 8.0 30% Pass
Chloride B17-Au26315 NCP mg/L 14 14 2.5 30% Pass
Nitrate (as N) M17-Au26893 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Sulphate (as SO4) B17-Au26315 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Carbonate Alkalinity (as CaCO3) B17-Au26301 CP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au26270 NCP mg/L 18 19 2.0 30% Pass
Magnesium M17-Au26270 NCP mg/L 21 21 2.0 30% Pass
Potassium M17-Au26270 NCP mg/L 3.9 3.8 2.0 30% Pass
Sodium M17-Au26270 NCP mg/L 140 140 <1 30% Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 11
Report Number: 559770-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 11
Report Number: 559770-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559774-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 23, 2017
Client Sample ID 0990_PB006_1_170802
Sample Matrix Water
Eurofins | mgt Sample No. B17-Au26315
Date Sampled Aug 02, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.12
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.04
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 137
13C5-PFPeA (surr.) 1 % 126
13C5-PFHxA (surr.) 1 % 133
13C4-PFHpA (surr.) 1 % 153
13C8-PFOA (surr.) 1 % 144
13C5-PFNA (surr.) 1 % 134
13C6-PFDA (surr.) 1 % 78
13C2-PFUnDA (surr.) 1 % 68
13C2-PFDoDA (surr.) 1 % 65
13C2-PFTeDA (surr.) 1 % 30
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 93
D3-N-MeFOSA (surr.) 1 % 62
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 11
Report Number: 559774-W
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB006_1_170802
Sample Matrix Water
Eurofins | mgt Sample No. B17-Au26315
Date Sampled Aug 02, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 40
D7-N-MeFOSE (surr.) 1 % 45
D9-N-EtFOSE (surr.) 1 % 52
D5-N-EtFOSAA (surr.) 1 % 48
D3-N-MeFOSAA (surr.) 1 % 56
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.09
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.11
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.85
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.05
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N091.5
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 134
18O2-PFHxS (surr.) 1 % 102
13C8-PFOS (surr.) 1 % 88
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 159
13C2-6:2 FTS (surr.) 1 % 132
13C2-8:2 FTS (surr.) 1 % 80
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 2.35
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 1.54
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 2.39
Sum of WA DER PFAS (n=10) 0.05 ug/L 2.65
Sum of PFASs (n=28) 0.1 ug/L 2.81
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 14
Nitrate (as N) 0.02 mg/L 0.22
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 440
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 110
Magnesium 0.5 mg/L 38
Potassium 0.5 mg/L 1.7
Sodium 0.5 mg/L 4.9
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 11
Report Number: 559774-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 24, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 24, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 11
Report Number: 559774-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 559774 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB006_1_170802
Aug 02, 2017 Water B17-Au26315 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 11
Report Number: 559774-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 11
Report Number: 559774-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 11
Report Number: 559774-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 88 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 87 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 74 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 79 50-150 Pass
Perfluorooctanoic acid (PFOA) % 84 50-150 Pass
Perfluorononanoic acid (PFNA) % 86 50-150 Pass
Perfluorodecanoic acid (PFDA) % 77 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 88 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 86 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 61 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 83 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 79 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 69 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 90 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 80 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 91 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 66 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 85 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 82 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 79 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 85 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 73 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 89 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 80 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 81 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 91 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 93 70-130 Pass
Chloride % 114 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 112 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 97 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 11
Report Number: 559774-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Au26301 NCP % 113 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Au26301 NCP % 123 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Au26301 NCP % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Au26301 NCP % 106 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Au26301 NCP % 112 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Au26301 NCP % 116 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Au26301 NCP % 103 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Au26301 NCP % 114 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Au26301 NCP % 122 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au26301 NCP % 81 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au26301 NCP % 133 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Au26301 NCP % 109 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au26301 NCP % 109 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au26301 NCP % 97 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au26301 NCP % 127 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au26301 NCP % 119 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au26301 NCP % 116 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au26301 NCP % 121 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Au26301 NCP % 89 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au26301 NCP % 112 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au26301 NCP % 122 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au26301 NCP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au26322 NCP % 103 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au26301 NCP % 111 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au26301 NCP % 117 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au26301 NCP % 113 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au26301 NCP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au26301 NCP % 120 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 11
Report Number: 559774-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au26893 NCP % 89 70-130 Pass
Chloride M17-Au27402 NCP % 114 70-130 Pass
Nitrate (as N) M17-Au26893 NCP % 92 70-130 Pass
Sulphate (as SO4) B17-Au26301 NCP % 115 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Carbonate Alkalinity (as CaCO3) M17-Au26275 NCP % 96 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au26270 NCP % 124 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium M17-Au26270 NCP % 121 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au26321 NCP ug/L 0.03 0.02 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au26321 NCP ug/L 0.05 0.05 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 11
Report Number: 559774-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au26321 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au26321 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au26903 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride B17-Au26315 CP mg/L 14 14 2.5 30% Pass
Nitrate (as N) M17-Au26903 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Sulphate (as SO4) B17-Au26315 CP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) B17-Au26301 NCP mg/L 510 470 8.0 30% Pass
Carbonate Alkalinity (as CaCO3) B17-Au26301 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au26270 NCP mg/L 18 19 2.0 30% Pass
Magnesium M17-Au26270 NCP mg/L 21 21 2.0 30% Pass
Potassium M17-Au26270 NCP mg/L 3.9 3.8 2.0 30% Pass
Sodium M17-Au26270 NCP mg/L 140 140 <1 30% Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 11
Report Number: 559774-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 11
Report Number: 559774-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
3G Marine Pde
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559777-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 10, 2017
Client Sample ID 0990_PB005_1_170801
0990_PB005_2_170801
0990_PB005_3_170801
Sample Matrix Water Water Water
Eurofins | mgt Sample No. B17-Au26320 B17-Au26321 B17-Au26322
Date Sampled Aug 02, 2017 Aug 02, 2017 Aug 02, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 154 149 111
13C5-PFPeA (surr.) 1 % 132 124 96
13C5-PFHxA (surr.) 1 % 139 137 128
13C4-PFHpA (surr.) 1 % 154 154 147
13C8-PFOA (surr.) 1 % 175 189 170
13C5-PFNA (surr.) 1 % 147 139 133
13C6-PFDA (surr.) 1 % 88 95 95
13C2-PFUnDA (surr.) 1 % 64 74 74
13C2-PFDoDA (surr.) 1 % 51 69 65
13C2-PFTeDA (surr.) 1 % 24 33 30
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 97 97 86
D3-N-MeFOSA (surr.) 1 % 53 61 54
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 1 of 11
Report Number: 559777-W
NATA AccreditedAccreditation Number 1261Site Number 20794
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB005_1_170801
0990_PB005_2_170801
0990_PB005_3_170801
Sample Matrix Water Water Water
Eurofins | mgt Sample No. B17-Au26320 B17-Au26321 B17-Au26322
Date Sampled Aug 02, 2017 Aug 02, 2017 Aug 02, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 38 46 41
D7-N-MeFOSE (surr.) 1 % 44 48 43
D9-N-EtFOSE (surr.) 1 % 46 51 48
D5-N-EtFOSAA (surr.) 1 % 49 46 48
D3-N-MeFOSAA (surr.) 1 % 55 57 57
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.03 N090.03 N090.03
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.06 N090.05 N090.04
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 143 141 131
18O2-PFHxS (surr.) 1 % 140 144 135
13C8-PFOS (surr.) 1 % 101 102 99
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 148 153 139
13C2-6:2 FTS (surr.) 1 % 116 122 129
13C2-8:2 FTS (surr.) 1 % 73 78 94
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.09 0.08 0.07
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.06 0.05 0.04
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.09 0.08 0.07
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.09 0.08 0.07
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1 < 0.1
Ammonia (as N) 0.01 mg/L < 0.01 - -
Chloride 1 mg/L 13 - -
Nitrate (as N) 0.02 mg/L 0.18 - -
Sulphate (as SO4) 5 mg/L < 5 - -
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 420 - -
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10 - -
Alkali Metals
Calcium 0.5 mg/L 91 - -
Magnesium 0.5 mg/L 38 - -
Potassium 0.5 mg/L 1.4 - -
Sodium 0.5 mg/L 3.2 - -
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 2 of 11
Report Number: 559777-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 23, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 24, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 24, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 3 of 11
Report Number: 559777-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 10, 2017 9:00 AMAddress: 3G Marine Pde Report #: 559777 Due: Aug 17, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB005_1_170801
Aug 02, 2017 Water B17-Au26320 X X
2 0990_PB005_2_170801
Aug 02, 2017 Water B17-Au26321 X
3 0990_PB005_3_170801
Aug 02, 2017 Water B17-Au26322 X
Test Counts 1 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 4 of 11
Report Number: 559777-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 5 of 11
Report Number: 559777-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 6 of 11
Report Number: 559777-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 88 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 87 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 74 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 79 50-150 Pass
Perfluorooctanoic acid (PFOA) % 84 50-150 Pass
Perfluorononanoic acid (PFNA) % 86 50-150 Pass
Perfluorodecanoic acid (PFDA) % 77 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 88 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 86 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 61 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 83 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 79 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 69 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 90 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 82 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 80 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 91 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 66 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 85 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 82 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 79 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 85 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 73 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 89 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 80 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 81 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 91 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 93 70-130 Pass
Chloride % 114 70-130 Pass
Nitrate (as N) % 96 70-130 Pass
Sulphate (as SO4) % 112 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Carbonate Alkalinity (as CaCO3) % 97 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 107 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 103 70-130 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 7 of 11
Report Number: 559777-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Result 1
Ammonia (as N) M17-Au26893 NCP % 89 70-130 Pass
Chloride M17-Au27402 NCP % 114 70-130 Pass
Nitrate (as N) M17-Au26893 NCP % 92 70-130 Pass
Sulphate (as SO4) B17-Au26301 NCP % 115 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Carbonate Alkalinity (as CaCO3) M17-Au26275 NCP % 96 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au26270 NCP % 124 70-130 Pass
Magnesium M17-Au26270 NCP % 122 70-130 Pass
Sodium M17-Au26270 NCP % 121 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Au26322 CP % 112 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Au26322 CP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Au26322 CP % 98 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Au26322 CP % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Au26322 CP % 113 50-150 Pass
Perfluorononanoic acid (PFNA) B17-Au26322 CP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Au26322 CP % 96 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Au26322 CP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Au26322 CP % 110 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au26322 CP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au26322 CP % 129 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Au26322 CP % 111 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au26322 CP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au26322 CP % 96 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au26322 CP % 109 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au26322 CP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au26322 CP % 118 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au26322 CP % 109 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Au26322 CP % 89 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au26322 CP % 115 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au26322 CP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au26322 CP % 99 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au26322 CP % 103 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au26322 CP % 123 50-150 Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 8 of 11
Report Number: 559777-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au26322 CP % 113 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au26322 CP % 114 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au26322 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au26322 CP % 127 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au26903 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride B17-Au26315 NCP mg/L 14 14 2.5 30% Pass
Nitrate (as N) M17-Au26903 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Sulphate (as SO4) B17-Au26315 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) B17-Au26301 NCP mg/L 510 470 8.0 30% Pass
Carbonate Alkalinity (as CaCO3) B17-Au26301 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au26270 NCP mg/L 18 19 2.0 30% Pass
Magnesium M17-Au26270 NCP mg/L 21 21 2.0 30% Pass
Potassium M17-Au26270 NCP mg/L 3.9 3.8 2.0 30% Pass
Sodium M17-Au26270 NCP mg/L 140 140 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 9 of 11
Report Number: 559777-W
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Au26321 CP ug/L 0.03 0.02 6.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Au26321 CP ug/L 0.05 0.05 5.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Au26321 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Au26321 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 10 of 11
Report Number: 559777-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 25, 2017
Eurofins | mgt 1/21 Smallwood Place, Murarrie, QLD, Australia, 4172
ABN : 50 005 085 521 Telephone: +61 7 3902 4600
Page 11 of 11
Report Number: 559777-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559790-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 21, 2017
Client Sample ID 0990_QCMW148_170814
0990_QCMW161_170814
0990_QCBH149_170815
0990_QCMW163_170816
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26488 M17-Au26489 M17-Au26490 M17-Au26491
Date Sampled Aug 14, 2017 Aug 14, 2017 Aug 15, 2017 Aug 16, 2017
Test/Reference LOR Unit
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 0.02 mg/L < 0.02 < 0.02 < 0.02 -
TRH C10-C14 0.05 mg/L < 0.05 < 0.05 < 0.05 -
TRH C15-C28 0.1 mg/L < 0.1 < 0.1 < 0.1 -
TRH C29-C36 0.1 mg/L < 0.1 < 0.1 < 0.1 -
TRH C10-36 (Total) 0.1 mg/L < 0.1 < 0.1 < 0.1 -
BTEX
Benzene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Toluene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Ethylbenzene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
m&p-Xylenes 0.002 mg/L < 0.002 < 0.002 < 0.002 -
o-Xylene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Xylenes - Total 0.003 mg/L < 0.003 < 0.003 < 0.003 -
4-Bromofluorobenzene (surr.) 1 % 70 52 73 -
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
NaphthaleneN02 0.01 mg/L < 0.01 < 0.01 < 0.01 -
TRH C6-C10 less BTEX (F1)N04 0.02 mg/L < 0.02 < 0.02 < 0.02 -
TRH C6-C10 0.02 mg/L < 0.02 < 0.02 < 0.02 -
TRH >C10-C16 0.05 mg/L < 0.05 < 0.05 < 0.05 -
TRH >C10-C16 less Naphthalene (F2)N01 0.05 mg/L < 0.05 < 0.05 < 0.05 -
TRH >C16-C34 0.1 mg/L < 0.1 < 0.1 < 0.1 -
TRH >C34-C40 0.1 mg/L < 0.1 < 0.1 < 0.1 -
Polycyclic Aromatic Hydrocarbons
Acenaphthene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Acenaphthylene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Anthracene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Benz(a)anthracene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Benzo(a)pyrene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Benzo(b&j)fluorantheneN07 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Benzo(g.h.i)perylene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Benzo(k)fluoranthene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Chrysene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Dibenz(a.h)anthracene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Fluoranthene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Fluorene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Indeno(1.2.3-cd)pyrene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 24
Report Number: 559790-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_QCMW148_170814
0990_QCMW161_170814
0990_QCBH149_170815
0990_QCMW163_170816
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26488 M17-Au26489 M17-Au26490 M17-Au26491
Date Sampled Aug 14, 2017 Aug 14, 2017 Aug 15, 2017 Aug 16, 2017
Test/Reference LOR Unit
Polycyclic Aromatic Hydrocarbons
Naphthalene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Phenanthrene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Pyrene 0.001 mg/L < 0.001 < 0.001 < 0.001 -
Total PAH* 0.001 mg/L < 0.001 < 0.001 < 0.001 -
2-Fluorobiphenyl (surr.) 1 % 104 98 135 -
p-Terphenyl-d14 (surr.) 1 % 81 97 127 -
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 91 92 95 72
13C5-PFPeA (surr.) 1 % 73 69 72 51
13C5-PFHxA (surr.) 1 % 104 95 102 73
13C4-PFHpA (surr.) 1 % 106 96 102 75
13C8-PFOA (surr.) 1 % 120 94 114 76
13C5-PFNA (surr.) 1 % 102 84 112 74
13C6-PFDA (surr.) 1 % 98 63 85 60
13C2-PFUnDA (surr.) 1 % 115 67 88 65
13C2-PFDoDA (surr.) 1 % 96 57 72 56
13C2-PFTeDA (surr.) 1 % 83 58 75 66
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 44 45 30 26
D3-N-MeFOSA (surr.) 1 % 13 INT INT INT
D5-N-EtFOSA (surr.) 1 % INT INT INT INT
D7-N-MeFOSE (surr.) 1 % 20 15 13 INT
D9-N-EtFOSE (surr.) 1 % 23 16 15 INT
D5-N-EtFOSAA (surr.) 1 % 26 20 25 13
D3-N-MeFOSAA (surr.) 1 % 38 24 34 18
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 24
Report Number: 559790-W
Client Sample ID 0990_QCMW148_170814
0990_QCMW161_170814
0990_QCBH149_170815
0990_QCMW163_170816
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26488 M17-Au26489 M17-Au26490 M17-Au26491
Date Sampled Aug 14, 2017 Aug 14, 2017 Aug 15, 2017 Aug 16, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 108 109 107 107
18O2-PFHxS (surr.) 1 % 128 129 125 125
13C8-PFOS (surr.) 1 % 143 136 136 120
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 129 119 127 122
13C2-6:2 FTS (surr.) 1 % 107 101 101 97
13C2-8:2 FTS (surr.) 1 % 101 68 73 62
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1 < 0.1 < 0.1
Heavy Metals
Aluminium 0.05 mg/L < 0.05 - < 0.05 -
Aluminium (filtered) 0.05 mg/L - < 0.05 - -
Arsenic 0.001 mg/L < 0.001 - < 0.001 -
Arsenic (filtered) 0.001 mg/L - < 0.001 - -
Cadmium 0.0002 mg/L < 0.0002 - < 0.0002 -
Cadmium (filtered) 0.0002 mg/L - < 0.0002 - -
Chromium 0.001 mg/L < 0.001 - < 0.001 -
Chromium (filtered) 0.001 mg/L - < 0.001 - -
Copper 0.001 mg/L < 0.001 - < 0.001 -
Copper (filtered) 0.001 mg/L - < 0.001 - -
Iron 0.05 mg/L < 0.05 - < 0.05 -
Iron (filtered) 0.05 mg/L - < 0.05 - -
Lead 0.001 mg/L < 0.001 - < 0.001 -
Lead (filtered) 0.001 mg/L - < 0.001 - -
Manganese 0.005 mg/L < 0.005 - < 0.005 -
Manganese (filtered) 0.005 mg/L - < 0.005 - -
Mercury 0.0001 mg/L < 0.0001 - < 0.0001 -
Mercury (filtered) 0.0001 mg/L - < 0.0001 - -
Nickel 0.001 mg/L < 0.001 - < 0.001 -
Nickel (filtered) 0.001 mg/L - < 0.001 - -
Zinc 0.005 mg/L < 0.005 - < 0.005 -
Zinc (filtered) 0.005 mg/L - < 0.005 - -
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 24
Report Number: 559790-W
Client Sample ID 0990_QCMW182_170816
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26495
Date Sampled Aug 16, 2017
Test/Reference LOR Unit
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 0.02 mg/L < 0.02
TRH C10-C14 0.05 mg/L < 0.05
TRH C15-C28 0.1 mg/L < 0.1
TRH C29-C36 0.1 mg/L < 0.1
TRH C10-36 (Total) 0.1 mg/L < 0.1
BTEX
Benzene 0.001 mg/L < 0.001
Toluene 0.001 mg/L < 0.001
Ethylbenzene 0.001 mg/L < 0.001
m&p-Xylenes 0.002 mg/L < 0.002
o-Xylene 0.001 mg/L < 0.001
Xylenes - Total 0.003 mg/L < 0.003
4-Bromofluorobenzene (surr.) 1 % 74
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
NaphthaleneN02 0.01 mg/L < 0.01
TRH C6-C10 less BTEX (F1)N04 0.02 mg/L < 0.02
TRH C6-C10 0.02 mg/L < 0.02
TRH >C10-C16 0.05 mg/L < 0.05
TRH >C10-C16 less Naphthalene (F2)N01 0.05 mg/L < 0.05
TRH >C16-C34 0.1 mg/L < 0.1
TRH >C34-C40 0.1 mg/L < 0.1
Polycyclic Aromatic Hydrocarbons
Acenaphthene 0.001 mg/L < 0.001
Acenaphthylene 0.001 mg/L < 0.001
Anthracene 0.001 mg/L < 0.001
Benz(a)anthracene 0.001 mg/L < 0.001
Benzo(a)pyrene 0.001 mg/L < 0.001
Benzo(b&j)fluorantheneN07 0.001 mg/L < 0.001
Benzo(g.h.i)perylene 0.001 mg/L < 0.001
Benzo(k)fluoranthene 0.001 mg/L < 0.001
Chrysene 0.001 mg/L < 0.001
Dibenz(a.h)anthracene 0.001 mg/L < 0.001
Fluoranthene 0.001 mg/L < 0.001
Fluorene 0.001 mg/L < 0.001
Indeno(1.2.3-cd)pyrene 0.001 mg/L < 0.001
Naphthalene 0.001 mg/L < 0.001
Phenanthrene 0.001 mg/L < 0.001
Pyrene 0.001 mg/L < 0.001
Total PAH* 0.001 mg/L < 0.001
2-Fluorobiphenyl (surr.) 1 % 97
p-Terphenyl-d14 (surr.) 1 % 92
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 24
Report Number: 559790-W
Client Sample ID 0990_QCMW182_170816
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26495
Date Sampled Aug 16, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 89
13C5-PFPeA (surr.) 1 % 66
13C5-PFHxA (surr.) 1 % 98
13C4-PFHpA (surr.) 1 % 100
13C8-PFOA (surr.) 1 % 96
13C5-PFNA (surr.) 1 % 85
13C6-PFDA (surr.) 1 % 64
13C2-PFUnDA (surr.) 1 % 65
13C2-PFDoDA (surr.) 1 % 55
13C2-PFTeDA (surr.) 1 % 60
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 43
D3-N-MeFOSA (surr.) 1 % 17
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 21
D9-N-EtFOSE (surr.) 1 % 23
D5-N-EtFOSAA (surr.) 1 % 17
D3-N-MeFOSAA (surr.) 1 % 23
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 106
18O2-PFHxS (surr.) 1 % 122
13C8-PFOS (surr.) 1 % 113
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 24
Report Number: 559790-W
Client Sample ID 0990_QCMW182_170816
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26495
Date Sampled Aug 16, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 118
13C2-6:2 FTS (surr.) 1 % 95
13C2-8:2 FTS (surr.) 1 % 58
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Heavy Metals
Aluminium 0.05 mg/L < 0.05
Arsenic 0.001 mg/L < 0.001
Cadmium 0.0002 mg/L < 0.0002
Chromium 0.001 mg/L < 0.001
Copper 0.001 mg/L < 0.001
Iron 0.05 mg/L < 0.05
Lead 0.001 mg/L < 0.001
Manganese 0.005 mg/L < 0.005
Mercury 0.0001 mg/L < 0.0001
Nickel 0.001 mg/L < 0.001
Zinc 0.005 mg/L < 0.005
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 24
Report Number: 559790-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Melbourne Aug 25, 2017 7 Day
- Method: LTM-ORG-2010 TRH C6-C36
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Melbourne Aug 24, 2017 7 Day
- Method: TRH C6-C40 - LTM-ORG-2010
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Melbourne Aug 25, 2017 7 Day
- Method: TRH C6-C40 - LTM-ORG-2010
BTEX and Naphthalene
BTEX Melbourne Aug 24, 2017 14 Day
- Method: TRH C6-C40 - LTM-ORG-2010
Polycyclic Aromatic Hydrocarbons Melbourne Aug 25, 2017 7 Day
- Method: LTM-ORG-2130 PAH and Phenols in Water by GCMS
Heavy Metals Melbourne Aug 24, 2017 180 Day
- Method: LTM-MET-3040 Metals in Waters by ICP-MS
Heavy Metals (filtered) Melbourne Aug 24, 2017 180 Day
- Method: LTM-MET-3040 Metals in Waters by ICP-MS
Mercury (filtered) Melbourne Aug 24, 2017 28 Day
- Method: USEPA 7470/1 Mercury
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 24
Report Number: 559790-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 21, 2017 9:43 AMAddress: Level 1, 436 Johnston Street Report #: 559790 Due: Aug 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Alum
inium (filtered)
Arsenic
Arsenic (filtered)
Cadm
ium
Cadm
ium (filtered)
Chrom
ium
Chrom
ium (filtered)
Copper
Copper (filtered)
HO
LD
Iron
Iron (filtered)
Lead
Lead (filtered)
Manganese
Manganese (filtered)
Mercury
Mercury (filtered)
Nickel
Nickel (filtered)
Zinc
Zinc (filtered)
Polycyclic A
romatic H
ydrocarbons
Organochlorine P
esticides
Organophosphorus P
esticides
Acid H
erbicides
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_MW122_7.0_170814
Aug 14, 2017 Soil M17-Au26485 X X X X X X X X X X X X X
2 0990_MW120_5.0_170814
Aug 14, 2017 Soil M17-Au26486 X X X X X X X X X X X X X
3 0990_MW120_19.0_170814
Aug 14, 2017 Soil M17-Au26487 X X X X X X X X X X X X X
4 0990_QCMW148_170814
Aug 14, 2017 Water M17-Au26488 X X X X X X X X X X X X X X X
5 0990_QCMW161_170814
Aug 14, 2017 Water M17-Au26489 X X X X X X X X X X X X X X X
6 0990_QCBH1 Aug 15, 2017 Water M17-Au26490 X X X X X X X X X X X X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 24
Report Number: 559790-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 21, 2017 9:43 AMAddress: Level 1, 436 Johnston Street Report #: 559790 Due: Aug 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Alum
inium (filtered)
Arsenic
Arsenic (filtered)
Cadm
ium
Cadm
ium (filtered)
Chrom
ium
Chrom
ium (filtered)
Copper
Copper (filtered)
HO
LD
Iron
Iron (filtered)
Lead
Lead (filtered)
Manganese
Manganese (filtered)
Mercury
Mercury (filtered)
Nickel
Nickel (filtered)
Zinc
Zinc (filtered)
Polycyclic A
romatic H
ydrocarbons
Organochlorine P
esticides
Organophosphorus P
esticides
Acid H
erbicides
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
49_170815
7 0990_QCMW163_170816
Aug 16, 2017 Water M17-Au26491 X
8 0990_QCMW164_170816
Aug 16, 2017 Water M17-Au26492 X
9 0990_MW126_0.0_170816
Aug 16, 2017 Soil M17-Au26493 X X X X X X X X X X X X X
10 0990_QCMW181_170816
Aug 16, 2017 Soil M17-Au26494 X X X X X X X X X X X X X
11 0990_QCMW182_170816
Aug 16, 2017 Water M17-Au26495 X X X X X X X X X X X X X X X
12 0990_MW120_3.0_170814
Aug 14, 2017 Soil M17-Au26496 X
13 0990_MW120 Aug 14, 2017 Soil M17-Au26497 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 24
Report Number: 559790-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 21, 2017 9:43 AMAddress: Level 1, 436 Johnston Street Report #: 559790 Due: Aug 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Alum
inium (filtered)
Arsenic
Arsenic (filtered)
Cadm
ium
Cadm
ium (filtered)
Chrom
ium
Chrom
ium (filtered)
Copper
Copper (filtered)
HO
LD
Iron
Iron (filtered)
Lead
Lead (filtered)
Manganese
Manganese (filtered)
Mercury
Mercury (filtered)
Nickel
Nickel (filtered)
Zinc
Zinc (filtered)
Polycyclic A
romatic H
ydrocarbons
Organochlorine P
esticides
Organophosphorus P
esticides
Acid H
erbicides
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_14.0_170814
14 0990_MW130_0.0_170816
Aug 16, 2017 Soil M17-Au26498 X
15 0990_MW130_0.2_170816
Aug 16, 2017 Soil M17-Au26499 X
16 0990_MW130_0.5_170816
Aug 16, 2017 Soil M17-Au26500 X
17 0990_MW130_1.0_170816
Aug 16, 2017 Soil M17-Au26501 X
18 0990_MW131_0.0_170816
Aug 16, 2017 Soil M17-Au26502 X
19 0990_MW131_0.2_170816
Aug 16, 2017 Soil M17-Au26503 X
20 0990_MW131 Aug 16, 2017 Soil M17-Au26504 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 24
Report Number: 559790-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 21, 2017 9:43 AMAddress: Level 1, 436 Johnston Street Report #: 559790 Due: Aug 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Alum
inium (filtered)
Arsenic
Arsenic (filtered)
Cadm
ium
Cadm
ium (filtered)
Chrom
ium
Chrom
ium (filtered)
Copper
Copper (filtered)
HO
LD
Iron
Iron (filtered)
Lead
Lead (filtered)
Manganese
Manganese (filtered)
Mercury
Mercury (filtered)
Nickel
Nickel (filtered)
Zinc
Zinc (filtered)
Polycyclic A
romatic H
ydrocarbons
Organochlorine P
esticides
Organophosphorus P
esticides
Acid H
erbicides
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_0.5_170816
21 0990_MW131_1.0_170816
Aug 16, 2017 Soil M17-Au26505 X
22 0990_QCMW165_170816
Aug 16, 2017 Soil M17-Au26506 X
23 0990_QCMW165A_170816
Aug 16, 2017 Soil M17-Au26507 X
24 0990_QCMW130_9.0_170816
Aug 16, 2017 Soil M17-Au26508X
25 0990_QCMW166_170816
Aug 16, 2017 Soil M17-Au26509 X
26 0990_SS166_170815
Aug 15, 2017 Soil M17-Au26513 X X X X X X X X X X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 24
Report Number: 559790-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 21, 2017 9:43 AMAddress: Level 1, 436 Johnston Street Report #: 559790 Due: Aug 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Alum
inium (filtered)
Arsenic
Arsenic (filtered)
Cadm
ium
Cadm
ium (filtered)
Chrom
ium
Chrom
ium (filtered)
Copper
Copper (filtered)
HO
LD
Iron
Iron (filtered)
Lead
Lead (filtered)
Manganese
Manganese (filtered)
Mercury
Mercury (filtered)
Nickel
Nickel (filtered)
Zinc
Zinc (filtered)
Polycyclic A
romatic H
ydrocarbons
Organochlorine P
esticides
Organophosphorus P
esticides
Acid H
erbicides
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
27 0990_QCSS180_170815
Aug 15, 2017 Soil M17-Au26514 X X X X X X X X X X X X X
28 0990_BH192_0.0_170815
Aug 15, 2017 Soil M17-Au26516 X X X X X X X X X X X X X
29 0990_BH192_0.2_170815
Aug 15, 2017 Soil M17-Au26517 X
30 0990_BH192_0.5_170815
Aug 15, 2017 Soil M17-Au26518 X X X X X X X X X X X X X
31 0990_BH193_0.0_170815
Aug 15, 2017 Soil M17-Au26519 X X X X X X X X X X X X X X X X X X X X X X
32 0990_BH193_0.2_170815
Aug 15, 2017 Soil M17-Au26520 X
33 0990_BH193_0.5_170815
Aug 15, 2017 Soil M17-Au26521 X X X X X X X X X X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 24
Report Number: 559790-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 21, 2017 9:43 AMAddress: Level 1, 436 Johnston Street Report #: 559790 Due: Aug 28, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Alum
inium
Alum
inium (filtered)
Arsenic
Arsenic (filtered)
Cadm
ium
Cadm
ium (filtered)
Chrom
ium
Chrom
ium (filtered)
Copper
Copper (filtered)
HO
LD
Iron
Iron (filtered)
Lead
Lead (filtered)
Manganese
Manganese (filtered)
Mercury
Mercury (filtered)
Nickel
Nickel (filtered)
Zinc
Zinc (filtered)
Polycyclic A
romatic H
ydrocarbons
Organochlorine P
esticides
Organophosphorus P
esticides
Acid H
erbicides
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
Test Counts 14 1 14 1 14 1 14 1 14 1 16 14 1 14 1 14 1 14 1 14 1 14 1 5 1 1 1 5 1 11 1 5 17 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 24
Report Number: 559790-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 24
Report Number: 559790-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 mg/L < 0.02 0.02 Pass
TRH C10-C14 mg/L < 0.05 0.05 Pass
TRH C15-C28 mg/L < 0.1 0.1 Pass
TRH C29-C36 mg/L < 0.1 0.1 Pass
Method Blank
BTEX
Benzene mg/L < 0.001 0.001 Pass
Toluene mg/L < 0.001 0.001 Pass
Ethylbenzene mg/L < 0.001 0.001 Pass
m&p-Xylenes mg/L < 0.002 0.002 Pass
o-Xylene mg/L < 0.001 0.001 Pass
Xylenes - Total mg/L < 0.003 0.003 Pass
Method Blank
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
Naphthalene mg/L < 0.01 0.01 Pass
TRH C6-C10 mg/L < 0.02 0.02 Pass
TRH >C10-C16 mg/L < 0.05 0.05 Pass
TRH >C16-C34 mg/L < 0.1 0.1 Pass
TRH >C34-C40 mg/L < 0.1 0.1 Pass
Method Blank
Polycyclic Aromatic Hydrocarbons
Acenaphthene mg/L < 0.001 0.001 Pass
Acenaphthylene mg/L < 0.001 0.001 Pass
Anthracene mg/L < 0.001 0.001 Pass
Benz(a)anthracene mg/L < 0.001 0.001 Pass
Benzo(a)pyrene mg/L < 0.001 0.001 Pass
Benzo(b&j)fluoranthene mg/L < 0.001 0.001 Pass
Benzo(g.h.i)perylene mg/L < 0.001 0.001 Pass
Benzo(k)fluoranthene mg/L < 0.001 0.001 Pass
Chrysene mg/L < 0.001 0.001 Pass
Dibenz(a.h)anthracene mg/L < 0.001 0.001 Pass
Fluoranthene mg/L < 0.001 0.001 Pass
Fluorene mg/L < 0.001 0.001 Pass
Indeno(1.2.3-cd)pyrene mg/L < 0.001 0.001 Pass
Naphthalene mg/L < 0.001 0.001 Pass
Phenanthrene mg/L < 0.001 0.001 Pass
Pyrene mg/L < 0.001 0.001 Pass
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 24
Report Number: 559790-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Heavy Metals
Aluminium mg/L < 0.05 0.05 Pass
Aluminium (filtered) mg/L < 0.05 0.05 Pass
Arsenic mg/L < 0.001 0.001 Pass
Arsenic (filtered) mg/L < 0.001 0.001 Pass
Cadmium mg/L < 0.0002 0.0002 Pass
Cadmium (filtered) mg/L < 0.0002 0.0002 Pass
Chromium mg/L < 0.001 0.001 Pass
Chromium (filtered) mg/L < 0.001 0.001 Pass
Copper mg/L < 0.001 0.001 Pass
Copper (filtered) mg/L < 0.001 0.001 Pass
Iron mg/L < 0.05 0.05 Pass
Iron (filtered) mg/L < 0.05 0.05 Pass
Lead mg/L < 0.001 0.001 Pass
Lead (filtered) mg/L < 0.001 0.001 Pass
Manganese mg/L < 0.005 0.005 Pass
Manganese (filtered) mg/L < 0.005 0.005 Pass
Mercury mg/L < 0.0001 0.0001 Pass
Mercury (filtered) mg/L < 0.0001 0.0001 Pass
Nickel mg/L < 0.001 0.001 Pass
Nickel (filtered) mg/L < 0.001 0.001 Pass
Zinc mg/L < 0.005 0.005 Pass
Zinc (filtered) mg/L < 0.005 0.005 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 % 83 70-130 Pass
TRH C10-C14 % 86 70-130 Pass
LCS - % Recovery
BTEX
Benzene % 115 70-130 Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 24
Report Number: 559790-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Toluene % 103 70-130 Pass
Ethylbenzene % 103 70-130 Pass
m&p-Xylenes % 101 70-130 Pass
Xylenes - Total % 102 70-130 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
Naphthalene % 91 70-130 Pass
TRH C6-C10 % 83 70-130 Pass
TRH >C10-C16 % 91 70-130 Pass
LCS - % Recovery
Polycyclic Aromatic Hydrocarbons
Acenaphthene % 125 70-130 Pass
Acenaphthylene % 108 70-130 Pass
Anthracene % 115 70-130 Pass
Benz(a)anthracene % 122 70-130 Pass
Benzo(a)pyrene % 118 70-130 Pass
Benzo(b&j)fluoranthene % 125 70-130 Pass
Benzo(g.h.i)perylene % 117 70-130 Pass
Benzo(k)fluoranthene % 129 70-130 Pass
Chrysene % 117 70-130 Pass
Dibenz(a.h)anthracene % 112 70-130 Pass
Fluoranthene % 120 70-130 Pass
Fluorene % 129 70-130 Pass
Indeno(1.2.3-cd)pyrene % 122 70-130 Pass
Naphthalene % 117 70-130 Pass
Phenanthrene % 115 70-130 Pass
Pyrene % 114 70-130 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 96 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 120 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 86 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 93 50-150 Pass
Perfluorononanoic acid (PFNA) % 139 50-150 Pass
Perfluorodecanoic acid (PFDA) % 103 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 98 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 114 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 121 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 119 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 75 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 131 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 121 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 91 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 94 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 104 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 93 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 92 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 72 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 96 50-150 Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 24
Report Number: 559790-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 88 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 114 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 90 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 77 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 108 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 144 50-150 Pass
LCS - % Recovery
Heavy Metals
Aluminium % 118 80-120 Pass
Aluminium (filtered) % 118 80-120 Pass
Arsenic % 103 80-120 Pass
Arsenic (filtered) % 103 80-120 Pass
Cadmium % 100 80-120 Pass
Cadmium (filtered) % 100 80-120 Pass
Chromium % 101 80-120 Pass
Chromium (filtered) % 101 80-120 Pass
Copper % 99 80-120 Pass
Copper (filtered) % 99 80-120 Pass
Iron % 108 80-120 Pass
Iron (filtered) % 108 80-120 Pass
Lead % 100 80-120 Pass
Lead (filtered) % 100 80-120 Pass
Manganese % 107 80-120 Pass
Manganese (filtered) % 107 80-120 Pass
Mercury % 96 75-125 Pass
Mercury (filtered) % 96 70-130 Pass
Nickel % 99 80-120 Pass
Nickel (filtered) % 99 80-120 Pass
Zinc % 102 80-120 Pass
Zinc (filtered) % 102 80-120 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1
TRH C6-C9 M17-Au25289 NCP % 76 70-130 Pass
TRH C10-C14 B17-Au26129 NCP % 118 70-130 Pass
Spike - % Recovery
BTEX Result 1
Benzene M17-Au25289 NCP % 105 70-130 Pass
Toluene M17-Au25289 NCP % 98 70-130 Pass
Ethylbenzene M17-Au25289 NCP % 96 70-130 Pass
m&p-Xylenes M17-Au25289 NCP % 100 70-130 Pass
o-Xylene M17-Au25289 NCP % 93 70-130 Pass
Xylenes - Total M17-Au25289 NCP % 98 70-130 Pass
Spike - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1
Naphthalene M17-Au25289 NCP % 74 70-130 Pass
TRH C6-C10 M17-Au25289 NCP % 81 70-130 Pass
TRH >C10-C16 B17-Au26129 NCP % 125 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Aluminium Z17-Au25837 NCP % 105 75-125 Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 24
Report Number: 559790-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Arsenic Z17-Au25837 NCP % 108 75-125 Pass
Cadmium Z17-Au25837 NCP % 102 75-125 Pass
Chromium Z17-Au25837 NCP % 103 75-125 Pass
Copper Z17-Au25837 NCP % 102 75-125 Pass
Iron Z17-Au25837 NCP % 103 75-125 Pass
Lead Z17-Au25837 NCP % 103 75-125 Pass
Manganese Z17-Au25837 NCP % 104 75-125 Pass
Mercury Z17-Au25837 NCP % 90 70-130 Pass
Nickel Z17-Au25837 NCP % 103 75-125 Pass
Zinc Z17-Au25837 NCP % 107 75-125 Pass
Spike - % Recovery
Heavy Metals Result 1
Aluminium (filtered) M17-Au26270 NCP % 97 75-125 Pass
Arsenic (filtered) M17-Au26270 NCP % 103 70-130 Pass
Cadmium (filtered) M17-Au26270 NCP % 100 70-130 Pass
Chromium (filtered) M17-Au26270 NCP % 92 70-130 Pass
Copper (filtered) M17-Au26270 NCP % 97 70-130 Pass
Iron (filtered) M17-Au26270 NCP % 100 70-130 Pass
Lead (filtered) M17-Au26270 NCP % 98 70-130 Pass
Manganese (filtered) M17-Au26270 NCP % 101 70-130 Pass
Mercury (filtered) M17-Au26270 NCP % 99 70-130 Pass
Nickel (filtered) M17-Au26270 NCP % 95 70-130 Pass
Zinc (filtered) M17-Au26270 NCP % 98 70-130 Pass
Spike - % Recovery
Polycyclic Aromatic Hydrocarbons Result 1
Acenaphthene M17-Au26490 CP % 106 70-130 Pass
Acenaphthylene M17-Au26490 CP % 96 70-130 Pass
Anthracene M17-Au26490 CP % 103 70-130 Pass
Benz(a)anthracene M17-Au26490 CP % 107 70-130 Pass
Benzo(a)pyrene M17-Au26490 CP % 126 70-130 Pass
Benzo(b&j)fluoranthene M17-Au26490 CP % 97 70-130 Pass
Benzo(g.h.i)perylene M17-Au26490 CP % 115 70-130 Pass
Benzo(k)fluoranthene M17-Au26490 CP % 122 70-130 Pass
Chrysene M17-Au26490 CP % 99 70-130 Pass
Dibenz(a.h)anthracene M17-Au26490 CP % 115 70-130 Pass
Fluoranthene M17-Au26490 CP % 104 70-130 Pass
Fluorene M17-Au26490 CP % 108 70-130 Pass
Indeno(1.2.3-cd)pyrene M17-Au26490 CP % 120 70-130 Pass
Naphthalene M17-Au26490 CP % 98 70-130 Pass
Phenanthrene M17-Au26490 CP % 92 70-130 Pass
Pyrene M17-Au26490 CP % 100 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26490 CP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26490 CP % 137 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26490 CP % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26490 CP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26490 CP % 110 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26490 CP % 140 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26490 CP % 116 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26490 CP % 105 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26490 CP % 127 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26490 CP % 128 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26490 CP % 128 50-150 Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 24
Report Number: 559790-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26490 CP % 94 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26490 CP % 126 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26490 CP % 117 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26490 CP % 96 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26490 CP % 100 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26490 CP % 115 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26490 CP % 100 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26490 CP % 110 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26490 CP % 78 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26490 CP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26490 CP % 113 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26490 CP % 102 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26490 CP % 113 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26490 CP % 101 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26490 CP % 90 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26490 CP % 124 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26490 CP % 124 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1 Result 2 RPD
TRH C6-C9 M17-Au23804 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Duplicate
BTEX Result 1 Result 2 RPD
Benzene M17-Au23804 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Toluene M17-Au23804 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Ethylbenzene M17-Au23804 NCP mg/L < 0.001 < 0.001 <1 30% Pass
m&p-Xylenes M17-Au23804 NCP mg/L < 0.002 < 0.002 <1 30% Pass
o-Xylene M17-Au23804 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Xylenes - Total M17-Au23804 NCP mg/L < 0.003 < 0.003 <1 30% Pass
Duplicate
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1 Result 2 RPD
Naphthalene M17-Au23804 NCP mg/L < 0.01 < 0.01 <1 30% Pass
TRH C6-C10 M17-Au23804 NCP mg/L < 0.02 < 0.02 <1 30% Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 24
Report Number: 559790-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26488 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26488 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 24
Report Number: 559790-W
Duplicate
Heavy Metals Result 1 Result 2 RPD
Aluminium Z17-Au25837 NCP mg/L < 0.05 < 0.05 <1 30% Pass
Arsenic Z17-Au25837 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Cadmium Z17-Au25837 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Chromium Z17-Au25837 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Copper Z17-Au25837 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Iron Z17-Au25837 NCP mg/L < 0.05 < 0.05 <1 30% Pass
Lead Z17-Au25837 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Manganese Z17-Au25837 NCP mg/L 0.068 0.061 10 30% Pass
Mercury Z17-Au25837 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Nickel Z17-Au25837 NCP mg/L 0.002 0.002 10 30% Pass
Zinc Z17-Au25837 NCP mg/L 0.009 0.011 20 30% Pass
Duplicate
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1 Result 2 RPD
TRH C10-C14 M17-Au26489 CP mg/L < 0.05 < 0.05 <1 30% Pass
TRH C15-C28 M17-Au26489 CP mg/L < 0.1 < 0.1 <1 30% Pass
TRH C29-C36 M17-Au26489 CP mg/L < 0.1 < 0.1 <1 30% Pass
Duplicate
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1 Result 2 RPD
TRH >C10-C16 M17-Au26489 CP mg/L < 0.05 < 0.05 <1 30% Pass
TRH >C16-C34 M17-Au26489 CP mg/L < 0.1 < 0.1 <1 30% Pass
TRH >C34-C40 M17-Au26489 CP mg/L < 0.1 < 0.1 <1 30% Pass
Duplicate
Polycyclic Aromatic Hydrocarbons Result 1 Result 2 RPD
Acenaphthene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Acenaphthylene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Anthracene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Benz(a)anthracene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(a)pyrene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(b&j)fluoranthene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(g.h.i)perylene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Benzo(k)fluoranthene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Chrysene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Dibenz(a.h)anthracene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Fluoranthene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Fluorene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Indeno(1.2.3-cd)pyrene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Naphthalene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Phenanthrene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Pyrene M17-Au26489 CP mg/L < 0.001 < 0.001 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Aluminium (filtered) M17-Au26270 NCP mg/L < 0.05 < 0.05 <1 30% Pass
Arsenic (filtered) M17-Au26270 NCP mg/L 0.001 0.001 <1 30% Pass
Cadmium (filtered) M17-Au26270 NCP mg/L < 0.0002 < 0.0002 <1 30% Pass
Chromium (filtered) M17-Au26270 NCP mg/L 0.077 0.073 5.0 30% Pass
Copper (filtered) M17-Au26270 NCP mg/L 0.003 0.003 1.0 30% Pass
Iron (filtered) M17-Au26270 NCP mg/L < 0.05 < 0.05 <1 30% Pass
Lead (filtered) M17-Au26270 NCP mg/L < 0.001 < 0.001 <1 30% Pass
Manganese (filtered) M17-Au26270 NCP mg/L < 0.005 < 0.005 <1 30% Pass
Mercury (filtered) M17-Au26270 NCP mg/L < 0.0001 < 0.0001 <1 30% Pass
Nickel (filtered) M17-Au26270 NCP mg/L 0.003 0.003 10 30% Pass
Zinc (filtered) M17-Au26270 NCP mg/L 0.029 0.027 5.0 30% Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 24
Report Number: 559790-W
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 23 of 24
Report Number: 559790-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N01F2 is determined by arithmetically subtracting the "naphthalene" value from the ">C10-C16" value. The naphthalene value used in this calculation is obtained from volatiles(Purge & Trap analysis).
N02
Where we have reported both volatile (P&T GCMS) and semivolatile (GCMS) naphthalene data, results may not be identical. Provided correct sample handling protocols havebeen followed, any observed differences in results are likely to be due to procedural differences within each methodology. Results determined by both techniques have passedall QAQC acceptance criteria, and are entirely technically valid.
N04F1 is determined by arithmetically subtracting the "Total BTEX" value from the "C6-C10" value. The "Total BTEX" value is obtained by summing the concentrations of BTEXanalytes. The "C6-C10" value is obtained by quantitating against a standard of mixed aromatic/aliphatic analytes.
N07Please note:- These two PAH isomers closely co-elute using the most contemporary analytical methods and both the reported concentration (and the TEQ) apply specifically tothe total of the two co-eluting PAHs
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Alex Petridis Senior Analyst-Organic (VIC)
Harry Bacalis Senior Analyst-Volatile (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Joseph Edouard Senior Analyst-Organic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 06, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 24 of 24
Report Number: 559790-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559812-S
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_MW129_0.1_170818
0990_MW129_0.5_170818
0990_QCMW184_170818
0990_QCMW175_170819
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26596 M17-Au26597 M17-Au26599 M17-Au26601
Date Sampled Aug 18, 2017 Aug 18, 2017 Aug 18, 2017 Aug 19, 2017
Test/Reference LOR Unit
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 20 mg/kg - < 20 - -
TRH C10-C14 20 mg/kg - < 20 - -
TRH C15-C28 50 mg/kg - < 50 - -
TRH C29-C36 50 mg/kg - < 50 - -
TRH C10-36 (Total) 50 mg/kg - < 50 - -
BTEX
Benzene 0.1 mg/kg - < 0.1 - -
Toluene 0.1 mg/kg - < 0.1 - -
Ethylbenzene 0.1 mg/kg - < 0.1 - -
m&p-Xylenes 0.2 mg/kg - < 0.2 - -
o-Xylene 0.1 mg/kg - < 0.1 - -
Xylenes - Total 0.3 mg/kg - < 0.3 - -
4-Bromofluorobenzene (surr.) 1 % - 83 - -
Volatile Organics
1.1-Dichloroethane 0.5 mg/kg - < 0.5 - < 0.5
1.1-Dichloroethene 0.5 mg/kg - < 0.5 - < 0.5
1.1.1-Trichloroethane 0.5 mg/kg - < 0.5 - < 0.5
1.1.1.2-Tetrachloroethane 0.5 mg/kg - < 0.5 - < 0.5
1.1.2-Trichloroethane 0.5 mg/kg - < 0.5 - < 0.5
1.1.2.2-Tetrachloroethane 0.5 mg/kg - < 0.5 - < 0.5
1.2-Dibromoethane 0.5 mg/kg - < 0.5 - < 0.5
1.2-Dichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.2-Dichloroethane 0.5 mg/kg - < 0.5 - < 0.5
1.2-Dichloropropane 0.5 mg/kg - < 0.5 - < 0.5
1.2.3-Trichloropropane 0.5 mg/kg - < 0.5 - < 0.5
1.2.4-Trimethylbenzene 0.5 mg/kg - < 0.5 - < 0.5
1.3-Dichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.3-Dichloropropane 0.5 mg/kg - < 0.5 - < 0.5
1.3.5-Trimethylbenzene 0.5 mg/kg - < 0.5 - < 0.5
1.4-Dichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
2-Butanone (MEK) 0.5 mg/kg - < 0.5 - < 0.5
2-Propanone (Acetone) 0.5 mg/kg - < 0.5 - < 0.5
4-Chlorotoluene 0.5 mg/kg - < 0.5 - < 0.5
4-Methyl-2-pentanone (MIBK) 0.5 mg/kg - < 0.5 - < 0.5
Allyl chloride 0.5 mg/kg - < 0.5 - < 0.5
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 35
Report Number: 559812-S
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_MW129_0.1_170818
0990_MW129_0.5_170818
0990_QCMW184_170818
0990_QCMW175_170819
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26596 M17-Au26597 M17-Au26599 M17-Au26601
Date Sampled Aug 18, 2017 Aug 18, 2017 Aug 18, 2017 Aug 19, 2017
Test/Reference LOR Unit
Volatile Organics
Benzene 0.1 mg/kg - < 0.1 - < 0.1
Bromobenzene 0.5 mg/kg - < 0.5 - < 0.5
Bromochloromethane 0.5 mg/kg - < 0.5 - < 0.5
Bromodichloromethane 0.5 mg/kg - < 0.5 - < 0.5
Bromoform 0.5 mg/kg - < 0.5 - < 0.5
Bromomethane 0.5 mg/kg - < 0.5 - < 0.5
Carbon disulfide 0.5 mg/kg - < 0.5 - < 0.5
Carbon Tetrachloride 0.5 mg/kg - < 0.5 - < 0.5
Chlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
Chloroethane 0.5 mg/kg - < 0.5 - < 0.5
Chloroform 0.5 mg/kg - < 0.5 - < 0.5
Chloromethane 0.5 mg/kg - < 0.5 - < 0.5
cis-1.2-Dichloroethene 0.5 mg/kg - < 0.5 - < 0.5
cis-1.3-Dichloropropene 0.5 mg/kg - < 0.5 - < 0.5
Dibromochloromethane 0.5 mg/kg - < 0.5 - < 0.5
Dibromomethane 0.5 mg/kg - < 0.5 - < 0.5
Dichlorodifluoromethane 0.5 mg/kg - < 0.5 - < 0.5
Ethylbenzene 0.1 mg/kg - < 0.1 - < 0.1
Iodomethane 0.5 mg/kg - < 0.5 - < 0.5
Isopropyl benzene (Cumene) 0.5 mg/kg - < 0.5 - < 0.5
m&p-Xylenes 0.2 mg/kg - < 0.2 - < 0.2
Methylene Chloride 0.5 mg/kg - < 0.5 - < 0.5
o-Xylene 0.1 mg/kg - < 0.1 - < 0.1
Styrene 0.5 mg/kg - < 0.5 - < 0.5
Tetrachloroethene 0.5 mg/kg - < 0.5 - < 0.5
Toluene 0.1 mg/kg - < 0.1 - < 0.1
trans-1.2-Dichloroethene 0.5 mg/kg - < 0.5 - < 0.5
trans-1.3-Dichloropropene 0.5 mg/kg - < 0.5 - < 0.5
Trichloroethene 0.5 mg/kg - < 0.5 - < 0.5
Trichlorofluoromethane 0.5 mg/kg - < 0.5 - < 0.5
Vinyl chloride 0.5 mg/kg - < 0.5 - < 0.5
Xylenes - Total 0.3 mg/kg - < 0.3 - < 0.3
Vic EPA IWRG 621 Chlorinated hydrocarbons (Total)* 0.5 mg/kg - < 0.5 - < 0.5
Vic EPA IWRG 621 Other chlorinated hydrocarbons(Total)* 0.5 mg/kg - < 0.5 - < 0.5
4-Bromofluorobenzene (surr.) 1 % - 83 - 81
Fluorobenzene (surr.) 1 % - 123 - 86
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
NaphthaleneN02 0.5 mg/kg - < 0.5 - -
TRH C6-C10 less BTEX (F1)N04 20 mg/kg - < 20 - -
TRH C6-C10 20 mg/kg - < 20 - -
TRH >C10-C16 50 mg/kg - < 50 - -
TRH >C10-C16 less Naphthalene (F2)N01 50 mg/kg - < 50 - -
TRH >C16-C34 100 mg/kg - < 100 - -
TRH >C34-C40 100 mg/kg - < 100 - -
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 35
Report Number: 559812-S
Client Sample ID 0990_MW129_0.1_170818
0990_MW129_0.5_170818
0990_QCMW184_170818
0990_QCMW175_170819
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26596 M17-Au26597 M17-Au26599 M17-Au26601
Date Sampled Aug 18, 2017 Aug 18, 2017 Aug 18, 2017 Aug 19, 2017
Test/Reference LOR Unit
Semivolatile Organics
2-Methyl-4.6-dinitrophenol 5 mg/kg - < 5 - < 5
Benzo(a)pyrene TEQ (lower bound) * 0.5 mg/kg - < 0.5 - < 0.5
Benzo(a)pyrene TEQ (medium bound) * 0.5 mg/kg - 0.6 - 0.6
Benzo(a)pyrene TEQ (upper bound) * 0.5 mg/kg - 1.2 - 1.2
1-Chloronaphthalene 0.5 mg/kg - < 0.5 - < 0.5
1-Naphthylamine 0.5 mg/kg - < 0.5 - < 0.5
1.2-Dichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.2.3-Trichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.2.3.4-Tetrachlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.2.3.5-Tetrachlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.2.4-Trichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.2.4.5-Tetrachlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.3-Dichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.3.5-Trichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
1.4-Dichlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
2-Chloronaphthalene 0.5 mg/kg - < 0.5 - < 0.5
2-Chlorophenol 0.5 mg/kg - < 0.5 - < 0.5
2-Methylnaphthalene 0.5 mg/kg - < 0.5 - < 0.5
2-Methylphenol (o-Cresol) 0.2 mg/kg - < 0.2 - < 0.2
2-Naphthylamine 0.5 mg/kg - < 0.5 - < 0.5
2-Nitroaniline 0.5 mg/kg - < 0.5 - < 0.5
2-Nitrophenol 1.0 mg/kg - < 1 - < 1
2-Picoline 0.5 mg/kg - < 0.5 - < 0.5
2.3.4.6-Tetrachlorophenol 0.5 mg/kg - < 0.5 - < 0.5
2.4-Dichlorophenol 0.5 mg/kg - < 0.5 - < 0.5
2.4-Dimethylphenol 0.5 mg/kg - < 0.5 - < 0.5
2.4-Dinitrophenol 5 mg/kg - < 5 - < 5
2.4-Dinitrotoluene 0.5 mg/kg - < 0.5 - < 0.5
2.4.5-Trichlorophenol 1.0 mg/kg - < 1 - < 1
2.4.6-Trichlorophenol 1.0 mg/kg - < 1 - < 1
2.6-Dichlorophenol 0.5 mg/kg - < 0.5 - < 0.5
2.6-Dinitrotoluene 0.5 mg/kg - < 0.5 - < 0.5
3&4-Methylphenol (m&p-Cresol) 0.4 mg/kg - < 0.4 - < 0.4
3-Methylcholanthrene 0.5 mg/kg - < 0.5 - < 0.5
3.3'-Dichlorobenzidine 0.5 mg/kg - < 0.5 - < 0.5
4-Aminobiphenyl 0.5 mg/kg - < 0.5 - < 0.5
4-Bromophenyl phenyl ether 0.5 mg/kg - < 0.5 - < 0.5
4-Chloro-3-methylphenol 1.0 mg/kg - < 1 - < 1
4-Chlorophenyl phenyl ether 0.5 mg/kg - < 0.5 - < 0.5
4-Nitrophenol 5 mg/kg - < 5 - < 5
4.4'-DDD 0.5 mg/kg - < 0.5 - < 0.5
4.4'-DDE 0.5 mg/kg - < 0.5 - < 0.5
4.4'-DDT 0.5 mg/kg - < 0.5 - < 0.5
7.12-Dimethylbenz(a)anthracene 0.5 mg/kg - < 0.5 - < 0.5
a-BHC 0.5 mg/kg - < 0.5 - < 0.5
Acenaphthene 0.5 mg/kg - < 0.5 - < 0.5
Acenaphthylene 0.5 mg/kg - < 0.5 - < 0.5
Acetophenone 0.5 mg/kg - < 0.5 - < 0.5
Aldrin 0.5 mg/kg - < 0.5 - < 0.5
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 35
Report Number: 559812-S
Client Sample ID 0990_MW129_0.1_170818
0990_MW129_0.5_170818
0990_QCMW184_170818
0990_QCMW175_170819
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26596 M17-Au26597 M17-Au26599 M17-Au26601
Date Sampled Aug 18, 2017 Aug 18, 2017 Aug 18, 2017 Aug 19, 2017
Test/Reference LOR Unit
Semivolatile Organics
Aniline 0.5 mg/kg - < 0.5 - < 0.5
Anthracene 0.5 mg/kg - < 0.5 - < 0.5
b-BHC 0.5 mg/kg - < 0.5 - < 0.5
Benz(a)anthracene 0.5 mg/kg - < 0.5 - < 0.5
Benzo(a)pyrene 0.5 mg/kg - < 0.5 - < 0.5
Benzo(b&j)fluorantheneN07 0.5 mg/kg - < 0.5 - < 0.5
Benzo(g.h.i)perylene 0.5 mg/kg - < 0.5 - < 0.5
Benzo(k)fluoranthene 0.5 mg/kg - < 0.5 - < 0.5
Benzyl chloride 0.5 mg/kg - < 0.5 - < 0.5
Bis(2-chloroethoxy)methane 0.5 mg/kg - < 0.5 - < 0.5
Bis(2-chloroisopropyl)ether 0.5 mg/kg - < 0.5 - < 0.5
Bis(2-ethylhexyl)phthalate 0.5 mg/kg - < 0.5 - < 0.5
Butyl benzyl phthalate 0.5 mg/kg - < 0.5 - < 0.5
Chrysene 0.5 mg/kg - < 0.5 - < 0.5
d-BHC 0.5 mg/kg - < 0.5 - < 0.5
Di-n-butyl phthalate 0.5 mg/kg - < 0.5 - < 0.5
Di-n-octyl phthalate 0.5 mg/kg - < 0.5 - < 0.5
Dibenz(a.h)anthracene 0.5 mg/kg - < 0.5 - < 0.5
Dibenz(a.j)acridine 0.5 mg/kg - < 0.5 - < 0.5
Dibenzofuran 0.5 mg/kg - < 0.5 - < 0.5
Dieldrin 0.5 mg/kg - < 0.5 - < 0.5
Diethyl phthalate 0.5 mg/kg - < 0.5 - < 0.5
Dimethyl phthalate 0.5 mg/kg - < 0.5 - < 0.5
Dimethylaminoazobenzene 0.5 mg/kg - < 0.5 - < 0.5
Diphenylamine 0.5 mg/kg - < 0.5 - < 0.5
Endosulfan I 0.5 mg/kg - < 0.5 - < 0.5
Endosulfan II 0.5 mg/kg - < 0.5 - < 0.5
Endosulfan sulphate 0.5 mg/kg - < 0.5 - < 0.5
Endrin 0.5 mg/kg - < 0.5 - < 0.5
Endrin aldehyde 0.5 mg/kg - < 0.5 - < 0.5
Endrin ketone 0.5 mg/kg - < 0.5 - < 0.5
Fluoranthene 0.5 mg/kg - < 0.5 - < 0.5
Fluorene 0.5 mg/kg - < 0.5 - < 0.5
g-BHC (Lindane) 0.5 mg/kg - < 0.5 - < 0.5
Heptachlor 0.5 mg/kg - < 0.5 - < 0.5
Heptachlor epoxide 0.5 mg/kg - < 0.5 - < 0.5
Hexachlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
Hexachlorobutadiene 0.5 mg/kg - < 0.5 - < 0.5
Hexachlorocyclopentadiene 0.5 mg/kg - < 0.5 - < 0.5
Hexachloroethane 0.5 mg/kg - < 0.5 - < 0.5
Indeno(1.2.3-cd)pyrene 0.5 mg/kg - < 0.5 - < 0.5
Methoxychlor 0.5 mg/kg - < 0.5 - < 0.5
N-Nitrosodibutylamine 0.5 mg/kg - < 0.5 - < 0.5
N-Nitrosodipropylamine 0.5 mg/kg - < 0.5 - < 0.5
N-Nitrosopiperidine 0.5 mg/kg - < 0.5 - < 0.5
Naphthalene 0.5 mg/kg - < 0.5 - < 0.5
Nitrobenzene 0.5 mg/kg - < 0.5 - < 0.5
Pentachlorobenzene 0.5 mg/kg - < 0.5 - < 0.5
Pentachloronitrobenzene 0.5 mg/kg - < 0.5 - < 0.5
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 35
Report Number: 559812-S
Client Sample ID 0990_MW129_0.1_170818
0990_MW129_0.5_170818
0990_QCMW184_170818
0990_QCMW175_170819
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26596 M17-Au26597 M17-Au26599 M17-Au26601
Date Sampled Aug 18, 2017 Aug 18, 2017 Aug 18, 2017 Aug 19, 2017
Test/Reference LOR Unit
Semivolatile Organics
Pentachlorophenol 1.0 mg/kg - < 1 - < 1
Phenanthrene 0.5 mg/kg - < 0.5 - < 0.5
Phenol 0.5 mg/kg - < 0.5 - < 0.5
Pronamide 0.5 mg/kg - < 0.5 - < 0.5
Pyrene 0.5 mg/kg - < 0.5 - < 0.5
Trifluralin 0.5 mg/kg - < 0.5 - < 0.5
Phenol-d6 (surr.) 1 % - 81 - 82
Nitrobenzene-d5 (surr.) 1 % - 90 - 93
2-Fluorobiphenyl (surr.) 1 % - 104 - 109
2.4.6-Tribromophenol (surr.) 1 % - 31 - 36
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg 13 < 5 10 < 5
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg 24 9.2 20 < 5
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg N0996 N0932 N0987 N0938
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg N0931 N0927 N0930 N097.4
Perfluorooctanoic acid (PFOA)N11 5 ug/kg N0956 N0994 N0956 N0911
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 114 117 118 115
13C5-PFPeA (surr.) 1 % 105 107 106 103
13C5-PFHxA (surr.) 1 % 112 120 116 115
13C4-PFHpA (surr.) 1 % 109 113 112 112
13C8-PFOA (surr.) 1 % 104 103 106 102
13C5-PFNA (surr.) 1 % 111 112 115 126
13C6-PFDA (surr.) 1 % 97 91 96 108
13C2-PFUnDA (surr.) 1 % 112 114 117 109
13C2-PFDoDA (surr.) 1 % 114 120 119 113
13C2-PFTeDA (surr.) 1 % 133 132 138 114
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg N0918 < 5 N0918 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 80 81 82 75
D3-N-MeFOSA (surr.) 1 % 133 135 141 120
D5-N-EtFOSA (surr.) 1 % 101 100 102 92
D7-N-MeFOSE (surr.) 1 % 120 123 130 113
D9-N-EtFOSE (surr.) 1 % 126 124 127 112
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 35
Report Number: 559812-S
Client Sample ID 0990_MW129_0.1_170818
0990_MW129_0.5_170818
0990_QCMW184_170818
0990_QCMW175_170819
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26596 M17-Au26597 M17-Au26599 M17-Au26601
Date Sampled Aug 18, 2017 Aug 18, 2017 Aug 18, 2017 Aug 19, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSAA (surr.) 1 % 145 142 149 140
D3-N-MeFOSAA (surr.) 1 % 156 155 155 158
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg 16 5.2 15 39
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg 23 11 22 32
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg N09180 N09170 N09170 N09320
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg N0925 N0965 N0926 < 5
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N091700 N091300 N091800 N0934
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 110 110 111 111
18O2-PFHxS (surr.) 1 % 103 106 106 101
13C8-PFOS (surr.) 1 % 103 86 110 99
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 19 < 10 < 10
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg 6.3 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 114 116 117 121
13C2-6:2 FTS (surr.) 1 % 106 108 108 115
13C2-8:2 FTS (surr.) 1 % 122 121 126 131
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 1880 1470 1970 354
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 1756 1394 1856 45
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 1936 1564 2026 365
Sum of WA DER PFAS (n=10) 10 ug/kg 2122.3 1656.4 2188 449.4
Sum of PFASs (n=28) 50 ug/kg 2188.3 1732.4 2254 481.4
1.4-Dioxane
1.4-Dioxane 10 ug/kg - < 10 - < 10
1.4-Dioxane-d8 (surr.) 1 % - 86 - 78
Heavy Metals
Arsenic 2 mg/kg 2.9 15 5.7 6.7
Cadmium 0.4 mg/kg < 0.4 < 0.4 < 0.4 < 0.4
Chromium 5 mg/kg 25 140 47 52
Copper 5 mg/kg 6.6 8.2 6.2 17
Lead 5 mg/kg 5.9 20 9.3 20
Mercury 0.1 mg/kg < 0.1 < 0.1 < 0.1 < 0.1
Nickel 5 mg/kg 6.5 < 5 6.9 14
Zinc 5 mg/kg 8.3 < 5 8.5 13
% Moisture 1 % 3.6 6.0 4.0 21
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 35
Report Number: 559812-S
Client Sample ID 0990_MW128_0.0_170819
0990_MW128_0.5_170819
0990_MW128_1.0_170819
0990_MW129_1.0_170818
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26603 M17-Au26604 M17-Au26605 M17-Au26625
Date Sampled Aug 19, 2017 Aug 19, 2017 Aug 19, 2017 Aug 18, 2017
Test/Reference LOR Unit
Volatile Organics
1.1-Dichloroethane 0.5 mg/kg < 0.5 - - -
1.1-Dichloroethene 0.5 mg/kg < 0.5 - - -
1.1.1-Trichloroethane 0.5 mg/kg < 0.5 - - -
1.1.1.2-Tetrachloroethane 0.5 mg/kg < 0.5 - - -
1.1.2-Trichloroethane 0.5 mg/kg < 0.5 - - -
1.1.2.2-Tetrachloroethane 0.5 mg/kg < 0.5 - - -
1.2-Dibromoethane 0.5 mg/kg < 0.5 - - -
1.2-Dichlorobenzene 0.5 mg/kg < 0.5 - - -
1.2-Dichloroethane 0.5 mg/kg < 0.5 - - -
1.2-Dichloropropane 0.5 mg/kg < 0.5 - - -
1.2.3-Trichloropropane 0.5 mg/kg < 0.5 - - -
1.2.4-Trimethylbenzene 0.5 mg/kg < 0.5 - - -
1.3-Dichlorobenzene 0.5 mg/kg < 0.5 - - -
1.3-Dichloropropane 0.5 mg/kg < 0.5 - - -
1.3.5-Trimethylbenzene 0.5 mg/kg < 0.5 - - -
1.4-Dichlorobenzene 0.5 mg/kg < 0.5 - - -
2-Butanone (MEK) 0.5 mg/kg < 0.5 - - -
2-Propanone (Acetone) 0.5 mg/kg < 0.5 - - -
4-Chlorotoluene 0.5 mg/kg < 0.5 - - -
4-Methyl-2-pentanone (MIBK) 0.5 mg/kg < 0.5 - - -
Allyl chloride 0.5 mg/kg < 0.5 - - -
Benzene 0.1 mg/kg < 0.1 - - -
Bromobenzene 0.5 mg/kg < 0.5 - - -
Bromochloromethane 0.5 mg/kg < 0.5 - - -
Bromodichloromethane 0.5 mg/kg < 0.5 - - -
Bromoform 0.5 mg/kg < 0.5 - - -
Bromomethane 0.5 mg/kg < 0.5 - - -
Carbon disulfide 0.5 mg/kg < 0.5 - - -
Carbon Tetrachloride 0.5 mg/kg < 0.5 - - -
Chlorobenzene 0.5 mg/kg < 0.5 - - -
Chloroethane 0.5 mg/kg < 0.5 - - -
Chloroform 0.5 mg/kg < 0.5 - - -
Chloromethane 0.5 mg/kg < 0.5 - - -
cis-1.2-Dichloroethene 0.5 mg/kg < 0.5 - - -
cis-1.3-Dichloropropene 0.5 mg/kg < 0.5 - - -
Dibromochloromethane 0.5 mg/kg < 0.5 - - -
Dibromomethane 0.5 mg/kg < 0.5 - - -
Dichlorodifluoromethane 0.5 mg/kg < 0.5 - - -
Ethylbenzene 0.1 mg/kg < 0.1 - - -
Iodomethane 0.5 mg/kg < 0.5 - - -
Isopropyl benzene (Cumene) 0.5 mg/kg < 0.5 - - -
m&p-Xylenes 0.2 mg/kg < 0.2 - - -
Methylene Chloride 0.5 mg/kg < 0.5 - - -
o-Xylene 0.1 mg/kg < 0.1 - - -
Styrene 0.5 mg/kg < 0.5 - - -
Tetrachloroethene 0.5 mg/kg < 0.5 - - -
Toluene 0.1 mg/kg < 0.1 - - -
trans-1.2-Dichloroethene 0.5 mg/kg < 0.5 - - -
trans-1.3-Dichloropropene 0.5 mg/kg < 0.5 - - -
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 35
Report Number: 559812-S
Client Sample ID 0990_MW128_0.0_170819
0990_MW128_0.5_170819
0990_MW128_1.0_170819
0990_MW129_1.0_170818
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26603 M17-Au26604 M17-Au26605 M17-Au26625
Date Sampled Aug 19, 2017 Aug 19, 2017 Aug 19, 2017 Aug 18, 2017
Test/Reference LOR Unit
Volatile Organics
Trichloroethene 0.5 mg/kg < 0.5 - - -
Trichlorofluoromethane 0.5 mg/kg < 0.5 - - -
Vinyl chloride 0.5 mg/kg < 0.5 - - -
Xylenes - Total 0.3 mg/kg < 0.3 - - -
Vic EPA IWRG 621 Chlorinated hydrocarbons (Total)* 0.5 mg/kg < 0.5 - - -
Vic EPA IWRG 621 Other chlorinated hydrocarbons(Total)* 0.5 mg/kg < 0.5 - - -
4-Bromofluorobenzene (surr.) 1 % 64 - - -
Fluorobenzene (surr.) 1 % 78 - - -
Semivolatile Organics
2-Methyl-4.6-dinitrophenol 5 mg/kg < 5 - - -
Benzo(a)pyrene TEQ (lower bound) * 0.5 mg/kg < 0.5 - - -
Benzo(a)pyrene TEQ (medium bound) * 0.5 mg/kg 0.6 - - -
Benzo(a)pyrene TEQ (upper bound) * 0.5 mg/kg 1.2 - - -
1-Chloronaphthalene 0.5 mg/kg < 0.5 - - -
1-Naphthylamine 0.5 mg/kg < 0.5 - - -
1.2-Dichlorobenzene 0.5 mg/kg < 0.5 - - -
1.2.3-Trichlorobenzene 0.5 mg/kg < 0.5 - - -
1.2.3.4-Tetrachlorobenzene 0.5 mg/kg < 0.5 - - -
1.2.3.5-Tetrachlorobenzene 0.5 mg/kg < 0.5 - - -
1.2.4-Trichlorobenzene 0.5 mg/kg < 0.5 - - -
1.2.4.5-Tetrachlorobenzene 0.5 mg/kg < 0.5 - - -
1.3-Dichlorobenzene 0.5 mg/kg < 0.5 - - -
1.3.5-Trichlorobenzene 0.5 mg/kg < 0.5 - - -
1.4-Dichlorobenzene 0.5 mg/kg < 0.5 - - -
2-Chloronaphthalene 0.5 mg/kg < 0.5 - - -
2-Chlorophenol 0.5 mg/kg < 0.5 - - -
2-Methylnaphthalene 0.5 mg/kg < 0.5 - - -
2-Methylphenol (o-Cresol) 0.2 mg/kg < 0.2 - - -
2-Naphthylamine 0.5 mg/kg < 0.5 - - -
2-Nitroaniline 0.5 mg/kg < 0.5 - - -
2-Nitrophenol 1.0 mg/kg < 1 - - -
2-Picoline 0.5 mg/kg < 0.5 - - -
2.3.4.6-Tetrachlorophenol 0.5 mg/kg < 0.5 - - -
2.4-Dichlorophenol 0.5 mg/kg < 0.5 - - -
2.4-Dimethylphenol 0.5 mg/kg < 0.5 - - -
2.4-Dinitrophenol 5 mg/kg < 5 - - -
2.4-Dinitrotoluene 0.5 mg/kg < 0.5 - - -
2.4.5-Trichlorophenol 1.0 mg/kg < 1 - - -
2.4.6-Trichlorophenol 1.0 mg/kg < 1 - - -
2.6-Dichlorophenol 0.5 mg/kg < 0.5 - - -
2.6-Dinitrotoluene 0.5 mg/kg < 0.5 - - -
3&4-Methylphenol (m&p-Cresol) 0.4 mg/kg < 0.4 - - -
3-Methylcholanthrene 0.5 mg/kg < 0.5 - - -
3.3'-Dichlorobenzidine 0.5 mg/kg < 0.5 - - -
4-Aminobiphenyl 0.5 mg/kg < 0.5 - - -
4-Bromophenyl phenyl ether 0.5 mg/kg < 0.5 - - -
4-Chloro-3-methylphenol 1.0 mg/kg < 1 - - -
4-Chlorophenyl phenyl ether 0.5 mg/kg < 0.5 - - -
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 35
Report Number: 559812-S
Client Sample ID 0990_MW128_0.0_170819
0990_MW128_0.5_170819
0990_MW128_1.0_170819
0990_MW129_1.0_170818
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26603 M17-Au26604 M17-Au26605 M17-Au26625
Date Sampled Aug 19, 2017 Aug 19, 2017 Aug 19, 2017 Aug 18, 2017
Test/Reference LOR Unit
Semivolatile Organics
4-Nitrophenol 5 mg/kg < 5 - - -
4.4'-DDD 0.5 mg/kg < 0.5 - - -
4.4'-DDE 0.5 mg/kg < 0.5 - - -
4.4'-DDT 0.5 mg/kg < 0.5 - - -
7.12-Dimethylbenz(a)anthracene 0.5 mg/kg < 0.5 - - -
a-BHC 0.5 mg/kg < 0.5 - - -
Acenaphthene 0.5 mg/kg < 0.5 - - -
Acenaphthylene 0.5 mg/kg < 0.5 - - -
Acetophenone 0.5 mg/kg < 0.5 - - -
Aldrin 0.5 mg/kg < 0.5 - - -
Aniline 0.5 mg/kg < 0.5 - - -
Anthracene 0.5 mg/kg < 0.5 - - -
b-BHC 0.5 mg/kg < 0.5 - - -
Benz(a)anthracene 0.5 mg/kg < 0.5 - - -
Benzo(a)pyrene 0.5 mg/kg < 0.5 - - -
Benzo(b&j)fluorantheneN07 0.5 mg/kg < 0.5 - - -
Benzo(g.h.i)perylene 0.5 mg/kg < 0.5 - - -
Benzo(k)fluoranthene 0.5 mg/kg < 0.5 - - -
Benzyl chloride 0.5 mg/kg < 0.5 - - -
Bis(2-chloroethoxy)methane 0.5 mg/kg < 0.5 - - -
Bis(2-chloroisopropyl)ether 0.5 mg/kg < 0.5 - - -
Bis(2-ethylhexyl)phthalate 0.5 mg/kg < 0.5 - - -
Butyl benzyl phthalate 0.5 mg/kg < 0.5 - - -
Chrysene 0.5 mg/kg < 0.5 - - -
d-BHC 0.5 mg/kg < 0.5 - - -
Di-n-butyl phthalate 0.5 mg/kg < 0.5 - - -
Di-n-octyl phthalate 0.5 mg/kg < 0.5 - - -
Dibenz(a.h)anthracene 0.5 mg/kg < 0.5 - - -
Dibenz(a.j)acridine 0.5 mg/kg < 0.5 - - -
Dibenzofuran 0.5 mg/kg < 0.5 - - -
Dieldrin 0.5 mg/kg < 0.5 - - -
Diethyl phthalate 0.5 mg/kg < 0.5 - - -
Dimethyl phthalate 0.5 mg/kg < 0.5 - - -
Dimethylaminoazobenzene 0.5 mg/kg < 0.5 - - -
Diphenylamine 0.5 mg/kg < 0.5 - - -
Endosulfan I 0.5 mg/kg < 0.5 - - -
Endosulfan II 0.5 mg/kg < 0.5 - - -
Endosulfan sulphate 0.5 mg/kg < 0.5 - - -
Endrin 0.5 mg/kg < 0.5 - - -
Endrin aldehyde 0.5 mg/kg < 0.5 - - -
Endrin ketone 0.5 mg/kg < 0.5 - - -
Fluoranthene 0.5 mg/kg < 0.5 - - -
Fluorene 0.5 mg/kg < 0.5 - - -
g-BHC (Lindane) 0.5 mg/kg < 0.5 - - -
Heptachlor 0.5 mg/kg < 0.5 - - -
Heptachlor epoxide 0.5 mg/kg < 0.5 - - -
Hexachlorobenzene 0.5 mg/kg < 0.5 - - -
Hexachlorobutadiene 0.5 mg/kg < 0.5 - - -
Hexachlorocyclopentadiene 0.5 mg/kg < 0.5 - - -
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 35
Report Number: 559812-S
Client Sample ID 0990_MW128_0.0_170819
0990_MW128_0.5_170819
0990_MW128_1.0_170819
0990_MW129_1.0_170818
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26603 M17-Au26604 M17-Au26605 M17-Au26625
Date Sampled Aug 19, 2017 Aug 19, 2017 Aug 19, 2017 Aug 18, 2017
Test/Reference LOR Unit
Semivolatile Organics
Hexachloroethane 0.5 mg/kg < 0.5 - - -
Indeno(1.2.3-cd)pyrene 0.5 mg/kg < 0.5 - - -
Methoxychlor 0.5 mg/kg < 0.5 - - -
N-Nitrosodibutylamine 0.5 mg/kg < 0.5 - - -
N-Nitrosodipropylamine 0.5 mg/kg < 0.5 - - -
N-Nitrosopiperidine 0.5 mg/kg < 0.5 - - -
Naphthalene 0.5 mg/kg < 0.5 - - -
Nitrobenzene 0.5 mg/kg < 0.5 - - -
Pentachlorobenzene 0.5 mg/kg < 0.5 - - -
Pentachloronitrobenzene 0.5 mg/kg < 0.5 - - -
Pentachlorophenol 1.0 mg/kg < 1 - - -
Phenanthrene 0.5 mg/kg < 0.5 - - -
Phenol 0.5 mg/kg < 0.5 - - -
Pronamide 0.5 mg/kg < 0.5 - - -
Pyrene 0.5 mg/kg < 0.5 - - -
Trifluralin 0.5 mg/kg < 0.5 - - -
Phenol-d6 (surr.) 1 % 78 - - -
Nitrobenzene-d5 (surr.) 1 % 93 - - -
2-Fluorobiphenyl (surr.) 1 % 111 - - -
2.4.6-Tribromophenol (surr.) 1 % 46 - - -
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 5 ug/kg < 5 < 5 < 5 6.3
Perfluoropentanoic acid (PFPeA)N11 5 ug/kg < 5 < 5 < 5 14
Perfluorohexanoic acid (PFHxA)N11 5 ug/kg N0920 < 5 < 5 N0952
Perfluoroheptanoic acid (PFHpA)N11 5 ug/kg < 5 < 5 < 5 N0930
Perfluorooctanoic acid (PFOA)N11 5 ug/kg N096.4 < 5 < 5 N09140
Perfluorononanoic acid (PFNA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorodecanoic acid (PFDA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluoroundecanoic acid (PFUnA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorododecanoic acid (PFDoA)N11 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotridecanoic acid (PFTrDA) 5 ug/kg < 5 < 5 < 5 < 5
Perfluorotetradecanoic acid (PFTeDA)N11 5 ug/kg < 5 < 5 < 5 < 5
13C4-PFBA (surr.) 1 % 116 126 123 129
13C5-PFPeA (surr.) 1 % 113 119 133 134
13C5-PFHxA (surr.) 1 % 120 131 128 127
13C4-PFHpA (surr.) 1 % 113 119 116 118
13C8-PFOA (surr.) 1 % 100 115 112 102
13C5-PFNA (surr.) 1 % 109 116 112 116
13C6-PFDA (surr.) 1 % 110 116 117 99
13C2-PFUnDA (surr.) 1 % 111 113 107 110
13C2-PFDoDA (surr.) 1 % 108 124 121 123
13C2-PFTeDA (surr.) 1 % 123 132 130 135
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 5 ug/kg < 5 < 5 < 5 < 5
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 35
Report Number: 559812-S
Client Sample ID 0990_MW128_0.0_170819
0990_MW128_0.5_170819
0990_MW128_1.0_170819
0990_MW129_1.0_170818
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26603 M17-Au26604 M17-Au26605 M17-Au26625
Date Sampled Aug 19, 2017 Aug 19, 2017 Aug 19, 2017 Aug 18, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 5 ug/kg < 5 < 5 < 5 < 5
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 10 ug/kg < 10 < 10 < 10 < 10
13C8-FOSA (surr.) 1 % 83 79 75 77
D3-N-MeFOSA (surr.) 1 % 132 142 137 142
D5-N-EtFOSA (surr.) 1 % 94 100 94 94
D7-N-MeFOSE (surr.) 1 % 118 149 148 161
D9-N-EtFOSE (surr.) 1 % 112 138 137 143
D5-N-EtFOSAA (surr.) 1 % 132 142 148 160
D3-N-MeFOSAA (surr.) 1 % 149 159 168 177
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 5 ug/kg 21 < 5 < 5 10
Perfluoropentanesulfonic acid (PFPeS) 5 ug/kg 17 < 5 < 5 10
Perfluorohexanesulfonic acid (PFHxS)N11 5 ug/kg N09160 < 5 < 5 N09290
Perfluoroheptanesulfonic acid (PFHpS) 5 ug/kg < 5 < 5 < 5 12
Perfluorooctanesulfonic acid (PFOS)N11 5 ug/kg N0923 N0953 N0929 N092200
Perfluorodecanesulfonic acid (PFDS) 5 ug/kg < 5 < 5 < 5 < 5
13C3-PFBS (surr.) 1 % 112 118 118 120
18O2-PFHxS (surr.) 1 % 106 117 112 111
13C8-PFOS (surr.) 1 % 102 109 104 67
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 10 ug/kg < 10 < 10 < 10 15
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 5 ug/kg < 5 < 5 < 5 < 5
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 5 ug/kg < 5 < 5 < 5 < 5
13C2-4:2 FTS (surr.) 1 % 119 124 124 124
13C2-6:2 FTS (surr.) 1 % 118 103 106 116
13C2-8:2 FTS (surr.) 1 % 125 134 133 140
PFASs Summations
Sum (PFHxS + PFOS) 5 ug/kg 183 53 29 2490
Sum of US EPA PFAS (PFOS + PFOA) 5 ug/kg 29.4 53 29 2340
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 5 ug/kg 189.4 53 29 2630
Sum of WA DER PFAS (n=10) 10 ug/kg 230.4 53 29 2757.3
Sum of PFASs (n=28) 50 ug/kg 247.4 53 < 50 2779.3
1.4-Dioxane
1.4-Dioxane 10 ug/kg < 10 - - -
1.4-Dioxane-d8 (surr.) 1 % 85 - - -
Heavy Metals
Arsenic 2 mg/kg 4.9 15 5.0 5.3
Cadmium 0.4 mg/kg < 0.4 < 0.4 < 0.4 < 0.4
Chromium 5 mg/kg 41 55 37 47
Copper 5 mg/kg 14 21 12 7.3
Lead 5 mg/kg 20 50 31 7.8
Mercury 0.1 mg/kg < 0.1 < 0.1 < 0.1 < 0.1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 35
Report Number: 559812-S
Client Sample ID 0990_MW128_0.0_170819
0990_MW128_0.5_170819
0990_MW128_1.0_170819
0990_MW129_1.0_170818
Sample Matrix Soil Soil Soil Soil
Eurofins | mgt Sample No. M17-Au26603 M17-Au26604 M17-Au26605 M17-Au26625
Date Sampled Aug 19, 2017 Aug 19, 2017 Aug 19, 2017 Aug 18, 2017
Test/Reference LOR Unit
Heavy Metals
Nickel 5 mg/kg 12 17 10 8.6
Zinc 5 mg/kg 45 6.9 6.5 < 5
% Moisture 1 % 3.0 12 21 7.5
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 35
Report Number: 559812-S
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Melbourne Aug 24, 2017 14 Day
- Method: LTM-ORG-2010 TRH C6-C36
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Melbourne Aug 24, 2017 14 Day
- Method: TRH C6-C40 - LTM-ORG-2010
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Melbourne Aug 24, 2017 14 Day
- Method: TRH C6-C40 - LTM-ORG-2010
BTEX and Naphthalene
BTEX Melbourne Aug 24, 2017 14 Day
- Method: TRH C6-C40 - LTM-ORG-2010
Volatile Organics Melbourne Aug 24, 2017 7 Days
- Method: LTM-ORG-2150 VOCs in Soils Liquid and other Aqueous Matrices
Semivolatile Organics Melbourne Aug 24, 2017 14 Day
- Method: USEPA 8270 Semivolatile Organics
Metals M8 Sydney Aug 24, 2017 28 Day
- Method: LTM-MET-3040_R0 TOTAL AND DISSOLVED METALS AND MERCURY IN WATERS BY ICP-MS
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 28, 2017 180 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
% Moisture Melbourne Aug 24, 2017 14 Day
- Method: LTM-GEN-7080 Moisture
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 35
Report Number: 559812-S
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB027_170817
Aug 17, 2017 Water M17-Au26590 X X X X X
2 0990_PB028_1_170817
Aug 17, 2017 Water M17-Au26591 X X X X X
3 0990_PB028_2_170817
Aug 17, 2017 Water M17-Au26592 X X X X X
4 0990_QCMW167_170817
Aug 17, 2017 Water M17-Au26593 X
5 0990_QCMW183_170817
Aug 17, 2017 Water M17-Au26594 X
6 0990_PB29_1 Aug 18, 2017 Water M17-Au26595 X X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 35
Report Number: 559812-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
70818
7 0990_MW129_0.1_170818
Aug 18, 2017 Soil M17-Au26596 X X X
8 0990_MW129_0.5_170818
Aug 18, 2017 Soil M17-Au26597 X X X X X X X X
9 0990_QCMW185_170818
Aug 18, 2017 Water M17-Au26598 X
10 0990_QCMW184_170818
Aug 18, 2017 Soil M17-Au26599 X X X
11 0990_QCMW168_170818
Aug 18, 2017 Water M17-Au26600 X
12 0990_QCMW175_170819
Aug 19, 2017 Soil M17-Au26601 X X X X X X
13 0990_QCMW1 Aug 19, 2017 Water M17-Au26602 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 35
Report Number: 559812-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
76_170819
14 0990_MW128_0.0_170819
Aug 19, 2017 Soil M17-Au26603 X X X X X X
15 0990_MW128_0.5_170819
Aug 19, 2017 Soil M17-Au26604 X X X
16 0990_MW128_1.0_170819
Aug 19, 2017 Soil M17-Au26605 X X X
17 0990_QCMW190_170819
Aug 19, 2017 Water M17-Au26606 X
18 0990_MW126_11.2_170817
Aug 17, 2017 Soil M17-Au26607 X
19 0990_MW139_0.0_170817
Aug 17, 2017 Soil M17-Au26608 X
20 0990_MW139 Aug 17, 2017 Soil M17-Au26609 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 35
Report Number: 559812-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_0.2_170817
21 0990_MW139_0.5_170817
Aug 17, 2017 Soil M17-Au26610 X
22 0990_MW139_1.0_170817
Aug 17, 2017 Soil M17-Au26611 X
23 0990_QCMW174_170818
Aug 18, 2017 Water M17-Au26612 X
24 0990_MW129_0.7_170818
Aug 18, 2017 Soil M17-Au26613 X
25 0990_QCMW184A_170818
Aug 18, 2017 Soil M17-Au26614 X
26 0990_MW139_10.0_170818
Aug 18, 2017 Soil M17-Au26615 X
27 0990_MW128 Aug 19, 2017 Soil M17-Au26616 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 35
Report Number: 559812-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_0.2_170819
28 0990_MW140_0.0_170819
Aug 19, 2017 Soil M17-Au26617 X
29 0990_MW140_0.2_170819
Aug 19, 2017 Soil M17-Au26618 X
30 0990_MW140_0.5_170819
Aug 19, 2017 Soil M17-Au26619 X
31 0990_MW140_1.0_170819
Aug 19, 2017 Soil M17-Au26620 X
32 0990_QCMW169_170819
Aug 19, 2017 Soil M17-Au26621 X
33 0990_QCMW169A_170819
Aug 19, 2017 Soil M17-Au26622 X
34 0990_MW129 Aug 18, 2017 Soil M17-Au26623 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 35
Report Number: 559812-S
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_3.8_170818
35 0990_MW129_1.0_170818
Aug 18, 2017 Soil M17-Au26625 X X X
Test Counts 4 17 4 4 4 8 1 3 8 3 1 18 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 35
Report Number: 559812-S
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 35
Report Number: 559812-S
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 mg/kg < 20 20 Pass
TRH C10-C14 mg/kg < 20 20 Pass
TRH C15-C28 mg/kg < 50 50 Pass
TRH C29-C36 mg/kg < 50 50 Pass
Method Blank
BTEX
Benzene mg/kg < 0.1 0.1 Pass
Toluene mg/kg < 0.1 0.1 Pass
Ethylbenzene mg/kg < 0.1 0.1 Pass
m&p-Xylenes mg/kg < 0.2 0.2 Pass
o-Xylene mg/kg < 0.1 0.1 Pass
Xylenes - Total mg/kg < 0.3 0.3 Pass
Method Blank
Volatile Organics
1.1-Dichloroethane mg/kg < 0.5 0.5 Pass
1.1-Dichloroethene mg/kg < 0.5 0.5 Pass
1.1.1-Trichloroethane mg/kg < 0.5 0.5 Pass
1.1.1.2-Tetrachloroethane mg/kg < 0.5 0.5 Pass
1.1.2-Trichloroethane mg/kg < 0.5 0.5 Pass
1.1.2.2-Tetrachloroethane mg/kg < 0.5 0.5 Pass
1.2-Dibromoethane mg/kg < 0.5 0.5 Pass
1.2-Dichlorobenzene mg/kg < 0.5 0.5 Pass
1.2-Dichloroethane mg/kg < 0.5 0.5 Pass
1.2-Dichloropropane mg/kg < 0.5 0.5 Pass
1.2.3-Trichloropropane mg/kg < 0.5 0.5 Pass
1.2.4-Trimethylbenzene mg/kg < 0.5 0.5 Pass
1.3-Dichlorobenzene mg/kg < 0.5 0.5 Pass
1.3-Dichloropropane mg/kg < 0.5 0.5 Pass
1.3.5-Trimethylbenzene mg/kg < 0.5 0.5 Pass
1.4-Dichlorobenzene mg/kg < 0.5 0.5 Pass
2-Butanone (MEK) mg/kg < 0.5 0.5 Pass
2-Propanone (Acetone) mg/kg < 0.5 0.5 Pass
4-Chlorotoluene mg/kg < 0.5 0.5 Pass
4-Methyl-2-pentanone (MIBK) mg/kg < 0.5 0.5 Pass
Allyl chloride mg/kg < 0.5 0.5 Pass
Bromobenzene mg/kg < 0.5 0.5 Pass
Bromochloromethane mg/kg < 0.5 0.5 Pass
Bromodichloromethane mg/kg < 0.5 0.5 Pass
Bromoform mg/kg < 0.5 0.5 Pass
Bromomethane mg/kg < 0.5 0.5 Pass
Carbon disulfide mg/kg < 0.5 0.5 Pass
Carbon Tetrachloride mg/kg < 0.5 0.5 Pass
Chlorobenzene mg/kg < 0.5 0.5 Pass
Chloroethane mg/kg < 0.5 0.5 Pass
Chloroform mg/kg < 0.5 0.5 Pass
Chloromethane mg/kg < 0.5 0.5 Pass
cis-1.2-Dichloroethene mg/kg < 0.5 0.5 Pass
cis-1.3-Dichloropropene mg/kg < 0.5 0.5 Pass
Dibromochloromethane mg/kg < 0.5 0.5 Pass
Dibromomethane mg/kg < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 35
Report Number: 559812-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Dichlorodifluoromethane mg/kg < 0.5 0.5 Pass
Iodomethane mg/kg < 0.5 0.5 Pass
Isopropyl benzene (Cumene) mg/kg < 0.5 0.5 Pass
Methylene Chloride mg/kg < 0.5 0.5 Pass
Styrene mg/kg < 0.5 0.5 Pass
Tetrachloroethene mg/kg < 0.5 0.5 Pass
trans-1.2-Dichloroethene mg/kg < 0.5 0.5 Pass
trans-1.3-Dichloropropene mg/kg < 0.5 0.5 Pass
Trichloroethene mg/kg < 0.5 0.5 Pass
Trichlorofluoromethane mg/kg < 0.5 0.5 Pass
Vinyl chloride mg/kg < 0.5 0.5 Pass
Method Blank
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
Naphthalene mg/kg < 0.5 0.5 Pass
TRH C6-C10 mg/kg < 20 20 Pass
TRH >C10-C16 mg/kg < 50 50 Pass
TRH >C16-C34 mg/kg < 100 100 Pass
TRH >C34-C40 mg/kg < 100 100 Pass
Method Blank
Semivolatile Organics
2-Methyl-4.6-dinitrophenol mg/kg < 5 5 Pass
1-Naphthylamine mg/kg < 0.5 0.5 Pass
1.2-Dichlorobenzene mg/kg < 0.5 0.5 Pass
1.2.3-Trichlorobenzene mg/kg < 0.5 0.5 Pass
1.2.3.4-Tetrachlorobenzene mg/kg < 0.5 0.5 Pass
1.2.3.5-Tetrachlorobenzene mg/kg < 0.5 0.5 Pass
1.2.4-Trichlorobenzene mg/kg < 0.5 0.5 Pass
1.2.4.5-Tetrachlorobenzene mg/kg < 0.5 0.5 Pass
1.3-Dichlorobenzene mg/kg < 0.5 0.5 Pass
1.3.5-Trichlorobenzene mg/kg < 0.5 0.5 Pass
1.4-Dichlorobenzene mg/kg < 0.5 0.5 Pass
2-Chloronaphthalene mg/kg < 0.5 0.5 Pass
2-Chlorophenol mg/kg < 0.5 0.5 Pass
2-Methylnaphthalene mg/kg < 0.5 0.5 Pass
2-Methylphenol (o-Cresol) mg/kg < 0.2 0.2 Pass
2-Naphthylamine mg/kg < 0.5 0.5 Pass
2-Nitroaniline mg/kg < 0.5 0.5 Pass
2-Nitrophenol mg/kg < 1 1.0 Pass
2-Picoline mg/kg < 0.5 0.5 Pass
2.3.4.6-Tetrachlorophenol mg/kg < 0.5 0.5 Pass
2.4-Dichlorophenol mg/kg < 0.5 0.5 Pass
2.4-Dimethylphenol mg/kg < 0.5 0.5 Pass
2.4-Dinitrophenol mg/kg < 5 5 Pass
2.4.5-Trichlorophenol mg/kg < 1 1.0 Pass
2.4.6-Trichlorophenol mg/kg < 1 1.0 Pass
2.6-Dichlorophenol mg/kg < 0.5 0.5 Pass
2.6-Dinitrotoluene mg/kg < 0.5 0.5 Pass
3&4-Methylphenol (m&p-Cresol) mg/kg < 0.4 0.4 Pass
3-Methylcholanthrene mg/kg < 0.5 0.5 Pass
3.3'-Dichlorobenzidine mg/kg < 0.5 0.5 Pass
4-Aminobiphenyl mg/kg < 0.5 0.5 Pass
4-Bromophenyl phenyl ether mg/kg < 0.5 0.5 Pass
4-Chloro-3-methylphenol mg/kg < 1 1.0 Pass
4-Chlorophenyl phenyl ether mg/kg < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 35
Report Number: 559812-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
4-Nitrophenol mg/kg < 5 5 Pass
4.4'-DDD mg/kg < 0.5 0.5 Pass
4.4'-DDE mg/kg < 0.5 0.5 Pass
4.4'-DDT mg/kg < 0.5 0.5 Pass
7.12-Dimethylbenz(a)anthracene mg/kg < 0.5 0.5 Pass
a-BHC mg/kg < 0.5 0.5 Pass
Acenaphthene mg/kg < 0.5 0.5 Pass
Acenaphthylene mg/kg < 0.5 0.5 Pass
Acetophenone mg/kg < 0.5 0.5 Pass
Aldrin mg/kg < 0.5 0.5 Pass
Aniline mg/kg < 0.5 0.5 Pass
Anthracene mg/kg < 0.5 0.5 Pass
b-BHC mg/kg < 0.5 0.5 Pass
Benz(a)anthracene mg/kg < 0.5 0.5 Pass
Benzo(a)pyrene mg/kg < 0.5 0.5 Pass
Benzo(b&j)fluoranthene mg/kg < 0.5 0.5 Pass
Benzo(g.h.i)perylene mg/kg < 0.5 0.5 Pass
Benzo(k)fluoranthene mg/kg < 0.5 0.5 Pass
Benzyl chloride mg/kg < 0.5 0.5 Pass
Bis(2-chloroethoxy)methane mg/kg < 0.5 0.5 Pass
Bis(2-chloroisopropyl)ether mg/kg < 0.5 0.5 Pass
Bis(2-ethylhexyl)phthalate mg/kg < 0.5 0.5 Pass
Butyl benzyl phthalate mg/kg < 0.5 0.5 Pass
Chrysene mg/kg < 0.5 0.5 Pass
d-BHC mg/kg < 0.5 0.5 Pass
Di-n-butyl phthalate mg/kg < 0.5 0.5 Pass
Di-n-octyl phthalate mg/kg < 0.5 0.5 Pass
Dibenz(a.h)anthracene mg/kg < 0.5 0.5 Pass
Dibenz(a.j)acridine mg/kg < 0.5 0.5 Pass
Dibenzofuran mg/kg < 0.5 0.5 Pass
Dieldrin mg/kg < 0.5 0.5 Pass
Diethyl phthalate mg/kg < 0.5 0.5 Pass
Dimethyl phthalate mg/kg < 0.5 0.5 Pass
Dimethylaminoazobenzene mg/kg < 0.5 0.5 Pass
Diphenylamine mg/kg < 0.5 0.5 Pass
Endosulfan I mg/kg < 0.5 0.5 Pass
Endosulfan II mg/kg < 0.5 0.5 Pass
Endosulfan sulphate mg/kg < 0.5 0.5 Pass
Endrin mg/kg < 0.5 0.5 Pass
Endrin aldehyde mg/kg < 0.5 0.5 Pass
Endrin ketone mg/kg < 0.5 0.5 Pass
Fluoranthene mg/kg < 0.5 0.5 Pass
Fluorene mg/kg < 0.5 0.5 Pass
g-BHC (Lindane) mg/kg < 0.5 0.5 Pass
Heptachlor mg/kg < 0.5 0.5 Pass
Heptachlor epoxide mg/kg < 0.5 0.5 Pass
Hexachlorobenzene mg/kg < 0.5 0.5 Pass
Hexachlorobutadiene mg/kg < 0.5 0.5 Pass
Hexachlorocyclopentadiene mg/kg < 0.5 0.5 Pass
Hexachloroethane mg/kg < 0.5 0.5 Pass
Indeno(1.2.3-cd)pyrene mg/kg < 0.5 0.5 Pass
Methoxychlor mg/kg < 0.5 0.5 Pass
N-Nitrosodibutylamine mg/kg < 0.5 0.5 Pass
N-Nitrosodipropylamine mg/kg < 0.5 0.5 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 23 of 35
Report Number: 559812-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
N-Nitrosopiperidine mg/kg < 0.5 0.5 Pass
Naphthalene mg/kg < 0.5 0.5 Pass
Nitrobenzene mg/kg < 0.5 0.5 Pass
Pentachlorobenzene mg/kg < 0.5 0.5 Pass
Pentachloronitrobenzene mg/kg < 0.5 0.5 Pass
Pentachlorophenol mg/kg < 1 1.0 Pass
Phenanthrene mg/kg < 0.5 0.5 Pass
Phenol mg/kg < 0.5 0.5 Pass
Pronamide mg/kg < 0.5 0.5 Pass
Pyrene mg/kg < 0.5 0.5 Pass
Trifluralin mg/kg < 0.5 0.5 Pass
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/kg < 5 5 Pass
Perfluoropentanoic acid (PFPeA) ug/kg < 5 5 Pass
Perfluorohexanoic acid (PFHxA) ug/kg < 5 5 Pass
Perfluoroheptanoic acid (PFHpA) ug/kg < 5 5 Pass
Perfluorooctanoic acid (PFOA) ug/kg < 5 5 Pass
Perfluorononanoic acid (PFNA) ug/kg < 5 5 Pass
Perfluorodecanoic acid (PFDA) ug/kg < 5 5 Pass
Perfluoroundecanoic acid (PFUnA) ug/kg < 5 5 Pass
Perfluorododecanoic acid (PFDoA) ug/kg < 5 5 Pass
Perfluorotridecanoic acid (PFTrDA) ug/kg < 5 5 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/kg < 5 5 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/kg < 5 5 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/kg < 5 5 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/kg < 5 5 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/kg < 5 5 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/kg < 5 5 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/kg < 10 10 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/kg < 10 10 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/kg < 5 5 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/kg < 5 5 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/kg < 5 5 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/kg < 5 5 Pass
Perfluorooctanesulfonic acid (PFOS) ug/kg < 5 5 Pass
Perfluorodecanesulfonic acid (PFDS) ug/kg < 5 5 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/kg < 10 10 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/kg < 5 5 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/kg < 5 5 Pass
Method Blank
1.4-Dioxane
1.4-Dioxane ug/kg < 10 10 Pass
Method Blank
Heavy Metals
Arsenic mg/kg < 2 2 Pass
Cadmium mg/kg < 0.4 0.4 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 24 of 35
Report Number: 559812-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Chromium mg/kg < 5 5 Pass
Copper mg/kg < 5 5 Pass
Lead mg/kg < 5 5 Pass
Mercury mg/kg < 0.1 0.1 Pass
Nickel mg/kg < 5 5 Pass
Zinc mg/kg < 5 5 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 1999 NEPM Fractions
TRH C6-C9 % 106 70-130 Pass
TRH C10-C14 % 78 70-130 Pass
LCS - % Recovery
BTEX
Benzene % 94 70-130 Pass
Toluene % 86 70-130 Pass
Ethylbenzene % 85 70-130 Pass
m&p-Xylenes % 122 70-130 Pass
Xylenes - Total % 116 70-130 Pass
LCS - % Recovery
Volatile Organics
1.1-Dichloroethene % 74 70-130 Pass
1.1.1-Trichloroethane % 111 70-130 Pass
1.2-Dichlorobenzene % 90 70-130 Pass
1.2-Dichloroethane % 102 70-130 Pass
Trichloroethene % 87 70-130 Pass
LCS - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions
Naphthalene % 70 70-130 Pass
TRH C6-C10 % 101 70-130 Pass
TRH >C10-C16 % 79 70-130 Pass
LCS - % Recovery
Semivolatile Organics
1.2.4-Trichlorobenzene % 109 70-130 Pass
1.4-Dichlorobenzene % 102 70-130 Pass
2-Chlorophenol % 108 30-130 Pass
2.4-Dinitrotoluene % 86 70-130 Pass
4-Chloro-3-methylphenol % 105 30-130 Pass
Acenaphthene % 97 70-130 Pass
N-Nitrosodipropylamine % 80 70-130 Pass
Phenol % 107 30-130 Pass
Pyrene % 105 70-130 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 117 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 134 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 120 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 116 50-150 Pass
Perfluorooctanoic acid (PFOA) % 118 50-150 Pass
Perfluorononanoic acid (PFNA) % 119 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 120 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 123 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 102 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 114 50-150 Pass
LCS - % Recovery
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 25 of 35
Report Number: 559812-S
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 121 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 121 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 133 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 118 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 110 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 130 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 124 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 118 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 111 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 116 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 120 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 121 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 109 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 120 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 123 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 123 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 123 50-150 Pass
LCS - % Recovery
1.4-Dioxane
1.4-Dioxane % 123 70-130 Pass
LCS - % Recovery
Heavy Metals
Arsenic % 95 70-130 Pass
Cadmium % 96 70-130 Pass
Chromium % 110 70-130 Pass
Copper % 112 70-130 Pass
Lead % 100 70-130 Pass
Mercury % 107 70-130 Pass
Nickel % 109 70-130 Pass
Zinc % 107 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au27528 NCP % 99 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au27528 NCP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au27528 NCP % 100 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au27528 NCP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au27528 NCP % 97 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au27528 NCP % 99 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au27528 NCP % 101 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au27528 NCP % 96 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au27528 NCP % 102 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au27528 NCP % 83 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au27528 NCP % 92 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 26 of 35
Report Number: 559812-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorooctane sulfonamide(FOSA) M17-Au27528 NCP % 106 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au27528 NCP % 101 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au27528 NCP % 120 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au27528 NCP % 112 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au27528 NCP % 92 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au27528 NCP % 99 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au27528 NCP % 102 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au27528 NCP % 103 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au27528 NCP % 96 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au27528 NCP % 95 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au27528 NCP % 99 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au27528 NCP % 86 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au27528 NCP % 107 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au27528 NCP % 103 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au27528 NCP % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au27528 NCP % 131 50-150 Pass
Spike - % Recovery
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1
TRH C6-C9 M17-Au27521 NCP % 101 70-130 Pass
TRH C10-C14 M17-Au29576 NCP % 86 70-130 Pass
Spike - % Recovery
BTEX Result 1
Benzene M17-Au30136 NCP % 104 70-130 Pass
Toluene M17-Au30136 NCP % 99 70-130 Pass
Ethylbenzene M17-Au30136 NCP % 89 70-130 Pass
m&p-Xylenes M17-Au30136 NCP % 129 70-130 Pass
o-Xylene M17-Au30136 NCP % 107 70-130 Pass
Xylenes - Total M17-Au30136 NCP % 121 70-130 Pass
Spike - % Recovery
Volatile Organics Result 1
1.1-Dichloroethene M17-Au30136 NCP % 98 70-130 Pass
1.2-Dichlorobenzene M17-Au30136 NCP % 109 70-130 Pass
1.2-Dichloroethane M17-Au30136 NCP % 109 70-130 Pass
Trichloroethene M17-Au30136 NCP % 118 70-130 Pass
Spike - % Recovery
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 27 of 35
Report Number: 559812-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Naphthalene M17-Au30136 NCP % 104 70-130 Pass
TRH C6-C10 M17-Au27521 NCP % 97 70-130 Pass
TRH >C10-C16 M17-Au29576 NCP % 83 70-130 Pass
Spike - % Recovery
Semivolatile Organics Result 1
1.2.4-Trichlorobenzene M17-Au25089 NCP % 108 70-130 Pass
1.4-Dichlorobenzene M17-Au25089 NCP % 102 70-130 Pass
2.4-Dinitrophenol M17-Au28241 NCP % 59 30-130 Pass
2.4-Dinitrotoluene M17-Au29145 NCP % 93 70-130 Pass
3&4-Methylphenol (m&p-Cresol) M17-Au25281 NCP % 34 30-130 Pass
4-Nitrophenol M17-Au28241 NCP % 31 30-130 Pass
N-Nitrosodipropylamine M17-Au25089 NCP % 72 70-130 Pass
Spike - % Recovery
Heavy Metals Result 1
Arsenic M17-Au26597 CP % 115 70-130 Pass
Cadmium M17-Au26597 CP % 117 70-130 Pass
Chromium M17-Au26597 CP % 85 70-130 Pass
Copper M17-Au26597 CP % 112 70-130 Pass
Lead M17-Au26597 CP % 107 70-130 Pass
Mercury M17-Au26597 CP % 105 70-130 Pass
Nickel M17-Au26597 CP % 111 70-130 Pass
Zinc M17-Au26597 CP % 114 70-130 Pass
Spike - % Recovery
Semivolatile Organics Result 1
2-Methyl-4.6-dinitrophenol M17-Au26601 CP % 72 30-130 Pass
2-Chlorophenol M17-Au26601 CP % 97 30-130 Pass
2-Methylphenol (o-Cresol) M17-Au26601 CP % 84 30-130 Pass
2-Nitrophenol M17-Au26601 CP % 86 30-130 Pass
2.4-Dichlorophenol M17-Au26601 CP % 89 30-130 Pass
2.4-Dimethylphenol M17-Au26601 CP % 103 30-130 Pass
2.4.5-Trichlorophenol M17-Au26601 CP % 120 30-130 Pass
2.4.6-Trichlorophenol M17-Au26601 CP % 76 30-130 Pass
2.6-Dichlorophenol M17-Au26601 CP % 106 30-130 Pass
4-Chloro-3-methylphenol M17-Au26601 CP % 104 30-130 Pass
Acenaphthene M17-Au26601 CP % 81 70-130 Pass
Acenaphthylene M17-Au26601 CP % 106 70-130 Pass
Anthracene M17-Au26601 CP % 92 70-130 Pass
Benz(a)anthracene M17-Au26601 CP % 84 70-130 Pass
Benzo(a)pyrene M17-Au26601 CP % 93 70-130 Pass
Benzo(b&j)fluoranthene M17-Au26601 CP % 111 70-130 Pass
Benzo(g.h.i)perylene M17-Au26601 CP % 65 70-130 Fail Q08
Benzo(k)fluoranthene M17-Au26601 CP % 86 70-130 Pass
Chrysene M17-Au26601 CP % 75 70-130 Pass
Dibenz(a.h)anthracene M17-Au26601 CP % 72 70-130 Pass
Fluoranthene M17-Au26601 CP % 98 70-130 Pass
Fluorene M17-Au26601 CP % 80 70-130 Pass
Indeno(1.2.3-cd)pyrene M17-Au26601 CP % 81 70-130 Pass
Naphthalene M17-Au26601 CP % 88 70-130 Pass
Pentachlorophenol M17-Au26601 CP % 33 30-130 Pass
Phenanthrene M17-Au26601 CP % 91 70-130 Pass
Phenol M17-Au26601 CP % 93 30-130 Pass
Pyrene M17-Au26601 CP % 96 70-130 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 28 of 35
Report Number: 559812-S
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorooctanesulfonic acid(PFOS) M17-Au25769 NCP % 99 50-150 Pass
Spike - % Recovery
1.4-Dioxane Result 1
1.4-Dioxane M17-Au26601 CP % 121 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
% Moisture M17-Au26726 NCP % 27 27 1.0 30% Pass
Duplicate
Total Recoverable Hydrocarbons - 1999 NEPM Fractions Result 1 Result 2 RPD
TRH C6-C9 M17-Au25140 NCP mg/kg < 20 < 20 <1 30% Pass
TRH C10-C14 M17-Au24954 NCP mg/kg < 20 < 20 <1 30% Pass
TRH C15-C28 M17-Au24954 NCP mg/kg < 50 < 50 <1 30% Pass
TRH C29-C36 M17-Au24954 NCP mg/kg < 50 < 50 <1 30% Pass
Duplicate
BTEX Result 1 Result 2 RPD
Benzene M17-Au25140 NCP mg/kg < 0.1 < 0.1 <1 30% Pass
Toluene M17-Au25140 NCP mg/kg < 0.1 < 0.1 <1 30% Pass
Ethylbenzene M17-Au25140 NCP mg/kg < 0.1 < 0.1 <1 30% Pass
m&p-Xylenes M17-Au25140 NCP mg/kg < 0.2 < 0.2 <1 30% Pass
o-Xylene M17-Au25140 NCP mg/kg < 0.1 < 0.1 <1 30% Pass
Xylenes - Total M17-Au25140 NCP mg/kg < 0.3 < 0.3 <1 30% Pass
Duplicate
Volatile Organics Result 1 Result 2 RPD
1.1-Dichloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.1-Dichloroethene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.1.1-Trichloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.1.1.2-Tetrachloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.1.2-Trichloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.1.2.2-Tetrachloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2-Dibromoethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2-Dichlorobenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2-Dichloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2-Dichloropropane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.3-Trichloropropane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.4-Trimethylbenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.3-Dichlorobenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.3-Dichloropropane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.3.5-Trimethylbenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.4-Dichlorobenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Butanone (MEK) M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Propanone (Acetone) M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4-Chlorotoluene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4-Methyl-2-pentanone (MIBK) M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Allyl chloride M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bromobenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bromochloromethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bromodichloromethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bromoform M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bromomethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Carbon disulfide M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Carbon Tetrachloride M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Chlorobenzene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 29 of 35
Report Number: 559812-S
Duplicate
Volatile Organics Result 1 Result 2 RPD
Chloroethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Chloroform M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Chloromethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
cis-1.2-Dichloroethene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
cis-1.3-Dichloropropene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dibromochloromethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dibromomethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dichlorodifluoromethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Iodomethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Isopropyl benzene (Cumene) M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Methylene Chloride M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Styrene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Tetrachloroethene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
trans-1.2-Dichloroethene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
trans-1.3-Dichloropropene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Trichloroethene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Trichlorofluoromethane M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Vinyl chloride M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Total Recoverable Hydrocarbons - 2013 NEPM Fractions Result 1 Result 2 RPD
Naphthalene M17-Au25140 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
TRH C6-C10 M17-Au25140 NCP mg/kg < 20 < 20 <1 30% Pass
TRH >C10-C16 M17-Au24954 NCP mg/kg < 50 < 50 <1 30% Pass
TRH >C16-C34 M17-Au24954 NCP mg/kg < 100 < 100 <1 30% Pass
TRH >C34-C40 M17-Au24954 NCP mg/kg < 100 < 100 <1 30% Pass
Duplicate
Semivolatile Organics Result 1 Result 2 RPD
2-Methyl-4.6-dinitrophenol M17-Au25088 NCP mg/kg < 5 < 5 <1 30% Pass
1-Chloronaphthalene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1-Naphthylamine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2-Dichlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.3-Trichlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.3.4-Tetrachlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.3.5-Tetrachlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.4-Trichlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.2.4.5-Tetrachlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.3-Dichlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.3.5-Trichlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
1.4-Dichlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Chloronaphthalene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Chlorophenol M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Methylnaphthalene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Methylphenol (o-Cresol) M17-Au25088 NCP mg/kg < 0.2 < 0.2 <1 30% Pass
2-Naphthylamine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Nitroaniline M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2-Nitrophenol M17-Au25088 NCP mg/kg < 1 < 1 <1 30% Pass
2-Picoline M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2.3.4.6-Tetrachlorophenol M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2.4-Dichlorophenol M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2.4-Dimethylphenol M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2.4-Dinitrophenol M17-Au25088 NCP mg/kg < 5 < 5 <1 30% Pass
2.4-Dinitrotoluene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2.4.5-Trichlorophenol M17-Au25088 NCP mg/kg < 1 < 1 <1 30% Pass
2.4.6-Trichlorophenol M17-Au25088 NCP mg/kg < 1 < 1 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 30 of 35
Report Number: 559812-S
Duplicate
Semivolatile Organics Result 1 Result 2 RPD
2.6-Dichlorophenol M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
2.6-Dinitrotoluene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
3&4-Methylphenol (m&p-Cresol) M17-Au25088 NCP mg/kg < 0.4 < 0.4 <1 30% Pass
3-Methylcholanthrene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
3.3'-Dichlorobenzidine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4-Aminobiphenyl M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4-Bromophenyl phenyl ether M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4-Chloro-3-methylphenol M17-Au25088 NCP mg/kg < 1 < 1 <1 30% Pass
4-Chlorophenyl phenyl ether M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4-Nitrophenol M17-Au25088 NCP mg/kg < 5 < 5 <1 30% Pass
4.4'-DDD M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4.4'-DDE M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
4.4'-DDT M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
7.12-Dimethylbenz(a)anthracene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
a-BHC M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Acenaphthene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Acenaphthylene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Acetophenone M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Aldrin M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Aniline M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Anthracene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
b-BHC M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benz(a)anthracene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(a)pyrene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(b&j)fluoranthene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(g.h.i)perylene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzo(k)fluoranthene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Benzyl chloride M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bis(2-chloroethoxy)methane M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bis(2-chloroisopropyl)ether M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Bis(2-ethylhexyl)phthalate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Butyl benzyl phthalate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Chrysene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
d-BHC M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Di-n-butyl phthalate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Di-n-octyl phthalate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dibenz(a.h)anthracene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dibenz(a.j)acridine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dibenzofuran M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dieldrin M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Diethyl phthalate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dimethyl phthalate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Dimethylaminoazobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Diphenylamine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Endosulfan I M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Endosulfan II M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Endosulfan sulphate M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Endrin M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Endrin aldehyde M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Endrin ketone M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Fluoranthene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Fluorene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
g-BHC (Lindane) M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Heptachlor M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 31 of 35
Report Number: 559812-S
Duplicate
Semivolatile Organics Result 1 Result 2 RPD
Heptachlor epoxide M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Hexachlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Hexachlorobutadiene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Hexachlorocyclopentadiene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Hexachloroethane M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Indeno(1.2.3-cd)pyrene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Methoxychlor M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
N-Nitrosodibutylamine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
N-Nitrosodipropylamine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
N-Nitrosopiperidine M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Naphthalene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Nitrobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Pentachlorobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Pentachloronitrobenzene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Pentachlorophenol M17-Au25088 NCP mg/kg < 1 < 1 <1 30% Pass
Phenanthrene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Phenol M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Pronamide M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Pyrene M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Trifluralin M17-Au25088 NCP mg/kg < 0.5 < 0.5 <1 30% Pass
Duplicate
Heavy Metals Result 1 Result 2 RPD
Arsenic M17-Au26597 CP mg/kg 15 14 11 30% Pass
Cadmium M17-Au26597 CP mg/kg < 0.4 < 0.4 <1 30% Pass
Chromium M17-Au26597 CP mg/kg 140 120 13 30% Pass
Copper M17-Au26597 CP mg/kg 8.2 7.2 13 30% Pass
Lead M17-Au26597 CP mg/kg 20 18 12 30% Pass
Mercury M17-Au26597 CP mg/kg < 0.1 < 0.1 <1 30% Pass
Nickel M17-Au26597 CP mg/kg < 5 < 5 <1 30% Pass
Zinc M17-Au26597 CP mg/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26603 CP ug/kg 20 21 4.0 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26603 CP ug/kg 6.4 6.6 3.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 32 of 35
Report Number: 559812-S
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26603 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26603 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26603 CP ug/kg 21 24 11 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26603 CP ug/kg 17 17 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26603 CP ug/kg 160 160 5.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26603 CP ug/kg 23 23 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26603 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26603 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
1.4-Dioxane Result 1 Result 2 RPD
1.4-Dioxane M17-Au26603 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 33 of 35
Report Number: 559812-S
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26604 CP ug/kg < 10 < 10 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26604 CP ug/kg < 10 < 10 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26604 CP ug/kg 53 50 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26604 CP ug/kg < 10 < 10 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26604 CP ug/kg < 5 < 5 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 34 of 35
Report Number: 559812-S
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N01F2 is determined by arithmetically subtracting the "naphthalene" value from the ">C10-C16" value. The naphthalene value used in this calculation is obtained from volatiles(Purge & Trap analysis).
N02
Where we have reported both volatile (P&T GCMS) and semivolatile (GCMS) naphthalene data, results may not be identical. Provided correct sample handling protocols havebeen followed, any observed differences in results are likely to be due to procedural differences within each methodology. Results determined by both techniques have passedall QAQC acceptance criteria, and are entirely technically valid.
N04F1 is determined by arithmetically subtracting the "Total BTEX" value from the "C6-C10" value. The "Total BTEX" value is obtained by summing the concentrations of BTEXanalytes. The "C6-C10" value is obtained by quantitating against a standard of mixed aromatic/aliphatic analytes.
N07Please note:- These two PAH isomers closely co-elute using the most contemporary analytical methods and both the reported concentration (and the TEQ) apply specifically tothe total of the two co-eluting PAHs
N09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Alex Petridis Senior Analyst-Organic (VIC)
Harry Bacalis Senior Analyst-Volatile (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Joseph Edouard Senior Analyst-Organic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 35 of 35
Report Number: 559812-S
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559812-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB027_170817
0990_PB028_1_170817
0990_PB028_2_170817
0990_QCMW167_170817
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26590 M17-Au26591 M17-Au26592 M17-Au26593
Date Sampled Aug 17, 2017 Aug 17, 2017 Aug 17, 2017 Aug 17, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03 < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.08 < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.03 < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 104 106 107 86
13C5-PFPeA (surr.) 1 % 78 84 83 66
13C5-PFHxA (surr.) 1 % 107 118 118 84
13C4-PFHpA (surr.) 1 % 116 126 123 82
13C8-PFOA (surr.) 1 % 112 123 124 87
13C5-PFNA (surr.) 1 % 101 103 97 82
13C6-PFDA (surr.) 1 % 59 70 68 65
13C2-PFUnDA (surr.) 1 % 69 70 73 63
13C2-PFDoDA (surr.) 1 % 64 66 69 56
13C2-PFTeDA (surr.) 1 % 66 68 74 48
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 35 46 62 36
D3-N-MeFOSA (surr.) 1 % INT 10 12 INT
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 22
Report Number: 559812-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB027_170817
0990_PB028_1_170817
0990_PB028_2_170817
0990_QCMW167_170817
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26590 M17-Au26591 M17-Au26592 M17-Au26593
Date Sampled Aug 17, 2017 Aug 17, 2017 Aug 17, 2017 Aug 17, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT INT 11 INT
D7-N-MeFOSE (surr.) 1 % INT 17 19 13
D9-N-EtFOSE (surr.) 1 % INT 17 19 13
D5-N-EtFOSAA (surr.) 1 % 13 10 10 20
D3-N-MeFOSAA (surr.) 1 % 16 13 13 25
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.08 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.07 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.63 < 0.01 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.08 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.81 < 0.01 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 97 102 103 104
18O2-PFHxS (surr.) 1 % 89 117 120 121
13C8-PFOS (surr.) 1 % 78 100 100 114
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 121 124 122 132
13C2-6:2 FTS (surr.) 1 % 115 124 113 126
13C2-8:2 FTS (surr.) 1 % 41 48 48 58
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.44 < 0.01 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.84 < 0.01 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.47 < 0.01 < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.68 < 0.05 < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L 1.83 < 0.1 < 0.1 < 0.1
Chloride 1 mg/L 11 13 15 -
Sulphate (as SO4) 5 mg/L < 5 < 5 < 5 -
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 480 570 500 -
Alkali Metals
Calcium 0.5 mg/L 38 34 41 -
Magnesium 0.5 mg/L 32 44 47 -
Potassium 0.5 mg/L 7.2 2.0 1.8 -
Sodium 0.5 mg/L 56 46 36 -
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 22
Report Number: 559812-W
Client Sample ID 0990_QCMW183_170817
0990_PB29_170818
0990_QCMW185_170818
0990_QCMW168_170818
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26594 M17-Au26595 M17-Au26598 M17-Au26600
Date Sampled Aug 17, 2017 Aug 18, 2017 Aug 18, 2017 Aug 18, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 108 92 40 54
13C5-PFPeA (surr.) 1 % 85 77 30 40
13C5-PFHxA (surr.) 1 % 115 106 38 50
13C4-PFHpA (surr.) 1 % 117 118 44 50
13C8-PFOA (surr.) 1 % 115 118 60 55
13C5-PFNA (surr.) 1 % 103 108 61 53
13C6-PFDA (surr.) 1 % 77 74 57 42
13C2-PFUnDA (surr.) 1 % 76 69 66 48
13C2-PFDoDA (surr.) 1 % 63 66 64 49
13C2-PFTeDA (surr.) 1 % 52 66 62 42
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 31 65 17 20
D3-N-MeFOSA (surr.) 1 % INT 15 INT INT
D5-N-EtFOSA (surr.) 1 % INT 13 INT INT
D7-N-MeFOSE (surr.) 1 % 12 24 INT INT
D9-N-EtFOSE (surr.) 1 % 12 23 INT INT
D5-N-EtFOSAA (surr.) 1 % 22 11 13 11
D3-N-MeFOSAA (surr.) 1 % 31 13 18 13
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 102 104 100 99
18O2-PFHxS (surr.) 1 % 120 122 118 114
13C8-PFOS (surr.) 1 % 122 112 123 105
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 22
Report Number: 559812-W
Client Sample ID 0990_QCMW183_170817
0990_PB29_170818
0990_QCMW185_170818
0990_QCMW168_170818
Sample Matrix Water Water Water Water
Eurofins | mgt Sample No. M17-Au26594 M17-Au26595 M17-Au26598 M17-Au26600
Date Sampled Aug 17, 2017 Aug 18, 2017 Aug 18, 2017 Aug 18, 2017
Test/Reference LOR Unit
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 126 114 128 115
13C2-6:2 FTS (surr.) 1 % 121 112 132 111
13C2-8:2 FTS (surr.) 1 % 63 51 72 59
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01 < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05 < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1 < 0.1 < 0.1
Chloride 1 mg/L - 13 - -
Sulphate (as SO4) 5 mg/L - < 5 - -
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L - 390 - -
Alkali Metals
Calcium 0.5 mg/L - 90 - -
Magnesium 0.5 mg/L - 37 - -
Potassium 0.5 mg/L - 2.8 - -
Sodium 0.5 mg/L - 7.5 - -
Client Sample ID 0990_QCMW176_170819
0990_QCMW190_170819
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au26602 M17-Au26606
Date Sampled Aug 19, 2017 Aug 19, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 54 71
13C5-PFPeA (surr.) 1 % 42 60
13C5-PFHxA (surr.) 1 % 51 80
13C4-PFHpA (surr.) 1 % 51 82
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 22
Report Number: 559812-W
Client Sample ID 0990_QCMW176_170819
0990_QCMW190_170819
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au26602 M17-Au26606
Date Sampled Aug 19, 2017 Aug 19, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
13C8-PFOA (surr.) 1 % 53 84
13C5-PFNA (surr.) 1 % 54 76
13C6-PFDA (surr.) 1 % 47 60
13C2-PFUnDA (surr.) 1 % 55 65
13C2-PFDoDA (surr.) 1 % 55 56
13C2-PFTeDA (surr.) 1 % 52 45
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 24 54
D3-N-MeFOSA (surr.) 1 % INT 11
D5-N-EtFOSA (surr.) 1 % INT 10
D7-N-MeFOSE (surr.) 1 % INT 20
D9-N-EtFOSE (surr.) 1 % INT 19
D5-N-EtFOSAA (surr.) 1 % 14 17
D3-N-MeFOSAA (surr.) 1 % 15 22
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 100 101
18O2-PFHxS (surr.) 1 % 117 117
13C8-PFOS (surr.) 1 % 107 121
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 112 110
13C2-6:2 FTS (surr.) 1 % 111 112
13C2-8:2 FTS (surr.) 1 % 57 64
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 22
Report Number: 559812-W
Client Sample ID 0990_QCMW176_170819
0990_QCMW190_170819
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au26602 M17-Au26606
Date Sampled Aug 19, 2017 Aug 19, 2017
Test/Reference LOR Unit
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 22
Report Number: 559812-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 22
Report Number: 559812-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB027_170817
Aug 17, 2017 Water M17-Au26590 X X X X X
2 0990_PB028_1_170817
Aug 17, 2017 Water M17-Au26591 X X X X X
3 0990_PB028_2_170817
Aug 17, 2017 Water M17-Au26592 X X X X X
4 0990_QCMW167_170817
Aug 17, 2017 Water M17-Au26593 X
5 0990_QCMW183_170817
Aug 17, 2017 Water M17-Au26594 X
6 0990_PB29_1 Aug 18, 2017 Water M17-Au26595 X X X X X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 22
Report Number: 559812-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
70818
7 0990_MW129_0.1_170818
Aug 18, 2017 Soil M17-Au26596 X X X
8 0990_MW129_0.5_170818
Aug 18, 2017 Soil M17-Au26597 X X X X X X X X
9 0990_QCMW185_170818
Aug 18, 2017 Water M17-Au26598 X
10 0990_QCMW184_170818
Aug 18, 2017 Soil M17-Au26599 X X X
11 0990_QCMW168_170818
Aug 18, 2017 Water M17-Au26600 X
12 0990_QCMW175_170819
Aug 19, 2017 Soil M17-Au26601 X X X X X X
13 0990_QCMW1 Aug 19, 2017 Water M17-Au26602 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 22
Report Number: 559812-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
76_170819
14 0990_MW128_0.0_170819
Aug 19, 2017 Soil M17-Au26603 X X X X X X
15 0990_MW128_0.5_170819
Aug 19, 2017 Soil M17-Au26604 X X X
16 0990_MW128_1.0_170819
Aug 19, 2017 Soil M17-Au26605 X X X
17 0990_QCMW190_170819
Aug 19, 2017 Water M17-Au26606 X
18 0990_MW126_11.2_170817
Aug 17, 2017 Soil M17-Au26607 X
19 0990_MW139_0.0_170817
Aug 17, 2017 Soil M17-Au26608 X
20 0990_MW139 Aug 17, 2017 Soil M17-Au26609 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 22
Report Number: 559812-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_0.2_170817
21 0990_MW139_0.5_170817
Aug 17, 2017 Soil M17-Au26610 X
22 0990_MW139_1.0_170817
Aug 17, 2017 Soil M17-Au26611 X
23 0990_QCMW174_170818
Aug 18, 2017 Water M17-Au26612 X
24 0990_MW129_0.7_170818
Aug 18, 2017 Soil M17-Au26613 X
25 0990_QCMW184A_170818
Aug 18, 2017 Soil M17-Au26614 X
26 0990_MW139_10.0_170818
Aug 18, 2017 Soil M17-Au26615 X
27 0990_MW128 Aug 19, 2017 Soil M17-Au26616 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 22
Report Number: 559812-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_0.2_170819
28 0990_MW140_0.0_170819
Aug 19, 2017 Soil M17-Au26617 X
29 0990_MW140_0.2_170819
Aug 19, 2017 Soil M17-Au26618 X
30 0990_MW140_0.5_170819
Aug 19, 2017 Soil M17-Au26619 X
31 0990_MW140_1.0_170819
Aug 19, 2017 Soil M17-Au26620 X
32 0990_QCMW169_170819
Aug 19, 2017 Soil M17-Au26621 X
33 0990_QCMW169A_170819
Aug 19, 2017 Soil M17-Au26622 X
34 0990_MW129 Aug 18, 2017 Soil M17-Au26623 X
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 22
Report Number: 559812-W
Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 22, 2017 9:52 PMAddress: Level 1, 436 Johnston Street Report #: 559812 Due: Aug 30, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
HO
LD
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Metals M
8
BT
EX
and Naphthalene
Volatile O
rganics
Moisture S
et
Sem
ivolatile Organics
Total R
ecoverable Hydrocarbons
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
1.4-Dioxane
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X X X X X X
Sydney Laboratory - NATA Site # 18217 X X
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
_3.8_170818
35 0990_MW129_1.0_170818
Aug 18, 2017 Soil M17-Au26625 X X X
Test Counts 4 17 4 4 4 8 1 3 8 3 1 18 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 22
Report Number: 559812-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 22
Report Number: 559812-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 22
Report Number: 559812-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Chloride % 122 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 101 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 106 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 115 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27869 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au27410 NCP % 152 70-130 Fail Q08
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 22
Report Number: 559812-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au27410 NCP % 118 70-130 Pass
Sodium M17-Au27410 NCP % 120 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26592 CP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26592 CP % 118 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26592 CP % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26592 CP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26592 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26592 CP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26592 CP % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26592 CP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26592 CP % 103 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26592 CP % 98 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26592 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26592 CP % 103 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26592 CP % 121 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26592 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26592 CP % 108 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26592 CP % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26592 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26592 CP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26592 CP % 100 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26592 CP % 98 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26592 CP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26592 CP % 126 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26592 CP % 105 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26592 CP % 106 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26592 CP % 93 50-150 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 22
Report Number: 559812-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26592 CP % 113 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26598 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26598 CP % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26598 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26598 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26598 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26598 CP % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26598 CP % 107 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26598 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26598 CP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26598 CP % 121 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26598 CP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26598 CP % 109 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26598 CP % 95 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26598 CP % 107 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26598 CP % 110 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26598 CP % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26598 CP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26598 CP % 106 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26598 CP % 93 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26598 CP % 104 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26598 CP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26598 CP % 108 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26598 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26598 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26598 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26598 CP % 122 50-150 Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 18 of 22
Report Number: 559812-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26590 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26590 CP ug/L 0.08 0.09 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26590 CP ug/L 0.02 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26590 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26590 CP ug/L 0.08 0.08 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26590 CP ug/L 0.07 0.07 2.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26590 CP ug/L 0.63 0.64 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26590 CP ug/L 0.08 0.08 4.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26590 CP ug/L 0.81 0.76 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 19 of 22
Report Number: 559812-W
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 14000 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 1800 7.0 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 63 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au27410 NCP mg/L 97 100 7.0 30% Pass
Magnesium M17-Au27410 NCP mg/L 110 120 7.0 30% Pass
Potassium M17-Au27410 NCP mg/L 720 770 6.0 30% Pass
Sodium M17-Au27410 NCP mg/L 360 380 6.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 20 of 22
Report Number: 559812-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 21 of 22
Report Number: 559812-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 01, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 22 of 22
Report Number: 559812-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559812-W-V2
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB027_170817
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26590
Date Sampled Aug 17, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.03
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.08
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.02
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.03
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 104
13C5-PFPeA (surr.) 1 % 78
13C5-PFHxA (surr.) 1 % 107
13C4-PFHpA (surr.) 1 % 116
13C8-PFOA (surr.) 1 % 112
13C5-PFNA (surr.) 1 % 101
13C6-PFDA (surr.) 1 % 59
13C2-PFUnDA (surr.) 1 % 69
13C2-PFDoDA (surr.) 1 % 64
13C2-PFTeDA (surr.) 1 % 66
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 35
D3-N-MeFOSA (surr.) 1 % INT
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 13
Report Number: 559812-W-V2
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB027_170817
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26590
Date Sampled Aug 17, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % INT
D9-N-EtFOSE (surr.) 1 % INT
D5-N-EtFOSAA (surr.) 1 % 13
D3-N-MeFOSAA (surr.) 1 % 16
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.08
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.07
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.63
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.08
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.81
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 97
18O2-PFHxS (surr.) 1 % 89
13C8-PFOS (surr.) 1 % 78
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 121
13C2-6:2 FTS (surr.) 1 % 115
13C2-8:2 FTS (surr.) 1 % 41
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.44
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.84
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.47
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.68
Sum of PFASs (n=28) 0.1 ug/L 1.83
Chloride 1 mg/L 11
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 480
Alkali Metals
Calcium 0.5 mg/L 38
Magnesium 0.5 mg/L 32
Potassium 0.5 mg/L 7.2
Sodium 0.5 mg/L 56
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 13
Report Number: 559812-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 13
Report Number: 559812-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 13
Report Number: 559812-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 13
Report Number: 559812-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Chloride % 122 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 101 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 106 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 115 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 13
Report Number: 559812-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27869 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au27410 NCP % 152 70-130 Fail Q08
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au27410 NCP % 118 70-130 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 13
Report Number: 559812-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Sodium M17-Au27410 NCP % 120 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26592 CP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26592 CP % 118 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26592 CP % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26592 CP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26592 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26592 CP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26592 CP % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26592 CP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26592 CP % 103 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26592 CP % 98 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26592 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26592 CP % 103 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26592 CP % 121 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26592 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26592 CP % 108 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26592 CP % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26592 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26592 CP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26592 CP % 100 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26592 CP % 98 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26592 CP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26592 CP % 126 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26592 CP % 105 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26592 CP % 106 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26592 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26592 CP % 113 50-150 Pass
Spike - % Recovery
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 13
Report Number: 559812-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26598 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26598 CP % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26598 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26598 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26598 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26598 CP % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26598 CP % 107 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26598 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26598 CP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26598 CP % 121 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26598 CP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26598 CP % 109 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26598 CP % 95 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26598 CP % 107 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26598 CP % 110 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26598 CP % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26598 CP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26598 CP % 106 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26598 CP % 93 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26598 CP % 104 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26598 CP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26598 CP % 108 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26598 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26598 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26598 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26598 CP % 122 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 13
Report Number: 559812-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26590 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26590 CP ug/L 0.08 0.09 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26590 CP ug/L 0.02 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26590 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26590 CP ug/L 0.08 0.08 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26590 CP ug/L 0.07 0.07 2.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26590 CP ug/L 0.63 0.64 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26590 CP ug/L 0.08 0.08 4.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26590 CP ug/L 0.81 0.76 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 13
Report Number: 559812-W-V2
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 14000 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 1800 7.0 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 63 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au27410 NCP mg/L 97 100 7.0 30% Pass
Magnesium M17-Au27410 NCP mg/L 110 120 7.0 30% Pass
Potassium M17-Au27410 NCP mg/L 720 770 6.0 30% Pass
Sodium M17-Au27410 NCP mg/L 360 380 6.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 13
Report Number: 559812-W-V2
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 13
Report Number: 559812-W-V2
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 13
Report Number: 559812-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559812-W-V3
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB028_1_170817
0990_PB028_2_170817
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au26591 M17-Au26592
Date Sampled Aug 17, 2017 Aug 17, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 106 107
13C5-PFPeA (surr.) 1 % 84 83
13C5-PFHxA (surr.) 1 % 118 118
13C4-PFHpA (surr.) 1 % 126 123
13C8-PFOA (surr.) 1 % 123 124
13C5-PFNA (surr.) 1 % 103 97
13C6-PFDA (surr.) 1 % 70 68
13C2-PFUnDA (surr.) 1 % 70 73
13C2-PFDoDA (surr.) 1 % 66 69
13C2-PFTeDA (surr.) 1 % 68 74
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 46 62
D3-N-MeFOSA (surr.) 1 % 10 12
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 14
Report Number: 559812-W-V3
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB028_1_170817
0990_PB028_2_170817
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au26591 M17-Au26592
Date Sampled Aug 17, 2017 Aug 17, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT 11
D7-N-MeFOSE (surr.) 1 % 17 19
D9-N-EtFOSE (surr.) 1 % 17 19
D5-N-EtFOSAA (surr.) 1 % 10 10
D3-N-MeFOSAA (surr.) 1 % 13 13
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 102 103
18O2-PFHxS (surr.) 1 % 117 120
13C8-PFOS (surr.) 1 % 100 100
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 124 122
13C2-6:2 FTS (surr.) 1 % 124 113
13C2-8:2 FTS (surr.) 1 % 48 48
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1
Chloride 1 mg/L 13 15
Sulphate (as SO4) 5 mg/L < 5 < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 570 500
Alkali Metals
Calcium 0.5 mg/L 34 41
Magnesium 0.5 mg/L 44 47
Potassium 0.5 mg/L 2.0 1.8
Sodium 0.5 mg/L 46 36
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 14
Report Number: 559812-W-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 14
Report Number: 559812-W-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 14
Report Number: 559812-W-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 14
Report Number: 559812-W-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Chloride % 122 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 101 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 106 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 115 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 14
Report Number: 559812-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27869 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au27410 NCP % 152 70-130 Fail Q08
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au27410 NCP % 118 70-130 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 14
Report Number: 559812-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Sodium M17-Au27410 NCP % 120 70-130 Pass
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27869 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au27410 NCP % 152 70-130 Fail Q08
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au28491 NCP % 116 70-130 Pass
Sodium M17-Au27410 NCP % 120 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26592 CP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26592 CP % 118 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26592 CP % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26592 CP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26592 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26592 CP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26592 CP % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26592 CP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26592 CP % 103 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26592 CP % 98 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26592 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26592 CP % 103 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26592 CP % 121 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26592 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26592 CP % 108 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26592 CP % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26592 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26592 CP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26592 CP % 100 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26592 CP % 98 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26592 CP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26592 CP % 126 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26592 CP % 105 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26592 CP % 106 50-150 Pass
Spike - % Recovery
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 14
Report Number: 559812-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26592 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26592 CP % 113 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26598 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26598 CP % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26598 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26598 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26598 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26598 CP % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26598 CP % 107 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26598 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26598 CP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26598 CP % 121 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26598 CP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26598 CP % 109 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26598 CP % 95 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26598 CP % 107 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26598 CP % 110 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26598 CP % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26598 CP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26598 CP % 106 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26598 CP % 93 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26598 CP % 104 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26598 CP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26598 CP % 108 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 14
Report Number: 559812-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26598 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26598 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26598 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26598 CP % 122 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26590 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26590 CP ug/L 0.08 0.09 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26590 CP ug/L 0.02 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26590 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26590 CP ug/L 0.08 0.08 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26590 CP ug/L 0.07 0.07 2.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26590 CP ug/L 0.63 0.64 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26590 CP ug/L 0.08 0.08 4.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26590 CP ug/L 0.81 0.76 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 14
Report Number: 559812-W-V3
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 14000 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 1800 7.0 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 63 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au27410 NCP mg/L 97 100 7.0 30% Pass
Magnesium M17-Au27410 NCP mg/L 110 120 7.0 30% Pass
Potassium M17-Au27410 NCP mg/L 720 770 6.0 30% Pass
Sodium M17-Au27410 NCP mg/L 360 380 6.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 14
Report Number: 559812-W-V3
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 ** 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 ** 7.0 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 ** 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au27410 NCP mg/L 97 ** 7.0 30% Pass
Magnesium M17-Au27410 NCP mg/L 110 ** 7.0 30% Pass
Potassium M17-Au27865 NCP mg/L 2.9 2.9 <1 30% Pass
Sodium M17-Au27410 NCP mg/L 360 ** 6.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 14
Report Number: 559812-W-V3
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 14
Report Number: 559812-W-V3
Comments
V2- Report split
V3- Report split
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 14
Report Number: 559812-W-V3
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 559812-W-V4
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 22, 2017
Client Sample ID 0990_PB029_170818
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26595
Date Sampled Aug 18, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 92
13C5-PFPeA (surr.) 1 % 77
13C5-PFHxA (surr.) 1 % 106
13C4-PFHpA (surr.) 1 % 118
13C8-PFOA (surr.) 1 % 118
13C5-PFNA (surr.) 1 % 108
13C6-PFDA (surr.) 1 % 74
13C2-PFUnDA (surr.) 1 % 69
13C2-PFDoDA (surr.) 1 % 66
13C2-PFTeDA (surr.) 1 % 66
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 65
D3-N-MeFOSA (surr.) 1 % 15
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 17
Report Number: 559812-W-V4
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB029_170818
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au26595
Date Sampled Aug 18, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 13
D7-N-MeFOSE (surr.) 1 % 24
D9-N-EtFOSE (surr.) 1 % 23
D5-N-EtFOSAA (surr.) 1 % 11
D3-N-MeFOSAA (surr.) 1 % 13
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 104
18O2-PFHxS (surr.) 1 % 122
13C8-PFOS (surr.) 1 % 112
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 114
13C2-6:2 FTS (surr.) 1 % 112
13C2-8:2 FTS (surr.) 1 % 51
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 13
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 390
Alkali Metals
Calcium 0.5 mg/L 90
Magnesium 0.5 mg/L 37
Potassium 0.5 mg/L 2.8
Sodium 0.5 mg/L 7.5
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 17
Report Number: 559812-W-V4
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 30, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 24, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 24, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 24, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 17
Report Number: 559812-W-V4
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 17
Report Number: 559812-W-V4
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 122 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 17
Report Number: 559812-W-V4
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 114 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 111 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 130 50-150 Pass
Perfluorooctanoic acid (PFOA) % 100 50-150 Pass
Perfluorononanoic acid (PFNA) % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) % 115 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 106 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 106 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 125 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 120 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 105 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 125 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 116 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 112 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 102 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 102 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 118 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 110 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 108 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 110 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 107 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 107 50-150 Pass
LCS - % Recovery
Chloride % 122 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 101 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 106 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 115 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 17
Report Number: 559812-W-V4
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27869 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au27410 NCP % 152 70-130 Fail Q08
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au27410 NCP % 118 70-130 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 17
Report Number: 559812-W-V4
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Sodium M17-Au27410 NCP % 120 70-130 Pass
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27869 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au27410 NCP % 152 70-130 Fail Q08
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au28491 NCP % 116 70-130 Pass
Sodium M17-Au27410 NCP % 120 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26592 CP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26592 CP % 118 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26592 CP % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26592 CP % 110 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26592 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26592 CP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26592 CP % 114 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26592 CP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26592 CP % 103 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26592 CP % 98 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26592 CP % 115 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26592 CP % 103 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26592 CP % 121 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26592 CP % 109 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26592 CP % 108 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26592 CP % 115 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26592 CP % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26592 CP % 104 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26592 CP % 100 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26592 CP % 98 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26592 CP % 102 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26592 CP % 126 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26592 CP % 105 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26592 CP % 106 50-150 Pass
Spike - % Recovery
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 17
Report Number: 559812-W-V4
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26592 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26592 CP % 93 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26592 CP % 113 50-150 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au25648 NCP % 114 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au25648 NCP % 143 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au25648 NCP % 97 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au25648 NCP % 120 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au25648 NCP % 111 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au25648 NCP % 142 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au25648 NCP % 117 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au25648 NCP % 108 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au25648 NCP % 133 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au25648 NCP % 136 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au25648 NCP % 137 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au25648 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au25648 NCP % 134 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au25648 NCP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au25648 NCP % 105 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au25648 NCP % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au25648 NCP % 120 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au25648 NCP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au25648 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au25648 NCP % 76 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au25648 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au25648 NCP % 141 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au25648 NCP % 107 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au25648 NCP % 115 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 17
Report Number: 559812-W-V4
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au25648 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au25648 NCP % 91 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au25648 NCP % 134 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au25648 NCP % 117 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au26270 NCP % 113 70-130 Pass
Sulphate (as SO4) M17-Au27503 NCP % 103 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au28491 NCP % 126 70-130 Pass
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au28491 NCP % 116 70-130 Pass
Sodium M17-Au28491 NCP % 108 70-130 Pass
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au26598 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au26598 CP % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au26598 CP % 105 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26598 CP % 99 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au26598 CP % 107 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au26598 CP % 121 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au26598 CP % 107 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26598 CP % 101 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au26598 CP % 111 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26598 CP % 121 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au26598 CP % 101 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26598 CP % 109 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26598 CP % 95 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26598 CP % 107 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26598 CP % 110 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26598 CP % 102 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26598 CP % 101 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au26598 CP % 106 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26598 CP % 93 50-150 Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 17
Report Number: 559812-W-V4
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorohexanesulfonic acid(PFHxS) M17-Au26598 CP % 104 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26598 CP % 109 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26598 CP % 108 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26598 CP % 105 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26598 CP % 102 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26598 CP % 92 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26598 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26598 CP % 122 50-150 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26590 CP ug/L 0.03 0.03 4.0 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26590 CP ug/L 0.08 0.09 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26590 CP ug/L 0.02 0.01 2.0 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26590 CP ug/L 0.03 0.03 6.0 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 17
Report Number: 559812-W-V4
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26590 CP ug/L 0.08 0.08 1.0 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26590 CP ug/L 0.07 0.07 2.0 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26590 CP ug/L 0.63 0.64 2.0 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26590 CP ug/L 0.08 0.08 4.0 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26590 CP ug/L 0.81 0.76 6.0 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26590 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26590 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 14000 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 1800 7.0 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 63 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au27410 NCP mg/L 97 100 7.0 30% Pass
Magnesium M17-Au27410 NCP mg/L 110 120 7.0 30% Pass
Potassium M17-Au27410 NCP mg/L 720 770 6.0 30% Pass
Sodium M17-Au27410 NCP mg/L 360 380 6.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 12 of 17
Report Number: 559812-W-V4
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 ** 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 ** 7.0 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 ** 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au27410 NCP mg/L 97 ** 7.0 30% Pass
Magnesium M17-Au27410 NCP mg/L 110 ** 7.0 30% Pass
Potassium M17-Au27865 NCP mg/L 2.9 2.9 <1 30% Pass
Sodium M17-Au27410 NCP mg/L 360 ** 6.0 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 13 of 17
Report Number: 559812-W-V4
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26594 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26594 CP ug/L < 0.01 < 0.01 <1 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 14 of 17
Report Number: 559812-W-V4
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au26495 NCP ug/L < 0.01 ** 200 30% Fail
Perfluorotetradecanoic acid(PFTeDA) M17-Au26495 NCP ug/L < 0.01 ** 200 30% Fail
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au26495 NCP ug/L < 0.05 ** 200 30% Fail
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au26495 NCP ug/L < 0.05 ** <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au26495 NCP ug/L < 0.05 ** 5.0 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au26495 NCP ug/L < 0.01 ** <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au26832 NCP mg/L 15000 ** 3.2 30% Pass
Sulphate (as SO4) M17-Au27408 NCP mg/L 1900 ** 7.0 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 15 of 17
Report Number: 559812-W-V4
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au26801 NCP mg/L 61 ** 3.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au26007 NCP mg/L 14 14 2.0 30% Pass
Magnesium M17-Au27865 NCP mg/L 3.3 3.4 3.0 30% Pass
Potassium M17-Au27865 NCP mg/L 2.9 ** <1 30% Pass
Sodium M17-Au28491 NCP mg/L 26 22 13 30% Pass
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 16 of 17
Report Number: 559812-W-V4
Comments
V2- Report split
V3- Report split
V4- Report split
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Sep 01, 2017
Date Reported: Sep 05, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 17 of 17
Report Number: 559812-W-V4
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560521-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 11, 2017
Client Sample ID 0990_PB009_1_170808
0990_PB009_2_170808
0990_PB009_3_170808
Sample Matrix Water Water Water
Eurofins | mgt Sample No. M17-Au24017 M17-Au24018 M17-Au24019
Date Sampled Aug 08, 2017 Aug 08, 2017 Aug 08, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 109 107 113
13C5-PFPeA (surr.) 1 % 106 104 110
13C5-PFHxA (surr.) 1 % 123 121 125
13C4-PFHpA (surr.) 1 % 119 119 122
13C8-PFOA (surr.) 1 % 119 122 126
13C5-PFNA (surr.) 1 % 102 105 117
13C6-PFDA (surr.) 1 % 88 91 101
13C2-PFUnDA (surr.) 1 % 79 81 93
13C2-PFDoDA (surr.) 1 % 70 70 78
13C2-PFTeDA (surr.) 1 % 50 50 53
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 78 80 92
D3-N-MeFOSA (surr.) 1 % 47 44 61
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560521-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB009_1_170808
0990_PB009_2_170808
0990_PB009_3_170808
Sample Matrix Water Water Water
Eurofins | mgt Sample No. M17-Au24017 M17-Au24018 M17-Au24019
Date Sampled Aug 08, 2017 Aug 08, 2017 Aug 08, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 38 35 49
D7-N-MeFOSE (surr.) 1 % 58 58 71
D9-N-EtFOSE (surr.) 1 % 55 54 68
D5-N-EtFOSAA (surr.) 1 % 67 84 82
D3-N-MeFOSAA (surr.) 1 % 68 80 77
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.02 < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.04 < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 118 118 122
18O2-PFHxS (surr.) 1 % 114 114 119
13C8-PFOS (surr.) 1 % 79 81 87
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 144 138 146
13C2-6:2 FTS (surr.) 1 % 149 149 159
13C2-8:2 FTS (surr.) 1 % 112 110 122
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.06 < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.04 < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.06 < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.06 < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1 < 0.1
Ammonia (as N) 0.01 mg/L < 0.01 - -
Chloride 1 mg/L 5.3 - -
Nitrate (as N) 0.02 mg/L 0.13 - -
Sulphate (as SO4) 5 mg/L < 5 - -
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 450 - -
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10 - -
Alkali Metals
Calcium 0.5 mg/L 34 - -
Magnesium 0.5 mg/L 31 - -
Potassium 0.5 mg/L 1.9 - -
Sodium 0.5 mg/L 3.7 - -
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560521-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 28, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 28, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 28, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 28, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 28, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 28, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560521-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 11, 2017 10:10 AMAddress: Level 1, 436 Johnston Street Report #: 560521 Due: Sep 4, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB009_1_170808
Aug 08, 2017 Water M17-Au24017 X X
2 0990_PB009_2_170808
Aug 08, 2017 Water M17-Au24018 X
3 0990_PB009_3_170808
Aug 08, 2017 Water M17-Au24019 X
Test Counts 1 3
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560521-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560521-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560521-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 101 50-150 Pass
Perfluorooctanoic acid (PFOA) % 108 50-150 Pass
Perfluorononanoic acid (PFNA) % 106 50-150 Pass
Perfluorodecanoic acid (PFDA) % 104 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 104 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 93 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 100 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 105 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 100 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 103 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 102 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 112 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 97 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 103 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 108 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 126 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 101 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 101 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 110 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 99 70-130 Pass
Chloride % 109 70-130 Pass
Nitrate (as N) % 100 70-130 Pass
Sulphate (as SO4) % 107 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) % 83 70-130 Pass
Carbonate Alkalinity (as CaCO3) % 84 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560521-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au17530 NCP % 100 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au17530 NCP % 102 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au17530 NCP % 101 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au17530 NCP % 103 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au17530 NCP % 103 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au17530 NCP % 103 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au17530 NCP % 101 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au17530 NCP % 100 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au17530 NCP % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au17530 NCP % 100 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au17530 NCP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au17530 NCP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au17530 NCP % 106 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au17530 NCP % 98 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au17530 NCP % 104 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au17530 NCP % 107 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au17530 NCP % 97 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au17530 NCP % 100 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au17530 NCP % 103 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au17530 NCP % 108 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au17530 NCP % 94 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au17530 NCP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au17530 NCP % 103 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au17530 NCP % 95 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au17530 NCP % 97 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au17530 NCP % 98 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au17530 NCP % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au17530 NCP % 124 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560521-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au28838 NCP % 98 70-130 Pass
Chloride M17-Au28087 NCP % 105 70-130 Pass
Nitrate (as N) M17-Au28838 NCP % 97 70-130 Pass
Sulphate (as SO4) M17-Au30502 NCP % 124 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) P17-Au30755 NCP % 78 70-130 Pass
Carbonate Alkalinity (as CaCO3) M17-Au31691 NCP % 87 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au24021 NCP % 138 70-130 Fail Q08
Magnesium M17-Au24021 NCP % 109 70-130 Pass
Potassium M17-Au32308 NCP % 104 70-130 Pass
Sodium M17-Au31197 NCP % 109 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au24020 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Au24021 NCP mg/L 4.5 4.5 <1 30% Pass
Nitrate (as N) M17-Au24020 NCP mg/L 0.20 0.20 2.0 30% Pass
Sulphate (as SO4) S17-Au28753 NCP mg/L 1300 1300 1.4 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au30271 NCP mg/L < 20 < 20 <1 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au30271 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au24021 NCP mg/L 49 56 13 30% Pass
Magnesium M17-Au24021 NCP mg/L 29 34 15 30% Pass
Potassium M17-Au24021 NCP mg/L 1.7 1.5 11 30% Pass
Sodium M17-Au24021 NCP mg/L 3.1 2.9 4.0 30% Pass
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560521-W
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au24019 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au24019 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560521-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560521-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560524-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 11, 2017
Client Sample ID 0990_PB011_170808
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au24021
Date Sampled Aug 08, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 138
13C5-PFPeA (surr.) 1 % 126
13C5-PFHxA (surr.) 1 % 151
13C4-PFHpA (surr.) 1 % 149
13C8-PFOA (surr.) 1 % 152
13C5-PFNA (surr.) 1 % 130
13C6-PFDA (surr.) 1 % 110
13C2-PFUnDA (surr.) 1 % 102
13C2-PFDoDA (surr.) 1 % 92
13C2-PFTeDA (surr.) 1 % 69
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 101
D3-N-MeFOSA (surr.) 1 % 75
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560524-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB011_170808
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au24021
Date Sampled Aug 08, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 60
D7-N-MeFOSE (surr.) 1 % 83
D9-N-EtFOSE (surr.) 1 % 76
D5-N-EtFOSAA (surr.) 1 % 89
D3-N-MeFOSAA (surr.) 1 % 84
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.02
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.04
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 145
18O2-PFHxS (surr.) 1 % 143
13C8-PFOS (surr.) 1 % 100
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 183
13C2-6:2 FTS (surr.) 1 % 188
13C2-8:2 FTS (surr.) 1 % 139
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.06
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.04
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.06
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.06
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Ammonia (as N) 0.01 mg/L < 0.01
Chloride 1 mg/L 4.5
Nitrate (as N) 0.02 mg/L 0.10
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) 20 mg/L 520
Carbonate Alkalinity (as CaCO3) 10 mg/L < 10
Alkali Metals
Calcium 0.5 mg/L 49
Magnesium 0.5 mg/L 29
Potassium 0.5 mg/L 1.7
Sodium 0.5 mg/L 3.1
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560524-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 22, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Eurofins | mgt Suite B11
Ammonia (as N) Melbourne Aug 28, 2017 28 Day
- Method: APHA 4500-NH3 Ammonia Nitrogen by FIA
Chloride Melbourne Aug 28, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Nitrate (as N) Melbourne Aug 28, 2017 7 Day
- Method: APHA 4500-NO3 Nitrate Nitrogen by FIA
Sulphate (as SO4) Melbourne Aug 28, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 28, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 28, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560524-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 11, 2017 10:10 AMAddress: Level 1, 436 Johnston Street Report #: 560524 Due: Sep 4, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Eurofins | m
gt Suite B
11
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB011_170808
Aug 08, 2017 Water M17-Au24021 X X
Test Counts 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560524-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560524-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Ammonia (as N) mg/L < 0.01 0.01 Pass
Chloride mg/L < 1 1 Pass
Nitrate (as N) mg/L < 0.02 0.02 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) mg/L < 20 20 Pass
Carbonate Alkalinity (as CaCO3) mg/L < 10 10 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560524-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) % 107 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 107 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 101 50-150 Pass
Perfluorooctanoic acid (PFOA) % 108 50-150 Pass
Perfluorononanoic acid (PFNA) % 106 50-150 Pass
Perfluorodecanoic acid (PFDA) % 104 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 104 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 115 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 93 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 100 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 105 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 100 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 103 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 102 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 105 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 112 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 97 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 103 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 108 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 126 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 101 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 101 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 106 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 110 50-150 Pass
LCS - % Recovery
Ammonia (as N) % 99 70-130 Pass
Chloride % 109 70-130 Pass
Nitrate (as N) % 100 70-130 Pass
Sulphate (as SO4) % 107 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Bicarbonate Alkalinity (as CaCO3) % 83 70-130 Pass
Carbonate Alkalinity (as CaCO3) % 84 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560524-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au24021 CP % 105 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au24021 CP % 106 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au24021 CP % 103 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au24021 CP % 103 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au24021 CP % 104 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au24021 CP % 106 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au24021 CP % 104 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au24021 CP % 99 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Au24021 CP % 121 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au24021 CP % 95 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au24021 CP % 107 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au24021 CP % 100 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au24021 CP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au24021 CP % 104 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au24021 CP % 104 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au24021 CP % 104 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au24021 CP % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au24021 CP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au24021 CP % 103 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au24021 CP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au24021 CP % 98 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au24021 CP % 106 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au24021 CP % 100 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au24021 CP % 127 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au24021 CP % 106 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au24021 CP % 104 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au24021 CP % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au24021 CP % 110 50-150 Pass
Spike - % Recovery
Result 1
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560524-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Ammonia (as N) M17-Au28838 NCP % 98 70-130 Pass
Chloride M17-Au28087 NCP % 105 70-130 Pass
Nitrate (as N) M17-Au28838 NCP % 97 70-130 Pass
Sulphate (as SO4) M17-Au30502 NCP % 124 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Bicarbonate Alkalinity (as CaCO3) P17-Au30755 NCP % 78 70-130 Pass
Carbonate Alkalinity (as CaCO3) M17-Au31691 NCP % 87 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au24021 CP % 138 70-130 Fail Q08
Magnesium M17-Au24021 CP % 109 70-130 Pass
Potassium M17-Au32308 NCP % 104 70-130 Pass
Sodium M17-Au31197 NCP % 109 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560524-W
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorooctanesulfonic acid(PFOS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au24019 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au24019 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Ammonia (as N) M17-Au24020 NCP mg/L < 0.01 < 0.01 <1 30% Pass
Chloride M17-Au24021 CP mg/L 4.5 4.5 <1 30% Pass
Nitrate (as N) M17-Au24020 NCP mg/L 0.20 0.20 2.0 30% Pass
Sulphate (as SO4) S17-Au28753 NCP mg/L 1300 1300 1.4 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Bicarbonate Alkalinity (as CaCO3) M17-Au30271 NCP mg/L < 20 < 20 <1 30% Pass
Carbonate Alkalinity (as CaCO3) M17-Au30271 NCP mg/L < 10 < 10 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au24021 CP mg/L 49 56 13 30% Pass
Magnesium M17-Au24021 CP mg/L 29 34 15 30% Pass
Potassium M17-Au24021 CP mg/L 1.7 1.5 11 30% Pass
Sodium M17-Au24021 CP mg/L 3.1 2.9 4.0 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560524-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560524-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560575-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB012_170810
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19918
Date Sampled Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 78
13C5-PFPeA (surr.) 1 % 79
13C5-PFHxA (surr.) 1 % 107
13C4-PFHpA (surr.) 1 % 116
13C8-PFOA (surr.) 1 % 118
13C5-PFNA (surr.) 1 % 104
13C6-PFDA (surr.) 1 % 73
13C2-PFUnDA (surr.) 1 % 60
13C2-PFDoDA (surr.) 1 % 56
13C2-PFTeDA (surr.) 1 % 27
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 63
D3-N-MeFOSA (surr.) 1 % 47
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560575-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB012_170810
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19918
Date Sampled Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 31
D7-N-MeFOSE (surr.) 1 % 36
D9-N-EtFOSE (surr.) 1 % 42
D5-N-EtFOSAA (surr.) 1 % 53
D3-N-MeFOSAA (surr.) 1 % 57
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 101
18O2-PFHxS (surr.) 1 % 104
13C8-PFOS (surr.) 1 % 81
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 130
13C2-6:2 FTS (surr.) 1 % 120
13C2-8:2 FTS (surr.) 1 % 73
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 14
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 530
Alkali Metals
Calcium 0.5 mg/L 76
Magnesium 0.5 mg/L 39
Potassium 0.5 mg/L 2.0
Sodium 0.5 mg/L 39
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560575-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 22, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 22, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560575-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 5:46 PMAddress: Level 1, 436 Johnston Street Report #: 560575 Due: Sep 5, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB012_170810
Aug 10, 2017 Water M17-Au19918 X X X X X
Test Counts 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560575-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560575-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 110 50-150 Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560575-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 121 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) % 96 50-150 Pass
Perfluorononanoic acid (PFNA) % 133 50-150 Pass
Perfluorodecanoic acid (PFDA) % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 110 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 134 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 91 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 124 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 129 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 104 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 100 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 139 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 117 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 125 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 88 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 121 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 106 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 104 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 129 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 104 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 105 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 129 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 112 50-150 Pass
LCS - % Recovery
Chloride % 108 70-130 Pass
Sulphate (as SO4) % 111 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 94 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 106 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 115 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Se06868 NCP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Se06868 NCP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Se06868 NCP % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Se06868 NCP % 112 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Se06868 NCP % 97 50-150 Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560575-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) B17-Se06868 NCP % 137 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Se06868 NCP % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Se06868 NCP % 117 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Se06868 NCP % 138 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se06868 NCP % 89 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se06868 NCP % 138 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Se06868 NCP % 114 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se06868 NCP % 103 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se06868 NCP % 96 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se06868 NCP % 92 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se06868 NCP % 128 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se06868 NCP % 116 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se06868 NCP % 120 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Se06868 NCP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se06868 NCP % 121 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se06868 NCP % 100 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se06868 NCP % 93 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se06868 NCP % 128 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se06868 NCP % 123 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se06868 NCP % 120 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se06868 NCP % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se06868 NCP % 127 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se06868 NCP % 128 50-150 Pass
Spike - % Recovery
Result 1
Chloride P17-Au25697 NCP % 122 70-130 Pass
Sulphate (as SO4) M17-Au25405 NCP % 90 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Total Alkalinity (as CaCO3) M17-Au25715 NCP % 122 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560575-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Calcium M17-Au28491 NCP % 126 70-130 Pass
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au28491 NCP % 116 70-130 Pass
Sodium M17-Au28491 NCP % 108 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560575-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au25404 NCP mg/L 5000 5200 4.5 30% Pass
Sulphate (as SO4) M17-Au25404 NCP mg/L 350 350 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au25693 NCP mg/L 220 210 5.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au28491 NCP mg/L 13 13 3.0 30% Pass
Magnesium M17-Au28491 NCP mg/L 1.7 1.7 2.0 30% Pass
Potassium M17-Au28491 NCP mg/L 5.6 5.4 4.0 30% Pass
Sodium M17-Au28491 NCP mg/L 26 22 13 30% Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560575-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560575-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560578-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB013_170810-1
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19919
Date Sampled Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.02
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.08
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L N090.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.03
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 78
13C5-PFPeA (surr.) 1 % 81
13C5-PFHxA (surr.) 1 % 111
13C4-PFHpA (surr.) 1 % 121
13C8-PFOA (surr.) 1 % 128
13C5-PFNA (surr.) 1 % 102
13C6-PFDA (surr.) 1 % 76
13C2-PFUnDA (surr.) 1 % 62
13C2-PFDoDA (surr.) 1 % 60
13C2-PFTeDA (surr.) 1 % 31
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 66
D3-N-MeFOSA (surr.) 1 % 47
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560578-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB013_170810-1
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19919
Date Sampled Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 27
D7-N-MeFOSE (surr.) 1 % 41
D9-N-EtFOSE (surr.) 1 % 44
D5-N-EtFOSAA (surr.) 1 % 55
D3-N-MeFOSAA (surr.) 1 % 63
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L N090.07
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.08
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.60
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.03
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.93
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 109
18O2-PFHxS (surr.) 1 % 103
13C8-PFOS (surr.) 1 % 84
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 117
13C2-6:2 FTS (surr.) 1 % 106
13C2-8:2 FTS (surr.) 1 % 78
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.53
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.96
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.56
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.74
Sum of PFASs (n=28) 0.1 ug/L 1.85
Chloride 1 mg/L 15
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 410
Alkali Metals
Calcium 0.5 mg/L 89
Magnesium 0.5 mg/L 33
Potassium 0.5 mg/L 1.6
Sodium 0.5 mg/L 4.4
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560578-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 31, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560578-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 5:34 PMAddress: Level 1, 436 Johnston Street Report #: 560578 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 2 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
CA
NC
ELLE
D
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB013_170810-1
Aug 10, 2017 Water M17-Au19919 X X X X X
2 0990_PB013_170810-2
Aug 10, 2017 Water M17-Au32911 X
Test Counts 1 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560578-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560578-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 110 50-150 Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560578-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 121 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) % 96 50-150 Pass
Perfluorononanoic acid (PFNA) % 133 50-150 Pass
Perfluorodecanoic acid (PFDA) % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 110 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 134 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 91 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 124 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 129 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 104 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 100 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 139 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 117 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 125 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 88 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 121 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 106 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 104 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 129 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 104 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 105 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 129 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 112 50-150 Pass
LCS - % Recovery
Chloride % 115 70-130 Pass
Sulphate (as SO4) % 107 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 101 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Se06868 NCP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Se06868 NCP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Se06868 NCP % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Se06868 NCP % 112 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Se06868 NCP % 97 50-150 Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560578-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) B17-Se06868 NCP % 137 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Se06868 NCP % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Se06868 NCP % 117 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Se06868 NCP % 138 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se06868 NCP % 89 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se06868 NCP % 138 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Se06868 NCP % 114 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se06868 NCP % 103 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se06868 NCP % 96 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se06868 NCP % 92 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se06868 NCP % 128 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se06868 NCP % 116 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se06868 NCP % 120 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Se06868 NCP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se06868 NCP % 121 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se06868 NCP % 100 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se06868 NCP % 93 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se06868 NCP % 128 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se06868 NCP % 123 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se06868 NCP % 120 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se06868 NCP % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se06868 NCP % 127 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se06868 NCP % 128 50-150 Pass
Spike - % Recovery
Result 1
Chloride B17-Au35297 NCP % 130 70-130 Pass
Sulphate (as SO4) M17-Au19878 NCP % 105 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Total Alkalinity (as CaCO3) M17-Au35727 NCP % 110 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560578-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Calcium B17-Au35173 NCP % 115 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au33386 NCP % 116 70-130 Pass
Sodium B17-Au35173 NCP % 124 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560578-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au19877 NCP mg/L 7.8 7.9 <1 30% Pass
Sulphate (as SO4) M17-Au19877 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) B17-Au35173 NCP mg/L < 20 < 20 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium B17-Au35173 NCP mg/L 120 100 19 30% Pass
Magnesium B17-Au35173 NCP mg/L 100 100 1.0 30% Pass
Potassium B17-Au35173 NCP mg/L 2.3 2.3 2.0 30% Pass
Sodium B17-Au35173 NCP mg/L 260 260 1.0 30% Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560578-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560578-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560580-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB014_170810
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19920
Date Sampled Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 73
13C5-PFPeA (surr.) 1 % 72
13C5-PFHxA (surr.) 1 % 107
13C4-PFHpA (surr.) 1 % 118
13C8-PFOA (surr.) 1 % 123
13C5-PFNA (surr.) 1 % 105
13C6-PFDA (surr.) 1 % 80
13C2-PFUnDA (surr.) 1 % 68
13C2-PFDoDA (surr.) 1 % 66
13C2-PFTeDA (surr.) 1 % 30
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 69
D3-N-MeFOSA (surr.) 1 % 46
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560580-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB014_170810
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19920
Date Sampled Aug 10, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 28
D7-N-MeFOSE (surr.) 1 % 42
D9-N-EtFOSE (surr.) 1 % 44
D5-N-EtFOSAA (surr.) 1 % 54
D3-N-MeFOSAA (surr.) 1 % 62
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L 0.03
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.06
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 103
18O2-PFHxS (surr.) 1 % 105
13C8-PFOS (surr.) 1 % 89
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 128
13C2-6:2 FTS (surr.) 1 % 115
13C2-8:2 FTS (surr.) 1 % 81
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.09
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.06
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.09
Sum of WA DER PFAS (n=10) 0.05 ug/L 0.09
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 5.4
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 450
Alkali Metals
Calcium 0.5 mg/L 74
Magnesium 0.5 mg/L 35
Potassium 0.5 mg/L 1.8
Sodium 0.5 mg/L 21
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560580-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 07, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 23, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 22, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 23, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 22, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560580-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 7:06 PMAddress: Level 1, 436 Johnston Street Report #: 560580 Due: Sep 5, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB014_170810
Aug 10, 2017 Water M17-Au19920 X X X X X
Test Counts 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560580-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560580-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 110 50-150 Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560580-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 121 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 113 50-150 Pass
Perfluorooctanoic acid (PFOA) % 96 50-150 Pass
Perfluorononanoic acid (PFNA) % 133 50-150 Pass
Perfluorodecanoic acid (PFDA) % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 110 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 134 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 91 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 124 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 129 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 104 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 100 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 139 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 123 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 117 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 125 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 88 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 121 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 106 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 104 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 129 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 104 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 105 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 109 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 129 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 112 50-150 Pass
LCS - % Recovery
Chloride % 108 70-130 Pass
Sulphate (as SO4) % 111 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 103 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 106 70-130 Pass
Magnesium % 106 70-130 Pass
Potassium % 100 70-130 Pass
Sodium % 115 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Se06868 NCP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Se06868 NCP % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Se06868 NCP % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Se06868 NCP % 112 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Se06868 NCP % 97 50-150 Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560580-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) B17-Se06868 NCP % 137 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Se06868 NCP % 105 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Se06868 NCP % 117 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Se06868 NCP % 138 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se06868 NCP % 89 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se06868 NCP % 138 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Se06868 NCP % 114 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se06868 NCP % 103 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se06868 NCP % 96 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se06868 NCP % 92 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se06868 NCP % 128 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se06868 NCP % 116 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se06868 NCP % 120 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Se06868 NCP % 86 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se06868 NCP % 121 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se06868 NCP % 100 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se06868 NCP % 93 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se06868 NCP % 128 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se06868 NCP % 123 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se06868 NCP % 120 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se06868 NCP % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se06868 NCP % 127 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se06868 NCP % 128 50-150 Pass
Spike - % Recovery
Result 1
Chloride P17-Au25697 NCP % 122 70-130 Pass
Sulphate (as SO4) M17-Au25405 NCP % 90 70-130 Pass
Spike - % Recovery
Alkalinity (speciated) Result 1
Total Alkalinity (as CaCO3) M17-Au25715 NCP % 122 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560580-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Calcium M17-Au28491 NCP % 126 70-130 Pass
Magnesium M17-Au27410 NCP % 139 70-130 Fail Q08
Potassium M17-Au28491 NCP % 116 70-130 Pass
Sodium M17-Au28491 NCP % 108 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560580-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se06866 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se06866 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au19106 NCP mg/L 1100 920 7.0 30% Pass
Sulphate (as SO4) M17-Au25404 NCP mg/L 350 350 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) P17-Au25693 NCP mg/L 220 210 5.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au28491 NCP mg/L 13 13 3.0 30% Pass
Magnesium M17-Au28491 NCP mg/L 1.7 1.7 2.0 30% Pass
Potassium M17-Au28491 NCP mg/L 5.6 5.4 4.0 30% Pass
Sodium M17-Au28491 NCP mg/L 26 22 13 30% Pass
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560580-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Q08The matrix spike recovery is outside of the recommended acceptance criteria. An acceptable recovery was obtained for the laboratory control sample indicating a sample matrixinterference
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 07, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560580-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560581-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB015_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19874
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Chloride 1 mg/L 14
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 410
Alkali Metals
Calcium 0.5 mg/L 92
Magnesium 0.5 mg/L 31
Potassium 0.5 mg/L 1.3
Sodium 0.5 mg/L 4.5
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 6
Report Number: 560581-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 6
Report Number: 560581-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 7:06 PMAddress: Level 1, 436 Johnston Street Report #: 560581 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 2 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB015_170811
Aug 11, 2017 Water M17-Au19874 X X X X
Test Counts 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 6
Report Number: 560581-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 6
Report Number: 560581-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Chloride % 104 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Result 1
Chloride M17-Au32777 NCP % 110 70-130 Pass
Sulphate (as SO4) M17-Au33189 NCP % 101 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium B17-Au35173 NCP % 115 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au33386 NCP % 116 70-130 Pass
Sodium B17-Au35173 NCP % 124 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au33188 NCP mg/L 24 23 3.7 30% Pass
Sulphate (as SO4) M17-Au33188 NCP mg/L 160 160 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) B17-Au35173 NCP mg/L < 20 < 20 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium B17-Au35173 NCP mg/L 120 100 19 30% Pass
Magnesium B17-Au35173 NCP mg/L 100 100 1.0 30% Pass
Potassium B17-Au35173 NCP mg/L 2.3 2.3 2.0 30% Pass
Sodium B17-Au35173 NCP mg/L 260 260 1.0 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 6
Report Number: 560581-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 6
Report Number: 560581-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560581-W-V2
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB015_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19874
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L 0.04
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L 0.17
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L 0.03
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L 0.05
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 52
13C5-PFPeA (surr.) 1 % 58
13C5-PFHxA (surr.) 1 % 68
13C4-PFHpA (surr.) 1 % 67
13C8-PFOA (surr.) 1 % 71
13C5-PFNA (surr.) 1 % 67
13C6-PFDA (surr.) 1 % 51
13C2-PFUnDA (surr.) 1 % 40
13C2-PFDoDA (surr.) 1 % 31
13C2-PFTeDA (surr.) 1 % 14
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 25
D3-N-MeFOSA (surr.) 1 % 10
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 9
Report Number: 560581-W-V2
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB015_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19874
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 14
D9-N-EtFOSE (surr.) 1 % 12
D5-N-EtFOSAA (surr.) 1 % 13
D3-N-MeFOSAA (surr.) 1 % 12
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.16
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L 0.15
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L 1.0
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L 0.06
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L 1.8
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 99
18O2-PFHxS (surr.) 1 % 90
13C8-PFOS (surr.) 1 % 78
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 117
13C2-6:2 FTS (surr.) 1 % 100
13C2-8:2 FTS (surr.) 1 % 66
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 2.8
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 1.85
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 2.85
Sum of WA DER PFAS (n=10) 0.05 ug/L 3.25
Sum of PFASs (n=28) 0.1 ug/L 3.46
Chloride 1 mg/L 14
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 410
Alkali Metals
Calcium 0.5 mg/L 92
Magnesium 0.5 mg/L 31
Potassium 0.5 mg/L 1.3
Sodium 0.5 mg/L 4.5
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 9
Report Number: 560581-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 08, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 08, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 08, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 08, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 9
Report Number: 560581-W-V2
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 7:06 PMAddress: Level 1, 436 Johnston Street Report #: 560581 Due: Sep 5, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB015_170811
Aug 11, 2017 Water M17-Au19874 X X X X
Test Counts 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
First Reported:Aug 31, 2017
Date Reported:Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 9
Report Number: 560581-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 9
Report Number: 560581-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 96 50-150 Pass
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 9
Report Number: 560581-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 93 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 95 50-150 Pass
Perfluorononanoic acid (PFNA) % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) % 97 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 109 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 90 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 99 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 109 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 98 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 101 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 107 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 107 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 107 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 102 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 86 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 80 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 73 50-150 Pass
LCS - % Recovery
Chloride % 104 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Result 1
Chloride M17-Au32777 NCP % 110 70-130 Pass
Sulphate (as SO4) M17-Au33189 NCP % 101 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium B17-Au35173 NCP % 115 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au33386 NCP % 116 70-130 Pass
Sodium B17-Au35173 NCP % 124 70-130 Pass
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 9
Report Number: 560581-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au33188 NCP mg/L 24 23 3.7 30% Pass
Sulphate (as SO4) M17-Au33188 NCP mg/L 160 160 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) B17-Au35173 NCP mg/L < 20 < 20 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium B17-Au35173 NCP mg/L 120 100 19 30% Pass
Magnesium B17-Au35173 NCP mg/L 100 100 1.0 30% Pass
Potassium B17-Au35173 NCP mg/L 2.3 2.3 2.0 30% Pass
Sodium B17-Au35173 NCP mg/L 260 260 1.0 30% Pass
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 9
Report Number: 560581-W-V2
Comments
Report amended to add in PFAS data
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
First Reported: Aug 31, 2017
Date Reported: Sep 08, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 9
Report Number: 560581-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560582-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB016_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19875
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 75
13C5-PFPeA (surr.) 1 % 76
13C5-PFHxA (surr.) 1 % 86
13C4-PFHpA (surr.) 1 % 84
13C8-PFOA (surr.) 1 % 87
13C5-PFNA (surr.) 1 % 73
13C6-PFDA (surr.) 1 % 52
13C2-PFUnDA (surr.) 1 % 39
13C2-PFDoDA (surr.) 1 % 35
13C2-PFTeDA (surr.) 1 % 22
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 20
D3-N-MeFOSA (surr.) 1 % INT
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560582-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB016_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19875
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % INT
D9-N-EtFOSE (surr.) 1 % INT
D5-N-EtFOSAA (surr.) 1 % 11
D3-N-MeFOSAA (surr.) 1 % INT
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 100
18O2-PFHxS (surr.) 1 % 93
13C8-PFOS (surr.) 1 % 76
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 114
13C2-6:2 FTS (surr.) 1 % 99
13C2-8:2 FTS (surr.) 1 % 58
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 12
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 360
Alkali Metals
Calcium 0.5 mg/L 74
Magnesium 0.5 mg/L 29
Potassium 0.5 mg/L 1.7
Sodium 0.5 mg/L 2.3
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560582-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 31, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560582-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 5:36 PMAddress: Level 1, 436 Johnston Street Report #: 560582 Due: Sep 5, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB016_170811
Aug 11, 2017 Water M17-Au19875 X X X X X
Test Counts 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560582-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560582-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 96 50-150 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560582-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 93 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 95 50-150 Pass
Perfluorononanoic acid (PFNA) % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) % 97 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 109 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 90 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 99 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 109 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 98 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 101 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 107 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 107 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 107 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 102 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 86 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 80 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 73 50-150 Pass
LCS - % Recovery
Chloride % 115 70-130 Pass
Sulphate (as SO4) % 107 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au19875 CP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au19875 CP % 98 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au19875 CP % 94 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19875 CP % 102 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au19875 CP % 97 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au19875 CP % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au19875 CP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19875 CP % 112 50-150 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560582-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorododecanoic acid (PFDoA) M17-Au19875 CP % 107 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19875 CP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19875 CP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au19875 CP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19875 CP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19875 CP % 101 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19875 CP % 95 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19875 CP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19875 CP % 92 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19875 CP % 97 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au19875 CP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19875 CP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19875 CP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19875 CP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19875 CP % 88 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19875 CP % 72 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19875 CP % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19875 CP % 98 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19875 CP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19875 CP % 64 50-150 Pass
Spike - % Recovery
Result 1
Chloride B17-Au35297 NCP % 130 70-130 Pass
Sulphate (as SO4) M17-Au19878 NCP % 105 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium B17-Au35173 NCP % 115 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au33386 NCP % 116 70-130 Pass
Sodium B17-Au35173 NCP % 124 70-130 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560582-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19851 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19851 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560582-W
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au19877 NCP mg/L 7.8 7.9 <1 30% Pass
Sulphate (as SO4) M17-Au19877 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) B17-Au35173 NCP mg/L < 20 < 20 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium B17-Au35173 NCP mg/L 120 100 19 30% Pass
Magnesium B17-Au35173 NCP mg/L 100 100 1.0 30% Pass
Potassium B17-Au35173 NCP mg/L 2.3 2.3 2.0 30% Pass
Sodium B17-Au35173 NCP mg/L 260 260 1.0 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560582-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560582-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560584-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB017_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19876
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 69
13C5-PFPeA (surr.) 1 % 69
13C5-PFHxA (surr.) 1 % 80
13C4-PFHpA (surr.) 1 % 78
13C8-PFOA (surr.) 1 % 81
13C5-PFNA (surr.) 1 % 75
13C6-PFDA (surr.) 1 % 57
13C2-PFUnDA (surr.) 1 % 42
13C2-PFDoDA (surr.) 1 % 37
13C2-PFTeDA (surr.) 1 % 22
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 43
D3-N-MeFOSA (surr.) 1 % 18
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560584-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB017_170811
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19876
Date Sampled Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % INT
D7-N-MeFOSE (surr.) 1 % 24
D9-N-EtFOSE (surr.) 1 % 18
D5-N-EtFOSAA (surr.) 1 % 11
D3-N-MeFOSAA (surr.) 1 % INT
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 96
18O2-PFHxS (surr.) 1 % 90
13C8-PFOS (surr.) 1 % 83
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 104
13C2-6:2 FTS (surr.) 1 % 90
13C2-8:2 FTS (surr.) 1 % 62
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 15
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 340
Alkali Metals
Calcium 0.5 mg/L 77
Magnesium 0.5 mg/L 31
Potassium 0.5 mg/L 2.1
Sodium 0.5 mg/L 6.2
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560584-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 31, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560584-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 5:36 PMAddress: Level 1, 436 Johnston Street Report #: 560584 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 2 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB017_170811
Aug 11, 2017 Water M17-Au19876 X X X X X
Test Counts 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560584-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560584-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 96 50-150 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560584-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 93 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 95 50-150 Pass
Perfluorononanoic acid (PFNA) % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) % 97 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 109 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 90 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 99 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 109 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 98 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 101 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 107 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 107 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 107 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 102 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 86 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 80 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 73 50-150 Pass
LCS - % Recovery
Chloride % 115 70-130 Pass
Sulphate (as SO4) % 107 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au19875 NCP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au19875 NCP % 98 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au19875 NCP % 94 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19875 NCP % 102 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au19875 NCP % 97 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au19875 NCP % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au19875 NCP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19875 NCP % 112 50-150 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560584-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorododecanoic acid (PFDoA) M17-Au19875 NCP % 107 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19875 NCP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19875 NCP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au19875 NCP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19875 NCP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19875 NCP % 101 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19875 NCP % 95 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19875 NCP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19875 NCP % 92 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19875 NCP % 97 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au19875 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19875 NCP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19875 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19875 NCP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19875 NCP % 88 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19875 NCP % 72 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19875 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19875 NCP % 98 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19875 NCP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19875 NCP % 64 50-150 Pass
Spike - % Recovery
Result 1
Chloride B17-Au35297 NCP % 130 70-130 Pass
Sulphate (as SO4) M17-Au19878 NCP % 105 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium B17-Au35173 NCP % 115 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au33386 NCP % 116 70-130 Pass
Sodium B17-Au35173 NCP % 124 70-130 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560584-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19877 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19877 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560584-W
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au19877 NCP mg/L 7.8 7.9 <1 30% Pass
Sulphate (as SO4) M17-Au19877 NCP mg/L < 5 < 5 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) B17-Au35173 NCP mg/L < 20 < 20 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium B17-Au35173 NCP mg/L 120 100 19 30% Pass
Magnesium B17-Au35173 NCP mg/L 100 100 1.0 30% Pass
Potassium B17-Au35173 NCP mg/L 2.3 2.3 2.0 30% Pass
Sodium B17-Au35173 NCP mg/L 260 260 1.0 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560584-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560584-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560587-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 17, 2017
Client Sample ID 0990_PB018_170811-1
0990_PB018_170811-2
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au19877 M17-Au19878
Date Sampled Aug 11, 2017 Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05 < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01 < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01 < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01 < 0.01
13C4-PFBA (surr.) 1 % 80 72
13C5-PFPeA (surr.) 1 % 82 76
13C5-PFHxA (surr.) 1 % 91 85
13C4-PFHpA (surr.) 1 % 87 80
13C8-PFOA (surr.) 1 % 89 82
13C5-PFNA (surr.) 1 % 79 71
13C6-PFDA (surr.) 1 % 61 51
13C2-PFUnDA (surr.) 1 % 45 38
13C2-PFDoDA (surr.) 1 % 40 34
13C2-PFTeDA (surr.) 1 % 28 24
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05 < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05 < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05 < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05 < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05 < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05 < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05 < 0.05
13C8-FOSA (surr.) 1 % 73 20
D3-N-MeFOSA (surr.) 1 % 24 INT
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 8
Report Number: 560587-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB018_170811-1
0990_PB018_170811-2
Sample Matrix Water Water
Eurofins | mgt Sample No. M17-Au19877 M17-Au19878
Date Sampled Aug 11, 2017 Aug 11, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 12 INT
D7-N-MeFOSE (surr.) 1 % 31 INT
D9-N-EtFOSE (surr.) 1 % 26 INT
D5-N-EtFOSAA (surr.) 1 % 13 13
D3-N-MeFOSAA (surr.) 1 % INT 10
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01 < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01 < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01 < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01 < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01 < 0.01
13C3-PFBS (surr.) 1 % 101 94
18O2-PFHxS (surr.) 1 % 95 88
13C8-PFOS (surr.) 1 % 83 73
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05 < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01 < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01 < 0.01
13C2-4:2 FTS (surr.) 1 % 115 106
13C2-6:2 FTS (surr.) 1 % 100 91
13C2-8:2 FTS (surr.) 1 % 67 58
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01 < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01 < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05 < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1 < 0.1
Chloride 1 mg/L 7.8 12
Sulphate (as SO4) 5 mg/L < 5 < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 330 390
Alkali Metals
Calcium 0.5 mg/L 73 70
Magnesium 0.5 mg/L 29 28
Potassium 0.5 mg/L 1.1 1.1
Sodium 0.5 mg/L 12 15
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 8
Report Number: 560587-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 31, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 8
Report Number: 560587-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 5:36 PMAddress: Level 1, 436 Johnston Street Report #: 560587 Due: Aug 31, 2017
Abbotsford Phone: 03 8413 6900 Priority: 2 DayVIC 3067 Fax: Contact Name: Sarah Richards
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB018_170811-1
Aug 11, 2017 Water M17-Au19877 X X X X X
2 0990_PB018_170811-2
Aug 11, 2017 Water M17-Au19878 X X X X X
Test Counts 2 2 2 2 2
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 8
Report Number: 560587-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 8
Report Number: 560587-W
Quality Control Results
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Result 1
Sulphate (as SO4) M17-Au19878 CP % 105 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 8
Report Number: 560587-W
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19877 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19877 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au19877 CP mg/L 7.8 7.9 <1 30% Pass
Sulphate (as SO4) M17-Au19877 CP mg/L < 5 < 5 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 8
Report Number: 560587-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 8
Report Number: 560587-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560588-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB019_170812
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19851
Date Sampled Aug 12, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 85
13C5-PFPeA (surr.) 1 % 86
13C5-PFHxA (surr.) 1 % 98
13C4-PFHpA (surr.) 1 % 94
13C8-PFOA (surr.) 1 % 98
13C5-PFNA (surr.) 1 % 86
13C6-PFDA (surr.) 1 % 65
13C2-PFUnDA (surr.) 1 % 51
13C2-PFDoDA (surr.) 1 % 46
13C2-PFTeDA (surr.) 1 % 31
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 74
D3-N-MeFOSA (surr.) 1 % 23
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 10
Report Number: 560588-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB019_170812
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au19851
Date Sampled Aug 12, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 12
D7-N-MeFOSE (surr.) 1 % 35
D9-N-EtFOSE (surr.) 1 % 30
D5-N-EtFOSAA (surr.) 1 % 17
D3-N-MeFOSAA (surr.) 1 % 12
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 102
18O2-PFHxS (surr.) 1 % 98
13C8-PFOS (surr.) 1 % 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 119
13C2-6:2 FTS (surr.) 1 % 105
13C2-8:2 FTS (surr.) 1 % 70
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 12
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 450
Alkali Metals
Calcium 0.5 mg/L 86
Magnesium 0.5 mg/L 37
Potassium 0.5 mg/L 1.6
Sodium 0.5 mg/L 6.3
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 10
Report Number: 560588-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Aug 31, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 10
Report Number: 560588-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 10
Report Number: 560588-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 96 50-150 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 10
Report Number: 560588-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 99 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 93 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 95 50-150 Pass
Perfluorononanoic acid (PFNA) % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) % 97 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 109 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 90 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 100 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 99 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 109 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 109 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 98 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 116 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 95 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 101 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 107 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 107 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 107 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 102 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 86 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 80 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 97 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 95 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 73 50-150 Pass
LCS - % Recovery
Chloride % 104 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Au19875 NCP % 97 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Au19875 NCP % 98 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Au19875 NCP % 94 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19875 NCP % 102 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Au19875 NCP % 97 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Au19875 NCP % 97 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Au19875 NCP % 99 50-150 Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19875 NCP % 112 50-150 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 10
Report Number: 560588-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorododecanoic acid (PFDoA) M17-Au19875 NCP % 107 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19875 NCP % 87 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19875 NCP % 103 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Au19875 NCP % 98 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19875 NCP % 104 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19875 NCP % 101 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19875 NCP % 95 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19875 NCP % 106 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19875 NCP % 92 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19875 NCP % 97 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Au19875 NCP % 108 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19875 NCP % 107 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19875 NCP % 111 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19875 NCP % 98 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19875 NCP % 88 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19875 NCP % 72 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19875 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19875 NCP % 98 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19875 NCP % 96 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19875 NCP % 64 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au32777 NCP % 110 70-130 Pass
Sulphate (as SO4) M17-Au33189 NCP % 101 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium B17-Au35173 NCP % 115 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au33386 NCP % 116 70-130 Pass
Sodium B17-Au35173 NCP % 124 70-130 Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 10
Report Number: 560588-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Au19851 CP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Au19851 CP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 10
Report Number: 560588-W
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au33188 NCP mg/L 24 23 3.7 30% Pass
Sulphate (as SO4) M17-Au33188 NCP mg/L 160 160 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) B17-Au35173 NCP mg/L < 20 < 20 <1 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium B17-Au35173 NCP mg/L 120 100 19 30% Pass
Magnesium B17-Au35173 NCP mg/L 100 100 1.0 30% Pass
Potassium B17-Au35173 NCP mg/L 2.3 2.3 2.0 30% Pass
Sodium B17-Au35173 NCP mg/L 260 260 1.0 30% Pass
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 10
Report Number: 560588-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Aug 31, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 10
Report Number: 560588-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560609-W-V2
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB030_170823
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au33050
Date Sampled Aug 23, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 97
13C5-PFPeA (surr.) 1 % 99
13C5-PFHxA (surr.) 1 % 127
13C4-PFHpA (surr.) 1 % 140
13C8-PFOA (surr.) 1 % 154
13C5-PFNA (surr.) 1 % 105
13C6-PFDA (surr.) 1 % 79
13C2-PFUnDA (surr.) 1 % 64
13C2-PFDoDA (surr.) 1 % 47
13C2-PFTeDA (surr.) 1 % 30
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 73
D3-N-MeFOSA (surr.) 1 % 49
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560609-W-V2
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB030_170823
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au33050
Date Sampled Aug 23, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 49
D7-N-MeFOSE (surr.) 1 % 36
D9-N-EtFOSE (surr.) 1 % 43
D5-N-EtFOSAA (surr.) 1 % 48
D3-N-MeFOSAA (surr.) 1 % 54
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 128
18O2-PFHxS (surr.) 1 % 135
13C8-PFOS (surr.) 1 % 85
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 187
13C2-6:2 FTS (surr.) 1 % 148
13C2-8:2 FTS (surr.) 1 % 72
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 22
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 430
Alkali Metals
Calcium 0.5 mg/L 27
Magnesium 0.5 mg/L 36
Potassium 0.5 mg/L 5.3
Sodium 0.5 mg/L 47
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560609-W-V2
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560609-W-V2
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 9:17 AMAddress: Level 1, 436 Johnston Street Report #: 560609 Due: Sep 4, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Jeni Young
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_QCMW197_170823
Aug 23, 2017 Water M17-Au33049 X
2 0990_PB30_170823
Aug 23, 2017 Water M17-Au33050 X X X X X
3 0990_PB31_170823
Aug 23, 2017 Water M17-Au33051 X X X X X
4 0990_QCMW198_170824
Aug 24, 2017 Water M17-Au33052 X
Test Counts 2 2 2 2 4
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560609-W-V2
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560609-W-V2
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 100 50-150 Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560609-W-V2
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 101 50-150 Pass
Perfluorononanoic acid (PFNA) % 138 50-150 Pass
Perfluorodecanoic acid (PFDA) % 101 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 107 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 125 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 98 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 115 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 112 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 103 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 117 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 102 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 115 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 106 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 94 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 103 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 95 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 98 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 118 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 97 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 108 50-150 Pass
LCS - % Recovery
Chloride % 104 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 104 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Se00306 NCP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Se00306 NCP % 111 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Se00306 NCP % 103 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Se00306 NCP % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Se00306 NCP % 104 50-150 Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560609-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) B17-Se00306 NCP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Se00306 NCP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Se00306 NCP % 102 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Se00306 NCP % 105 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se00306 NCP % 106 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se00306 NCP % 119 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Se00306 NCP % 96 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se00306 NCP % 112 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se00306 NCP % 103 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se00306 NCP % 150 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se00306 NCP % 125 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se00306 NCP % 114 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se00306 NCP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Se00306 NCP % 101 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se00306 NCP % 109 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se00306 NCP % 106 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se00306 NCP % 108 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se00306 NCP % 117 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se00306 NCP % 102 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se00306 NCP % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se00306 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se00306 NCP % 115 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se00306 NCP % 103 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au32777 NCP % 110 70-130 Pass
Sulphate (as SO4) M17-Au33189 NCP % 101 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au32308 NCP % 114 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au32308 NCP % 104 70-130 Pass
Sodium M17-Au32308 NCP % 111 70-130 Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560609-W-V2
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560609-W-V2
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au33188 NCP mg/L 24 23 3.7 30% Pass
Sulphate (as SO4) M17-Au33188 NCP mg/L 160 160 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) M17-Au32307 NCP mg/L 550 580 5.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au32583 NCP mg/L 0.6 0.5 6.0 30% Pass
Magnesium M17-Au32583 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au24021 NCP mg/L 1.7 1.5 11 30% Pass
Sodium M17-Au24021 NCP mg/L 3.1 2.9 4.0 30% Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560609-W-V2
Comments
V2 - Split report for PB030
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560609-W-V2
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Sarah Richards
Report 560609-W-V3
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Aug 28, 2017
Client Sample ID 0990_PB031_170823
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au33051
Date Sampled Aug 23, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L < 0.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L < 0.01
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L < 0.01
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 99
13C5-PFPeA (surr.) 1 % 97
13C5-PFHxA (surr.) 1 % 131
13C4-PFHpA (surr.) 1 % 143
13C8-PFOA (surr.) 1 % 154
13C5-PFNA (surr.) 1 % 105
13C6-PFDA (surr.) 1 % 77
13C2-PFUnDA (surr.) 1 % 64
13C2-PFDoDA (surr.) 1 % 47
13C2-PFTeDA (surr.) 1 % 26
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 76
D3-N-MeFOSA (surr.) 1 % 51
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 560609-W-V3
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB031_170823
Sample Matrix Water
Eurofins | mgt Sample No. M17-Au33051
Date Sampled Aug 23, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 51
D7-N-MeFOSE (surr.) 1 % 35
D9-N-EtFOSE (surr.) 1 % 46
D5-N-EtFOSAA (surr.) 1 % 48
D3-N-MeFOSAA (surr.) 1 % 60
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L < 0.01
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L < 0.01
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L < 0.01
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L < 0.01
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L < 0.01
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 130
18O2-PFHxS (surr.) 1 % 131
13C8-PFOS (surr.) 1 % 86
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 197
13C2-6:2 FTS (surr.) 1 % 158
13C2-8:2 FTS (surr.) 1 % 78
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L < 0.01
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L < 0.01
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L < 0.01
Sum of WA DER PFAS (n=10) 0.05 ug/L < 0.05
Sum of PFASs (n=28) 0.1 ug/L < 0.1
Chloride 1 mg/L 26
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 420
Alkali Metals
Calcium 0.5 mg/L 43
Magnesium 0.5 mg/L 110
Potassium 0.5 mg/L 13
Sodium 0.5 mg/L 40
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 560609-W-V3
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 06, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Aug 29, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Aug 29, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Aug 29, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 560609-W-V3
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Aug 28, 2017 9:17 AMAddress: Level 1, 436 Johnston Street Report #: 560609 Due: Sep 4, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Jeni Young
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_QCMW197_170823
Aug 23, 2017 Water M17-Au33049 X
2 0990_PB30_170823
Aug 23, 2017 Water M17-Au33050 X X X X X
3 0990_PB31_170823
Aug 23, 2017 Water M17-Au33051 X X X X X
4 0990_QCMW198_170824
Aug 24, 2017 Water M17-Au33052 X
Test Counts 2 2 2 2 4
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 560609-W-V3
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 560609-W-V3
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 100 50-150 Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 560609-W-V3
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 109 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 106 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 100 50-150 Pass
Perfluorooctanoic acid (PFOA) % 101 50-150 Pass
Perfluorononanoic acid (PFNA) % 138 50-150 Pass
Perfluorodecanoic acid (PFDA) % 101 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 107 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 125 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 98 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 115 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 112 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 103 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 112 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 117 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 102 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 115 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 106 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 94 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 103 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 95 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 98 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 118 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 97 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 100 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 93 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 108 50-150 Pass
LCS - % Recovery
Chloride % 104 70-130 Pass
Sulphate (as SO4) % 115 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 104 70-130 Pass
LCS - % Recovery
Alkali Metals
Calcium % 97 70-130 Pass
Magnesium % 100 70-130 Pass
Potassium % 92 70-130 Pass
Sodium % 96 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) B17-Se00306 NCP % 104 50-150 Pass
Perfluoropentanoic acid (PFPeA) B17-Se00306 NCP % 111 50-150 Pass
Perfluorohexanoic acid (PFHxA) B17-Se00306 NCP % 103 50-150 Pass
Perfluoroheptanoic acid (PFHpA) B17-Se00306 NCP % 105 50-150 Pass
Perfluorooctanoic acid (PFOA) B17-Se00306 NCP % 104 50-150 Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 560609-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluorononanoic acid (PFNA) B17-Se00306 NCP % 114 50-150 Pass
Perfluorodecanoic acid (PFDA) B17-Se00306 NCP % 109 50-150 Pass
Perfluoroundecanoic acid (PFUnA) B17-Se00306 NCP % 102 50-150 Pass
Perfluorododecanoic acid (PFDoA) B17-Se00306 NCP % 105 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se00306 NCP % 106 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se00306 NCP % 119 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) B17-Se00306 NCP % 96 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se00306 NCP % 112 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se00306 NCP % 103 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se00306 NCP % 150 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se00306 NCP % 125 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se00306 NCP % 114 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se00306 NCP % 108 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) B17-Se00306 NCP % 101 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se00306 NCP % 109 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se00306 NCP % 106 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se00306 NCP % 108 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se00306 NCP % 117 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se00306 NCP % 102 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se00306 NCP % 109 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se00306 NCP % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se00306 NCP % 115 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se00306 NCP % 103 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Au32777 NCP % 110 70-130 Pass
Sulphate (as SO4) M17-Au33189 NCP % 101 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Au32308 NCP % 114 70-130 Pass
Magnesium M17-Au32308 NCP % 112 70-130 Pass
Potassium M17-Au32308 NCP % 104 70-130 Pass
Sodium M17-Au32308 NCP % 111 70-130 Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 560609-W-V3
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se00305 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se00305 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 560609-W-V3
Duplicate
Result 1 Result 2 RPD
Chloride M17-Au33188 NCP mg/L 24 23 3.7 30% Pass
Sulphate (as SO4) M17-Au33188 NCP mg/L 160 160 <1 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) M17-Au32307 NCP mg/L 550 580 5.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Au32583 NCP mg/L 0.6 0.5 6.0 30% Pass
Magnesium M17-Au32583 NCP mg/L < 0.5 < 0.5 <1 30% Pass
Potassium M17-Au24021 NCP mg/L 1.7 1.5 11 30% Pass
Sodium M17-Au24021 NCP mg/L 3.1 2.9 4.0 30% Pass
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 560609-W-V3
Comments
V3 - Split report for PB031
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident Yes
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code Description
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 11, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 560609-W-V3
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 561801-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Sep 04, 2017
Client Sample ID 0990_PB034_170829
Sample Matrix Water
Eurofins | mgt Sample No. M17-Se04588
Date Sampled Aug 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.06
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 78
13C5-PFPeA (surr.) 1 % 82
13C5-PFHxA (surr.) 1 % 86
13C4-PFHpA (surr.) 1 % 82
13C8-PFOA (surr.) 1 % 74
13C5-PFNA (surr.) 1 % 65
13C6-PFDA (surr.) 1 % 68
13C2-PFUnDA (surr.) 1 % 63
13C2-PFDoDA (surr.) 1 % 62
13C2-PFTeDA (surr.) 1 % 45
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 72
D3-N-MeFOSA (surr.) 1 % 48
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 561801-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB034_170829
Sample Matrix Water
Eurofins | mgt Sample No. M17-Se04588
Date Sampled Aug 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 29
D7-N-MeFOSE (surr.) 1 % 52
D9-N-EtFOSE (surr.) 1 % 44
D5-N-EtFOSAA (surr.) 1 % 66
D3-N-MeFOSAA (surr.) 1 % 60
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.06
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.07
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.37
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.02
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.58
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 82
18O2-PFHxS (surr.) 1 % 70
13C8-PFOS (surr.) 1 % 57
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 44
13C2-6:2 FTS (surr.) 1 % 37
13C2-8:2 FTS (surr.) 1 % 38
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 0.95
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.6
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 0.97
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.1
Sum of PFASs (n=28) 0.1 ug/L 1.19
Chloride 1 mg/L 14
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 430
Alkali Metals
Calcium 0.5 mg/L 73
Magnesium 0.5 mg/L 32
Potassium 0.5 mg/L 1.1
Sodium 0.5 mg/L 4.8
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 561801-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Sep 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Sep 06, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Sep 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Sep 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 561801-W
.Company Name: Coffey Environments Pty Ltd VIC Order No.: Received: Sep 4, 2017 11:55 AMAddress: Level 1, 436 Johnston Street Report #: 561801 Due: Sep 11, 2017
Abbotsford Phone: 03 8413 6900 Priority: 5 DayVIC 3067 Fax: Contact Name: Ian Newby
Project Name: DOD TINDALProject ID: 754-MELEN199420
Eurofins | mgt Analytical Services Manager : Mary Makarios
Sample Detail
Chloride
Sulphate (as S
O4)
Total A
lkalinity (as CaC
O3)
Alkali M
etals
Per- and P
olyfluorinated Alkyl S
ubstances(P
FA
Ss)
Melbourne Laboratory - NATA Site # 1254 & 14271 X X X X
Sydney Laboratory - NATA Site # 18217
Brisbane Laboratory - NATA Site # 20794 X
Perth Laboratory - NATA Site # 23736
External Laboratory
No Sample ID Sample Date SamplingTime
Matrix LAB ID
1 0990_PB034_170829
Aug 29, 2017 Water M17-Se04588 X X X X X
Test Counts 1 1 1 1 1
ABN– 50 005 085 521e.mail : [email protected] : www.eurofins.com.au
MelbourneMelbourneMelbourneMelbourne2-5 Kingston Town CloseOakleigh VIC 3166Phone : +61 3 8564 5000NATA # 1261Site # 1254 & 14271
SydneySydneySydneySydneyUnit F3, Building F16 Mars RoadLane Cove West NSW 2066Phone : +61 2 9900 8400NATA # 1261 Site # 18217
BrisbaneBrisbaneBrisbaneBrisbane1/21 Smallwood PlaceMurarrie QLD 4172Phone : +61 7 3902 4600NATA # 1261 Site # 20794
PerthPerthPerthPerth2/91 Leach HighwayKewdale WA 6105Phone : +61 8 9251 9600NATA # 1261Site # 23736
Date Reported:Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 4 of 11
Report Number: 561801-W
Internal Quality Control Review and Glossary
General
Holding Times
Units
Terms
QC - Acceptance Criteria
QC Data General Comments
1. Laboratory QC results for Method Blanks, Duplicates, Matrix Spikes, and Laboratory Control Samples are included in this QC report where applicable. Additional QC data may be available on
request.
2. All soil results are reported on a dry basis, unless otherwise stated.
3. All biota results are reported on a wet weight basis on the edible portion, unless otherwise stated.
4. Actual LORs are matrix dependant. Quoted LORs may be raised where sample extracts are diluted due to interferences.
5. Results are uncorrected for matrix spikes or surrogate recoveries except for PFAS compounds.
6. SVOC analysis on waters are performed on homogenised, unfiltered samples, unless noted otherwise.
7. Samples were analysed on an 'as received' basis.
8. This report replaces any interim results previously issued.
Please refer to 'Sample Preservation and Container Guide' for holding times (QS3001).
For samples received on the last day of holding time, notification of testing requirements should have been received at least 6 hours prior to sample receipt deadlines as stated on the Sample
Receipt Advice.
If the Laboratory did not receive the information in the required timeframe, and regardless of any other integrity issues, suitably qualified results may still be reported.
Holding times apply from the date of sampling, therefore compliance to these may be outside the laboratory's control.
**NOTE: pH duplicates are reported as a range NOT as RPD
mg/kg: milligrams per kilogram mg/L: milligrams per litre
ug/L: micrograms per litre ppm: Parts per million
ppb: Parts per billion %: Percentage
org/100mL: Organisms per 100 millilitres NTU: Nephelometric Turbidity Units
MPN/100mL: Most Probable Number of organisms per 100 millilitres
Dry Where a moisture has been determined on a solid sample the result is expressed on a dry basis.
LOR Limit of Reporting.
SPIKE Addition of the analyte to the sample and reported as percentage recovery.
RPD Relative Percent Difference between two Duplicate pieces of analysis.
LCS Laboratory Control Sample - reported as percent recovery.
CRM Certified Reference Material - reported as percent recovery.
Method Blank In the case of solid samples these are performed on laboratory certified clean sands and in the case of water samples these are performed on de-ionised water.
Surr - Surrogate The addition of a like compound to the analyte target and reported as percentage recovery.
Duplicate A second piece of analysis from the same sample and reported in the same units as the result to show comparison.
USEPA United States Environmental Protection Agency
APHA American Public Health Association
TCLP Toxicity Characteristic Leaching Procedure
COC Chain of Custody
SRA Sample Receipt Advice
QSM Quality Systems Manual ver 5.1 US Department of Defense
CP Client Parent - QC was performed on samples pertaining to this report
NCP Non-Client Parent - QC performed on samples not pertaining to this report, QC is representative of the sequence or batch that client samples were analysed within.
TEQ Toxic Equivalency Quotient
RPD Duplicates: Global RPD Duplicates Acceptance Criteria is 30% however the following acceptance guidelines are equally applicable:
Results <10 times the LOR : No Limit
Results between 10-20 times the LOR : RPD must lie between 0-50%
Results >20 times the LOR : RPD must lie between 0-30%
Surrogate Recoveries: Recoveries must lie between 50-150%-Phenols & PFASs
PFAS field samples that contain surrogate recoveries in excess of the QC limit designated in QSM 5.1 where no positive PFAS results have been reported have been reviewed and no data was
affected.
1. Where a result is reported as a less than (<), higher than the nominated LOR, this is due to either matrix interference, extract dilution required due to interferences or contaminant levels within
the sample, high moisture content or insufficient sample provided.
2. Duplicate data shown within this report that states the word "BATCH" is a Batch Duplicate from outside of your sample batch, but within the laboratory sample batch at a 1:10 ratio. The Parent
and Duplicate data shown is not data from your samples.
3. Organochlorine Pesticide analysis - where reporting LCS data, Toxaphene & Chlordane are not added to the LCS.
4. Organochlorine Pesticide analysis - where reporting Spike data, Toxaphene is not added to the Spike.
5. Total Recoverable Hydrocarbons - where reporting Spike & LCS data, a single spike of commercial Hydrocarbon products in the range of C12-C30 is added and it's Total Recovery is reported
in the C10-C14 cell of the Report.
6. pH and Free Chlorine analysed in the laboratory - Analysis on this test must begin within 30 minutes of sampling.Therefore laboratory analysis is unlikely to be completed within holding time.
Analysis will begin as soon as possible after sample receipt.
7. Recovery Data (Spikes & Surrogates) - where chromatographic interference does not allow the determination of Recovery the term "INT" appears against that analyte.
8. Polychlorinated Biphenyls are spiked only using Aroclor 1260 in Matrix Spikes and LCS.
9. For Matrix Spikes and LCS results a dash " -" in the report means that the specific analyte was not added to the QC sample.
10. Duplicate RPDs are calculated from raw analytical data thus it is possible to have two sets of data.
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 5 of 11
Report Number: 561801-W
Quality Control Results
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Method Blank
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) ug/L < 0.05 0.05 Pass
Perfluoropentanoic acid (PFPeA) ug/L < 0.01 0.01 Pass
Perfluorohexanoic acid (PFHxA) ug/L < 0.01 0.01 Pass
Perfluoroheptanoic acid (PFHpA) ug/L < 0.01 0.01 Pass
Perfluorooctanoic acid (PFOA) ug/L < 0.01 0.01 Pass
Perfluorononanoic acid (PFNA) ug/L < 0.01 0.01 Pass
Perfluorodecanoic acid (PFDA) ug/L < 0.01 0.01 Pass
Perfluoroundecanoic acid (PFUnA) ug/L < 0.01 0.01 Pass
Perfluorododecanoic acid (PFDoA) ug/L < 0.01 0.01 Pass
Perfluorotridecanoic acid (PFTrDA) ug/L < 0.01 0.01 Pass
Perfluorotetradecanoic acid (PFTeDA) ug/L < 0.01 0.01 Pass
Method Blank
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) ug/L < 0.05 0.05 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) ug/L < 0.05 0.05 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) ug/L < 0.05 0.05 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) ug/L < 0.05 0.05 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) ug/L < 0.05 0.05 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) ug/L < 0.05 0.05 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) ug/L < 0.05 0.05 Pass
Method Blank
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) ug/L < 0.01 0.01 Pass
Perfluoropentanesulfonic acid (PFPeS) ug/L < 0.01 0.01 Pass
Perfluorohexanesulfonic acid (PFHxS) ug/L < 0.01 0.01 Pass
Perfluoroheptanesulfonic acid (PFHpS) ug/L < 0.01 0.01 Pass
Perfluorooctanesulfonic acid (PFOS) ug/L < 0.01 0.01 Pass
Perfluorodecanesulfonic acid (PFDS) ug/L < 0.01 0.01 Pass
Method Blank
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) ug/L < 0.05 0.05 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) ug/L < 0.01 0.01 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) ug/L < 0.01 0.01 Pass
Method Blank
Chloride mg/L < 1 1 Pass
Sulphate (as SO4) mg/L < 5 5 Pass
Method Blank
Alkalinity (speciated)
Total Alkalinity (as CaCO3) mg/L < 20 20 Pass
Method Blank
Alkali Metals
Calcium mg/L < 0.5 0.5 Pass
Magnesium mg/L < 0.5 0.5 Pass
Potassium mg/L < 0.5 0.5 Pass
Sodium mg/L < 0.5 0.5 Pass
LCS - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA) % 102 50-150 Pass
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 6 of 11
Report Number: 561801-W
Test Units Result 1 AcceptanceLimits
PassLimits
QualifyingCode
Perfluoropentanoic acid (PFPeA) % 119 50-150 Pass
Perfluorohexanoic acid (PFHxA) % 101 50-150 Pass
Perfluoroheptanoic acid (PFHpA) % 98 50-150 Pass
Perfluorooctanoic acid (PFOA) % 102 50-150 Pass
Perfluorononanoic acid (PFNA) % 103 50-150 Pass
Perfluorodecanoic acid (PFDA) % 103 50-150 Pass
Perfluoroundecanoic acid (PFUnA) % 104 50-150 Pass
Perfluorododecanoic acid (PFDoA) % 104 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) % 103 50-150 Pass
Perfluorotetradecanoic acid (PFTeDA) % 109 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA) % 102 50-150 Pass
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA) % 106 50-150 Pass
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA) % 96 50-150 Pass
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol (N-MeFOSE) % 112 50-150 Pass
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE) % 108 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA) % 108 50-150 Pass
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA) % 103 50-150 Pass
LCS - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS) % 104 50-150 Pass
Perfluoropentanesulfonic acid (PFPeS) % 109 50-150 Pass
Perfluorohexanesulfonic acid (PFHxS) % 98 50-150 Pass
Perfluoroheptanesulfonic acid (PFHpS) % 115 50-150 Pass
Perfluorooctanesulfonic acid (PFOS) % 97 50-150 Pass
Perfluorodecanesulfonic acid (PFDS) % 83 50-150 Pass
LCS - % Recovery
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2 FTS) % 103 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS) % 102 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2 FTS) % 89 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2 FTS) % 77 50-150 Pass
LCS - % Recovery
Chloride % 112 70-130 Pass
Sulphate (as SO4) % 114 70-130 Pass
LCS - % Recovery
Alkalinity (speciated)
Total Alkalinity (as CaCO3) % 94 70-130 Pass
LCS - % Recovery
Alkali Metals
Potassium % 104 70-130 Pass
Sodium % 114 70-130 Pass
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Spike - % Recovery
Perfluoroalkyl carboxylic acids (PFCAs) Result 1
Perfluorobutanoic acid (PFBA) M17-Se02960 NCP % 98 50-150 Pass
Perfluoropentanoic acid (PFPeA) M17-Se02960 NCP % 103 50-150 Pass
Perfluorohexanoic acid (PFHxA) M17-Se02960 NCP % 99 50-150 Pass
Perfluoroheptanoic acid (PFHpA) M17-Se02960 NCP % 94 50-150 Pass
Perfluorooctanoic acid (PFOA) M17-Se02960 NCP % 98 50-150 Pass
Perfluorononanoic acid (PFNA) M17-Se02960 NCP % 98 50-150 Pass
Perfluorodecanoic acid (PFDA) M17-Se02960 NCP % 98 50-150 Pass
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 7 of 11
Report Number: 561801-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Perfluoroundecanoic acid (PFUnA) M17-Se02960 NCP % 95 50-150 Pass
Perfluorododecanoic acid (PFDoA) M17-Se02960 NCP % 95 50-150 Pass
Perfluorotridecanoic acid (PFTrDA) M17-Se02960 NCP % 88 50-150 Pass
Perfluorotetradecanoic acid(PFTeDA) M17-Se02960 NCP % 99 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonamides (PFASAs) Result 1
Perfluorooctane sulfonamide(FOSA) M17-Se02960 NCP % 96 50-150 Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) M17-Se02960 NCP % 100 50-150 Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) M17-Se02960 NCP % 91 50-150 Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) M17-Se02960 NCP % 101 50-150 Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) M17-Se02960 NCP % 95 50-150 Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) M17-Se02960 NCP % 100 50-150 Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) M17-Se02960 NCP % 91 50-150 Pass
Spike - % Recovery
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1
Perfluorobutanesulfonic acid(PFBS) M17-Se02960 NCP % 99 50-150 Pass
Perfluoropentanesulfonic acid(PFPeS) M17-Se02960 NCP % 103 50-150 Pass
Perfluorohexanesulfonic acid(PFHxS) M17-Se02960 NCP % 96 50-150 Pass
Perfluoroheptanesulfonic acid(PFHpS) M17-Se02960 NCP % 100 50-150 Pass
Perfluorooctanesulfonic acid(PFOS) M17-Se02960 NCP % 93 50-150 Pass
Perfluorodecanesulfonic acid(PFDS) M17-Se02960 NCP % 81 50-150 Pass
Spike - % Recovery
n:2 Fluorotelomer sulfonic acids Result 1
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) M17-Se02960 NCP % 95 50-150 Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) M17-Se02960 NCP % 87 50-150 Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) M17-Se02960 NCP % 81 50-150 Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) M17-Se02960 NCP % 75 50-150 Pass
Spike - % Recovery
Result 1
Chloride M17-Se04660 NCP % 102 70-130 Pass
Sulphate (as SO4) S17-Se04262 NCP % 94 70-130 Pass
Spike - % Recovery
Alkali Metals Result 1
Calcium M17-Se04116 NCP % 106 70-130 Pass
Magnesium M17-Se05120 NCP % 95 70-130 Pass
Potassium M17-Se05371 NCP % 121 70-130 Pass
Sodium M17-Se05371 NCP % 117 70-130 Pass
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 8 of 11
Report Number: 561801-W
Test Lab Sample ID QASource Units Result 1 Acceptance
LimitsPass
LimitsQualifying
Code
Duplicate
Perfluoroalkyl carboxylic acids (PFCAs) Result 1 Result 2 RPD
Perfluorobutanoic acid (PFBA) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Perfluoropentanoic acid (PFPeA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanoic acid (PFHxA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanoic acid (PFHpA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanoic acid (PFOA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorononanoic acid (PFNA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanoic acid (PFDA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroundecanoic acid (PFUnA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorododecanoic acid (PFDoA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotridecanoic acid (PFTrDA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorotetradecanoic acid(PFTeDA) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
Perfluoroalkane sulfonamides (PFASAs) Result 1 Result 2 RPD
Perfluorooctane sulfonamide(FOSA) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methylperfluoro-1-octanesulfonamide (N-MeFOSA) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethylperfluoro-1-octanesulfonamide (N-EtFOSA) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-methylperfluoro-1-octanesulfonamido)-ethanol (N-MeFOSE) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol (N-EtFOSE) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-ethyl-perfluorooctanesulfonamidoaceticacid (N-EtFOSAA) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
N-methyl-perfluorooctanesulfonamidoaceticacid (N-MeFOSAA) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
Duplicate
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Result 1 Result 2 RPD
Perfluorobutanesulfonic acid(PFBS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoropentanesulfonic acid(PFPeS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorohexanesulfonic acid(PFHxS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluoroheptanesulfonic acid(PFHpS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorooctanesulfonic acid(PFOS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Perfluorodecanesulfonic acid(PFDS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Duplicate
n:2 Fluorotelomer sulfonic acids Result 1 Result 2 RPD
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2FTS) B17-Se07707 NCP ug/L < 0.05 < 0.05 <1 30% Pass
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
1H.1H.2H.2H-perfluorododecanesulfonic acid(10:2 FTS) B17-Se07707 NCP ug/L < 0.01 < 0.01 <1 30% Pass
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 9 of 11
Report Number: 561801-W
Duplicate
Result 1 Result 2 RPD
Chloride M17-Se04900 NCP mg/L 560 560 <1 30% Pass
Sulphate (as SO4) S17-Se04261 NCP mg/L 350 340 1.4 30% Pass
Duplicate
Alkalinity (speciated) Result 1 Result 2 RPD
Total Alkalinity (as CaCO3) M17-Se04665 NCP mg/L 430 470 8.0 30% Pass
Duplicate
Alkali Metals Result 1 Result 2 RPD
Calcium M17-Se04116 NCP mg/L 6.9 7.0 2.0 30% Pass
Magnesium M17-Se05120 NCP mg/L 8.0 7.7 4.0 30% Pass
Potassium M17-Se04116 NCP mg/L 2.8 2.7 3.0 30% Pass
Sodium M17-Se05371 NCP mg/L 800 670 16 30% Pass
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 10 of 11
Report Number: 561801-W
Comments
Sample IntegrityCustody Seals Intact (if used) N/A
Attempt to Chill was evident No
Sample correctly preserved Yes
Appropriate sample containers have been used Yes
Sample containers for volatile analysis received with minimal headspace Yes
Samples received within HoldingTime Yes
Some samples have been subcontracted No
Qualifier Codes/Comments
Code DescriptionN09 Quantification of linear and branched isomers has been conducted as a single total response using the relative response factor for the corresponding linear/branched standard.
N11
Isotope dilution is used for calibration of each native compound for which an exact labelled analogue is available (Isotope Dilution Quantitation). The isotopically labelledanalogues allow identification and recovery correction of the concentration of the associated native PFAS compounds. Where the native PFAS compound does not have labelledanalogue then the quantification is made using the Extracted Internal Standard Analyte with the closest retention time to the analyte and no recovery correction has been made(Internal Standard Quantitation).
Authorised By
Mary Makarios Analytical Services Manager
Alex Petridis Senior Analyst-Metal (VIC)
Huong Le Senior Analyst-Inorganic (VIC)
Jonathon Angell Senior Analyst-Organic (QLD)
Glenn Jackson
National Operations Manager
- Indicates Not Requested
* Indicates NATA accreditation does not cover the performance of this service
Measurement uncertainty of test data is available on request or please click here.Eurofins | mgt shall not be liable for loss, cost, damages or expenses incurred by the client, or any other person or company, resulting from the use of any information or interpretation given in this report. In no case shall Eurofins | mgt be liable for consequential damages including, but notlimited to, lost profits, damages for failure to meet deadlines and lost production arising from this report. This document shall not be reproduced except in full and relates only to the items tested. Unless indicated otherwise, the tests were performed on the samples as received.
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 11 of 11
Report Number: 561801-W
Certificate of Analysis
Coffey Environments Pty Ltd VIC
Level 1, 436 Johnston Street
Abbotsford
VIC 3067
Attention: Ian Newby
Report 561805-W
Project name DOD TINDAL
Project ID 754-MELEN199420
Received Date Sep 04, 2017
Client Sample ID 0990_PB035_170829
Sample Matrix Water
Eurofins | mgt Sample No. M17-Se04620
Date Sampled Aug 29, 2017
Test/Reference LOR Unit
Perfluoroalkyl carboxylic acids (PFCAs)
Perfluorobutanoic acid (PFBA)N11 0.05 ug/L < 0.05
Perfluoropentanoic acid (PFPeA)N11 0.01 ug/L N090.01
Perfluorohexanoic acid (PFHxA)N11 0.01 ug/L N090.06
Perfluoroheptanoic acid (PFHpA)N11 0.01 ug/L < 0.01
Perfluorooctanoic acid (PFOA)N11 0.01 ug/L N090.02
Perfluorononanoic acid (PFNA)N11 0.01 ug/L < 0.01
Perfluorodecanoic acid (PFDA)N11 0.01 ug/L < 0.01
Perfluoroundecanoic acid (PFUnA)N11 0.01 ug/L < 0.01
Perfluorododecanoic acid (PFDoA)N11 0.01 ug/L < 0.01
Perfluorotridecanoic acid (PFTrDA) 0.01 ug/L < 0.01
Perfluorotetradecanoic acid (PFTeDA)N11 0.01 ug/L < 0.01
13C4-PFBA (surr.) 1 % 80
13C5-PFPeA (surr.) 1 % 81
13C5-PFHxA (surr.) 1 % 88
13C4-PFHpA (surr.) 1 % 86
13C8-PFOA (surr.) 1 % 75
13C5-PFNA (surr.) 1 % 65
13C6-PFDA (surr.) 1 % 66
13C2-PFUnDA (surr.) 1 % 59
13C2-PFDoDA (surr.) 1 % 57
13C2-PFTeDA (surr.) 1 % 40
Perfluoroalkane sulfonamides (PFASAs)
Perfluorooctane sulfonamide (FOSA)N11 0.05 ug/L < 0.05
N-methylperfluoro-1-octane sulfonamide (N-MeFOSA)N11 0.05 ug/L < 0.05
N-ethylperfluoro-1-octane sulfonamide (N-EtFOSA)N11 0.05 ug/L < 0.05
2-(N-methylperfluoro-1-octane sulfonamido)-ethanol(N-MeFOSE)N11 0.05 ug/L < 0.05
2-(N-ethylperfluoro-1-octane sulfonamido)-ethanol (N-EtFOSE)N11 0.05 ug/L < 0.05
N-ethyl-perfluorooctanesulfonamidoacetic acid (N-EtFOSAA)N11 0.05 ug/L < 0.05
N-methyl-perfluorooctanesulfonamidoacetic acid (N-MeFOSAA)N11 0.05 ug/L < 0.05
13C8-FOSA (surr.) 1 % 74
D3-N-MeFOSA (surr.) 1 % 46
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 1 of 11
Report Number: 561805-W
NATA AccreditedAccreditation Number 1261Site Number 1254
Accredited for compliance with ISO/IEC 17025 – TestingThe results of the tests, calibrations and/ormeasurements included in this document are traceableto Australian/national standards.
Client Sample ID 0990_PB035_170829
Sample Matrix Water
Eurofins | mgt Sample No. M17-Se04620
Date Sampled Aug 29, 2017
Test/Reference LOR Unit
Perfluoroalkane sulfonamides (PFASAs)
D5-N-EtFOSA (surr.) 1 % 28
D7-N-MeFOSE (surr.) 1 % 47
D9-N-EtFOSE (surr.) 1 % 40
D5-N-EtFOSAA (surr.) 1 % 58
D3-N-MeFOSAA (surr.) 1 % 57
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs)
Perfluorobutanesulfonic acid (PFBS)N11 0.01 ug/L 0.06
Perfluoropentanesulfonic acid (PFPeS) 0.01 ug/L N090.06
Perfluorohexanesulfonic acid (PFHxS)N11 0.01 ug/L N090.38
Perfluoroheptanesulfonic acid (PFHpS) 0.01 ug/L N090.02
Perfluorooctanesulfonic acid (PFOS)N11 0.01 ug/L N090.65
Perfluorodecanesulfonic acid (PFDS) 0.01 ug/L < 0.01
13C3-PFBS (surr.) 1 % 83
18O2-PFHxS (surr.) 1 % 72
13C8-PFOS (surr.) 1 % 54
n:2 Fluorotelomer sulfonic acids
1H.1H.2H.2H-perfluorohexanesulfonic acid (4:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorooctanesulfonic acid (6:2 FTS)N11 0.05 ug/L < 0.05
1H.1H.2H.2H-perfluorodecanesulfonic acid (8:2FTS)N11 0.01 ug/L < 0.01
1H.1H.2H.2H-perfluorododecanesulfonic acid (10:2FTS) 0.01 ug/L < 0.01
13C2-4:2 FTS (surr.) 1 % 48
13C2-6:2 FTS (surr.) 1 % 38
13C2-8:2 FTS (surr.) 1 % 38
PFASs Summations
Sum (PFHxS + PFOS) 0.01 ug/L 1.03
Sum of US EPA PFAS (PFOS + PFOA) 0.01 ug/L 0.67
Sum of enHealth PFAS (PFHxS + PFOS + PFOA) 0.01 ug/L 1.05
Sum of WA DER PFAS (n=10) 0.05 ug/L 1.18
Sum of PFASs (n=28) 0.1 ug/L 1.26
Chloride 1 mg/L 10
Sulphate (as SO4) 5 mg/L < 5
Alkalinity (speciated)
Total Alkalinity (as CaCO3) 20 mg/L 420
Alkali Metals
Calcium 0.5 mg/L 73
Magnesium 0.5 mg/L 32
Potassium 0.5 mg/L 1.1
Sodium 0.5 mg/L 4.8
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 2 of 11
Report Number: 561805-W
Sample HistoryWhere samples are submitted/analysed over several days, the last date of extraction and analysis is reported.A recent review of our LIMS has resulted in the correction or clarification of some method identifications. Due to this, some of the method reference information on reports has changed. However,no substantive change has been made to our laboratory methods, and as such there is no change in the validity of current or previous results (regarding both quality and NATA accreditation).
If the date and time of sampling are not provided, the Laboratory will not be responsible for compromised results should testing be performed outside the recommended holding time.
Description Testing Site Extracted Holding Time
Per- and Polyfluorinated Alkyl Substances (PFASs)
Perfluoroalkyl carboxylic acids (PFCAs) Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonamides (PFASAs) Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Perfluoroalkane sulfonic acids & Perfluoroalkane sulfonates (PFSAs) Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
n:2 Fluorotelomer sulfonic acids Brisbane Sep 11, 2017 14 Day
- Method: LTM-ORG-2100 Per- and Polyfluorinated Alkyl Substances by LC-MS/MS
Chloride Melbourne Sep 06, 2017 28 Day
- Method: LTM-INO-4090 Chloride by Discrete Analyser
Sulphate (as SO4) Melbourne Sep 06, 2017 28 Day
- Method: LTM-INO-4110 Sulfate by Discrete Analyser
Alkalinity (speciated) Melbourne Sep 06, 2017 14 Day
- Method: APHA 2320 Alkalinity by Titration
Alkali Metals Melbourne Sep 06, 2017 180 Day
- Method: USEPA 6010 Alkali Metals
Date Reported: Sep 13, 2017
Eurofins | mgt 2-5 Kingston Town Close, Oakleigh, Victoria, Australia, 3166
ABN : 50 005 085 521 Telephone: +61 3 8564 5000
Page 3 of 11
Report Number: 561805-W